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JEE Advanced Paper -1 Question Paper with Solutions and Key

PART I : PHYSICS
SECTION 1(Maximum Marks:28)
 This section contians SEVEN questions
 Each question has FOUR options [A],[B],[C] and [D]. ONE OR MORE THAN ONE of these four
options is (are ) correct
 For each question,darken the bubble(s) corresponding to all the correct option(s) in the ORS
 For each question, marks will be awarded in one of the following categories
Full Marks : +4 If only the bubbles (s) corresponding to all the correct option(s) is
(are) darkened
Partial Marks : +1 For darkening a bubble corresponding to each correct option,
provided NO incorrect option is darkened
Zero Marks : 0 If none of the bubbles is darkened
Negative Marks: -2 In all other cases

in
 For example, if [A],[C] and [D] are all the correct options for a question, darkening all these three
will get +4 marks; darkening only [A] and [D] will get +2 marks; and darkening [A] and [B] will get -
2 marks, as a wrong option is also darkened
01. A flat plate is moving normal to its plane through a gas the action of a constant force F. The gas

p.
is kept at a very low pressure. The speed of the plate v is much less than the average speed u
of the gas molecules. Which of the following options is/are true?
A) The resistive force experienced by the plate is proportional to v
B) At a later time the external force F balances the resistive force
re
C) The plate will continue to move with constant non-zero acceleration, at all times
D) The pressure difference between the leading and trailing faces of the plate propertional to uv
Key : B, C
Sol : A) Assume the plate is at rest. Let n be the no.of molecules per unit volume
A be the Area of plate
tP

m be the mass of each molecule

p of one molecule = 2 mV (being elastic collism)
No.of molecules striking per unit time= nAV
The corresponding resistive force f   nAV  2mU  , f  2nAmV 2
ar

 f V 2
1 1 ax
B) a 2
x 2

2a
log
ax
Sm

dv
FF  f  m is of the form
dt
dV
F  KV 2  m
dt
1 1
or  F  KV 2
dv 
m
dt

Integrating 'V ' is of the form

 ekt  1 
V  C  kt 
 e  1
As t   V  C

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Therefore at a later time F balances f

C) At all times the acceleration of the plate is non-zero
D) Pressure on rear side of plate is proportional to u 2
Pressure on front side of plate has two components
(1) pressure proportional to u2 (2) pressure propotional to v 2
Net pressure is propartional to v 2
02. A human body has a surface area of approaximately 1 m 2 . The normal body temperature is 10
K above teh surrounding room temperature T0 . Take the room temperature to be T0  300 K .
For T0  300 K , the value of  T03  460 Wm 2 (Where  is the stefan Boltzmann constant).
Which of the following options is/are correct?
A) If the surrounding temperature reduces by a small amount T0  T0 , then to maintain the same body

in
temperature the same (living) human being needs to radiate W  4 T03 T0 more energy per unit time
B) If the body temperature rises significantly then the peak in the spectrum of electromagnetic radiation
emitted by the body would shift to longer wavelengths
C) Reducing teh exposed surface area of the body (e.g. by curling up allows humans to maintain the same

p.
body temperature while reducing teh energy lost by radiation
D) The amount of energy radiated by the body in 1 second is close to 60 Joules
Key : A,C,D
Sol : A] W   A[T 4  T0 4 ]
re
differentiating
W   A4T03  T0  as T is to be constant
as T0 is - re (reducing)
tP

W   A4T03 T0

W   4T03 T0  A  1m 2 
as W is positive, he has to radiate more energy per unit time.
ar

03. A block M hangs vertically at teh bottom end of a uniform rope of constant mass per unit length.
The top end of the rope is attached to fixed rigid support at O. A transverse wave pulse (Pulse 1)
of wavelength 0 is produced at point O on the rope. The pulse takes time T0 A to reach point A.
If the wave pulse of wavelength 0 to reach point A (Pulse 2) without disturbing the position of
Sm

M it takes time TA0 to reach point O. Which of the following options is/are correct?

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A) The time TA0  T0 A

B) The velocity of the two pulses (Pulse 1 and Pulse 2) are the same at the midpoint of rope
C) The wavelength of Pulse 1 becomes longer when it reaches point A
D) The velocity of any pulse along the rope is independent of its frequency and wavelength
Key : A,B,D
Sol : Rope is uniform T0 A  TA0
Af mid point velocities of two pulses are equal
When pulse (1) reaches to bottom point A velocity decreases (tension decreases)
 wave length decreases
D) Velocity at any point V  xg i.e independent of frequency and wavelength
04. For an isosceles prism of angle A and refractive index  , it is found that the angle of minimum
deviation  m  A. Which of the following options is/are correct?

in
A) At minimum deviation, the incident angle i1 and the refracting angle r1 at the first refracting surface are
related by r1   i1 / 2 

1   

p.
1
B) For this prism, the refractive index  and the of prism A are related as A  cos  
2 2
C) For this prism, the emergent ray at the second surface will be tangential to the surface when the angle of

1
 2 A

incidence at the first surface is i1  sin sin A 4 cos 2  1  cos A
re
 
D) For the angle of incidence i1  A, the ray inside the prism is parallel to the base of the prism
Key : A C D
tP

Sol :
A) In min div position r  A / 2
A D A A
i   A  2r
2 2
ar

sin  A  D / 2  sin A
B)   ,  2 cos A / 2
sin A / 2 sin A / 2

A / 2  cos 1  
2
Sm


A  2 cos 1  
2
C) At first face sin c1   sin  A  C 

  sin A cos C  cos A sin C 

  2 1 1
  sin A  cos A 
   

sin , 2 sin A  2  1  cos A

 

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 A 
 sin A 4 cos 2  1  cos A
 2 
A D A A
D) i    A  2r  i1
2 2
05. In the circuit shown, L  1 H , C  1  F and R  1 k . They are connected in series with an a.c.
source V  V0 sin t as shown. Which of the following options is/are correct?

in
A) At   106 rad .51 , the circuit behaves like a capacitor
B) At   0 the current flowing through the circuit becomes nearly zero

p.
C) The current will be in phase with the voltage if   104 rad . s 1
D) The frequency at which the current will be in phase with teh voltage is independent of R
Key : B,D
re
1
Sol : A) w0   106 rad / sec
LC
for w. 106      inductive
tP

I
ar

B)
w0 w
I 0
Sm

C) for w0  104 rad/sec, a.c. not in phase with a.v

D) Conceptual
06. A block of mass M has a circular cut with a frictionless surface as shown. The block rests on the
borizontal frictionless surface of a fixed table. Initially the right edge of the block is at x=0, in a
co-ordinate system fixed to the table, A point mass m is released from rest at the topmost point
of the path as shown and it slides down. When the mass loses contact with the block, its position
is x and the velocity is v. At thet instant, which of the following options is/are correct?

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m
A) The velocity of the block M is: V   2 gR
M
mR
B) The x component of displacement of the center of mass of the block M is: 
M m
mR
C) The position of the point mass is: x   2
M m

2 gR
v
m
D) The velocity of the point mass m is: 1
M
Key : B,D
V 1  vel  of block ( M )

in
Sol : w.r.t ground frame
V  vel. vel of m w.r.t M .

MV 1  m V  V 1 

p.
mV
V1  __________ 1
M m
using LCE,

M V 1   m V  V 1   mgR ________  2 
1 2 1 2
re
2 2
Solving (1) & (2)
M m
V 2 gR
M
tP

mV m M m
and V  
1
2 gR
M m M m M

m 2 2 gR
ar

V  1

M  mM 
A)
mR
B) The displacement of block M= 
Sm

M m
C) M x  m  R  x  x  displ of block M .w.r.t Ground
mR
x
M m
mR MR
displ of m  R  x  R  
M m M m
D) vel. of point mass m is V-V
mV
V 
M m

MV M M m
  2 gR
M m M m M

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2 gR
m
Vel. of point mass m = 1
M
07. A circular insulated copper wire loop is twisted to form two loops of area A and 2A as shown in
the figure. At the point of crossing the wires remains electrically insulated from each other. The

entire loop lies in the plane (of the paper). A uniform magnetic field B points into the plane of
the paper. At t=0, the loop starts rotating about the common diameter as axis with a constant
angular velocity  in the magnetic field. Which of the following options is/are correct?

in
p.
re
A) The amplitude of the maximum net emf induced due to both the loops is equal to the amplitude of
maximum emf induced in the smaller loop alone
B) The rate of change of the flux is maximum when the plane of the loops is perpendicular to plane of the
tP

paper
C) The emf induced in the loop is proportional to the sum of the areas of the two loops
D) The net emf induced due to both the loops is proportional to cos t
Key : A,B
ar

d
Sol : e1   BA cos t   BAW , COnWt  e0
dt
e2  B2 AWS inwt  e0 wt

e   BAW
Sm

mgx 1

 emax 2  2 BAW
Option  A closed
enet  BA sin t
Hence Option [C] correct
 A & B are correct
SECTION 2 (Maximum Mars: 15)
 This section contains FIVE questions
 The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both
inclusive
 For each question, darken the bubble corresponding to the correct integer in the ORS
 For eavch question, marks will be awarded in one of the following categories:

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Full marks : +3 If only the bubble corresponding to the correct answer is darkened
Zero Marks : 0 In all other cases
08. A stationary source emits sound of frequency f 0  492 Hz. The sound is reflected by a large car
approaching the source with a speed of 2 ms 1. The reflected signal is received by the source
and superposed with the original. What will be the beat frequency of the resulting signal in Hz ?
(Given that the speed of sound in air is 330 ms 1 and the car reflects the sound at the frequency
it has received).
Key : 6
Sol : n  492 H Z

V u 
n|  n  
V u 

in
 330  2 
n|  492   498 Hz
 330  2 
 beats  n  n|  n  6 Hz

p.
09. An electron in a hydrogen atom undergoes a transition from an orbit with quantum number ni to
another with quantum number n f .Vi and V f are respectively the initial and final potential energies
Vi
of the electron. If V  6.25, then the smallest possible n f is
re
f

Key : 5
Sol : PE = 2  TE
13.6  2
Vi 
tP

ni2

13.6  2
Vf  2
nf
ar

2
Vi n f 625
 2 
Vf ni 100

nf 25 5
  
Sm

ni 10 2

 Min value of n f  5
0.3
10. A drop of liquid of radius R  102 m having surface tension S  Nm 1 divides itself into K
4
identical drops. In this process the total change in the surface energy U  103 . If K  10
then the value of  is
Key : 6
Sol : U  4 R  n  n 
2 2/3

0.1
103  4  104   x  x 2 / 3  Soving = k  106
4 

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11. 1 is an isotope of iodine that  decays to an isotope of Xenon with a half - life of 8 days. A
3

small amount of a serum labelled with 31 is injected into the blood of a person. The activity of
the amount of 31 injected was 24  105 Beequerel (Bq.). It is known that the injected serum will
get distributed unifomly in the blood stream in less than half an hour. After 11.5 hours, 2.5 ml of
blood is drawn from the person’s body, and gives an activity of 11.5 Bq. The total volume of
blood is drawn from the person’s body, and gives an activity of (you may use
e x  1  x for x  1and in 2  0.7 )
Key : 5
Sol : For activity of 2.4 105 Bd volume of blood

2.4  105
  2.5  103
120.76

in
12. A monochromatic light is travelling in a medium of refractive index   1.6 . It enters a stack of
glass layers from the bottom side at an angle   300 . The interfaces of the glass layers are
parallel to each other. The refractive indices of different glass layers are monotonically decreasing
as nm  n  mn , where nm is the refractive index of the m th slab and n  0.1 (sec the figure).

p.
The ray is refracted out parallel to the interface between the  m  1 and m th slabs from the
th

right side of the stack. What is the value of m?

Key : 8
re
2 sin i
Sol : I intiger   sin r
1

1.6 sin 30 1.6 1 1.6

  sin r   
tP

1.5 sin r 1.5 2 3

Second intiger 2 sin r  1 sin r1
1.6 1.6 1 1.6
1.5   1.4sin r1  sin r1   
3 2 1.4 2.8
ar

III intiger   2 Rr1  1 sin r11

1.6
1.4   1.6sin r11
2.8
Sm

1.6
sin r11 
2.6
1.6
IV  sin r3 
2.4
1.6
V  sin r4 
2.2
1.6
VI  sin r5 
2.0

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A c h a r g e d p a r t i c le ( e le c t r o n o r p r o t o n ) i s i n t r o d u c e d a t t h e o r i g i n
 
 x  0 , y  0 , z  0  w i t h a g iv e n i n i t i a l v e l o c i t y v A u n i f o r m e l e c t r ic f i e l d E a n d a
  
u n i f o r m m a g n e t i c f i e l d B e x i s t e v e r y w h e r e , T h e v e l o c i t y v , e l e c t r i c f ie l d E a n d

m a g n e t i c f i e l d B a r e g iv e n i n c o l u m n s 1 , 2 a n d 3 , r e s p e c t iv e l y , T h e q u a n t i t i e s E 0 , B 0
a r e p o s it i v e i n m a g n i t u d e .
C o lu m n 1 C o lu m n 2 C o lu m n 3
 
(I) E l e c t r o n w it h ( i) E  E 0 z ( P ) B   B 0 x
 E0
v  2 x
B0
 
(II) E l e c t r o n w it h ( ii) E  E y ( Q ) B  B 0 x
 E0
0

v  y
B0
  
(III) P r o t o n w it h v  0 ( iii) E   E 0 x (R ) B  B 0 y

 
(IV ) P r o t o n w it h ( iv ) E  E 0 x ( S ) B  B 0 z
 E0
v  2 x
B0

in
SECTION 3 (Maximum Marks : 18)
 This Section contains SIX questions of matching type
 This section contains TWO tables (each having 3 columns and 4 rows)
 Based on each table, there are THREE questions
 Each questions has FOUR options [A],[B], [C], and [D]. ONLY ONE of these four options is

p.
correct.
 For each question, darken the bubble corresponding to the correct option in the ORS
 For each question, marks will be awarded in one of the following categories:
re
Full Marks : +3 If only the bubble corresponding to the correct option is darkened
Zero Marks : 0 If one of the bubbles in darkened
Negative Marks: -1 In all other cases
13. In which case would the particle move in a straight line along the negative direction of y  axis
(i.e., move along - y ) ?
tP

A) (III) (ii) (P) B) (II) (iii) (Q) C) (IV) (ii) (S) D) (III) (ii) (R)
Key : A
Sol : The resultant face must be along -y direction i.e acording to the condition of ‘A’. It is possible.
14. In which ease will the particle descrive a helical path with axis along the positive z direction?
ar

A) (II) (ii) (R) B) (III) (iii) (Q) C) (IV) (ii) (R) D) (IV) (i) (S)
Key : D
Sol : For helical path E,B direction must be perpendicular to V
15. In which case will the particle move in a straight line with constant velocity ?
Sm

A) (II) (iii) (S) B) (III) (ii) (R) C) (IV) (i) (S) D) (III) (iii) (P)
Key : D
Sol : Resultant force acting on the charged particle must be zero.
16. Which one of the following options correctly represents a thermodynamic process that is used as
a correction in the determination of the speed of sound in an ideal gas?
A) (1) (ii) (Q) B) (I) (iv) (Q) C) (IV) (ii) (R) D) (III) (iv) (R)
Key : B
Sol : According to the given table let us first range accadinngly such that
1
workd are in adiabatic moces. w   p2v2  p1v1 
r1
i.e (I) ------- (IV)
workdone in isobaric process w   pv2  pv1
i.e II -------- ii

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v 
wark done in isothermal w   nt log  2 
 v1 
i.e IV -- --------- i
Adiabatic candition for sound propagation

17. Which one of the following options is the correct combination?

A) (II) (iv) (P) B) (III) (ii) (S) C) (II) (iv) (R) D) (IV) (ii) (S)
Key : B
Sol : workdone Isobanic mocen
18. Which of the following options is the only correct representation of a process in which
U  Q  PV ?
A) (III) (iii) (P) B) (II) (iii) (P) C) (II) (iii) (S) D) (II) (iv) (R)

in
Key : B
Sol : It is the condition for isobanic process.
PART - II CHEMISTRY
SECTION 1 (Maximum Marks:15)


p.
This section contians SEVEN questions
 Each question has FOUR options [A],[B],[C] and [D]. ONE OR MORE THAN ONE of these four
options is (are ) correct
 For each question,darken the bubble(s) corresponding to all the correct option(s) in the ORS
 For each question, marks will be awarded in one of the following categories
re
Full Marks : +4 If only the bubbles (s) corresponding to all the correct option(s) is
(are) darkened
Partial Marks : +1 For darkening a bubble corresponding to each correct option,
provided NO incorrect option is darkened
Zero Marks : 0 If none of the bubbles is darkened
tP

Negative Marks: -2 In all other cases

 For example, if [A],[C] and [D] are all the correct options for a question, darkening all these three
will get +4 marks; darkening only [A] and [D] will get +2 marks; and darkening [A] and [B] will get -
2 marks, as a wrong option is also darkened
ar

19. The IUPAC name(s) of the following compound is(are)

Sm

A) 1- chloro -4-methylbenzene B) 1- methyl -4- chlorobenzene

C) 4- chlorotoluene D) 4- methylchlorobenzene
Key : A, C
Sol : A) 1- chloro -4-methylbenzene
C) 4- chlorotoluene
20. The correct statement(s) about the oxoacids, HClO4 and HClO , is(are)
A) The central atom in both HClO4 and HClO is sp3 hybridized
B) The conjugate base of HClO4 is weaker base than H 2O
C) HClO4 is formed in the reaction between Cl2 and H 2O
D) HClO4 is more acidic than HClO because of the resonance stabilization of its anion

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Key : A, B, D
Sol : (A) Hybridisation is sp3 in HClO4 & HClO

(B) HClO4 Strong acid   ClO4 Week Base

H 2OWeek Acid   OH   Strong Base 

ClO4 is weaker base than H 2O

(D) Conceptual
21. For a solution formed by mixing liquids L and M, the vapour pressure of L plotted against the
mole fraction of M in solution is shown in the following figure. Here xL and xM represent mole
fractions of L and M, respectively, in the solution. The correct statement(s) applicable to this
system is(are)

in
p.
re
A) The point Z represents vapour pressure of pure liquid M and Raoult’s law is obeyed when xL  0
B) The point Z epresents vapour pressure of pure liquid M and Raoult’s law is obeyed from xL  0 to
xL  1
tP

C) Attractive intermolecular interactions between L-L in pure liquid L and M- M in pure liquid M are
stronger than those between L- M when mixed in solution.
D) The point Z represents vapour pressure of pure liquid L and Raoult’s law is obeyed when xL  1
Key : C, D
Sol : Conceptual
ar

22. Addition of excess aqueous ammonia to a pink coloured aqueous solution of MCl2 .6 H 2O (X) and
NH 4Cl gives an octahedral complex Y in the presence of air. In aqueous solution, complex Y
behaves as 1:3 electrolyte. The reaction of X with excess HCl at room temperature results in
Sm

the formation of a blue coloured complex Z. The calculated spin only magnetic moment of X and
Z is 3.87 B.M., whereas it zero for complex Y. Among the following options, which statement(s)
is(are) correct?
A)Z is a tetrahedral complex
B) The hybridization of the central metal ion in Y is d 2 sp 3
C) When X and Z are in equilibrium at 00 C , the colour of the solution is pink
D) Addition of silver nitrate to Y gives only two equivalents of silver chloride
Key : A, B, C
Sol:
Step (1)
MCl2 .6 H 2O   M  H 2O 6  Cl2  
aquous excess NH 4Cl
air
  M  NH 3 6  Cl3
Pink  X  Y d 2 sp 3  Hyb n

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Step(2)
 M  H 2O 6  Cl2 
Excess HCl
   MCl4   Hyb n  sp 3
2
00 C

Pink  X   Z  Blue Tetrahedral

23. The correct statement(s) for the following addition reactions is (are)

in
A) Bromination proceeds through trans-addition in both the reactions
B) O and P are identical molecules

p.
C) (M and O) and ( N and P) are two pairs of distereomers
D) (M and O) and (N and P) are two pairs of enantiomers
Key : A, C
Sol :
re
tP
ar
Sm

(A)
(B) (M &O) and (W & P) are two pairs of diastereomers
24. An ideal gas is expanded from  p1 ,V1 , T1  to  p2 ,V2 , T2  under different conditions. The correct
statement(s) among the following is (are)
A) The work done on the gas is maximum when it is compressed irreversibly from  p2 ,V2  to  p1 , V1 

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against constant pressure p1

B) The work done by the gas is less when it is expanded reversibly from V1 to V2 under adiabatic
conditions as compared to that when expanded reversibly from V1 to V2 under isothermal conditions
C) If the expansion is carried out freely, it is simultaneously both isothermal as well as adiabatic
D) The change in internal energy of the gas is (i) zero, if it is expanded reversibly with T1  T2 , and (ii)
positive, if it is expanded reversibly under adiabatic conditions with T1  T2
Key : A, B, C
Sol : Conceptual
25. The colour of the X 2 molecules of group 17 elements changes gradually from yellow to violet
down the group. This is due to
A) The physical state of X 2 at room temperature changes from gas to solid down the group

in
B) Decrease in  *   * gap down the group
C) Decrease in HOMO- LUMO gap down the group
D) Decrease in ionization energy down the group
Key : B, C

p.
Sol : Conceptual
SECTION 2 (Maximum Mars: 15)
 This section contains FIVE questions
 The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both
re
inclusive
 For each question, darken the bubble corresponding to the correct integer in the ORS
 For eavch question, marks will be awarded in one of the following categories:
tP

Full marks : +3 If only the bubble corresponding to the correct answer is darkened
Zero Marks : 0 In all other cases

26. The conductance of a 0.0015 M aqueous solution of a weak monobasic acid was determined by
using a conductivity cell consisting of platinized Pt electrodes. The distance between the electrodes
ar

is 120 cm with an area of cross section of 1cm 2 . The conductance of this solution was found to be

5  10 7 S . The pH of the solution is 4. The value of limiting molar conductivity   m  of this weak
0

monobasic acid in aqeous solution is Z  102 S cm 1 mol 1 . The value of Z is

Sm

Key : 6
Sol :
l
Cell const 
A
120

1
 120 cm 1

l
K  C.
A

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120
K  5  107 
1
K  600  10 7
K  6  10 5
K 103
C 
C
6  105  103
C 
0.0015
2
 C   102
5

in
200
C 
5
 C  40

p.
 H    C 

104  0.0015 
104

re
0.0015
1

15

C
tP


0
1 40

15  0
ar

 0  15  4  10
 0  600

 0  6  102
Sm

Z 6
27. The sum of the number of lone pairs of electrons on each central atom in the following species is
TeBr6  ,  BrF2  , SNF3 , and  XeF3 
2  

(Atomic numbers: N = 7, F = 9, S = 16, Br = 35, Te = 52, Xe = 54)

Key : 6
Sol: No.of lone pairs
TeBr6 
2
1

 BrF2 

2

 SNF3   0

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 XeF3   3
Total 6
28. A crystalline solid of a pure substance has a face-centred cubic structure with a cell edge of
400pm. If the density of the substance in the crystal is 8 g cm 3 , then the number of atoms
present in 256 g of the crystal is N  10 24 . The value of N is
Key :
Z .M
Sol : d  N .G 3
0

4 M
8
6  1023   4  108 
3

in
M= 76.8
76.8 gr  6  1023
256 gr  ?
256  6  1023

p.
 20  1023  2  1024
76.8
N= 2
29. Among the following the number of aromatic compound(s) is
re
tP
ar

Key : 4
Sm

Sol:

30. Among H 2 , He2 , Li2 , Be2 , B2 , C2 , N 2 , O2 and F2 , the number of diamagnetic species is
(Atomic numbers: H = 1, He = 2, Li = 3, Be = 4, B = 5, C = 6, N = 7, O = 8, F = 9)
Key : 6
Sol: H 2 , Li2 , Be2 , C2, N 2 , F2 all diamagnatic

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SECTION 3 (Maximum Marks : 18)

 This Section contains SIX questions of matching type
 This section contains TWO tables (each having 3 columns and 4 rows)
 Based on each table, there are THREE questions
 Each questions has FOUR options [A],[B], [C], and [D]. ONLY ONE of these four options is
correct.
 For each question, darken the bubble corresponding to the correct option in the ORS
 For each question, marks will be awarded in one of the following categories:

Full Marks : +3 If only the bubble corresponding to the correct option is darkened
Zero Marks : 0 If one of the bubbles in darkened
Negative Marks: -1 In all other cases

in
Answer Q-31, Q-32, Q-33 by appropriately matching the information given in the three coloumns of
the following table
The wave function,  n ,l , ml is a mathematical function whose value depends upon spherical polar
coordinates  r , ,   of the electron and characterized by the quantum numbers n, l and ml . Here r

p.
is the distance from nucleus,  is colatitude and  is azimuth. In the mathematical functions
given in the Table, Z is atomic number and a0 is Bohr radius
Column 1 Column 2 Column 3
(I) 1s orbital 3
 Zr 
 Z  2  a  (P)
(i)  n ,l ,ml    e  0 
re
 0
a
tP

(II) 2s orbital (ii) One radial node 1

ar

(Q) Probability density at nucleus 

a03
(III) 2 pz orbital 5  Zr  (R) Probability density is maximum at
 Z  2  2 a 
(iii)  n ,l ,ml   0  re  0  cos  nucleus
a 
(IV) 3d z2 orbital (iv) xy- plane is a nodal plane (S) Energy needed to excite electron
Sm

27
from n=2 state to n=4 state is
32
times the energy needed to excite
electron from n=2 state to n=6 state

31. For hydrogen atom, the only CORRECT combination is

A) (II) (i) (Q) B) (I) (iv) (R) C) (I) (i) (S) D) (I) (i) (P)
Key : C
Sol: Conceptual
32. For He  ion, the only INCORRECT combination is
A) (I) (iii) (R) B) (II) (ii) (Q) C) (I) (i) (S) D) (I) (i) (R)
Key : A

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Sol: Conceptual
33. For the given orbital in Column 1, the only CORRECT combination for any hydrogen - like
species is
A) (IV) (iv) (R) B) (III) (iii) (P) C) (II) (ii) (P) D) (I) (ii) (S)
Key : C
Sol: Conceptual

Answer Q-34, Q-35, Q-36 by appropriately matching the information given in the three coloumns
of the following table

Columns 1,2 and 3 contain starting materials, reaction conditions, and type of
reactions, respectively

in
Column 1 Column 2 Column 3
(I) Toluene (i) NaOH / Br2
(P) Condensation

p.
(II) Acetophenone (ii) Br2 / hv (Q) Carboxylation

(III) Benzaldehyde (iii)  CH 3CO  O / CH 3COOK (R) Substitution

2

(IV) Phenol (iv) NaOH / CO2 (S) Haloform

re
34. The only CORRECT combination that gives two different carboxylic acids is
A) (II) (iv) (R) B) (III) (iii) (P) C) (I) (i) (S) D) (IV) (iii) (Q)
Key: B
Sol: Conceptual
tP
ar

35. The only CORRECT combination in which the reaction proceeds through radical mechanism is
A) (III) (ii) (P) B) (I) (ii) (R) C) (IV) (i) (Q) D) (II) (iii) (R)
Sm

Key: B
Sol: Conceptual

36. For the synthesis of benzoic acid, the only CORRECT combination is
A) (I) (iv) (Q) B) (III) (iv) (R) C) (IV) (ii) (P) D) (II) (i) (S)
Key: D
Sol: Conceptual

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PART-III : MATHEMATICS
SECTION 1(Maximum Marks:28)
 This section contians SEVEN questions
 Each question has FOUR options [A],[B],[C] and [D]. ONE OR MORE THAN ONE of these four

in
options is (are ) correct
 For each question,darken the bubble(s) corresponding to all the correct option(s) in the ORS
 For each question, marks will be awarded in one of the following categories
Full Marks : +4 If only the bubbles (s) corresponding to all the correct option(s) is
(are) darkened

p.
Partial Marks : +1 For darkening a bubble corresponding to each correct option,
provided NO incorrect option is darkened
Zero Marks : 0 If none of the bubbles is darkened
Negative Marks: -2 In all other cases
re
 For example, if [A],[C] and [D] are all the correct options for a question, darkening all these three
will get +4 marks; darkening only [A] and [D] will get +2 marks; and darkening [A] and [B] will get -
2 marks, as a wrong option is also darkened
37. If a chord, which is not a tangent, of the parabola y 2  16 x has the equation 2x  y  p , and
tP

midpoint (h,k), then which of the followin is (are) possible value(s) of p,h and k?
A) p=-1,h=1,k=-3 B) p=5,h=4,k=-3 C) p=-2,h=2,k=-4 D) p=2,h=3,k=-4
Key : D
Sol : S1  S11  8 x  ky   k  8h   0    (1)
ar

but (1) is same as 2x+y-p=0

8 k k 2  8h
  
2 1 p
Sm

 k   4,  4 P  k 2  8 h  4 P  16  8h
 k  4, 2h  p  4
satisfied for D
38. Let a,b,x and y be real numbers such that a-b=1 and y  0 . If the complex number
 az  b 
z  x  ty satisfies in    y , then which of the following is (are) possible value (s) of x?
 z 1 

A) 1  1  y 2 B) 1 1 y2 C) 1  1  y 2 D) 1  1  y 2
Key : B,D
az  b a ( x  iy )  b ax  b  aiy ( x  1  iy )
Sol :  
2 1 x  iy  1 ( x  1)  iy x  1  iy
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az  b ay ( x  1)  y (ax  b)
 y
Z 1 ( x  1) 2  y 2
a  b  x2  b2  2 x  1
x2  y 2  2x  0

2  4  4  y 2 
x  1  1  y 2
2
1 1 2
39. Let X and Y be two events such that P ( X )  , P  X / Y   and P  X / Y   .Then
3 2 5
2 4 1 1
A) P  X  Y   B) P Y   C) P  X / Y   D) P  X  Y  
5 5 2 5

in
Key : B,C
Sol : x, y  Any 2 events
1  x 1  y 2
p( x)  , p    , p   

p.
3  y 2  x 5

1 2 21 2
p  x  y  p ( y ), p ( x  y )  p ( x )    
2 5 5  3  15
p  x  y   p ( x)  p ( y )  p  x  y 
re
1 4 2 5 42 2 1 4
     p( x)  p( y ) 
3 15 15 15 15 2 15
7
tP


15

 x  p x y  
p( y )  p( x  y )
also   
p 
 y p( y ) p( y )
ar

4 2

 15 15  2  1
4 4 2
Sm

15

x2 y 2
40. If 2x-y+1=0 is a tangent to the hyperbola   1 , then which of the following CANNOT be
a 2 16
sides of a right angled triangle?
A) 2a,4,1 B) a,4,1 C) a,4,2 D) 2a,8,1
Key : B,C,D
17
Sol : c  a m  b  1  4a  16  a 
2 2 2 2 2

2
options (B),(C),(D) are not forming rt angled  les
41. Let [x] be the greatest integer less than or equals to x. Then at which of the following point(s) the
function f(x)= x cos  ( x  [ x])  is discontinuous?
A) x=2 B) x=0 C) x=1 D) x=-1
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Key : A,C,D
Sol : option (a)
f (2)  2 cos 4  2
lim
x2  f ( x )  2.cos(3 )  2
x=2 is discent point option (b)
f(0)=0
lim
x2  f ( x )  0,lim
x 0  f ( x)  0

x=0 cant point

option (c)
f (1)  1cos 2  1
lim
x 1 f ( x )  (1) cos( )  1

in
x=+1 is discent point
option (d)
f (1)  (1)(1)  1
lim
 f ( x )  (1) cos(3 )  1
x 1

p.
x=-1 is discent point

42. Which of the following is (are)NOT the square of a 3  3 matrix with real entries?

1 0 0  1 0 0  1 0 0   1 0 0 
re
0 1 0  0 1 0  0 1 0  0 1 0 
A)   B)   C)   D)  
0 0 1 0 0 1 0 0 1   0 0 1
Key : A,D
tP

Sol : Options (A),(B),(D) gives A with imaginary entries

43. Let f :   (0,1) be a continuous function . Then which of the following function(s) has (have)
the value zero at some point in the interval (0,1)?
 
f (t ) sin tdt B) e  0 f (t )sin tdt
x
A) f ( x)   C) x  
x
2 x 2
f (t ) cos tdt D) x9  f ( x)
ar

0 0

Key : C,D

x
2
Sol : g ( x)  x   f ( f ).cos t dt
Sm

Let x  0

2
g ( x)  0   f ( f ).cos tdt
0

 2 
 
    f ( f ).cos tdt  (ve)
 0 

Let h( x)  x 9  f ( x)
Let x=0 h( x )   f ( x)  Ve

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 f ( x)  (0,1)
Let x=1
hX )  1  f ( x) (Ve)
 f ( x)  (0,1)

 1   2   x  1 
 
  1    y    1
44. For a real number  , if the system 2 of linear equations, has infinitely
  1   z   1 
 
many solutions, then 1     2  0
Key : 1

 1  2 1 1  2 1 

in
   
 1  1  0 1   2    3 1   
 A B    2 
Sol :   1 1  0 0 1 2 1  
   
   

p.
infinite soltions  1   2  0,1    0    1
now 1     2  1
45. For how many values of p, the cirlce x 2  y 2  2 x  4 y  p  0 and the coordinate have exactly
re
three common points?
Key : 2
Sol : case ( 1)
rad= 2
tP

5  p  2
p  1
but r<d  5  p  1  p  4
ar

now p<-4 and p=-1 is not possible

case (2)
r  d  5  p  1
 p  4 also we get p<-1 as in cae ..(1)
Sm

case (3)
also p  0  x 2  2 x  y 2  4 y  0
cirlce through origin  x( x  1)  y ( y  4)  0  ( x  0, 1), ( y  0, 4)
 2 possibilities
46. The sides of a right angled triangle are in arithmetic progression. If the triangle has area 24 then
what is the length of its smallest side?
Key : 6
Sol : sides (a-d),(a),(a+d)
pyth thum   a  d   (a  d ) 2  a 2  2ad  2ad  a 2
2

 4ad  a 2  a  4d
thus sides  (a  d ), a, (a  d )  3d , 4d ,5d

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1
area of   (3d )(4d )  6d 2  (24)( given)
le

2
 d2  4  d  2
sides  3d , 4d ,5d  6,8,10
length of smallest side=6
47. Words of length 10 are fomred using the letters A,B,C,D,E,F,G,H,I,J. Let x be the number of
such words where no letter is repeated; and let y be the number of such words where exactly one
y
letter is repeated twice and no other letter is repeated. Then , 
9x
Key : 1
10! y
Sol : x  10!and y  10C1  9C8   5

in
2! 9x
 
48. Let f :  be a differentiable function such that f (0)  0, f    3 and f ' (0)  1 .If
2


p.
2
 
g ( x)    f ' (t ) cos ec t  cot t cos ec t f (t )  dt for x   0,  , then lim x 0 g ( x) 
x
 2
Key : 5
 
re
Sol : f (0)  0; f    3; f (0)  1
'

2

f ( x)   [ f ' (t ) cos ect  cot t cos ect.t (t )]dt
2
x
tP

 
 2 2
  cos ect. f (t )     cos ect cot t . f (t )dt    cos ect cot t . f (t )dt
2
x
x x

  
ar

 cos ec . f    cos ecx. f ( x)

2 2
f ( x)
 3
sin x
Sm

 f ( x) 
now
lt
x 0 g ( x ) ltx 0  3  
 sin x 
f ( x)
 3 ltx0
sin x
f ' ( x)
 3 ltx0
cos x
1
 3   3 1  2
1

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C olum ns 1,2 and 3 contain conics, equations of tangents to the conics and points of contact
respectively
Colum n 1 Colum n 2 Colum n 3
1) x2  y2  a2 i) my  m 2 x  a  a 2a 
(P)  , 
m m 
2

(II) x 2  a 2 y 2  a 2 (ii) y  m x  a m 2  1   ma a 
(Q )  , 2 
 m 1 m 1
2

(III) y 2  4 ax (iii) y  m x  a 2m 2  1  a2m 1 

(R)  , 
 a m 1 a m 1 
2 2 2 2

(IV) x 2  a 2 y 2  a 2 (iv) y  m x  a m 1
2 2  a2m 1 
(S)  , 
 a m 1 a m 1 
2 2 2 2

49. If a tangent to a suitable conic ( Column 1) is found to be y  x  8 and its point of contact is (

in
8,16), then which of the following options is the only CORRECT combination?
A)(III) (ii) (Q) B) (III) (i) (P) C) (II) (iv) (R) D) (I) (ii) (Q)
Key : B

p.
a
Sol : y 2  4ax Equation of tangent y  mx 
m
given y  x  8
m = 1, c= 8
re
a
but c 
m
a a
8  8
m 1
tP

a 8
 a 29 
  m 2 , m    8,16 
 
ar

50. For a  2, if a tangent is derawn to a suitable conic (Column 1) at the point of contact (-1,1),
then which of the following options is the only CORRECCT combination for obtaining its equation?
A) (I) (ii) (Q) B) (III) (i) (Q) C) (II) (ii) (Q) D) (III) (i) (P)
Key : A
Sm

 a 2 m b 2 
Sol :  , .
 c c 

c  a 2 x2  b2

c  2x2  1
 a 2 m 1 
 , 
 2m  1 2 x  1 
2 2

 1
51. The tangent to a suitable conic ( Column 1) at  3,  is found to be 3 x  2 y  4, then which of
 2
the following options is the only CORRECT combination?
A) (IV) (iii) (S) B) (II) (iv) (R) C) (II) (iii) (R) D) (IV)(iv) (S)

21 May 2017 JEE ADVANCED 2017 P1 QUESTION PAPER (CODE-3) 

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Key : B
x2 y 2
Sol :   1  (1)
a2 1
y  mx  a 2 m 2  1  (2)

3
y x2
2
3
m ,c2
2
c2  a 2m2  b2
 a2  4  a  2

in
Let f  x   x  log e x  x log e x , x   0,  

p.
 Column 1 contains information about zeros of f  x  . f '  x  and f "  x 
 Column 2 contains information about the limiting behavior of f  x  , f '  x  and f "  x  at infinity
 Column 3 contains information about increasing decreasing nature of f  x  and f '  x 
Column 1 Column 2 Column 3
re

(I) f  x   0 for some x  1, e 2
 (i) lim x   f  x   0 (P) f is increasing in (0,1)

(II) f '
 x   0 for some x  1, e  (ii) lim x   f  x    (Q) f is decreasing in ( e,e 2)

(III) f  x   0 for some x   0,1

'
lim x   f '  x    (R) f’ is increasing in ( 0.1)

f "  x   0 for some x  1, e  lim x   f "  x   0

tP

(IV) (S) f’ is decreasing in (e,e 2)

ar

52. Which of the following options is the only CORRECT combination?

A) (IV) (iv) (S) B) (II) (ii) (Q) C) (I) (i) (P) D) (III) (iii) (R)
Key : B) (II) (ii) (Q)
Sol : f  x   x  log e n  x log e n
Sm

1  1 
f '  x   1    x  logex 
x  x 
1
  lo g x
e
x
1 1
f "  x   
x2 x
(I) f 1  1  0

f  e 2   2  e 2  0 (T )

( II ) f 1  1  0
'

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1
f ' e  10 T
e
( III ) f
'
0  

f '
1   1 F 
( IV ) f
"
1    2
1 1
f " e    (F)
e2 e

(i) Lt x  log e x  x log e x  0 (F )

x

(ii) Lt f  x    (T )

in
x 

(iii) Lt f '  x    T 
x 

(iv) Lt f "  x   0 T 
x 

p.
(P) f '  x   0 (T )

f '  x   0  log x  0  e, e 2  (T )
1
(Q)
4
re
 1 x 
(R) f "  x   0   2   0  0,1 ( F )
 x 

f "  x  0
tP

 1 x 
(S)   2   0  e, e2  (T )
 x 
53. Which of the following options is the only INCORRECT combination ?
A) (II) (iii) (P) B) (II) (iv) (Q) C) (I) (iii) (P) D) (III) (i) (R)
ar

Key : D) (III) (i) (R)

Sol : f  x   x  log en  x log en

1  1 
f '  x   1    x  logex 
Sm

x  x 
1
  lo g x
e
x
1 1
f "  x   
x2 x
(I) f 1  1  0

f  e 2   2  e 2  0 (T )

( II ) f 1  1  0
'

1
f ' e  10 T
e

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( III ) f
'
0  

f '
1   1 F 
( IV ) f
"
1    2
1 1
f " e    (F)
e2 e

(i) Lt x  log e x  x log e x  0 (F )

x

(ii) Lt f  x    (T )
x 

(iii) Lt f '  x    T 
x 

in
(iv) Lt f "  x   0 T 
x 

(P) f '  x   0 (T )

f '  x   0  log x  0  e, e 2  (T )

p.
1
(Q)
4
 1 x 
(R) f "  x   0   2   0  0,1 ( F )
 x 
re
f "  x  0
 1 x 
(S)   2   0  e, e2  (T )
 x 
tP

54. Which of the following options is the only CORRECT combination ?

A) (II) (iii) (S) B) (I) (ii) (R) C) (III) (iv) (P) D) (IV) (i)(S)
Key : A
Sol : f  x   x  log en  x log en
ar

1  1 
f '  x   1    x  logex 
x  x 
1
  lo g x
Sm

e
x
1 1
f "  x   
x2 x
(I) f 1  1  0

f  e 2   2  e 2  0 (T )

( II ) f 1  1  0
'

1
f ' e  10 T
e
( III ) f
'
0  

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f '
1   1 F 
( IV ) f
"
1    2
1 1
f " e    (F)
e2 e

(i) Lt x  log e x  x log e x  0 (F )

x 

(ii) Lt f  x    (T )
x 

(iii) Lt f '  x    T 
x 

(iv) Lt f "  x   0 T 
x 

in
(P) f '  x   0 (T )

f '  x   0  log x  0  e, e 2  (T )
1
(Q)
4

p.
 1 x 
(R) f "  x   0   2   0  0,1 ( F )
 x 

f "  x  0
re
 1 x 
(S)   2   0  e, e2  (T )
 x 
tP

*****
ar
Sm

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