CHEMISTRY - NCERT UPDATES

FOR CLASS XII

Dear Students and Teachers,
NCERT has revised the previous edition of Chemistry book and incorporated certain new facts, gures and
examples. Ambiguous and controversial facts have also been removed as well as corrections have been made (Divisions of Aakash Educational Services Limited)
wherever required.
Aakash brings to you, all the applied changes/additions/deletions in new text of NCERT.

CHAPTER 1 - THE SOLID STATE

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You must have noticed that when tiles are placed to cover a oor, a repeated pattern
is generated. If after setting tiles on oor we mark a point at same location in all the
tiles (e.g. Centre of the tile) and see the marked positions only ignoring the tiles, we
obtain a set of points. This set of points is the scaffolding on which pattern has been
developed by placing tiles. This scaffolding is a space lattice on which two-dimensional
pattern has been developed by placing structural units on its set of points (i.e. tile in
this case). The structural unit is called basis or motif. When motifs are placed on
points in space lattice, a pattern is generated. In crystal structure, motif is a
molecule, atom or ion. A space lattice, also called a crystal lattice, is the pattern of
points representing the locations of these motifs. In other words, space lattice is an
abstract scaffolding for crystal structure. When we place motifs in an identical
The main characteristic of crystalline solids is a regular and repeating pattern of
manner on points of space lattice, we get crystal structure. Fig. 1.5 shows a motif, a
constituent particles. If the three dimensional arrangement of constituent particles in
two-dimensional lattice and a hypothetical two-dimensional crystal structure
a crystal is represented diagrammatically, in which each particle is depicted as a point,
obtained by placing motifs in the two-dimensional lattice. Spacial arrangement of
the arrangement is called crystal lattice. Thus, a regular three dimensional
lattice points gives rise to different types of lattices. Fig 1.6 shows arrangement of
arrangement of points in space is called a crystal lattice. A portion of a crystal lattice
points in two different lattices. In the case of crystalline solids, space lattice is a
is shown in Fig. 1.5. There are only 14 possible three dimensional lattices. These are
three-dimensional array of points. The crystal structure is obtained by associating
called Bravais Lattices (after the French mathematician who rst described them).
structurral motifs with lattice points. Each repeated basis or motif has same
The following are the characteristics of a crystal lattice:
structure and same spacial orientation as other one in a crystal. The environment of
(a) Each point in a lattice is called lattice point or lattice site. (b) Each point in a crystal
each motif is same throughout the crystal except for on surface. Following are the
lattice represents one constituent particle which may be an atom, a molecule (group
characteristics of a crystal lattice:
of atoms) or an ion. (c) Lattice points are joined by straight lines to bring out the
(a) Each point in a lattice is called lattice point or lattice site. (b) Each point in a crystal
geometry of the lattice. Unit cell is the smallest portion of a crystal lattice which,
lattice represents one constituent particle which may be an atom, a molecule (group
when repeated in different directions, generates the entire lattice. A unit cell is
of atoms) or an ion. (c) Lattice points are joined by straight lines to bring out the
characterised by: (i) its dimensions along the three edges, a, b and c. These edges may
geometry of the lattice. We need only a small part of the space lattice of a crystal to
or may not be mutually perpendicular. (ii) angles between the edges, α (between b and
spacify crystal completely. This small part is called unit cell. One can choose unit cell in
c) β (between a and c) and γ (between a and b). Thus, a unit cell is characterised by six
many ways. Normally that cell is chosen which has perpendicular sides of shortest
parameters, a, b, c, α, β and γ. These parameters of a typical unit cell are shown in
length and one can construct entire crystal by translational displacement of the unit
Fig. 1.6.
cell in three dimensions. Fig. 1.7 shows movement of unit cell of a two-dimensional
lattice to construct the entire crystal structure. Also, unit cells have shapes such
that these ll the whole lattice without leaving space between cells. In two dimensions
a parallelogram with side of length ‘a’ and ‘b’ and an angle r between these sides is
1. 7-9 1.4 chosen as unit cell. Possible unit cells in two dimensions are shown in Fig. 1.8. A
portion of three-dimensional crystal lattice and its unit cell is shown in Fig. 1.9. In the
three-dimensional crystal structure, unit cell is characterised by: (i) its dimensions
along the three edges a, b and c. These edges may or may not be mutually
perpendicular. (ii) angles between the edges, a (between b and c), b (between a and c)
and g (between a and b). Thus, a unit cell is characterised by six parameters a, b, c, a ,
b and g. These parameters of a typical unit cell are shown in Fig. 1.10.
 CHAPTER 1 - THE SOLID STATE
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1. 7-9 1.4

CHAPTER 5 - SURFACE CHEMISTRY

If two particles of an insoluble material (precipitate) do not have double layers they
can come close enough and attractive van der Waals forces pull them together. When
particles possess double layer as shown in Fig. 5.13, the overall effect is that particles
The presence of equal and similar charges on colloidal particles is largely responsible in
repel each other at large distances of separation. This repulsion prevents their close
providing stability to the colloidal solution, because the repulsive forces between
approach. They remain dispersed and colloid is stabilised. The addition of more
charged particles having same charge prevent them from coalescing or aggregating
electrolytes to sol supresses the diffused double layer and reduces the zita potential.
when they come closer to one another.
This decreases the electrostatic repulsion between particles to a large extent and
colloid precipitates. That is why colloid is particularly sensitive to oppositely
chargedions.

2. 143 5.13

CHAPTER 6 - GENERAL PRINCIPLES AND PROCESSES OF ISOLATION OF ELEMENTS

A few elements like carbon, sulphur, gold and noble gases, occur in free state while “The history of civilisation is linked to the use of metals in antiquity in many ways.
others in combined forms in the earth’s crust. The extraction and isolation of an Different periods of early human civilisations have been named after metals. The skill of
element from its combined form involves various principles of chemistry. A particular extraction of metals gave many metals and brought about several changes in the
element may occur in a variety of compounds. The process of etallurgy and isolation human society. It gave weapons, tools, ornaments, utensils, etc., and enriched the
should be such that it is chemically feasible and commercially viable. Still, some general cultural life. The ‘Seven metals of antiquity’, as they are sometimes called, are gold,
principles are common to all the extraction processes of metals. For obtaining a copper, silver, lead, tin, iron and mercury. Although modern metallurgy had
particular metal, rst we look for minerals which are naturally occurring chemical exponential growth after Industrial Revolution, it is interesting to note that many
substances in the earth’s crust obtainable by mining. Out of many minerals in which a modern concepts in metallurgy have their roots in ancient practices that pre-dated
metal may be found, only a few are viable to be used as sources of that metal. Such the Industrial Revolution. For over 7000 years, India has had a rich tradition of
3. 149-152 minerals are known as ores. Rarely, an ore contains only a desired substance. It is metallurgical skills. The two important sources for the history of Indian metallurgy are
usually contaminated with earthly or undesired materials known as gangue. The archeological excavations and literary evidences. The rst evidence of metal in Indian
extraction and isolation of metals from ores involve the following major steps: • subcontinent comes from Mehrgarh in Baluchistan, where a small copper bead, dated
Concentration of the ore, • Isolation of the metal from its concentrated ore, and • to about 6000 BCE was found. It is however thought to be native copper, which has
Purication of the metal. The entire scientic and technological process used for not been extracted from the ore. Spectrometric studies on copper ore samples
isolation of the metal from its ores is known as metallurgy. In the present Unit, rst we obtained from the ancient mine pits at Khetri in Rajasthan and on metal samples cut
shall describe various steps for effective concentration of ores. After that we shall from representative Harappan artefacts recovered from Mitathal in Haryana and
discuss the principles of some of the common metallurgical processes. Those eight other sites distributed in Rajasthan, Gujarat, Madhya Pradesh and Maharashtra
principles shall include the thermodynamic and electrochemical aspects involved in the prove that copper metallurgy in India dates back to the Chalcolithic cultures in the
effective reduction of the concentrated ore to the metal. subcontinent. Indian chalcolithic copper objects were in all probability made
 CHAPTER 6 - GENERAL PRINCIPLES AND PROCESSES OF ISOLATION OF ELEMENTS
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indigenously. The ore for extraction of metal for making the objects was obtained from
chalcopyrite ore deposits in Aravalli Hills. Collection of archeological texts from
copper-plates and rock-inscriptions have been compiled and published by the
Archeological Survey of India during the past century. Royal records were engraved
on copper plates (tamra-patra). Earliest known copperplate has a Mauryan record
that mentions famine relief efforts. It has one of the very few pre-Ashoka Brahmi
inscriptions in India. Harappans also used gold and silver, as well as their joint alloy
electrum. Variety of ornaments such as pendants, bangles, beads and rings have been
found in ceramic or bronze pots. Early gold and silver ornaments have been found from
Indus Valley sites such as Mohenjodaro (3000 BCE). These are on display in the
National Museum, New Delhi. India has the distinction of having the deepest ancient
gold mines in the world, in the Maski region of Karnataka. Carbon dating places them in
mid 1st millennium BCE. Hymns of Rigveda give earliest indirect references to the
alluvial placer gold deposits in India. The river Sindhu was an important source of gold
in ancient times. It is interesting that the availability of alluvial placer gold in the river
Sindhu has been reported in modern times also. It has been reported that there are
great mines of gold in the region of Mansarovar and in Thokjalyug even now. The Pali
text, Anguttara Nikaya narrates the process of the recovery of gold dust or particles
from alluvial placer gold deposits. Although evidence of gold rening is available in Vedic
texts, it is Kautilya’s Arthashastra, authored probably in 3rd or 4th century BCE,
during Mauryan era, which has much data on prevailing chemical practices in a long
section on mines and minerals including metal ores of gold, silver, copper, lead, tin and
iron. Kautilya describes a variety of gold called rasviddha, which is naturally occurring
gold solution. Kalidas also mentioned about such solutions. It is astonishing how
people recognised such solutions. The native gold has different colours depending
upon the nature and amount of impurity present in it. It is likely that the different
colours of native gold were a major driving force for the development of gold rening.
Recent excavations in central parts of Ganges Valley and Vindhya hills have shown that
iron was produced there possibly as early as in 1800 BCE. In the recent excavations
conducted by the Uttar Pradesh State Archeological Department, iron furnaces,
artefacts, tuyers and layers of slag have been found. Radiocarbon dating places them
between BCE 1800 and 1000. The results of excavation indicate that the knowledge
of iron smelting and manufacturing of iron artefacts was well known in Eastern
Vindhyas and it was in use in the Central Ganga Plains, at least from the early 2nd
millennium BCE. The quantity and types of iron artefacts and the level of technical
advancements indicate that working of iron would have been introduced much earlier.
The evidence indicates early use of iron in other areas of the country, which proves
that India was indeed an independent centre for the development of the working of
iron. Iron smelting and the use of iron was especially established in South Indian
megalithic cultures. The forging of wrought iron seems to have been at peak in India in
the Ist millennium CE. Greek accounts report the manufacture of steel in India by
crucible process. In this process, iron, charcoal and glass were mixed together in a
3. 149-152 crucible and heated until the iron melted and absorbed the carbon. India was a major
innovator in the production of advanced quality steel. Indian steel was called ‘the
Wonder Material of the Orient’. A Roman historian, Quintus Curtius, records that one
of the gifts Porus of Taxila (326 BCE) gave to Alexander the Great was some two-and-
a-half tons of Wootz steel. Wootz steel is primarily iron containing a high proportion of
carbon (1.0 – 1.9%). Wootz is the English version of the word ‘ukku’ which is used for
steel in Karnataka and Andhra Pradesh. Literary accounts suggest that Indian Wootz
steel from southern part of the Indian subcontinent was exported to Europe, China
and Arab world. It became prominent in the Middle East where it was named
asDamasus Steel. Michael Faraday tried to duplicate this steel by alloying iron with a
variety of metals, including noble metals, but failed. When iron ore is reduced in solid
state by using charcoal, porous iron blocks are formed. Therefore, reduced iron blocks
are also called sponge iron blocks. Any useful product can be obtained from this
material only after removing the porosity by hot forging. The iron so obtained is
termed as wrought iron. An exciting example of wrought iron produced in ancient India
is the world famous Iron Pillar. It was erected in its present position in Delhi in 5th
century CE. The Sanskrit inscription engraved on it suggests that it was brought here
from elsewhere during the Gupta Period. The average composition (weight%) of the
components present in the wrought iron of the pillar, besides iron, are 0.15% C,
0.05% Si, 0.05% Mn, 0.25% P, 0.005% Ni, 0.03%Cu and 0.02% N. The most
signicant aspect of the pillar is that there is no sign of corrosion inspite of the fact
that it has been exposed to the atmosphere for about 1,600 years. Radiocarbon
dating of charcoal from iron slag revealed evidence of continuous smelting in Khasi
Hills of Meghalaya. The slag layer, which is dated to 353 BCE – CE 128, indicates that
Khasi Hill region is the earliest iron smelting site studied in the entire region of North
East India. The remnants of former iron-ore excavation and iron manufacturing are
visible even now in the landscape of Khasi Hills. British naturalists who visited
Meghalaya in early 19th century described the iron industry that had developed in the
upper part of the Khasi Hills. There is archeological evidence of zinc production in
Rajasthan mines at Zawar from the 6th or 5th BCE. India was the rst country to
master zinc distillation. Due to low boiling point, zinc tends to vapourise while its ore is
smelted. Pure zinc could be produced after a sophisticated ‘downward’ distillation
technique in which the vapour was condensed in a lower container. This technique was
also applied to mercury. Indian metallurgists were masters in this technique. This has
been described in Sanskrit texts of 14th century.Indians had knowledge about
mercury. They used it for medicinal purpose. Development of mining and metallurgy
declined during the British colonial era. By the 19th century, once ourished mines of
Rajasthan were mostly abandoned and became almost extinct. In 1947 when India got
independence, European literature on science had already found its wayslowly into the
country. Thus, in post independence era, the Government of India initiated the process
of nation building through the establishment of various institutes of science and
technology. In the following sections, we will learn about the modern methods of
extraction of elements."
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Some basic concepts of thermodynamics help us in understanding the theory of
metallurgical transformations. Gibbs energy is the most signicant term. To
understand the variation in the temperature required for thermal reductions and to
predict which element will suit as the reducing agent for a given metal oxide (MxOy),
Some basic concepts of thermodynamics help us in understanding the theory of Gibbs energy interpretations are made. The criterion for the feasibility of a thermal
metallurgical transformations. Gibbs energy is the most signicant term here.The reduction is that at a given temperture Gibbs energy change of the reaction must be
change in Gibbs energy, ΔG for any process at any specied temperature, is described negative. The change in Gibbs energy, DG for any process at any specied
by the equation: ΔG = ΔH – TΔS (6.14) where, ΔH is the enthalpy change and ΔS is temperature, is described by the equation: DG = DH – TDS (6.14) where, DH is the
the entropy change for the process. For any reaction, this change could also be enthalpy change and DS is the entropy change for the process. When the value of DG
explained through the equation: ΔGV = – RTlnK (6.15) where, K is the equilibrium is negative in equation 6.14, only then the reaction will proceed. DG can become
constant of the ‘reactant – product’ system at the temperature,T. A negative ΔG negative in the following situations: 1. If DS is positive, on increasing the temperature
implies a +ve K in equation 6.15. And this can happen only when reaction proceeds (T), the value of TDS increases so that DH < TDS. In this situation DG will become
4. 152-153 6.1 towards products. From these facts we can make the following conclusions: 1. When negative on increasing temperature. 2. If coupling of the two reactions, i.e. reduction
the value of ΔG is negative in equation 6.14, only then the reaction will proceed. If ΔS and oxidation, results in negative value of DG for overall reaction, the nal reaction
is positive, on increasing the temperature (T), the value of TΔS would increase (ΔH < becomes feasible. Such coupling is easily understood through Gibbs energy (DrG-) vs T
TΔS) and then ΔG will become –ve. 2. If reactants and products of two reactions are plots for the formation of the oxides (Fig. 6.4). These plots are drawn for free energy
put together in a system and the net ΔG of the two possible reactions is –ve, the changes that occur when one gram mole of oxygen is consumed. The graphical
overall reaction will occur. So the process of interpretation involves coupling of the representation of Gibbs energy was rst used by H.J.T. Ellingham. This provides a
two reactions, getting the sum of their ΔG and looking for its magnitude and sign. sound basis for considering the choice of reducing agent in the reduction of oxides.
Such coupling is easily understood through Gibbs energy (ΔGV) vs T plots for This is known as Ellingham Diagram. Such diagrams help us in predicting the feasibility
formation of the oxides (Fig. 6.4). of thermal reduction of an ore. As we know, during reduction, the oxide of a metal
decomposes and the reducing agent takes away the oxygen. The role of reducing
agent is to provide DrG- negative and large enough to make the sum of DrG- of the two
reactions, i.e, oxidation of the reducing agent and reduction of the metal oxide
negative.

5. 156-159 6.4

As we know, during reduction, the oxide of a metal decomposes and the reducing
agent takes away the oxygen. The role of reducing agent is to provide DrG- negative
and large enough to make the sum of DrG- of the two reactions, i.e, oxidation of the
reducing agent and reduction of the metal oxide negative.
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3. 149-152

(a) Ellingham diagram normally consists of plots of DfG- vs T for the formation of
oxides of common metals and reducing agents i.e., for the reaction given below.
2xM(s) + O2(g) ® 2MxO(s) In this reaction, gas is consumed in the formation
of oxide hence, molecular randomness decreases in the formation of oxide which
leades to a negative value of DS as a result sign of TDS term in equation (6.14)
becomes positive. Subsequently DfG- shifts towards higher side despite rising T.
The result is positive slope in the curve for most of the reactions for the
formation of MxO(s).
(b) Each plot is a straight line and slopes upwards except when some change in phase
(s® l or l® g) takes place. The temperature at which such change occurs, is
indicated by an increase in the slope on positive side (e.g., in the Zn, ZnO plot, the
melting is indicated by an abrupt change in the curve) [Fig. 6.4].
(c) When temperature is raised, a point is reached in the curve where it crosses
DrG-= 0 line. Below this temperature, DrG- for the formation of oxide is negative
so MxO is stable. Above this point, free energy of formation of oxide is positive.
The oxide, MxO will decompose on its own.
(d) Similar diagrams are constructed for suldes and halides also. From them it
becomes clear that why reduction of MxS is difcult.
Limitations of Ellingham Diagram
1. The graph simply indicates whether a reaction is possible or not, i.e., the
tendency of reduction with a reducing agent is indicated. This is so because it is
based only on the thermodynamic concepts. It does not explain the kinetics of the
reduction process. It cannot answer questions like how fast reduction can
proceed? However, it explains why the reactions are sluggish when every species
is in solid state and smooth when the ore melts down. It is interesting to note
here that DH (enthalpy change) and the DS (entropy change) values for any
chemical reaction remain nearly constant even on varying temperature. So the
only dominant variable in equation(6.14) becomes T. However, DS depends much
on the physical state of the compound. Since entropy depends on disorder or
randomness in the system, it will increase if a compound melts (s® l) or
vapourises (l® g) since molecular randomness increases on changing the phase
from solid to liquid or from liquid to gas.
2. The interpretation of DrGV- is based on K (DG- = – RT lnK). Thus it is presumed
that the reactants and products are in equilibrium: MxO + Ared ƒ xM + AredO
This is not always true because the reactant/product may be solid. In commercial
processes reactants and products are in contact for a short time.
The reactions 6.18 and 6.21 describe the actual reduction of the metal oxide, MxO,
that we want to accomplish. The DrG- values for these reactions in general, can be
obtained from the corresponding DfG- values of oxides.

(a) Extraction of iron from its oxides After concentration, mixture of oxide ores of iron
(Fe2O3, Fe3O4) is subjected to calcination/roasting to remove water, to decompose
carbonates and to oxidise sulphides. After that these are mixed with limestone and
coke and fed into a Blast furnace from its top, in which the oxide is reduced to the
metal. In the Blast furnace, [Fig. 6.5] reduction of iron oxides takes place at different
temperature ranges. A blast of hot air is blown from the bottom of the furnace by
burning coke in the lower portion to give temperature upto about 2200K. The burning
of coke, therefore, supplies most of the heat required in the process. The CO and heat
move to the upper part of the furnace. In upper part, the temperature is lower and the
iron oxides (Fe2O3 and Fe3O4) coming from the top are reduced in steps to FeO.
These reactions can be summarised as follows: At 500 – 800 K (lower temperature
range in the blast furnace),

4. 152-153 6.1
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6. 159-161 6.4.1

At 900 – 1500 K (higher temperature range in the blast furnace): C + CO2 → 2 CO

(6.31) FeO + CO → Fe + CO2 (6.32) Limestone is also decomposed to CaO which
removes silicate impurity of the ore as slag. The slag is in molten state and eparates
out from iron.

CHAPTER 7 - THE P-BLOCK ELEMENTS

Oxygen is the most abundant of all the elements on earth. Oxygen Oxygen is the most abundant of all the elements on earth. Oxygen
forms about 46.6% by mass of earth’s crust. Dry air contains 20.946% oxygen by forms about 46.6% by mass of earth’s crust. Dry air contains 20.946%
volume. However, the abundance of sulphur in the earth’s crust is only 0.03-0.1%. oxygen by volume. However, the abundance of sulphur in the earth’s crust is only
Combined sulphur exists primarily as sulphates such as gypsum CaSO4.2H2O, epsom 0.03-0.1%. Combined sulphur exists primarily as sulphates such as gypsum
salt MgSO4.7H2O, baryte BaSO4 and sulphides such as galena PbS, zinc blende ZnS, CaSO4.2H2O, epsom salt MgSO4.7H2O, baryte BaSO4 and sulphides such as galena
copper pyrites CuFeS2. Traces of sulphur occur as hydrogen sulphide in volcanoes. PbS, zinc blende ZnS, copper pyrites CuFeS2. Traces of sulphur occur as hydrogen
Organic materials such as eggs, proteins, garlic, onion, mustard, hair and wool sulphide in volcanoes. Organic materials such as eggs, proteins, garlic, onion,
contain sulphur. Selenium and tellurium are also found as metal selenides and mustard, hair and wool contain sulphur. Selenium and tellurium are also found as metal
7. 186 7.10.1 tellurides in sulphide ores. Polonium occurs in nature as a decay product of thorium selenides and tellurides in sulphide ores. Polonium occurs in nature as a decay product
and uranium minerals. The important atomic and physical properties of Group16 along of thorium and uranium minerals. Livermorium is a synthetic radioactive element. Its
with electronic conguration are given in Table 7.6. Some of the atomic, physical and symbol is Lv, atomic number 116, atomic mass 292 and electronic conguration [Rn]
chemical properties and their trends are discussed below. 5f146d107s27p4. It has been produced only in a very small amount and has very
short half-life (only a small fraction of one second). This limits the study of properlies of
Lv. Here, except for livermorium, important atomic and physical properties of other
elements of Group16 along with their electronic congurations are given in Table 7.6.
Some of the atomic, physical and chemical properties and their trends are discussed
below.
 CHAPTER 7- THE P-BLOCK ELEMENTS
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7. 186 7.10.1

8. 186 7.10.8

CHAPTER 10 - HALOAKANES AND HALOARENES

(a) Alkyl halides or haloalkanes (R—X):-
In alkyl halides, the halogen atom is bonded to an alkyl group ®. They form a
(a) Alkyl halides or haloalkanes (R—X):- In alkyl halides, the halogen atom is bonded to homologous series represented by CnH2n+1X. They are further classied as primary,
an alkyl group (R). They form a homologous series represented by CnH2n+1X. They secondary or tertiary according to the nature of carbon to which halogen is attached.
9. 290 10.1.2
are further classied as primary, secondary or tertiary according to the nature of If halogen is attached to a primary carbon atom in an alkyl halide, the alkyl halide
carbon to which halogen is attached. is called primary alkyl halide or 1° alkyl halide. Similarly, if halogen is attached
to secondary or tertiary carbon atom, the alkyl halide is called secondary alkyl
halide (2°) and tertiary (3°) alkyl halide, respectively.

From Alcohol:- Alkyl halides are best prepared from alcohols, which are easily
accessible. The hydroxyl group of an alcohol is replaced by halogen on reaction with
concentrated halogen acids, phosphorus halides or thionyl chloride.
From Alcohol:- Alkyl halides are best prepared from alcohols, which are easily Thionyl chloride is preferred because in this reaction alkyl halide is formed along with
accessible. The hydroxyl group of an alcohol is replaced by halogen on reaction with gases SO2 and HCl. The two gaseous products are escapable, hence, the
concentrated halogen acids, phosphorus halides or thionyl chloride. reaction gives pure alkyl halides. The reactions of primary and secondary
Thionyl chloride is preferred because the other two products are escapable gases. alcohols with HCl require the presence of a catalyst, ZnCl2. With tertiary
10. 294 10.4.1 Hence the reaction gives pure alkyl halides. Phosphorus tribromide and triiodide are alcohols, the reaction is conducted by simply shaking the alcohol with
usually generated in situ (produced in the reaction mixture) by the reaction of red concentrated HCl at room temperature. Constant boiling with HBr (48%) is
phosphorus with bromine and iodine respectively. The preparation of alkyl chloride is used for preparing alkyl bromide. Good yields of R—I may be obtained by
carried out either by passing dry hydrogen chloride gas through a solution of alcohol or heating alcohols with sodium or potassium iodide in 95% orthophosphoric acid.
by heating a solution of alcohol in concentrated aqueous acid. The order of reactivity of alcohols with a given haloacid is 3°>2°>1°.
Phosphorus tribromide and triiodide are usually generated in situ (produced in the
reaction mixture) by the reaction of red phosphorus with bromine and iodine
respectively.

(I) From alkanes by free radical halogenation (a) By free radical halogenation Free
radical chlorination or bromination of alkanes gives a complex mixture of isomeric
mono- and polyhaloalkanes, which is difcult to separate as pure compounds.
Consequently, the yield of any one compound is low (Unit 13, class XI).

Previously this rection was after Sandmeyer's reaction under the heading (d) from
alkenes
(II) From alkenes (II) From alkenes
(I) Addition of hydrogen halides: An alkene is converted to corresponding alkyl halide by
reaction with hydrogen chloride, hydrogen bromide or hydrogen iodide.

(a) By free radical halogenation

Free radical chlorination or bromination of alkanes gives a complex mixture of isomeric
mono- and polyhaloalkanes, which is difcult to separate as pure compounds.
11. 294 10.4.2 Consequently, the yield of any one compound is low (Unit 13, Class XI).

Propene yields two products, however only one predominates as per Markovnikov’s
rule. (Unit 13, Class XI)
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(ii) Addition of halogens: In the laboratory, addition of bromine in CCl4 to an alkene

resulting in discharge of reddish brown colour of bromine constitutes an important
method for the detection of double bond in a molecule. The addition results in the
synthesis of vic-dibromides, which are colourless (Unit 13, Class XI). Alkyl iodides are
11. 294 10.4.2 often prepared by the reac

Previously this rection was after the heading (d) from alkenes
Halogen Exchange Alkyl iodides are often prepared by the reaction of alkyl chlorides/
bromides with NaI in dry acetone. This reaction is known as Finkelstein reaction.

12. 295-296 10.1.2

NaCl or NaBr thus formed is precipitated in dry acetone. It facilitates the forward
reaction according to Le Chatelier’s Principle. The synthesis of alkyl uorides is best
accomplished by heating an alkyl chloride/bromide in the presence of a metallic uoride
such as AgF, Hg2F2, CoF2 or SbF3. The reaction is termed as Swarts reaction.

Prepation of Haloarenes
(b) By electrophilic substitution (I) From hydrocarbons by electrophilic substitution
13. 296 10.5 (c) Sandmeyer’s reaction (ii) From amines by Sandmeyer’s reaction

14. 297 10.6 Previous Number was 10.5, Physical Properties Now 10.6, Physical Properties

15. 302 10.7

(c) Stereochemical aspects of nucleophilic substitution reactions In order to

(c) Stereochemical aspects of nucleophilic substitution reactions understand the stereochemical aspects of substitution reactions, we need to learn
A SN2 reaction proceeds with complete stereochemical inversion while a SN1 some basic stereochemical principles and notations (optical activity, chirality,
reaction proceeds with racemisation. In order to understand this concept, we need to retention, inversion, racemisation, etc.).
learn some basic stereochemical principles and notations (optical activity, chirality, (I) Optical activity: Plane of plane polarised light produced by passing ordinary light
retention, inversion, racemisation, etc.). (i) Plane polarised light and optical activity: through Nicol prism is rotated when it is passed through the solutions of certain
Certain compounds rotate the plane polarised light (produced by passing ordinary compounds. Such compounds are called optically active compounds. The angle by
light through Nicol prism) when it is passed through their solutions. Such compounds which the plane polarised light is rotated is measured by an instrument called
are called optically active compounds. The angle by which the plane polarised light is polarimeter. If the compound rotates the plane of plane polarised light to the right, i.e.,
rotated is measured by an instrument called polarimeter. If the compound rotates the clockwise direction, it is called dextrorotatory (Greek for right rotating) or the d-form
plane polarised light to the right, i.e., clockwise direction, it is called dextrorotatory and is indicated by placing a positive (+) sign before the degree of rotation. If the light
(Greek for right rotating) or the d-form and is indicated by placing a positive (+) sign is rotated towards left (anticlockwise direction), the compound is said to be laevo-
before the degree of rotation. If the light is rotated towards left (anticlockwise rotatory or the l-form and a negative (–) sign is placed before the degree of rotation.
direction), the compound is said to be laevorotatory or the l-form and a negative (–) Such (+) and (–) isomers of a compound are called optical isomers and the
sign is placed before the degree of rotation. Such (+) and (–) isomers of a compound phenomenon is termed as optical isomerism.
16. 305-306 10.7 are called optical isomers and the phenomenon is termed as optical isomerism. (ii) (ii) Molecular asymmetry, chirality and enantiomers: The observation of Louis Pasteur
Molecular asymmetry, chirality and enantiomers: The observation of Louis Pasteur (1848) that crystals of certain compounds exist in the form of mirror images laid the
(1848) that crystals of certain compounds exist in the form of mirror images laid the foundation of modern stereochemistry. He demonstrated that aqueous solutions of
foundation of modern stereochemistry. He demonstrated that aqueous solutions of both types of crystals showed optical rotation, equal in magnitude (for solution of
both types of crystals showed optical rotation, equal in magnitude (for solution of equal concentration) but opposite in direction. He believed that this difference in
equal concentration) but opposite in direction. He believed that this difference in optical activity was associated with the three dimensional arrangements of atoms in
optical activity was associated with the three dimensional arrangements of atoms the molecules (congurations) of two types of crystals. Dutch scientist, J. Van’t Hoff
(congurations) in two types of crystals. Dutch scientist, J. Van’t Hoff and French and French scientist, C. Le Bel in the same year (1874), independently
scientist, C. Le Bel in the same year (1874), independently argued that the spatial argued that the spatial arrangement of four groups (valencies) around a central
arrangement of four groups (valencies) around a central carbon is tetrahedral and if carbon is tetrahedral and if all the substituents attached to that carbon are different,
all the substituents attached to that carbon are different, such a carbon is called the mirror image of the molecule is not superimposed overlapped) on the molecule;
asymmetric carbon or stereocentre. The resulting molecule would lack symmetry and such a carbon is called asymmetric carbon or stereocentre. The resulting molecule
is referred to as asymmetric molecule. The asymmetry of the molecule is responsible would lack symmetry and is referred to as asymmetric molecule. The asymmetry of
for the optical activity in such organic compounds. the molecule along with non superimposability of mirror images is responsible for the
optical activity in such organic compounds.

17. 309 10.7

 CHAPTER 10 - HALOAKANES AND HALOARENES
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Headings

18. 309 10.7

CHAPTER 11 - ALCOHOLS, PHENOLS AND EHERES

Mono, Di, Tri or Polyhydric alcohols

Alcohols— Mono, Di, Tri or Polyhydric alcohols.

19. 324 11.1.1 Phenols are removed under this heading and added in phenol segment.

11.1.2 Phenols— Mono, Di and trihydric phenols

20. 325 11.1.2

CHAPTER 12 - ALDEHYDES, KETONES AND CARBOXYLIC ACIDS

In aldehydes, the carbonyl group is bonded to a carbon and hydrogen while in the
In aldehydes, the carbonyl group is bonded to a carbon and hydrogen while in the
ketones, it is bonded to two carbon atoms. The carbonyl compounds in which carbon
ketones, it is bonded to two carbon atoms. The carbonyl compounds in which carbonyl
of carbonyl group is bonded to carbon or hydrogen and oxygen of hydroxyl moiety
group is bonded to oxygen are known as carboxylic acids, and their derivatives (e.g.
21. 357 (-OH) are known as carboxylic acids, while in compounds where carbon is attached
esters, anhydrides) while in compounds where carbon is attached to nitrogen and to
to carbon or hydrogen and nitrogen of -NH2 moiety or to halogens are called
halogens are called amides and acyl halides respectively. The general formulas of these
amides and acyl halides respectively. Esters and anhydrides are derivatives of
classes of compounds are given below:
carboxylic acids. The general formulas of these classes of compounds are given below:

22. 357

23. 358

24. 375 12.7

CHAPTER 13 - AMINES
Nomenclature, In common system, an aliphatic amine is named by prexing alkyl group
to amine, i.e., alkylamine as one word (e.g., methylamine). In secondary and tertiary
Nomenclature, In common system, an aliphatic amine is named by prexing alkyl group
amines, when two or more groups are the same, the prex di or tri is appended before
to amine, i.e., alkylamine as one word (e.g., methylamine). In secondary and tertiary
the name of alkyl group. In IUPAC system, primary amines are named as alkanamines.
amines, when two or more groups are the same, the prex di or tri is appended before
The name is derived by replacement of ‘e’ of alkane by the word amine. For example,
the name of alkyl group. In IUPAC system, primary amines are named as alkanamines.
CH3NH2 is named as methanamine. In case, more than one amino group is present at
The name is derived by replacement of ‘e’ of alkane by the word amine. For example,
different positions in the parent chain, their positions are specied by giving numbers
CH3NH2 is named as methanamine. In case, more than one amino group is present at
to the carbon atoms bearing –NH2 groups and suitable prex such as di, tri, etc. is
different positions in the parent chain, their positions are specied by giving numbers
attached to the amine. The letter ‘e’ of the sufx of the hydrocarbon part is retained.
to the carbon atoms bearing –NH2 groups and suitable prex such as di, tri, etc. is
25. 390-391 13.3 For example, H2N–CH2–CH2–NH2 is named as ethane-1, 2-diamine. To name
attached to the amine. The letter ‘e’ of the sufx of the hydrocarbon part is retained.
secondary and tertiary amines, we use locant N to designate substituent attached to
For example, H2N–CH2–CH2–NH2 is named as ethane-1, 2-diamine.
a nitrogen atom. For example, CH3 NHCH2CH3 is named as N-methylethanamine and
In arylamines, –NH2 group is directly attached to the benzene ring. C6H5NH2 is the
(CH3CH2)3N is named as N, Ndiethylethanamine. More examples are given in Table
simplest example of arylamine. In common system, it is known as aniline. It is also an
13.1. In arylamines, –NH2 group is directly attached to the benzene ring. C6H5NH2
accepted IUPAC name. While naming arylamines according to IUPAC system, sufx ‘e’
is the simplest example of arylamine. In common system, it is known as aniline. It is also
of arene is replaced by ‘amine’. Thus in IUPAC system, C6H5–NH2 is named as
an accepted IUPAC name. While naming arylamines according to IUPAC system, sufx
benzenamine. Common and IUPAC names of some alkylamines and arylamines are given
‘e’ of arene is replaced by ‘amine’. Thus in IUPAC system, C6H5–NH2 is named as
in Table 13.1.
benzenamine. Common and IUPAC names of some alkylamines and arylamines are given
in Table 13.1.
 CHAPTER 14 - BIOMOLECULUES
NCERT
S. No. Pg. No. Previous Content Updated Content
Headings
26. 412 14.1.2.1 I Glucose 14.1.2.1 Glucose

(+) Isomer of glyceraldehyde has ‘D’ conguration. It means that when its
structural formula is written on paper following specic conventions which you
will study in higher classes, the –OH group lies on right hand side in the
All those compounds which can be chemically correlated to (+) isomer of structure. All those compounds which can be chemically correlated to D (+)
glyceraldehyde are said to have D-conguration whereas those which can be isomer of glyceraldehyde are said to have Dconguration hereas those which
correlated to (–) isomer of glyceraldehyde are said to have L—conguration. For can be correlated to ‘L’ (–) isomer of glyceraldehyde are said to have
assigning the conguration of monosaccharides, it is the lowest asymmetric carbon L—conguration. In L (–) isomer –OH group is on left hand side as you can see in
27. 414-415 atom (as shown below) which is compared. As in (+) glucose, —OH on the lowest the structure. For assigning the conguration of monosaccharides, it is the
asymmetric carbon is on the right side which is comparable to (+) glyceraldehyde, so lowest asymmetric carbon atom (as shown below) which is compared. As in
it is assigned D-conguration. For this comparison, the structure is written in a way (+) glucose, —OH on the lowest asymmetric carbon is on the right side which
that most oxidised carbon is at the top. is comparable to (+) glyceraldehyde, so (+) glucose is assigned D-
conguration. Other asymmetric carbon atoms of glucose are not considered
for this comparison. Also, the structure of glucose and glyceraldehyde is
written in a way that most oxidised carbon (in this case –CHO)is at the top.

CHAPTER 14- BIOMOLECULUES

14.6 Hormones:- Hormones are molecules that act as intercellular messengers.
These are produced by endocrine glands in the body and are poured directly in the
blood stream which transports them to the site of action. In terms of chemical nature,
some of these are steroids, e.g., estrogens and androgens; some are poly peptides
for example insulin and endorphins and some others are amino acid derivatives such as
epinephrine and norepinephrine. Hormones have several functions in the body. They
help to maintain the balance of biological activities in the body. The role of insulin in
keeping the blood glucose level within the narrow limit is an example of this function.
Insulin is released in response to the rapid rise in blood glucose level. On the other
hand hormone glucagon tends to increase the glucose level in the blood. The two
hormones together regulate the glucose level in the blood. Epinephrine and
norepinephrine mediate responses to external stimuli. Growth hormones and sex
hormones play role in growth and development. Thyroxine produced in the thyroid
gland is an iodinated derivative of amino acid tyrosine. Abnormally low level of
thyroxine leads to hypothyroidism which is characterised by lethargyness and obesity.
Increased level of thyroxine causes hyperthyroidism. Low level of iodine in the diet may
28. 430-431 14.6 lead to hypothyroidism and enlargement of the thyroid gland. This condition is largely
being controlled by adding sodium iodide to commercial table salt (“Iodised” salt).
Steroid hormones are produced by adrenal cortex and gonads (testes in males and
ovaries in females). Hormones released by the adrenal cortex play very important role
in the functions of the body. For example, glucocorticoids control the carbohydrate
metabolism, modulate inammatory reactions, and are involved in reactions to
stress. The mineralocorticoids control the level of excretion of water and salt by the
kidney. If adrenal cortex does not function properly then one of the results may be
Addison’s disease characterised by hypoglycemia, weakness and increased
susceptibility to stress. The disease is fatal unless it is treated by glucocorticoids and
mineralocorticoids. Hormones released by gonads are responsible for development of
secondary sex characters. Testosterone is the major sex hormone produced in males.
It is responsible for development of secondary male characteristics (deep voice, facial
hair, general physical constitution) and estradiol is the main female sex hormone. It is
responsible for development of secondary female characteristics and participates in
the control of menstrual cycle. Progesterone is responsible for preparing the uterus
for implantation of fertilised egg.

CHAPTER 15 - POLYMERS
No changes No changes

CHAPTER 16 - CHEMISTRY IN EVERYDAY LIFE

16.4.3 Antioxidants in Food:- These are important and necessary food additives.
These help in food preservation by retarding the action of oxygen on food. These are
more reactive towards oxygen than the food material which they are protecting. The
two most familiar antioxidants are butylated hydroxy toluene (BHT) and butylated
458 16.4.3 hydroxy anisole (BHA). The addition ofBHA to butter increases its shelf life from
months to years. Sometimes BHT and BHA along with citric acid are added to produce
more effect. Sulphur dioxide and sulphite are useful antioxidants for wine and beer,
sugar syrups and cut, peeled or dried fruits and vegetables.

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