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IARJSET ISSN (Online) 2393-8021

ISSN (Print) 2394-1588

International Advanced Research Journal in Science, Engineering and Technology


ISO 3297:2007 Certified
Vol. 3, Issue 8, August 2016

Consequence of Temperature, pH, Turbidity and


Dissolved Oxygen Water Quality Parameters
Vijay S. Kale
Associate Professor, Department of Electronic Science, KTHM College, Nashik, Maharashtra, India

Abstract: Water is an important constituent for all the living beings. The water quality guidelines provide a limit value
for each parameter for drinking water. It is necessary that the quality of drinking water should be checked at regular
time interval, because due to use of contaminated drinking water, human population suffers from varied of water borne
diseases. The availability of good quality water is a necessary feature for preventing diseases and improving quality of
life. The different physico-chemical parameters are color, temperature, hardness, turbidity, pH, sulphate, chloride,
dissolved oxygen (DO), biochemical oxygen demand (BOD), chemical oxygen demand (COD) etc. used for testing of
water quality. Heavy metals like Pb, Cr, Fe, Hg etc. are of special concern or chronic poisoning in aquatic animals. This
paper summarized the importance of monitoring temperature, turbidity, pH and dissolved oxygen parameters of
drinking water and its adverse effect. A lot of drinking water quality parameters are described by world health
organization (WHO). It gives the guidelines of parameters for comparing the value of real water sample from that we
can decide the quality of water.

Keywords: Drinking water, Parameters, Temperature, Dissolved Oxygen, Turbidity, pH.

I. INTRODUCTION

Three sources are used to collect water, where we live in Safe drinking water should be: Free of pathogens, Low in
the world are: concentrations of toxic chemicals, Clear, Tasteless and
colourless (for aesthetic purposes) [3]
 Ground water- its depth and quality varies from place
to place. About half of the world‟s drinking water „Pure‟ water does not actually exist in nature, as all water
comes from the ground. contains some naturally occurring chemicals that have
 Surface water- directly from a stream, river, lake, pond, leached from the surrounding environment. In most cases,
spring etc. Its quality is generally unsafe to drink the levels of naturally occurring chemicals are either
without treatment. beneficial, or minimal and of little consequence. There are
 Rainwater- is collected and stored using a roof top, many human made chemicals that can contaminate water
ground surface or rock catchment. and affect its usability. Sources of chemical contaminants
can be naturally occurring chemicals, chemicals from
The quality of rain water collected from a roof surface is agricultural activities, chemicals from human settlements,
usually better than a ground surface or rock catchment. chemicals from industrial activities and chemicals from
Water is in continuous movement on, above and below the water treatment and distribution [4].
surface of the earth. As water is recycled through the
earth, it picks up many things along its path [1]. Water Good quality of drinking water is very necessary for
quality varies from place to place, with the seasons and improving the life of people and to prevent from diseases.
with various kinds of rock and soil which it moves It is necessary that the quality of drinking water should be
through. 70% surface of earth is covered by water, checked at regular time interval, because due to use of
majority of water available on the earth is saline in the contaminated drinking water, human population suffers
nature and only 3 % of exists as fresh water. Fresh water from varied of water borne diseases. It is necessary to
has become a scare commodity due to over exploitation know the details about different physico-chemical
and pollution. Pollution of surface and ground water is parameters, which are used for testing of water quality
great problem due to rapid urbanization and such as colour, temperature, hardness, pH, turbidity,
industrialization. The increasing number of human sulphate, chloride, dissolved oxygen (DO), biochemical
activities has gradually speed-up contamination and oxygen demand (BOD), chemical oxygen demand (COD)
damage to fresh water resources [2]. etc.. Heavy metals like Pb, Cr, Fe, Hg etc. are of special
concern because they produce water or chronic poisoning
It is important to judge the safety of water by taking three in aquatic animals. There is lot of parameter for drinking
qualities into consideration: water quality parameter described by world health
 Microbiological- bacteria, viruses, protozoa and worms organization (WHO), Indian Standard IS 12500:2012,
 Chemical- minerals, metals and chemicals Environmental Protection Agency (EPA), Environmental
 Physical- temperature, colour, smell, taste and turbidity Quality Standards (EQA) [5]. The World Health

Copyright to IARJSET DOI 10.17148/IARJSET.2016.3834 186


IARJSET ISSN (Online) 2393-8021
ISSN (Print) 2394-1588

International Advanced Research Journal in Science, Engineering and Technology


ISO 3297:2007 Certified
Vol. 3, Issue 8, August 2016

Organization (WHO) is part of the United Nations (UN) accepted by the Ministry of Health Services for
and it focuses on international public health. The WHO application in British Columbia.
writes the Guidelines for Drinking Water Quality to make Objectives are derived from criteria by considering the
sure that people are drinking safe water around the world local water quality, water uses, water movement, waste
[6, 7]. P. Fowler et. Al. in their study recommended that discharges, and socioeconomic factors [13]. Temperature
temperature, turbidity, DO, and pH be monitored directly is important because of its influence on water chemistry.
on a continuous basis since they tend to change rapidly The rate of chemical reactions generally increases at
and have a significant adverse effect on the human being if higher temperature. Water, particularly groundwater, with
allowed to operate out-of-range [8]. higher temperatures can dissolve more minerals from the
Water is called the „universal solvent‟ because it dissolvesrocks. Therefore, it will have a higher electrical
more substances than any other liquid. This means that conductivity. Temperature exerts a major influence on
wherever water goes, either through the ground or through biological activity and growth. Temperature governs the
our bodies, it takes along valuable chemicals, minerals, kinds of organisms that can live in rivers and lakes.
and nutrients. Pure water has a neutral pH of 7. The water From the user‟s viewpoint, cool drinking water is
molecule is highly cohesive. It is very sticky. Pure water, preferable to warm; a temperature of 10 C is usually
does not conduct electricity. Water becomes a conductor satisfactory. The figure of 19 C, often quoted as a „limit‟
once it starts dissolving substances. Water has a high above which most consumers complain, is based on an
specific heat index. It absorbs a lot of heat before it begins
empirical relationship derived about 60 years ago.
to get hot [9]. This is why water is valuable to industries Pangborn and Bertolero, using distilled water, solutions of
and in car's radiator as a coolant. mineral salts in distilled water and samples of drinking
water, showed that the intensity of taste is greatest for
A drinking-water quality guideline value represents the water at room temperature and is significantly reduced by
concentration of a constituent that does not result in any chilling or heating [9, 13].
significant health risk to the consumer over a lifetime of
consumption. When a guideline value is exceeded, the Turbidity and colour are indirectly related to temperature,
cause should be investigated and corrective action to be because temperature affects coagulation. The efficiency of
taken. The amount by which and for how long, any coagulation is strongly temperature dependent and the
guideline value can be exceeded without endangering optimum pH for coagulation decreases as temperature
human health depends on the specific substance involved increases. Because of the complex combination of
[10]. In drawing up national standards for drinking water chemical equilibrium involved in coagulation, it is
quality, it will be necessary to take into account various recommended that, in order to achieve the most
local, geographical, socioeconomic and cultural factors. economical use of coagulant, jar tests be carried out at the
As a result, national standards may differ appreciably from temperature of the treated water and not at room
the WHO guideline values. Water quality monitoring and temperature. Corrosion rate is also a function of the
evaluation is therefore very critical for sustainable water dissolved oxygen concentration in water. The solubility of
resources and has increasingly attracted a great deal of oxygen decreases with increasing temperature (10.15
research and development attention. The permissible limits mg/L at 15 C to 7.1 mg/L at 35 C). The change in
of different parameter set by different agencies do not dissolved oxygen with temperature is small compared with
show uniformity [11]. This article summarized two the larger change in corrosion rates. Warm water holds
physical (Temperature, Turbidity) and two chemical (pH, less dissolved oxygen than cool water and may not contain
Dissolved Oxygen) water quality parameters. Guidelines enough dissolved oxygen for the survival of different
of physic-chemical parameters also have been given for species of aquatic life. Some compounds are also more
comparing the value of real water sample. toxic to aquatic life at higher temperatures [14].

II. PHYSICAL WATER QUALITY PARAMETERS Factors affecting water temperature:


 Air temperature
Two physical parameters temperature and turbidity are  Amount of shade
described.  Soil erosion increasing turbidity
 Thermal pollution from human activities
A. Temperature  Unknown chemical reactions those weren‟t previously
Temperature refers to degree of hotness or coldness and it occurring in the water.
can be measured in degree Celsius. Water temperature
needs to be monitored regularly as outside tolerable Effects of water temperature:
temperature range, disease and stress will become more  Solubility of dissolved oxygen– more gas can be
prevalent. Among the consequences of temperature dissolved in cold water than warm.
changes are; photosynthetic activity, diffusion rate or  Rate of plant growth– increased water temperature can
gases, amount of oxygen that can be dissolved etc. [12]. cause an increase in the photosynthetic rate of aquatic
The aesthetic objective for temperature of less than or plants and algae, which can lead to increased plant
equal to 15 degrees Celsius is adopted from the growth and algal blooms and harm the local
'Guidelines for Canadian Drinking Water', which has been ecosystems.

Copyright to IARJSET DOI 10.17148/IARJSET.2016.3834 187


IARJSET ISSN (Online) 2393-8021
ISSN (Print) 2394-1588

International Advanced Research Journal in Science, Engineering and Technology


ISO 3297:2007 Certified
Vol. 3, Issue 8, August 2016

 Resistance in organisms– if water becomes too hot or Effects of Turbidity:


too cold, organisms become stressed, lowering their  Reduces water clarity
resistance to pollutants, diseases and parasites [15].  Aesthetically unpleasant
 Decreases rate of photosynthesis
B. Turbidity  Increases water temperature
Turbidity is a measure of the cloudiness/clarity of water.
Cloudiness is caused by suspended solids mainly soil III. CHEMICAL WATER QUALITY PARAMETERS
particles (sand, silt, clay), microscopic plants and animals
that are suspended in the water column. Moderately low Two chemical parameters pH and dissolved oxygen are
levels of turbidity may indicate a healthy, well-functioning described.
ecosystem, with moderate amounts of microscopic plants
and animals present to fuel the food chain. However, A. pH
higher levels of turbidity pose several problems for stream The pH refers to the hydrogen ion concentration or how
systems. Higher turbidity levels are often associated with acidic or basic as water is and pH is defined as –log[H+].
higher levels of viruses, parasites and some bacteria pH value range from 0-14; pH 7 is neutral, pH<7 is acidic
because they can sometimes attach themselves to the dirt and pH>7 is basic. pH is a measure of the relative amount
in the water. Therefore, we must be cautious of turbid of free hydrogen and hydroxyl ions in the water. Water
water as it usually has more pathogens, so drinking it that has more free hydrogen ions is acidic, whereas water
increases our chances of becoming sick. Turbidity blocks that has more free hydroxyl ions is basic. Since pH can be
out the light needed by submerged aquatic vegetation. It affected by chemicals in the water, pH is an important
also can raise surface water temperatures above normal indicator of water that is changing chemically [19]. The
because suspended particles near the surface facilitate the pH of water determines the solubility (amount that can be
absorption of heat from sunlight [16]. dissolved in the water) and biological availability (amount
Nephelometers measure the intensity of light scattered by that can be utilized by aquatic life) of chemical
the suspended particles. The result is a measurement of constituents such as nutrients (phosphorus, nitrogen and
turbidity in Nephelometric turbidity units (NTU). The carbon) and heavy metals (lead, copper, cadmium etc.). In
WHO Guideline for turbidity in drinking water is less than case of heavy metals, the degree to which they are soluble
5 NTU. The turbidity in excess of 5 NTU or 5JTU may be determines their toxicity. Metals tend to be more toxic at
noticeable and consequently objectionable to the lower pH because they are more soluble. pH is most
consumers [17]. Highly turbid water reduces light important in determining the corrosive nature of water.
penetration therefore affecting levels of photosynthesis, Lower the pH value higher is the corrosive nature of
warming is increased due to absorption of sunlight, and it water. pH was positively correlated with electrical
is generally aesthetically unpleasing. These particles conductance and total alkalinity. The reduced rate of
decrease the passage of light through the water. Turbidity photosynthetic activity, the assimilation of carbon dioxide
sensor measures the murkiness by measuring the quantity and bicarbonates which are ultimately responsible for
of light scattered at ninety degree. Normally, turbidity increase in pH, the low oxygen values coincided with high
sensor makes use of LDR and LED. temperature during the summer month. Karanth in 1987,
Excessive turbidity or cloudiness, in drinking water is mentioned that, the higher pH values observed suggests
aesthetically unappealing and may also represent a health that carbon dioxide, carbonate-bicarbonate equilibrium is
concern. Turbidity can provide food and shelter for affected more due to change in physico-chemical
pathogens. If not removed, turbidity can promote regrowth condition [20]. Very high pH (greater than 9.5) or very
of pathogens in the distribution system, leading to low pH (lower than 4.5) values are unsuitable for most
waterborne diseases, which have caused significant cases aquatic organisms. Aquatic organisms are extremely
of gastroenteritis. Although turbidity is not a direct sensitive to pH levels below 5 and may die at these low
indicator of health risk, numerous studies show a strong pH values. High pH levels (9-14) can harm fish due to the
relationship between removal of turbidity and removal of fact that ammonia will turn to toxic ammonia at high pH
protozoa. The particles of turbidity provide shelter for (>9) [4].
microbes by reducing their exposure to attack by The pH for drinking water generally lies between 6.5 and
disinfectants. Fortunately, traditional water treatment 8.0 at 25°C (80° F). The pH of the water in a stream, river,
processes have the ability to effectively remove turbidity lake or underground flow will vary depending on a source
when operated properly [18]. of the water, type of soil, bedrock, types of contaminants
the water encounters in its path etc. The effects of a
Causes of Turbidity: specific type of water pollution on living plants and
 Soil erosion– silt and clay deposition animals can vary greatly. No health-based guideline value
 Urban runoff– road grime, rooftops, parking areas is proposed for pH by the WHO. Although pH usually has
 Industrial waste– sewage treatment effluent, no direct impact on consumers, it is one of the most
particulates important water quality parameters. For example, for
 Organic matter– microorganisms, decaying plants and effective disinfection with chlorine, the pH should
animals, petrol, diesel or oil from roads preferably be less than 8. The optimum range for chlorine

Copyright to IARJSET DOI 10.17148/IARJSET.2016.3834 188


IARJSET ISSN (Online) 2393-8021
ISSN (Print) 2394-1588

International Advanced Research Journal in Science, Engineering and Technology


ISO 3297:2007 Certified
Vol. 3, Issue 8, August 2016

disinfection is between pH 5.5 and 7.5. High pH causes a changing the flow of water, raising the water temperature
bitter taste, water pipes and water-using appliances and the addition of chemicals [22].
become coated with deposits and it depresses the
effectiveness of the disinfection of chlorine, thereby Sources of dissolved oxygen are:
causing the need for additional chlorine when pH is high.  Diffusion from the atmosphere and water at the surface
Low pH water will corrode or dissolve metals and other  Aeration as water flows over rocks & uneven surfaces
substances [21].  Aeration through churning action of wind and waves
 Photosynthesis from aquatic plants
Factors that affect pH levels:
 Acidic rainfall- may have little effect if the region is The concentration of dissolved oxygen is affected by [23]:
rich in minerals that result in high alkalinity values i.e.  Plant activity– DO levels fluctuate throughout the day,
higher concentrations of carbonate, bicarbonate, and increasing during the morning and peaking in the
hydroxide ions from limestone can provide a natural afternoon. Decreases occur at night when
buffering capacity capable of neutralising many of the photosynthesis ceases.
H+ ions from the acid. Other regions may have low  Temperature– affects the ability of water to dissolve
concentrations of alkalinity ions to reduce the effects of oxygen due to the different solubility‟s at different
acids in the rainfall area. temperatures. Cooler water have a greater capacity to
 Level of hard- water minerals dissolve oxygen than warmer water
 Releases from industrial processes- depends on  Decaying organic matter in water– decomposition
whether acids or bases are released releases heat, warming water and decreasing dissolved
 Release of detergents into water oxygen capacity
 Carbonic acid from decomposition  Stream flow – the faster the water moves and churns,
 Oxidation of sulphides in sediments (acidic) the greater the amount of oxygen is dissolved
 Altitude/atmospheric pressure– high altitudes and
B. Dissolved oxygen (DO) atmospheric pressure reduce dissolved oxygen capacity
DO describe the concentration of oxygen molecular in the  Human activities – removal of shade or the release of
water and it dependents on the temperature of the water warm water used in industrial processes can cause an
and the biological demand of the system. DO is supplied increase in water temperature, resulting in lower
to water through several method; direct diffusion of dissolved oxygen capacity
oxygen from the atmosphere, wind and wave action; and
photosynthesis. It is used in aerobic decomposition of IV. CONCLUSION
organic matter, respiration of aquatic organism and
chemical oxidation of mineral. As DO is used by many It is very essential and important to test the water before it
organisms in the water, it tends to change rapidly [5]. is used for drinking, domestic, agricultural or industrial
The quantity of oxygen that the water can hold depends on purpose. Water must be tested with different physico-
the temperature salinity and pressure of the water. Gas chemical parameters. Selection of parameters for testing of
solubility increases with decreasing salinity. Fresh water water is solely depends upon for what purpose we going to
holds more oxygen than saltwater. Gas solubility use that water and what extent we need its quality and
decreases as pressure decreases. The amount of oxygen purity. Water may contain different types of floating,
absorbed in water decreases as altitude increases because dissolved, suspended and microbiological as well as
of the decrease in relative pressure. Levels of dissolved bacteriological impurities. Groundwater is the most
oxygen vary depending on factors including water important source of water supply for drinking, irrigation
temperature, time of day, season, depth, altitude, and rate and industrial purposes. Increasing population and its
of flow. Water at higher temperatures and altitudes will necessities have lead to the deterioration of surface and
have less dissolved oxygen. Dissolved oxygen reaches its sub surface water. The cause of ground water gets pollute
peak during the day. At night, it decreases as and create health problems. Once the groundwater is
photosynthesis has stopped [10]. contaminated, its quality cannot be restored by stopping
Rapidly moving water, such as in a mountain stream or the pollutants from the source it therefore becomes
large river, tends to contain a lot of dissolved oxygen, imperative to regularly monitor the quality of groundwater
whereas stagnant water contains less. Bacteria in water can and to device a ways and means to protect it. So before
consume oxygen as organic matter decays. Thus, excess using of water, investigate qualitative analysis of some
organic material in lakes and rivers can cause eutrophic physico-chemical parameters of water. This may be
conditions. Aquatic life can have a hard time in stagnant considered as reference for the society to get cautious
water that has a lot of rotting, organic material in it, about the impending deterioration of their environment
especially in summer. Conditions may become especially and health.
serious during a period of hot, calm weather, resulting in The physical characteristics of water are usually things
the loss of many fish. Human factors that affect dissolved that we can measure with our own senses such as:
oxygen in streams include addition of oxygen consuming turbidity, colour, taste, odour and temperature. In general,
organic wastes such as sewage, addition of nutrients, drinking water to have good physical qualities if it is clear,

Copyright to IARJSET DOI 10.17148/IARJSET.2016.3834 189


IARJSET ISSN (Online) 2393-8021
ISSN (Print) 2394-1588

International Advanced Research Journal in Science, Engineering and Technology


ISO 3297:2007 Certified
Vol. 3, Issue 8, August 2016

tastes good, has no smell and is cool. Physical [4] Manoj Kumar, Avinash Pun, “A review of permissible limits of
drinking water”, Indian J. Occup. Environ. Med., Jan-April, 16(1),
contaminants generally do have not direct health effects PP.40-44, 2012.
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[10] WHO, Guidelines for drinking water, Vol. 1, Recommendations,
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„limit‟ above which most consumers complain (WHO). At [11] Szabo, J. and Hall, J., Detection of contamination in drinking water
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[12] http://www.env.gov.bc.ca/wat/wq/BCguidelines/temptech/temperat
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temperature on water treatment processes is controlled by [13] Pangborn, R.M. and Bertolero, L.I. Influence of temperature on
altering the amounts of chemicals used in treatment; low taste intensity and degree of liking of drinking water. J. Am. Water
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[16] Minnesota river basin data center, 2008,
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parasites and some bacteria. Since pathogens are the main [17] Protocol for turbidity TMDL development March 2008,
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of water. Lower the pH value higher is the corrosive temperature on the coagulation of color-causing organic compounds
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low pH (lower than 4.5) values are unsuitable for most Management, Tata McGraw-Hill Education, 1987.
aquatic organisms. Aquatic organisms are extremely [21] Lan gelier, W.F. Effect of temperature on the pH of natural waters.
J. Am. Water Works Assoc., 38: 179, 1946.
sensitive to pH levels below 5 and may die at these low
[22] Rao, A.S., Marshall, S., Gubbi, J., Palaniswami, M., Sinnott, R. and
pH values. High pH levels (9-14) can harm fish due to the Pettigrove, V. , “Design of Low-Cost Autonomous Water Quality
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22-25, August 2013, 14-19.
and 8.0 at 25°C. DO is supplied to water through several [23] P.A.Araoye,” The seasonal variation of pH and dissolved oxygen
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concentration of dissolved oxygen is affected by plant
activity, temperature, decaying organic matter in water, BIOGRAPHY
stream flow, altitude/atmospheric pressure and human
activities. Vijay S. Kale (M.Sc, M.Phil, Ph.D,
PGDIM, ADCSSA) is working as
ACKNOWLEDGMENT Associate Professor, Department of
Electronic science, KTHM College,
This research is supported by the Principal, Dr. R. D. Nashik, Maharashtra, India. He has been
Darekar and Head, Department of Electronic Science, Dr. in the teaching profession (UG and PG)
M. B. Matsagar of KTHM College, Nashik, Maharashtra, since 28 years. He has been presented
India. research paper in international
conferences (USA, Bangkok). He published research
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