Page: 1/6

SL-1801 Material Safety Data Sheet

Material Safety Data Sheet according to EC directive 2001/58/EC Date Issued: 12/12/2007
and REACH regulation 1907/2006 Annex II Date Revised:12/12/2007
Revision No.: 1

1. INFORMATION OF THE SUBSTANCE / COMPANY

1.1 IDENTIFICATION OF THE SUBSTANCE / PREPARATION

Product name: SL-1801
Product description: para-tert-octylphenol formaldehyde resin
CAS No.: 26678-93-3

1.2 USE OF THE SUBSTANCE

Use of the substance: rubber industry

1.3 COMPANY IDENTIFICATION

Manufacturer: Sino Legend (Zhangjiagang) Chemical Co.,Ltd
Address: 99#, Tianba Road Yangtze International Chemical Industrial
Park,Zhangjiagang City , Jiangsu Province, China, 215635
Tel: +86-512-58326999
Fax: +86-512-58326111
Web: www.sinolegend.com

1.4 EMERGENCY PHONE NUMBER

Emergency tel: +86-512-58326999

2. COMPOSITION / INFORMATION ON INGREDIENTS

Composition
Name CAS No. EC index No. EC/EINECS R-phrase Content
ELINCS No.
formaldehyde 50-00-0 605-001-00-5 200-001-8 R23/24/25 ≤0.1%
R34,R40,R43
p-t-octylphenol 140-66-9 205-426-2 R36/38、R21 ≤4.0%
R50/53
polymer of p-t-octylphenol 26678-93-3 ≥96.0%
and formaldehyde
 Page: 2/6

SL-1801 Material Safety Data Sheet

Material Safety Data Sheet according to EC directive 2001/58/EC Date Issued: 12/12/2007
and REACH regulation 1907/2006 Annex II Date Revised:12/12/2007
Revision No.: 1

3. HAZARDS IDENTIFICATION

DANGERS FOR HUMAN HEALTH AND THE ENVIRONMENT

R-phrase Improper disposal may be harmful to human health and aquatic organisms,
may cause long-term adverse effects on the environment.

4. FIRST AID MEASURES

IN GENERAL check the vital functions

unconscious: maintain adequate airway and respiration

EYES immediately flush eyes directly with a stream of water while; washing eyes within
several seconds of exposure is essential to achieve maximum effectiveness.
If irritation accurs,seek medical treatment immediately.

SKIN for skin contact, wash immediately with soap and water. Wash contaminated clothing
before reuse.
If irritation accurs,seek medical treatment immediately.

INGESTION rinse mouth immediately with water.

if ingestion, drink lots of water.
if large amounts of ingestion, induce vomiting immediately, then go to hospital quickly.
call the local Poison Treatment Center.

INHALATION remove the victim to a place with good air ventilation.

if respiratory problem occurs, go for medical treatment promptly.

5. FIRE FIGHTING MEASURES

FLASHPOINT AND METHOD not determined.

FLAMMABLE LIMITS not determined.
AUTOIGNITION TEMPERATURE not determined.
FLAMMABLE CLASS non-flammable.
 Page: 3/6

SL-1801 Material Safety Data Sheet

Material Safety Data Sheet according to EC directive 2001/58/EC Date Issued: 12/12/2007
and REACH regulation 1907/2006 Annex II Date Revised:12/12/2007
Revision No.: 1

6. ACCIDENTAL RELEASE MEASURES

GENERAL PROCEDURES keep unnecessary personnel away.

eliminate all sources of ignition.
do not allow the spilled product to enter sewers or open waterways.

PERSONAL PRECAUTIONS gloves

protective clothing

ENVIRONMENTAL PRECAUTIONS prevent dust cloud formation by wetting.

wash contaminated clothes.

7. HANDLING AND STORAGE

HANDING guard against dust accumulation of this material.

do not cut,drill,grind,or weld empty containers.
carry operations in the open ventilation or with respiratory protection.
avoid raising dust.
keep away from naked flames/heat/ignition sources/sparks.

STORAGE store in a dry area.

keep the materials in a well-ventilated place.
store in a cool area.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

TLV
TLV-TWA (ppm) 10ppm total dust
3
TLV-TWA (mg/m ) 5mg/m3 dust
*: Threshold Limit Value,Time Weighted Average limits for 8hr per day or 40 hr weekly. the maximum airborne
concentration of a material to which most workers can be exposed during a normal daily and weekly work
schedule without adverse effects.
 Page: 4/ 6

SL-1801 Material Safety Data Sheet

Material Safety Data Sheet according to EC directive 2001/58/EC Date Issued: 12/12/2007
and REACH regulation 1907/2006 Annex II Date Revised:12/12/2007
Revision No.: 1

PERSONAL PROTECTION
EYE PROTECTION safety glasses
SKIN PROTECTION gloves, protective clothing
RESPIRATORY PROTECTION when heating: gas mask with filter type A
on dust generation: dust mask with filter type P2
HAND PROTECTION gloves

9. PHYSICAL AND CHEMICAL PROPERTIES

GENERAL INFORMATION
PHYSICAL STATE solid
ODOR not determined
APPEARANCE white to yellowish pastilles
VAPOR PRESSURE not determined
VAPOR DENSITY not determined
BOILING POINT not determined
SOFTENING POINT 85-105℃
FLASH POINT not determined
SOLUBILITY soluble in acetone/THF/organic solvents

10. STABILITY AND REACTIVITY

CHEMICAL STABILITY stable in normal condition.

CONDITIONS TO AVOID keep away from heat,sparks or open flame.

POLYMERIZATION does not undergo hazardous polymerization.

INCOMPATIBILITY do not mix with strong acids.

HAZARDOUS DECOMPOSITION complete combustion yields carbon dioxide and water.

trace amounts of formaldehyde may be released in the resin curing process.
for formaldehyde, symptoms of exposure including eye,nose,throat, and
respiratory irritation usually are experienced at air concentrations in the
range of 0.2-1.0ppm and become more severe above 1ppm.
 Page: 5/ 6

SL-1801 Material Safety Data Sheet

Material Safety Data Sheet according to EC directive 2001/58/EC Date Issued: 12/12/2007
and REACH regulation 1907/2006 Annex II Date Revised:12/12/2007
Revision No.: 1

11. TOXICOLOGICAL INFORMATION

GENERAL PRODUCT INFORMATION formaldehyde, polymer with 4-(1,1,3,3-tetramethylbutyl)phenol is used

in the synthesis of this resin. The following acute toxicology data are
based on tests done for one product from a family of products. This
substance is practically non-toxic by the oral,dermal,and inhalation
routes. It is slightly irritating to the eyes. It does not irritate skin.

COMPONENT ANALYSIS: LD50 phenol,4-(1,1,3,3-tetramethylbutyl)-(140-66-9)

oral LD50 rat: 4600mg/kg
oral LD50 mouse: 3210mg/kg
dermal LD50 rabbit:1880mg/kg

OTHER TOXICOLOGICAL INFORMATIONthis resin may generate "nuisance"dust. A study in mice indicated
that dust overloading compromised pulmonary immune function.
the exposure limits for nuisance dust are:
PEL: 15mg/m3(total)8hrs TWA
PEL: 5mg/m3(resp)8hrs TWA
TLV: 10mg/m3(total)8hrs TWA

12. ECOLOGICAL INFORMATION

ECOLOGY: WATER no bioaccumulation data available.

ECOLOGY: SOIL no data available.

ENVIRONMENTAL FATE there is no significant environmental fate and effects data available.

13. DISPOSAL CONSIDERATIONS

ECOLOGY: WASTE remove to an authorized industrial waste incinerator.

materials should be disposed of in accordance with local and
national regulations.
 Page: 6/ 6

SL-1801 Material Safety Data Sheet

Material Safety Data Sheet according to EC directive 2001/58/EC Date Issued: 12/12/2007
and REACH regulation 1907/2006 Annex II Date Revised:12/12/2007
Revision No.: 1

14. TRANSPORTATION INFORMATION

NOT REGULATED

15. REGULATORY INFORMATION

NAME OF THE COMPONENTS DETERMING THE DANGER

formaldehyde
para-tert-octylphenol

R-PHRASES R51/53: toxic to aquatic organisms, may cause long term adverse effects in the
aquatic environment.
S-PHRASES S26: in case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
S57: use appropriate container to avoid environmental contamination.
S61: avoid release to the environment. Refer to special instructions.
EC LIST contains para-tert-octylphenol.

16. OTHER INFORMATION

Reasonable care has been taken in the preparation of this information, but the manufacturer makes
no warranty of merchantability or any other warranty,expressed or implied,with respect to this information.The
manufacturer makes no representations and assumes no liability for any direct, incidental or consequential
damages resulting from its application.

completed on: 12/12/2007