Safety Data Sheet (SDS / MSDS)

Ammonium Persulphate (NH4)2S2O8

Section 1: Chemical Product and Company Identification

Product Name: Ammonium Persulphate
CAS Number: 7727-54-0
UN Number: 56356
Synonym: Ammonium Peroxydisulfate, Ammonium Persulfate
Chemical Name: Ammonium Persulphate
Chemical Formula: (NH4)2S2O8
Company: Silverprint Ltd
Unit 26, Albany Park, Cabot Lane, Poole
BH17 7BX
Tel: +44 (0)1202 051180
Emergency: 9-17h: +44 (0)1202 051180
24 Hrs: 112

E-mail address: [email protected]

Section 2: Data Composition

Name: Ammonium Persulphate

Formula: (NH4)2S2O8
CAS Number: 7727-54-0
% By Weight: 100%

Toxicological Data on Compositions: Ammonium Persulphate LD50: Not available. LC50: Not available.
Section 3: Hazards Identification

Potential Acute Health Effects:

Hazardous in case of skin contact (irritant, sensitizer), of eye contact (irritant), of ingestion, of inhalation (lung
irritant, lung sensitizer). Prolonged exposure may result in skin burns and ulcerations. Over-exposure by
inhalation may cause respiratory irritation.

Potential Chronic Health Effects:

CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available. The substance is toxic to lungs, mucous membranes. Repeated or
prolonged exposure to the substance can produce target organs damage
Section 4: First Aid Measures
Eye Contact:

Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids
open. Cold water may be used. Do not use an eye ointment. Seek medical attention.

Skin Contact:

After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin with
running water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. Cold water may be
used.
Cover the irritated skin with an emollient. If irritation persists, seek medical attention.

Serious Skin Contact:

Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical attention.

Inhalation:

If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
medical attention.

Serious Inhalation:

Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If
breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek
medical attention.

Ingestion:

Do not induce vomiting. Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not breathing,
perform mouth-to-mouth resuscitation. Seek immediate medical attention.

Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: May be combustible at high temperature.

Auto-Ignition Temperature: Not applicable.

Flash Points: Higher than 93.3°C (200°F).

Flammable Limits: Not applicable.

Products of Combustion: Not available.

Fire Hazards in Presence of Various Substances: Slightly flammable to flammable in presence of open flames and sparks, of
heat, of reducing materials, of combustible materials.

Explosion Hazards in Presence of Various Substances: Risks of explosion of the product in presence of mechanical
impact: Not available. Risks of explosion of the product in presence of static discharge: Not available. Slightly explosive
in presence of reducing materials, of combustible materials, of organic materials, of metals.

Risks of explosion of the product in presence of mechanical impact: Not available.

Risks of explosion of the product in presence of static discharge: Not available.

Fire Fighting Media and Instructions: Oxidizing material. Do not use water jet. Use flooding quantities of water. Avoid
contact with organic materials.

Special Remarks on Fire Hazards: Not available. Special Remarks on Explosion Hazards: Not available.
Section 6: Accidental Release Measures
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.

Large Spill: Oxidizing material. Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil,
clothing etc). Keep substance damp using water spray. Do not touch spilled material. Prevent entry into sewers, basements
or confined areas; dyke if needed. Call for assistance on disposal.

Section 7: Handling and Storage

Precautions: Keep locked up Keep container dry. Keep away from heat. Keep away from sources of ignition. Keep away
from combustible material Keep away from direct sunlight or strong incandescent light. Do not breathe dust. Never add
water to this product. Avoid shock and friction. In case of insufficient ventilation, wear suitable respiratory equipment If
you feel unwell, seek medical attention and show the label when possible. Avoid contact with skin and eyes

Storage: Strong Oxidiser. Moisture Sensitive. Keep container tightly closed. Keep container in a cool, well-ventilated area.
Separate from acids, alkalis, reducing agents and combustibles. Do not store above 23°C (73.4°F).

Section 8: Exposure Controls and Personal Protection

Engineering Controls:

Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below
recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne
contaminants below the exposure limit.

Personal Protection:

Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.

Personal Protection in Case of a Large Spill:

Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self-contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.

Exposure Limits: Not available.

Section 9: Physical and Chemical Properties

Physical state and appearance: Solid.

Odour: Not Available Taste: Not available.

Molecular Weight: 228.2 g/mole Colour: White to Yellowish

pH (1% soln/water): Not available. Boiling Point: Not available.

Melting Point: 120°C (248°F) Critical Temperature: Not available.

Specific Gravity: 1.98 (Water = 1) Vapour Pressure: Not applicable. Vapour Density: Not available. Volatility: Not
available.

Odour Threshold: Not available.

Water/Oil Dist. Coeff.: Not available. Ionicity (in Water): Not available.

Dispersion Properties: See solubility in water.

Solubility: Very soluble in water (Hot and Cold)

Section 10: Stability and Reactivity

Stability: The product is stable.

Instability Temperature: Not available.

Conditions of Instability: Excess heat, ignition sources, incompatible materials

Incompatibility with various substances: Reactive with reducing agents, combustible materials, organic materials, metals.

Corrosivity: Non-corrosive in presence of glass.

Special Remarks on Reactivity: Strong oxidiser. Moisture sensitive. May decompose on exposure to moist air or water. May
be shock sensitive and thermally unstable. Decomposes when heated. Incompatible with powdered aluminium, iron,
sodium peroxide.

Special Remarks on Corrosivity: Not available. Polymerization: No.

Section 11: Toxicological Data

Routes of Entry: Eye contact. Inhalation. Ingestion.

Toxicity to Animals: Acute oral toxicity (LD50): 689 mg/kg [Rat].

Chronic Effects on Humans: May cause damage to the following organs: upper respiratory tract

Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant, sensitizer), of ingestion, of inhalation (lung
irritant, lung sensitizer).

Special Remarks on Toxicity to Animals: Not available.

Special Remarks on Chronic Effects on Humans: Not available.

Special Remarks on other Toxic Effects on Humans: Acute Potential Health Effects: Skin: Causes skin irritation. May cause
skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. Eyes: Causes eye
irritation. Ingestion: Causes gastrointestinal (digestive) tract irritation with nausea, vomiting, and diarrhoea. May be
harmful if swallowed. Inhalation: Causes respiratory tract irritation. May cause chemical pneumonitis and pulmonary
oedema, inflammation, oedema of bronchi and larynx. Chronic Potential Health Effects: Repeated or prolonged skin
exposure may cause allergic reactions in sensitive individuals. Repeated or prolonged exposure by inhalation may affect
respiration and metabolism.

Section 12: Ecological Data

Ecotoxicity: Not available.

BOD5 and COD: Not available.

Products of Biodegradation:

Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.

Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself

Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:

Waste must be disposed of in accordance with local environmental control regulations.

Section 14: Transport

DOT Classification: CLASS 5.1: Oxidizing material.

Identification: Ammonium Persulphate: UN1444 PG: III

Special Provisions for Transport: Not available.

Section 15: Other Information

The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we
assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall the author be liable for any claims, losses, or damages of any
third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising,
even if the author has been advised of the possibility of such damages