Chapter 2

2.1 0.2596 W/m K

2.2 (a) 257.95 kcal/(h m2
�C) (b) 52.832 Btu/(h ft2
�F)
2.3 iron
2.4 (a) 10�3 Pa s (b) 2.419 lb/(ft h)
2.5 5.69 � 10�2 lb/ft2.
s
2.6 66.67 kg, 654 N
2.7 1.0197 kgf/cm2, 14.5038 psi
2.8 472.7 mm
2.9 15.3 m, 12.5 kJ
2.10 18 W
2.11 (a) 1286.305 N (b) 1.6378 bar (c) 0.5145 kJ (d) 196.2 J
2.12 30.6305 � 105 J
2.13 1.8829 � 10�4
2.14 (i) 3.038 (ii) 10.94
2.15 CP = 26.5386 + 4.24 � 10�2T � 1.4295 � 10�5T2
2.16 (a) CP = 6.35 + 1.811 � 10�3T � 2.675 � 10�7T2
(b) CP = 6.825 + 1.665 � 10�3T � 2.675 � 10�7T2
(c) CP = 9.495 � 102 + 0.271T � 4.0 � 10�5T2
(d) CP = 6.795 + 0.93 � 10�3T � 8.256 � 10�8T2
2.17 (a) A = 18.2773, B = 3799.887, C = � 226.296
(b) A = 14.331 28, B = 6839.7966, C = � 375.0628
560 Answers to Exercises
2.18 (a) CP = 96.55 + 0.1562T (b) CP = 33.24 + 0.0373T
2.19 5.6629 � 10�8 W/(m2.
K4)
2.20 36.81 kg/s
2.21 (a)
0.25
2 1.25
Btu(inch)
ft (h)(�F)
(b) q = 1.313
1.25
0.25
T
D
D where q is in W/m2, D is in m and DT is in K
2.22 (a) 1 3 2.2
kmol
m (min)(atm)
k = ; 2 3 0.5
kmol
m (min)(atm)
k = (b) k �
1 = 4.795 � 105, k �
2 = 24.185
2.23 a = 3.602 atm L2/(mol)2, b = 4.28 � 10�2 L/(mol)
2.24 V(inch3
) = 0.0610e3600t
2.25
0.15 0.85 1.85
1.15 7.5885
P
H V P
D
m r D ? ? = ? ?
? ?
where DP is in Pa, m is in lb/(ft s), H is in ft, r is in lb/ft3, V is in ft/s and
DP is in ft.
Chapter 3
3.1 267.41 g
3.2 3 mol
3.3 266.45 kg
3.4 72 g
3.5 58% C, 3.4% H and 38.6% Br
3.6 9 kg-equivalents
3.7 57.026
3.8 31.607
3.9 2
3.10 C7H5
N
3.11 (a) 125.38 kg (b) 12.685 g
3.12 (a) 684.48 kg (b) 254.10 kg
3.13 (a) 93.65 kg (b) 88.68 kg
3.14 (a) 146.58 g (b) BaCl2
: 44.61 g, Na2SO4
: 30.43 g (c) 25.04 g
3.15 1292.76 kg
3.16 0.41%
3.17 43.74 kg, 22.28 m3 at STP
3.18 (a) 17.64 m3 (b) 164.21 kg
3.19 1053.2 kg, 895.2 kg
3.20 0.8651 N
3.21 1.5
Answers to Exercises 561
3.22 1.076
3.23 7.273
3.24 (a) 420 kg/m3 (b) 2.24 kmol/h
3.25 18.91�B�, 30�Tw
3.26 45�B�
3.27 29.1�B� , 29.3�API
3.28 0.25
3.29 947 kg/m3
3.30 (a) 768.37 kg/m3 (b) 52.46
(c) gasoline = 24.66%, kerosene = 26.82%, gasoil = 28.30% and isopentane = 20.22%
3.31 0.9263
3.32 131.53 kg of Mg, 1136.78 kg of Na, 2132.67 kg of Cl2
3.33 75.69
3.34 K 44.87%, S 18.4%, O2 36.73%
3.35 47.23
3.36 Ferrous 36.06%, Ferric 30.65%
3.37 12.38% NaNO3, 87.62% water
3.38 567.04 kg
3.39 90.02%
3.40 0.4959, 0.33
3.41 55.23%
3.42 3.7203 � 105 kg
3.43 557.3 mol
3.44 24.57% SiO2
.
2CaO, 43.43% SiO2
.
3CaO
3.45 95.58% (weight) ethanol
3.46 (a) 1.688% (b) 3.48%
3.47 720 kg
3.48 1.0753
3.49 0.2860
3.50 39.75%, 0.6596
3.51 (a) 622.5 (b) 1.297l (c) 1.213 kg
3.52 (a) 0.4751 (b) 42.77 (c) 33.75
3.53 (a) 40.78% A, 27.18% B, 32.04% C (b) 63.07 (c) 41.38% (d) 0.6242
3.54 16.66%
3.55 30.73
3.56 Rs. 275.5
562 Answers to Exercises
3.57 (a) 1.557 g-atom Ca, 3.133 g-atom C (b) CaC2
3.58 (a) 33.27 kg (b) 36.96 kg
3.59 (a) 3.09% (b) 0.0319
3.60 (a) 23.29% O2, 76.71% N2 (b) 28.85
3.61 Chlorine 74.03%, Bromine 13.73%, Oxygen 12.24%
3.62 7.7%
3.63 10.43
3.64 1291 kg/m3
3.65 70 000 ppm
3.66 (a) 179.2 (b) 0.046
3.67 2.78 mol/kg, 2.646 mol/L
3.68 (a) 12.94% (b) 65.00% (c) 5.773 mol/L (d) 8.25 mol/kg solvent
3.69 (a) 29.77% (b) 8.1467 mol/L (c) 8.1467 g eq/L (d) 15.27% LiCl, 84.73% water
3.70 (a) 0.293 (b) 0.0727, 4.35 mol/kg water (d) 8 g eq/L
3.71 (a) 58.59% (b) 9.92 mol/L (c) 21.716 mol/kg water
3.72 (a) KCl = 24%, water = 76% (b) 0.0709 (c) 5.15 mol/L (d) 4.24 mol/kg
3.73 (a) 0.0287 kg (b) 0.26602 mol/L
3.74 (a) Nitrogen (b) 32.76% (c) 30%
3.75 94%, 94.5%
3.76 (a) 90% (b) 100% (c) 75%
3.77
0
0.5
n 0.5
e
+ e
3.78
4 3
8 2
e
e
+
+
3.79 1 2
1 2
3 4
52 2
e e
e e
+
+ +
3.80 1 2
1
3
5 0.5
e e
e
- -
-
3.81 43.43 kg of trisilicate and 24.57 kg of disilicate
3.82 10%, 94.4%, 5.44%
3.83 (a) carbon 240 kg, silica 865 kg (b) 188 kg (c) 1491 kg
3.84 (a) 474.8 kg (b) 8.4% SO2, 10.11% O2 and 81.49% N2
3.85 (a) Ammonia, 17.97% (b) 53.89 kg
3.86 (a) 25.96 m3 (b) 12.46 m3 (c) 35.3 m3
(d) 35.25% SO3
, 23.53% SO2, 41.18% O2 (e) 56.47
3.87 (a) 29.5% (b) 14.71 kPa
Answers to Exercises 563
3.88 (a) 0.4 (b) 0.343 bar
3.89 20%
3.90 (a) 300 m3 (b) 994.29 m3 (c) N2 = 29.32 m3, H2 = 87.96 m3
, NH3 = 58.64 m3
3.91 (a) 0.292 m3 (b) 40%
Chapter 4
4.1 1010.79 kg
4.2 91.67 m3
4.3 7.688 m3
4.4 (a) 2.167 kg (b) 1.702 kg
4.5 0.3557 m3/kg; 0.65% greater
4.6 12.67 bar
4.7 5.6686 � 105 N/m2
4.8 288.8 K
4.9 (a) 0.7153 kg/m3 (b) 2.8582 kg/m3
4.10 7.6098 � 104 kg
4.11 78.98 kg
4.12 0.355 kg
4.13 1.0195 � 10�3 m3
4.14 102�C
4.15 1.119 � 10�3 m3
4.16 (a) 3.0068 kmol (b) 0.3757 kmol, 0.125 (c) 0.7578 kg, 0.007
(d) 6.25 m3 (e) 35.95
4.17 (a) 120 kPa (b) 1.3826 m3 (c) 2 kg/m3
4.18 (a) 30.53 (b) CO2
= 20.18, SO2 = 1.05, CO = 1.83, O2
= 2.62, N2
= 74.32
(c) 1.7213 kg/m3 (d) 1.0528
4.19 28.96, 1.1836 kg/m3
4.20 (a) 71.73% ethane, 2.01% hydrogen and 26.26% carbon dioxide
(b) 2.8865 � 105 mol/L ethane, 1.2027 � 105 mol/L hydrogen, 7.2163 � 105 mol/L CO2
(c) 241.82 kg/h
4.21 (a) 250 bar, 750 bar (b) 8.5155 (c) 204.84 kg/m3
4.22 (a) 35.74 kPa (b) 11.59 m3
4.23 3.2462 m3
4.24 (a) 20.14 kPa (b) 4.42 m3 (c) 2.196 m3/kg
4.25 C3H8
4.26 78%
564 Answers to Exercises
4.27 (a) 25.15 (b) 1.21 kg/m3
4.28 0.0252 kg
4.29 air: 4.313 � 105 N/m2, methyl alcohol: 1.951 � 105 N/m2, and steam: 1.936 �
105 N/m2
4.30 (a) 19.68 (b) 22.36% CO2, 53.44% Cl2, 17.8% N2, 6.4% H2
4.31 (a) 34.62 (b) 38.82
4.32 20
4.33 0.11, (a) 0.648% NH3, 99.352% air (b) 26.27
4.34 (a) CO2 2.12%, N2 5.39%, CH4 92.5% (b) 16.64 (c) 0.7424 kg/m3
4.35 30.25
4.36 (a) CO: 54.34, H2: 4.72, CH4: 0.36, CO2
: 13.50, O2: 0.36, N2
: 26.72,
(b) 17.93 (c) 0.8
4.37 (a) 38.98
(b) Ethylene: 22.0%, Benzene: 49.05%, Oxygen: 1.07%,
Methane: 6.37%, Ethane: 19.27%, Nitrogen: 2.23% (c) 1.7391
4.38 2.48 g, 7.52 g
4.39 (a) 121.6 m3 (b) 24.7 kg
4.40 (a) 70.76 m3 (b) 37.1 kg (c) 2.1% HCl, 97.9% Air
4.41 (a) 70.85 m3 (b) 36.98 kg
4.42 (a) 92.02 m3 (b) 1.082 kg
4.43 (a) 46.44 m3 (b) 34.22 m3 (c) 87.72%
4.44 (a) 81.91 m3 (b) 25.92 kg
4.45 (a) 33.36 (b) 30.28 (c) 20.73 kg (d) 60.28%
4.46 (a) 2.778 m3/min (b) 22.727 m3/min
4.47 (a) 91.43 m3/h (b) 15.05 kg/h (c) 91.84%
4.48 (a) 37.41 kg (b) 115.838 kg
4.49 0.3177 m3
4.50 (a) Ammonia, 17.97% (b) 53.89 kg
4.51 (a) 25.96 m3 (b) 12.46 m3 (c) 35.31 m3 (d) 35.29% SO3, 23.53% SO2
, 41.18% O2
(e) 56.51
4.52 (a) 29.5% (b) 14.71 kPa
4.53 (a) 70% (b) 0.6 bar
4.54 (a) 195.4 m3 (b) 36.036 kg
4.55 (a) 64.34% (b) 15.074 m3 (c) 8.605 m3
4.56 404
4.57 (a) 4.98% CH3OH, 3.73% O2, 51.48% N2, 19.9% HCHO, 19.9% H2O
(b) 395.13 m3
Answers to Exercises 565
4.58 20%
4.59 30%
4.60 0.333 ethylene, 0.667 ethane
4.61 (a) 11.08% CO2, 83.35% N2, 5.57% H2O (b) 26.98 kg (c) 0.0836 bar
4.62 (a) 1142.58 m3 (b) 4588.6 m3/h (c) 259.39 kg, 51.37% HNO3
Chapter 5
5.1 380.1 K
5.2 601.3 K
5.3 (a) 68.30 bar (b) 51.8 bar
5.4 23.84 bar
5.5 93.8 kPa, 94.23 kPa by ideal gas equation
5.6 9.78 kg
5.7 1.48 kg
5.8 (a) 3.502 � 10�3 m3
/mol, 0.936 (b) 3.5235 � 10�3 m3
/mol, 0.942
5.9 0.045 m3, 0.06751 m3
5.10 0.3206 � 10�3 m3/mol
5.11 (a) V = 0.249 � 10�3 m3 (b) 0.23 � 10�3 m3
/mol
5.12 (a) 3 � 10�3 m3/mol (b) 2.98 � 10�3 m3/mol
5.13 1.8 � 10�4 m3/mol, a = 0.54985 N m4/mol2, b = 6.41 � 10�5 m3/mol
5.14 7.134 � 10�5 m3/mol, 1.712 � 10�3 m3/mol
5.15 3.485 � 10�3 m3/mol, 0.8862
5.16 (a) 4.157 � 10�5 m3/mol (b) 6.44 � 10�5 m3/mol (c) 5.3 � 10�5 m3/mol
5.17 76.76 bar
5.18 551 K
5.19 0.1255 m3, 0.1357 m3 using ideal gas equation
5.20 (a) 3.775 � 10�4 m3/mol (b) 3.827 � 10�4 m3/mol
5.21 (a) 3.639 � 10�3 m3/mol (b) 3.52 � 10�3 m3/mol (c) 3.514 � 10�3 m3/mol
5.22 (a) 2.036 � 10�4 m3/mol (b) 1.433 � 10�4 m3/mol (c) 1.4575 � 10�4 m3/mol
5.23 165.2 bar
5.24 V = 1.426 � 10�4 m3/mol
5.25 0.1136 m3
5.26 371.8 K
5.27 (a) 3.1178 � 10�4 m3/mol (b) 2.8635 � 10�4 m3/mol
(c) 2.847 � 10�4 m3
/mol (Amagat�s law) 3.046 � 10�4 m3
/mol (Dalton�s law)
(d) 2.962 � 10�4 m3/mol
5.28 (a) 2.8776 kg/m3 (b) 2.8769 kg/m3
566 Answers to Exercises
Chapter 6
6.1 63.51 kPa and 118.04 kPa
6.2 4.184 � 102
kJ/kg
6.3 2.34 kPa (293 K), 7.63 kPa (313 K), 13.04 kPa (323 K),
20.87 kPa (333 K), 47.95 kPa (353 K)
6.4 0.4653 bar
6.5 234.39 K
6.6 (a) 314.6 K (b) 28.06 kPa
6.7 15.33 kPa
6.8 6.7 kg
6.9 42 kPa, 0.5%
6.10 (a) 1.39 kg
6.11 1.32 kg
6.12 27.76 kPa, 0.18%
6.13 350.6 K, 30.55 kPa, 4.5%
6.14 (a) A = 14.655, B = 2209.7, C = 43 (b) 2861 kPa
6.15 370 K
6.16 (a) 181.97 kPa (b) 444.94 kJ/kg
6.17 (a) 27.102 kPa, 1.66% (b) 379.5 K
6.18 27.46 kPa, 3.0% deviation
Chapter 7
7.1 (a) 25.2% A (b) 57.55 kPa
7.2 92.49% A
7.3 (a) 366.82 K (b) 20.85% n-hexane
7.4 (a) 39.06 kPa (0, 0), 66.99 kPa (0.2, 0.5335), 94.92 kPa (0.4, 0.7531), 108.88
kPa
(0.5, 0.8206), 122.84 kPa (0.6, 0.8728), 150.77 kPa (0.8, 0.9482), 178.7 kPa (1, 1)
(b) 108.9 kPa, 64 kPa
7.5 mole fraction of heptane x = 0.853, y = 0.893
7.6 Between 350.9 K and 357.6 K
7.7 72.32% (Raoult�s law)
7.8 94.7 kPa and 77.2 kPa
7.9 54%
7.10 (a) 26.7% A, 26.7% B, 46.6% C (b) 11.47% A, 33.25% B, 55.3% C
7.11 x = 0.5608, y = 0.7344
7.12 T = 330.4 K, y = 0.5886; Answer: P = 57.63 kPa, y = 0.5908
7.13 f = 0.1982, x = 0.5608, y = 0.7344
Answers to Exercises 567
7.14 T (K) 353.1 358 363 368 373 378 383 383.6
x 1.0 0.78 0.581 0.411 0.258 0.130 0.017 0
y 1.0 0.90 0.777 0.632 0.456 0.261 0.039 0
7.15 7.47 kPa (benzene), 1.91 kPa (toluene); 76.8% (weight) benzene
7.16 pA = 8.53 and Bp = 2.24 kPa. Weight percent of benzene in vapour = 76.4%
7.17 Exhibits positive deviation from Raoult�s law. If Raoult�s law is obeyed,
vapour
composition would be 0.413 mole fraction methanol
7.18 131.24 kPa, 46.2% A
7.19 (a) 8.245 � 102 kPa,
(b) 25.1% butane, 46.3% propane, 28.6% ethane,
(c) 6.19 � 102
kPa, 35.17% butane, 64.83% propane
7.20 The liquid contains 67.42% (mol) nitrogen and the vapour contains 90.34% (mol)
nitrogen
7.21 (a) 342 K (1, 1), 343 K (0.958, 0.983), 348 K (0.726, 0.875), 353 K (0.527,
0.735),
358 K (0.360, 0.581), 363 K (0.210, 0.389), 368 K (0.094, 0.195) 372.4 K (0, 0)
7.22 (a) x and y are given in brackets against P in kPa:
33.79 (0, 0), 43.426 (0.2, 0.3775), 53.062 (0.4, 0.6179), 62.698 (0.6, 0.7844),
72.334
(0.8, 0.9066), 81.79 (1, 1)
(b) x and y are given in brackets against T in K:
311.45 (1, 1), 315 (0.787, 0.902), 319 (0.581, 0.773), 323 (0.405, 0.623), 327
(0.254,
0.449), 331 (0.123, 0.250), 335.33 (0, 0)
7.22 (a) 352.8 K, 405.3 K,
(b) 352.8 (1,1), 363.2 (0.685, 0.914), 373.2 (0.446, 0.786),
383.2 (0.266, 0.611), 393.2 (0.129, 0.378), 405.3 (0,0)
(c) 369 K, 386.5 K
7.24 (a) x and y are given in brackets against P in kPa:
30.74 (0, 0), 57.58 (0.2, 0.573), 84.42 (0.4, 0.782), 111.26 (0.6, 0.89), 138.1
(0.8,
0.956), 164.94 (1, 1)
(b) x and y are given in brackets against T in K:
352.88 (1, 1), 360.0 (0.7658, 0.9474), 370.0 (0.5160, 0.8512), 380.0 (0.3310,
0.7137),
390.0 (0.1900, 0.5273), 400.0 (0.0797, 0.2805), 408.9 (0, 0)
7.25 (a) 77.3% benzene (b) 57.5% benzene (c) 37.9%
7.26 (a) 89.26 kPa (b) 59.5% benzene, 29.5% toluene and 11.0% xylene (c) 92.80,
85.26
7.27 (a) x = 0.5095, y = 0.8866 (b) 338.9 K, 75.7% pentane
(c) 108.5 kPa, 83.4% pentane
7.28 (a) 355.7 K (b) 0.56 (c) mole fraction of alcohol 0.16
7.29 64.86% A, 34.00% B, 1.14% C
568 Answers to Exercises
7.30 9.0 kPa
7.31 0.101 � 10�4 kg oxygen per kg water
7.32 3.074 � 10�4 m3
7.33 4.44 � 104
bar
7.34 HA = 0.23 bar, HB = 0.217 bar
7.35 5.0564 � 10�4 mol/kg
7.36 533 bar
7.37 (a) 15.7 kPa (b) 391.4 K (c) 374.1 K (d) 36.68 kPa
7.38 329.7 K, 356.9 K
7.39 1310 kPa, liquid composition: 6.8% ethane, 66.2% propane, 23.8% isobutene and
the
rest n-butane
7.40 (a) 330 K (b) 340.6 K
(c) Mole % in the liquid and vapour given in brackets: Ethane (0.48, 0.09),
Propane (36.3, 17.45), Isobutane (18.18, 18.74), n-Butane (44.98, 63.35),
Isopentane (0.13, 0.38)
7.41 500 mol each.
Component Mole % in liquid Mole % in vapour
Methane 3.26 28.78
Ethane 16.30 29.68
Propane 42.10 29.90
Isobutene 16.30 5.70
n-Butane 22.04 5.94
7.42 (a) 930.3 kPa
(b) 337.4 K, Composition of condensate: Ethane (1.8%), Propane (6.2%),
Isobutane (17.3%), n-Butane (67.1%), Isopentane (7.50%) 330.2 K,
Composition of the liquid and vapour: Ethane (3.22%, 16.81%),
Propane (9.31%, 18.7%), Isobutane (19.55%, 18.46%), n-Butane
(63.38%, 44.57%), Isopentane (4.54%, 1.46%)
7.43 2205 kPa, Methane: 41.91, Ethane: 20.25, Propane: 21.96, Isobutane: 8.57, n-
Butane:
7.31 706 kPa, Methane: 0.2, Ethane: 1.91, Propane: 16.14, Isobutane: 30.88, n-
Butane:
50.88
7.44 861.4 kPa, 2446 kPa
7.45 758 kPa
7.46 (a) 717 kPa (b) Propane: 63.93%, n-Butane: 36.07%
(c) Propane: 36.07%, n-Butane: 63.93%
7.47 (a) 356 K, 58.8% methanol, 24.1% ethanol, 8.4% propanol, 8.7% butanol,
(b) 373 K, 8.8% methanol, 8.9% ethanol, 13.6% propanol, 68.6% butanol
7.48 (a) 84.2 kPa (b) Ether = 51.26%, Water = 48.74%
7.49 (a) 347.97 K, Pure benzene (b) 342.2 K
Answers to Exercises 569
7.50 (a) 107.3 kPa (b) 66.44%
7.51 342 K, 0.0975 kg
7.52 (a) 342 K (b) 0.7 (c) 0.0989 kg
7.53 (a) 372.3 K (b) 3% aniline
7.54 (a) 306.5 K, 59.15% chlorobenzene (b) 341.1 K, 28.96% chlorobenzene
7.55 (a) 346.5 K (b) 79.43% Chloroform (c) 76.29% Chloroform
7.56 (a) 369.2 K (b) 4.78% aniline
7.57 (a) 178.65 kPa (b) 361.14 K
7.58 Mole fractions of ether in the liquid and vapour against temperature in K:
Water-rich phase:
307(0.0123, 0.9295), 313(0.00914, 0.9277), 323(0.0056, 0.8796), 333(0.0034,
0.8047),
343(0.0018, 0.6945), 353(0.00098, 0.5334), 363(0.00037, 0.3092
7.59 (a) 327.2 K (b) Pure water (c) 316.7 K
7.60 (a) 369.2 K (b) 4.78% aniline
7.61 (a) 361.6 K, 21.9% toluene, 13.1% ethylbenzene, 65.0% water
(b) 387.8 K, 26.8% toluene, 73.2% ethyl benzene
7.62 (a) 25 kPa (b) 12.5% A, 37.5% B, 50.0% C
7.63 Mole fraction of heptane in the vapour against temperature in K:
361.53(0.35), 359.45(0.40), 357.23(0.45), 354.83(0.50), 353.82(0.52), 352.40(0.548)
7.64 (a) 366 K, pure water
(b) 374.9 K, pure toluene, last drop of vapour contains 44.36% toluene
7.65 (a) 388.8 K, pure component 1 (b) 365.5 K, pure component 2
7.66 16.7% A, 83.3% B
7.67 3.35 kg
7.68 (a) 72.704 kg (b) 73.27%
7.69 (a) L = 74.6 mol, V = 25.4 mol
(b) Liquid: 0.062 (A), 0.737 (B), 0.201 (C) Vapour: 0.409 (A), 0.591 (B)
7.70 2.842 kPa
7.71 372.47 K
7.72 (a) 8.85 K (b) 7.8 K
Chapter 8
8.1 (a) 16.6% (b) 29.2% (c) 0.1991 (d) 0.4127 (e) 0.3914 kg/m3
8.2 (a) 104.86 kPa (b) 0.0351
8.3 (a) 3.56% (b) H2
O = 1.49%, CO2 = 98.51% (c) 0.0369 (d) 0.0151
(e) 0.0257 kg/m3
8.4 25.71 kg
570 Answers to Exercises
8.5 Contains 0.946 � 10�2 kg benzene per m3
8.6 51.93 m3
8.7 50.99 kg
8.8 4 kg
8.9 18.8%
8.10 262.7 K
8.11 1623 kPa
8.12 (a) 0.1429 (b) 0.3172 (c) 0.1667 (d) 0.4643 (e) 0.7988 (f) 2.2254
(g) 42.67 kg (h) 20.87% (i) 32.17%
8.13 43.6%
8.14 (a) 10.13 kPa (b) 0.2364 (c) 0.111 (d) 0.3096 (e) 70.44%
(f) 73.41% (g) 106.2 kg
8.15 (a) 0.1526 (b) 0.3163 (c) 13.90 kPa (d) 82.66% (e) 296 K
8.16 (a) 3.6122 kPa (b) 49.65% (c) 0.023 (d) 47.79% (e) 340.2 K
8.17 7.35%
8.18 (a) 0.0537 (b) 82.42% (c) 81.48% (d) 327.45 K
8.19 315.4 K
8.20 19349 kJ/m3
8.21 (a) 288.9 K (b) 0.0954 m3
8.22 (a) 285.75 K (b) 283.76 K
8.23 0.035
8.24 (a) 0.2281, 0.0846 (b) Benzene 7.8% (V), 18.6% (W) (c) 49.37%, 45.08%
8.25 (a) 306.8 K (b) 420.9 kPa
8.26 344.22 kPa
8.27 (a) 0.3467 kg (b) 41.73%
8.28 309.7 K, 0.0253 kg/kg dry air
8.29 0.0117 kg, 0.9857 m3
8.30 (a) 19.2%, 90.6% (b) 0.67% water, 2.2% water (c) 18.63%, 90.3%
(d) 0.487 kg, 1.625 kg (e) 0.484 kg, 1.614 kg
8.31 (a) 2.36% (b) 0.244 (c) 0.384 (d) 298.9 K (e) 236.6
8.32 13.25 kg
8.33 (a) 0.1608 kg of acetone/kg dry of nitrogen, 0.2827 kg of acetone/kg dry
nitrogen
(b) 0.1219 kg (c) 12.7 kg (d) 104.75 m3
8.34 306.9 kPa
8.35 6489.35 m3/h
8.36 (a) 78.8% (b) 24.23 m3/min
Answers to Exercises 571
8.37 1.65 kg/h
8.38 (a) 0.0191 kmol/kmol dry air, 0.00494 kmol/kmol dry air
(b) 1.0276 kg (c) 38.10 m3
8.39 284.6 K
8.40 159.75 kPa
8.41 164.53 m3/h
8.42 322.9 K
8.43 20.5%
8.44 0.0258 kg of water per kg of dry air
8.45 0.0408 kg of water per kg of dry air
8.46 (a) 314.1 K (b) 0.224 kg of benzene per kg of dry air (c) 205.4 kJ
8.48 (a) 299.3 K (b) 304 K
8.49 (a) 279 K (b) 312.3 K
8.50 (a) 310 K (b) 382.2 K (c) 3393.3 kg/h (d) 2851.9 m3
/h
8.51 (a) 6.25% (b) 1.602 kPa (c) 0.16 kg water/kg dry air (d) 20.7 kPa
(e) 7.73% (f) 287.7 K (g) 1.0238 kJ/kg (h) 300.7 K
8.53 (a) 0.04 (b) 0.0644 (c) 26.5% (d) 1.0036 m3 (e) 310.2 K (f) 158.05 kJ/kg
8.54 (a) 0.035 kg/kg (b) 0.0564kmol/kmol (c) 14% (d) 1.0345 m3/kg
(e) 313 K (f) 186.2 kJ/kg
8.55 55.81 m3
8.56 0.99875 m3/kg, 153 kJ/kg, 155 kJ/kg
8.57 (a) 0.035 kg/kg of dry air, 0.0564 kmol/kmol dry air, 30%
(b) 5.407 kPa, 34.4% (c) 310.7 K (d) 1.071 kJ/kg, 0.979 m3/kg, 150.3 kJ/kg
8.59 (a) 0.013 kg/kg of dry air, 0.0209 kmol/kmol dry air 1%
(b) 326 K, 308 K, 0.028 kg/kg dry air, 28%
8.60 0.007 kg
8.61 (a) 299.5 K (b) 0.004 kg
8.62 (a) 298 K (b) 5.55 kg
8.63 (a) 0.04 kg/kg of dry air (b) 313 K (c) 310 K (d) 70%
(e) 0.046 kg/kg of dry air, 318 K (f) 0.598 kg
8.64 (a) 0.01 kg/kg dry air (b) 40% (c) 370 K (d) 68.6 kJ
8.65 0.0085 kg, 41.3 kJ/kg
8.66 (a) 333 K (b) 298 K (c) 31.82 kJ (d) 27.6 kJ
8.67 (a) 0.0322, 50%, 283.2 K (b) 0.1206, 85%, 316.2 K (c) 6.07 kg
8.68 (a) 289 K (b) 0.01 kg/kg dry air (c) 0.004 kg
8.69 12056.6 kg/h
8.70 6643 m3/h
572 Answers to Exercises
8.71 (a) 44.9% (b) 18 912.3 m3/h
8.72 (a) 3604.6 m3/h (b) 3355.4 m3/h
8.73 (a) 305 K (b) 0.2489 kg (c) 8.76 m3/h
8.74 3.15 kg
8.75 (a) 0.017 kg/kg dry air, 58%, 295 K (b) 6782.5 kJ (c) 2.706 kg (d) 310 K
8.76 (a) 312 K, 323 K (b) 48% (c) 90.07 m3
8.77 (a) 0.028 and 0.096 kg/kg dry air (b) 45.45 kg/h (c) 147895 kJ/h
8.78 (a) 0.0175, 44%; 0.02, 100%; 0.02, 0.9%, 0.038, 45% (b) 2778 kg (c) 2686 m3
8.79 (a) 295.7 K, 300.7 K (b) 16.69 kg/h (c) 342.7 K
8.80 (a) 313.15 K, 318.65 K (b) 70% (c) 89.22 m3
8.81 (a) 318.65 K (b) 70%
8.82 (a) 311 K (b) 2.43 kg (c) 9.11 kg
Chapter 9
9.1 25 kg
9.2 3.457 kg
9.3 Urea 214.4 kg, Phosphoric acid 359 kg, KCl 411.5 kg
9.4 0.8F � 0.11P = 400; B � 0.675P = 0; 0.2F � 0.215P = 0; F = 573.3 kg, P = 533.3
kg,
B = 360 kg
9.5 6250
9.6 5625 kg
9.7 33.33 kg
9.8 Waste acid 419.18 kg; Con. HNO3 397.26 kg, Con. H2SO4, 183.56 kg
9.9 43.48 kg
9.10 Spent acid = 381.55 kg, Con. HNO3
=179.83 kg, Con. H2SO4
= 438.62 kg
9.11 0.0244 g/L
9.12 106.28 mol/h
9.13 (a) 530.95 kg/h
9.14 0.3184 m3
9.15 40%
9.16 8 : 3 : 9
9.17 1 : 10.64
9.18 Rs. 19.19
9.19 (a) Rs. 1 22 105 (b) Rs. 75 958
9.20 3.3322 � 104 kg/h
9.21 9.51 kg
Answers to Exercises 573
9.22 (a) 1.6349 � 10�3 m3 (b) 853 kg
9.23 (a) 2000 kg, 1200 kg (b) 2000 kg/h (c) 800 kg/h
9.24 (a) 25% NaOH (b) 60% NaOH, 2% NaCl, 38% H2O (c) 3500 kg
9.25 (a) NaCl 62.5%, Water 37.5%
9.26 (a) NaBr 2.68%, MgCl2
8.04% (b) NaCl 78.95%, NaBr 5.26%, MgCl2 15.79%
9.27 (a) 35200 kg (b) 4800 kg (c) 10000
9.28 10.526 kg/100 kg of water
9.29 299.7 K
9.30 (a) 17.5 kg (b) 18.61 kg
9.31 (a) 294.12 kg (b) 85.47 kg
9.32 (a) 251.26 kg (b) 10.3 kg
9.33 (a) 1857 kg of water, 368 kg of crystals (b) 399 kg of crystals
9.34 700 kg, 94.7%
9.35 (a) 3.58 m3 (b) 534 kg
9.36 Na2
SO4
5.2%, water 94.8%
9.37 Na2SO4 : Na2CO3 = 1 : 2
9.38 536.86 kg
9.39 (a) Na2SO4 = 27.96%, H2O = 72.04% (b) 0.0147 kg
9.40 30.2 kg crystals
9.41 30% Ca (NO3)
2
.
4H2O, 70% CuSO4
.
5H2O
9.42 211 kg
9.43 (a) 844 kg (b) 128.2 kg
9.44 (a) 6370 kg (b) 6630 kg
9.45 261.15 kg, 35 kg
9.46 70.01 kg
9.47 750.25 kg
9.48 10.1%
9.49 (a) 47.42 kg (b) 25.91 kg
9.50 (a) 32.5 kg (b) 2.5 kg (c) 30.77% A, 23.08% B, 46.15% H2O
9.51 (a) 7607.1 kg (b) 1085.7 kg
9.52 (a) 4567.47 kg (b) 4732.53 kg
9.53 (a) 332.74 kg (b) 16.48 kg MgSO4/100 kg of water
9.54 (a) 262.5 (b) 3863 kg (c) 3374.5 kg
9.55 (a) 607.95 kg (b) 130.85 kg
9.56 (a) 19.33 kg (b) 66.3%
574 Answers to Exercises
9.57 (a) 29.63 (b) 329.52 kg (c) 8487.14 kg (d) 102.86 kg
9.58 75%
9.59 93.1%
9.60 (a) 5.79% (b) 44.22% (c) 96.03%
9.61 (a) 588.24 kg (b) 420.59 kg
9.62 96.31%
9.63 96.91%
9.64 (a) 229.17 kg/h (b) 55%
9.65 (a) 1.105 kg of water per kg of dry leather
(b) 1.05 kg of water per kg of dry leather (c) 95.24%
9.66 (a) 42 kg (b) Pulp = 51.72%, Water = 48.28%
9.67 150 kg
9.68 0.4167 kg
9.69 (a) 125 kg, 102.04 kg (b) 97.22%, 2.55%
9.70 6250
9.71 (a) 17.74 kg/h (b) 97.99 m3
/h
9.72 (a) 313.15 K, 318.65 K (b) 70% (c) 89.22 m3
9.73 (a) 318.65 K (b) 70%
9.74 (a) 311 K (b) 2.43 kg (c) 9.11 kg
9.75 5279.5 kg of wet air/h
9.76 (a) 820 kg (b) 105.26 kg (c) 4024.16 kg
9.77 (a) 911.77 kg (b) 508 kg
9.78 (a) 37.1% acid, 62.9% water (b) 97.8 kg of raffinate, 149.2 kg of extract (c)
147 kg
9.79 30 kg, 70 kg
9.80 (a) 68.23 kg, 131.77 kg (b) 74.13%
9.81 50.82 g (upper layer), 49.18 g (lower layer)
9.82 (a) 166.93 kg, 133.62 kg (b) 31.72 kg
9.83 (a) 97.49 kg (upper) 101.91 kg (lower) (b) 1: 1.006
(c) S1 59.17%, S2
40.83%
9.84 82.05%
9.85 2.2383 � 10�2 kg
9.86 1.318 kg
9.87 36.11 kg
9.88 (a) 1373.93 m3 (b) N2
= 10.97%, CH4
= 89.03%
9.89 75%
9.90 (a) 7.58 kg (b) 986 mol/min (c) 3.41% (d) 21.3 m3/min
Answers to Exercises 575
9.91 (a) 74.89 kmol/h (b) 1286.9 m3/h (c) 5.88%
9.92 (a) 2916.37 kg (b) 75.25%
9.93 (a) 961.67 kg (b) 77.42%
9.94 (a) 157.73 kg (b) 1336.68 kg (c) 221.05 kg (d) 34.9 kg (e) 186.15 kg
9.95 (a) 903.06 kmol/h (b) Benzene: 0.554%, Toluene = 99.446%
9.96 (a) 40 kg (b) 4.44 weight % alcohol
9.97 (a) 37.5 kg (b) 0.6
9.98 462.48 kg
9.99 (a) Feed 44.02%, distillate 97.44%, residue 5.85%
(b) Distillate 41.67 mol, residue 58.33 mol
9.100 (a) 615.84 kg (b) B = 3.2%, T = 64.32%, X = 32.48%
9.101 (a) 7895 mol; 49.6% propane, 50.4% butane (b) 35.9 mol
9.102 247.8 kg
9.103 Overhead: Ethylene 7.79%, Ethane 11.68%, Propylene 19.46%, Propane 56.07%,
Isobutane 5.0%;
Bottoms: Propane 0.8%, Isobutane 31.91%, n-Butane 47.10%, n-Pentane 20.19%
9.104 (a) F = 40 kg/s, G = 60 kg/s, H = 20 kg/s
(b) Feed: B = 36.36%, C = 23.64%; D: B = 4.55%, C = 0.45%;
F: B = 86.35%, C = 8.64%
9.105 (a) 92.33% (b) 240.9 mol/s
9.106 0.1
9.107 55.56%
9.108 0.8333
9.109 0.1837
9.110 0.875
9.111 (a) 0.3591 (b) 4.22 kg (c) 129.9 m3
9.112 (a) 375 kg (b) 10% (c) 30%
9.113 (a) 100 000 kg/h (b) 6.75%
9.114 0.7093 kg/kg
9.115 (a) 26.56% (b) 6000 kg/h (c) 1816.24 kg/h
9.116 1263.04 kg
9.117 (a) 23.44 kg/h
9.118 (a) 1.2 (b) 46.51 (c) 0.973 kg
9.119 (a) 3571.43 kg (b) 58 204 kg
9.120 (a) 0.2 (b) 2.25 kg
9.121 (a) 404.21 m3 (b) 57.86 kg (c) 190.97 kg
576 Answers to Exercises
9.122 (a) Benzene 2%, toluene 55.34%, xylene 42.67%
(b) 2438.21 kg, 6768.62 kg (c) 96.92% (d) 9752.84 kg
9.123 (a) 7205.93 kg/h (b) 6195.52 kg/h (c) 93.66 kg/h (d) 6.05%
9.124 23 295.37 kg; 10.83% NaCl, 84.88% H2O, 4.29% KCl
9.125 0.6132
9.126 (a) 6.97% (b) 46.99 kg/h (c) 1.37%
9.127 (a) 926.32 kg/h (b) 74.42 kg (c) 37.21 kg
9.128 (a) 1:6 (b) 75.19 kg (c) 12.53 kg
9.129 (a) 2777.78 kg/h (b) 2109.88 kg/h (c) 17 400 kg/h
(d) M: 1932.1 kg/h pure NaCl; N: 667.90 kg/h, 89.83% KCl, 10.17% NaCl
(e) 22 109 kg/h, 10.85% NaCl, 2.71% KCl, 86.44% H2O
9.130 (a) 130.16 kg/h (b) 0.838 kg of dry air/kg of dry air in the fresh air feed
9.131 (a) 4.0953 kg/min (b) 52.21 kg/min (c) 45.44 m3/min (d) 358.34 kg/min
9.132 (a) 24.53% (b) 5142.8 kg/h (c) 2007.06 kg/h
9.133 (a) 315.8 kg/h (b) 105.26 kg/h (c) 894.74 kg/h
9.134 (a) 0.9067 (b) 6.9% A, 12.3% B, 6.3% C, 74.5% D
9.135 (a) 0.9 (b) 30% A, 43.33% B, 2.22% C, 24.45% D
(c) A = 13.33%, B = 10.00%, C = 5.00%, D = 71.67%
9.136 (a) 20% (b) 9.09%
9.137 20%
9.138 3.1
9.139 (a) 586.54 kg/h (b) 413.46 kg/h (c) 0.5551
9.140 0.6312
Chapter 10
10.1 49.1%
10.2 (a) 195.4 m3 (b) 36.036 kg
10.3 (a) 11.08% CO2, 83.35% N2, 5.57% H2O (b) 26.98 kg (c) 0.0836 bar
10.4 0.3374 ethene, 0.6626 ethane
10.5 (a) 1.900 kmol (b) 13.78% CO2, 4.59% CO, 4.25% O2, 77.38% N2
10.6 (a) Ethane: 0.21%, CO2 = 3.32%, CO = 0.41%, H2O = 5.6%,
O2 = 14.41% and N2 = 76.05%
(b) Ethane: 0.22%, CO2 = 3.51%, CO = 0.44%, O2 = 15.27% and N2 = 80.56%
10.7 CO2 = 12.34%, O2
= 5.97%, H2
O =13.41%, N2 = 68.28%
10.8 (a) CO2 = 9.97%, H2
O = 15.03%, N2 = 75.0% (b) 0.553 kg (c) 28.09 kg
10.9 (a) 6.93 m3 (b) 54.286 m3 (c) 20.45% CO2, 1.34% O2
, 78.21% N2
Answers to Exercises 577
10.10 (a) CO2 = 6.61%, O2 = 6.45%, N2 = 71.88%, H2O = 15.06%
(b) 2784.93 m3 (c) 327.56 K
10.11 (a) 6216 m3/h (b) 10.96% CO2, 0.61% CO, 85.69% N2 and 2.74% O2
(c) 17 138 m3/h
10.12 (a) CO 1.71%, CO2 17.5%, O2 2.19%, N2 78.6% (b) 177.29 kg
10.13 (a) CO2 9.83%, CO 0.52%, O2 6.57%, N2 83.08%
10.14 25%
10.15 (a) 25.0% (b) C : H = 1 : 0.338
10.16 (a) Methane = 50.0%, N2 = 50.0% (b) 7.73%
10.17 (a) 33.33% (b) 8
10.18 (a) 60.14% CH4, 39.86% C2H6 (b) 39.94%
10.19 (a) 19.71% (b) 0.374 (c) 13.72 m3
10.20 (a) 12.19% (b) 60.81% (c) 12.3304 mol (d) 1767.14 m3
10.21 (a) 405 (b) 3:1, C2H6 (c) 18.72 m3
10.22 (a) 1:7.5 (b) 22.69 kg (c) 0.812 kmol
10.23 37.0%
10.24 (a) 2.67:1, C3H8 (b) 85:1 (c) 77.81 m3/min
10.25 (a) 10% (b) C4H10 (c) 5716.7 m3 (d) 3812.8 kg/h
10.26 24.2%
10.27 79.36%
10.28 (a) 12.44% (b) 1:0.2778 (c) 15.66 m3 (d) 1.94 kg
10.29 26.57%
10.30 (a) 16.24% (b) 1216.7 m3
10.31 (a) 0.811
10.32 94.23% C, 5.77% H2
10.33 (a) 2237.76 kg (b) CO2 = 8.76%, H2O = 9.19%, O2 = 6.68%, N2 = 75.37%
(c) 28.76
10.34 319.08 K
10.35 19.9%
10.36 (a) 251.61 kg (b) 1.056 (c) 2.28 kmol (d) 34.7%
10.37 (a) 24.6% (b) 37.62 kmol
10.38 CO2 = 11.33%, SO2 = 0.33%, CO = 2.12%, O2 = 3.38%, H2
O = 6.49%, N2
= 76.35%
10.39 75.3%
10.40 (a) 2.188 kg (b) 4.6% (c) 14.26 kg
10.41 (a) 6.67 kg (b) 0.834%
10.42 (a) 63.42% (b) 41.71 m3 (c) 13.54 m3
578 Answers to Exercises
10.43 (a) 16.61% (b) 11.41 kg (c) 16.4517 m3 (d) 22.08% C, 77.92% inerts
10.44 (a) 1190.53 kg (b) 43.02 kmol/h
(c) CO2 13.08%, CO 1.44%, H2O 6.60%, O2 4.03%, SO2 0.09%, N2 74.76%
10.45 50%
10.46 (a) 8.92 kmol (b) 47.29% (c) 381.93 m3
10.47 (a) 196.154 kmol (b) 170.57 kmol (c) 1.75%
10.48 (a) 1231.824 kg (b) 11.17%
10.49 (a) 3.72% (b) 40% (c) 10.87 m3
10.50 3.88%, 5.12%
10.51 (a) 50.2% (b) 1362.6 kg (c) 52.91 kg (d) 1085.06 m3
10.52 (a) 2.572 kg (b) 1458.6 kg (c) 1197.8 m3 (d) 3.897%
(e) C: 73.8%, H: 5.129%, O: 9.771, S: 1.1, Ash: 10.2%
10.53 (a) 27.14% (b) CO2 7.71%, CO 1.94%, N2 83.37%, O2
6.92% (c) 14.256 kPa
10.54 6.34% SO2, 1.59% SO3, 10.10% O2, 81.97% N2
10.55 2.0276 kg
10.56 2.7886 kg
10.57 (a) 80.789 kg, 2.24% FeS2, 54.11% Fe2O3, 18.09% ZnO, 6.99% SO3, 18.57% inerts
(b) 7.73%
10.58 89.35%
10.59 17.02%
10.60 312.8 m3
10.61 (a) 347 m3 (b) 70.0% (c) 864.04 m3
10.62 (a) 361.42 m3 (b) 77.0% (or 69.5% or 64.6%) (c) 892.84 m3
10.63 76.8%
10.64 (a) 60% (b) 14.23 m3 (c) 8.42 m3
10.65 0.2975
10.66 (a) 73.64 kg (b) 1.8501 kmol O2, 14.8371 kmol N2, 1.4511 kmol SO2
(c) 40.5% (d) 3.07%
10.67 67.6%
10.68 95.6%
10.69 (a) 604.29 kg (b) SO3 7.21%, SO2 8.65%, O2 10.90%, N2
73.24%
(c) 110.05 kg (d) SO3 7.01%, SO2
0.22%, O2 8.87%, N2 83.91%
(e) 71.57 kg
10.70 80.07%
10.71 (a) 957.08 kg (b) SO2 = 9.45%, O2
= 11.55%, N2 = 79.00%
(c) SO2 = 0.5%, SO3 = 9.4%, O2 = 7.39%, N2 = 82.71%
10.72 (a) 6.043 kg (b) SO2 9.13%, SO3 7.66%, N2 73.01%, O2 10.20%
(c) 117.24 kg (d) 87.84%
Answers to Exercises 579
10.73 (a) 1.2465 kmol (b) 8.8% (c) 182.77 kg
10.74 (a) 1.32 � 105 kg (b) 2.64 � 104 kg
10.75 (a) 9.70% (b) 197.5 kg (c) 95.95 (d) 507.84 kg/h
(e) 0.32% SO2, 10.30% O2, 89.38% N2
10.76 (a) 523.81 kg (b) 0.4334 kg (c) 1765 kg
10.77 (a) CaCO3 60.31%, MgCO3 35.13%, inerts 4.56% (b) 9.12% (c) 43.93 kg
10.78 CaCO3 70%
10.79 (a) 65% CaCO3, 30% MgCO3, 5% inerts
(b) 7.97 kmol (c) 86.2 kg (d) 8.54%
10.80 (a) 40% (b) Air/Fuel: 15.35:1 (c) 99.55 kg (d) 94.73 kg
10.81 (a) Phosphate:sand:charcoal = 1:0.663:0.288 (b) 6.04 kg
10.82 (a) 3.36% (b) 49.886%
10.83 (a) 114.15 kg (b) 718.44 kg (c) 72%
10.84 51.58 kg
10.85 (a) 185.08 kg
(b) CaSO4 = 70.35%, H2SO4 = 15.11%, HF = 1.03%, inerts = 13.51%
10.86 298.3 kg
10.87 (a) 13.16% (b) 91.52% (c) 595.62 kg; Al2O3 16.05%, impurities 83.95%
10.88 (a) NO 2%, N2 78%, O2 20% (b) 0.7 kPa 0.68 kPa (c) 29.49 kg
10.89 (a) 131.84 kg (b) Na2SO4 63.38%, H2SO4 34%, H2O 1.5%, HNO3 1.12%
(c) 107.91 kg (d) 72.35 kg, 3.42 kg
10.90 30%
10.91 (a) 1244.27 m3 (b) 300.04 kg
10.92 (a) 1142.86 m3
(b) 51.34 kmol; 1.19% NH3, 10.58% O2, 71.42% N2, 6.72% NO, 10.09% H2O
(c) 49.79 kmol, 1.22% NH3, 7.79% O2, 73.65% N2, 0.69% NO,
6.24% NO2, 10.4% H2O (d) 205.15 kg, 63.32%
10.93 (a) 276 mol (b) 0.7567 kg
10.94 2.8303 � 107 m3
/day
10.95 (a) 178.6 m3 (b) 297.24 m3 (c) 117.62 kg
(d) 9.15% HCl, 8% O2
, 18.3% Cl2, 64.55% N2
10.96 (a) 1.136 kg
(b) HCl = 18.78%, Cl2 = 27.38%, O2 = 6.18%, N2 = 40.70%, H2O = 6.96%
(c) 324.53 K
10.97 (a) 2020.29 kg of CCl4, 842.37 kg of S (b) 1660 kg of CC4, 644.42 kg of S
10.98 (a) CS2, 20.28% (b) 71.89% (c) 51.98 kg
10.99 (a) 1417.26 kmol, 1079.76 kmol (b) 44 477.92 kg, 44 477.92 kg
(c) HCl = 40.98%, Ethylene = 16.54%, O2 = 9.89%, N2 = 32.58%
580 Answers to Exercises
(d) HCl = 4.1%, Ethylene = 2.36%, O2 = 1.8%, N2 = 32.58%,
H2O = 9.11%, EDC = 50.05%
10.100 90.7%, 91.9%
10.101 (a) 97.49% (b) 94.55% (c) 1123.4 kg (d) 1255.77 kg
(e) HCl 603.07 kg, H2
O 266.18 kg
10.102 (a) 1:1.2313
(b) HCl 20.69%, Cl2 15.09%, O2 7.95%, N2 48.61%, H2O 7.67%
10.103 404
10.104 30 300 kg/h
10.105 (a) 4.98% CH3OH, 3.73% O2, 51.48% N2, 19.9% HCHO, 19.9% H2O
(b) 395.13 m3
10.106 (a) 30.1% (b) 4.54:1
10.107 (a) 42.04 kg (b) 81.15 kg (c) 0.67 kg/h
10.108 50%
10.109 (a) 5 mol (b) 50% (c) 86.5 mol (d) 72.57%
10.110 (a) 2710.71 kg (b) 2403.21 kg (c) 27.81:1
10.111 C2H4 23.08%, H2
O 64.23%, ether 0.13%, ethanol 2.31%, inerts 10.26%
10.112 Ethylene 50.72%, ethanol 2.4%, ether 0.13%, water 33.4%, inerts 13.35%
10.113 (a) 18.94 kg, 86.28 kg
(b) monosulphonate 7.58%, disulphonate 34.51%, H2SO4 51.34%, H2O 6.57%
10.114 (a) 3:11
(b) Mass%: ethanol 29.22%, acetaldehyde 9.31%, H2
O 3.81%, O2 10.83%, N2
46.82%;
Mol%: ethanol 20.69%, acetaldehyde 6.90%, H2O 6.90%, O2 11.03%, N2 54.48%
10.115 77.27%
10.116 (a) 294.46 kg, 91.46% (b) 0.49 (c) 108.9 kmol
10.117 (a) 4 kmol/h (b) 80% (c) 1 kmol/h
10.118 (a) 177.45 kg/h (b) 106.93 kg/h
10.119 (a) 1.66 kmol, 2.13 kmol (b) 314.86 kg/h (c) 28.21% (d) 37.24 m3
10.120 (a) 3001.6 kg (b) 100.8 kg (c) 3203.2 kg
10.121 S1 60 kmol/h C3H8
; S2 200 kmol/h C3
H8
; S3 140 kmol/h C3
H8
, 60 kmol/h C3
H6,
60 kmol/h H2; S4
60 kmol/h H2; S5 60 kmol/h C3
H6
; S6 140 kmol/h C3H8
10.122 (a) 300 (b) 1700
10.123 (a) 42.86 mol NH3 (b) 1:2.14
10.124 (a) 227.6 kmol/h to A, 190.6 kmol/h to B (b) 404.04 kmol/h
10.125 (a) 544 mol
(b) CO 31.27%, CH3
OH 4.82%, CH4 0.69%, H2O 0.69%, H2 62.53%
(c) 28 mol
Answers to Exercises 581
10.126 (a) 0.0079 (b) 48.4 mol (c) 97.0%
10.127 (a) 673.74 mol (b) 6.667 mol
(c) CO 20.38%, H2 76.17%, CH4 3.0% (d) 31.11 mol
10.128 (a) 1:5.71 (b) 24.13 kmol (c) 111.41 kg (d) 27.24 kg/h
10.129 (a) 860 kmol (b) 4 kmol (c) 9.43%
10.130 (a) 50.08 kmol (b) 5.87 kmol (c) 2.93 kmol
10.131 (a) 0.0157 (b) 0.2 mol Ar/3 mol N2-H2 (c) 382 mol
10.132 4 mol to 100 mol feed
10.133 (a) 130.92 mol (b) 42.71% H2, 57.29% CH4 (c) 127.17 mol
10.134 (a) 63.79 kmol (b) 95.69% (c) 6.18 kmol
Chapter 11
11.1 17.845 m, 25 kJ
11.2 13.86 kJ
11.3 89.55 kg, 878.51 N
11.4 30.6305 � 105 J
11.5 1.667 � 102 kJ
11.6 7.355 kJ, 61.29 W
11.7 (a) 14.715, 0 (b) 0, 14.715 (c) 0.035 K
11.8 16.8 W
11.9 123.46 m3
11.10 (a) 4.164 � 103
N (b) 1.3254 � 105 N/m2 (c) 2.082 � 103
J (d) 490.5 J
11.11 17.15 m/s
11.12 (a) 1 J (b) 147.15 J
11.13 2.156 � 105 J
11.14 20.39 m
11.15 3:1
11.16 1.146 � 104 kJ
11.17 6.073 � 104 J
11.18 (a) 183.94 kJ (b) 1839.4 kJ (c) 1655.46 kJ (d) 38.36 m/s (e) 1839.4 kJ
11.19 DU = 37.9 kJ/mol; DH = 41 kJ/mol
11.20 Ul
= � 0.9045 kJ/kg, Uv
= 282.11 kJ/kg, Hv
= 320.5 kJ/kg
11.21 58.4 � 104
J
11.22 420.1 kJ, 2214 kJ/kg, 2423.9 kJ/kg
11.23 (a) 3.572 kJ (b) 10.97 min
11.24 (a) 4122.2 J (b) CP = 8.85394 + 8.2744 � 10�3T � 3.4150 � 10�6T2
582 Answers to Exercises
11.25 (a) 41.2339 J/mol K (b) 39.6355 J/mol K (c) 79.27 kJ
11.26 (a) 50.0395 kJ/kmol K (b) 22.3251 � 104 kJ
11.27 (a) 440.22 kJ (b) 4.40 kJ/kg K
11.28 (a) 30.7324 kJ/kmol K (b) 30732.4 kJ/kmol
11.29 31.496 kJ/kmol K
11.30 (a) CP = 7.7844 + 0.1344T � 4.7696 � 10�5T2 (b) 46 237.6 J
11.31 4525.07 kJ
11.32 46.31 kJ/kmol K, 46 310 kJ/kmol
11.33 1.55 � 10�4 kJ
11.34 14 187 kJ/kmol
11.35 233.55 m3
/min
11.36 322.44 kJ
11.37 3105 kJ
11.38 2223.3 kJ/kg
11.39 4.184 � 102 kJ/kg
11.40 255.95 kJ/kg
11.41 397.7 kJ/kg
11.42 117 895 kJ/kmol, 112 582 kJ/kmol
11.43 8918.5 kJ/kg
11.44 (a) 482 624 kJ/h (b) 178 831 kJ/h
11.45 (a) 181.97 kPa (b) 444.94 kJ/kg
11.46 (a) 125.44 kJ/kg (b) 2622.14 kJ/kg
11.47 (a) 40 kPa (b) 223 kPa (c) 19 699 kJ
11.48 18 467 kJ
11.49 995.96 kJ/kg water
11.50 195 814 kJ
11.51 1.246 � 106 kJ
11.52 914.86 kJ, 139.35 kJ
11.53 389.8 K
11.54 2.6% liquid
11.55 0.9948 kg/s
11.56 6.877 � 105 kJ
11.57 759 K
11.58 (a) 11 987.5 kJ (b) 272.4 K
11.59 442.224 kJ
Answers to Exercises 583
11.60 (a) 60 522 kJ (b) 140.3�C
11.61 T = 305.8 K
11.62 62 187.5 kJ
11.63 9.661 � 106 kJ
11.64 250.77 J/kg
11.65 340.62 K
11.66 � 10.217 kJ/mol
11.67 178 873 kJ
11.68 5100 kJ removed
11.69 1.2914 � 109 kJ/h
11.70 2328.7 kJ
11.71 21 783 kJ
11.72 (a) �1514.6 J/mol (b) 0 (c) 4.31 bar (d) 25.12 mol
11.73 (a) � 24.0685 kJ (b) � 17.695 kJ (c) 6.374 kJ
11.74 (a) 250 kJ (b) 173.3 kJ
11.75 (a) 981 J (b) 981 J (c) 0.234 K
11.76 6.92 � 105
J
11.77 25 kJ, 75 kJ, � 100 kJ, 100 kJ
11.78 (a) 14 m/s (b) 0.78 K
11.79 (a) 22 480 kJ (b) 8730 kJ
11.80 166.67 kJ
11.81 � 895 879.7 kJ
11.82 (a) 1.48 � 104
kg (b) 3.022 � 10�4 (c) 50 h
11.83 2168.6 kJ, 3000 kJ, � 125.32 kJ, 2043.28 kJ
11.84 391.4 K, 1.96 Pa
11.85 1243.6 kJ, 1742.4 kJ
11.86 407.18 kJ
11.87 (a) 2282 kJ (b) 2206 kJ (c) 0
11.88 (a) 472.5 kJ (b) � 4863 kJ (c) 0 (d) 4863 kJ (e) 5981 kJ
11.89 (a) 997.68, 1662.8, � 997.68 kJ/kmol (b) � 997.68, � 1662.8, � 665.12 kJ/kmol
(c) 0, 0, 1490, 1490 kJ/kmol (d) 0, 0, � 172.8, � 172.8 kJ/kmol
11.90 � 2329, � 3252, 3395, 1066 kJ/kmol
11.91 (a) 1 bar, 56 K, 4656, 6518, 0, 4656 kJ
(b) 5 bar, 1400 K, 22 380.3, 32 592.0, 0, 22 380.3 kJ
11.92 (a) 0.373 kg (b) 0.304 kg
11.93 418.5 K, 7.65 bar
584 Answers to Exercises
11.94 (a) 2 bar, 4605 kJ (b) 132.9 K, 0.443 bar, 2376 kJ (c) 900 kJ
11.95 70 kJ
11.96 313.46 hp
11.97 722.51 kJ/h
11.98 435.5 hp
11.99 92.9 hp
11.100 144.1 kJ/h
11.101 (a) Q = 3122 kJ/kg, Ws = 0, DH = 3122 kJ/kg
(b) Q = 0, Ws = 588.34 kJ/kg, DH = � 588.34 kJ/kg
11.102 1744 hp
11.103 35 kJ
11.104 (a) 402.64 m/s (b) 5.751 � 10�4 m2
11.105 344 K
11.106 (a) 46.88 J/kg (b) 50 J/kg
11.107 15.35 hp
11.108 2453 kJ/kg
11.109 2.03 hp
11.110 1.72 K
11.111 30.523 kW
11.112 2.95 � 105 N/m2, 1481.3 W
11.113 4.316 kW, 86.22 kPa, 966 kPa
11.114 81.51 kW
11.115 567 K
11.116 (a) 6259 kg/h (b) 378 kg/h
11.117 0.86 hp
11.118 82.785 kPa
11.119 (a) 5725.2 kWh/day (b) 1.099 m
11.120 122 155 kg/h, 7759 kg/h
11.121 3.174 � 106 kJ/h
11.122 35 kg
11.123 (a) 9.4313 � 105 kJ/h (b) 12.3470 � 105 kJ/h
11.124 (a) 2976.1 kg/h (b) 1.94 � 105 kJ/h
11.125 178 354 kJ/h
11.126 214 030 kJ/h, 17.26 kg
11.127 1 029 025 kJ
11.128 3314.8 kJ
Answers to Exercises 585
Chapter 12
12.1 � 1207.43 kJ
12.2 � 194.9 kJ/mol
12.3 � 323.53 kJ/kmol
12.4 � 81.46 kJ
12.5 � 102.933 kJ/mol
12.6 � 110.52 kJ/mol
12.7 � 74.79 kJ
12.8 � 110.52 kJ/mol
12.9 (a) 240 kg/h (b) 95.71 kmol/h
12.10 49.819 � 103
kJ/m3 and 45.224 � 103 kJ/m3
at STP
12.11 greater by � 142.216 kJ
12.12 �114.408 kJ
12.13 � 904.7 kJ/mol
12.14 � 1654.27 kJ/mol
12.15 � 241.83 kJ/mol
12.16 � 2204.14 kJ/mol
12.17 49.02 kJ/mol
12.18 1.16 kJ/mol
12.19 117.715 kJ/mol
12.20 � 110.52 kJ/mol
12.21 � 199.5 kJ/mol
12.22 � 5.608 � 103 kJ/kg
12.23 � 177.0 kJ
12.24 � 286.46 kJ
12.25 5.7 K
12.26 � 183.950 kJ
12.27 �185.342 kJ/mol
12.28 � 42.62 kJ/mol
12.29 23 178 kJ/kg methane
12.30 328 299.8 kJ/kmol CH4
12.31 � 393.83 kJ/mol
12.32 155.509 kJ/mol
12.33 � 886.83 kJ/mol
12.34 � 224.5 kJ
586 Answers to Exercises
12.35 2.072 � 105
12.36 � 132.385 � 103
kJ/h
12.37 32 525.5 kJ/kmol acid
12.38 19 662.7 kJ
12.39 � 377.45 kJ/mol
12.40 617.88 kJ
12.41 � 3283.43 kJ/mol
12.42 70.35 � 103
kJ
12.43 5641.26 kJ
12.44 � 191.88 � 103 kJ/kmol
12.45 28 098 kJ
12.46 320.97 kJ
12.47 (a) 9.298 kg/h (b) 297.04 m3/h (c) 548 865 kJ/h
12.48 1 805 449 kJ/h
12.49 1308 K
12.50 2285.3 K
12.51 82%
12.52 387.1 K
12.53 854 K
12.54 1215 K
12.55 1914.7 K
12.56 400 K
12.57 857 K
12.58 2237 K
Index
587
Absolute humidity, 208
Absolute pressure, 22
Absorption, 9, 279
Acentric factor, 115, 117�18
Adiabatic
cooling curves, 227
flame temperature, 493
humidification, 226
process, 442�43
reaction temperature, 493
saturation chamber, 226
saturation temperature, 225�27
Adsorbate, 273
Adsorbent, 273
Adsorption, 10, 87, 273
isotherm, 273
Amagat�s law, 83
American Institute of Chemical Engineers, 1, 4
Antoine
constants, 136
equation, 135, 136
API scale, 47
Atom, 40
Atomic heat capacities, 418�19
of elements, 418
values for use in Kopp�s rule, 419
Atomic weight, 40
Avogadro number, 41
Avogadro�s principle (hypothesis, law), 77, 91
Basic material balance