Nand Foundation Academy, shegaon

JEE CELL
Chemistry
Total Questions : 50 Total Marks : 50
Roll No.
10-Oct-2019
XII - A Div 10:00 AM To 12:00 PM
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Note :
i) All Questions are compulsory
ii) Darken ( ) the appropriate circle(#) of the most correct option/response with black ball point pen.

States Of Matter

1) Ten grams of a gas occupies 2 L at N.T.P. At 5) A gas occupies a volume of 250 ml at 700 mm
what temperature will the volume of the same Hg pressure and 25◦ C. What additional
quantity of a gas become double at the same pressure is required to reduce the gas volume
pressure ? to its 4/5th value at the same temperature ?

A) 273 K B) −273◦ C C) 546 K D) 546◦ C A) 225 mm Hg B) 175 mm Hg

2) At what temperature in the Celsius scale, V

C) 150 mm Hg D) 265 mm Hg
(volume) of a certain mass of gas at 27◦ C will
be doubled keeping the pressure constant ? 6) From a porous vessel containing equimolar
proportions of hydrogen and oxygen, the
A) 54◦ C B) 327◦ C C) 427◦ C D) 527◦ C. composition by mass of the mixture effusing
out is : hydrogen and oxygen in the ratio of
3) Equal weights of two gases of molecular mass
4 and 40 are mixed. The pressure of the mixture √
A) 1 : 4 B) 2 2 : 1
is 1.1 atm. The partial pressure of the lighter
gas in this mixture is √
C) 1 : 2 2 D) 4 : 1.
A) 0.55 atm B) 0.11 atm 7) The volume occupied by 0.25 mol of an ideal
gas at S.T.P. is :
C) 1.0 atm D) 0.1 atm.
A) 89.6 L B) 11.2 L C) 5.6 L D) 22.4 L.
4) A gaseous mixture was prepared by taking
equal mole of CO and N2 . If the total pressure 8) The volume of NH3 obtained by the
of the mixture was found 1 atmosphere, the combination of 10 mL of N2 and 30 mL of H2 is
partial pressure of the nitrogen (N2 ) in the
mixture is A) 20 mL B) 40 mL C) 30 mL D) 10 mL

A) 0.5 atm B) 0.8 atm 9) 3.2 g of oxygen and 0.2 g of hydrogen are
placed in a 1.12 L flask at 0◦ C. The total
C) 0.9 atm D) 1 atm pressure of the gas mixture will be
 A) 1 atm B) 4 atm C) 3 atm D) 2 atm. A) 3 B) 2 C) 6 D) 4

10) A litre of gas is measured at 27◦ C. What volume 17) If the root mean square speed of helium is 4.75
will it occupy at −23◦ C ? m s−1 at 25◦ C, then its speed will become 9.50
m s−1 at
A) 1200 ml B) 1800 ml
A) 100◦ C B) 323◦ C C) 919◦ C D) 1192◦ C.
C) 883 ml D) 167 ml
18) 50 ml of hydrogen diffuses through a small hole
11) The ratio of the rate of diffusion of helium and from a vessel in 20 minutes. Time taken for 40
methane under identical conditions of pressure ml of oxygen to diffuse under similar conditions
and temperature will be : will be

A) 4 B) 2 C) 1 D) 0.5 A) 12min B) 64min C) 8 min D) 32min.

12) At what temperature, will the rms velocity of a 19) The vapour density of a mixture containing NO2
gas at 50◦ C be doubled? and N2 O4 is 38.3 at 26.7◦ C. The number of
moles of NO2 in 100 g mixture is
A) 626 K B) 1019 K C) 200◦ C D) 1019◦ C
A) 0.437 B) 8.2 C) 3.62 D) 4.62
13) 0.6 L of an ideal gas weighs 1.80 g at 27◦ C and
1 atm pressure. ts approximate molar mass is : 20) A what temperature, the rate of effusion of N2
would be 1.625 times that of SO2 at 50◦ C ?
A) 36.9 B) 72.0 C) 147.6 D) 369
A) 135 K B) 373 K C) 546 K D) 303 K
14) The molecular velocity of any gas is :
21) 160 ml of a gas are collected over water at 25◦ C
A) inversely proportional to absolute and 768.8 mm Hg. If aqueous tension at 25◦ C is
temperature 23.8 mm Hg, then pressure of dry gas at 25◦ C is
:
B) directly proportional to square of
temperature A) 76.8 mm Hg B) 760mmHg

C) directly proportional to square root of C) 721.2 mm Hg D) 600mmHg.

temperature
22) For an ideal gas, number of moles per litre in
terms of its pressure p, gas constant R and
D) inversely proportional to the square root of temperature T is :
temperature

15) 56 g of N2 (molar mass = 28) are mixed with 44 A) pT/R B) pRT C) p/RT D) RT/p.
g of CO2 (molar mass = 44) and the pressure of
23) A 10 L flask at 300 K contains a gaseous
the resulting gaseous mixture is 3 atm. The
mixture of CO and CO2 at a total pressure of 2.0
partial pressure of N2 in the mixture is :
atm. If 0.2 mol of CO is present, the partial
pressure of CO2 is (Use R = 0.082 L atm
A) 1 atm B) 1.5 atm mol−1 K−1 )

C) 2 atm D) 3 atm. A) 0.49 atm B) 1.49 atm

16) At same temperature and pressure,
√ the rate of
diffusion of hydrogen gas is 3 3 times that of a C) 1.51 atm D) 2.49 atm.
hydrocarbon having molecular formula,
24) Which of the following statements is not correct
Cn H2n−2 The value of n is
?
 31) The compressibility factor for a real gas at high
A) Light gases diffuse faster than heavier
pressure is :
gases.
A) 1 − pb/RT B) 1 + RT/pb
B) The volume of a gas always increases when
the temperature increases.
C) 1 D) 1 + Pb/RT
C) Molecules of different gases have the same 32) Two gases A and B having the same volume
average kinetic energy at given temperature. diffuse through a porous partition in 20 and 10
seconds respectively. The molecular mass of A
D) Hydrogen molecules diffuse faster in a is 49 u. Molecular mass of B will be :
vacuum than in air
A) 50.00 u B) 12.25 u
25) At S.T.P. the density of nitrogen monoxide is :
C) 6.50 u D) 25.00 u.
A) 3.0 g L−1 B) 30 g L−1
33) Vapour densities of O2 and CH4 are 32 and 16
C) 1.34 g L−1 D) 2.68 g L−1 respectively. The ratio of rate of diffusion of
CH4 to that of O2 is
26) When the pressure and absolute temperature of
5 L nitrogen are doubled, the gas would have a √ √
A) 2 =1 B) 1 : 2 C) 2 : 1 D) 1 : 2
volume of :
34) The pressure of 2 moles of an ideal gas at
A) 10 L B) 5 L C) 15 L D) 20L. 273◦ C occupying a volume of 44.8 L is :

27) Two separate bulbs contain ideal gases A and B

A) 2 atm B) 1 atm C) 3 atm D) 4 atm
respectively. The density of gas A is twice that
of gas B and the molar mass of gas A is half 35) The temperature of an ideal gas is increased
that of gas B. If the two gases are at the same from 140 K to 560 K. If at 140 K, the root mean
temperature, the ratio of pressure of A to that of square velocity of the gas is x, at 560 K it
B is : becomes

A) 4 B) 2 C) 1/4 D) 1/2 A) 5x B) 4x C) 2x D) x/2

28) The relative rates of diffusion of sulphur 36) If 1000 ml of a gas A at 600 torr and 500 ml of
dioxide (molar mass = 64) and helium (at. mass gas B at 800 torr are placed in a 2 L flask, the
= 4) at the same temperature and pressure are : final pressure will be

A) 16 : 1 B) 1 : 4 C) 8 : 1 D) 1 : 8. A) 500 torr B) 1000 torr

29) Which of the following molecules will have the
C) 850 torr D) 200 torr.
highest r.m.s. velocity at 27◦ C ?
37) At constant temperature, if pressure increases
A) H2 B) O2 C) CH4 D) NO2 by 1%, the percentage decrease of volume is :
30) If Z is the compressibility factor, van der Waals
A) 1% B) 100/101%
equation at low pressure can be written as
RT a C) 1/101% D) 1/100%
A) Z = 1 + B) Z = 1 −
pb VRT
38) The average velocity at T1 K and the most
pb pb
C) Z = 1 − D) Z = 1 + probable velocity at T2 K of CO2 gas is
RT RT 9.0 × 104 cms−1 .The values of T1 and T2
respectively are
 45) If 4 g of O2 diffuse through a very narrow hole,
A) 1682.5,2042 B) 896,2143
how much H2 would have diffused under
identical conditions ?
C) 1682.5,2143 D) 1896,2243

39) A gas at 10◦ C occupies a volume of 283 ml. If it A) 1 g B) 1/4g C) 16 g D) 64 g.

is heated to 20◦ C keeping the pressure
46) The temperature at which the r.m.s. velocity of
constant, the new volume will be
gas molecules is double than that at 27◦ C is :

A) 293 ml B) 283 ml C) 566 ml D) 586 ml.

A) 108◦ C B) 927◦ C C) 327◦ C D) 54◦ C.
40) At identical temperature and pressure,
√ the rate
47) The relative rate of diffusion of a gas (molar
of diffusion of hydrogen gas is 3 3 times that
mass = 128) as compared to oxygen is :
of a hydrocarbon having molecular formula
Cn H2n−2 What is the value of n?
A) 2 times B) 1/4th C) 1/8 th D) 1/2.
A) 1 B) 4 C) 3 D) 8 48) What is the molar mass of a gas whose density
is 1.5 g L−1 at 27◦ C and 1 atm pressure ? (Use
41) The units of constant "a" in van der Waals
R = 0.08 L atm mol−1 K−1 )
equation is :
A) 360 B) 720 C) 36 D) 18
A) dm6 atm mol−2 B) dm3 atm mol−1
49) Two samples of gases A and B are at the same
C) dm atm. mol−1 D) atm mol−1 . temperature. The molecules of A are travelling
4 times faster than molecules of B. The ratio
42) The mean free path of a gas at 1 atm pressure MA / MB of their masses will be
is l. Its mean free path at 5 atm pressure will be
A) 16 B) 1/16 C) 4 D) 11/4.
A) 5 l B) l/5 C) 25 l D) 0.04 l
50) A cylinder of V litre capacity containing NH3
43) For gaseous state, if most probable speed is gas is inverted over another vessel of V litre
denoted by C∗ , average speed by C and mean capacity containing HCl gas at same
square speed by C, then for a large number of temperature and pressure. After some time the
molecules the ratios of these speeds are : pressure in cylinder will :

A) C∗ : C : C = 1.225 : 1.128 : 1 A) become double

B) C∗ : C :C = 1.128: 1.225: 1 B) remain same

C) C∗ : C : C = 1 : 1.128: 1.225 C) drop considerably

D) C∗ : C : C = 1:1.225:1.128 D) become 3/2 of original pressure

44) As the temperature is raised from 20◦ C to 40◦ C,
the average kinetic energy of neon atoms
changes by a factor of which of the following ?
p
A) 313/293 B) 313/293

C) 1/2 D) 2
 Answer Sheet

Chemistry : States Of Matter

Total Questions : 50 Total Marks : 50

1 C 2 B 3 C 4 A 5 B 6 D 7 C 8 A 9 B 10 C 11 B 12 D
13 B 14 C 15 C 16 D 17 C 18 B 19 A 20 B 21 C 22 C 23 C 24 B
25 C 26 B 27 A 28 B 29 A 30 B 31 D 32 B 33 A 34 A 35 C 36 A
37 C 38 C 39 A 40 B 41 A 42 B 43 C 44 A 45 C 46 B 47 D 48 C
49 B 50 C
 Solution Sheet

Chemistry : States Of Matter

Total Questions : 50 Total Marks : 50

V1 V
1) = 2 7) Volume occupied by 1 mol of gas at S.T.P.
T1 T2
(Charles law) = 22.4 L
4L × 273 Volume occupied by 0.25 mol of gas at S.T.P.
T2 = = 546K = 22.4 × 0.25 = 5.6 L
2L
V1 V
2) = 2 at constant pressure 8) N2 (g) + 3H2 (g) −→ 2NH3 (g)
T1 T2
V 2V 1 vol 3 vol −→ 2 vol
= 10 mL 30 mL−→ 20 mL
300 T2
or T2 = 300 × 2 = 600 3.2
9) Moles of O2 = = 0.1
or = 600−273 = 327◦ C 32
0.2
W Moles of H2 = = 0.1
3) Moles of lighter gas= 2
4 nRT
W Pressure, p =
Moles of heavier gas= V
40 0.2 × 0.082 × 273
Mole fraction of lighter gas = =4 atm
W/4 1.12
= = 10/11 V V
W/4 + W/40 10) 1 = 2
Partial pressure of lighter gas T1 T2
V T
= Mole fraction x Total pressure or V2 = 1 2
10 T1
= × 1.1 = 1.0 atm 1000 × 250
11 =
300
=883 ml
s r
r (He) M (CH4 ) 16
4) n (CO) = n (N2 ) 11) r = = =2
p (CO) = p (N2 ) =1 atm (CH4 ) M (He) 4
√
r
1 3RT
Mole fraction of N2 , xN2 = = 0.5 12) ur.m.s = ∴ ur.m.s ∝ T
1+1 M
p (N2 ) = p × xN2 =1 × 0.5 = 0.5 atm. For ur.m.s to be doubled, temperature must be
raised by 4 times.
5) V1 = 250 ml., P1 = 700 mm Hg
4 T = (50 + 273) K = 323 K
V2 = 250 × ∴ 4T = 4 × 323 K= 1292 K
5
=200 mL.,P2 =? = (1292−273) C = 1019◦ C.
According to Boyle"s law, mRT 1.80 × 0.08 × 300
13) M = = = 72
P1 V1 = P2 V2 pV 1 × 0.6
250 × 700 √
or P2 = =875 mm Hg 14) Molecular velocity ∝ T
200
Additional pressure required 56
15) Moles of N2 = =2
= 875−700 28
= 175 mm Hg 44
Moles of CO2 = =1
RateofeffusionofH2 44
6) Mole fraction of
RateofeffusionOr 2 2 2
N2 = =
Mass (H2 ) /t 32 2+1 3
= = Partial pressure of
Mass (O2 ) /t 2
MassofH2 4 2
= N2 = × 3 =2 atm
MassofO2 1 3
or 4 : 1
 s
r (H2 ) M (hydrocarbon) 22) pV = nRT
16) = n p
r (hydrocarbon) M (H2 ) =
√
r
M (hydrocarbon) v RT
3 3= ∴ No. of moles per litre = p/RT
2
√ 2 23) p = p(CO) + p(CO2 ) = 2.0 atm
M (hydrocarbon) = 3 3 × 2 = 54 0.2 × 0.082 × 300
For Cn H2n−2 , 12n + (2n − 2) = 54 p (CO) =
10
or n = 4 p(CO2 ) = 2 − 0.49 = 1.51 atm.
√
17) r.m.s. speed ∝ T 24) This is true only when pressure is constant.
r
4.75 298
= 25) 30/22.4 = 1.34 g L−1
9.50 T
4.75 2 298

26) p1 = p,
or =
9.50 T p2 = 2p,
or T = 1192 K T1 = T,
or T = 1192−273 =919◦ C T2 = 2T,
r
r (H2 ) 50/20 32 V1 = 5L,
18) = = V2 =?
r (O2 ) 40/t 2
50 t P1 V1 P V
or × =4 = 2 2
20 40 T1 T2
4 × 20 × 40 p1 V1 T2
or t = =64min or V2 =
50 T1 p 2
p × 5 × 2T
19) Molecular weight of mixture = = 5L
T × 2p
= 2 × vapour density
= 2 × 38.3 = 76.6
Let the mixture contains x of NO2 and (100−x) g dRT
27) p =
of N2 O4 M
x dx RT
Moles of NO2 = px =
46 Mx
100 dy RT
Moles of mixture= py =
76.6 My
Now, moles of NO2 and N2 O4 = Moles of px dx dy 2
mixture = = =4
x 100 100 py Mx My 1
+ = 2
46 92 76.6 r
100−92 r (SO2 ) 4 1
2x + 100−x = 28) = =
76.6 r (He) 64 4
100−x = 120.1
x = 120.1−100 = 20.1 29) Root mean square velocity is inversely
20.1 proportional to mass.
∴ Moles of NO2 = = 0.437
v46 Therefore, hydrogen having lowest mass will
u 3RT (N ) have highest r.m. s. velocity.
u 2
r (N2 ) u
28
20) = 1.625 = tu
r (SO2 ) 3R × 323
r 64
16 × T (N2 )
1.625 =
7 × 323
∴ T (N2 ) = 373K
21) Pressure of dry gas
= Pressure of gas collected over water −
Aqueous tension
= 745−23.8 =721.2 mm
 pV
30) Compressibility factor (Z)= 36) Applying Boyle"s law,
RT
For one mole of a real gas van der Waals Pressure of gas A in 2L flask
equation 1000 × 600
= =300 torr.
 a  2000
p + 2 (V − b) = RT Pressure of gas B in 2L flask
V
At low pressure 500 × 800
= =200 torr.
V
 −b a≈V (b can be neglected) 2000
Total pressure = 300 + 200 = 500 torr
p + 2 V = RT
V
a 37) Let p1 = 100 mm Hg.
pV + = RT
V Increase in pressure
a 1
pV = RT − = 100 × =1
V 100
pV a p2 = 100 + 1 = 101 mm Hg
= 1−
RT VRT Let V1 = V and V2 = ?
a
∴ Z = 1− p1 V1 = p2 V2
VRT
p V 100 × V 100
31) van or V2 = 1 1 = = V
 der a 
Waals equation is : p2 101 101
p + 2 (V − b) = RT 100
V V− V
a Decrease in volume = 101
At high pressure, 2 can be neglected so that V
V  
p(V − b) = RT 100
1−
pV − pb = RT 101
pV pb =V =1/101%
or − =1 V r
RT RT 8RT
pV pb pb 38) Average volocity =
or = 1+ ∴ z = 1+ πM
RT r RT RT Most probable velocity =
r MB Average velocity at, T1 K
32) A =
rB MA
r = Most Probable velocity at T2 K
V/20 MB 9.0 × 104 cms−1
=
V/10r 49 R = 8.314 × 107 ergs K−1 moL−1 ,
1 MB M
= s = 44 Averae velocity at T1 K
2 49 8 × 8.13 × 107 × T1
1 = 9.0 × 104
∴ MB = 49 × = 12.25 3.14 × 44
s 4
r (CH4 ) d (O2 )
r
32 √ 81 × 108 × 3.143 × 44
33) = = = 2:1 T1 =
r (O2 ) d (CH4 ) 16 8 × 8.314 × 107
= 1682.5 Kr
nRT 2 × 0.082 × 546 2 × 8.314 × 107 × T2
34) p = = =2 atm Similarly, = 9.0 × 104
V 44.8 44
35) r.m.s. r
speed at 140 K = x 81 × 108 × 44
T2 =
3R × 140 2 × 8.314 × 107
∴x= = 2143 K.
Mr
3R × 560
at, 560K, x0 =
M 39) V1 = 283 ml,
x0
r
560 T1 = 273 + 10 = 283 K
= =2
x 140 V2 = ?
0
x =2
T2 = 273+ 20 = 293 K
At constant P,
V1 V
= 2
T1 T2
V T
or V2 = 1 2
T1
283 × 293
V2 = = 293ml
283
 s
rH2 MHydrocarbon √
40) = =3 3
rHydrocarbon MH2
r
MHydrocarbon √
∴ =3 3
2
MHydrocarbon
= 27
2
MHydrocarbon = 2 × 27 = 54
∴ n = 4 and hydrocarbon is C4 H6
41) Units of "a" =L2 atm. mol−2
1L = 1 dm3
Hence units of "a" = dm6 atm mol−2
1
42) Mean free path, l ∝
r r p r
2RT 8RT 3RT
43) C∗ = ,C = ,C =
M πM M
C∗ : C : C = 1 : 1.128: 1.225
44) Temp, changes from 293 K to 313 K.
Average K.E. ∝ T
KE (40◦ C) 313
∴ ◦
=
KE (20rC) 293
4g/t 2
45) =
x/t 32
(x is r
the amount of H2 diffused and t is the time)
4 1 1
= =
x 16 4
∴ x = 16 g
r r
3RT 3R × 300
46) =2
M M
or T = 1200 K = 927◦ C
r
r (gas) 32 1
47) = =
r (O2 ) 128 2
dRT 1.5 × 0.08 × 300
48) M = = = 36
r p 1
r MB
49) A =
rB r MA
MB
4=
r M A
MA 1
or =
MB 16
50) Because of the formation of solid NH4 Cl