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final exam questions
Section I-‐-‐-‐-‐Atomic structure / Electron configuration /Periodic trends
• Subatomic particles of an atom-‐A, Z & n
• Calculating isotope abundance
• Electron configurations for all elements upto atomic number 56
• Periodic trends for I.E, EN, atomic size/radius, ionic size across the PT & going
down a group.
• Electromagnetic spectrum (order of waves), frequency, wavelength
relationship.
1. A
new
element,
Tyserium
(Ty),
has
recently
been
discovered
and
consists
of
two
isotopes.
One
isotope
has
a
mass
of
331
g/mol
and
is
35.0
%
abundant.
The
other
isotope
is
337
g/mole
and
is
65.0
%
abundant.
What
is
the
mass
of
Ty
as
it
appears
on
the
periodic
table?
1] 332 g/mol 2] 333 g/mol 3] 334 g/mol 4] 335 g/mol 5]336 g/mol
2. Copper
has
two
isotopes,
63Cu
and
65Cu.
If
the
atomic
mass
of
copper
is
63.5
g/mol,
what
is
the
%
of
each
isotope?
1] 25.0 % 63Cu and 75.0 % 65Cu 2] 33.0 % 63Cu and 66.0 % 65Cu
3] 50.0 % 63Cu and 50.0 % 65Cu 4] 66.0 % 63Cu and 33.0 % 65Cu
5] 75.0 % 63Cu and 25.0 % 65Cu
3. How many electrons are in a chromium (III) ion, 2452Cr+3 ?
1 ) 52 2) 49 3) 27 4) 24 5) 21
4. An atom has atomic number 13 and mass number 27. The number of valence e-‐ is:
1) 5 2) 2 3) 3 4) 4 5) none of these.
5. Which is a set of iso-‐electronic species?
1) S-‐2, Cl-‐, Ar0 2) Li+, Ne0, Na+ 3) Cl-‐, Ar0, Na+ 4) Ar0, K+, Mg+2
6. How many completely filled orbitals are indicated by the electronic configuration
1s2, 2s22p6, 3s23p6, 4s2, 3d6 ?
l) 6 2) 26 3) 11 4) 15 5)10
7. The electron configuration ls2, 2s22p6, 3s23p6 represents all of the following except
1) Ti+4 2) Cr+6 3) S-‐2 4) V+3 5) Ca+2
8. Identify the element with a 4d configuration for its last electron.
1) 23V 2) 42Mo 3) 29Cu 4) 24Cr 5) none of these
9. Different forms of radiation arranged in the order of decreasing wavelength are
1) radio waves, gamma rays, visible light, ultraviolet rays.
2) radio waves, visible light, ultraviolet rays, X rays.
3) gamma rays, radio waves, X rays, ultraviolet rays.
4) radio waves, ultraviolet rays, visible light, gamma rays.
5) X rays, visible light, ultraviolet rays, radio waves.
10. Which ground state electronic configuration will most readily produce a plus two ion?
1) 1s2 2s22p6 3s23p4 2) 1s2 2s22p6 3s23p6 4s1
3) 1s2 2s22p6 3s23p63d10 4s 4) 1s2 2s22p6 3s23p63d10 4s24p2
5) 1s2 2s22p6 3s23p63d10 4s24p6
11. The frequency and wavelength of a wave are
1) equal 2) inversely proportional 3) directly proportional 4) unrelated
12. An ion has 13 electrons, 12 protons, and 14 neutrons. What is the mass of the ion?
1) 14 a.m.u. 2) 25 a.m.u. 3) 26 a.m.u. 4) 27 a.m.u. 5) 39 a.m.u.
13. A certain element has an Z= 7 and an A= 14.This means that there must be:
1) 14 electrons in the nucleus of the element
2) 14 protons in the nucleus of the element
3) 7 protons and 7 neutrons in the nucleus of the element
4) 7 protons, 7 electrons & 7 neutrons in the nucleus of the element
14. The size of an element’s atomic radius __________ from left to right across the periodic
table.
1. increases 2. decreases
3. remains constant 4. is randomly assigned
15 Arrange the following elements from lowest to highest IE: Be, Mg, Ca, Rb, Sr
1] Be, Mg, Ca, Rb, Sr 2] Rb, Sr, Ca, Be, Mg 3] Rb, Sr, Ca, Mg, Be 4] Be, Mg, Ca, Sr, Rb
16. Electronegativity __________ from left to right within a period and __________ from top to
bottom within a group.
1] decreases, increases 2] increases, increases 3] increases, decreases
4] stays the same, increases 5] increases, stays the same
17. The IE of the elements __________ as you go from left to right across a period of the
periodic table, and __________ as you go from the bottom to the top of a group in the table.
1] increase, increase 2] increase, decrease 3] decrease, increase
4] decrease, decrease 5] are completely unpredictable
18. Of the choices below, which gives the order for first ionization energies?
1] Cl > S > Al > Ar > Si 2] Ar > Cl > S > Si > Al 3] Al > Si > S > Cl > Ar
4] Cl > S > Al > Si > Ar 5] S > Si > Cl > Al > Ar
19.What is the formula for tetra-‐phosphorus hex-‐oxide?
1] P6O4 2] P4O6 3] P4O7 4] None of these are correct 5] P2O3
20.
Find
the
percent
of
hydrogen
in
ferric
hydroxide
Fe(OH)3.
1)
2.2
%
2)
2.8
%
3)
4.0
%
4)
6.7
%
21.
A
compound
is
40.0
%
carbon,
6.66
%
hydrogen
and
53.3
%
oxygen.
What
is
its
empirical
formula?
1] C4H7O5 2] CH3O2 3] C2H6O4 4] CH2O
Section
II-‐-‐-‐-‐Bonding-‐
Lewis
dot,
shapes
&
intermolecular
forces
• Drawing Lewis dot structure ( no resonance/ expanded
octet/hybridization)
• Geometry names for all molecules from AX2 AX3 AX4 ( chart will be
given no need to memorize names but you should recognize them)
• Hydrogen bonding, dipole-‐dipole force & London forces( Vander waal’s
force
• Blue sheet with properties of solids chart
22.
The
bonding
in
the
barium
fluoride
crystal
is
primarily:
1)
ionic;
2)
polar
covalent;
3)
metallic;
4)
non-‐polar;
23.
Which
compound
is
the
most
ionic?
1)
CCl4(l)
2)
SiO2(s)
3)
KCl(s)
4)
NH3(g)
5)
Br2(l)
24.
The
shape
of
NH4+
is
best
described
by:
1)
Linear
2]
Planar
3]
Pyramidal
4]
Tetrahedral
5]
Octahedral
25.
In
which
compound
does
the
bond
have
the
least
degree
of
ionic
character?
1)
KBr
2)
HF
3)
MgO
4)
BrCl
5)
All
have
the
same
degree.
26.
Which
molecule
has
the
most
polar
bonding
characteristics?
1)
H2O
2)
H2S
3)
H2Se
4)
H2Te
5)
NaBr
27.
Which
of
the
following
is
not
a
polar
molecule?
1)
hydrogen
fluoride
2)
hydrogen
3)
water
4)
ammonia
(NH3)
28.
Which
of
the
following
kinds
of
bonds
exists
in
a
N2
molecule?
1)
ionic
2)
polar
3)
single
4)
double
5)
triple
29.
Element
X
has
an
electron
configuration
of
1s2
2s22p6
3s2.
Element
X
will
most
likely
form
oxides
with
the
formula
1)
X2O;
2)
X2O3;
3)
XO;
4)XO2.
30.
Which
represents
a
polar
molecule?
1)
F2
2)
O2
3)
CH4
4)
CO2
5)
HCl
31.
The
geometry
of
the
SO3
molecule
is
best
described
as
1)
trigonal
planar
2)
tetrahedral
3)
trigonal
pyramidal
4)
bent
32.
Pi
(π)
bonding
occurs
in
each
of
the
species
except
1)
CO2;
2)
C2H4;
3)
CN-‐;
4)
C6H6;
5)
CH4
33.
Which
of
the
following
molecules
are
non-‐polar?
1)
CO
and
CO2;
2)
H2O
and
CO;
3)
CO
and
CH4;
4)
CO2
and
CH4;
5)
CH4
and
H2O
34.
The
molecular
shape
for
carbon
disulfide,
CS2
is
1)
Linear
2)
Angular
3)
Pyramidal
4)
Tetrahedral
5)
Trigonal
planar
35.
Which
of
these
statements
about
solid
NaCl
is
false?
1)
Within
the
crystal,
each
Na
ion
is
surrounded
by
Cl
ions.
2)
The
bonding
in
NaCl
crystals
is
strong.
3)
Each
chloride
ion
is
surrounded
by
Na
ions
in
a
crystal.
4)
Each
Na
ion
is
attracted
to
Cl
ions
because
of
their
opposite
charges.
5)
Each
Na
ion
is
bonded
tightly
to
only
one
Cl
ion,
forming
molecules
of
NaCl
within
the
crystal.
36.
Which
has
a
trigonal
planar
configuration?
1)
C1O3-‐
2)
NO3-‐
3)
PH3
4)
CO2
5)
NH4+
37.
Which
of
the
following
molecules
would
be
tetrahedral?
1)
SO2
2)
SiH4
3)
SF4
4)
BC13
5)
XeF4
38.
The
shapes
of
BF3
and
NF3
molecules
are
1)
trigonal
planar.
2)
different
3)
pyramidal
4)
tetrahedral.
5)
hydrogen
bonding.
39.
A
substance
which
is
highly
soluble
in
water
is
probably
1)
ionic.
2)
either
ionic
or
polar
covalent.
3)
polar
covalent.
4)
neither
ionic
nor
polar
covalent.
5)
non-‐polar
covalent.
40.
Iodine,
I2,
is
very
slightly
soluble
in
water,
a
polar
solvent,
but
quite
soluble
in
toluene,
a
non-‐polar
solvent.
What
can
be
inferred
about
the
nature
of
the
I2
molecule?
1)
It
is
ionic.
2)
It
is
non-‐polar.
3)
It
is
polar.
4)
It
is
hydrogen
bonded.
5)
Nothing
can
be
inferred.
41.
Alcohol
is
very
soluble
in
water
because
both
compounds
1)
are
liquids;
2)
are
ionic;
3)
possess
molecules
that
can
link
by
hydrogen
bonds;
4)
are
non-‐polar.
42.
Which
of
the
following
statements
is
characteristic
of
an
ionic
compound?
1)
reflects
light
2)
melting
point
is
low
3)
is
soluble
in
non-‐polar
solvents
4)
has
a
high
vapor
pressure
5)
conducts
electric
current
in
liquid
phase
43.
The
boiling
point
of
CH4
is
much
lower
than
that
of
HF.
This
is
because:
1)
of
ion-‐dipole
interactions
in
CH4.
2)
of
hydrogen
bonding
in
HF.
3)
HF
is
more
polarizable.
4)
CH4
is
polar.
44.
The
difference
between
an
ionic
compound
and
molecular
compound
is:
1) the
transfer
or
sharing
of
electrons.
2)
the
ionization
energy
of
the
nonmetal.
3)
the
electronegativity
of
the
metal.
4)
the
electron
affinity
of
the
metal.
45.
The
concept
of
"like
dissolves
like"
is
illustrated
by
which
of
the
following?
1)
NaCl
(s)
is
more
soluble
in
CCl4
than
in
water.
2)
I2(s)
is
more
soluble
in
CCl4
than
in
water.
3)
CuSO4(s)
is
more
soluble
in
CCl4
than
in
water.
4)
CCl4
is
soluble
in
water.
5)
I2(s)
is
more
soluble
in
water
than
in
CCl4.
46.
Which
one
of
the
following
molecules
would
be
most
polar?
1)
HF
2)
HCl
3)
HBr
4)
H2
5)
HI
47.
Based
on
the
following
information:
CF4,
molar
mass
87.99
&
B.P
is
-‐182°C,
CCl4,
molar
mass
153.8,
&
B.P
is
-‐123°C
The
reason
that
CCl4
has
a
higher
boiling
point
than
CF4
is
that:
1)
CF4
molecule
have
a
greater
polarizability
2)
CCl4
molecules
have
a
greater
polarizability
3)
CCl4
molecules
are
more
polar
4)
CF4
molecules
are
more
polar
48.
Solid
iodine
would
be
most
soluble
in
which
of
the
following
solvents?
1)
H2O
2)
CCl4
3)
iodine
would
be
equally
soluble
in
H2O
and
CCl4
4)
iodine
would
be
insoluble
in
both
H2O
and
CCl4
49.
Which
pure
substance
would
have
the
largest
molar
heat
of
vaporization?
1)
Ar
2)
H2
3)
N2
4)
H2O
5)
CH4
50.
Which
pure
substance
would
have
the
smallest
molar
heat
of
vaporization
(energy
needed
to
change
liquid
to
gas)?
1)
C4H10
2)
C5H12
3)
C3H8
4)
CH4
5)
C2H6
Section
III-‐-‐-‐-‐-‐-‐Equationsns/Types
of
Reactions/
Naming
&
Formula/
Moles/E.F
M.F/Stoichiometry/Molarity/Dilution
• Balancing
equations
&
identifying
types
of
reactions
(no
ionic
eq)
• Writing
names
&
formulas
using
a
flow
chart
(will
be
given)
• Using
moles
map
&
completing
unit
cancellation
problems
for
moles.
• Finding
EF
&
MF
using
%
composition
of
elements
(no
organic
EF)
• Stoichiometry-‐
limiting
&
excess
reagent.
&
Molarity
&
Dilution
problems.
51.
The
percent
composition
of
aluminum
in
aluminum
hydroxide
is:
1)
50%
2)
25%
3)
14%
4)
none
of
these
answers
52.
There
are
6.02
x
1023
water
molecules
in
a
mole
of
water.
What
is
the
mass
of
3.01
x
1023
molecules
of
water?
1)
0.50
grams
2)
9.00
grams
3)
18.0
grams
4)
27.0
grams
53.
What
is
the
mass
of
3.4
moles
of
aluminum
hydroxide?
1)
156.4
g.
2)
207.4
g.
3)
265.2
g.
4)
294.1
g.
54.
Which
substance
is
limiting
if
3.8
moles
of
Ca
are
reacted
with
5.6
moles
of
hydrogen
bromide?
1)
calcium
2)
calcium
bromide
3)
hydrogen
bromide
4)
hydrogen
55.
If
500
grams
of
a
gas
contain
7.6
x
1023
molecules,
what
will
be
the
volume
of
this
gas
at
STP
conditions?
1)
17.7
liters
2)
24.5
liters
3)
28.4
liters
4)
31.2
liters
56.
Find
the
mass
of
3.9
x
1023
molecules
of
carbon
dioxide
gas
at
STP
conditions.
1)
19.1
grams
2)
28.6
grams
3)
67.7
grams
4)
76.4
grams
57.
What
volume
of
hydrogen
sulfide
gas,
H2S,
has
the
same
number
of
molecules
as
10.0
liters
of
neon
gas,
Ne?
Both
gases
are
at
the
same
temperature
and
pressure.
1)
3.33
liters
2)
10.0
liters
3)
22.4
liters
4)
30.0
liters
58.
The
number
of
moles
of
sodium
chloride
represented
by
117
grams
is
1)
1
2)
2
3)
3
4)
3.25
5)
22.4
59.
A
gas
has
a
density
of
0.717
gram/liter
at
STP.
What
is
the
molecular
mass
in
grams/mole?
1)
4.0
g/m
2)
16.1
g/m
3)
28.0
g/m
4)
32.0
g/m
5)
35.5
g/m
60.Which
set
of
coefficients
correctly
balances
the
reaction
K3PO4
+
MgCl2
______?
1)
1,
3,
1,
6
2)
2,
3,
1,
6
3)
2,
3,
2,
1
4)
3,
2,
1,
6
5)
none
of
these
61.
How
many
moles
of
water
are
formed
when
one
mole
of
butane,
C4H10
(g),
is
burned
in
oxygen?
1)
1
mole
2)
5
moles
3)
8
moles
4)
11.2
moles
5)
22.4
moles
62.
The
chemical
reaction
represented
by
the
equation:
2
NaOH
+
H2SO4
=>,
is
an
example
of:
1)
double
replacement
2)
single
replacement
3)
decomposition;
4)
combination.
63.
The
reaction
between
zinc
and
hydrogen
chloride
is:
l)
combination;
2)
single
replacement;
3)
neutralization;
4)
double
replacement.
64.
The
breaking
down
of
a
complex
substance
to
form
two
or
more
simpler
substances
is:
1)
decomposition;
2)
composition;
3)
replacement;
4)
double
replacement.
65.
In
the
thermite
reaction
iron
is
produced
from
iron
ore,
Fe3O4.
What
type
of
reaction
is
this.
1)
double
replacement
2)
single
replacement
3)
decomposition;
4)
combination.
66.
In
the
reaction
Al
+
O2
__________
,
how
many
moles
of
aluminum
oxide
are
produced
from
one
mole
of
aluminum?
1)
0.5
mole
2)
2.0
moles
3)
3.0
moles
4)
4.0
moles
5)
none
of
these
67.
Which
substance
is
in
excess
if
7.0
moles
of
Al
are
reacted
with
10.0
moles
of
H2SO4
1)
H2SO4
2)
aluminum
sulfate
3)
hydrogen
4)
aluminum
68.
How
many
grams
of
AgBr
will
form
when
45.0
mL
of
0.842
M
CaBr2
combines
with
excess
AgNO3?
CaBr2(aq)
+
2
AgNO3(aq)
2
AgBr(s)
+
Ca(NO3)2(aq)
1)
14.2
g
2)
2.31
g
3)
20.1
g
4)
7.12
g
69.
What
is
the
coefficient
of
chromic
nitrate
in
the
following
chemical
reaction
when
it
is
balanced?
calcium
chloride
+
chromium
(III)
nitrate
__________________
.
1)
1
2)
2
3)
3
4)
4
5)
5
70.
When
water
and
carbon
dioxide
are
formed
during
an
exothermic
reaction,
it
is
a-‐
a)
synthesis
reaction
b)
combustion
reaction
c)
single
displacement
reaction
d)
double
displacement
reaction
71.
Which
of
the
following
compounds
are
insoluble
in
water?
A.
Na2CO3
B.
PbSO4
C.
AgBr
D.
K2S
1]
A
&
B
only
2]
C
&
D
only
3]
D
&
B
only
4]
C
&
B
only
72.
A
20.0
grams
sample
of
NaOH
is
used
to
make
a
250.
mL
NaOH
solution.
What
is
the
molarity
of
the
NaOH
solution?
1)
5.00
M
2)
8.00
M
3)
2.00
M
4)
1.00
M
73.
How
many
grams
of
NaCl
are
needed
to
prepare
0.500
L
of
a
4.00
M
NaCl
solution?
1)
117
g
2)
4.00
g
3)
58.5
g
4)
2.00
g
74.
Calculate
the
new
concentration
when
25.00
mL
of
a
5.0
M
stock
solutions
of
CuSO4
is
diluted
to
500.00
mL.
1]
0.025
M
2)
0.250
M
3)
0.25
M
4)
0.0250
M
Section
IV-‐-‐-‐-‐Gas
Laws/Energy/
Chemical
equilibrium/
Acids
Bases
75.
Hydrogen
has
a
volume
of
48
ml.
at
STP
conditions.
What
pressure
is
needed
to
convert
this
gas
to
60
ml.
at
300C
conditions?
1)
0.68
atm.
2)
0.95
atm.
3)
1.48
atm.
4)
1.06
atm.
5)
none
of
these
76.
At
4000C
and
0.878
atm.,
4.55
liters
of
NO2
(g)
are
converted
completely
to
N2O4
(g)
at
00C
and
0.945
atm.
The
reaction
is
2
NO2
(g)
!
N2O4
(g).
Calculate
V.
1)
0.00
liter
2)
3.42
liters
3)
2.44
liters
4)0.86
liter
5)
1.71
liters
76.
If
the
density
for
the
gas
neon
is
0.3
gram/liter,
what
volume
will
one
mole
of
this
gas
occupy?
1)
9.7
liters
2)
67.3
liters
3)
84.1
liters
4)
89.3
5)
101
liters
77.
A
substance
which
is
easily
changed
to
a
gas
is
said
to
be:
1)
flammable;
2)
non-‐flammable;
3)
diffusable;
4)
volatile;
5)
deliquescent.
78.
Four
grams
of
magnesium
react
with
an
excess
of
dilute
hydrochloric
acid.
Calculate
the
volume
in
liters
of
hydrogen
gas
collected
over
water
at
300
K,
if
the
vapor
pressure
of
water
at
that
temperature
is
26.7
mm
and
the
barometric
pressure
is
730
mm.
1)
3.14
1iters
2)
3.69
1iters
3)
3.81
1iters
4)
4.39
1iters
5)
5.20
1iters
79.
A
sample
of
air
is
heated
from
100C
to
400C.
P=
30
lbs/sq.
in,
what
will
be
the
new
pressure?
1)
14.6
lbs/sq.
in.
2)
27.1
lbs/sq.
in.
3)
21.7
lbs/sq.
in.
4)
33.2
lbs/sq.
in.
5)
41.9
p.s.i.
80.
If
1.60
grams
of
a
gas
occupy
230
ml.
at
300C
and
3
atm.,
what
is
the
density
of
the
gas
at
standard
pressure
and
temperature?
1)
2.17
g/1
2)
18.8
g/l
3)
2.58
g/1
4)
23.2
g/l
5)
none
of
these
81.
In
a
reaction
HCl,
72
mg.
of
Mg
metal
produced
91
ml.
of
a
gas
collected
over
water
at
220C
and
630
mm.
of
Hg
pressure.
How
many
mg
of
aluminum
metal
would
be
needed
to
produce
the
same
volume
of
the
same
gas
under
the
same
conditions?
1)
36
mg.
2)
48
mg.
3)
56
mg.
4)
71
mg.
5)
81
mg.
82.
A
sealed
bottle,
which
can
stand
an
internal
pressure
of
4.0
atmospheres,
is
filled
with
air
at
l60C
and
760
mm
pressure.
At
what
temperature
would
the
bottle
break?
1)
65
K
2)
73
K
3)
724
K
4)
1,157
K
5)
1,214
K
- -
83. HF + HCO3 " F + H2CO3 Identify the bases in the reaction.
1] HF and HCO3- 2] F - and H2CO3 3] HF and H2CO3 4] F - and HCO3-
84.
If
the
density
of
a
certain
gas
at
273
K
and
760
mm
of
Hg
is
1.4
grams
per
liter,
its
molar
weight
may
be
found
by
the
expression
1)
1.4
g.
x
4
x
22.4
1
3)
1.4
g.
x
2
x
22.4
1
5)
760
x
1.4
g
2)
1.4
g.
x
22.4
1
4)
2
x
22.4
1
273
K
1.4
g
85.
A
gas
occupies
a
volume
of
1.25
liters
at
800
mm
of
Hg
and
50.00C.
Which
mathematical
expression
determines
its
volume
at
S.T.P.?
1)
1.25
x
800
x
273
3)
1.25
x
760
x
323
760
x
323
800
x
273
5)
1.25
x
760
x
273
2)
1.25
x
760
x
273
4)
1.25
x
800
x
50.0
800
x
50.0
800
x
323
760
x
273
86.
Calculate
the
partial
pressures
of
gases
A
and
B.
They
are
mixed
in
a
ratio
of
2.0
moles:3.0
moles.
The
total
pressure
of
the
system
is
600
mm
of
Hg.
1)
200
mm
and
400
mm.
3)
300
mm
and
300
mm.
2)
240
mm
and
360
mm.
4)
400
mm
and
200
mm.
5)
500
mm
&
100
mm.
87.
At
the
same
temperature
which
gas
has
the
fastest
average
molecular
speed?
1) H2 2) N2 3) CO2 4) CH4 5) C8H18
88.
If
there
is
no
change
in
temperature,
what
pressure
is
necessary
to
change
750
ml.
of
carbon
dioxide
at
1.20
atm.
to
520
ml?
1)
0.99
atm.
2)
10.73
atm.
3)
22.22
atm.
4)
509.9
atm.
5)
none
of
these
89.
One
mole
of
nitrogen,
two
moles
of
neon,
and
four
moles
of
argon
are
sealed
in
a
cylinder.
The
combined
pressure
of
the
gases
is
1400
mm
of
Hg.
What
is
the
partial
pressure
of
the
nitrogen,
in
mm
of
Hg?
1)
100
mm.
2)
200
mm.
3)
400
mm.
4)
500
mm.
5)
1,400
mm.
90.
If
3.00
moles
of
neon
in
a
flask
has
a
pressure
of
l.50
atm.
The
pressure
rises
to
4.50
atm.
when
1.00
mole
of
hydrogen
and
some
oxygen
are
added.
How
many
moles
of
oxygen
are
added?
1)
1.50
moles
2)
3.00
moles
3)
5.00
moles
4)
2.50
moles
5)
4.50
moles
91.
The
density
of
a
gas
at
273
K
and
760
mm
of
Hg
is
4.00
g/l.
What
is
its
molecular
mass
in
g/mol?
1)
0.0112
2)
0.176
3)
5.60
4)
32.2
5)
89.6
92.
If
the
density
of
a
gas
is
1.87
grams/liter
at
340C
and
745
mm
Hg,
what
will
be
its
density
at
840C
and
721
mm
Hg?
1)
0.64
g/l.
2)
0.73
g/l.
3)
1.11
g/l.
4)
1.56
g/l.
5)
2.10
g/l.
93.
The
mercury
level
inside
a
eudiometer
tube
is
8
mm
higher
than
the
mercury
level
outside.
The
gas
pressure
outside
the
tube
is
13
mm
less
than
standard
pressure.
What
is
the
gas
pressure
inside
the
tube?
1)
739
mm.
2)
747
mm.
3)
755
mm.
4)
781
mm.
5)
none
of
these
94.
When
a
bottle
of
perfume
is
opened,
its
fragrance
spreads
quickly
all
over
a
room.
This
is
an
example
of:
1)
molarity;
2)
compressibility;
3)
diffusion;
4)
expansibility.
95.
A
rubber
balloon
containing
hydrogen
has
a
volume
of
3.0
liters.
It
is
being
used
to
study
the
acceleration
behavior
of
hydrogen
upon
its
release
into
the
atmosphere.
The
temperature
here
is
200C
and
the
pressure
exerted
by
the
hydrogen
is
9.0
cm
above
that
of
standard
conditions.
The
balloon
rises
to
the
top
of
the
tower
where
it
expands
to
3200
ml.
and
the
pressure
changes
to
840
mm.
Calculate
the
temperature
at
the
top
of
the
tower.
1)
21.10C.
2)
35.90C.
3)
271.5
K.
4)
316.3
K.
5)
326.7
K.
96.
Given
the
reaction:
2
Al(s)
+
3/2
O2(g)
A12O3(s);
ΔH
=
-‐400
kcal/mol.
How
much
heat
will
be
given
off
by
the
reaction
of
27
grams
of
aluminum?
1)
100
kcal
2)
200
kcal
3)
300
kcal
4)
400
kcal
97.
When
100
calories
of
heat
energy
are
added
to
10
grams
of
water
at
200C,
the
final
temperature
of
the
water
will
be
1)
100C;
2)
300C;
3)
400C;
4)
1000C.
98.
The
equation
MgCO3(s)
+
energy
!
MgO(s)
+
CO2(g)
is
a(n)
1)
combustion
reaction;
2)
exothermic
decomposition
reaction;
3)
endothermic
synthesis
reaction;
4)
endothermic
decomposition
reaction.
99.
Fifty
grams
of
water
are
heated
from
22.00C
to
36.00C.
How
much
heat
is
absorbed?
1)
360cal
2)
1,080cal
3)
700cal
4)
1,100cal
5)
1,800cal
100.
Use
the”
heat
of
formation”
of
each
substance
to
determine
the
ΔH
for
the
overall
reaction:
C6H14(g)
+
O2(g)
6
CO2(g)
+
7
H2O(g).
1)
-‐40.0
kcal
2)
–111.8
kcal
3)
–928.6
kcal
4)
–1,008.6
kcal
5)
none
of
these
101.
Use
the
“heat
of
formation”
of
each
substance
to
determine
the
ΔH
for
the
overall
reaction:
2
Al(s)
+
Fe2O3(s)
Al2O3(s)
+
2
Fe(s).
1)
+595.0
kcal
2)
–203.0
kcal
3)
–196.0
kcal
4)
–399.0
kcal
5)
–595.0
kcal
102.
When
C2H5OH(l)
reacts
with
O2(g),
CO2(g)
and
H2O(g)
are
produced.
With
the
help
of
a
“heats
of
formation”
table,
calculate
the
H
of
this
reaction.
1)
–85.4
kcal
2)
+295.0
kcal
3)
–66.4
kcal
4)
–427.8
kcal
5)
none
of
these
103.
Calculate
ΔH
for
the
reaction
4
NH3
(g)
+
5
O2
(g)
-‐-‐>
4
NO
(g)
+
6
H2O
(g),
from
the
following
data:
N2 (g) + O2 (g) -‐-‐> 2 NO (g) ΔH = -‐180.5 kJ
N2 (g) + 3 H2 (g) -‐-‐> 2 NH3 (g) ΔH = -‐91.8 kJ
2 H2 (g) + O2 (g) -‐-‐> 2 H2O (g) ΔH = -‐483.6 kJ
Answer
-‐1628.2kJ
104.
Find
ΔH
°
for
the
reaction
producing
1
mole
of
ethyl
alcohol
from
its
elements.
Use
the
following
thermochemical
data.
C2H5OH (l) + 3 O2 (g) -‐-‐> 2 CO2 (g) + 3 H2O (l) ΔH = -‐875. kJ
C (s) + O2 (g) -‐-‐> CO2 (g) ΔH = -‐394.51 kJ
H2 (g) + ½ O2 (g) -‐-‐> H2O (l) ΔH = -‐285.8 kJ
Answer -‐771.42kJ
105. Calculate ΔH for the reaction CH4 (g) + NH3 (g) -‐-‐> HCN (g) + 3 H2 (g), given:
N2 (g) + 3 H2 (g) -‐-‐> 2 NH3 (g) ΔH = -‐91.8 kJ
C (s) + 2 H2 (g) -‐-‐> CH4 (g) ΔH = -‐74.9 kJ
H2 (g) + 2 C (s) + N2 (g) -‐-‐> 2 HCN (g) ΔH = +270.3 kJ
Answer 255.95kJ
106. Calculate ΔH for the reaction for formation of solid AlCl3 from the Data.
2 Al (s) + 6 HCl (aq) -‐-‐> 2 AlCl3 (aq) + 3 H2 (g) ΔH = -‐1049. kJ
HCl (g) -‐-‐> HCl (aq) ΔH = -‐74.8 kJ
H2 (g) + Cl2 (g) -‐-‐> 2 HCl (g) ΔH = -‐1845. kJ
AlCl3 (s) -‐-‐> AlCl3 (aq) ΔH = -‐323. kJ
Answer
-‐3193.4kJ
107.
For
any
chemical
reaction
at
equilibrium,
which
of
the
following
will
change
the
value
of
the
equilibrium
constant?
1)
adding
a
catalyst
2)
increasing
the
pressure
3)
increasing
concentration
of
the
reactants
4)
increasing
temperature
5)
increasing
concentration
of
the
products
108.
Increasing
the
initial
concentrations
of
reactants
1)
has
no
effect
on
a
reaction.
2)
increases
the
energy
produced.
4)
increases
the
number
of
collisions
per
sec.
3)
has
no
effect
on
the
reverse
reaction.
5)
none
of
these
possibilities
occur.
109.
If
a
bottle
1/2
full
of
H2O
is
tightly
corked,
equilibrium
will
be
reached
between
H2O(g)
and
H2O(l)
in
the
bottle.
Which
of
the
following
is
wrong?
1) Raising temperature favors formation of more H2O(g).
2) Lowering temperature will decrease pressure on inside walls.
3) Water vapor pressure will increase as temperature increases.
4) Decreasing volume by pushing the cork farther in favors formation of more H2O(g).
5) Raising temperature will decrease the amount of H2O(l) present in the bottle.
110. Consider the equilibrium reaction: 1/2 Br2(g) + 1/2 H2(g) ⇄ HBr(g) + 52 kcal.
Which statement is false?
1) The rate of HBr formation equals its rate of decomposition.
2) A temperature increase would cause less HBr to be present.
3) A catalyst would not change the equilibrium concentrations.
4) A pressure increase would shift the equilibrium so that more HBr would be present.
5) The [H2(g)] at equilibrium would decrease if the [Br2(g)] were increased.
111. In the reaction 2 A + B ⇄ C + 3 D, the molar concentrations at equilibrium
are: A = 1; B = 4; C = 8; and D = 2. What is the value of the equilibrium constant?
1) 1/16 2) 1/6 3) 16 4) 64 5) none of these
112. Into a system which contained only A, a limited amount of B is injected. The
equilibrium, A + B ⇄ C is established. Which of the following statements applies?
1) The concentration of A is unchanged.
2) The concentration of B is zero at equilibrium.
3) The concentration of C increases until either A or B is exhausted.
4) The concentration of A decreases initially, then becomes constant.
5) The concentrations of A and B become equal.
113. Kp is 0.16 at 250C, and H = -‐82 kcal for the following reaction:
2 NOBr(g) ⇄ 2 NO(g) + Br2(g).
Which one of the following statements is false?
1) Kp for the reaction at 1000C will be less than 0.16.
2) If the equilibrium mixture is compressed, the number of moles of Br2 will decrease.
3) Addition of Br2 to the equilibrium mixture will result in an increase in NO.
4) Addition of NOBr to the equilibrium mixture will cause no change in Kp.
5) If the temperature is decreased, more Br2 is produced.
114. Consider the reaction NO(g) + O3(g) ⇄ NO2(g) + O2(g) + 43.5 kcal. If the reaction
is in a closed vessel at a given temperature, consider the following possible changes:
A. Decrease temperature B. Add a catalyst C. Add O3 D. Reduce the pressure
Which changes would increase the amount of NO2 present at the new equilibrium?
1) A and B only 2) B and D only 3) B and C only 4) C and D only 5) A and C only
115. Consider the all-‐gas equilibrium H2O + CO ⇄ H2 + CO2 for which Keq = 4.0
at a certain temperature. If you were to begin with 1.5 moles of H2O and 1.5 moles
of CO in a 1.0 liter vessel, what would be the equilibrium concentration of CO2?
1) 0.5 M 2) 0.8 M 3) 1.0 M 4) 1.2 M 5) 2.0 M
116. Consider he reaction: 2 SO2(g) + O2(g) ⇄ 2 SO3(g). The equilibrium constant
is 8.6 x 10-‐2. If the equilibrium concentrations of SO2 and SO3 are 4.2 x 10-‐1 M and
6.4 x l0-‐3 M respectively, what is the molarity of O2?
1) 4.1 x 10-‐5 M 2) 1.3 x 10-‐2 M 3) 2.7 x 10-‐3 M 4) 1.8 x 10-‐1 M 5) 3.6 x l01 M
117. The substance that acts as both a Bronsted acid and a Bronsted base is:
1) HClO; 2) H2SO4; 3) PO4-‐3; 4) HSO3-‐; 5) ClO4-‐.
118. The pH of a 1.25 x 10-‐3 M NaOH solution is:
1] 2.90 2] 11.10 3] 3.10 4] 7.00 5] 10.90
119. A _____ M solution of Ba(OH)2 has a pH of 12.7.
1] 2.0 x 10-‐13 M 2] 5.0 x 10-‐2 M 3] 1.0 x 10-‐13 M 4] 1.27 x 101 M 5] 2.5 x 10-‐2 M
120.
What
is
the
hydronium
ion
concentration,
[H3O+]
,
of
a
solution
that
has
a
pH
of
8?
1)
10-‐4
M
2)
10-‐6
M
3)
10-‐8
M
4)
107
M
5)
none
of
these
121.
What
is
the
pH
of
a
0.01
M
solution
of
sodium
hydroxide,
NaOH?
1)
12
2)
2
3)
10-‐2
4)
10-‐12
122.
Which
hydroxide
ion
concentration
indicates
the
solution
is
the
most
acid
in
content?
1)
1
x
10-‐10
M
2)
1
x
10-‐8
M
3)
1
x
10-‐6
M
4)
1
x
10-‐4
M
123. The conjugate acid of HSO4-‐ is
1) HSO3+ 2) SO42-‐ 3) HSO4+ 4) H2SO4 5) H+
What not to study
Nuclear reactions & half-‐life
Scientist names from history of atomic structure & gas
laws
Exceptions for electron configurations,
E.C for f-‐elements & box diagrams
Explanation for periodic trends
Organic Chemistry & functional groups
Shapes of molecules besides the basic shapes: linear,
bent, trigonal planar (flat triangle), tetrahedral and
trigonal pyramidal
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