MSDS LPG by Airgas (2018)
MSDS LPG by Airgas (2018)
Propane
Section 1. Identification
GHS product identifier : Propane
Chemical name : propane
Other means of : Propyl hydride; n-Propane; Dimethyl methane; Bottled gas; propane in gaseous state;
identification propane liquefied, n-Propane; Dimethylmethane; Freon 290; Liquefied petroleum gas;
Lpg; Propyl
hydride; R 290; C3H8; UN 1075; UN 1978; A-108; Hydrocarbon propellant.
Product type : Liquefied gas
Product use : Synthetic/Analytical chemistry.
Synonym : Propyl hydride; n-Propane; Dimethyl methane; Bottled gas; propane in gaseous state;
propane liquefied, n-Propane; Dimethylmethane; Freon 290; Liquefied petroleum gas;
Lpg; Propyl
hydride; R 290; C3H8; UN 1075; UN 1978; A-108; Hydrocarbon propellant.
SDS # : 001045
Supplier's details : Airgas USA, LLC and its affiliates
259 North Radnor-Chester Road
Suite 100
Radnor, PA 19087-5283
1-610-687-5253
Date of issue/Date of revision : 5/6/2018 Date of previous issue : 6/28/2017 Version :1 1/12
Propane
Specific hazards arising : Contains gas under pressure. Extremely flammable gas. In a fire or if heated, a
from the chemical pressure increase will occur and the container may burst, with the risk of a subsequent
explosion. The vapor/gas is heavier than air and will spread along the ground. Gas
may accumulate in low or confined areas or travel a considerable distance to a source
of ignition and flash back, causing fire or explosion.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training. Contact supplier immediately for specialist advice. Move containers from fire
area if this can be done without risk. Use water spray to keep fire-exposed containers
cool. If involved in fire, shut off flow immediately if it can be done without risk. If this is
impossible, withdraw from area and allow fire to burn. Fight fire from protected location
or maximum possible distance. Eliminate all ignition sources if safe to do so.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode. For
incidents involving large quantities, thermally insulated undergarments and thick textile
or leather gloves should be worn.
Date of issue/Date of revision : 5/6/2018 Date of previous issue : 6/28/2017 Version :1 3/12
Propane
Environmental precautions : Ensure emergency procedures to deal with accidental gas releases are in place to avoid
contamination of the environment. Avoid dispersal of spilled material and runoff and
contact with soil, waterways, drains and sewers. Inform the relevant authorities if the
product has caused environmental pollution (sewers, waterways, soil or air).
Conditions for safe storage, : Store in accordance with local regulations. Store in a segregated and approved area.
including any Store away from direct sunlight in a dry, cool and well-ventilated area, away from
incompatibilities incompatible materials (see Section 10). Eliminate all ignition sources. Cylinders
should be stored upright, with valve protection cap in place, and firmly secured to
prevent falling or being knocked over. Cylinder temperatures should not exceed 52 °C
(125 °F). Keep container tightly closed and sealed until ready for use. See Section 10
for incompatible materials before handling or use.
Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
controls other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Date of issue/Date of revision : 5/6/2018 Date of previous issue : 6/28/2017 Version :1 5/12
Propane
Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions
Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not
allow gas to accumulate in low or confined areas.
Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.
Hazardous polymerization : Under normal conditions of storage and use, hazardous polymerization will not occur.
Date of issue/Date of revision : 5/6/2018 Date of previous issue : 6/28/2017 Version :1 6/12
Propane
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Date of issue/Date of revision : 5/6/2018 Date of previous issue : 6/28/2017 Version :1 7/12
Propane
Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
Propane 1.09 - low
Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)
Date of issue/Date of revision : 5/6/2018 Date of previous issue : 6/28/2017 Version :1 8/12
Propane
Packing group - - - - -
Environmental No. No. No. No. No.
hazards
“Refer to CFR 49 (or authority having jurisdiction) to determine the information required for shipment of the
product.”
Additional information
DOT Classification : Limited quantity
Yes.
Packaging instruction
Passenger aircraft
Quantity limitation: Forbidden.
Cargo aircraft
Quantity limitation: 150 kg
Special provisions
19, T50
For domestic transportation only, UN1075 may be substituted for the UN number
shown as long as the substitution is consistent on package markings, shipping
papers, and emergency response information. See 49 CFR 172.102 Special Provision
19.
Containers of NON-ODORIZED liquefied petroleum gas must be marked either
NON-ODORIZED or NOT ODORIZED as of September 30, 2006. [49 CFR 172.301(f),
326(d), 330(c) and 338(e)]
TDG Classification : Product classified as per the following sections of the Transportation of Dangerous
Goods Regulations: 2.13-2.17 (Class 2).
Explosive Limit and Limited Quantity Index 0.125
ERAP Index 3000
Passenger Carrying Ship Index 65
Passenger Carrying Road or Rail Index Forbidden
Special provisions 29, 42
IATA : Quantity limitation Passenger and Cargo Aircraft: Forbidden. Cargo Aircraft Only: 150
kg.
Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
Date of issue/Date of revision : 5/6/2018 Date of previous issue : 6/28/2017 Version :1 9/12
Propane
State regulations
Massachusetts : This material is listed.
New York : This material is not listed.
New Jersey : This material is listed.
Pennsylvania : This material is listed.
International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.
Montreal Protocol (Annexes A, B, C, E)
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Informed Consent (PIC)
Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.
Inventory list
Australia : This material is listed or exempted.
Canada : This material is listed or exempted.
China : This material is listed or exempted.
Europe : This material is listed or exempted.
Japan : Japan inventory (ENCS): This material is listed or exempted.
Japan inventory (ISHL): This material is listed or exempted.
Malaysia : This material is listed or exempted.
New Zealand : This material is listed or exempted.
Philippines : This material is listed or exempted.
Republic of Korea : This material is listed or exempted.
Date of issue/Date of revision : 5/6/2018 Date of previous issue : 6/28/2017 Version :1 10/12
Propane
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS®
ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
National Fire Protection Association (U.S.A.)
4 Flammability
Health 2 0 Instability/Reactivity
Special
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.
Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to
be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Procedure used to derive the classification
Classification Justification
FLAMMABLE GASES - Category 1 Expert judgment
GASES UNDER PRESSURE - Liquefied gas Expert judgment
History
Date of printing : 5/6/2018
Date of issue/Date of : 5/6/2018
revision
Date of previous issue : 6/28/2017
Version : 1
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
Date of issue/Date of revision : 5/6/2018 Date of previous issue : 6/28/2017 Version :1 11/12
Propane
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
Date of issue/Date of revision : 5/6/2018 Date of previous issue : 6/28/2017 Version :1 12/12