Chapter 2
Chapter 2
2
2–1 ■ INTRODUCTION
• Property: Any characteristic of a
system.
• Some familiar properties are
pressure P, temperature T, volume
V, and mass m.
• Properties are considered to be
either intensive or extensive.
• Intensive properties: Those that
are independent of the mass of a
system, such as temperature,
pressure, and density.
• Extensive properties: Those
whose values depend on the size—
or extent—of the system.
• Specific properties: Extensive
properties per unit mass.
Criterion to differentiate intensive
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and extensive properties.
Continuum
• Matter is made up of atoms that are
widely spaced in the gas phase. Yet it is
very convenient to disregard the atomic
nature of a substance and view it as a
continuous, homogeneous matter with
no holes, that is, a continuum.
• The continuum idealization allows us to
treat properties as point functions and to
assume the properties vary continually
in space with no jump discontinuities.
• This idealization is valid as long as the
size of the system we deal with is large Despite the relatively large gaps
relative to the space between the between molecules, a substance can
molecules. be treated as a continuum because
of the very large number of
• This is the case in practically all
molecules even in an extremely
problems.
small volume.
• In this text we will limit our consideration
to substances that can be modeled as a
continuum. 5
The length scale associated with most
flows, such as seagulls in flight, is orders
of magnitude larger than the mean free
path of the air molecules. Therefore,
here, and for all fluid flows considered in
this book, the continuum idealization is
appropriate.
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2–2 ■ DENSITY AND SPECIFIC GRAVITY
Density Specific gravity: The ratio
of the density of a
substance to the density of
some standard substance
Specific volume at a specified temperature
(usually water at 4°C).
Density is
mass per unit
volume;
specific volume
is volume per
unit mass.
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Density of Ideal Gases
Equation of state: Any equation that relates the pressure,
temperature, and density (or specific volume) of a substance.
Ideal-gas equation of state: The simplest and best-known
equation of state for substances in the gas phase.
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2–3 ■ VAPOR PRESSURE AND CAVITATION
• Saturation temperature Tsat: The temperature at which
a pure substance changes phase at a given pressure.
• Saturation pressure Psat: The pressure at which a
pure substance changes phase at a given temperature.
• Vapor pressure (Pv): The pressure exerted by its vapor
in phase equilibrium with its liquid at a given
temperature. It is identical to the saturation pressure
Psat of the liquid (Pv =Psat).
• Partial pressure: The pressure of a gas or vapor in a
mixture with other gases. For example, atmospheric air
is a mixture of dry air and water vapor, and atmospheric
pressure is the sum of the partial pressure of dry air and
the partial pressure of water vapor.
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The vapor pressure (saturation
pressure) of a pure substance (e.g.,
water) is the pressure exerted by its
vapor molecules when the system is in
phase equilibrium with its liquid
molecules at a given temperature.
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• There is a possibility of the liquid
pressure in liquid-flow systems
dropping below the vapor
pressure at some locations, and
the resulting unplanned
vaporization.
• The vapor bubbles (called
cavitation bubbles since they
form “cavities” in the liquid)
collapse as they are swept away
from the low-pressure regions,
generating highly destructive, Cavitation damage on a 16-mm by
extremely high-pressure waves. 23-mm aluminum sample tested at
60 m/s for 2.5 h. The sample was
• This phenomenon, which is a
located at the cavity collapse
common cause for drop in
region downstream of a cavity
performance and even the
generator specifically designed to
erosion of impeller blades, is
produce high damage potential.
called cavitation, and it is an
important consideration in the
design of hydraulic turbines and
pumps. 13
14
Speed of Sound and Mach Number
Mach number Ma: The ratio of the
actual speed of the fluid (or an object
in still fluid) to the speed of sound in
the same fluid at the same state.