Amador Valley itigh School .

AP Chemistry

Review Name Date_Pd

Mid-Term Review
f) The correct electron configuation for calcium is

a1 t*z*zp6z*lp6+* d; 1s22s22p63s23p64sr3dl
b) ls22s42purs',rpu+s2 e; 1s22s32p53s23p64s2
c) t*z*zp6l*3p64s4

2) What is the de Broglie wavelength of an electron moving at 80.0% the speed of light? (The mass of an
electron is 9.11 x 10-28g)

a) 3.03 x 10-12 m b) 2.42 x 10-15 m c)2.42x 10-12 m d) 3.03 x 10-15 m

3) What is the frequency of radiation that has a wavelength of 489 nm?

a) 6.13x10lam b) 6.13xl0las'r c)1.63x10-15m d)1.63x10-15sl

4) What is the smallest incrbment of energy that can be emitted or absorbed at a wavelength of 812 nm?

a)1.99x10-25J b) 2.45x10-leJ c)2.45x10-28J d)3.7x1014J

5) What is the energy of a photon of frequency 232 x l0r3 Hz?

a)2.45 x l(lre J b) 2.44x1047 J c) 6.63 x l0rl J d) 1.80 x 10-20 J

7) What is the energy per mole of photons of frequenc y 2.72x l0r3 Hz?
a) 14800 kg b) 1080 { c) 148 kJ d) 10.9 kJ e) 1.80 x 10'20 J

8) What is f called?
a) wave function b) electron probability c) quantum wave number d) probability density

9) Heisenberg's Uncertainty Principle is based on

a) the dual nature of matter b) the Theory of General Relativity

c) modern atomic theory d) Schrodinger's wave functions

l0) The electron configuration of the indicated atom in the ground state is correctly written for which
atom?
a) Sc [Ar] 4sr3d2
b) Pb gxel of+fto5d'o6f
c) Se [Ar] 4s23dlo4p4
d) Cd tKrl 5s24d8

e) Ar [Ne] 4s23dto4po
11) Which one of the following elements has 3 electrons in a p dubshell?
a)Sb b)Na c)Sc d)V e)Nd

12) Which of the following sets of quantum numbers is possible for a3d electron?
a) n - 3,1= 3, tr\= -2, fr": */z
b) n= 2,1: l, ltI1 = *1, nir"= -r/z
c) n= 3, I = 1, fill =0, fflr= -Vz
d) n = 3,1 = 2, tr4 = -2, fr"= *Yz
e) n : 4,1: 1,[11 = *1, fr"= *Yz

13) The value of / that is related to the following orbital is:

a)0 b)1 c)2 d)3 e)4

14) The stratospheric ozone (O3) decomposes by absorbing energy and falling apart into an Oz molecule
and an oxygen atom, a process known as photodissociation.

Substance AIlf &J/mol)

.#

o{e))oz(g)+o(g) o(s) 247.5

oz(g) 0

or(e) t42.3

a) What is the maximum wavelength (in nm) a photon can have if it is to possess sufficient energy to
cause this dissociation?
b) Is this wavelength visible lighL ulha-violet or infrared?
15) Some sulfuric acid is spilled on a lab bench. It can be neutrali zedby sprinkling sodium bicarbonate on
it and then mopping up ttre resultant solution. The sodium bicarbonate reacts with sulfiric acid in the
following way:
2NaHCO:(s) + H2SOa(aq) *Na2SO+(aq) + 2COz(d + 2HzO(D

Sodium bicarbonate is added until the finrngdue to the formation of COzG) stops. If 35 mL of 6.0 M
HzSO+ was spilled, what is the minimum mass of NaHCOT that must be added to the spill to neutalize
the acid?

16) The watt is the derived SI unit of power, the measure of energy per unit time: IW=I J/s. A typical

laser used as a pointer in lecture presentations outputs red light of wavelength 6300 A, with a power of
5.0mW. The laser is pointed at a surface for 2.0 minutes. How many photons of laser light will strike
the surface during this interval?

l7) Balance the following redox equation in an acidic solution

PH3 + I2-':> HIPOZ- + I-

18) Consider the reaction between 50.0 mL of liquid methyl alcohol, CH:OH (density:0.850 g/ml), and
22.8L of Oz at27.0"C and a pressure of 2.00 atm. The products of the reaction are COz(g) and H2O(g).
Calculate the number of moles of HzO formed if the reaction goes to completion.

19) The preparation of NOz(g) fromNz(g) and Odg) is an endothermic reaction. The enthalpy change of
:
the reaction for the balanced equation (with the lowest whole-number coefficients) is H 67.7 kJ. If
250. mL Nr(g) at 100.oC and 3.50 atm and 450. mL of Oz(g) at 100.oC and 3.50 atm are mixed, what
amount of heat is necessary to synthesize NOz(g)?
20) Group 2 is also known as the

21) The d-block elements are also known as the

2})Thenumber 0.07088090 writtento 3 signifrcant figures is

23) Identifi thenumberofvalence electrons: N- Be- K

.
-I-
24) Write the net ionic equation for the reaction of iron(III) nitrate and sodium hydroxide

2s)
First Second Third
lonization Energy Ionization Energy lonization Energy
ftJ mol'') (kJ mol-r) (kJ mol-')
Element I l -251 2.300 3,820
Element 2 496 4,560 6.910
Element 3 738 1.450 7.730
Element 4 1.000 22s0 3.360

The table above shows the first three ionization energies for atoms of four elements from the third period of
the periodic table. The elements are numbered randomly. Use the information in the table to answer the
following questions.
(a) Which element is most metallic in character? Explain your reasoning.

(b) Identify element 3. Explain your reasoning.

(c) Write the complete electron configuration for an atom of element 3.

(d) What is the expected oxidation state for the most common ion of element 2?

(e) What is the chemical symbol for element 2?

(0 A neutral atom of which of the four elements has the smallest radius?