Master JEE CLASSES

Kukatpally, Hyderabad.

IIT-JEE ADVANCED-2016-PAPER-II Max.Marks:186

2016_PAPER-II
IMPORTANT INSTRUCTIONS:
1) This booklet is your Question Paper.
2) Use the Optical Response Sheet (ORS) provided separately for answering the questions
3) Blank spaces are provided within this booklet for rough work.
4) Write your name, roll number and sign in the space provided on the back cover of this booklet.
5) You are allowed to take away the Question Paper at the end of the examination.
OPTICAL RESPONSE SHEET:
6) Darken the appropriate bubbles on the ORS by applying sufficient pressure. This will leave an impression
at the corresponding place on the Candidate’s sheet.
7) The ORS will be collected by the invigilator at the end of the examination.
8) Do not tamper with or mutilate the ORS. Do not use the ORS for rough work.
9) Write your name, roll number and code of the examination center, and sign with pen in the space
provided for this purpose on the ORS. Do not write any of these details anywhere else on the ORS. Darken
the appropriate bubble under each digit of your roll number.
DARKENING THE BUBBLES ON THE ORS
10) Use a BLACK BALL POINT PEN to darken the bubbles on the ORS.
11) Darken the bubble COMPLETELY.
12) The correct way of darkening a bubble is as:
13) The ORS is machine-gradable. Ensure that the bubbles are darkened in the correct way.
14) Darken the bubbles ONLY IF you are sure of the answer. There is NO WAY to erase or
“un-darken” a darkened bubble.
 JEE-ADVANCE-2016-P2-Model
Time: 3:00 hours IMPORTANT INSTRUCTIONS Max Marks: 186
PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 6) Questions with Single Correct Choice 3 -1 6 18
Questions with Multiple Correct Choice
Sec – II(Q.N : 7 – 14) 4 -2 8 32
(Partial Marking +1)
Questions with Comprehension Type
Sec – III(Q.N : 15 – 18) 3 0 4 12
(2 Comprehensions – 2 + 2 = 4Q)
Total 18 62
CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 19 – 24) Questions with Single Correct Choice 3 -1 6 18
Questions with Multiple Correct Choice
Sec – II(Q.N : 25 – 32) 4 -2 8 32
(Partial Marking +1)
Questions with Comprehension Type
Sec – III(Q.N : 33 – 36) 3 0 4 12
(2 Comprehensions – 2 + 2 = 4Q)
Total 18 62
MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 37 – 42) Questions with Single Correct Choice 3 -1 6 18
Questions with Multiple Correct Choice
Sec – II(Q.N : 43 – 50) 4 -2 8 32
(Partial Marking +1)
Questions with Comprehension Type
Sec – III(Q.N : 51 – 54) 3 0 4 12
(2 Comprehensions – 2 + 2 = 4Q)
Total 18 62
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PHYSICS Max Marks: 62
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 6 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and –1 in all other cases.
1. The displacement of two identical particles executing SHM are represented by equations
x1  4sin 10t   / 6  and x2  5cos t .For what value of  energy of both the particles is
same? (At the mean position potential energy is taken as zero].
A) 16 units B) 6 units C) 4 units D) 8 units
2 A particle is performing SHM. Its amplitude is 5 m and time period of oscillation is 4 s.
The minimum time taken by the particle to move from point A to B is (O is mean
position E1 and E2 are extreme positions)

E1 O A B E2
3m
4m
A) 0.12 s B) 0.16 s C) 0.18 s D) 0.19 s.
3. The mass of the astronauts in a space station cannot be checked with the scales used on
the Earth. Instead we use a spring balance, which oscillates when a mass is suspended
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 from it. Imagine a seat of a mass of 20 kg, which oscillates with a frequency of 2Hz.
After the astronaut sits in the seat the frequency decreases to 1 Hz. How much is the
mass of the astronaut?
A) 40kg B) 60 kg C) 80 kg D) 100 kg
4. A particle performs simple harmonic motion on y-axis with amplitude A and time
period T. The time taken by the particle to travel a distance A/5 starting from rest is
T 4 T 1 T 1
A) T B) cos 1   C) cos 1   D) sin 1  
20 2 5 2 5 2 5

5. A particle of mass m is located at a place where it is acted upon by a one dimensional

conservative force and its potential energy is given by:
U  x   A 1  cos px  , where A and p are constants. The period of small oscillations of the

particle is:
m m
A) 2 B) 2
 Ap   Ap 2 
m 1 Ap
C) 2 D)
A 2 m

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6. The displacement x of a particle in motion is given in terms of time by
x  x  4   1  5cos t

A) The particle executes SHM

B) The particle executes oscillatory motion which is not SHM
C) The motion of the particle is neither oscillatory nor simple harmonic
D) The particle is not acted upon by a force when it is at x  4
SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -2 in all other cases
7. The x-coordinate of a particle moving on x-axis is given by x  3sin100t  8cos 2 50t
where x is in cm and t is time in seconds. Which of the following is/are correct about
this motion.
A) The motion of the particle is not S.H.M
B) The amplitude of the S.H.M of the particle is 5 cm
C) The amplitude of the resultant S.H.M is 73 cm
D) The maximum displacement of the particle from the origin is 9 cm

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8. A particle is executing SHM with a time period T and amplitude A. At t = 0
displacement of the particle was +A/2 and it was moving away from the mean position.
  
x, v and a are the displacement from the mean position, velocity and acceleration of the
particle at any instant. Choose the correct statement(s).
 
A) at t  T / 4,a.v  0 B) at t  T / 4, x.v  0
 
C) at t  T / 2,a.v  0 D) at t  T / 2, x.v  0

9. A coin is placed on a horizontal platform, which undergoes vertical simple harmonic

motion of angular frequency  . The amplitude of oscillation is gradually increased. The
coin will leave contact with the platform for the first time
A) at the highest position of the platform

B) at the mean position of the platform

C) for an amplitude of g /  2

D) for an amplitude of g /

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10. A particle is executing SHM between points  X m and X m , as shown in figure – 1. The
velocity V (t) of the particle is partially graphed and shown in figure – II. Two points A
and B corresponding to time t1 and time t2 respectively are marked on the V (t) curve,

B
t1
+x
 Xm O Xm t2 t

Figure – I Figure – II
A) At time t1 , it is going towards  X m

B) At time t1 , its speed is decreasing

C) At time t2 , its position lies in between  X m and O

D) The phase difference  between points A and B must be expressed as

90º    180º

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11. The potential energy of a particle of mass 0.1 kg, moving along x-axis under the action
of a single force, is given by U  5x  x  4  J where x is in metres. It can be concluded that
A) The particle is acted upon by a constant force
B) The speed of the particle is maximum at x = 2 m
C) The particle executes simple harmonic motion
D) The period of oscillation of the particle is  / 5s
12. In the given figure, the block is attached with a system of three ideal springs A,B,C. The
block is displaced by a small distance x from its equilibrium position vertically
downwards and released. T represents the time period of small vertical oscillations of
the block. Then (Pulleys are ideal)

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 A) T  2 11m
2K
B) The deformation of the spring A due to displacement of block is (2/11) times the
displacement of the Block
C) The deformation of the spring C due to displacement of block is (1/11) times the
displacement of the block
D) The deformation of the spring B due to displacement of block is (4/11) times the
displacement of the block
13. An ideal spring has natural length 40 cm and spring constant 500 N/m. A block of mass
1 kg is attached at one end of the spring and other end of the spring is attached to
ceiling. The block released from the position, where the spring has length 45 cm.
A) the block will perform SHM of amplitude 5 cm.

B) the block will have maximum velocity 30 5 cm / sec

C) the block will have maximum acceleration 15 m / s 2 .

D) the minimum potential energy of the spring will be zero.

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14. Two particles execute SHM with amplitudes A and 2A respectively and angular
frequencies  and 2 respectively. At t = 0 they start with some initial phase
2
difference. At, t  . They are in same phase. Their initial phase difference is:
3
 2 4
A) B) C) D) 
3 3 3
SECTION – III
(PARAGRAPH TYPE)
This section contains 2 groups of questions. Each group has 2 multiple choice questions based on a
paragraph. Each question has 4 choices A), B), C) and D) for its answer, out of which ONLY ONE is correct.
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases.
Paragraph For Questions 15 and 16
A disc of mass m and radius R is attached with a spring of force constant k at its centre
as shown in figure. At x  0 , the spring is unstretched. The disc is moved to x  A and
then released. There is no slipping between disc and ground. Let f be the force of
friction on the disc from the ground. Based on the information given, answer the
following questions.

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15. The f versus t (time) graph will be as
f

A) B)
f

C) D)

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16. If k  10 Nm 1, m  2 kg , R  1 m and A  2 m , then the linear speed of the disc at mean
position is
40 10 50
A) ms 1 B) 20 ms 1 C) ms 1 D) ms 1
3 3 3
Paragraph For Questions 17 and 18
A forced action on a block is F   4 x  8  , where F is in Newton and x the position of
block on x-axis in meters. The energy of oscillation is 18J. Based on the information
given, answer the following questions.
17. The motion of the block is
A) Periodic but not simple harmonic
B) Not periodic
C) Simple harmonic about origin, x  0
D) Simple harmonic about x  2 m
18. The block will oscillate between the points
A) x  0 and x  4 m B) x  1 m and x  5 m
C) x  2 m and x  6 m D) x  1 m and x  3 m

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 CHEMISTRY Max Marks: 62

SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 6 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and –1 in all other cases.
19. Which is incorrect product?
H 3C CH 3
Na / Liq.NH 3
CH 3  C  C  CH 3    C C
H (cis) H
A)
H 3C CH3
H2
CH 3  C  C  CH 3   
 Pd / BaSO 4
C C
H (cis) H
B)
CH3 CH3
H CH3
H Br Br H
 B
r2

Br H H Br
H CH3
CH3 CH3
cis -B u t-2 -e n e
(  ) -2 , 3 -D ib r om o b u ta n e
C)
CH3
H CH3
H Br
 B
r2

H Br
H 3C H
CH3
t r a n s -B u t-2 - e n e
M e s o -2 , 3 - d i b r o m o b u ta n e
D)
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 0
20. NBS ,500 C
CH 2  CH  CH 3 
CCl
 A .The chief product A is
4

Br
CH2
A) H 3C  CH  Br   CH 2  Br  B)

C) CH 2  C  Br   CH 2  Br  D) CH  Br   CH  CH 2  Br 
21. Which of the following reaction takes place by formation and rearrangement of
carbocation
(i) Hg(OAc)2, H2O
(A) R CH CH CH2
(ii) NaBH4
CH3

(i) BH3
(B) R CH CH CH2
(ii) H2O2
CH3

(C) CH3 C CH2 HX

CH3

(D) (i) HNO2

(ii)
OH NH2

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22. The major product of the following reaction would be

A) B) C) D)
(Assume solvent to be nonpolar)

excess
HCl


N

23. The most possible product of the above reaction is

Cl Cl

N N

A) Cl
B) Cl

OH Cl
Cl

N N

C) Cl D) Cl

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24. Hydrogenation of the adjoining compound in the presence of Na in liq. NH 3 Gives.
H3C H CH3
Na/liq.NH3
x is number of organic products obtained(including stereo isomers)
H
H3C

A) 2 B) 4 C) 5 D) 1
SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -2 in all other cases

Product (A) is not a

OH
D
H3C D H3C D
H

A) B) C) D)

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26.

Reagent
(A)

O
Reagent
(B) OH
OH

Reagent
(C)
O

Me
Reagent
(D)

Which statements are correct for reagents A, B, C and D?

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 (A) (B) (C) (D)
a. H2/Pt MMPP Cold alk. O2 + PdCl2
MMPP = Magnesium
KMnO4 + CuCl2 mono peroxy phthalate
+ H2O
CO3H
b. H2/Pd + BaSO4 HCO3H Hot alk. Dil. H2SO4
+ quinoline KMnO4 + Hg2+ COO )2 Mg 2
c. Sia2BH PhCO3H OsO4/ O2 + PdCl2
+ CH3COOH NaHSO4 + CuCl2
+ H2O
d. BH3 + THF MCPBA OsO4 O2+PdCl2
+ CH3COOH H2O2 + CuCl2
+H2O

27. Amongst the given options, the compounds in which all the atoms are in one plane in all
the possible conformations are
H H

C C
H2C
HC C C CH2
A) CH2 B) H

H 2C C H 2C C CH 2
C) D)
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28.. When cis-but-2-ene reacts with Baeyer’s reagent
A) an optically inactive compound is formed.
B) a brown inorganic precipitate is formed along with the organic product.
C) it undergoes oxidation.
D) an optically inactive mixture of two chiral compounds is formed.

Br2

CCl4

29. A) The major products (P)

CH3

Br2

CCl4

B) The major products (Q)

A) ‘A’ gives meso compound ‘B’ gives diastereoisomers

B) Both ‘A’ & ‘B’ gives enantiomers

C) ‘A’ gives enantiomers where as ‘B’ gives diastereoisomers

D) ‘P’ & ‘Q’ are optically inactive and active respectively

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30.. Which of the following pair of reagents gives syn-addition with alkenes individually
A) H 2 / Pd  BaSO4  quinoline & Br2 / CCl4
B2 H 6 / THF
B)  Ph3 P 3 ClRh  / H 2 &
CH 3COOH

B2 H 6 / THF
C) Ni2 B / H 2 &
CH 3COOH

D) Pd  CaCO3 / H 2 & Na / NH 3  l 
31. Sleet the correct statements.
a) Addition of Br2 on trans -2-butene gives erythro product
b) Addition of Cl2 on cis-2-butene gives threo product
c) Addition of Br2 on cis-2-butene gives racemic mixture
d) Addition of D2 on cis-2-butene gives meso product
Which of the following will give R-X?
32.
SO Cl Cl2 ,800 K
A) H 2C  CH  CH 3  
2 2
hv B) H 2 C  CH  CH 3 
low concentration

NBS H 2O2
C) H 2C  CH  CH 3 
CCl4 ,
 D) H 2C  CH  CH 3  HBr 

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 SECTION – III
(PARAGRAPH TYPE)
This section contains 2 groups of questions. Each group has 2 multiple choice questions based on a
paragraph. Each question has 4 choices A), B), C) and D) for its answer, out of which ONLY ONE is correct.
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases.
Paragraph For Questions 33 and 34
When the halogenation of an alkene is carried out in aqueous solution , rather than in a
non-nucleophilic solvent, the major product is a halohydrin (also called a halo alcohol)
instead of a vic-dihalide. In this case, molecules of water are in high concentration
(since it is the solvent) and therefore react with the halonium ion intermediate as the
predominant nucleophile. The result is formation of a halohydrin as the major product.
If the halogen is bromine, it is called a bromohydrin and if chlorine, a chlorohydrin.

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33. What is the major product in the following reaction?
CH3
Br2/H2O
CH3 CCH2   

Br OH

CH3 CCH2OH CH3 CCH2Br

CH3 CH3
A) B)
CH3 CH3

CH3 CCH2 CH3 CCH2

C) Br Br D) OHOH

34. When ethene gas is passed into an aqueous solution containing bromine and sodium
chloride , which of the following product is not formed in the reaction ?
A) Br CH 2CH 2 Br B) Br CH 2CH 2OH

C) Br CH 2CH 2Cl D
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Paragraph For Questions 35 and 36
Hydroboration oxidation reaction is a process of addition of H 2O according to
BH .THF
Anti-Markownikoff’s rule. R  CH  CH 2  3
 R  CH 2  CH 2  OH

H 2 O2 ,O H

Reaction is regioselective. Regioselectiveity of reaction is increased by using hindered

boranes. THF (Tetrahydrofuran) is used to control reactivity of borane.
R

THF
B
R  CH  CH 2  BH 3 

R
R
R

B
OH
R H 2O2 / OH 
R  R

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 B
D3 /THF
 
18 
H2O2 ,OH

Major product:
35.
CH 3 CH 3
CH 3 CH 3

18
D OH OH
D

18 OH D
OH OH
A) H B) H C) H D) H

HOOC H
BD3 .THF
36. C C    Product, possible fischer projection of product is :
COOH D2O2 ,O D
H

COOH COOH
COOH COOH
D H H D
H D H OD

H OD H D H OD H OH

A) COOH B) COOH C) COOH D) COOH

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MATHEMATICS Max Marks: 62

SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 6 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and –1 in all other cases.

37. If the sides of a triangle are sin  , cos  , 1  sin  .cos  ,0    , the largest angle is
2
A) 600 B) 1200 C) 900 D) 1500

A C 1
38. In a triangle ABC, if tan tan  and ac  4 , then the least value of b is :
2 2 3
A) 1 B) 2 C) 4 D) 6
39. In triangle ABC, if 2b  a  c and A  C  900 , then sin B equals:
7 5 7 5
A) B) C) D)
5 8 4 3

40. Triangle ABC is right angled at A. The points P and Q are on the hypotenuse BC such

that BP  PQ  QC. If AP  3 and AQ  4 then the length BC is equal to:

A) 27 B) 36 C) 45 D) 54

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41. In triangle ABC if A : B : C  1: 2 : 4 , then  a 2  b2  b2  c 2  c 2  a 2    a 2b2c 2 , where  =

(where notations have their usual meaning)

A) 1 B) 2 C) 4 D) 9
42. Let AD be a median of the ABC . If AE and AF are median of the triangle ABD and
a2
ADC respectively and AD  m1 , AE  m2 AF  m3 then 
8
A) m22  m32  2m12 B) m12  m22  2m32

C) m12  m32  2m22 D) m12  m12  m32

SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -2 in all other cases
43. If  represents the area of acute angled triangle ABC, then
a 2b 2  4 2  b 2 c 2  4 2  c 2 a 2  4 2 
a2  b2  c2
A) a 2  b 2  c 2 B)
2

C) ab cos C  bc cos A  ca cos B D) ab sin C  bc sin A  ca sin B

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 
44. If in a ABC ; C  ; a  2; b  2  2 then the measure of A can be:
8
A) 450 B) 1350 C) 300 D) 1500

a b c
45. Sides a,b,c of a triangle ABC are in AP and cos1  ,cos 2  , cos3 
bc ac ab
1 
then tan 2  tan 2 3 
2 2
1 2 40 2
A) B) C) D)
2 3 60 6

46. If in a triangle ABC, BC  5 AC  4, AB  3, D, E are points on BC such that

BD  DE  EC,CAE   then
73 73 3 2 13
A) AE 2  B) AE 2  C) tan   D) AD 
3 9 8 3

3 3
47. If the area of cyclic quadrilateral of ABCD is . The radius of its circumcrcle is 1. If
4
AB  1, BD  3 then BC.DC =
A) 1 B) 2 C) 3 D) 4

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48. In ABC if AB  x, BC  x  1, c 
 then the possible integer value of ‘x’ is
3
A) 6 B) 7 C) 8 D) 9
49. In a triangle ABC with given base BC, the vertex A moves such that
A
cos B  cos C  4sin 2 . If a,b and c denote the lengths of the sides of triangle opposite
2
of the angles A,B and C respectively then
A) c  a  2b
B) b  c  2a
 A  B C 
C) cos ec    2.sec  
2  2 

D) Locus of point A is a pair of straight lines

50. In a ABC , a,b and A are given, c1,c2 are possible values of 3rd side then
A) c1  c2  2b cos A

B) c1 c2  b 2  a 2

C) c12  c22  2c1c2 cos 2 A  4a 2 cos 2 A

D) c1  c2  2a cos B
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 SECTION – III
(PARAGRAPH TYPE)
This section contains 2 groups of questions. Each group has 2 multiple choice questions based on a
paragraph. Each question has 4 choices A), B), C) and D) for its answer, out of which ONLY ONE is correct.
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases.
Paragraph For Questions 51 and 52
a,b,c are the length of sides BC,CA,AB respectively of ABC satisfying
 c
  
log 1    log a  log b  log 2. Also the quadratic equation a 1  x 2  2bx  c 1  x 2  0
 a

has two equal roots.
51. Measure of angle C is:
A) 300 B) 450 C) 600 D) 900
52. The value of sin A  sin B  sin C  is equal to:
5 12 8
A) B) C) D) 2
2 5 3
Paragraph For Questions 53 and 54
4
Let a  6, b  3 and cos  A  B  
5
53. Angle C is equal to
3   
A) B) C) D)
4 4 2 6
54. Area (in Sq units) of the triangle ABC is equal to
A) 9 B) 12 C) 11 D) 10
space for rough work Page 29
 Master JEE CLASSES
Kukatpally, Hyderabad.

IIT-JEE ADVANCED-2016-PAPER-II Max.Marks: 186

KEY SHEET

PHYSICS
1 D 2 C 3 B 4 B 5 B

6 A 7 BD 8 ABCD 9 AC 10 BC

11 BCD 12 ABCD 13 BCD 14 BC 15 C

16 A 17 D 18 B

CHEMISTRY
19 A 20 B 21 D 22 B 23 C

24 D 25 ABD 26 ACD 27 ABCD 28 ABC

29 CD 30 BC 31 CD 32 ABC 33 B

34 D 35 B 36 C

MATHS
37 B 38 B 39 C 40 C 41 A

42 A 43 BC 44 A 45 BC 46 BCD

47 AB 48 BCD 49 BC 50 ABC 51 D

52 B 53 C 54 A
 SOLUTIONS
PHYSICS
1 2
1. E m  A 
2
2
E  A 
2 2
 A11    A22 
4 10  5
   8units

2. : y = A sin t
4
t1  sin 1
5
3
t 2  sin 1
5
8
 t 2  t1   0.18 s
45

m
3. T  2
k

1 1 k
f  
T 2 m

1 k
f  2
2 20

1 k
1
2 20  m

k
 2  2 
20

k  2 20 2

k = 4(20). 4 2  320 2
2
1 320
1 
2 20  m
2
4  20  m   320 2
20 + m = 80
M = 60 kg
4. Method: I
Particle is starting from rest, i.e. from one of its extreme position.

Page 2
 As particle moves a distance A , we can represent it on a circle as shown.
5

4A/5 A/5
P
x

A
Q

4A /5 4 4
cos      cos 1  
A 5 5

 4 1 4
t  cos 1   t cos 1  
5  5

T  4
 cos 1  
2 5

Method: II
As starts from rest i.e. from extreme position x = A sin  t   
 A
At t = 0; x = A    A  A cos t
2 5
4 4 T 4
 cos t  t  cos 1 t cos 1  
5 5 2 5

5. : Here, V  x   A 1  cos px 

dv d
Force, F    A  A cos px 
dx dx

For small x, F   Ap 2 x
F Ap 2 x
Acceleration, a  ……….. (i)
m m

The standard equation of SHM is, a   2 x

Comparing equations (i) and (ii), we get ……….. (ii)
Ap 2 Ap 2
2  or  
m m

2 m
Period of oscillation, T   2
 Ap 2

Page 3
6. x  x  4  1  5cos t

or x 2  4 x  4  5  5cos t
2 t
or  x  2  5 1  cos t   10 sin 2
2
t
or x  2  10 sin
2
t
or y  x  2  12 sin
2
dy t   
 10 cos   
dt 2 2

d2y   2   t 
  10   sin  
dt 2  4   2 

d 2  x  2 2
  x  2
dt 2 4
i.e., motion is simple harmonic.
7. x  3sin100t  8cos 2 50t

8 1  cos100t 
 3sin100t 
2
x  4  3sin100t  4 cos100t

4
 x  4   5sin 100t    tan   
 3

Amplitude = 5 units Maximum displacement = 9 units.

8.
T T
At t  particle will be at point B and at t  it will be at point A.
4 2

9. Acceleration of platform is maximum at extreme  g  a 2 

10. At time t1 , velocity of the particle is negative i.e. going towards  X m . From the graph,

at time t1 , its speed is decreasing. Therefore particle lies in between  X m and 0. At

time t2 , velocity is positive and its magnitude is less than maximum i.e. it has yet not
crossed O
It lies in between  X m and 0

Page 4
 Phase of particle at time t1 is 180  1 

Phase of particle at time t2 is  270   2 

Phase difference is 90  2  1 

 2  1 can be negative making   90º but can not be more than 90º

 du
11. u  5 x 2  20 x  F   10  x  2 
dx
M.P. at x  2m
12. Let the deformation in each spring be x1 , x2 and x3 respectively as shown
Let the block be displaced by x.
Then x  x1  2 x2  x3 .....  i 

F  2Kx3 ; 2 F  Kx2 ; 2F  2 Kx1;...  ii 

Also F  K eq x....  iii 
From equation (i), (ii) and (iii)
2K
 K eq 
11
11m
 T  2
2K
F  K eq x  Kx1

2K
x  Kx1
11
2
x1  x
11
Kx2
F  K eq x 
2
4
x2  x
11
F  K eq x  2 Kx3
2K
x  2 Kx3
11
1
x1  x
11
10
13. mg  KX o Xo   2cm
500

500 red
  10 5
1 sec

Page 5
  Maximum velocity = A  3 102 10 5

 30 5cm / sec.  Maxm Accn  A 2  15m / s 2

  2 2
14. Phase by   
3 3
2 4 2
Phase by 2    2  ,     0, 2 , 4
3 3 3
2 4
 , ........
3 3
15. The forces on the disc at displacement x of the spring are shown in figure
For pure rolling to take place, we have
kx  f R  fR  2 f
  
m 1 m
mR 2
2

k
 f  x
3

The cylinder is starting from x  A, so the x  t equation would be

x  A cos  t 

kA
 f  cos  t 
3
 f  t curve will be a cosine curve.

1 1
16. Energy of oscillation E  kA2  10  4  20 J
2 2
At mean position this is totally kinetic energy (translational + rotational). In case of
1
pure rolling ratio of rotational and translational kinetic energy is in case of disc
2
1 2 40
Hence, KT  mV 2   20 
2 3 3
80 40 2 2
V2   mS
3 2 3

40 1
V  ms
3

17. F  4 x  8
Page 6
 Let us write X   x  2 
This is the equation of SHM.
Hence, mean position is x  2 m
18. F  4 X

 k  4 Nm 1

2E 2 18
A  3m
k 4

Mean position of the particle is x  2 m

Hence, the extreme points are 5 m and – 1 m
CHEMISTRY
19. Conceptual
20. It is free radical substitution at allylic position
21. d) Its pincol-pinacolone type reaction and product is formed after formation of carbocation
and its rearrangement by ring expansion.
O

22. Conceptual
23. Electrophilic addition reaction
24. Conceptual
25. Conceptual
26. Conceptual
27. Conceptual
28. Conceptual
29. Conceptual
30. Conceptual
31. Conceptual
32. Conceptual

33.

Page 7
34. Conceptual
35. Conceptual
36. Conceptual
MATHS
37. Greatest side  1  sin  .cos  , apply cosine rule.
38. 2b  a  c, use AM  GM

AC ac B
39. Use tan  
 cot
 2  a c 2

40. Let A  0,0  B  0,   C  , 0 

 2     2 
Q , . P  , 
 3 3 3 3 

AQ 2  16, AP 2  9

4 2   2  144 , 4 2  16 2  324

15 2  80

 2   2  45

41. Let A  K , B  2K , C  3K
Use sine rule
42. Conceptual
43. Conceptual
44. C 2  2  2 then use sine rule
45. 2b  a  c
1  1  cos 1 1  cos  2
tan 2  tan 2 3  
2 2 1  cos 1 1  cos  2

25 5 4
46. AE 2  16   2 4 
9 3 5
47. In. ABD
AB BD
  2  ADB  300
sin ADB sin A
BD
sin A   A  60 0 Or 1200
2
48. Using cosine rule
2 
x 2   x  1  b 2  2  x  1 b cos
3

Page 8
 b 2   x  1 b  2 x  1  0

Since b is real are we have

2
 x  1  4  2 x  1  0

x  3  12
Least integral value is 7
BC A
49. cos  2sin
2 2
50. a 2  b2  c 2  2bc cos A

 c 2  2b cos A c  b 2  a 2  0

c1  c2  2b cos A, c1 c2  b 2  a 2

51. a  c  2b
52.
 AB 1
53. tan  
 2  3
a b c 1 c
cot   cot  1
ab 2 3 2

Page 9