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Merck Photocatalysis Chart

The document summarizes the electrochemical series of photocatalysts and common organic compounds. It lists the excited state oxidation and reduced state reduction potentials of various photocatalysts such as ruthenium and iridium complexes, as well as organic dyes. The potentials are given versus saturated calomel electrode (SCE). Key photocatalysts included are ruthenium bipyridine, ruthenium phenanthroline, and iridium ppy complexes. Common organic compounds listed are triphenylpyrylium, eosin Y, mesitylacridinium, and fluorescein. The potentials provide information about the photoinduced electron transfer driving forces and redox properties of the photoc

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Ragav G
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3K views

Merck Photocatalysis Chart

The document summarizes the electrochemical series of photocatalysts and common organic compounds. It lists the excited state oxidation and reduced state reduction potentials of various photocatalysts such as ruthenium and iridium complexes, as well as organic dyes. The potentials are given versus saturated calomel electrode (SCE). Key photocatalysts included are ruthenium bipyridine, ruthenium phenanthroline, and iridium ppy complexes. Common organic compounds listed are triphenylpyrylium, eosin Y, mesitylacridinium, and fluorescein. The potentials provide information about the photoinduced electron transfer driving forces and redox properties of the photoc

Uploaded by

Ragav G
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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Electrochemical Series of Photocatalysts and Common Organic Compounds

Excited State Oxidations Reduced State Reductions


E* (V vs SCE))

N 2+ 2+ 1+
N 2+ F F 2+ 1+
Me N 2+
N N Br Br N N
N N N N N N
HO O O HO O O N
BF4- N 2+ N N N N N N N N N
2+ 2+ N 3+ N 2+ N 2+ N 3+ N 3+ N
Ru Ru Ru Me Me
Ir Ru Ru Ir Ir
N N Br Br F F
N N N N N N N N N
O N CO2H CO2H
N N N N N N
N N N N tBu N
N N N
N F F Me ClO - N
N 4
tBu
Triphenylpyrylium Ru(bpz)32+ = Ru(II) Ru(bpm)32+ = Ru(II) Eosin Y Ru(bpy)32+ = Ru(II) f ac-Ir(dF-ppy)33+ = Ir(III) Mes-Acr+ Ru(bpm)32+ = Ru(II) Fluorescein Ru(phen)32+ = Ru(II) Ir(ppy)2(dtbpy)3+ = Ir(III) f ac-Ir(ppy)33+ = Ir(III)
Et (S*/S ) 2.3V (T1) Ru(II)*/Ru(I) = 1.45V Ru(II)*/Ru(I) = 0.99V Ru(II)*/Ru(I) = 0.77V Ir(III)/Ir(II) = -2.11V Ru(II)*/Ru(I) = 0.99V Ru(II)*/Ru(I) = 0.82V Ir(III)*/Ir(II) = 0.66V Ir(III)*/Ir(II) = 0.31V
Et (S*/S ) 0.79V Et (S*/S ) 2.06V Et (S*/S ) 0.78V
Eo (S/S ) -0.35 V Ru(II)*/Ru(III) = -0.26V Ru(II)*/Ru(III) = -0.21V Ru(II)*/Ru(III) = -0.81V Ir(IV)/Ir(III) = 1.18V Ru(II)*/Ru(III) = -0.87V Ir(III)*/Ir(IV) = -0.96V Ir(III)*/Ir(IV) = -1.73V
Eo (S/S ) -1.06V Eo (S/S ) -0.57V Ru(II)*/Ru(III) = -0.21V Eo (S/S ) -1.27V
Ru(II)/Ru(I) = -0.80V Ru(II)/Ru(I) = -0.91V lmax Ru(II)/Ru(I) = -1.33V lmax 347 nm Ru(II)/Ru(I) = -0.91V Ru(II)/Ru(I) = -1.36V Ir(III)/Ir(II) = -1.51V Ir(III)/Ir(II) = -2.19V
lmax 417 nm 539 nm lmax 528 nm
Ru(III)/Ru(II) = 1.69V Ru(III)/Ru(II) = 1.29V lmax 430 nm Ir(IV)/Ir(III) = 0.77V
Ru(III)/Ru(II) = 1.86V Ru(III)/Ru(II) = 1.69V Ru(III)/Ru(II) = 1.26V Ir(IV)/Ir(III) = 1.21V
lmax 454 nm lmax 452 nm lmax 454 nm lmax 422 nm lmax 380 nm lmax 375 nm
lmax 443 nm

I O
Me N
OMe Me N3 Ph Me
H
S N -2.14V
S Me Me O -1.16V N O
NH2 O O2N O
2.28V Ph O -2.08V
2.15V 0.98V F3C S Cl Ph OH
1.81V Me 1.76V 1.21V -0.83V
1.63V O -0.45V Ph H -2.24V
Et3N -0.18V -1.93V
0.96

+2.5 +2.0 +1.5 O +1.0 +0.5 0 0 -0.5 -1.0 -1.5 -2.0 -2.5
Me
Ph - Br
O Me
1.60V
1.24V O CF3I N
O Ph Br O I
O O -1.22V -1.71V -1.76V Cl -2.30V -2.33V
Br -0.85V
2.30V Ph
-0.49V
-2.09V

1+ 1+ 1+
F F 1+ N 2+ F F F F
Me CF3 2+ CF3
2+ Br Br
HO O O N N N HO O O N
N N N N N
N N 3+ 3+ BF4- N 2+ N N 2+ N N 3+ N N 3+ N
Me Me F3C
3+ N 2+ N Ir Ir F3C
Ir Ru Br Br Ru Ir Ir
F Ru N F F F
N CO2H N N CO2H N N N
N N N N O
N tBu N N N N N N
N tBu N tBu
Me ClO - F F F F
4 N
tBu tBu
tBu
Mes-Acr+ Fluorescein Eosin Y
Ru(phen)32+ = Ru(II) Ir(ppy)2(dtbpy)3+ = Ir(III) f ac-Ir(ppy)33+ = Ir(III) Triphenylpyrylium Ru(bpz)32+ = Ru(II) Ru(bpy)32+ = Ru(II) Ir(dF-CF3-ppy)2(dtbpy)3+ = Ir(III) f ac-Ir(dF-ppy)33+ = Ir(III)
Ir(dF-CF3-ppy)2(dtbpy)3+ = Ir(III)
Et (S*/S ) 2.06V Ru(II)*/Ru(I) = 0.82V Et (S*/S ) 0.78V Ir(III)*/Ir(II) = 0.66V Ir(III)*/Ir(II) = 0.31V Ru(II)*/Ru(I) = 1.45V Et (S*/S ) 0.79V Ru(II)*/Ru(I) = 0.77V Ir(III)*/Ir(II) = 1.21V Ir(III)/Ir(II) = -2.11V
Ir(III)*/Ir(II) = 1.21V Et (S*/S ) 2.3V (T1)
Eo (S/S ) -0.57V Ru(II)*/Ru(III) = -0.87V Eo (S/S ) -1.27V Ir(III)*/Ir(IV) = -0.96V Ir(III)*/Ir(IV) = -1.73V Ru(II)*/Ru(III) = -0.26V Eo (S/S ) -1.06V Ru(II)*/Ru(III) = -0.81V Ir(III)*/Ir(IV) = -0.89V Ir(IV)/Ir(III) = 1.18V
Ir(III)*/Ir(IV) = -0.89V Eo (S/S ) -0.35 V
lmax 430 nm Ru(II)/Ru(I) = -1.36V lmax 528 nm Ir(III)/Ir(II) = -1.51V Ir(III)/Ir(II) = -2.19V Ru(II)/Ru(I) = -0.80V lmax 539 nm Ru(II)/Ru(I) = -1.33V Ir(III)/Ir(II) = -1.37V lmax 347 nm
Ir(III)/Ir(II) = -1.37V lmax 417 nm
Ru(III)/Ru(II) = 1.26V Ir(IV)/Ir(III) = 1.21V Ir(IV)/Ir(III) = 0.77V Ru(III)/Ru(II) = 1.86V Ru(III)/Ru(II) = 1.29V Ir(IV)/Ir(III) = 1.69V
Ir(IV)/Ir(III) = 1.69V
lmax 380 nm lmax 422 nm lmax 380 nm lmax 375 nm lmax 452 nm lmax 380 nm
lmax 443 nm

E* (V vs SCE))
Common Oxidizing Agents Common Reducing Agents

F F S2O 8 MnO4 Br Br O O OH
Ag S2O42-
Fluorine = 2.62V (2e-) - HO
persulfate = 1.85V (2e-) permanganate = 1.43V (4e ) - silver(I) = 0.6V O dithionite = -0.77V Magnesiumo = -2.62V (2e-)
oxygen = 0.99V (4e ) H
N Cl CN O
SO4 H2O2 O Sm(II)I2 = -1.65V (2e-) Sodiumo = -2.95V
(NH4)2[Ce(NO3)6] HO
persulfate= 2.36V hydrogen peroxide = 1.45V (2e-) Cl CN OH Lithiumo = -3.28V
CAN = 0.96V
O ascorbic acid = -0.19V (2e-) Irono = -0.65V (2e-) Zinco = -1.00V (2e-)
HOCl
Hypochlorite = 1.39V Br
DDQ = 0.53V
TBPA = 1.05V Copper(II)= 0.28V (1e-)
compiled by D. DiRocco 2014

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