Statistical Physics
Statistical Physics
Contents
1Statistical mechanics
o 1.1Quantum statistical mechanics
2Scientists and universities
3Achievements
4See also
5Notes
6References
7Further reading
Statistical mechanics[edit]
Statistical mechanics
Thermodynamics
Kinetic theory
Particle statistics[show]
Thermodynamic ensembles[show]
Models[show]
Potentials[show]
Scientists[show]
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Main article: Statistical mechanics
Statistical mechanics provides a framework for relating the microscopic properties of
individual atoms and molecules to the macroscopic or bulk properties of materials that
can be observed in everyday life, therefore explaining thermodynamics as a natural
result of statistics, classical mechanics, and quantum mechanics at the microscopic
level. Because of this history, statistical physics is often considered synonymous with
statistical mechanics or statistical thermodynamics.[note 1]
One of the most important equations in statistical mechanics (akin to in Newtonian
mechanics, or the Schrödinger equation in quantum mechanics) is the definition of
the partition function , which is essentially a weighted sum of all possible
states available to a system.
where is the Boltzmann constant, is temperature and is energy of state .
Furthermore, the probability of a given state, , occurring is given by
Here we see that very-high-energy states have little probability of occurring, a
result that is consistent with intuition.
A statistical approach can work well in classical systems when the number
of degrees of freedom (and so the number of variables) is so large that the exact
solution is not possible, or not really useful. Statistical mechanics can also
describe work in non-linear dynamics, chaos theory, thermal physics, fluid
dynamics (particularly at high Knudsen numbers), or plasma physics.
Although some problems in statistical physics can be solved analytically using
approximations and expansions, most current research utilizes the large
processing power of modern computers to simulate or approximate solutions. A
common approach to statistical problems is to use a Monte Carlo simulation to
yield insight into the properties of a complex system.
Quantum statistical mechanics[edit]
Quantum statistical mechanics is statistical mechanics applied to quantum
mechanical systems. In quantum mechanics a statistical ensemble (probability
distribution over possible quantum states) is described by a density operator S,
which is a non-negative, self-adjoint, trace-class operator of trace 1 on
the Hilbert space H describing the quantum system. This can be shown under
various mathematical formalisms for quantum mechanics. One such formalism is
provided by quantum logic.