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Lewis Structures Molecular Geometry and Polarity 1A KEY

The document describes the molecular geometry of various compounds including NO−, HCN, NO2+, CH4, CO2, H2O, O3, NO2−, HNO3, CH3OH, CH3COOH, and H3BO3. It provides the Lewis structure, electron domain geometry, molecular geometry, bond angles, and indicates whether each molecule is polar or nonpolar. Key features include linear, bent, trigonal planar, tetrahedral geometries and sp, sp2, sp3 hybridization. Bond angles are reported as less than or equal to 109.5°, 120°, and 180° as appropriate for the different molecular geometries.

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0% found this document useful (0 votes)
517 views3 pages

Lewis Structures Molecular Geometry and Polarity 1A KEY

The document describes the molecular geometry of various compounds including NO−, HCN, NO2+, CH4, CO2, H2O, O3, NO2−, HNO3, CH3OH, CH3COOH, and H3BO3. It provides the Lewis structure, electron domain geometry, molecular geometry, bond angles, and indicates whether each molecule is polar or nonpolar. Key features include linear, bent, trigonal planar, tetrahedral geometries and sp, sp2, sp3 hybridization. Bond angles are reported as less than or equal to 109.5°, 120°, and 180° as appropriate for the different molecular geometries.

Uploaded by

rsleo
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© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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MOLECULAR GEOMETRY NAME: Key

Last First

Formula Lewis Structure e− Domain Molecular Bond Angle Molecular Geometry Polar?
(Show Resonance Structures) Geometry, Geometry (Use wedges and dashed lines)
Hybridization Show bond angles.
- -
NO− N O Linear, sp2 Linear NA N O Ion

Linear Linear 180° H C N


HCN H C N sp Yes
180°

+ 180°
NO2 + O N O Linear, sp Linear 180° + Ion
O N O

H H
109.5°
CH4 H C H Tetrahedral Tetrahedral 109.5° No
C
sp3 H H
H H

Linear O C O
CO2 sp Linear 180° No
O C O
180°

O
H2O Tetrahedral Bent <109.5° Yes
H O H
sp3 H H
<109.5°
O O O
Trigonal O
O3 Planar Bent <120° Yes
O O
sp2
O O O <1200

Reyes
MOLECULAR GEOMETRY
Formula Lewis Structure e− Domain Molecular Bond Molecular Geometry Polar?
(Show Resonance Structures) Geometry, Geometry Angle (Use wedges and dashed lines)
Hybridization Show bond angles.
O N O
N
NO2− Trigonal Bent <120° Ion
Planar, sp2 <120°
O O
O N O
O
Trigonal Planar Trigonal Planar <120° O
on N, sp2 H
O N O H <109.5°
O N
HNO3 Tetrahedral on <120° Yes
O, sp3 Bent <109.5°
O
O

O N O H
H Tetrahedral 109.5° on H
Tetrahedral on around C C 109.5°
<109.5°
CH3OH C, sp3 Less than C H
Yes
H C O H Tetrahedral on Bent around O 109° H
O
O, sp3 on O H
H
H
H O C1, sp3 Tetrahedral 109.5° 109.5°
CH3COOH C2, sp2 Trig. planar <120° O Yes
C
O, sp3 Bent <109.5° H
H C C O H C
1 2 H <109.5°
<120°
H O H
H O B O H Trigonal Planar 120°
O O
on B Trigonal Planar 120° H H
H3BO3 O
sp2 B No
or Bent on O’s Bent <109.5
B(OH)3 sp3 <109.5°
H O
H

Reyes
MOLECULAR GEOMETRY
Formula Lewis Structure e− Domain Molecular Bond Molecular Geometry Polar?
(Show Resonance Structures) Geometry, Geometry Angle (Use wedges and dashed lines)
Hybridization Show bond angles.
Cl Cl
120° 90°
Cl Cl
PCl5 Trigonal Trigonal and No
(violate Cl P Bipyramidal Bipyramidal 90° Cl P
120°
octet Cl sp3d
Cl
rule) Cl Cl

I 3− - Trigonal -
(violate I I I Bipyramidal Linear 180° I I I Ion
octet sp3d
rule)
F 90° F 90°
and F
SF4 Trigonal Seesaw Less S <120° Yes
F S F
(violate Bipyramidal than F
octet sp3d 120°
F
rule) F

- -
F F
F F 90°
PF6− Octahedral Octahedral 90° F F Ion
(violate P sp3d2 90°
P
octet
rule) F F F F
F F

Reyes

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