FIITJEE

TOPIC: PERIODIC PHASE– I CLASS: XI (Chemistry)

PROPERTIES

NAME…………………….. ENROLL NO……………. BATCH…………………

1. In which of the following compound manganese shows maximum radius?

(A) M nO 2 (B) KM nO 4 (C) M nO (D) K M n  C N  

3  6 

2. Select correct statement

(A) Atomic size of the same group elements of 3d and 4d-series re almost similar.
(B) First ionisation energies of 5d-series elements are smaller than that of 3d and 4d-series
elements.
(C) Both are correct
(D) Both are incorrect
3. Fluorine is more electronegative than nitrogen. The best explanation is that
(A) the valency electrons in F are on the average, a little farther to the nucleus than in N.
(B) the charge on a F nucleus is -9, while that of N nucleus is +7.
2 3
(C) the nitrogen has half filled valence shell electron configuration, ns np where as fluorine has
2 5
partially filled electron configuration ns np .

(D) the electronegativity decreases from top to bottom in each of the group as the effective
nuclear charge remains constant.
4. Metallic nature increases moving down the group because
(A) Nuclear charge decrease
(B) shielding increases
(C) A and B both
(D) None of these
5. Select the correct statement
(A) More active metals are on the left side of the periodic table.
(B) Less active metals are on the left side of the periodic table.
(C) Reducing power of alkali metals (g) decreases moving down the group
(D) Metallic character decreases down the group
6. Match List I with List II and then select the correct answer from the codes given below the lists
List-I List-II
(A) Isoelectronic (a) A

+ energy  A++
(B) Half filled orbital (b) Ar, K+, Ca++
(C) Second ionisation energy (c) Cerium
(D) Lanthanide (d) Arsenic

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Codes:
A B C D A B C D
(A) c b d a (B) b c a d
(C) d c a B (D) b d a c

7. Consider the following statements.

Statement 1: Fluorine does not form any polyhalide as it has low F – F bond energy.
Statement 2: The chlorine has the most negative electron gain enthalpy.
Statement 3: The first ionization potential of N and O atoms are 14.6 and 13.6 eV respectively.
Which of the above statements are correct?
(A) S1, S2 and S3 (B) S1 and S2
(C) S1 and S3 (D) S2 and S3
8. Match list I (elements) with list II (properties) and select the correct answer using the codes given
below this lists:
List-I List-II
(P) Tl, Pb, Bi (1) Have almost same atomic radii.
(Q) Fe, Co, Ni (2) Have only dispersion forces as inter
molecular force of attraction.
(R) Ne, Ar, Kr (3) Show inert pair effect.
(S) As, Sb, Ge (4) Show metallic and non-metallic character

P Q R S P Q R S
(A) 1 3 2 1 (B) 3 1 2 4
(C) 4 3 2 1 (D) 1 2 3 4

ONE OR MORE THAN ONE CORRECT OPTION(S)

9. Which of the following statement(s) is/are correct?
(A) The second ionization energy of sulphur is greater than that of chlorine.
(B) The third ionization energy of phosphorus is greater than that of aluminium.
(C) The first ionization energy of aluminium is nearly the same as that of gallium.
(D) The second ionization energy of boron is greater than that of carbon.
10. Which of the following order(s) is/are correct?
2   2
(A) O  F  Na  Mg in c re a s in g Z e ffe c tiv e

2  2 2
(B) Mg  Na  O  Mg in c re a s in g s iz e

2   2
(C) O  F  Na  Mg in c re a s in g io n is a tio n e n e rg y

2   2
(D) O  F  Na  Mg in c re a s in g e le c tro n a ffin ity

11. Which of the following is/are true order(s)?

(A) B' B  B S iz e (B) I'  B r  C l F E le c tro n a ffin ity

(C) OOO' Z e ffe c tiv e (D) Na  Al Mg  Si Io n is a tio n p o te n tia l

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12. Poor shielding of nuclear charge by d or f – orbital electrons is responsible for which of the
following facts?
(A) Atomic radius of Nb (4–d series) is comparable to that of Ta (5–d series)
(B) The 1st ionisation energy of copper is less than that of zinc
(C) The value of electron gain enthalpy is more negative for sulphur than for oxygen.
(D) The 1st ionisation energy for gold is greater than that of silver.
13. Which is not correct order for the properties specified?
(A) I  Br  Cl  F  o x id i s in g c h a ra c te r 

(B) K  Mg  Al  B  m e ta llic c h a ra c te r 

(C) Li  B  Be  C  O  N  F  Ne  firs t io n is a tio n e n th a lp y 

(D) Li  Na  K  Rb  Cs  c h e m ic a l re a c tiv ity 

MATCH THE FOLLOWING

14. Column-I contains some increasing orders of various species and column-II has the properties of
the elements/ ions. Accordingly match the column-I and column-II
Column–I Column-II
(A) Na+ < F– < O2– < N3– (p) Electronegativity
(B) Li+ < Na+ < K+ <Rb+ < Cs+ (q) Mobility of hydrated ions
(C) O < S < F < Cl (r) Ionisation energy
(D) Cl– < K+ < Ca2+ < Sc3+ (s) Electron affinity
(t) Ionic size

15. Match the values of 1st and 2nd ionisation energy and electron gain enthalpy given in the column-I
with types of elements/compounds given in column-II
Column–I Column-II
 IH 1 ,  IH 2 ,  egH (in KJ mol–1) of few elements

(A) 2372 5251 +48 (p) Element which exists as a strong

reducing agent
(B) 419 3051 –48 (q) Element which exists as a
monoatomic molecule.
(C) 1681 3374 –333 (r) Least reactive non-metal
(D) 1008 1846 –295 (s) Element which acts as a strong
oxidising agent.
(t) Element which oxide is a stronger
basic in nature.
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ANSWER

1. C
2. D
3. B
4. B
5. A
6. D
7. D
8. B
9. ABCD
10. ACD
11. ACD
12. AD
13. AD
14. (A t); (B  q, t); (C s); (D p, r, s)

15. (A q); (B  p, t); (C s); (D r)