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BasicDeriv PDF

This document discusses basic derivatives of volume (V) with respect to temperature (T) and pressure (P). It defines the isobaric thermal expansivity (α) and isothermal compressibility (κ) which describe how V changes with T at constant P, and with P at constant T, respectively. It then shows that the total change in V (dV) can be expressed as a function of α, κ, dT and dP. The document questions whether α and κ fully describe the mechanical behavior and derives an expression for the derivative of P with respect to T at constant V.

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senahid
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57 views

BasicDeriv PDF

This document discusses basic derivatives of volume (V) with respect to temperature (T) and pressure (P). It defines the isobaric thermal expansivity (α) and isothermal compressibility (κ) which describe how V changes with T at constant P, and with P at constant T, respectively. It then shows that the total change in V (dV) can be expressed as a function of α, κ, dT and dP. The document questions whether α and κ fully describe the mechanical behavior and derives an expression for the derivative of P with respect to T at constant V.

Uploaded by

senahid
Copyright
© © All Rights Reserved
Available Formats
Download as PDF, TXT or read online on Scribd
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Basic Derivatives

V(T,P)

∂V ∂V
dV = ( ∂T )P dT + ( ∂P )T dP

1 ∂V
α = V ( )P isobaric thermal expansivity, coefficient of thermal expansion
∂T
1 ∂V
β = κ = – V ( )T isothermal compressibility
∂P
dV = V α dT - V κ dP
do α and κ give everything we need to know about mechanical behavior?
(∂P ) =?
∂T V
∂V ∂V
0 = dV = ( ) dT + ( )T dP
∂T P ∂P

(∂V)
∂P T
dP = –(
∂V
) dT
∂T P
∂V
–( ) dT
∂T P
dP =
(∂V )
∂P T
∂V
–( )
(∂P ) =
∂T V
∂T P
(∂V)
∂P T
for small changes V doesn't change much: V ≅ Vo
cst. P dV = V α dT
V2 T2
∫ dV = ∫ V α dT ∆V = Vo α ∆T
V1 T1

cst. T dV = -V κ dP
∆V = -Vo κ ∆P

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