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Group IV Cations Anions Flowcharts

The document outlines qualitative analysis schemes for identifying Group IV cations and anions. The scheme for cations involves using ammonium sulfate, ammonium oxalate, sodium hydrogen phosphate, sodium hydroxide, and magnesium indicator to separate and identify barium, calcium, and magnesium ions through the observation of precipitates and flame colors. The scheme for anions uses silver nitrate, ammonium hydroxide, barium nitrate, and nitric acid to separate and identify iodide, chloride, and sulfate ions through the observation of precipitates.

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489 views

Group IV Cations Anions Flowcharts

The document outlines qualitative analysis schemes for identifying Group IV cations and anions. The scheme for cations involves using ammonium sulfate, ammonium oxalate, sodium hydrogen phosphate, sodium hydroxide, and magnesium indicator to separate and identify barium, calcium, and magnesium ions through the observation of precipitates and flame colors. The scheme for anions uses silver nitrate, ammonium hydroxide, barium nitrate, and nitric acid to separate and identify iodide, chloride, and sulfate ions through the observation of precipitates.

Uploaded by

Faith Domingo
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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MTCC 104

Analytical Chemistry- Laboratory


1. QUALITATIVE ANALYSIS SCHEME/ FLOWCHART FOR GROUP IV CATIONS

Solution Containing Ba2+, Ca2+,


and Mg2+

Ammonium Sulfate

Presumptive ID for Supernate (T2)


BaSO4 contains Calcium and
Magnesium
(White PPT)

Ammonium Oxalate

Flame Test:

Confirmatory for
Barium:
Presumptive Supernate (T3)
Green Flame
ID for Calcium contains Mg2+
Oxalate
Co
(White PPT)

Sodium Hydrogen
Phosphate +
NaOH
Flame Test:

Confirmatory for
Calcium:
Presumptive
Brick Red Flame ID for
Magnesium
Co Phosphate

(White PPT)

Magnesium Indicator +
NaOH

Confirmatory for
Magnesium:

Blue Gel PPT


By: EFREN II C. DEOCADES, RMT
MTCC 104
Analytical Chemistry- Laboratory
2. QUALITATIVE ANALYSIS SCHEME/ FLOWCHART FOR ANIONS

Solution Containing I-, Cl-, and SO42-

Silver Nitrate

Precipitates AgI (Yellow PPT) Supernate (T3)


and AgCl (White PPT) contains Sulfate

Ammonium
Hydroxide

Barium Nitrate

Yellow Precipitate
remains (AgI) White Precipitate
(BaSO4)

Supernate (T2)
contains Cl-

Nitric Acid

White Precipitate
(AgCl)

By: EFREN II C. DEOCADES, RMT

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