The document discusses fuel cells, which convert chemical energy directly into electricity through electrochemical reactions. Fuel cells were first invented in 1838 but did not see commercial use until 1932 with the hydrogen-oxygen fuel cell. Fuel cells are used to provide primary and backup power and to power vehicles, and have higher efficiency than internal combustion engines. A typical fuel cell produces 0.6-0.7 volts, with the voltage decreasing as the current increases due to various loss factors. Fuel cells can be combined in series and parallel configurations to achieve desired energy output.
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Digital Assignment: - ADITYA GHOSH (19BME0519)
The document discusses fuel cells, which convert chemical energy directly into electricity through electrochemical reactions. Fuel cells were first invented in 1838 but did not see commercial use until 1932 with the hydrogen-oxygen fuel cell. Fuel cells are used to provide primary and backup power and to power vehicles, and have higher efficiency than internal combustion engines. A typical fuel cell produces 0.6-0.7 volts, with the voltage decreasing as the current increases due to various loss factors. Fuel cells can be combined in series and parallel configurations to achieve desired energy output.
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DIGITAL ASSIGNMENT :-
-ADITYA GHOSH(19BME0519)
A fuel cell is an electrochemical cell that converts the chemical
energy of a fuel (often hydrogen) and an oxidizing agent (often oxygen]) into electricity through a pair of redox reactions. Fuel cells are different from most batteries in requiring a continuous source of fuel and oxygen (usually from air) to sustain the chemical reaction, whereas in a battery the chemical energy usually comes from metals and their ions or oxides [3] that are commonly already present in the battery, except in flow batteries. Fuel cells can produce electricity continuously for as long as fuel and oxygen are supplied. The first fuel cells were invented by Sir William Grove in 1838. The first commercial use of fuel cells came more than a century later following the invention of the hydrogen–oxygen fuel cell by Francis Thomas Bacon in 1932. The alkaline fuel cell, also known as the Bacon fuel cell after its inventor, has been used in NASA space programs since the mid-1960s to generate power for satellites and space capsules. Since then, fuel cells have been used in many other applications. Fuel cells are used for primary and backup power for commercial, industrial and residential buildings and in remote or inaccessible areas. They are also used to power fuel cell vehicles, including forklifts, automobiles, buses, boats, motorcycles and submarines. Fuel cells come in many varieties; however, they all work in the same general manner. They are made up of three adjacent segments: the anode, the electrolyte, and the cathode. Two chemical reactions occur at the interfaces of the three different segments. The net result of the two reactions is that fuel is consumed, water or carbon dioxide is created, and an electric current is created, which can be used to power electrical devices, normally referred to as the load. At the anode a catalyst oxidizes the fuel, usually hydrogen, turning the fuel into a positively charged ion and a negatively charged electron. The electrolyte is a substance specifically designed so ions can pass through it, but the electrons cannot. The freed electrons travel through a wire creating the electric current. The ions travel through the electrolyte to the cathode. Once reaching the cathode, the ions are reunited with the electrons and the two react with a third chemical, usually oxygen, to create water or carbon dioxide.
A block diagram of a fuel cell
Design features in a fuel cell include:
The electrolyte substance, which usually defines
the type of fuel cell, and can be made from a number of substances like potassium hydroxide, salt carbonates, and phosphoric acid.[19] The fuel that is used. The most common fuel is hydrogen.
The anode catalyst, usually fine platinum powder, breaks
down the fuel into electrons and ions.
The cathode catalyst, often nickel, converts ions into
waste chemicals, with water being the most common type of waste.[20]
Gas diffusion layers that are designed to resist oxidization.
[20]
A typical fuel cell produces a voltage from 0.6 V to 0.7 V at full
rated load. Voltage decreases as current increases, due to several factors:
Activation loss
Ohmic loss (voltage drop due to resistance of the cell
components and interconnections)
Mass transport loss (depletion of reactants at catalyst sites
under high loads, causing rapid loss of voltage).[21] To deliver the desired amount of energy, the fuel cells can be combined in series to yield higher voltage, and in parallel to allow a higher current to be supplied. Such a design is called a fuel cell stack. The cell surface area can also be increased, to allow higher current from each cell. Within the stack, reactant gases must be distributed uniformly over each of the cells to maximize the power output.[22][23][24]
A fuel cell, like a battery, is inherently a high-efficiency device.
Unlike internal-combustion machines, in which a fuel is burned and gas is expanded to do work, the fuel cell converts chemical energy directly into electrical energy. Because of this fundamental characteristic, fuel cells may convert fuels to useful energy at an efficiency as high as 60 percent, whereas the internal-combustion engine is limited to efficiencies near 40 percent or less. The high efficiency means that much less fuel and a smaller storage container are needed for a fixed energy requirement. For this reason, fuel cells are an attractive power supply for space missions of limited duration and for other situations where fuel is very expensive and difficult to supply. They also emit no noxious gases such as nitrogen dioxide and produce virtually no noise during operation, making them contenders for local municipal power-generation stations. A fuel cell can be designed to operate reversibly. In other words, a hydrogen-oxygen cell that produces water as a product can be made to regenerate hydrogen and oxygen. Such a regenerative fuel cell entails not only a revision of electrode design but also the introduction of special means for separating the product gases. Eventually, power modules comprising this type of high-efficiency fuel cell, used in conjunction with large arrays of thermal collectors for solar heating or other solar energy systems, may be utilized to keep energy-cycle costs lower in longer-lived equipment. Major automobile companies and electrical-machinery manufacturing companies worldwide have announced their intention to produce or use fuel cells commercially in the next few years.