Lecture8 Salt PDF
Lecture8 Salt PDF
Salt
By the end of these lectures, you will be able to:
• To explain the different • To describe the origin and
forms of commercial salts production of table salt
for food use
• To discuss the nutritional
and health value of salt
consumption
Food
Food
Technology
• To outline the history and • To recognize the cultural
economics of salt dimension of salt
production and
Chemical sense
Taste bud
1. Unrefined salt
Fleur de sel, bamboo salt, raw sea salt
2. Refined salt
Majorly sold for industrial uses
3. Table salt
97 – 99% sodium chloride with anti-caking
and/ or desiccant
4. Salty condiments
Soy sauce, fish sauce, oyster sauce, ketchup
Processes to refine salt
Salt feeding
Salt washing & milling
Centrifuging
Dosing of additives &
coating
Salt drying
Sizing and conditioning
Storing
Packaging
Varieties of Refined Salt
Components
Type of NaCl Mg Ca SO4 Insolubles
Salt
Pure Vacuum 99.95 0.0001 0.002 0.04 tr
Evaporated
Salt
Vacuum Salt 99.70 0.01 0.01 0.2 tr
Refined salt 99 0.06 0.05 0.2 0.02-0.3
Solar Salt 96-99 0.01-0.17 0.04-1.1 0.2-1.3 1-5
Rock Salt 90-99 0.01-0.17 0.04-1.1 0.2-1.3 0-5
Refined salt is high in purity (NaCl content 99.5%), dry, and white with uniform
grain size (0.3 mm). Depending on the application, it is sold with or without
additives such as: anti-caking, free flowing and iodizing agents.
Table salt
http://industrialhistoryhk.org/salt‐
production‐oldest‐industry‐hong‐
kong‐tai/
Nowadays !
Salt Production
Water from salt wells/
springs
In some places (like
Sichuan, China), people
draw salty water in deep
wells, then boil them in
large iron pans
Energy input (e.g. wood,
natural gas) is needed
for high temperature,
but the salt production is Making salt by boiling water (Zigong, Sichuan)
faster
Salt Production
Vacuum evaporation
A faster and more efficient
method for salt production
The brine is boiled (at lower
temperatures) under near‐
vacuum conditions
Small salt seed crystals were
added to promote
crystallization
The steam produced can be
recycled for heating, which
increase the efficiency of the
process
Nearly automatic operation
Rock Salt
Rock Salt (Halite) is the
mineral form of sodium
chloride
It is usually colorless
crystals, but it may be
colored by the impurities
Found in sedimentary
evaporate deposits of
dried lakes or seas
Rock Salt
Salt can be mined
from underground
deposits
Mining salt
Similar to mining
other raw materials,
like coal
Before the industrial
revolution, mining
salts was very labor‐
intensive and
dangerous
Mining rock salts
After the development of
internal combustion
engines and earth
moving equipment, the
mining process become
much easier
Salt are produced either by
rock salt mining or
solution mining (adding
water into mines, pumping
out the brine and followed
by vacuum evaporation)
The mines are usually
operated by multi‐national
companies. Modern rock salt mine near Mount
Morris, New York
Salt Production
Annual world salt production (2006) : 210,000,000 tonnes
The top five salt producers are: USA, China, India, Canada
and Australia
Uses of salt
Food‐grade salt constitute
17.5% of global salt
production in 2011
Others uses
Chemical industries : ‐
‐ Chloralkali process
(electrolysis of
production of NaOH
and Chlorine gas),
‐ producing soda ash
(sodium carbonate) Various uses of sodium chloride
De‐icing in different areas
Animal feedstuff
Salt: Global Industry Markets and Outlook, 13th edition 2011 ‐
http://www.roskill.com/reports/industrial‐minerals/salt
Uses as electrolyte Na+ /K+ pumps
Salt is an essential element in
the diet of most living things
Sodium is one of the primary
electrolyte in the body
Various electrolytes (Na,K,Ca)
are used to maintain voltage
across the cell membranes
and carry electrical impulses
They will be lost through
sweating and urination and
so have to replaced to keep
the concentration constant
Salt as electrolyte
• Too much or too little salt
in diet can cause muscle
cramps, dizziness or
electrolytic disturbances
• Similarly, if one drink too
much water without salt
intake, they may got water
intoxication, which is
potentially fatal
• Therefore, saline solution
(instead of pure water) is
used in medical treatment
Uses as (Food) Preservatives
Salt is used as a preservative
since ancient times (and not
limited in foods)
For example, ancient Egyptian
people use a lot of salt in
preserving mummies and
their funeral offerings (salted
fish, birds, etc.)
via Osmosis
Uses of salt
(Food) preservative
Principle:
By creating a high salt
concentration, water in
the cells will be drawn
out by osmosis
Salt concentration
around 20% is required
to kill most bacteria
(Using salt water for
sterilizing (to kill
bacteria)
Uses of Salt
Salt is added to bread
dough to strengthen
the gluten (the elastic
protein‐water complex)
It also act as a binder in
sausages by forming a
gel of meat, fat and
moisture
Making Table Salt
Uses as Flavor Enhancer
To give a unique saltiness
taste
The taste is produced primarily
by the interaction of Sodium
ions and the ion channels in
the tongue
Other alkali metal ions (like
K+) give a less salty taste,
while the alkali earth metal
ions (like Ca2+) have a bitter
taste
Making table Salt
Unrefined salt
Raw sea salts are
often bitter in taste
(contains Magnesium
or Calcium
compounds)
not good for eating
Usually used in
bathing additives
(bath salts) and Typical mass of different substances in
cosmetic products 1kg(~1L) of sea water
Making table Salt
Refined salt
Produced by more
carefully controlled
evaporation/
crystallization
processes
Contains 97‐99% NaCl
Particle size varies
depending on uses
Various additives
Various additives of table salt
Iodine
Iodine (actually in the form
of iodide ions) is essential
to human health
Mainly come from marine
T3
foods
Human with iodine
deficiency will have thyroid T4
gland problems (e.g. swelling
of thyroid gland) or cause
stunted mental and physical
growth in children.
Various additives of table salt
From 1924, iodine‐containing
compounds were added to
table salts to help reducing
iodine deficiency in humans.
Potassium iodide (KI)
Sodium iodide (NaI)
Sodium iodate (NaIO3)
The amount of iodine
compound added is minute,
In US, iodized salt contains
46‐77ppm of iodine
In UK the value is 10‐22ppm Sample of potassium iodide
Various additives of table salt
Fluoride Enamel of teeth is
In places which have not mainly composed of
benefited from calcium phosphate
fluoridated toothpastes which can be
or water, fluorides are dissolved by acids
added to salt to protect
people’s teeth. Ca3(PO4)2
For example, in France,
35% of salts contains
sodium fluoride. F F F F F F F F
Protective layer of
F F F
F F F
fluoride on the surface
of teeth against corrosion
Ca3(PO4)2
by acids
Various additives of table salt
Iron
For some developing countries,
both iron and iodide salts
are added to table salt since
the last decade.
They are called double
fortified salt
This can prevent iron
deficiency anemia, which
interferes mental
development of infants.
It is previously impossible
to add iron as it will react
with iodide in the mixture,
but now new technology is
developed to avoid that
Various additives of table salt
Anti‐caking agents
To make table salt move more
freely (and don’t clump into
large pieces), various anti‐
caking agents may be added to
the salt.
Sodium ferrocyanide
Calcium/Magnesium
carbonate
Tricalcium phosphate
Fatty acid salts
Magnesium oxide
Silicon dioxide
Calcium silicate
Sodium/Calcium
aluminosilicate
Various additives of table salt
Others
Folic acid (Vitamin B9)
may be added to the salt
which helps prevent
some infant defects of
young mothers in
developing countries
The presence of folic
acid will give the salt a
slightly yellow color
Salt, Culture and Society
Salt in ancient China
Chinese character for “salt 鹽“ also implicate the
origin and supervision of salt making
Ancient Modern
Chinese character for salt
Two possible meanings A man (working in salt
(i) Eyes (under watch) evaporation pond)
(ii) Government Officials
Salt evaporation pond
A pan (for holding the salty
water during evaporation)
Salt in history
Politically and
economically important
since ancient times
Many stories, legend and
tales are related to it
Many traditions in various
culture are related to salt
Served as money in
various time and places
Causes of numerous riots,
oppositions and warfare Salt evaporation ponds in ancient China
Salt in ancient times
Salt making can be traced
to pre‐historic times
Evidence indicates that
Neolithic people in
Romania boiled the salt
spring water to extract salt
(as far back in 6500BC) and
the salt extracted may be
related to the rapid growth
of the population
The salt extracted in Xiechi
near Yuncheng, China was
dated back to 6000BC, Xiechi(解池), the largest lake in Shanxi province.
which is one of the oldest It was known to produce salt for at least 4000
verifiable salt works years
Natron: Mixture of sodium carbonate, sodium
Salt in ancient Egypt bicarbonate, along with small quantities of sodium
chloride and sodium sulfate.
Salt making can be traced to
pre‐historic times
Due to its durability and
immunity to decay, salt was a
symbol of immortality
Egyptians discovered a type of
salt in a dry riverbed, which
they called Natron, and they
used it in the mummification
process
From 2800BC, the Egyptians
began exporting salted fish
to Phoenicians for Lebanon
cedar (a kind of wood for
construction), glass and dyes
Salt in ancient culture
Salt has also been referenced in religious books and arts
Bible
Old Testament, Leviticus 2:13
Season all your grain offerings with salt. Do not leave the salt of the
covenant of your God out of your grain offerings; add salt to all your
offerings.
New Testament, Matthew 5:13
You are the salt of the earth. But if the salt loses its saltiness, how
can it be made salty again? It is no longer good for anything, except
to be thrown out and trampled underfoot.
Salt in ancient culture
Salt has also been referenced in religious books and
arts
Painting
The Last Supper (Leonardo da Vinci), restored
Salt is a symbol of sanctity and protection
Spilling salt represents a bad omen
https://en.wikipedia.org/wiki/Spilling_salt
Origins of words that are related to salt
Many words are derived (or
suspected to be derived) by parts
of the word salt
Salad (14th century) Salade
(French) Salata (Latin,
feminine form of salted/salty)
Sauce Sauce (French)
Salsus (Latin, masculine
form of salty/salted,)
Salsa Salsa (Spanish)
Salsa (Latin, feminine form of
salty)
Sausage Saussiche (Old
French) Salsus
Soldier – “Sal dare” (Latin, “to
give salt”)
Origin of the word ‘salary’
Salary – Salarium
An allowance for the
purchase of salt in
ancient Rome—Salt
money
In another version, it
was the price paid to
soldiers conquering
the salt supplies and
guarding the salt roads
that lead to Rome Naturalis Historia (Natural History), ca. 77‐79 by
Pliny the Elder. It explained that salary was ‘derived
from salt, as it was originally the soldier’s pay.’
Salt tax
How much do you need to pay for salt nowadays?
Free?
Salt tax
Throughout history, salt
have been subjected to
taxes and governmental
monopolies
The salt tax revenues
were so high that it can
support a country like
France, Britain and even
China
Oppositions to salt tax
As the salt tax were often high (and related to a large
part of the governments revenues), numerous
riots/protests occurred in different countries was
related to it
Also, illegal salt production and salt smuggling were
common as it was highly profitable to sell salts without
paying the tax
Salt tax in china
There are three types of
policies regarding the salt
trade in ancient china:
No control (and no
taxation)
Imposition of salt taxes
(and controlling the
production)
Monopolizing salt
production and trades.
There were much
discussion on different salt Machine for drilling salt wells, 17th century
tax implementations
Arguments of tax policies
No control
Salt is one of the commodities which can’t be replaced by
other things. People should not be taxed for survival
Salt tax
The need of salt (per person) is small compared to other
commodities (e.g. food).
Also, it is easy to implement salt tax than other taxes (e.g. just
collect them at production site)
The amount of revenue generated by such tax would be great.
Monopoly
The salt mining business was too profitable, and it should be
controlled (or even done) by governments instead.
Salt smugglers in China
Salt smuggling was endemic and
widespread in China
The higher the tax/stricter the
rules, the more serious was the
problem
The problem exists since the tax was
levied, but it became more serious
after late Yuan dynasty (14th century)
The cost of making salt was
decreasing, while the price of salt
remained high (due to the tax)
The need for salt increases as the
population is rising rapidly
The traffic was advanced enough to Salt smugglers
smuggle large amount of salt (a few
tons at a time)
Salt smugglers in China
The salt smuggling business were highly
organized, often operated by bandits
and influential people
Traders carry illegal salts in addition to
the legal ones
Armed bandits produced and traded
illegal salts, they might also rob salt
from salt traders and sold them for
profit
Their actions were not prosecuted as
there were much corruptions among
the government officials
Poor people also took part in producing
illegal salt, especially when the economy
is tumbling
It is estimated in Qing dynasty, more
than half of the salt produced were illegal Salt smugglers
in origin
Salt smuggling in British India
To avoid salt smuggling, a thorn
fence and custom check points
were erected along the Bengal in
1803
Later, the line was extended
throughout India, forming a
continuous barrier of more than
4000 km
Laws were set up to ban
unlawful production and
procession of salts, and salt can
only be handled at official
government salt depots after
paying the tax
Salt tax in British India
Britain abolished its own
salt tax in 1825, when the
material becomes
important in the
manufacturing processes
emerging from Industrial
revolution
However, the tax was
levied in British India
In 1858, it contributed to
10% of revenues of
British India
In 1880, the income from
salt is 7 million pounds
Protests of salt tax in British India
At one time, the price of salt in
Britain was 1.5 pounds per ton.
But in India, the same amount
cost 20 pounds
In 1900 and 1905, India was one
of the largest salt producers in
the world, with a yield of
1,021,426 and 1,212,600 tonnes
respectively
However, the high price of salt
made it unaffordable to people
in India, resulting a number of
diseases due to iodine deficiency
Protests of salt tax in British India
There were much
criticism of salt tax since
the introduction, both in
Britain and in India
However, the tax was
still in force and even
doubled in 1923
In 1930s, people in salt‐
production provinces
were close to open
rebellion
Map of India (1930)
Protests of salt tax in British India
Dandi March(1930)
Salt March
They aimed to produce salt
without paying the tax,
defying the laws of salt
production by British
rulers
Their production of illegal
salt sparked a nation‐wide
protest against salt tax
which last for a year
The tax was finally
abolished in 1946
French gabelle
The high tax was one of the
contributing factors of
French Revolution
Abolished in 1790 (French
Revolution)
Reinstated in 1806 (by
Napoleon for financing war
campaigns)
Briefly abolished again in
1848‐1852 (during Second
Republic)
Finally abolished
permanently in 1945 (after
the WWII)
Salt riot in Russia (1648)
The state treasury of Russia was
drained in the Time of Troubles
(1598‐1613)
To replenish the treasury, the
government replaced the old tax
system with a universal salt tax
The new tax drove up the price
of salt
Workers and serfs were the most
affected by the increased price,
as salted fish was a staple of the
Russian diet at the 17th century
Meanwhile, townsmen and
nobles had ways to evade the tax
Salt riot in Russia (1648)
The angry population
blamed the Tsar’s advisors
who placed a higher
burden on them
They tried to complain to
the Tsar about the officials,
but was dispersed by the
royal bodyguards
This caused a major
outbreak of anger
The rebels burst into
Kremlin and set fires in the
city, laying half of the
Moscow in ruin
Researchers have suggested that taxes on food