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Hydrogen Peroxide: Physical Properties

Hydrogen peroxide is a chemical compound with formula H2O2. It has a molecular weight of 34.01 g/mol. The document provides physical and thermodynamic properties of hydrogen peroxide such as boiling point, melting point, heat capacities, enthalpies of formation and vaporization, and critical temperature and pressure. The properties are reported from various sources including the NIST Chemistry WebBook and estimations from the Joback and Crippen methods.

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74 views3 pages

Hydrogen Peroxide: Physical Properties

Hydrogen peroxide is a chemical compound with formula H2O2. It has a molecular weight of 34.01 g/mol. The document provides physical and thermodynamic properties of hydrogen peroxide such as boiling point, melting point, heat capacities, enthalpies of formation and vaporization, and critical temperature and pressure. The properties are reported from various sources including the NIST Chemistry WebBook and estimations from the Joback and Crippen methods.

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Hydrogen peroxide

InChI: InChI=1S/H2O2/c1-2/h1-2H
InChI Key: MHAJPDPJQMAIIY-UHFFFAOYSA-N
Formula: H2O2
SMILES: OO
Molecular Weight: 34.01
CAS: 7722-84-1

Physical Properties

Property Value Unit Source

PAff 674.50 kJ/mol NIST Webbook

BasG 643.80 kJ/mol NIST Webbook

∆fG° -324.52 kJ/mol Joback Method

∆fH°gas -347.79 kJ/mol Joback Method

∆fusH° 3.93 kJ/mol Joback Method

∆vapH° 48.95 kJ/mol Joback Method

IE 10.58 ± 0.04 eV NIST Webbook

IE 10.62 eV NIST Webbook

IE 10.54 eV NIST Webbook

IE 10.92 ± 0.05 eV NIST Webbook

IE 11.26 ± 0.05 eV NIST Webbook

IE 11.70 eV NIST Webbook

IE 11.69 eV NIST Webbook

logPoct/wat 0.02 Crippen Method

Pc 22000.00 ± 2000.00 kPa NIST Webbook

Tboil 383.76 K Joback Method

Tc 728.00 ± 15.00 K NIST Webbook


Property Value Unit Source

Tfus 272.26 ± 0.30 K NIST Webbook

Vc 0.07 m3/kg-mol Joback Method

Temperature Dependent Properties

Property Value Unit Temperature (K) Source

Cp,gas 36.05 J/mol×K 383.76 Joback Method

η 0.00 Pa×s 383.76 Joback Method

∆vapH 48.50 kJ/mol 320.0 NIST Webbook

Sources

Joback Method: https://en.wikipedia.org/wiki/Joback_method


NIST Webbook: http://webbook.nist.gov/cgi/inchi/InChI=1S/H2O2/c1-2/h1-2H
Crippen Method: http://pubs.acs.org/doi/abs/10.1021/ci990307l

Legend

PAff: Proton affinity (kJ/mol).


BasG: Gas basicity (kJ/mol).
Cp,gas: Ideal gas heat capacity (J/mol×K).
η: Dynamic viscosity (Pa×s).
∆fG°: Standard Gibbs free energy of formation (kJ/mol).
∆fH°gas: Enthalpy of formation at standard conditions (kJ/mol).
∆fusH°: Enthalpy of fusion at standard conditions (kJ/mol).
∆vapH°: Enthalpy of vaporization at standard conditions (kJ/mol).
∆vapH: Enthalpy of vaporization at a given temperature (kJ/mol).
IE: Ionization energy (eV).
logPoct/wat: Octanol/Water partition coefficient .
Pc: Critical Pressure (kPa).
Tboil: Normal Boiling Point Temperature (K).
Tc: Critical Temperature (K).
Tfus: Normal melting (fusion) point (K).
Vc: Critical Volume (m3/kg-mol).
Latest version available from:
https://www.chemeo.com/cid/67-803-6/Hydrogen%20peroxide
Generated by Cheméo on Sun, 26 May 2019 17:00:34 +0000.
Cheméo (https://www.chemeo.com) is the biggest free database of chemical and physical data for the
process industry.

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