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CH16502 - Assignment I

This document contains instructions for Assignment 1 for students in the Chemical Engineering department. It provides details about the assignment such as the topics to be covered, submission instructions, marking rubrics, and allotted questions for each student. The assignment involves questions on topics related to thermodynamics including partial molar properties, activity coefficients, tangent-intercept method, excess properties, chemical potential, and Henry's law. Students are asked to submit handwritten solutions with their details on the cover sheet by July 31st, 2018. The assignment will be marked based on content, timely submission, and presentation.

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53 views

CH16502 - Assignment I

This document contains instructions for Assignment 1 for students in the Chemical Engineering department. It provides details about the assignment such as the topics to be covered, submission instructions, marking rubrics, and allotted questions for each student. The assignment involves questions on topics related to thermodynamics including partial molar properties, activity coefficients, tangent-intercept method, excess properties, chemical potential, and Henry's law. Students are asked to submit handwritten solutions with their details on the cover sheet by July 31st, 2018. The assignment will be marked based on content, timely submission, and presentation.

Uploaded by

Laaptu Mail
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd
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FT/GN/61/04/18.03.

16
Date: 31-07-18
DEPARTMENT : CHEMICAL ENGINEERING
Academic Year: 2018 - 2019
UG /PG: B Tech Specialisation(for PG): N/A
Sub Code: CH16502 Sub Name :CHEMICAL ENGINEERING THERMODYNAMICS II MARKS: 40
Student Branch: CH Semester : V ASSIGNMENT :I /II/ III

Instructions: Students are asked to adhere to following:


1. Assignment should be hand written
2. Submit with a cover sheet in a presentable form
3. On the Cover Sheet fill Name, University Register Number, Semester and Date of Submission.
4. Date of Submission: 31st July, 2018

Rubrics for Marking and Assignment – I Details are as given below


Content 30
ASSIGNMENT-I
Timely submission 5
Presentation 5

Student Roll
Number Allotted Assignment
Sec A Sec B
Consider any binary mixture namely ethanol-water system and explain
the partial
1-6 59-64 molar property of each, total molar property and pure component molar
65-
7-12 69,81 How does the activity coefficient vary with respect to pressure and
temperature
14-18, 70-
21 74,84 Apply tangent-intercept method for a binary solution
20,22,2 75-
3,25,27 80,82,
, 29 85 Derive an expression for excess molar volume
24,30,3 83,86,87
2,33, , Prove that all property changes of mixing are zero for ideal solution
34,40 90,91,92
26, 35- Relate chemical potential to enthalpy, entropy and Helmholtz free
39 93-98 energy
31,42,4 99-
3,45,46 104,106 Derive an expression for excess molar enthalpy
,48
44,49,5 105,107 Prove that the rate of change of chemical potential with pressure is
0,52,53 -110 equal to partial
,54 molar of the solution
The enthalpy of binary liquid mixture containing components 1 and 2
51,56,5 111,113, at 298K and 1
7,301,3 114,307, bar is given by H = 400x1 + 600x2 + x1x2(40x1 + 4x2)
02,303 308,309 where H is in J/mol. Determine a) Pure component enthalpies and b)
Partial molar enthalpies
55,58, Calculate the concentration of nitrogen in water exposed to air at 298 K
303,30 and 1 bar if Henry’s law constant for nitrogen in water is 8.68 x 104 bar
5, 112,115, at this temperature. Express the results in moles of nitrogen in per kg of
306 310-313 water (Air is 79 percent nitrogen by volume)
Prepared By
Ms G Thayanidhi, Asst. Professor / CH
Ms S Swathi, Asst.Professor / CH

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