Safety Data Sheet

Shell Corena S4 R 46

Version 1.1 Revision Date 2015/12/31 Print Date 2016/05/02

1. IDENTIFICATION OF THE HAZARDOUS CHEMICALS AND OF THE SUPPLIER

Product name : Shell Corena S4 R 46

Product code : 001D7786

Manufacturer or supplier's details

Supplier : Shell Malaysia Trading Sdn Bhd
(6087-M)
Menara Shell
No. 211 Jalan Tun Sambanthan
50470 Kuala Lumpur
Malaysia
Telephone : (+60) 3 2385 2888
Telefax :

Emergency telephone : 1 800 88 3899

number
Email Contact for Safety : If you have any enquiries about the content of this SDS
Data Sheet please email [email protected]

Recommended use of the chemical and restrictions on use

Recommended use : Compressor oil.

2. HAZARDS IDENTIFICATION

GHS Classification
Not a dangerous substance or mixture according to the Globally Harmonised System (GHS).

GHS Label element

Hazard pictograms : No Hazard Symbol required

Signal word : No signal word

Hazard statements : PHYSICAL HAZARDS:

Not classified as a physical hazard under GHS criteria.
HEALTH HAZARDS:
Not classified as a health hazard under GHS criteria.
ENVIRONMENTAL HAZARDS:
Not classified as an environmental hazard under GHS criteria.

Precautionary statements :
Prevention:
No precautionary phrases.

Response:
No precautionary phrases.

Storage:
No precautionary phrases.

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Disposal:
No precautionary phrases.

Sensitising components : Contains dialkyl thiophosphate ester.

May produce an allergic reaction.

Other hazards which do not result in classification

Prolonged or repeated skin contact without proper cleaning can clog the pores of the skin
resulting in disorders such as oil acne/folliculitis.Used oil may contain harmful impurities.Not
classified as flammable but will burn.

3. COMPOSITION AND INFORMATION OF THE INGREDIENTS OF THE HAZARDOUS CHEMICAL

Chemical nature : Blend of polyolefins and additives.

Hazardous components

Chemical Name CAS-No. Classification Concentration [%]

Alkaryl amine 68411-46-1 Aquatic Chronic3; H412 1- 3
Dialkyl thiophosphate ester 268567-32-4 Eye Dam.1; H318 0.1 - 0.9
Aquatic Chronic3; H412
Skin Sens.1; H317
For explanation of abbreviations see section 16.

4. FIRST-AID MEASURES

General advice : Not expected to be a health hazard when used under normal
conditions.

If inhaled : No treatment necessary under normal conditions of use.

If symptoms persist, obtain medical advice.

In case of skin contact : Remove contaminated clothing. Flush exposed area with
water and follow by washing with soap if available.
If persistent irritation occurs, obtain medical attention.

In case of eye contact : Flush eye with copious quantities of water.

If persistent irritation occurs, obtain medical attention.

If swallowed : In general no treatment is necessary unless large quantities

are swallowed, however, get medical advice.

Most important symptoms : Oil acne/folliculitis signs and symptoms may include formation
and effects, both acute and of black pustules and spots on the skin of exposed areas.
delayed Ingestion may result in nausea, vomiting and/or diarrhoea.

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Protection of first-aiders : When administering first aid, ensure that you are wearing the
appropriate personal protective equipment according to the
incident, injury and surroundings.

Notes to physician : Treat symptomatically.

5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Foam, water spray or fog. Dry chemical powder, carbon
dioxide, sand or earth may be used for small fires only.

Unsuitable extinguishing : Do not use water in a jet.

media

Specific hazards during : Hazardous combustion products may include:

firefighting A complex mixture of airborne solid and liquid particulates and
gases (smoke).
Carbon monoxide may be evolved if incomplete combustion
occurs.
Unidentified organic and inorganic compounds.

Specific extinguishing : Use extinguishing measures that are appropriate to local

methods circumstances and the surrounding environment.

Special protective equipment : Proper protective equipment including chemical resistant

for firefighters gloves are to be worn; chemical resistant suit is indicated if
large contact with spilled product is expected. Self-Contained
Breathing Apparatus must be worn when approaching a fire in
a confined space. Select fire fighter's clothing approved to
relevant Standards (e.g. Europe: EN469).

Hazchem Code : NONE/TIADA

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, : Avoid contact with skin and eyes.

protective equipment and
emergency procedures
Environmental precautions : Use appropriate containment to avoid environmental
contamination. Prevent from spreading or entering drains,
ditches or rivers by using sand, earth, or other appropriate
barriers.

Local authorities should be advised if significant spillages

cannot be contained.

Methods and materials for : Slippery when spilt. Avoid accidents, clean up immediately.
containment and cleaning up Prevent from spreading by making a barrier with sand, earth
or other containment material.
Reclaim liquid directly or in an absorbent.
Soak up residue with an absorbent such as clay, sand or other

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suitable material and dispose of properly.

Additional advice : For guidance on selection of personal protective equipment

see Chapter 8 of this Safety Data Sheet.
For guidance on disposal of spilled material see Chapter 13 of
this Safety Data Sheet.

7. HANDLING AND STORAGE

Handling
General Precautions : Use local exhaust ventilation if there is risk of inhalation of
vapours, mists or aerosols.
Use the information in this data sheet as input to a risk
assessment of local circumstances to help determine
appropriate controls for safe handling, storage and disposal of
this material.

Advice on safe handling : Avoid prolonged or repeated contact with skin.

Avoid inhaling vapour and/or mists.
When handling product in drums, safety footwear should be
worn and proper handling equipment should be used.
Properly dispose of any contaminated rags or cleaning
materials in order to prevent fires.

Avoidance of contact : Strong oxidising agents.

Product Transfer : This material has the potential to be a static accumulator.

Proper grounding and bonding procedures should be used
during all bulk transfer operations.

Storage
Other data : Keep container tightly closed and in a cool, well-ventilated
place.
Use properly labeled and closable containers.

Store at ambient temperature.

Packaging material : Suitable material: For containers or container linings, use mild
steel or high density polyethylene.
Unsuitable material: PVC.

Container Advice : Polyethylene containers should not be exposed to high

temperatures because of possible risk of distortion.

8. EXPOSURE CONTROLS AND PERSONAL PROTECTION

Components with workplace control parameters

Components CAS-No. Value type Control Basis
(Form of parameters /

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exposure) Permissible
concentration
Oil mist, mineral Not Assigned TWA 5 mg/m3 US. ACGIH
((inhalable Threshold
fraction)) Limit Values
Oil mist, mineral Not Assigned TWA (Mist) 5 mg/m3 Malaysia.
Occupational
Safety and
Health (Use
and
Standards of
Exposure of
Chemicals
Hazardous to
Health)
Regulations
2000.
Biological occupational exposure limits
No biological limit allocated.

Monitoring Methods
Monitoring of the concentration of substances in the breathing zone of workers or in the general
workplace may be required to confirm compliance with an OEL and adequacy of exposure
controls. For some substances biological monitoring may also be appropriate.
Validated exposure measurement methods should be applied by a competent person and
samples analysed by an accredited laboratory.
Examples of sources of recommended exposure measurement methods are given below or
contact the supplier. Further national methods may be available.
National Institute of Occupational Safety and Health (NIOSH), USA: Manual of Analytical Methods
http://www.cdc.gov/niosh/
Occupational Safety and Health Administration (OSHA), USA: Sampling and Analytical Methods
http://www.osha.gov/
Health and Safety Executive (HSE), UK: Methods for the Determination of Hazardous Substances
http://www.hse.gov.uk/
Institut für Arbeitsschutz Deutschen Gesetzlichen Unfallversicherung (IFA) , Germany
http://www.dguv.de/inhalt/index.jsp
L'Institut National de Recherche et de Securité, (INRS), France http://www.inrs.fr/accueil

Engineering measures : The level of protection and types of controls necessary will
vary depending upon potential exposure conditions. Select
controls based on a risk assessment of local circumstances.
Appropriate measures include:
Adequate ventilation to control airborne concentrations.

Where material is heated, sprayed or mist formed, there is

greater potential for airborne concentrations to be generated.

General Information:
Define procedures for safe handling and maintenance of
controls.
Educate and train workers in the hazards and control
measures relevant to normal activities associated with this
product.

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Ensure appropriate selection, testing and maintenance of
equipment used to control exposure, e.g. personal protective
equipment, local exhaust ventilation.
Drain down system prior to equipment break-in or
maintenance.
Retain drain downs in sealed storage pending disposal or
subsequent recycle.
Always observe good personal hygiene measures, such as
washing hands after handling the material and before eating,
drinking, and/or smoking. Routinely wash work clothing and
protective equipment to remove contaminants. Discard
contaminated clothing and footwear that cannot be cleaned.
Practice good housekeeping.

Personal protective equipment

Protective measures
Personal protective equipment (PPE) should meet recommended national standards. Check with
PPE suppliers.

Respiratory protection : No respiratory protection is ordinarily required under normal

conditions of use.
In accordance with good industrial hygiene practices,
precautions should be taken to avoid breathing of material.
If engineering controls do not maintain airborne
concentrations to a level which is adequate to protect worker
health, select respiratory protection equipment suitable for the
specific conditions of use and meeting relevant legislation.
Check with respiratory protective equipment suppliers.
Where air-filtering respirators are suitable, select an
appropriate combination of mask and filter.
Select a filter suitable for the combination of organic gases
and vapours [Type A/Type P boiling point >65°C (149°F)].

Hand protection
Remarks : Where hand contact with the product may occur the use of
gloves approved to relevant standards (e.g. Europe: EN374,
US: F739) made from the following materials may provide
suitable chemical protection. PVC, neoprene or nitrile rubber
gloves Suitability and durability of a glove is dependent on
usage, e.g. frequency and duration of contact, chemical
resistance of glove material, dexterity. Always seek advice
from glove suppliers. Contaminated gloves should be
replaced. Personal hygiene is a key element of effective hand
care. Gloves must only be worn on clean hands. After using
gloves, hands should be washed and dried thoroughly.
Application of a non-perfumed moisturizer is recommended.

For continuous contact we recommend gloves with

breakthrough time of more than 240 minutes with preference
for > 480 minutes where suitable gloves can be identified. For
short-term/splash protection we recommend the same, but
recognize that suitable gloves offering this level of protection
may not be available and in this case a lower breakthrough

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time maybe acceptable so long as appropriate maintenance
and replacement regimes are followed. Glove thickness is not
a good predictor of glove resistance to a chemical as it is
dependent on the exact composition of the glove material.
Glove thickness should be typically greater than 0.35 mm
depending on the glove make and model.

Eye protection : If material is handled such that it could be splashed into eyes,
protective eyewear is recommended.

Skin and body protection : Skin protection is not ordinarily required beyond standard
work clothes.
It is good practice to wear chemical resistant gloves.

Thermal hazards : Not applicable

Environmental exposure controls

General advice : Take appropriate measures to fulfill the requirements of
relevant environmental protection legislation. Avoid
contamination of the environment by following advice given in
Chapter 6. If necessary, prevent undissolved material from
being discharged to waste water. Waste water should be
treated in a municipal or industrial waste water treatment plant
before discharge to surface water.
Local guidelines on emission limits for volatile substances
must be observed for the discharge of exhaust air containing
vapour.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : Liquid at room temperature.

Colour : light brown

Odour : Slight hydrocarbon
Odour Threshold : Data not available
pH : Not applicable
pour point : -45 °C / -49 °FMethod: ASTM D97

Initial boiling point and boiling : > 280 °C / 536 °Festimated value(s)
range
Flash point : 230 °C / 446 °F
Method: ASTM D92

Evaporation rate : Data not available

Flammability (solid, gas) : Data not available

Upper explosion limit : Typical 10 %(V)

Lower explosion limit : Typical 1 %(V)

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Vapour pressure : < 0.5 Pa (20 °C / 68 °F)

estimated value(s)
Relative vapour density : > 1estimated value(s)
Relative density : 0.843 (15 °C / 59 °F)

Density : 843 kg/m3 (15.0 °C / 59.0 °F)

Method: ASTM D1298

Solubility(ies)
Water solubility : negligible
Solubility in other solvents : Data not available

Partition coefficient: n- : Pow: > 6(based on information on similar products)

octanol/water
Auto-ignition temperature : > 320 °C / 608 °F

Viscosity
Viscosity, dynamic : Data not available
Viscosity, kinematic : 46 mm2/s (40.0 °C / 104.0 °F)
Method: ASTM D445

7.7 mm2/s (100 °C / 212 °F)

Method: ASTM D445

Explosive properties : Not classified

Oxidizing properties : Data not available

Conductivity : This material is not expected to be a static accumulator.

Decomposition temperature : Data not available

10. STABILITY AND REACTIVITY

Reactivity : The product does not pose any further reactivity hazards in
addition to those listed in the following sub-paragraph.

Chemical stability : Stable.

Possibility of hazardous : Reacts with strong oxidising agents.

reactions
Conditions to avoid : Extremes of temperature and direct sunlight.

Incompatible materials : Strong oxidising agents.

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Hazardous decomposition : Hazardous decomposition products are not expected to form

products during normal storage.

11. TOXICOLOGICAL INFORMATION

Basis for assessment : Information given is based on data on the components and
the toxicology of similar products.Unless indicated otherwise,
the data presented is representative of the product as a
whole, rather than for individual component(s).

Symptoms of Overexposure : Oil acne/folliculitis signs and symptoms may include formation
of black pustules and spots on the skin of exposed areas.
Ingestion may result in nausea, vomiting and/or diarrhoea.
Information on likely routes of : Skin and eye contact are the primary routes of exposure
exposure although exposure may occur following accidental ingestion.

Acute toxicity
Product:
Acute oral toxicity : LD50 rat: > 5,000 mg/kg
Remarks: Expected to be of low toxicity:

Acute inhalation toxicity : Remarks: Not considered to be an inhalation hazard under

normal conditions of use.

Acute dermal toxicity : LD50 Rabbit: > 5,000 mg/kg

Remarks: Expected to be of low toxicity:

Skin corrosion/irritation
Product:
Remarks: Expected to be slightly irritating., Prolonged or repeated skin contact without proper
cleaning can clog the pores of the skin resulting in disorders such as oil acne/folliculitis.

Serious eye damage/eye irritation

Product:
Remarks: Expected to be slightly irritating.

Respiratory or skin sensitisation

Product:
Remarks: Not expected to be a skin sensitiser.

Components:
Dialkyl thiophosphate ester:
Remarks: May cause an allergic skin reaction in sensitive individuals.

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Germ cell mutagenicity
Product:
: Remarks: Not considered a mutagenic hazard.
Carcinogenicity
Product:

Remarks: Not expected to be carcinogenic.

Material GHS/CLP Carcinogenicity Classification

Highly refined mineral oil No carcinogenicity classification.

Reproductive toxicity

Product:
:
Remarks: Not expected to impair fertility., Not expected to be
a developmental toxicant.

STOT - single exposure

Product:
Remarks: Not expected to be a hazard.

STOT - repeated exposure

Product:
Remarks: Not expected to be a hazard.

Aspiration toxicity
Product:
Not considered an aspiration hazard.

Further information
Product:
Remarks: Used oils may contain harmful impurities that have accumulated during use. The
concentration of such impurities will depend on use and they may present risks to health and the
environment on disposal., ALL used oil should be handled with caution and skin contact avoided
as far as possible.

Remarks: Slightly irritating to respiratory system.

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12. ECOLOGICAL INFORMATION

Basis for assessment : Ecotoxicological data have not been determined specifically
for this product.
Information given is based on a knowledge of the components
and the ecotoxicology of similar products.
Unless indicated otherwise, the data presented is
representative of the product as a whole, rather than for
individual component(s).(LL/EL/IL50 expressed as the
nominal amount of product required to prepare aqueous test
extract).

Ecotoxicity
Product:
Toxicity to fish (Acute :
toxicity) Remarks: Expected to be practically non toxic:
LL/EL/IL50 > 100 mg/l

Toxicity to crustacean (Acute :

toxicity) Remarks: Expected to be practically non toxic:
LL/EL/IL50 > 100 mg/l

Toxicity to algae/aquatic :
plants (Acute toxicity) Remarks: Expected to be practically non toxic:
LL/EL/IL50 > 100 mg/l

Toxicity to fish (Chronic : Remarks: Data not available

toxicity)
Toxicity to crustacean : Remarks: Data not available
(Chronic toxicity)
Toxicity to microorganisms : Remarks: Data not available
(Acute toxicity)

Persistence and degradability

Product:
Biodegradability : Remarks: Expected to be not readily biodegradable., Major
constituents are expected to be inherently biodegradable, but
contains components that may persist in the environment.

Bioaccumulative potential
Product:
Bioaccumulation : Remarks: Contains components with the potential to
bioaccumulate.

Partition coefficient: n- : Pow: > 6Remarks: (based on information on similar products)

octanol/water
Mobility in soil
Product:
Mobility : Remarks: Liquid under most environmental conditions., If it
enters soil, it will adsorb to soil particles and will not be
mobile.

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Remarks: Floats on water.
Other adverse effects
no data available
Product:
Additional ecological : Product is a mixture of non-volatile components, which are not
information expected to be released to air in any significant quantities.,
Not expected to have ozone depletion potential,
photochemical ozone creation potential or global warming
potential.
Poorly soluble mixture., May cause physical fouling of aquatic
organisms.

13 DISPOSAL INFORMATION

Disposal methods
Waste from residues : Waste product should not be allowed to contaminate soil or
ground water, or be disposed of into the environment.
Waste, spills or used product is dangerous waste.

Disposal should be in accordance with applicable regional,

national, and local laws and regulations.
Local regulations may be more stringent than regional or
national requirements and must be complied with.

Contaminated packaging : Dispose in accordance with prevailing regulations, preferably

to a recognized collector or contractor. The competence of
the collector or contractor should be established beforehand.
Disposal should be in accordance with applicable regional,
national, and local laws and regulations.

14. TRANSPORTATION INFORMATION

National Regulations
Hazchem Code : NONE/TIADA
International Regulation
ADR
Not regulated as a dangerous good
IATA-DGR
Not regulated as a dangerous good
IMDG-Code
Not regulated as a dangerous good
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Pollution category : Not applicable
Ship type : Not applicable

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Product name : Not applicable
Special precautions : Not applicable
Special precautions for user
Remarks : Special Precautions: Refer to Chapter 7, Handling & Storage,
for special precautions which a user needs to be aware of or
needs to comply with in connection with transport.

Additional Information : MARPOL Annex 1 rules apply for bulk shipments by sea.

15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or

mixture
Occupational Safety and Health (Classification, Labelling and Safety Data Sheet of Hazardous
Chemicals) Regulations 2013. Occupational Safety and Health (Use and Standards of Exposure
of Chemicals Hazardous to Health) Regulations 2000.
OSHA 1994 and relevant regulations.
Factories and Machinery Act 1967 and relevant regulations.
Petroleum (Safety Measures) Act 1984.
Environmental Quality Act 1974 and regulation.
Motor Vehicles (Construction and Use) (Vehicles Carrying Petroleum Products) Rules, 1965-
L.N.405/65 under Road Transport Act 1987.
Motor Vehicles (Construction, Equipment and Use) (Use Of Liquefied Petroleum Gas Fuel
System in Motor Vehicles) Rules 1982 – P.U. (A) 392/82 under Road Transport Act, 1987.

Other international regulations

The components of this product are reported in the following inventories:
EINECS : All components listed or polymer exempt.
TSCA : All components listed.

16. OTHER INFORMATION

Full text of H-Statements

H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H412 Harmful to aquatic life with long lasting effects.
Full text of other abbreviations
Aquatic Chronic Chronic aquatic toxicity
Eye Dam. Serious eye damage
Skin Sens. Skin sensitisation

Abbreviations and Acronyms : The standard abbreviations and acronyms used in this
document can be looked up in reference literature (e.g.
scientific dictionaries) and/or websites.

Further information

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Other information : A vertical bar (|) in the left margin indicates an amendment
from the previous version.

This information is based on our current knowledge and is intended to describe the product for
the purposes of health, safety and environmental requirements only. It should not therefore be
construed as guaranteeing any specific property of the product.

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