Safety Data Sheet

According to Globally Harmonized System of Classification and Labelling

of Chemicals (GHS)

PCTSB Natural Gas

Version 1.0 Release Date: 2017.08.28

1. PRODUCT AND COMPANY IDENTIFICATION

Product name : PCTSB Natural Gas

Synonyms : Natural Gas, Fuel Gas
Recommended use : Fuel gas

Manufacturer or supplier's details

Headquarters
Company : PETRONAS Upstream Business
Address : Level 56, Tower 2, PETRONAS Twin Towers,
Kuala Lumpur City Centre,
50088 Kuala Lumpur,
Malaysia

Plant Site
Company : PETRONAS Carigali (Turkmenistan) Sdn Bhd
Address : 81 (block-B), Turkmenbashy Shayoly
744027, Ashgabat
Turkmenistan
Telephone : (+993) 12 398000
2. HAZARDS IDENTIFICATION

GHS Classification
Flammable gases : Category 1
Gases under pressure : Compressed gas
Reproductive toxicity : Category 2
GHS Label element
Hazard pictograms :

Signal word : Danger

Hazard statements : H220 Extremely flammable gas.
H280 Contains gas under pressure; may explode if heated.
H361 Suspected of damaging fertility or the unborn child.
Precautionary statements : Prevention:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read
and understood.
P210 Keep away from heat, hot surfaces, sparks, open flames
and other ignition sources. No smoking.
P280 Wear protective gloves/ protective clothing/ eye
protection/ face protection.
Response:
P308 + P313 IF exposed or concerned: Get medical advice/
attention.
P377 Leaking gas fire: Do not extinguish, unless leak can be
stopped safely.
P381 In case of leakage, eliminate all ignition sources.
Storage:
P405 Store locked up.
P410 + P403 Protect from sunlight. Store in a well-ventilated
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place.
Disposal:
P501 Dispose of contents/ container to an approved waste
disposal plant.

Other hazards which do not result in classification

No information available.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : UVCB

Hazardous components
Chemical Name CAS-No. Concentration (%)
Methane 74-82-8 >= 70 - < 90
Ethane 74-84-0 >= 5 - < 10
Propane 74-98-6 >= 5 - < 10
Butane 106-97-8 >= 1 - < 3.5
Isobutane 75-28-5 >= 1 - < 3.5
N-hexane 110-54-3 >= 0.1 - < 1

Other information
This product may contain traces of hydrogen sulphide and mercury which, by inhalation can
cause headache, dizziness, cough

4. FIRST AID MEASURES

If inhaled : If unconscious, place in recovery position and seek medical

advice.
If symptoms persist, call a medical doctor.
In case of eye contact : Flush eyes with water as a precaution.
Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.
If swallowed : Keep respiratory tract clear.
Do NOT give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
Take victim immediately to hospital.
If symptoms persist, call a medical doctor.
Induce vomiting immediately and call a medical doctor.
General advice : Move out of dangerous area.
Show this safety data sheet to the doctor in attendance.
Do not leave the victim unattended.
Most important symptoms : No information available.
and effects, both acute and
delayed

5. FIREFIGHTING MEASURES

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Suitable extinguishing media : Alcohol-resistant foam

Dry chemical
Carbon dioxide (CO2)
Unsuitable extinguishing : High volume water jet
media
Specific hazards during : Do not allow run-off from fire fighting to enter drains or water
firefighting courses.
Specific extinguishing : Collect contaminated fire extinguishing water separately. This
methods must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
be disposed off in accordance with local regulations.
For safety reasons in case of fire, cans should be stored
separately in closed containments.
Use a water spray to cool fully closed containers.
Special protective equipment : Wear self-contained breathing apparatus for firefighting if
for firefighters necessary.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, : Use personal protective equipment.

protective equipment and Ensure adequate ventilation.Remove all sources of ignition.
emergency procedures Evacuate personnel to safe areas.
Beware of vapours accumulating to form explosive
concentrations. Vapours can accumulate in low areas.
Environmental precautions : If the product contaminates rivers and lakes or drains inform
respective authorities.
Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.

7. HANDLING AND STORAGE

Advice on protection against : Do not spray on a naked flame or any incandescent material.
fire and explosion Keep away from open flames, hot surfaces and sources of
ignition.
Take necessary action to avoid static electricity discharge
(which might cause ignition of organic vapours).
Use only explosion-proof equipment.
Normal measures for preventive fire protection.
Advice on safe handling : Take precautionary measures against static discharges.
Do not breathe vapours/dust.
Avoid exposure - obtain special instructions before use.
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the
application area.
Provide sufficient air exchange and/or exhaust in work rooms.
Open drum carefully as content may be under pressure.
Dispose of rinse water in accordance with local and national
regulations.
Avoid contact with skin and eyes.
Conditions for safe storage : Prevent unauthorized access.
Keep container tightly closed in a dry and well-ventilated
place.
Observe label precautions.
Electrical installations / working materials must comply with
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the technological safety standards.

No smoking.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Contains no substances with occupational exposure limit values.
Personal protective equipment
Hand protection
Remarks : The suitability for a specific workplace should be discussed
with the producers of the protective gloves.
Eye protection : Eye wash bottle with pure water.
Tightly fitting safety goggles.
Skin and body protection : Impervious clothing.
Choose body protection according to the amount and
concentration of the dangerous substance at the work place.
Hygiene measures : Wash hands before breaks and at the end of workday.
When using do not eat or drink.
When using do not smoke.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : Compressed gas

Colour : Colourless
Odour : Hydrocarbon-like
Odour Threshold : No data available
pH : No data available
Melting point/freezing point : No data available
Initial boiling point and boiling : No data available
range
Flash point : No data available
Evaporation rate : No data available
Flammability (solid, gas) : Extremely flammable gas.
Upper explosion limit : 15 %(V)
Lower explosion limit : 5 %(V)
Vapour pressure : No data available
Relative vapour density : 0.62
Density : 0.0008 g/cm3
Solubility(ies)
Water solubility : No data available
Partition coefficient: n- : No data available
octanol/water
Decomposition temperature : No data available
Viscosity, dynamic : No data available
Viscosity, kinematic : No data available
Molecular weight : 19 g/mol

10. STABILITY AND REACTIVITY

Reactivity : Hazardous polymerisation does not occur.

Chemical stability : Stable under normal conditions.
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Possibility of hazardous : No dangerous reaction known under conditions of normal use.

reactions
Conditions to avoid : Heat, sparks, flame and build-up of static electricity.
Incompatible materials : Strong oxidizing agents.
Hazardous decomposition : Fumes, smoke, carbon monoxide
products

11. TOXICOLOGICAL INFORMATION

Acute toxicity
Components:
Methane:
Acute oral toxicity : Remarks: No data available
Acute inhalation toxicity : LC50 (Mouse): 353553 ppm
Exposure time: 4 h
Acute dermal toxicity : Remarks: No data available
Ethane:
Acute oral toxicity : Remarks: No data available
Acute inhalation toxicity : Remarks: No data available
Acute dermal toxicity : Remarks: No data available
Propane:
Acute oral toxicity : Remarks: No data available
Acute inhalation toxicity : LC50 (Rat): > 800000 ppm
Exposure time: 15 min
Acute dermal toxicity : Remarks: No data available
Butane:
Acute oral toxicity : Remarks: No data available
Acute inhalation toxicity : LC50 (Rat): 277374 ppm
Exposure time: 4 h
Acute dermal toxicity : Remarks: No data available
Isobutane:
Acute oral toxicity : Remarks: No data available
Acute inhalation toxicity : LC50 (Mouse, male): 1,237 mg/l, 520400 ppm
Exposure time: 2 h
Acute dermal toxicity : Remarks: No data available
N-hexane:
Acute oral toxicity : LD50 (Rat): 25,000 mg/kg
Acute inhalation toxicity : LC50 (Rat): 169 mg/l
Exposure time: 4 h
Acute dermal toxicity : LD50 (Rabbit): 3,297 mg/kg

Skin corrosion/irritation
Components:
Methane:
Remarks : No data available
Ethane:
Remarks : No data available
Propane:
Remarks : No data available
Butane:
Remarks : No data available
Isobutane:
Remarks : No data available
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N-hexane:
Species : Rabbit
Exposure time : 24 h
Result : Skin irritation

Serious eye damage/eye irritation

Components:
Methane:
Remarks : No data available
Ethane:
Remarks : No data available
Propane:
Remarks : No data available
Butane:
Remarks : No data available
Isobutane:
Remarks : No data available
N-hexane:
Species : Rabbit
Result : No eye irritation

Respiratory or skin sensitisation

Components:
Methane:
Exposure routes : Inhalation
Remarks : No data available
Exposure routes : Skin contact
Remarks : No data available
Ethane:
Exposure routes : Inhalation
Remarks : No data available
Exposure routes : Skin contact
Remarks : No data available
Propane:
Exposure routes : Inhalation
Remarks : No data available
Exposure routes : Skin contact
Remarks : No data available
Butane:
Exposure routes : Inhalation
Remarks : No data available
Exposure routes : Skin contact
Remarks : No data available
Isobutane:
Exposure routes : Inhalation
Remarks : No data available
Exposure routes : Skin contact
Remarks : No data available
N-hexane:
Exposure routes : Inhalation
Remarks : No data available
Exposure routes : Skin contact
Remarks : No data available

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Germ cell mutagenicity

Components:
Methane:
Germ cell mutagenicity - : No data available
Assessment
Ethane:
Germ cell mutagenicity - : In vivo tests did not show mutagenic effects
Assessment
Propane:
Germ cell mutagenicity - : In vivo tests did not show mutagenic effects
Assessment
Butane:
Germ cell mutagenicity - : In vivo tests did not show mutagenic effects
Assessment
Isobutane:
Germ cell mutagenicity - : Did not show mutagenic effects in animal experiments.
Assessment
N-hexane:
Germ cell mutagenicity - : No data available
Assessment

Carcinogenicity
Components:
Methane:
Carcinogenicity - : No data available
Assessment
Ethane:
Carcinogenicity - : No data available
Assessment
Propane:
Carcinogenicity - : No data available
Assessment
Butane:
Carcinogenicity - : No data available
Assessment
Isobutane:
Carcinogenicity - : No data available
Assessment
N-hexane:
Carcinogenicity - : No data available
Assessment

Reproductive toxicity
Components:
Methane:
Reproductive toxicity - : No data available
Assessment
Ethane:
Reproductive toxicity - : No toxicity to reproduction
Assessment
Propane:
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Reproductive toxicity - : No toxicity to reproduction

Assessment
Butane:
Reproductive toxicity - : No data available
Assessment
Isobutane:
Reproductive toxicity - : Did not show reproductive toxicity in animal study.
Assessment
N-hexane:
Reproductive toxicity - : Suspected to cause disturbances in fertility.
Assessment

STOT - single exposure

Components:
Methane:
Remarks : No data available
Ethane:
Remarks : No data available
Propane:
Assessment : May cause drowsiness or dizziness.
Butane:
Assessment : May cause drowsiness or dizziness.
Isobutane:
Target Organs : Central nervous system
Assessment : Slight disturbances of the central nervous system
N-hexane:
Remarks : No data available

STOT - repeated exposure

Components:
Methane:
Remarks : No data available
Ethane:
Assessment : The substance or mixture is not classified as specific target
organ toxicant, repeated exposure.
Propane:
Remarks : No data available
Butane:
Remarks : No data available
Isobutane:
Assessment : NOAEC ( Rat, Inhalation) = 4000 ppm (7214mg/m3)
Remarks : OECD Test Guideline 422
N-hexane:
Remarks : No data available

Aspiration toxicity
Components:
Methane:
Statement on Aspiration Tox. : No data available
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Ethane:
Statement on Aspiration Tox. : No data available
Propane:
Statement on Aspiration Tox. : No data available
Butane:
Statement on Aspiration Tox. : No data available
Isobutane:
Statement on Aspiration Tox. : No data available
N-hexane:
Statement on Aspiration Tox. : No data available

12. ECOLOGICAL INFORMATION

Ecotoxicity
Product:
Further information
The following percentage of the mixture consists of ingredient(s) with unknown hazards to the
aquatic environment: 3 %
Components:
Methane:
Toxicity to fish : LC50 (Fish): 147.54 mg/l
Exposure time: 96 h
Toxicity to daphnia and other : LC50 (Daphnia magna (Water flea)): 69.43 mg/l
aquatic invertebrates Exposure time: 48 h
Toxicity to algae : EC50 (Algae): 19.37 mg/l
Exposure time: 96 h
Toxicity to microorganisms : Remarks: No data available
Toxicity to fish (Chronic : Remarks: No data available
toxicity)
Toxicity to daphnia and other : Remarks: No data available
aquatic invertebrates
(Chronic toxicity)
Ethane:
Toxicity to fish : Remarks: No data available
Toxicity to daphnia and other : Remarks: No data available
aquatic invertebrates
Toxicity to algae : Remarks: No data available
Toxicity to microorganisms : Remarks: No data available
Toxicity to fish (Chronic : Remarks: No data available
toxicity)
Toxicity to daphnia and other : Remarks: No data available
aquatic invertebrates
(Chronic toxicity)
Propane:
Toxicity to fish : Remarks: No data available
Toxicity to daphnia and other : Remarks: No data available
aquatic invertebrates
Toxicity to algae : Remarks: No data available
Toxicity to microorganisms : Remarks: No data available
Toxicity to fish (Chronic : Remarks: No data available
toxicity)
Toxicity to daphnia and other : Remarks: No data available

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aquatic invertebrates
(Chronic toxicity)
Butane:
Toxicity to fish : LC50 (Fish): 27.98 mg/l
Exposure time: 96 h
Toxicity to daphnia and other : LC50 (Daphnia (water flea)): 14.22 mg/l
aquatic invertebrates Exposure time: 48 h
Toxicity to algae : EC50 (Green Algae): 7.71 mg/l
Exposure time: 96 h
Toxicity to microorganisms : Remarks: No data available
Toxicity to fish (Chronic : Remarks: No data available
toxicity)
Toxicity to daphnia and other : Remarks: No data available
aquatic invertebrates
(Chronic toxicity)
Isobutane:
Toxicity to fish : LC50 (Fish): 147.54 mg/l
Exposure time: 96 h
Toxicity to daphnia and other : LC50 (Daphnia (water flea)): 27.14 mg/l
aquatic invertebrates Exposure time: 48 h
Toxicity to algae : EC50 (Green Algae): 8.57 mg/l
Exposure time: 96 h
Toxicity to microorganisms : Remarks: No data available
Toxicity to fish (Chronic : Remarks: No data available
toxicity)
Toxicity to daphnia and other : Remarks: No data available
aquatic invertebrates
(Chronic toxicity)
N-hexane:
Toxicity to fish : LL50 (Oncorhynchus mykiss (rainbow trout)): 12.15 mg/l
Exposure time: 96 h
Toxicity to daphnia and other : EL50 (Daphnia magna (Water flea)): 21.85 mg/l
aquatic invertebrates Exposure time: 48 h
Toxicity to algae : EL50 (Selenastrum capricornutum (green algae)): 9.285 mg/l
Exposure time: 72 h
Toxicity to microorganisms : EL50 (Tetrahymena pyriformis): 48.39 mg/l
Exposure time: 48 h
Toxicity to fish (Chronic : NOELR (Oncorhynchus mykiss (rainbow trout)): 2.8 mg/l
toxicity) Exposure time: 28 d
Toxicity to daphnia and other : NOELR (Daphnia magna (Water flea)): 4.888 mg/l
aquatic invertebrates Exposure time: 21 d
(Chronic toxicity)

Persistence and degradability

Components:
Methane:
Biodegradability : Result: Readily biodegradable
Ethane:
Biodegradability : Result: Readily biodegradable
Propane:
Biodegradability : Result: Readily biodegradable
Butane:
Biodegradability : Result: Readily biodegradable
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Isobutane:
Biodegradability : Result: Readily biodegradable
N-hexane:
Biodegradability : Result: Readily biodegradable

Bioaccumulative potential
Components:
Methane:
Bioaccumulation : Remarks: No data available
Partition coefficient: n- : log Pow: 1.09
octanol/water
Ethane:
Bioaccumulation : Remarks: No data available
Partition coefficient: n- : log Pow: 2.8
octanol/water
Propane:
Bioaccumulation : Remarks: No data available
Partition coefficient: n- : log Pow: 1.81
octanol/water
Butane:
Bioaccumulation : Remarks: No data available
Partition coefficient: n- : log Pow: 1.81
octanol/water
Isobutane:
Bioaccumulation : Remarks: No data available
Partition coefficient: n- : log Pow: 2.8
octanol/water
N-hexane:
Bioaccumulation : Bioconcentration factor (BCF): 501.19

Partition coefficient: n- : log Pow: 4 (20 °C)

octanol/water

Mobility in soil
Components:
Methane:
Mobility : Medium: Soil
Remarks: High mobility in soils.
Ethane:
Mobility : Remarks: No data available
Propane:
Mobility : Remarks: No data available
Butane:
Mobility : Medium: Soil
Remarks: Moderate to low mobility.
Isobutane:
Mobility : Medium: Soil
Remarks: No data available
N-hexane:
Mobility : Medium: Soil
Remarks: High mobility in soils.

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Other adverse effects

Product:
Additional ecological : No data available
information
Components:
Methane:
Additional ecological : No data available
information
Ethane:
Additional ecological : No data available
information
Propane:
Additional ecological : No data available
information
Butane:
Additional ecological : No data available
information
Isobutane:
Additional ecological : No data available
information
N-hexane:
Additional ecological : Electrostatic chargeable.
information

13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : Do not dispose of waste into sewer.
Do not contaminate ponds, waterways or ditches with
chemical or used container.
Send to a licensed waste management company.
Contaminated packaging : Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers.
Do not burn, or use a cutting torch on the empty drum.

14. TRANSPORT INFORMATION

International Regulation
UNRTDG
UN number : UN 1954
Proper shipping name : COMPRESSED GAS, FLAMMABLE, N.O.S.
Class : 2.1
Packing group : Not assigned by regulation
Labels : 2.1
IATA-DGR
UN/ID No. : UN 1954
Proper shipping name : Compressed gas, flammable, n.o.s.
Class : 2.1
Packing group : Not assigned by regulation
Packing instruction (cargo : 200
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aircraft)
Packing instruction : Not permitted for transport
(passenger aircraft)
IMDG-Code
UN number : UN 1954
Proper shipping name : COMPRESSED GAS, FLAMMABLE, N.O.S.
Class : 2.1
Packing group : Not assigned by regulation
Labels : 2.1
EmS Code : F-D, S-U
Marine pollutant : no
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.

15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or

mixture

The components of this product are reported in the following inventories:

CH INV : On the inventory, or in compliance with the inventory.
TSCA : On TSCA Inventory.
DSL : All components of this product are on the Canadian DSL
AICS : On the inventory, or in compliance with the inventory.
NZIoC : On the inventory, or in compliance with the inventory.
ENCS : Not in compliance with the inventory
ISHL : Not in compliance with the inventory
KECI : On the inventory, or in compliance with the inventory.
PICCS : On the inventory, or in compliance with the inventory.
IECSC : On the inventory, or in compliance with the inventory.

16. OTHER INFORMATION

Revision Date : 2017.08.28

Sources of key data used to : ECHA - European Chemicals Agency
compile the Safety Data GESTIS database on hazardous substances - DGUV
Sheet
Full text of other abbreviations
(Q)SAR - (Quantitative) Structure Activity Relationship
ACGIH - American Conference of Governmental Industrial Hygienists
AICS - Australian Inventory of Chemical Substances
ANTT - National Agency for Transport by Land of Brazil
ASTM - American Society for the Testing of Materials
bw - Body weight
CCHC - Chemicals Classification and Hazard Communication
CMR - Carcinogen, Mutagen or Reproductive Toxicant
CPR - Controlled Products Regulations
DIN - Standard of the German Institute for Standardisation
DSL - Domestic Substances List (Canada)
ECx - Concentration associated with x% response
ELx - Loading rate associated with x% response
EmS - Emergency Schedule
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ENCS - Existing and New Chemical Substances (Japan)

ErCx - Concentration associated with x% growth rate response
ERG - Emergency Response Guide
GHS - Globally Harmonized System
GLP - Good Laboratory Practice
IARC - International Agency for Research on Cancer
IATA - International Air Transport Association
IBC - International Code for the Construction and Equipment of Ships carrying
Dangerous Chemicals in Bulk
IC50 - Half maximal inhibitory concentration
ICAO - International Civil Aviation Organization
ICOP - Industry Code of Practice on Chemicals Classification and Hazard
Communication
IECSC - Inventory of Existing Chemical Substances in China
IMDG - International Maritime Dangerous Goods
IMO - International Maritime Organization
ISHL - Industrial Safety and Health Law (Japan)
ISO - International Organisation for Standardization
KECI - Korea Existing Chemicals Inventory
LC50 - Lethal Concentration to 50 % of a test population
LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose)
MARPOL - International Convention for the Prevention of Pollution from Ships
MY PEL - Malaysian Permissible Exposure Limit
n.o.s. - Not Otherwise Specified
Nch - Chilean Norm
NITE - National Institute of Technology and Evaluation
NO(A)EC - No Observed (Adverse) Effect Concentration
NO(A)EL - No Observed (Adverse) Effect Level
NOELR - No Observable Effect Loading Rate
NOM - Official Mexican Norm
NTP - National Toxicology Program
NZIoC - New Zealand Inventory of Chemicals
OCSPP - Office of Chemical Safety and Pollution Prevention
OECD - Organization for Economic Co-operation and Development
PBT - Persistent, Bioaccumulative and Toxic
PICCS - Philippines Inventory of Chemicals and Chemical Substances
REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council
concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals
SADT - Self-Accelerating Decomposition Temperature
SDS - Safety Data Sheet
STEL - Short Term Exposure Limit
TCSI - Taiwan Chemical Substance Inventory
TDG - Transportation of Dangerous Goods
TSCA - Toxic Substances Control Act (United States)
TWA - Time Weighted Average
UN - United Nations
UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods
UVCB - Unknown or Variable Composition, Complex Reaction Products and
Biological Materials
vPvB - Very Persistent and Very Bioaccumulative
WHMIS - Workplace Hazardous Materials Information System

Further information
Other information : This product may contain traces of hydrogen sulphide and
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mercury which, by inhalation can cause headache, dizziness,

cough
Disclaimer
To the best of PETRONAS knowledge, the information contained herein is accurate and
reliable as of the date of publication. Any use of information provided should be undertaken in
consultation with a professional with the appropriate expertise, as necessary in the
circumstances. No warranty, express or implied, is given as to the quality, accuracy, reliability,
applicability or completeness of the contents of this SDS. The information presented here
pertains only to the product as shipped. It is the responsibility of the customer to ensure that
any activities relating to the product comply with all federal, state or local laws. Any hazards
associated with any product regulatory requirements are subject to change and may differ
between various locations. Except to the extent required by law, re-publication or
retransmission of this SDS, in whole or in part, is strictly prohibited. PETRONAS does not take
responsibility for use, transportation, storage, handling, packaging or disposal of the product
that is beyond our knowledge and recommendation by this SDS.

Product Stewardship Advisory:

PETRONAS aims to increase awareness of all the hazards associated with the storage,
handling and use of its products. Thoroughly reviewing the accompanying Safety Data Sheets
and disseminating the information to all dependent and interested parties is an essential part
of any 'Responsible Care' programme.

TM / EN

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