Unit 3-Alternate Fuel
Unit 3-Alternate Fuel
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ALTERNATE FUELS
SOLID FUELS
Solid fuels are obsolete for IC engines. In order to have historical
perspective we will describe some of the earlier attempts.In the latter
half of the 1800s, before petroleum-based fuels were perfected, many
other fuels were tested and used in IC engines. When Rudolf Diesel
was developing his engine, one of the fuels he used was a coal dust
mixed with water. Fine particles of coal (carbon) were dispersed in
water and injected and burned in early diesel engines.Although this
never became a common fuel, a number of experimental engines
using this fuel have been built over the last hundred years. Even
today, some work continues on this fuel technology.
The major improvement in this type of fuel has been the reduction of
the average coal particle size. In 1894 the average particle size was on
the order of 100 µ (1 µ = 1 micron = 10-6 m). This was reduced to
about 70 µ in the"1940-1970 period and further reduced to about 10µ
by the early 1980s. The typical slurry is about 50% coal and 50%
water by mass. One major problem with this fuel is the abrasiveness
of the solid particles, which manifests itself in worn injectors and
piston rings.
Coal is an attractive fuel because of the large supply which is
available. However, as an engine fuel, other methods of use seem
more feasible. These include liquefaction or gasification of the coal.
In the late 19308and early 1940s petroleum products became very
scarce, especially in Europe, due to World War II. Just about all
gasoline products were claimed by the German army, leaving no fuel
for civilian automobile use. Although this was an inconvenience for
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the civilian population, it did not stop them from using their beloved
automobiles. Enterprising people in several countries, mainly Sweden
and Germany, developed a way to operate their automobiles using
solid fuels like charcoal, wood, or coal.
LIQUID FUELS
Liquid fuels are preferred for IC engines because they are easy to
store and have reasonably good calorific value. In the liquid fuel
category the main alternative is the alcohol.
Alcohol
Alcohols are an attractive alternate fuel because they can be obtained
from both natural and manufactured sources. Methanol (methyl
alcohol) and ethanol (ethyl alcohol) are two kinds of alcohols that
seem most promising.
distance which could be driven with a given fuel tank volume would
be cut in half. Automobiles as well as distribution stations would
require twice as much storage capacity, twice the number of storage
facilities, twice the volume of storage at the service station, twice as
many tank trucks and pipelines, etc. Even with the lower energy
content of alcohol, engine power for a given displacement would be
about the same. This is because of the lower air-fuel ratio needed by
alcohol. Alcohol contains oxygen and thus requires less air for
stoichiometric combustion. More fuel can be burned with the same
amount of air.
Combustion of alcohols produce more aldehydes in the exhaust. If as
much alcohol fuel was consumed as gasoline, aldehyde emissions
would be a serious exhaust pollution problem.
Alcohol is much more corrosive than gasoline on copper,
brass,aluminum, rubber, and many plastics. This puts some
restrictions on the design and manufacturing of engines to be used
with this fuel. Fuel lines and tanks, gaskets, and even metal engine
parts can deteriorate with long-term ,alcohol use (resulting in cracked
fuel lines, the need for special fuel tank, etc).Methanol is very
corrosive on metals.
It has poor cold weather starting characteristics due to low vapor
pressure and evaporation. Alcohol-fuelled engines generally have
difficulty in starting at temperatures below 10 °C. Often a small
amount of gasoline is added to alcohol fuel, which greatly improves
cold-weather starting. The need to do this,how- ever, greatly reduces
the attractiveness of. any alternate fuel.
Alcohols have poor ignition characteristics in general.
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METHANOL
Of all the fuels being considered as an alternate to gasoline, methanol
is one of the most promising and has experienced major research and
development. Pure methanol and mixtures of methanol and gasoline in
various percentages have been extensively tested in engines and
vehicles for a number of years.
The most common mixtures are .
M85 (85% methanol and 15% gasoline) and MI0 (10% methanol and
90% gasoline). The data of these tests which include performance and
emission levels are compared to pure gasoline (MO) and pure
methanol (MI00). Some smart flexible fuel (or variable-fuel) engines
are capable of using any random mixture combination of methanol
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and gasoline ranging from pure methanol to pure gasoline. Two fuel
tanks are used and various flow rates of the two fuels can be pumped
to the engine, passing through a mixing chamber. Using information
from sensors in the intake and exhaust, the electronic monitoring
system (EMS) adjusts to the proper air-fuel ratio, ignition timing
injection timing, and valve timing (where possible) for the fuel
mixture being used.
One problem with gasoline-alcohol mixtures as a fuel is the tendency
for alcohol to combine with any water present. When this happens the
alcohol separates locally from the gasoline, resulting in a non-
homogeneous mixture. This causes the engine to run erratically due to
the large air-fuel ratio differences between the two fuels.
Methanol can be obtained from many sources, both fossil and
renewable.These include coal, petroleum, natural gas, biomass,
wood,landfills, and even the ocean. However, any source that requires
extensive manufacturing or processing raises the price of the fuel.
Emissions from an engine using M10 fuel are about the same as those
using gasoline. The advantage (and disadvantage) of using this fuel is
mainly the 10% decrease in gasoline use. With M85 fuel there is a
measurable decrease in HC and CO exhaust emissions.However, there
is an increase in NOx and a large increase in formaldehyde formation.
Methanol is used in some dual-fuel CI engines..Methanol by Itself is
not a good CI fuel because of its high octane number, but if a small
amount of diesel oil is used for ignition, it can be used with good
results. This is very attractive for developing countries because
methanol can often be obtained from much cheaper source than diesel
oil.
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ETHANOL
Ethanol has been used as automobile fuel for many years in various
regions of the world. Brazil is probably the leading user, where in the
early 1990s. About 5 million vehicles operated on fuels that were 93%
ethanol. For a number of years gasohol (gasoline +. alcohol). has been
available at service stations in the United States.
Gasohol is a mixture of 90% gasoline and 10% ethanol. As with
methanol . the development of systems using mixtures of gasoline and
ethanol continues. Two mixture combinations that are important are
E85 (85% ethanol) and E10 (gasohol).
E85 is basically an alcohol fuel with 15% gasoline added to eliminate
some of the problems of pure alcohol (i.e., cold starting, tank
flammability, etc.). E10 reduces the use of gasoline with no
modification needed to the automobile engine. Flexible-fuel engines
are being tested which can operate on any-ratio of ethanol-gasoline.
Ethanol can be made from ethylene or from fermentation of grains
and sugar. Much of it is made from corn, sugar beets, sugar cane,and
even cellulose (wood and paper). The present cost of ethanol is high
due to the manufacturing and processing required. This would be
reduced if larger amounts of this fuel were used. However, very high
production would create a food-fuel competition, with resulting higher
costs for both. Some studies show that at present in the United States,
crops grown for the production of ethanol consume more energy in
plowing, planting, harvesting, fermenting, and delivery than what is in
the final product. This defeats one major reason for using an. alternate
fuel. Ethanol has less HC emissions than gasoline but more than
methanol.
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GASEOUS FUELS
Gaseous fuels are best suited for to engines since physical delay is almost
nil. However, as fuel displaces equal amount of air the engines may have
poor volumetric efficiency. There are quite few gaseous fuels that can be
used as alternate fuels. We will discuss them in details in the following
sections.
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Hydrogen
A number of automobile manufacturers have built with prototype or
modified engines which operate on hydrogen fuel. The advantages of
hydrogen as an IC engine fuel include:
• Low emissions.
Essentially no CO or HC in the exhaust as there is no carbon in the
fuel. Most exhaust would be H20 and N2'
Fuel availability.
There are a number of different ways of making hydrogen, including
electrolysis of water.
Fuel leakage to environment is not a pollutant.
High energy content per volume when stored as a liquid. This would
give a large vehicle range for a given fuel tank capacity,but see the
following.
The disadvantages of using hydrogen as a fuel include:
Requirement of heavy, bulky fuel storage both in vehicle and at the
service station. Hydrogen can be stored either as a cryogenic liquid. or
as a compressed.gas. If stored as a liquid, it would have to be kept
under pressure at a very low temperature.This would require a
thermally super-insulated fuel tank.Storing in a gas phase would
require a high pressure vessel with limited capacity.
Difficult to refuel.
Poor engine volumetric efficiency. Any time a gaseous fuel is used in
an engine, the fuel will displace some of the inlet air and poorer
volumetric efficiency will result.
Fuel cost would be high at present-day technology and availability
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HYDROGEN ENGINES
Hydrogen is another alternate fuel tried for IC engines. Investigations
were carried out extensively in many countries. The most attractive
features of hydrogen as an IC engine fuel are that it can be produced
from a potentially available raw material, water, and the main product
of its combustion again is water.
Hydrogen has very low density both as gas and as liquid. Hence,in
spite of its high calorific value on mass basis its energy density as a
liquid is only one fourth that of gasoline. As a gas it has less than one
tenth the density of air and its heating value per unit volume is less
than one third that of methane. This is one of its chief disadvantages.
Hydrogen has to be stored as compressed gas, as liquid (in cryogenic
containers) or in absorbed form (as metal hydrides), none of which is
as convenient as gasoline storage.
Hydrogen has extremely wide ignition limits. This allows a spark
ignition engine to operate on hydrogen with very little throttling, a
decided advantage. Stoichiometric hydrogen air mixture burns seven
times as fast as the corresponding gasoline air mixture. This too is a
great advantage in IC engines, leading to higher engine speeds and
greater thermal efficiency.
Hydrogen has a high self-ignition temperature but requires very little
energy to ignite it. Hence, it is highly prone to preignition and
backflash in SI engines. Adiabatic flame temperature for hydrogen is
a little lower than for gasoline but the rapid combustion allows very
little heat loss to the surroundings and hence, high, instantaneous,
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NATURAL GAS
Natural gas is found in various localities in oil and gas bearing sand
strata located at various depths below the earths surface. The gas is
usually under considerable pressure, and flows out naturally from the
oil well. If the gas is used in an engine located near the well any
entrained sand must be separated from the gas before its use.
Natural gas obtained from oil wells is called casing head gas. It is
usually treated for the recovery of gasoline. After this, it is called dry
gas. It is delivered into the pipeline systems to be used as fuel.Natural
gas can be used in the production of natural gasoline.
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Need for large pressurized fuel storage tank. There is some safety
concern with a pressurized fuel tank.
Inconsistent fuel properties.
Refuelling is a slow process.
Some very large stationary CI engines operate on a fuel combination
of methane and diesel fuel. Methane is the major fuel, amounting to
more than 90% of the total. It is supplied to the engine as a gas
through high-pressure pipes. A small amount of high grade,low sulfur
diesel fuel is used for ignition purposes. The net result is very clean
running engines. These engines would also be good power plants for
large ships, except that high-pressure gas pipes are undesirable on
ships.
COMPRESSED NATURAL GAS (CNG)
Petroleum and natural gas are obtained by the process of drilling wells. As
already known crude petroleum is composed of hydrocarbons,It contains
some amount of water, sulphur and other impurities. Petroleum when mixed
with natural gas produce a highly volatile liquid. This liquid is known as
natural gasoline. When this petroleum-natural gas mixture is cooled, the
gasoline condenses.
The natural gas can be compressed and then it is called Compressed Natural
Gas (CNG). CNG is used to run an automobile vehicle just like LPG. The
CNG fuel feed system is similar to the LPG fuel feed system. CNG
conversion kits are used to convert petrol driven cars into CNG-driven cars.
These kits contain auxiliary parts "like the converter, mixer and other
essential partsrequired for conversion.Emission levels and a comparison
between CNG:.driven vehicles and petrol-driven vehicles are given in Table
7.2..
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The LPG (Propane) fuel feed system is shown in Fig.7.4. This fuel
feed system has a storage tank which is placed in the rear portion of
the vehicle. In the front side of the system, there is the vacuum filter
fuel lock, the converter-regulator and the LPG propane carburetor.
In the fuel feed system, liquid LPG is pushed through the fuel pipe
line to the converter. The liquid is converted into vapour by the
converter. A large temperature drop occurs, as LPG changes from
liquid to vapour.
LPG should be prevented from freezing within the converter. For this
purpose, the engine cooling water is passed close to the converter
which prevents the gas from freezing. LPG vapours move to the LPG
propane carburetor. This carburetor supplies the air-fuel mixture to the
engine for combustion.
At present, LPG auto conversion kits are available for converting
petrol run cars into LPG gas run cars. These kits contain auxiliaries
like the converter or pressure regulator, LPG vapour/air mixing unit
known as the mixer and other units which are essential for conversion
from petrol-driven vehicles to LPG-driven vehicles
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