International Journal of Trend in Scientific Research and Development (IJTSRD)

Volume: 3 | Issue: 3 | Mar-Apr 2019 Available Online: www.ijtsrd.com e-ISSN: 2456 - 6470

Effect of Operating Temperatures on the

Performance of a SOFC/GT Hybrid System
Abdulrazzak Akroot
Assistant Professor, Department of Mechanical Engineering, Karabük University, Turkey

How to cite this paper: Abdulrazzak ABSTRACT

Akroot "Effect of Operating This article presents a steady-state thermodynamic model of a solid oxide fuel
Temperatures on the Performance of a cell/gas turbine hybrid cycle which developed by using a simulation software,
SOFC/GT Hybrid System" Published in MATLAB®. The hybrid model integrates a zero-dimensional level SOFC model
International Journal of Trend in with gas turbine. The hybrid system was used to study the effects of some
Scientific Research and Development operation parameter such as SOFC operating temperature, and current density
(ijtsrd), ISSN: 2456- on the specific work output, electrical efficiency, and exergy efficiency of a
6470, Volume-3 | generic hybrid cycle. The results show that if the SOFC operating temperature,
Issue-3, April 2019, the power output, electrical efficiency, and exergy efficiency increase. The
pp.1512-1515, URL: electrical efficiency of the hybrid system increase from 62% to 68%, and the
https://www.ijtsrd.c exergy efficiency of the hybrid system increases from 60% to 66% when the
om/papers/ijtsrd23 operation temperature increases from 600°C to 750°C at a current density of
412.pdf IJTSRD23412 6000 A/cm2. On the other hand, the system efficiency and exergy decreases with
an increase in the current density.
Copyright © 2019 by author(s) and
International Journal of Trend in
Scientific Research and Development KEYWORDS: Hybrid system, SOFC operating temperature, Exergy , Efficiency
Journal. This is an Open Access article
distributed under
the terms of the
Creative Commons
Attribution License (CC BY 4.0)
(http://creativecommons.org/licenses/
by/4.0)
Introduction
Solid oxide fuel cell is a favorable technology for electricity This study introduces a SOFC stack model based on the
generation and it has great potential for a diverse range of methane feed planar internal reforming SOFC technology
combined heat power applications because it operates at and integrated with gas turbine in a hybrid system. Different
elevated temperature (600–1000 °C) amidst fuel cells , and operation temperature were applied to understand its effect
very high electrical efficiencies can be achieved [1]. The on the power produced, efficiency, and exergy of the hybrid
SOFC can be applied with a difference of power generation system.
systems; both stationary power generators and auxiliary
power sources [2, 3]. Combining a SOFC with common heat SYSTEM MODELING AND ASSUMPTIONS
engines like gas turbines can be increases the efficiency to Solid oxide fuel cell hybrid systems consist of a stack , and
reaches 70% [4] . Therefore, integrated of SOFC-GT systems auxiliary components, whose arrangement strongly depends
have attracted the notice of many investigator because of the on the particular application. For the purpose of this study,
boost in efficiency, capability of heat recycling, and created the system (Figure 1) consists of a SOFC stack, a combustion
electrical power in diverse capacities [5] [6][7][8]. Bavarsad chamber, a gas turbine, a water pump, mixers, compressors
et al. [9] studied the integrated of SOFC-GT hybrid cycle and heat exchangers. The developed model for SOFC is made
established on the first and second law of thermodynamics. on the following assumptions, and the input parameters to
They investigated the effect of some operation parameters the hybrid system are listed in Table 1:
such as the operating temperature, air flow ratio, fuel flow
Steady state conditions.
ratio, and operating pressure. Rajabinasab et al [10]
Air, methane and water enter the fuel cell with the same
investigated the influence of recycling SOFC products on the temperature.
power output and electrical efficiency of integrated (SOFC-
The reforming reaction is completely developed in the
GT) hybrid system. Oryshchyn et al [11] designed a hybrid SOFC
systems of SOFC-GT for different levels of SOFC fuel
The stream temperatures at the exits of the SOFC
utilization. They showed that the Lower fuel utilization cathode and the anode are the same.
factor increased the Nernst potential, and GT inlet
There is no heat interaction with the environment.
temperature. Yi et al [12] presented different applicable
The pressure drop within the cell stack is neglected,
options for combining a GT/SOFC to ensure very high power
Only hydrogen is electrochemically reacted. CO is
generation electrical efficiency. converted to CO2 and H2 by water–gas shift reaction.

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 International Journal of Trend in Scientific Research and Development (IJTSRD) @ www.ijtsrd.com eISSN: 2456-6470
Electrochemical reaction
(3)
where x, y, and z are the molar rates of converted in
reforming reaction, carbon monoxide converted in shifting
reaction, and hydrogen converted in the electrochemical
reaction, respectively.
The reversible voltage of each planar SOFC is calculated by
the Nernst equation:

(4)

Figure1. Schematic Diagram of SOFC /GT hybrid system where is the fuel cell voltage at standard conditions; R is
Table1. The SOFC stack parameters the universal gas constant; T is the SOFC operating
Parameter Value temperature; is the number of moles of electrons
Specific resistivity of transferred per mole of fuel consumed.
anode
Specific resistivity of The cell voltage , is calculated according to equation (5):
cathode
(5)
Specific resistivity of
electrolyte
Specific resistivity of The activation losses is obtained by simplifying the
interconnection Butlere-Volmers equation of the sum of activation losses of
Active surface area the anode and cathode:
Thickness of anode (6)
Thickness of cathode The ohmic losses are referred to the transmit of ions and
Thickness of electrons in the electrolyte, electrodes, and internal
electrolyte connectors. The ohmic losses are calculated by the following
Thickness of equations (7-8):
interconnect (7)
Exchange current
density of anode (8)
Exchange current
density of cathode
The concentration losses is calculated by the following
Baseline current
equation:
density
Effective gaseous (9)
diffusivity through
anode where, is the limiting current density.
Effective gaseous
The power produced by SOFC stack can be obtained based
diffusivity through on the cell voltage by equations (10-11):
cathode
(10)
Stack pressure drop
(11)
Fuel utilization factor
Number of cell 667
GAS TURBINE MODEL
By calculating the turbine inlet temperature from the energy
FUEL CELL MODEL
balance of the combustion chamber, and knowing
The fuel cell used in this research is a type of planar SOFC
compression ratio, and the isentropic efficiency of the gas
with internal reforming. Reforming processes is required to
turbine , the exhaust gas temperature and the actual power
convert the fuel into hydrogen ( ) in a solid oxide fuel cell
of the gas turbine can be obtained as:
fed by a conventional fuel like methane ( ). The
techniques of the reforming and electrochemical reactions
(12)
that occur at the electrodes are based on the following
equilibrium equations:
Steam reforming (13)
(1)
SYSTEM PERFORMANCE
Water gas Shifting
The net output power , the electrical efficiency, and the
(2) exergy efficiency are obtained by the following equations:

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(14) of current density shown, and a SOFC operating temperature

of 750 °C. It is seen also from the results when the operation
(15) temperature increases from 600°C to 750°C at current
density of 6000 A/cm2, the power output from the hybrid
(16) system increases from 30.4 kW to 33,28 kW.

Where is the molar flow rate of fuel, is the lower

heating value of fuel, and is the standard chemical
exergy of gases.

Results and discussion

The impact of the different SOFC operating temperatures on
the thermodynamic performance of the hybrid system such
as power output, electrical efficiency and exergy efficiency is
discussed. Figures 2-3 present the influence of current
density on the SOFC voltage and power density with
different operating temperature. It is seen from these figures Figure4. Net system power as a function of current density
that an increase in current density causes a reduction in cell for three different temperatures
voltage which is proportional to SOFC power density. It is
observed in Figure 3 that the power density of SOFC stack Figure 5 indicates the effect of current density on the gas
enhances at high SOFC operating temperature . The power turbine power output, and the network of the gas turbine for
density for SOFC stack ranges approximately from 16 kW to several operating temperature. The figure showed that the
39 kW for the range of current density shown for a SOFC GT power output increases with increasing of current
operating temperature of 750 °C. density and SOFC operating temperature but the most power
output from the gas turbine (approximate 75% ) is used to
drive the compressors and pump.

Figure2. Polarization curve for three different

temperatures
Figure5. Gas turbine power as a function of current
density for three different temperatures

Fig. 6 shows the influence of current density on the exergy

efficiencies of the SOFC stack and hybrid system for different
operating temperature. As current density increases, the
exergy efficiency decrease. However the increases in SOFC
operating temperature causes an increase in the exergy
efficiency of both SOFC stack and hybrid system as a result of
an improvement of power output at high operating
temperature. It is seen from the figure when the operation
Figure3. SOFC power as a function of current density for temperature increases from 600°C to 750°C at current
three different temperatures density of 6000 A/cm2, the exergy efficiency of the hybrid
system increases from 60% to 66%.

Figures 4-7 show the influence of current density on the

power output, gas turbine power output, electrical efficiency,
and exergy efficiency with different SOFC operating
temperature, for a fuel utilization factor of 0.85, and a system
pressure of 8 bar.

The effect of current density on the hybrid system power

output indicates in Figure 5. It is observed from this figure
that the power output from the hybrid system increases with
an increase of current density, and SOFC operating
temperature. The power output from the hybrid system Figure6. Exergy efficiencies as a function of current
ranges approximately from 18.2 kW to 45.7 kW for the range density for three different temperatures

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 International Journal of Trend in Scientific Research and Development (IJTSRD) @ www.ijtsrd.com eISSN: 2456-6470
The effect of current density on the electrical efficiencies of T Absolute temperature, (K)
the SOFC stack and hybrid system for different operating R Universal gas constant, (J/mol K)
temperature indicates in Figure 7. The results showed that Stack voltage, (V)
the electrical efficiency reduces as a current density Greek
increases and it enhances at high SOFC operating Latters
temperature. At current density of 6000 A/cm2, the electrical Thickness, (cm)
efficiency of the hybrid system increase from 62% to 68%,
and the electrical efficiency of the SOFC increase from 54.4% Energy efficiency
to 57% when the operation temperature increases from Ψ Exergy efficiency
600°C to 750°C. Electrical resistivity, ( −1 cm−1)
Exchange current density, (A cm−2)
Acronyms
an Anode
ca Cathode
el Electrolyte
int Interconnection

REFERENCE
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