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2.0 Student 1: Mass Balance: Stoichiometric Equation

The document discusses the mass balance of a reaction to produce vinyl chloride from two reactants. Mass flow rates of the reactants and products were calculated for production rates ranging from 100,000 to 200,000 pounds per year. Graphs and tables show the relationships between production rate, mass flow rates of species A, B, and C at the inlet and outlet. The overall mass balance was maintained as production rate was varied from 0% to 100%.

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Meck Lotfi
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0% found this document useful (0 votes)
63 views10 pages

2.0 Student 1: Mass Balance: Stoichiometric Equation

The document discusses the mass balance of a reaction to produce vinyl chloride from two reactants. Mass flow rates of the reactants and products were calculated for production rates ranging from 100,000 to 200,000 pounds per year. Graphs and tables show the relationships between production rate, mass flow rates of species A, B, and C at the inlet and outlet. The overall mass balance was maintained as production rate was varied from 0% to 100%.

Uploaded by

Meck Lotfi
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd
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2.

0 STUDENT 1: MASS BALANCE

Overall mass balance

Stoichiometric Equation;

ClCH2CH2Cl CH2CHCl + HCl


A B+C

Where;
Element A: ClCH2CH2Cl with (Molecular Weight = 98.96 g/mol)
Element B: CH2CHCl with (Molecular Weight = 62.50 g/mol)
Element C: HCl with (Molecular Weight = 36.46 g/mol)

Given;
Production Rate : 100000 lbm/year
ṁB : 5384.53 g/hr
ṁC : 5236.97 g/hr
Temperature : 500oC
Conversion : 60% (0.60)
Assuming working days in a year : 351 days

Mass Balance Table


Table 1.0: Mass Balance Table
Types of species Inlet (g/hr) Outlet (g/hr)
A 14209.71 5683.89
B - 5384.64
C - 3141.19
Total 14209.71 14209.71
The production rate for vinyl chloride production was given at 100,000 lbm/year.
Calculation was made based on the change of species mass flowrate if the production rate
increased from 0% to 100%. A graph was plotted for each specific mass increment.

Table 2.1 Increment Table for Each Species Mass Flowrate.


Increment Production Mass Flowrate A Mass Flowrate B Mass Flowrate C
(%) Rate (g/hr) (g/hr) (g/hr)
(lbm/year)
Inlet Outlet Inlet Outlet Inlet Outlet
0 100000 14209.71 5683.89 - 5384.53 - 3141.19
20 120000 17051.31 6820.52 - 6461.44 - 3769.35
40 140000 19893.29 7957.27 - 7538.34 - 4397.57
60 160000 22735.07 9094.03 - 8615.25 - 5025.79
80 180000 25576.96 10230.78 - 9692.19 - 5654.02
100 200000 28418.83 11367.53 - 10769.0 - 6282.24
6
mass flowrate against production rate increment for each species inlet and outlet
250000 30000
28418.83

25576.96
25000
200000
200000
22735.07
180000
Production Rate per year (lbm/year)

19893.29
160000 20000

Mass Flowrate(g/hr)
150000 17051.31 140000

14209.71 120000 15000

100000
100000
10769.06
11367.53
9692.19
10230.78 10000
8615.25
9094.03
7538.34
7957.27
6461.44
6820.52 6282.24
5384.53
50000 5654.02
5683.89 5025.79
4397.57 5000
3769.35
3141.19

0 0
0 20 40 60 80 100

production rate per yearProduction RateA Increment


Outlet (%) C
Outlet Outlet B Inlet A

Figure 1.0 shows a graph of Mass Flowrate against Production Rate Increment for Each Species Inlet and Outlet was plotted.
Increment Tables for 20%,40%,60%,80% and 100% from Production Rate

Table 2.2 shows the increment of 20% from actual production rate.
Species Inlet (g/hr) Outlet (g/hr)
A 17051.31 6820.52
B - 6461.44
C - 3769.35
Total 17051.31 17051.31

Table 2.3 shows the increment of 40% from actual production rate.
Species Inlet (g/hr) Outlet (g/hr)
A 19893.29 7957.27
B - 7538.34
C - 4397.57
Total 19893.29 19893.29

Table 2.4 shows the increment of 60% from actual production rate.
Species Inlet (g/hr) Outlet (g/hr)
A 22735.07 9094.03
B - 8615.25
C - 5025.79
Total 22735.07 22735.07

Table 2.5 shows the increment of 80% from actual production rate.
Species Inlet (g/hr) Outlet (g/hr)
A 25576.96 10230.78
B - 9692.19
C - 5654.02
Total 25576.96 25576.96

Table 2.6 shows the increment of 100% from actual production rate.
Species Inlet (g/hr) Outlet (g/hr)
A 28418.83 11367.53
B - 10769.06
C - 6282.24
Total 28418.83 28418.83
STUDENT 1: MASS BALANCE

Mass Flowrate from The Production Rate of Vinyl Chloride:


lbm 1kg 1000 g 1 yr 1day
100000   
ṁ= yr 2.20462lbm 1kg 351day 24hr
ṁ = 5384.53 g/hour

Species Inlet (g/hr) Outlet (g/hr)


FB  FA0 X FA  FA0 (1  X )
86.15428 mol FA  143.59047 mol  (1  0.6)
FA0  hr hr
0.60 FA  57.436188 mol
A hr
FA0  143.59047 mol
hr 
g

g m  57.436188 mol hr  98.96 mol
m  143.59047 mol hr  98.96 mol 
g

g m  5683.89 hr
m  14209.71 hr
FB 0  0 mol 5384.53
g
hr
 FB  hr
g
m  FB 0  M m 62.5
 mol
B g
m0 hr FB  86.15428 mol
hr

g
m  86.15428 mol hr  62.5 mol

g
m  5384.64 hr
FC 0  0 mol FC  FA0 X
hr
 FC  143.59047 mol  0.6
hr
m  FC 0  M m
 FC  86.15428 mol
hr
C
m  0g
hr 
g
m  86.15428 mol hr  36.46 mol

g
m  3141.19 hr
Total 14209.71 14209.71
Increment of 20%
lbm 1kg 1000 g 1 yr 1day
120000   
ṁ= yr 2.20462lbm 1kg 351day 24hr
ṁ = 6461.44 g/hour

Species Inlet (g/hr) Outlet (g/hr)


FB  FA0 X FA  FA0 (1  X )
103.38304 mol FA  172.30507 mol  (1  0.6)
FA0  hr hr
0.60 FA  68.92203 mol
A hr
FA0  172.30507 mol
hr 
g

g m  68.92203 mol hr  98.96 mol
m  172.30507 mol hr  98.96 mol 
g

g m  6820.52 hr
m  17051.31 hr
FB 0  0 mol 6461.44
g
hr
 FB  hr
g
m  FB 0  M m 62.5
 mol
B g
m0 hr FB  103.38304 mol
hr

g
m  103.38304 mol hr  62.5 mol

g
m  6461.44 hr
FC 0  0 mol FC  FA0 X
hr
 FC  172.30507 mol  0.6
hr
m  FC 0  M m
 FC  103.38304 mol
hr
C
m  0g
hr 
g
m  103.38304 mol hr  36.46 mol

g
m  3769.35 hr
Total 17051.31 17051.31
Increment of 40%
lbm 1kg 1000 g 1 yr 1day
140000   
ṁ= yr 2.20462lbm 1kg 351day 24hr
ṁ = 7538.3437 g/hour

Species Inlet (g/hr) Outlet (g/hr)


FB  FA0 X FA  FA0 (1  X )
120.6135 mol FA  201.0225 mol  (1  0.6)
FA0  hr hr
0.60 FA  80.409 mol
A hr
FA0  201.0225 mol
hr 
g

g m  80.409 mol hr  98.96 mol
m  201.0225 mol hr  98.96 mol 
g

g m  7957.27 hr
m  19893.19 hr
FB 0  0 mol 7538.3437
g
hr
 FB  hr
g
m  FB 0  M m 62.5
 mol
B g
m0 hr FB  120.6135 mol
hr

g
m  120.6135 mol hr  62.5 mol

g
m  7538.34 hr
FC 0  0 mol FC  FA0 X
hr
 FC  201.0225 mol  0.6
hr
m  FC 0  M m
 FC  120.6135 mol
hr
C
m  0g
hr 
g
m  120.6135 mol hr  36.46 mol

g
m  4397.57 hr
Total 19893.19 19893.19
Increment of 60%
lbm 1kg 1000 g 1 yr 1day
160000   
ṁ= yr 2.20462lbm 1kg 351day 24hr
ṁ = 8615.25 g/hour

Species Inlet (g/hr) Outlet (g/hr)


FB  FA0 X FA  FA0 (1  X )
137.8440 mol FA  229.74 mol  (1  0.6)
FA0  hr hr
0.60 FA  91.896 mol
A hr
FA0  229.74 mol
hr 
g

g m  91.896 mol hr  98.96 mol
m  229.74 mol hr  98.96 mol 
g

g m  9094.03 hr
m  22735.07 hr
FB 0  0 mol 8615.25
g
hr
 FB  hr
g
m  FB 0  M m 62.5
 mol
B g
m0 hr FB  137.844 mol
hr

g
m  137.844 mol hr  62.5 mol

g
m  8615.25 hr
FC 0  0 mol FC  FA0 X
hr
 FC  229.74 mol  0.6
hr
m  FC 0  M m
 FC  137.844 mol
C g hr
m0 hr 
g
m  137.844 mol hr  36.46 mol

g
m  5025.79 hr
Total 22735.07 22735.07
Increment of 80%
lbm 1kg 1000 g 1 yr 1day
180000   
ṁ= yr 2.20462lbm 1kg 351day 24hr
ṁ = 9692.15619 g/hour

Species Inlet (g/hr) Outlet (g/hr)


FB  FA0 X FA  FA0 (1  X )
155.075 mol FA  258.4575 mol  (1  0.6)
FA0  hr hr
0.60 FA  103.383 mol
A hr
FA0  258.4575 mol
hr 
g

g m  103.383 mol hr  98.96 mol
m  258.4575 mol hr  98.96 mol 
g

g m  10230.78 hr
m  25576.96 hr
FB 0  0 mol 9692.15619
g
hr
 FB  hr
g
m  FB 0  M m 62.5
 mol
B g
m0 hr FB  155.075 mol
hr

g
m  155.075 mol hr  62.5 mol

g
m  9692.19 hr
FC 0  0 mol FC  FA0 X
hr
 FC  258.4575 mol  0.6
hr
m  FC 0  M m
 FC  155.075 mol
hr
C
m  0g
hr 
g
m  155.075 mol hr  36.46 mol

g
m  5654.02 hr
Total 25576.95 25576.95
Increment of 100%
lbm 1kg 1000 g 1yr 1day
200000   
ṁ= yr 2.20462lbm 1kg 351day 24hr
ṁ = 10769.06 g/hour

Species Inlet (g/hr) Outlet (g/hr)


FB  FA0 X FA  FA0 (1  X )
172.30496 mol FA  287.17493 mol  (1  0.6)
FA0  hr hr
0.60 FA  114 .86997 mol
A hr
FA0  287.17493 mol
hr 
g
 m  114 .86997 mol hr  98.96 mol
m  287.17493 mol hr  98.96 g
mol 
g

g m  11367 .53 hr
m  28418.83 hr
FB 0  0 mol 10769.06
g
hr
 FB  hr
g
mF B0  Mm 62.5
 mol
B g
m0 hr FB  172.30496 mol
hr

g
m  172.30496 mol hr  62.5 mol

g
m  10769.06 hr
FC 0  0 mol FC  FA0 X
hr
 FC  287.17493 mol  0.6
hr
mF C0  Mm
 FC  172.30496 mol
hr
C
m  0g
hr 
g
m  172.30496 mol hr  36.46 mol

g
m  6282.24 hr
Total 28418.83 28418.83

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