X.

REAKSI DAN PERHITUNGAN

10.1 REAKSI
 Standardisasi Larutan NaOH
H2C2O4 + NaOH HC2O4Na + H2O
 Standardisasi Larutan Asam Format
HCOOH + NaOH HCOONa + H2O
 Standardisasi Larutan Asam Asetat
CH3COOH + NaOH CH3COONa + H2O
10.2 PERHITUNGAN
 Standardisasi Larutan NaOH dan Larutan Asam
1. Standardisasi Larutan NaOH 0,5 M
BMH2C2O4.2H2O = 126 g⁄mol
massa H2C2O4. 2H2O 1000 mL
MH2C2O4.2H2O
. = x
BM H2C2O4.2H2O Vpel
1,26 g 1000 mL
. = g x = 0,1 M
126 ⁄mol 100 mL

V1 + V2 10,3 mL+10,5 mL
VNaOH = = = 10,4 mL
2 2
MNaOH × bNaOH × VNaOH = M H2C2O4.2H2O × aH2C2O4.2H2O × V H2C2O4.2H2O
MNaOH ×1 × 10,4 mL = 0,1 M × 2 × 25 mL
MNaOH = 0,4807 M
= 0,5 M
2. Standardisasi Larutan CH3COOH 0,2 M
V1 + V2 10,1 mL+10,1 mL
VNaOH = = = 10,1 mL
2 2
MCH3COOH × VCH3COOH = MNaOH × VNaOH
MCH3COOH × 25 mL = 0,5 ×10,1 mL
MCH3COOH = 0,202 M
= 0,2 M
3. Standardisasi Larutan HCOOH 0,2 M
V1 + V2 10 mL+ 9,5 mL
VNaOH = = = 9,75 mL
2 2
MHCOOH × VHCOOH = MNaOH × VNaOH

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 MHCOOH × 25 mL = 0,5 M × 9,75 ml
MHCOOH = 0,195 M
= 0,2 M
1. Asam Asetat
a. Penambahan 0 mL NaOH
CH3COOH + NaOH CH3COONa + H2O
m 2 mmol - - -
b - - - - +
s 2 mmol - - -
2 mmol
[sisa asam lemah] = = 0,2 M
10 mL

[garam] = 0M
pH = 3,43
[H+] = anti log – pH = 10–pH = 10-3,43
[H+] = 3,715×10-3,43
[3,715 x 10-4 ][3,715 x 10-4 ]
Ka =
[0,2]

Ka = 69,006×10-8
pKa = – log 69,006 × 10-8 = 8 – log 69,006
pKa = 6,161.
b. Penambahan 2 mL NaOH
CH3COOH + NaOH CH3COONa + H2O
m 2 mmol 1 mmol - -
b 1 mmol 1 mmol 1 mmol 1 mmol +
s 1 mmol - 1 mmol 1 mmol
1 mmol
[sisa asam lemah] = = 0,083 M.
12 mL
1 mmol
[garam] = = 0,083 M
12 mL

. pH = 4,75.
[garam]
pKa = pH – log
[sisa asam lemah]

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 [0,083]
. pKa = 4,75 – log
[0,083]

pKa = 4,75 – log 1 .

pKa = 4,75
- log Ka = 4,75
Ka = anti log – pKa = 10-4,75= 0,1778×10-4
c. Penambahan 4 mL NaOH (saat titik ekivalen)
CH3COOH + NaOH CH3COONa + H2O
m 2 mmol 2 mmol - -
b 2 mmol 2 mmol 2 mmol 2 mmol +
s - - 2 mmol 2 mmol

[CH3COONa] 2 mmol
= = 0,143 M
14 mL
pH = 10,6
pOH = 14 – pH
pOH = 14 – 10,6
pOH = 3,4
[OH-] = antilog - pOH = 10-pOH = 10-3,4
Hidrolisis Garam

Kw
[OH-] √ . [Anion Garam]
Ka

-14
10
10 -3,4
=√ . [ 0,143M ]
Ka

10-14
.[10 -3,4
]² = . [ 0,143 M ]
Ka

10-14
[10 -6,8
] = . [ 0,143 M ]
Ka

10-14
Ka = . [ 0,143 M ]
10-6,8
Ka = 0,143 x 10-3,2
pKa = - log Ka = 10-Ka
pKa
. = 3,2 – log 0,143

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 pKa = 4,0446
 Penentuan Konstanta Asam
2. Asam Format
a. Penambahan NaOH 0 mL
HCOOH + NaOH HCOONa + H2O
m 2 mmol . -
b - - - -
+
s 2 mmol - - -
2 mmol
[sisa asam lemah] .= = 0,2 M
10 mL
[garam] =0M
pH = 2,79
[H+] = anti log – pH = 10–pH = 10-2,79 = 16,21×10-4
[16,21 x 10-4 ]²
Ka = = 1313,8×10-8
[0,2]

. pKa = – log 1313,8×10-8 = 8 – log 1313,8

= 4,881
b. Penambahan NaOH 2 mL
HCOOH + NaOH HCOONa + H2O
m 2 mmol . 1 mmol - -
b 1 mmol 1 mmol 1 mmol 1mmol +
s 1 mmol - 1 mmo 1mmol
1 mmol
[sisa asam lemah] = = 0,083 M
12 mL
1 mmol
[garam] = = 0,083 M
12 mL
pH = 3,38
[garam]
. pKa = pH – log
[sisa asam lemah]
[0,083]
pKa = 3,38 – log
[0,083]
.

.pKa = 3,38 – log 1

pKa = 3,38
- log Ka = 3,38

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 Ka = anti log – pKa = 10-3,38 = 4,1686 x 10-4
c. Penambahan NaOH 4 mL
HCOOH + NaOH HCOONa + H2O
m 2 mmol 2 mmol - -
b 2 mmol 2 mmol 2 mmol 2 mmol +
s - - 2 mmol 2 mmol
2 mmol
[HCOONa] = = 0,143 M
14 mL
pH = 4,55
pOH = 14 – 4,55
= 9,45
[OH-] = antilog – pOH = 10-pOH = 10-9,45
Hidrolisis Garam

Kw
[OH-] =√ . [anion garam]
Ka

10-14
10-9,45 =√ . [ 0,143M ]
Ka

10-14
.[10-9,45]² = . [ 0,143 M ]
Ka

10-14
[10-18,9] = . [ 0,143 M ]
Ka

10-14
Ka = . [ 0,143 M ]
10-18,9
Ka = 0,143 x 104,9
pKa = - log Ka = 10-Ka
pKa
. = 4,9 – log 0,143
pKa = 5,7446

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