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Paper-1: Advanced Pattern Part Test-1 (Apt-1)

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Paper-1: Advanced Pattern Part Test-1 (Apt-1)

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® SET/CODE

P7 -19
1
ADVANCED PATTERN PART TEST-1 (APT-1)
TARGET : JEE (MAIN + ADVANCED) 2021
PAPER-1 COURSE : VIJETA (01JPA)
Date : 03-05-2020 Time: 3 Hours Maximum Marks : 180
Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
GENERAL %
1. The sealed booklet is your Question Paper. Do not break the seal till you are instructed to do so.
2. The question paper CODE is printed on the right hand top corner of this sheet and the right hand top corner of the
back cover of this booklet.
3. Use the Optical Response Sheet (ORS) provided separately for answering the question.
4. Blank spaces are provided within this booklet for rough work.
5. Write your Name and Roll Number in the space provided on the below cover.
6. After the open booklet, verify that the booklet contains all the 54 questions along with the options are legible.

DO NOT BREAK THE SEAL WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR

QUESTION PAPER FORMAT AND MARKING SCHEME :
7. The question paper has three parts : Mathematics, Physics and Chemistry. Each part has three sections.
8. Each section as detailed in the following table :
Category-wise Marks for Each Question Maximum
Number of
Section Question Type Negative Marks
Questions Full Marks Partial Marks Zero Marks
Marks of the Section
+4 +1
0
If only the bubble(s) For darkening a bubble –2
One or More If none of the
1 6 corresponding to all the corresponding to each correct In all other 24
Correct Option(s) bubbles is
correct option(s) is(are) option, provided NO incorrect cases
darkened
darkened option is darkened
+3 0
Single Correct –1
If only the bubble If none of the
2 Option (5 8 – In all other 24
corresponding to the correct bubbles is
choices) cases
option is darkened darkened
+3 0
Comprehension –1
If only the bubble If none of the
3 (Single Correct 4 – In all other 12
corresponding to the correct bubbles is
Option) cases
option is darkened darkened
OPTICAL RESPONSE SHEET :
9. Darken the appropriate bubbles on the original by applying sufficient pressure.
10. The original is machine-gradable and will be collected by the invigilator at the end of the examination.
11. Do not tamper with or mutilate the ORS.
12. Write your name, roll number and the name of the examination centre and sign with pen in the space provided for
this purpose on the original. Do not write any of these details anywhere else. Darken the appropriate bubble
under each digit of your roll number.
DARKENING THE BUBBLES ON THE ORS :
13. Use a BLACK BALL POINT to darken the bubbles in the upper sheet.
14. Darken the bubble COMPLETELY.
15. Darken the bubble ONLY if you are sure of the answer.
16. The correct way of darkening a bubble is as shown here :
17. There is NO way to erase or "un-darkened bubble.
18. The marking scheme given at the beginning of each section gives details of how darkened and not darkened
bubbles are evaluated.

NAME OF THE CANDIDATE : ………………………………………………………………..………………………

ROLL NO. : ………………………..………………………

I have read all the instructions I have verified the identity, name and roll number
and shall abide by them of the candidate.

------------------------- -------------------------
Signature of the Candidate Signature of the Invigilator

Resonance Eduventures Ltd.

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MATHEMATICS
PART : I MATHEMATICS

MATHEMATICS
SECTION – 1 : (Maximum Marks : 24)


 This section contains SIX questions

 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four option(s) is(are) correct
 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
 For each question, marks will be awarded in one of the following categories :
Full Marks : +4 If only the bubble(s) corresponding to all the correct option(s) is(are)
darkened.
Partial Marks : +1 For darkening a bubble corresponding to each correct option, provided
NO incorrect option is darkened.
Zero Marks : 0 If none of the bubbles is darkened.
Negative Marks : –2 In all other cases.
 For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three
will result in +4 marks ; darkening only (A) and (D) will result in +2 marks and darkening (A) and
(B) will result in –2 marks, as a wrong option is also darkened.

1. The number of the functions f from the set X = {1, 2, 3} to the set Y = {1, 2, 3, 4, 5, 6, 7} such that
f(i)  f(j) for i < j and i, j  X is
(A) 8C2 + 8C3 (B) 7C3 + 7C3 (C) 8C3 (D) 9C3

2. If f : [–1, 5]  [–10, 2] is an invertible function and g(x) is inverse function of f(x), then range of
log 1
2
g(x) 2

 2(g(x))  3 is

     
(A) log 1 83,log 1 11 (B) log 1 38,–1 (C) log 1 38,1 (D) [–2, 1]
 2 2   2   2 

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MATHEMATICS
3. If 1 > 2 are roots of x2 + kx – 1 = 0, then

MATHEMATICS

(A) tan–1 1 – tan–12 = –
2

1 
(B) tan–1 1 + tan–1 =–
1 2

1 
(C) tan–12 + tan–1 =–
2 2


(D) tan–1 1 – tan–12 =
2

4. For the equation x + y + z + w = 19, the number of positive integral solutions is equal to

(A) The number of ways in which 15 identical things can be distributed among 4 persons.

(B) The number of ways in which 19 identical things can be distributed among 4 persons.

(C) Coefficients of x19 in (x0 + x1 + x2 + ..... + x19)4

(D) Coefficients of x15 in (x + x2 + x3 + ....... + x19)4

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MATHEMATICS
5. If 4 whole numbers taken at random are multiplied together

MATHEMATICS
16
(A) Probability that the last digit in the product is 1, 3, 7 or 9 is
625

369
(B) Probability that the last digit in the product is ‘5’ is
10 4

3727
(C) Probability that the last digit in the product is 0 is
10 4

2357
(D) Probability that the last digit in the product is 0 is
10 4

6. 4 people are selected randomly out of six married couple. Then the probability that

240
(A) exactly one married couple is formed is 12
C4

15
(B) exactly two married couple are formed is 12
C4

240
(C) they do not form a married couple is 12
C4

15
(D) they do not form a married couple is 12
C4

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MATHEMATICS

MATHEMATICS
SECTION – 2 : (Maximum Marks : 24)
 This section contains EIGHT questions
 Each question has FIVE options (A), (B), (C), (D) and (E). ONLY ONE of these five option is
correct
 For each question, darken the bubble corresponding to the correct option in the ORS
 Marking scheme :
+3 If only the bubble corresponding to the correct option is darkened
0 If none of the bubble is darkened
–1 In all other cases

7. Let A = {1, 2, 3, 4} and R be a relation on A given by R = {(1, 1) (2, 2) (3, 3) (4, 4) (1, 2) (2, 1) (1, 3)
(3, 1)} then R is
(A) only reflexive (B) only symmetric (C) only transitive (D) equivalence relation
(E) reflexive and symmetric both

(1  x  x 2 )( x 4  1)
8. If x  R+, then range of f(x) = is
x3
 5 2  2 5
(A) 2,  (B) [6, ) (C)  ,   (D)  , 
 3 3  3 3 

(E) (5, )

9. Let f(x) = 1 + 9x + 36x2 + 84x3 + 126x4 + 126x5 + 84x6 + 36x7 + 9x8 + x9. Then f(– 0.99) =
(A) 10–9 (B) 10–18 (C) 10–99 (D) 1099
(E) 109

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MATHEMATICS
10. If (y2 – y + 1)[x – 2] < y2 + y + 1,  y  R then x belongs to ([.] denotes G.I.F)

MATHEMATICS
 7  7
(A) (–, 3) (B) (–, 3] (C)  – ,  (D)  – , 
 3  3
(E) (3, )

11. If x  [0, 6], y[0, 6] then the number of ordered pair (x, y) which satisfy the equation
3
sin–1 (sinx) + cos–1 (cosy) = are
2
(A) less than 8 (B) more than 9 (C) less than 7 (D) more than 7
(E) less than 6

 3x  1 , x  1  3x , x2 lim f(g(x)) =

12. If f(x) =  , g(x) =  , then
  x2
 2x 3 , x 1 2x  3 , x2
(A) 7 (B) 2 (C) 4 (D) 5 (E) 6

13. The coefficient of x3y4z in the expansion of (1 + x + y – z)9 is

(A) 2 . 9C7 . 7C4 (B) – 2. 9C2 . 7C5 (C) 9P2 . 7C3 (D) –70 9C7
(E) 70 9C7

14. In an examination, a candidate is required to pass in all the four subjects he is studying. The
number of ways in which he can fail is
(A) 4P1 + 4P2 + 4P3 + 4P4 (B) 44 – 1
(C) 24 + 1 (D) 4C1 + 4C2 + 4C3 + 4C4 (E) 24

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MATHEMATICS

SECTION – 3 : (Maximum Marks : 12)

MATHEMATICS
 This section contains TWO paragraphs
 Based on each paragraph, there will be TWO questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four option is
correct 
 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
 Marking scheme :
+3 If only the bubble(s) corresponding to all the correct option(s) is(are) darkened
0 If none of the bubbles is darkened
–1 In all other cases

Paragraph for Question Nos. 15 to 16

1 x2
Let f(x) = x + and g(x) = ,
x 2x  1

15. Find the domain of fog

 1 5  1
(A) R –  ,   (B) R – {–1, 0} (C) R – {0} (D) R –  2,  
 2 4  2

16. Find the domain of gof

 1 5  1
(A) R –  ,   (B) R – {–1, 0} (C) R – {0} (D) R –  2,  
 2 4  2

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MATHEMATICS
Paragraph for Question Nos. 17 to 18

MATHEMATICS
There are n intermediate stations on a railway line from one terminus to another terminus.

17. In how many ways can the train stop at 3 of these stations if all the stations are consecutive:

(A) n (B) n – 1 (C) n – 2 (D) n –2C3

18. In above question what will be the answer if at least two of them are consecutive:

(A) (n – 1) (n – 2) (B) (n – 1)2 (C) (n – 2)2 (D) (n – 2)

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PHYSICS
PART : II PHYSICS

PHYSICS
SECTION – 1 : (Maximum Marks : 24)
 This section contains SIX questions
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four option(s) is (are) correct
 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
 For each question, marks will be awarded in one of the following categories :
Full Marks : +4 If only the bubble(s) corresponding to all the correct option(s) is (are)
darkened.
Partial Marks : +1 For darkening a bubble corresponding to each correct option, provided
NO incorrect option is darkened.
Zero Marks : 0 If none of the bubbles is darkened.
Negative Marks : –2 In all other cases.
 For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three
will result in +4 marks ; darkening only (A) and (D) will result in +2 marks and darkening (A) and
(B) will result in –2 marks, as a wrong option is also darkened.

19. A point object is kept at a distance of OP  u. The radius of curvature of spherical surface APB is
CP  R. The refractive index of the media are n1 and n2 which are as shown in the diagram, then
(consider only paraxial rays)

(A) If n1  n2 image is virtual for all values of u

Space for Rough Work
(B) If n2  2n1 image is virtual when R  u

(C) The image is real for all values of u, n1 and n2

(D) If n2  n1 then image will be always real

Space for Rough Work

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PHYSICS
20. At t = 0 spring is in its natural length and velocity of two block shown in figure then which of the
following option is incorrect

PHYSICS
3m
(A) length of spring is maximum at a time t = 7 
8K

 2m
(B) length of spring is minimum at a time t =
2 3K

2m
(C) Acceleration of the two block is zero at a time t = 
3K

(D) Acceleration of the two block never be equal to zero, while acceleration of centre of mass is
always zero.

21. Two equal negative charges –q each are fixed at the points (0, a) and (0, -a) on the y-axis .A
positive charge Q is released from rest at the point (2a, 0) on the x-axis. The charge Q will :

(A) Execute simple harmonic motion about the origin

(B) At origin velocity of particle is maximum.

(C) Move to infinity

(D) Execute oscillatory but not simple harmonic motion.

Space for Rough Work

22. Two non-conducting solid spheres of radii R and 2R, having uniform volume charge densities 1

PHYSICS
and 2 respectively, touch each other. The net electric field at a distance 2R from the centre of the

smaller sphere, along the line joining the centres of the spheres, is zero. Then the ratio 1 may
2
be ;

32 32
(A) –4 (B)  (C) (D) 4
25 25

23. Figure here shows four small elements A, B, C and D on a uniform string carrying a wave
travelling in positive x direction. Unstretched lengths of the elements are same. At given instant.

(A) The elements D has downward velocity

(B) The elements B has maximum elastic potential energy

(C) The elastic potential energy of element A due to wave is zero

(D) Total energy of any element remains constant with time

Space for Rough Work

24. A ray OP of monochromatic light is incident on the face AB of prism ABCD near vertex B at an

PHYSICS
incident angle of 60º (see figure). If the refractive index of the material of the prism is 3 , which of
the following is (are) correct ?

(A) The ray gets totally internally reflected at face CD

(B) The ray comes out through face AD

(D) The angle between the incident ray and the emergent ray is 120º

Space for Rough Work

SECTION – 2 : (Maximum Marks : 24)

PHYSICS
 This section contains EIGHT questions
 Each question has FIVE options (A), (B), (C), (D) and (E). ONLY ONE of these four option is
correct
 For each question, darken the bubble corresponding to the correct option in the ORS
 Marking scheme :
+3 If only the bubble corresponding to the correct option is darkened
0 If none of the bubble is darkened
–1 In all other cases

25. A transverse wave is propagating along +x direction. At t=2 sec, the particle at x=4m is at
y=2 mm.With the passage of time its y coordinate increases and reaches to a maximum of 4 mm.
The wave equation is (using  and k with their usual meanings)

 
(A) y  4sin[(t  2)  k(x  2)  ] (B) y  4sin[(t  2)  k(x)  ]
6 6

5 
(C) y  4sin[(t  2)  k(x  4)  ] (D) y  4sin[(t  2)  k(x  4)  ]
6 6

(E) None of these

Space for Rough Work

26. Consider a uniform speherical charge distribution of radius R 1 centred at the origin O. In this

PHYSICS
distribution, a spherical cavity of radius R2, centred at P with distance OP = a = R1 – R2 (see
figure) is made. If the electric field inside the cavity at position r is E(r) , then the correct
statement(s) is(are)

(A) E is uniform, its magnitude is independent of R2 but its direction depends on r

(B) E is uniform, its magnitude depends on R2 and its direction depends on r

(C) E is uniform, its magnitude is independent of a but its direction depends on a

(D) E is uniform, and both its magnitude and direction depends on a

(E) None of these

Space for Rough Work

27. V–T diagram for a process of a given mass of ideal gas is as shown in the figure. During the

PHYSICS
process pressure of gas.

(A) first increases then decreases (B) continuously decreases

(C) continuously increases (D) first decreases then increases.

(E) None of these

28. The figure shows a prism surrounded by air on all the faces. Considering the ray incident on face
AB to be incident on face AC next, deviation suffered by ray as it emerges into air again is –

AIR
30º AIR

30º = 3 60º
B C
AIR

(A) 90º (B) 60º (C) 30º (D) 0º (E) 10º

Space for Rough Work

29. Focal length of a biconvex lens in air is 40 cm. The focal length of the lens in water is 120 cm. If

PHYSICS
4
refractive index of water is , then what is refractive index of the material of the lens?
3

(A) 1.4 (B) 1.5 (C) 1.6 (D) 1.7 (E) 1

30. If the electric potential of the inner shell is 10 volt & that of the outer shell is 5 volt, then the
potential at the centre will be: (the shells are uniformly charged)

(A) 10 volt (B) 5 volt (C) 15 volt (D) 0 (E) 2 volt

31. A sound source emits two sinusoidal sound waves, both of wavelength , along paths A and B as
shown in figure. The sound travelling along path B is reflected from five surfaces as shown and
then merges at point Q, producing minimum intensity at that point. The minimum value of d in
terms of  is :

  Space for Rough Work

3 
(A) (B) (C) (D) (E) None of these
8 4 8 2

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PHYSICS
32. The lengths of two metallic rods at temperatures  are LA and LB and their linear coefficient of

PHYSICS
expansion are A and B respectively. If the difference in their lengths is to remain constant at any
temperature then

(A) LA/LB=A/B (B) LA/LB=B/A (C) A=B (D) AB=1

(E) None of these

SECTION – 3 : (Maximum Marks : 12)

 This section contains TWO paragraphs
 Based on each paragraph, there will be TWO questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four option is
correct 
 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
 Marking scheme :
+3 If only the bubble(s) corresponding to all the correct option(s) is(are) darkened
0 If none of the bubbles is darkened
–1 In all other cases

Space for Rough Work

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PHYSICS
Paragraph for Question Nos. 33 to 34

PHYSICS
A long string having cross–sectional area 0.80 mm2 and density 12.5 gm/cm3 is subjected to a
tension of 64N along the x-axis. One end of this string is attached to a oscillator moving in
transverse direction at a frequency of 20 Hz. At t = 0 the source is at maximum displacement y =
1.0 cm. Answer the following questions :

33. Choose the CORRECT option(s) :

(A) The speed of wave travelling on the string is 80 m/sec

(B) The speed of wave travelling on the string is 8 m/sec


(C) The equation of the wave travelling along the string is y = (1.0 cm) cos[20t – x].
2

(D) The equation of the wave travelling along the string is y = (1.0 cm) sin[20t – x]

34. Choose the CORRECT option(s) :

40
(A) The speed of the particle at x = 50 cm at time t = 0.05 sec. is cm/sec
2

(B) The speed of the particle at x = 50 cm at time t = 0.05 sec. is 20 2 cm/sec

KW
(C) Average intensity is 200
sec.

KW
(D) Average intensity is 1600
sec.

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PHYSICS
Paragraph for Question Nos. 35 to 36

PHYSICS
In a container of negligible heat capacity, 200 gm ice at 0°C and 100 gm steam at 100°C are

added to 200 gm of water that has temperature 55°C. Assume no heat is lost to the surroundings

and the pressure in the container is constant 1.0 atm.

35. What is the final temperature of the system ?

(A) 48°C (B) 72°C (C) 94°C (D) 100°C

36. Amount of the steam left in the system, is equal to

(A) 16.7 gm (B) 12.0 gm

(C) 8.4 gm (D) 0 gm, as there is no steam left.

Space for Rough Work

PART : III CHEMISTRY

CHEMISTRY
Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27, Si = 28,
P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5, Zn = 65, As = 75,
Br = 80, Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207]

SECTION – 1 : (Maximum Marks : 24)



 This section contains SIX questions

 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these

four option(s) is(are) correct

 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS

 For each question, marks will be awarded in one of the following categories :

Full Marks : +4 If only the bubble(s) corresponding to all the correct option(s) is(are)
darkened.
Partial Marks : +1 For darkening a bubble corresponding to each correct option, provided
NO incorrect option is darkened.
Zero Marks : 0 If none of the bubbles is darkened.
Negative Marks : –2 In all other cases.

 For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three
will result in +4 marks ; darkening only (A) and (D) will result in +2 marks and darkening (A) and
(B) will result in –2 marks, as a wrong option is also darkened.

Space for Rough Work

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37. A solution containing 0.3198 g of complex CrCl3. 6H2O was passed through cation exchanger
and the solution given out was neutralized by 28.8 ml of 0.125 M NaOH. The correct formula of

CHEMISTRY
complex is:
(A) [Cr(H2O)6]Cl3 (B) [Cr(H2O)5Cl]Cl2.H2O
(C) [Cr(H2O)4Cl2]Cl . 2H2O (D) [Cr(H2O)3Cl3] . 3H2O

38. Which of the following can produce B2O3?

(A) Treating borax with H2SO4 (B) Passing CO2 through aq. NaBO2
(C) Combustion of diborane B2H6 (D) Warming H3BO3 crystals till red hot.

39. Consider a simple cubical unit cell which is divided into two equal parts as shown :

If the total surface area of one part is 16Å2 then the correct option(s) is/are:
(A) Edge length = 2Å
(B) Diameter of the particle = 2Å
(C) Effective number of particles in one part = 0.5
(D) Packing efficiency of the unit cell = 52% (approximate)

Space for Rough Work

40. For non ideal solution (positive deviation) which of the following is/are correct?

CHEMISTRY
(A) S surroundin g   ve (B) S surroundin g  ve

(C) Gmixing  ve (D) Hmixing   ve

41. Which of the following is/are NOT an electrophile?

(A) H2O (B) NH3

(C) CH3OH (D) AlCl3

42. Choose the correct order of nucleophilicity.

   
(A) F(DMSO) > Cl(DMSO) > Br(DMSO) > I(DMSO)

   
(B) F(aq) > Cl(aq) > Br(aq) > I(aq)

   
(C) I(aq) > Br(aq) > Cl(aq) > F(aq)

   
(D) I(DMSO) > Br(DMSO) > Cl(DMSO) > F(DMSO)

Space for Rough Work

SECTION – 2 : (Maximum Marks : 24)

CHEMISTRY
 This section contains EIGHT questions
 Each question has FIVE options (A), (B), (C), (D) and (E). ONLY ONE of these five option is
correct
 For each question, darken the bubble corresponding to the correct option in the ORS
 Marking scheme :
+3 If only the bubble corresponding to the correct option is darkened
0 If none of the bubble is darkened
–1 In all other cases

43. Henry’s law constant for CO2 in water is 2.5 × 108 Pa at 298 K. Calculate millimole of CO2
dissolved in 144 g water at 2.5 atm pressure at 298 K. [Take 1 atm = 105N/m2 or Pa]
(A) 8 (B) 4 (C) 0.8 (D) 0.04 (E) 0.4

44. Examine the phase diagram for the binary ideal liquid mixture of '1' and '2' shown in figure.

then which pair of points represent different phases in equilbrium with each other?
(A) P and T (B) S and M (C) A and S (D) A and M (E) A and T

Space for Rough Work

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CHEMISTRY
45. A buffer solution is prepared in which the concentration of NH 3 is 0.30 M and the concentration of

CHEMISTRY
NH4+ is 0.20 M. If the equilibrium constant, pKb for NH3 equal to 4.74, what is the pH of this

solution? (log2 = 0.30, log 3 = 0.48)

(A) 9.08 (B) 9.44 (C) 11.72 (D) 8.73

(E) 10.44

7
46. A sample of one mole of an ideal gas having  = is heated at constant pressure and the heat
5

absorbed by the gas is 21J. Determine the work done by the gas:

(I) 6 J (II) 9 J (III) 25.20 calorie (IV) 37.62 calorie

(A) Only I (B) Only II (C) I, III (D) II, IV

(E) None of these

47. [Co(H2O)6]3+ and [PdBr4]2– complex ions are respectively.

(A) low spin, high spin (B) high spin, low spin

(C) both low spin (D) both high spin

(E) both are high spin and paramagnetic

Space for Rough Work

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CHEMISTRY
48. Which of the following has incorrect configuration nomenclature.
CH3–CH2 CH2–OH CH3 OH

CHEMISTRY
(A) C=C E (B) C=N Anti
CH2=CH CN H
CH3
CH3 CH2–CH3
(C) C=C  Z (D) H NH2  L
H CH3
COOH
CHO

CH2OH D
(E) H
OH
CHO

H2N H
49. The absolute configuration of is
H OH

CH3
(A) (1S, 2R) (B) (2S, 3S) (C) (2S, 3R) (D) (1R, 2S) (E) (2R, 3R)
50. Which of the following is not correct order.

(A) NH2 < N2 (Leaving group ability in SN reaction) (B) F < I (Nucleophilicity)

(C) < (Basicity) (D) < (Stability)


(E) NH2 > N2 (Nucleophilicity)

Space for Rough Work

SECTION – 3 : (Maximum Marks : 12)

CHEMISTRY
 This section contains TWO paragraphs
 Based on each paragraph, there will be TWO questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four option is
correct 
 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
 Marking scheme :
+3 If only the bubble(s) corresponding to all the correct option(s) is(are) darkened
0 If none of the bubbles is darkened
–1 In all other cases

Paragraph for Question Nos. 51 to 52

In the valence bond theory, hybridisation of orbitals is an integral part of bond formation.
Hybridisation consists of mixings or linear combination of the "pure" atomic orbitals in such a way
as to form new hybrid orbitals such as sp, sp2, sp3, sp3d, sp3d2 etc.
Now answer the following questions:

51. Which of the following atomic orbital(s) participates in trigonal bipyramidal hybridisation i.e. sp 3d
hybridisation?
(I) dZ2 (II) d (III) dxy (IV) pz
x2 –y2

(A) II, IV (B) III, IV (C) I, IV (D) Only II

52. Which of the following atomic orbitals participitates in hybridisation in [Pt(NH 3)4]+2 as well as in
[Cr(CN)6]3–?
(I) s (II) d (III) d (IV) px
x2 –y2 z2

(A) III, IV (B) I, III, IV (C) I, II, III, IV (D) I, II, IV

Space for Rough Work

CHEMISTRY
The carbonyl compounds which have alpha hydrogen atom, tautomerise on keeping in aqueous

solution

OH–/H2O
CH3–CH2–CHO CH3–CH=CH–OH

Product enol can show geometrical isomerism.

CH3 OH CH3 H
C=C C=C
H H OH
H (Trans)
(cis)

53. Which of the following compound will give two enol in aqueous solution.

(A) CH3–CHO (B) Ph–C–CH2–CH3 (C) CH3–C–CH3 (D) CH3–CH–CHO

O O CH3

54. How many total enolic forms (including stereoisomers) are possible for butanone.

(A) 1 (B) 2 (C) 3 (D) 4

Space for Rough Work

PART-I MATHEMATICS 8. If x  R+, then....................

1. The number ....................
 1  x  x 2  x 4  1 
Sol. 7C3 + 2 × 7C2 + 7C1 = 9C3 . Sol. f(x) =   2 
 x  x 
  
2. If f : [–1, 5] ....................
Sol. Range of g(x) = [–1, 5]  1  2 1 
(g(x))2 + 2g(x) + 3 = (g(x) + 1)2 + 2  f ( x )   x   1 x  2 
Range of (g(x))2 + 2g(x) + 3 = [2, 38]  x  x 
Range of 
log 1 g(x))2  2g(x)  5 is  1
 x   2  2  R+
2 x
     1   1
log 1 38, log 1 2 = log 1 38,–1 f ( x )   x    1 x 2  2   (2  1)(2)
 2 2   2   x   x 
3. If 1 > 2 are ....................  f(x)  6,  range of f(x) is [6, )
Sol. 1 2 = – 1
9. Let f(x) = 1 + 9x ....................
1 > 0 and2 < 0
Sol. f(x) = 1 + 9x + 36x2 + 84x3 + 126x4 +
1  126x5 + 84x6 + 36x7 + 9x8 + x9
tan–11 + tan–1 = = (1 + x)9
1 2 f(– 0.99) = (1 – 0.99)9 = (0.01)9 = 10–18
1  10. If (y2 – y + 1)[x – 2] ....................
tan–12 + tan–1 =–
2 2 y2  y  1
Sol. [x – 2] <
tan 1 – tan 2
–1 –1
y2 – y  1
= tan–1 1 – tan–1
 1  1 y2  y  1 1
    3, [x – 2] <
 1  3 y2 – y  1 3
1  [x – 2]  0
= tan–11 + tan–1 = x<3
1 2
4. For the equation.................... 11. x  [0, 6], y[0, 6] ....................
If
Sol. Number of positive integral solution = 19 – 1C4 – 1 = 18C3
= Coefficients of x19 in (x + x2 + x3 + ....... + x19)4 
Sol. max sin–1 sinx =
Number of ways in which 15 identical things can be 2
distributed among 4 persons = 15 + 4 – 1C15 = 18C15 = 18C3 max cos–1 cosy = 
equation has solution if both are maximum
5. If 4 whole numbers....................
hence sin x = 1, cos y = –1
Sol. At end of any number there could be 10 possible digits n
(S) = 10 × 10 × 10 × 10 to get last digit of product 1, 3, 7   5 9 
or 9, end place should be occupid by these digits only. x   , , , y  {, 3, 5}
44 2 2 2 
Hence n (E) = 44 P= number of ordered pair = 9
10 4
Probability that the last digit in the product is 0 is  3x  1 , x  1
12. If f(x) =  ....................
10 4  8n  5n  4n 5535 2x  3 , x  1
=
10n 10 4 Sol. As x  2–  3 – x  1+ i.e. g(x)  1+
6. 4 people are .................... As x  2+  2x – 3  1+ i.e. g(x)  1+
6 6  x  2  g(x)  1+
C1.10 C1.8 C1 C2 12
C1.10 C1.8 C1
Sol. (i)
12
(ii)
12
(iii)
12 lim f(g(x)) = lim f(g(x))
C4 .2! C4 C4 .3! x2 g(x) 1

= lim f(x) = lim (3x – 1) = 2

7. Let A = {1, 2, 3, 4} .................... x 1 x 1
Sol. A = {1, 2, 3, 4}
R = {(1, 1) (2, 2) (3, 3) (4, 4) (1, 2) (2,1) (1, 3) (3, 1)}
 (a, a)  R  a  A
So it is reflexive
 (a, b) and (b, a) both are present in R so it is symmetric
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13. The coefficient ....................
Sol. (1 + x + y – z)9 = {(1 – z) + (x + y)}9 20. At t = 0 system is in equilibrium position and perform SHM
= 9C0 (1 – z)9 + 9C1 (1 – z)8 (x + y) + 9C2 (1 – z)7 (x + 2m
with time period = T = 2
y)2 +....+ 9C7 (1 – z)2 (x + y)7 +....... 3K
x3y4 appears in (x + y)7 only T 5T
length of spring is minimum at , ...........
so, the required coefficient = 9C7 (–2) . 7C4 4 4
14. In an examination.................... 3T 7T
length of spring is maximum at , ...........
Sol. Number of ways he can fail is either one or two, three or 4 4
four subject then total of ways. length of spring is natural length and it acceleation is zero
4C +4C + 4C +4C = 24 – 1
1 2 3 4 T 3T
at a time t = 0, , ...........
15. Find the .................... 2 2
16. Find the domain............. 21.
1 x2
Sol. f(x) = x + , g(x) =
x 2x  1
 1
domain of f is R – {0} and domain of g is R –  
 2
x2 (i) From diagram, force on Q at general position x, is given
15. g(x) = = 0 iff x = – 2 by
2x  1
kQqx
 1  Fnet = – 2F cos  = – (Towards origin)
 domain of fog is R –  ,  2 (a  x 2 )3 / 2
2
 2 
(ii) When charge moves from (2a, 0) to origin O, force
1 1 keeps on acting on Q and becomes zero at O.
16. f(x) = x + =– iff 2x2 + x + 2 = 0 has no real
x 2  Velocity of Q is max. at O.
solution (iii) Motion is SHM for very small displacements, but here
 domain of gof is R – {0} 2a is not very small so the motion is periodic but not
SHM.
17. In how many ....................
Sol. The number of triples of consecutive stations, viz. 22.
S1S2S3, S2S3S4, S3S4S5, … Sn – 2Sn – 1Sn is (n – 2)

18. In above question...............

Sol. The total number of consecutive pair of stations, viz.
S1S2, S2S3, … Sn – 1Sn
Each of the above pair can be associated with a third
station in (n – 2) ways. Thus, choosing a pair of stations
and any third station can be done in (n – 1) (n – 2) ways.
The above count also includes the case of three At point P
consecutive stations. However, we can see that each such If the resultant electric field is zero
case has counted twice. For example, the pair S4S3 then
combined with S6 and the pair S5S6 combined with S4 are KQ1 KQ2
identical.  R
Hence subtracting the excess counting, the number of 4R2 8R3
ways which three statins can be chosen so that at least 1
two of them are consecutive = (n – 1) (n – 2) – (n – 2) = =4
(n – 2)2 2
 At point Q
If the resultant electric field is zero
PART-II PHYSICS then
n2 n n  n1 KQ1 KQ2
19.  1  2  0
v ( u) R 4R2 25R2
A 1 32
=– (1 must be negative)
i r 2 25
23. D moves down as shown
O u P C
n2
n1
B
n2 n2  n1 n1
 
v R u
(a) if n1 > n2  v is – ve  (a)
2n1 n1 n1 2 1 1
(b)   ;   Also, at mean position as stretched length is maximum,
v R u v R u elastic potential energy is maximum as well.
if R > u  v is -ve
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28.

60º 30º
30º
60º 60º
45º Q
24. 60º

60º
 = 1 + 2 = 30º + 60º = 90º.
By refraction at face AB :
1     1 1
1.sin60º = 3 . sinr1 29.   1    
So r1 = 30º f  0   R1 R2 
This shows that the refracted ray is parallel to side BC of  = R.I. of surrounding
prism. For side 'CD' angle of incidence will be 45º,
fw  1
which can be calculated from quadrilateral PBCQ. 
By refraction at face CD : fa 
1
3 sin45º = 1 sinr2 w
3
3=
   1
So sin r2 =
2  3 
which is impossible. So, there will be T.I.R. at face CD.  4  1
Now, by geometry angle of incidence at AD will be 30º.
So, angle of emergence will be 60º. 9
Hence, angle between incident and emergent beams is
 3   1
4
90º
5 8
SHM equation of the particle at x = 4 is
2 =
25. 4 5

y = 4 sin((t – 2) + ) 30. Let q1 = charge on inner sphere
6
q2 = change on outer sphere
  x  4  C = common centre
  Wave equation, replacing t by , t     is
  v  kq1 kq2 kq1 kq2
+ = 10, VC = + = 10 Ans. (A)
M.Bank_String_Waves_1.59 a b a b
  (x  4)  
y = 4 sin   t   2   31. Path difference = Path B – Path A
  v  6 = 7d – 3d = 4d
[Note that there is no phase change in reflections from
 mirror in case of sound]
= 4 sin ( (t – 2) – k (x – 4) + )
6 For being out of phase :
26. Electric field in cavity  3
x = 4d = ; ; ................
OP 2 2
E =
3 0 
For minima , 4d =
OP = R1 –- R2 2
a 
=  d= Ans.
3 0 8
27. V = KT + C 32. Change in LA = change in LB
nRT nRT i.e. LA = LB
P=  P=
V KT  C  AT LA = BTLB

dP nRC or ALA = BLB .


dT (KT  C)2 T
33. v= ,  = A = 0.80 × 10–6 × 12.5 × 103 = 10–2
As C < 0 by diagram 
dP kg/m.
 < 0 for all T  P continuously decreases.
dT  = 2f = 40

y 
34. vp = = –40sin[40t – x]
t 2
 40
= –40sin[2 – ] = cm/sec.
4 2

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35–36. As steam has comparatively large amount of heat to 46. A sample of one mole of………….
provide in the form of latent heat we check what Sol dq = 21J = H = nCP dT (At constant P)
amount of heat is required by the water and ice to go E = nCVdT
up to 100°C, that is
nCV 1
(mi L + mi Sw T) + mw. Sw . T = . CPdT = H
= [(200 × 80) + (200 × 1 × 100)] + (200 × 1× 45) CP 
= 45,000 cal. 1
That is given by m mass of steam, then E =  21 = 15J
ms.L = 45,000 7/5
E = dq + dw
45,000 500 15 = 21 + dw
ms = = = 83.3 gm
540 6 dw = –6 J or –6 / 4.2 = –1.42 calorie
therefore 83.3 gm steam converts into water of 100°C.
Total water = 200 + 200 + 83.3 = 483.3 gm 47. [Co(H2O)6]3+ and [PdBr4]2– complex………….
steam left = 16.7 gm. Sol. [Co(H2O)6]3+  t 62 g e 0g (low spin)
[PdBr4]2–  dsp2 (low spin)
PART-III CHEMISTRY
37. A solution containing…………. 50. Which of the following is………….
Sol. Moles of Cl– = moles of HCl = moles of NaOH
0.3198
Moles of complex = = 0.0012 mol
266.5
Sol. > (Stability of anion due to –m effect
28.8  0.125
Moles of NaOH used =  0.0036
1000
0.0036 of –NO2 group)
 1 mole of complex has = moles of Cl–
0.0012 52. Which of the following atomic………….
 3 moles of Cl– Sol. (Q.51 to 52)
Hybridisation Atomic orbitals Bond angle(s) Geometry
38. Which of the following…………. sp s + arbitrary pn 180º Linear
Sol. Theory based sp2 s + arbitrary pn 120º Trigonal
3 n
sp s + arbitrary p 109.5º Tetrahedral
39. Consider a simple …………. sp3d d 2 + s + px + py + pz 90º, 120º Trigonal bipyramidal
Sol. Surface area = 4a2 = 16, a = 2Å = 2R z

sp3d2 dz 2  d x 2  y 2 + s + px + py + pz 90º Octahedral

40. For non ideal solution………….
Sol. For positive deviation solution the inter molecular
interaction is weaker as interaction found in any one of
the pure components.
PAPER-2
PART-I MATHEMATICS
42. Choose the correct order…………. 1. Let f(x) be ..........................
Sol. In aprotic solvent Nu increases, as compare to polar  x xQ
protic solvent. Sol. f(x) =  ;
1– x xQ
43. Henry’s law constant for………….  f(x) f(x)  Q
nCO2 nCO2 fof(x) = 
Sol. PCO2 = KH. x CO2 = KH × 1– f(x) f(x) Q
nCO2  nwater nCO2  nty xQ
 x x x  Q
nCO2
=  = 
= KH 1– (1– x) 1– x  Q  x x  Q
nwater  f(f(x)) = x ; a = 0 ; b = 1
nCO2
2.5 × 105 = 2.5 × 108 × 2. Let f(x)= ([a]2 ..........................
144 /18 Sol. f(x) = ([a]2 –5[a] + 4) x3 – (6{a}2 – 5{a} + 1) x – tan x(sgn
nCO2 = 8 × 10–3 x)
x>0
44. Examine the phase…………. f(x) = ([a]2 –5[a] + 4) x3 – (6{a}2 – 5{a} + 1) x – tan x
Sol. Point A & M represent the equilibrium mixture of liquid and x<0
vapour. f(x) = ([a]2 –5[a] + 4) x3 – (6{a}2 – 5{a} + 1) x + tan x
Given that function is even function  x  R
45. A buffer solution is prepared…………. So f(x) – f(–x) = 0  n  R
Sol. [NH3] = 0.3M [NH4+] = 0.2 M
Kb = 1.8 × 10-5 2x3 ([a]2 – 5[a] + 4) – 2x (6{a}2 – 5{a} + 1) = 0
So this equation should be independent from x  
OH
salt  0.2 coff. of x3 & x will be zero.
P = Pkb + log 4.74 + log = 4.56
base  0.3 [a]2 – 5[a] + 4 = 0 ; 6{a}2 –5{a} + 1 = 0
PH = 14 -4.56 = 9.44 [a] = 1, 4 ; {a} = 1/2,1/3
a = 1+ 1/2, 4 + 1/2, 1 + 1/3, 4 + 1/3 = 3/2, 9/2, 4/3, 13/3
Sum = 3/2 + 9/2 + 4/3 + 13/3 = 6 + 17/3 = 35/3

= lim  sin(a  1)x  sin x  7. If solution of ..........................

x  0  x x 
Sol. cot (sin–1 1  x2 )
= lim  sin(a  1)x  . (a  1) + lim sin x x
x 0
 (a  1)x  x 0 x
= ( a + 1) + 1 = a + 2 1  x2
lim lim x  bx 2 – x x 6
= f(x) = sin (tan–1 x 6 )=
x 0 x 0 bx 3 / 2 6x 2  1
6 1 1 5
x  1  bx – 1    12x2 = 5  x = ±
= lim 6x 2  1 1  x2 2 3
x  0 bx x
1 5
= lim [ 1  bx  1] ×
1  bx  1 so x =
2 3
(but x will be positive
x 0 bx 1  bx  1  p = 2, q = 5, r = 3
lim bx pqr 253
=
x 0 bx( 1  bx  1)
So  =2
p 2
1 1 1 8. An insurance..........................
 lim = = Sol. Let E1, E2 and E3 be the events that the insured person is
x 0 1  bx  1 11 2 a scooter, a car and a truck driver respectively. Let A be
1 the event that the insured person meets the accident Now
a+2= =c 2000 2000 1
2 P(E1) = = =
1 –3 1 2000  4000  6000 12000 6
a+2= a = ,c= 4000 1 6000 1
2 2 2 P(E2) = = ; P(E3) = =
12,000 3 12000 2
Hence for f(x) to be continuous at x = 0 , we must have Also
–3 1 1 3 3
a= ,c= and b may be any real value P(A/E1) = ; P(A/E2) = ; P(A/E3) =
2 2 100 100 20
By Bayes' Theorem
n  2n P(E1/A)
5. If lim .............
n  n(3x  4)n  n.2n 1  2n P(E1 ).P(A / E1 )
=
P(E1 ).P(A / E1 )  P(E2 ).P(A / E2 )  P(E3 ).P(A / E3 )
1 1
Sol. lim n
 [Baye's theorem]
n 
 3x  4  1 2 1 1
 2  2 n 
  6 100 1
= =
3x  4 1 1 1 3 1 3 52
 –1< < 1  – 2 < 3x – 4 < 2     
2 6 100 3 100 2 20
2 If two distinct ..........................
2 < 3x < 6  <x<2 9.
3 Sol. 2m + 2n + 1
Only one integer x = 1
= (3 – 1)m + (3 – 1)n + 1=3 (integer) + (– 1)m + (– 1)n + 1
Now, m and n should be even for 2m + 2n + 1 to be
divisible by 3.
50
C2
i.e. P(E) =
100
C2

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10. The value of .......................... 14. If f: R  [  1, 1], ..........................
Sol. = Coefficient of xn in nC0 (1 + x)2n – nC1 (1 + x)2n–1 + ........ + Sol. f : R  [–1, 1]
(–1)n nCn (1 + x)n
= Coefficient of xn in (1 + x)n [nC0 (1 + x)n – nC1 (1 + x)n–1 +
........ + (–1)n nCn]  –1 , –1  x  0
  
= Coefficient of xn in (1 + x)n xn = 1 f(x) = sin  [x]  =  0 , 0  x  1
2  
11. If the 9th term .......................... 1 , 1  x 2
Sol. T10 < T9 > T8 Many - one function
n–9 9 n – 8 8 into function
 1  2   1 2

n
C9     < nC8   5 
5 5 5   [x  4] 
Also f(x + 4) = sin 
2 
2  1
   
n
C9   < nC8   
5 5 = sin  2  [x]  = sin  [x] 
 2  2 
2n! n!
<   = f(x) and hence periodic
(n – 9)! 9! (n – 8)! 8! 15. If f(x) = x2, ..........................
2 1 Sol. gof(x) exists when f(x)  1 and x [–1, 4]
 <  n < 12.5 x2  1  x  (–, –1]  [1, )
9 n8   x  [1, 4]  {–1}
n–8 8 n–7 7
n
 1  2  n  1 2 Range of gof(x) = [0, sec–1 16]
C8     > C7  5  5
5 5     3
16. For P(A) = ; ..........................
n
 2  1 n
8
C8   > C7 Sol. P(A  B) = P(A) + P(B) – P(A  B)
5 5
2 . n! n! 5 3 4 2 1
> =  – P(A  B)  P(A  B) = =
(n – 8)! 8! (n – 7)! 7! 8 8 8 8 4
2 1 
P Ac  B 

8
>
(n – 7)
 n > 11
Now 
P Ac B = P(B)
n = 12
P(B)  P  A  B  2 8 1
12. B-1, B-2, B-3 .......................... = =1– · =
P(B) 8 4 2
15! 15!
Sol. .  3!  3!  (15 P10 )3

2P A  Bc  
2 P(A)  P  A  B  
5! 5! 5! 3! 5! 5! 5! 3!
3
2P A Bc  =
P(B ) c
=
1  P(B)
(15! )2  15!  (15! )5
  
(5! )6  5!  (5! )9 3 2 1
= 4   =  (A) is correct
8 8 2
13. If a, b, c are..........................
P(A  B) 1 2 1
P  A B = = · = = P(B)
P(B) 4 1 2
 (B) is correct
a c

P A c  Bc  = 1 P  A  B
 
Sol.
again P Ac Bc =
P(B ) c
1  P(B)
b
 5 3
a2 + b2 = c2 = 2 1   =
if a  odd (except 1)  8 4
a2  1 a2  1 A ) c
P(B)  P(A  B)
b=
2
; c=
2 
P B Ac  = P(B
1  P(A)
=
58
so at most two of a, b, c can be odd
so atleast one of a, b, c can be even a. b. c is divisible by 1 1
 1 8 2
4 = 2 4 = · =
32 5 4 5 5
3
2 5 8

4
Hence 8 P Ac Bc  15 P B Ac    
25  (C) is not correct
5
2 5
a2 + b2 = c2 again 2P A Bc   = 21 from (1)
2 2
a 1 a 1
if a  odd b =
2
c=
2  
P A Bc  = 41 = P(A  B)
so, atmost 2 a, b, c can be odd & atleast are of a, b, c is hence % (D) is correct
even
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17. The number of ..........................  4
Sol. WE have 4 consonant NVLT and 4 vowels IOUE 3 vowels 24. 1 = 10 log 2 = 10 log
and 2 consonant can be selected in 4C3 × 4C2 ways 0 0
Now the number of such word 4C3 × 4C2 × 5! 2 –  1 = 10 log4
= 2880 = 26 32 51 2 = 10 + 10 log4 = 10 + 6 = 16
18. For the binomial .......................... 25. Amplitude phasor diagram :
Sol. Tr+1 = 10Cr(x sin p)10–r(x–1cos p)r
= 10Cr x10–2r(sin p)10– r (cos p)r
For the term independent of x,
10 – 2r = 0  r = 5
 T6 = 10C5 (sin p)5 (cos p)5
 
(sin2p)5 1
10
= C5 . 5
 greatest value of T6 = 10C5. 5
2 2
Now T6 will be least if sin 2p = – 1
  resultant amplitude = 6 2
 2p = 2n –
2 26. Conserving mechanical energy
  KQq 1
 p = n –  p = (4n – 1) , n   mv 2
4 4 R 2
 sum of coefficients is = (sin p + cos p)10 putting values V = 30m/s
= (1 + sin 2p)5
 2 x 2  1
27. U = mgy = mg   = kx2
 50g
Least greatest   2
5
0 2 mπ 2 m
  K= T = 2 = 10 unit
25 k
PART-II PHYSICS 28. 2T cos37° = Mg
19.  =  ( – 1) A
= (1.5 – 1) 1 + (2 – 1) 2 = 0.5 + 2 = 2.5  1 T
3  2d    25
 
hi fv v
20.   hi = - h0  h0
h0 f f 29. Equation of stationary wave from closed end = a sink x
cos t
v
 |hi| =  h0  h0 -  vf
f Now at x =
v 7
|hi| = h0  h0 f  v  –
f
So h2 = h0 = 1 cm
From second eq. v2 = 2f
Or When v  0, u  0 & hi  h0 so h2 = h0 = 1 cm Image
of same height is obtained when v = 2f so v2 = 2f

21.

7
=
4
E1sin 30 + E1 + E1sin 30 = E0 2
Amplitude = a sin kx = a sin
2E1 = E0  7
E0 2 7 
E1 = = a sin = a sin =a
2  47 2
E0 max. velocity of particle A
Thus reamaining field = 30. (b) = = = kA
2 wave velocity /k
= 500 × 2 × 10–2 = 10
1 Qr r 31. At closed end Displacement node and pressure antinode.
22. E 
4 0 R3 0 2 1
32. For refraction at plane surface, use 
Q = 4R3 = 12 v u
. Let x = height of the bird above the water surface
For light travelling from the bird to the fish
C  1 = 1, 2 =  (refractive index of water), u = x.
23. nCP 30 = nCVT T = 30  P   42 Ans.
 CV 

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 1 1
 No. of C =
v x 4
or v = x or v  x  x.  A 3B15 C 1  A12 B15 C1
4 4
Speed of bird = x, apparent speed of bird = v  x. So x = 12, y = 15 & z = 1

33. 38. Consider the following complex………….

Sol. EAN of Fe = 26 – 2 + 6 × 2 = 36 .
P Monoatomic
39. Diborane reacts with ammonia………….
2NH
Sol. B2H6 
3
 2BH3.
NH3    B3N3H6  3H2 
Pr essure
(Borazole )

V B3N3H6  
BN  H2 
V0 (Borazole ) ( White graphite )

40. Find the total number………….

Sol. d 2 2 orbital involved in dsp2 & sp3d2 /d2sp3
For monoatomic gas pressure will be more so temperature x y
will also be more. hybridisation
(1) [Pt(NH3)Cl (H2O)Br]  dsp2
34. Displacement of centre of mass is zero. So take centre of
(2) SF4  sp3d
mass as origin then find displacement of all points.
(3) [Cu(NH3)4]2+  dsp2
(4) [XeO3F2]  sp3d
35. y = 3sin(100t) + 4(1 – cos (100t)) – 6
(5) [XeO2F2]  sp3d
2
so amplitude is = 3  42 =5 (6) [Co(en)3]3+  d2sp3
and at t = 0, y = – 2 (7) [Ni(CO)4]  sp3
(8) POCl3  sp3
(9) PCl5  sp3d
V  Vs V  V / 5 4V (10) XeO64–  sp3d2
36. For observer O1 , 1 = = 
f f 5f
For O2, there is change of medium hence at the surface of 41. What should be the minimum………….
water, keeping frequency unchanged Sol.  = CRT = 0.2 × 0.0821 × 300
= 4.926 atm = 5 atm
V 4V

a  w 42. Depression of freezing………….
Sol. For urea, Tf = Kf × m
16V
 w = 4a = Tf 1.8
5f  Kf = =
= 1.8
m 1
Now, for CH3COOH
Tf = i × Kf × m
W 4V  i = 1.1
Thus, i = 1 +  so  = 0.1
Now, [H+] = C = 0.01 × 0.1 = 10–3 M
 pH = 3
velo. of wave relative
to observer 43. A certain mixture of………….
f = Sol. m. moles of HCl = 0.1 × 20 = 2
w m. moles of CH3COOH = 0.1 × 20 = 2
V After titration of HCl by NaOH
4V 
5 = 21V . 5 f = 21 f 2 1
= [CH3COOH] =  M
w 5 16V 16 40 20
1 1 1
 pHfinal= (pKa – log C) = [5 – log 2 – log ( )] = 3
2 2 20
PART-III CHEMISTRY pHinitial = 1
37. A solid A+B– having ZnS…………. pH = 3-1 = 2
Sol. Along body diagonal  A+ = 1 (T.V.) 
43. Portland cement contains………….
1 1 Sol. MgO, CaO, SiO2, Fe2O3, Al2O3 , SO3
 B–   2 (Corner) 
8 4
45. The number of geometrical………….
3 1 1 2 3 4
+ve charge is required, so C+3 = Sol. CH=CH–C=CH–CH=CH–C=CH–CH2OH
4 4
Formula  No. of A = 3 CH3 CH3
15
No. of B = Number of stereo unit = 4
4 Total stereoisomers = 24 = 16

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47. Levonorgestrel is a commonly…………. 51. Which of the following is/are………….
Sol. Number of chiral centres are 6.
Sol. (A) [Fe(CN)6]4–  d2sp3, Diamagnetic
CH
OH (B) [Ni(NH3)6]2+  sp3d2, Paramagnetic
C
* * (C) [Cr(NH3)6]3+  d2sp3, Paramagnetic
* (D) [Co(NH3)6]3+  d2sp3, Diamagnetic
* *
*
O 52. Which of the following………….
Sol. Theory based
Levonorgestrel
54. The correct nucleophilicity………….
O3/Zn – Anionic nucleophiles are better nucleophile than their
Sol.
48. Penta-1,3-diene ………….
neutral species.

Sol. CH3–CH=CH–CH=CH2  CH3–CHO + OHC–CHO +

HCHO (3)
CH3
C=O+NH2–OH  (2)
H
H
C=O+NH2–OH  (1)
H
OHC–CHO+ NH2–OH  (3)

49. Which of the following………….

Sol. Values of Henry's Law Constant for Some
Selected Gases in Water
G Temper KH/k Gas Temper KH/k
as ature/K bar ature/K bar
H 293 144. Argon 298 40.3
e 97
H2 293 69.1 CO2 298 1.67
6
N2 293 76.4 Formald 298 1.83
8 ehyde ×10-
5

N2 303 88.8 Methan 298 0.41

4 e 3
O 293 34.8 Vinyl 298 0.61
2 6 chloride 1
O 303 46.8
2 2

50. A solution is made by………….

Sol. 
Ag2C2O4  2Ag  C2O24

 2x  2y  x


Ag2CrO4  2Ag  CrO24

 2x  2y  y

K sp  Ag2C2O4  x 1
 
K sp  Ag2CrO4  y 2
So y  2x
Ksp (Ag2C2O4) = (2x + 2y)2 x = 10–12
= 36x3 = 10–12
x = 0.3 × 10–4 M & y = 0.6×10–4 M
[Ag+] = [2x + 2y] = 1.8 × 10–4 M

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ADVANCED PATTERN
PART TEST-1 (APT-1)
TARGET : JEE (MAIN + ADVANCED) 2021
DATE : 03-05-2020 SET/CODE-1 COURSE : VIJETA (01JPA)
ANSWER KEY
CODE-1
PAPER-1
PART-I MATHEMATICS
1. (AD) 2. (B) 3. (CD) 4. (A) 5. (AB) 6. (ABC) 7. (A)
8. (B) 9. (B) 10. (A) 11. (D) 12. (B) 13. (D) 14. (D)
15. (D) 16. (C) 17. (C) 18. (C)

PART-II PHYSICS
19. (A) (B) 20. (A) (D) 21. (B) (D) 22. (B) (D) 23. (A)(B) (C) 24. (A)(B)(C)
25. (D) 26. (D) 27. (B) 28. (A) 29. (C) 30. (A)
31. (A) 32. (B) 33. (A) 34. (A) 35. (D) 36. (A)

PART-III CHEMISTRY
37. (A) 38. (CD) 39. (ABCD) 40. (BCD) 41. (ABCD) 42. (AC) 43. (A)
44. (D) 45. (B) 46. (A) 47. (C) 48. (E) 49. (C) 50. (D)
51. (C) 52. (D) 53. (B) 54. (C)

PAPER-2
PART-I MATHEMATICS
1. (20) 2. (35) 3. (35) 4. (14) 5. (01) 6. (16) 7. (02)
8. (04) 9. (02) 10. (01) 11. (04) 12. (04) 13. (ABCD) 14. (BCD)
15. (AC) 16. (ABD) 17. (ABCD) 18. (ABC)

PART-II PHYSICS
19. 25 20. 10 21. 20 22. 12 23. 42 24. 16 25. 24
26. 30 27. 10 28. 16 29. 13 30. 10 31. (A) (D)
32. (A)(C) 33. (B) (D) 34. (A) (B) (D) 35. (A) (B) (C) 36. (A) (C)(D)

PART-III CHEMISTRY
37. (28) 38. (36) 39. (00) 40. (06) 41. (05) 42. (03) 43. (02)
43. (24) 45. (16) 46. (30) 47. (06) 48. (36) 49. (ABC) 50. (AD)
51. (AD) 52. (CD) 53. (ABD) 54. (BC)

Corp. / Reg. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : [email protected]
SOL01JAAPT1050519C1-10
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
® SET/CODE
P7-19
1
ADVANCED PATTERN PART TEST-1 (APT-1)
TARGET : JEE (MAIN + ADVANCED) 2021
PAPER-1 COURSE : VIJETA (01JPA)
fnukad : 03-05-2019 le; : 3 ?k.Vs egÙke vad : 180
Ñi;k bu funsZ'kksa dks /;ku ls i<+saA vkidks 5 feuV fo'ks"k :i ls bl dke ds fy, fn;s x;s gSaA
lkekU; %
1. ;g eksgjcU/k iqfLrdk vkidk iz'u i=k gSA bldh eqgj rc rd u rksMsa tc rd bldk funsZ'k u fn;k tk;sA
2. iz'u&i=k dk dksM (CODE) bl i`"B ds Åijh nk;sa dksuas ij Nik gSA
3. iz'uksa dk mÙkj nsus ds fy, vyx ls nh x;h vkWIVhdy fjLikal 'khV ¼vks- vkj- ,l-½ (ORS) dk mi;ksx djsaA
4. dPps dk;Z ds fy, bl iqfLrdk esa [kkyh LFkku fn;s x;s gSaA
5. bl i`"B ij uhps fn, x, LFkku esa viuk uke rFkk jksy uEcj fyf[k,A
6. bl iqfLrdk dks [kksyus ds i'pkr~] d`i;k tk¡p ysa fd lHkh 54 iz'u vkSj muds mÙkj fodYi Bhd ls i<sa tk ldrs gSaA
iz'u i=k dk izk:i vkSj vadu ;kstuk %
7. bl iz'u&i=k esa rhu Hkkx gSa% xf.kr] HkkSfrd foKku vkSj jlk;u foKkuA gj Hkkx esa rhu [kaM gSaA
8. çR;sd [kaM dk fooj.k fuEufyf[kr rkfydk esa fn;k x;k gS %

fujh{kd ds vuqns'kksa ds fcuk eqgj u rksMs

iz 'uksa dh oxkZ uq lkj iz R;s d iz'u ds va d [kaM es a
[ka M iz 'u dk iz dkj
la[;k iw .kZ va d vka f'kd va d 'kw U; va d _.k vad vf/kdre vad
+4 +1
0 –2
,dy ;k ,d ls ;fn flQZ lgh fodYi@fodYiksa ds izR;sd lgh fodYi ds vuq:i cqycqys dks
1 6 ;fn fdlh Hkh cqycqys dks vU; lHkh 24
vf/kd lgh fodYi vuq:i cqycqys@cqycqyksa dks dkyk dkyk djus ij] ;fn dksbZ xyr fodYi
dkyk ugha fd;k gS ifjfLFkfr;ksa esa
fd;k gS dkyk ugha fd;k gS

+3 0 –1
,dy lgh fodYi ¼5
2 8 ;fn flQZ lgh fodYi ds vuq:i – ;fn fdlh Hkh cqycqys dks vU; lHkh 24
fodYi½
cqycqys dks dkyk fd;k gS dkyk ugha fd;k gS ifjfLFkfr;ksa esa

+3 0 –1
vuqPNsn
3 4 ;fn flQZ lgh fodYi ds vuq:i – ;fn fdlh Hkh cqycqys dks vU; lHkh 12
¼,dy lgh fodYi½
cqycqys dks dkyk fd;k gS dkyk ugha fd;k gS ifjfLFkfr;ksa esa

vkWfIVdy fjLikal 'khV %

9. Åijh ewy i`"B ds vuq:i cqycqyksa (BUBBLES) dks i;kZIr ncko Mkydj dkyk djsaA
10. ewy i`"B e'khu&tk¡P; gS rFkk ;g ijh{kk ds lekiu ij fujh{kd ds }kjk ,d=k dj fy;k tk;sxkA
11. vks-vkj-,l- dks gsj&Qsj@fod`fr u djsaA
12. viuk uke] jksy ua- vkSj ijh{kk dsna z dk uke ewy i`"B esa fn, x, [kkuksa esa dye ls Hkjsa vkSj vius gLRkk{kj djsaA buesa ls dksbZ Hkh
tkudkjh dgha vkSj u fy[ksaA jksy uEcj ds gj vad ds uhps vuq:i cqycqys dks dkyk djsaA
ORS ij cqycqyksa dks dkyk djus dh fof/k %
13. Åijh ewy i`"B ds cqycqyksa dks dkys ckWy ikbUV dye ls dkyk djsaA
14. cqycqys dks iw.kZ :i ls dkyk djsaA
15. cqycqyksa dks rHkh dkyk djsa tc vkidk mÙkj fuf'pr gksA
16. cqycqyksa dks dkyk djus dk mi;qDr rjhdk ;gk¡ n'kkZ;k x;k gS %
17. dkys fd;s gq;s cqycqys dks feVkus dk dksbZ rjhdk ugha gSA
18. gj [k.M ds izkjEHk esa nh x;h vadu ;kstuk esa dkys fd;s x;s rFkk dkys u fd;s x;s cqycqyksa dks ewY;kafdr djus dk rjhdk fn;k x;k gSA

ijh{kkFkhZ dk uke : ………………………………………………………………..………………………

jksy uEcj : ………………………..………………………

eSaus lHkh funsZ'kksa dks i<+ fy;k gS vkSj eSa mudk eSusa ijh{kkFkhZ dk ifjp;] uke vkSj jksy uEcj
vo'; ikyu d:¡xk@d:¡xhA dks iwjh rjg tk¡p fy;k gSA

------------------------- -------------------------
ijh{kkFkhZ ds gLrk{kj ijh{kd ds gLrk{kj

Resonance Eduventures Ltd.

xf.kr
 bl [kaM esa N% iz'u gSaA
 izR;sd iz'u esa pkj fodYi (A), (B), (C) rFkk (D) gSaA bu pkj fodYiksa esa ls ,d ;k ,d ls vf/kd fodYi lgh gSaA
 izR;sd iz'u esa] lHkh lgh fodYi ¼fodYiksa½ ds vuq:i cqycqys ¼cqycqykas½ dks vks- vkj- ,l- esa dkyk djsaA
 izR;sd iz'u ds fy, vad fuEufyf[kr ifjfLFkfr;ksa esa ls fdlh ,d ds vuqlkj fn;s tk;saxs %
 iw.kZ vad : +4 ;fn flQZ lgh fodYi ¼fodYiksa½ ds vuq:i cqycqys ¼cqycqyksa½ dks dkyk fd;k gSA
vkaf'kd vad : +1 çR;sd lgh fodYi ds vuq:i cqycqys dks dkyk djus ij] ;fn dksbZ xyr fodYi dkyk
ugha fd;k gSA
'kwU; vad : 0 ;fn fdlh Hkh cqycqys dks dkyk ugha fd;k gSA
_.k vad : –2 vU; lHkh ifjfLFkfr;ksa esa
 mnkgj.k % ;fn ,d ç'u ds lkjs lgh mÙkj fodYi (A), (C) rFkk (D) gSa] rc bu rhuksa ds vuq:i cqycqyksa dks
dkys djus ij +4 vad feysaxs flQZ (A) vkSj (D) ds vuq:i cqycqyksa dks dkys djus ij +2 vad feysaxs rFkk
(A) vkSj (B) ds vuq:i cqycqyksa dks dkys djus ij –2 vad feysaxs D;ksafd ,d xyr fodYi ds vuq:i cqycqys
dks Hkh dkyk fd;k x;k gSA
1. leqPp; X = {1, 2, 3} ls Y = {1, 2, 3, 4, 5, 6, 7} esa Qyuksa f dh la[;k gksxh tcfd f(i)  f(j) , i < j ds fy,
vkSj i, j  X gS&
(A) 8C2 + 8C3 (B) 7C3 + 7C3 (C) 8C3 (D) 9C3

2. ;fn f : [–1, 5]  [–10, 2] ,d izfrykse Qyu gS vkSj g(x), f(x) dk izfrykse Qyu gS] rks

log 1
2
g(x) 2
 2(g(x))  3  dk ifjlj gksxk&
     
(A) log 1 83,log 1 11 (B) log 1 38,–1 (C) log 1 38,1 (D) [–2, 1]
 2 2   2   2 

dPps dk;Z ds fy, LFkku

Reg,& Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : [email protected]
P1JPA*APT1030520C1-1
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PTC024029
xf.kr
3. ;fn 1 > 2 lehdj.k x + kx – 1 = 0, ds ewy gS] rks &
2

xf.kr

(A) tan–1 1 – tan–12 = –
2

1 
(B) tan–1 1 + tan–1 =–
1 2

1 
(C) tan–12 + tan–1 =–
2 2


(D) tan–1 1 – tan–12 =
2

4. lehdj.k x + y + z + w = 19 ds fy, /kukRed iw.kk±d gyksa dh la[;k gS &

(A) 15 le:i oLrqvksa dks 4 O;fDr;ksa esa ck¡Vus ds rjhdksa dh la[;kA

(B) 19 le:i oLrqvksa dks 4 O;fDr;ksa esa ck¡Vus ds rjhdksa dh la[;kA

(C) (x0 + x1 + x2 + ..... + x19)4 esa x19 dk xq.kkad

(D) (x + x2 + x3 + ....... + x19)4 esa x15 dk xq.kkad

dPps dk;Z ds fy, LFkku

Reg,& Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : [email protected]
P1JPA*APT1030520C1-2
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PTC024029
xf.kr
5. ;fn 4 iw.kZ la[;k;sa ;kn`fPNd ysdj mudk xq.kuQy fudkyk tkrk gS
16
(A) muds xq.kuQy esa vfUre vad 1, 3, 7 ;k 9 gksus dh izkf;drk gSA

xf.kr
625

369
(B) xq.kuQy esa vfUre vad ‘5’ gksus dh izkf;drk gSA
10 4

3727
(C) xq.kuQy esa vfUre vad 0 gksus dh izkf;drk gSA
10 4

2357
(D) xq.kuQy esa vfUre vad 0 gksus dh izkf;drk gSA
10 4

6. 6 fookfgr ;qxy esa ls 4 O;fä ;kn`fPNd :i ls pqus tkrs gS] rks

240
(A) Bhd ,d fookfgr ;qxy fy;s tkus dh izkf;drk 12
gSA
C4

15
(B) Bhd nks fookfgr ;qxy fy;s tkus dh izkf;drk 12
gSA
C4

240
(C) os dksbZ Hkh fookfgr ;qxy ugha cukus dh izkf;drk 12
gSA
C4

15
(D) os dksbZ Hkh fookfgr ;qxy ugha cukus dh izkf;drk 12
gSA
C4

dPps dk;Z ds fy, LFkku

[kaM 2 : (vf/kdre vad : 24)

xf.kr
 bl [kaM esa vkB iz'u gSaA
 izR;sd iz'u esa ik¡p fodYi (A), (B), (C), (D) rFkk (E) gSaA bu ik¡pksa fodYiksa esa ls dsoy ,d fodYi lgh gSaA
 izR;sd iz'u esa] lgh fodYi ds vuq:i cqycqys dks vks- vkj- ,l- esa dkyk djsaA
 vadu ;kstuk :
+3 ;fn flQZ lgh fodYi ds vuq:i cqycqys dks dkyk fd;k tk,A
0 ;fn dksbZ Hkh cqycqyk dkyk u fd;k gksA
–1 vU; lHkh voLFkkvksa esa

7. ekuk A = {1, 2, 3, 4} vkSj R, A ij lEcU/k gS R = {(1, 1) (2, 2) (3, 3) (4, 4) (1, 2) (2, 1) (1, 3) (3, 1)} rc R
gS&
(A) dsoy LorqY; (B) dsoy lefer (C) dsoy laØked (D) rqY;rk lEcU/k
(E) LorqY; rFkk lefer nksuksa

(1  x  x 2 )( x 4  1)
8. ;fn x  R+ rc f(x) = dk ifjlj gS –
x3
 5 2  2 5
(A) 2,  (B) [6, ) (C)  ,   (D)  , 
 3 3  3 3 

(E) (5, )

9. ekuk f(x) = 1 + 9x + 36x2 + 84x3 + 126x4 + 126x5 + 84x6 + 36x7 + 9x8 + x9 rc f(– 0.99) =
(A) 10–9 (B) 10–18 (C) 10–99 (D) 1099
(E) 109

dPps dk;Z ds fy, LFkku

Reg,& Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : [email protected]
P1JPA*APT1030520C1-4
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PTC024029
xf.kr
10. ;fn (y2 – y + 1)[x – 2] < y2 + y + 1,  y  R rc x fLFkr gS ([.]egÙke iw.kk±d Qyu gS)
 7  7
(A) (–, 3) (B) (–, 3] (C)  – ,  (D)  – , 

xf.kr
 3  3
(E) (3, )

11. ;fn x  [0, 6], y[0, 6] rc Øfer ;qXeksa (x, y) dh la[;k gksxh tks lehdj.k
3
sin–1 (sinx) + cos–1 (cosy)= dks larq"B djrh gS -
2
(A) 8 ls de (B) 9 ls vf/kd (C) 7 ls de (D) 7 ls vf/kd
(E) 6 ls de

 3x  1 , x  1  3x , x2 lim f(g(x)) =

12. ;fn f(x) =  , g(x) =  , rc
x2
 2x  3 , x  1 2x  3 , x2
(A) 7 (B) 2 (C) 4 (D) 5 (E) 6

13. (1 + x + y – z)9 ds foLrkj esa x3y4z dk xq.kkad gS&

(A) 2 . C7 . C4
9 7
(B) – 2. 9C2 . 7C5 (C) 9P2 . 7C3 (D) –70 9C7
(E) 70 9C7

14. ,d ijh{kk esa] ,d ijh{kkFkhZ dks mu lHkh pkj fo"k;ksa esa ikl gksuk vko';d gSa ftUgs og i<+ jgk gSaA og fdrus
rjhdksa ls Qsy gks ldrk gSa&
(A) 4P1 + 4P2 + 4P3 + 4P4 (B) 44 – 1
(C) 2 + 1
4
(D) 4C1 + 4C2 + 4C3 + 4C4 (E) 24

dPps dk;Z ds fy, LFkku

[kaM 3 : (vf/kdre vad : 12)

xf.kr
 bl [kaM esa nks vuqPNsn gSaA
 izR;sd vuqPNsn ij nks iz'u gaSA
 izR;sd iz'u esa pkj fodYi (A), (B), (C) rFkk (D) gSaA bu pkj fodYiksa esa ls dsoy ,d fodYi lgh gSA
 izR;sd iz'u ds fy,] lHkh lgh fodYi ¼fodYiksa½ ds vuq:i cqycqys ¼cqycqykas½ dks vks- vkj- ,l- esa dkyk djsaA
 vadu ;kstuk :
+3 ;fn flQZ lHkh lgh fodYi ¼fodYiksa½ ds vuq:i cqycqys ¼cqycqykas½ dks dkyk fd;k tk,A
0 ;fn dksbZ Hkh cqycqyk dkyk u fd;k gksA
–1 vU; lHkh voLFkkvksa esa

ç'u 15 ls 16 ds fy, vuqPNsn

1 x2
ekukfd f(x) = x + rFkk g(x) =
x 2x  1

15. fog dk izkUr gS &

 1 5  1
(A) R –  ,   (B) R – {–1, 0} (C) R – {0} (D) R –  2,  
 2 4  2

16. gof dk izkUr gS &

 1 5  1
(A) R –  ,   (B) R – {–1, 0} (C) R – {0} (D) R –  2,  
 2 4  2

dPps dk;Z ds fy, LFkku

xf.kr
,d jsy ykbu ij ,d Nksj(fdukjs) ls rd vfUre LVs'ku rd n vkUrfjd LVs'ku gS

17. fdrus rjhdksa ls ,d jsy dks 3 LVs'kuksa ij jksdh tk ldrh gS ftlesa lHkh LVs'ku Øekxr gS -
(A) n (B) n – 1 (C) n – 2 (D) n –2C3

18. mijksDr iz'u esa mÙkj D;k gksxk ;fn muesa ls de ls de nks Øekxr gS –

(A) (n – 1) (n – 2) (B) (n – 1)2 (C) (n – 2)2 (D) (n – 2)

dPps dk;Z ds fy, LFkku

HkkSfrd foKku
[kaM 1 : (vf/kdre vad : 24)
 bl [kaM esa N% iz'u gSaA
 izR;sd iz'u esa pkj fodYi (A), (B), (C) rFkk (D) gSaA bu pkj fodYiksa esa ls ,d ;k ,d ls vf/kd fodYi lgh gSaA
 izR;sd iz'u esa] lHkh lgh fodYi ¼fodYiksa½ ds vuq:i cqycqys ¼cqycqykas½ dks vks- vkj- ,l- esa dkyk djsaA
 izR;sd iz'u ds fy, vad fuEufyf[kr ifjfLFkfr;ksa esa ls fdlh ,d ds vuqlkj fn;s tk;saxs %
 iw.kZ vad : +4 ;fn flQZ lgh fodYi ¼fodYiksa½ ds vuq:i cqycqys ¼cqycqyksa½ dks dkyk fd;k gSA
vkaf'kd vad : +1 çR;sd lgh fodYi ds vuq:i cqycqys dks dkyk djus ij] ;fn dksbZ xyr fodYi dkyk
ugha fd;k gSA
'kwU; vad : 0 ;fn fdlh Hkh cqycqys dks dkyk ugha fd;k gSA
_.k vad : –2 vU; lHkh ifjfLFkfr;ksa esa
 mnkgj.k % ;fn ,d ç'u ds lkjs lgh mÙkj fodYi (A), (C) rFkk (D) gSa] rc bu rhuksa ds vuq:i cqycqyksa dks
dkys djus ij +4 vad feysaxs flQZ (A) vkSj (D) ds vuq:i cqycqyksa dks dkys djus ij +2 vad feysaxs rFkk
(A) vkSj (B) ds vuq:i cqycqyksa dks dkys djus ij –2 vad feysaxs D;ksafd ,d xyr fodYi ds vuq:i cqycqys
dks Hkh dkyk fd;k x;k gSA
19. ,d fcUnqor oLrq OP  u nwjh ij fLFkr gSA xksfy; i`"B APB fd ozdrk f=kT;k CP  R gSA ek/;eksa ds
viorZukd Øe'k% n1 rFkk n2 gS] tks fd fp=k easa iznf'kZr gSA rks (lekf{k; fdj.kksa dks fyft,s)

(A) ;fn n1  n2 gks rks u ds lHkh ekuksa ds fy, izfrfcEc vkHkklh gksxkA
dPps dk;Z ds fy, LFkku
(B) ;fn n2  2n1 gks rks R  u ds fy, izfrfcEc vkHkklh gksxkA

(C) u, n1 rFkk n2 ds lHkh ekuksa ds fy, izfrfcEc okLrfod gksxkA

(D) ;fn n2  n1 gks rks izfrfcEc ges'kk okLrfod gksxkA

dPps dk;Z ds fy, LFkku

Corp. Reg. / Office: CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)- 324005
®
Website : www.resonance.ac.in | E-mail : [email protected]
P1SET101JPAPT1030520-8
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
HkkSfrd foKku
20. t = 0ij fLiazx viuh ewy yEckbZ esa rFkk nksuksa CykWdksa dk osx fp=kkuqlkj gS rc fuEu esa ls dkSulk fodYi

HkkSfrd foKku
vlR; gSA

3m
(A) t = 7  le; ij fLiazx dh yEckbZ vf/kdre gksxhA
8K

 2m
(B) t = le; ij fLiazx dh yEckbZ U;wure gksxhA
2 3K

2m
(C) t =  ij nksuksa CykWdksa dk Roj.k 'kwU; gksxkA
3K

(D) nksuksa CykWdksa dk Roj.k dHkh Hkh 'kwU; ds cjkcj ugha gksxk tcfd nzO;eku dsUnz dk Roj.k lnSo 'kwU; gksxkA

21. nks _.kkRed vkos'k çR;sd –q dks y v{k ij fcUnq (0, a) vkSj (0, -a) ij tM+or (fixed) j[kk x;k gSA ,d /kukos'k Q dks x
v{k ij fLFkr fcUnq (2a, 0) ls fLFkj voLFkk ls NksM+k tkrk gSA vkos'k Q :

(A) ewy fcUnq ds lkis{k ljy vkorZ xfr djsxkA

(B) ewy fcUnq ij d.k dk osx vf/kdre gSA

(C) vuUr dh rjQ tk;sxkA

(D) nksyu xfr djsxk ijUrq ljy vkorZ xfr ughaA

dPps dk;Z ds fy, LFkku

nks R o 2R f=kT;k okys vpkyd Bksl xksydks dks ftu ij Øe'k% 1 rFkk 2 ,dleku vk;ru vkos'k ?kuRo gS]

HkkSfrd foKku
22.
,d nwljs ls Li'kZ djrs gq, j[kk x;k gSA nksauks xksydksa ds dsUnzksa ls xqtjrh gqbZ js[kk [khaph tkrh gSA bl js[kk
1
ij NksVs xksyd ds dsUnz ls 2R nwjh ij dqy fo|qr {ks=k 'kwU; gSA rc vuqikr dk eku gks ldrk gS :
2

32 32
(A) –4 (B)  (C) (D) 4
25 25

23. ;gk¡ fp=k esa pkj NksVs vo;o A, B, C rFkk D gS tks ,dleku Mksjh ij fLFkr gS] bl Mksjh esa /kukRed x fn'kk
ds vuqfn'k ,d rjax lapfjr gSA vo;oksa dh fcuk [khaph gqbZ yEckbZ leku gSA fn;s x;s {k.k ij

rjax lapj.k dh fn'kk

(A) vo;o D uhps dh vksj osx j[krk gSA

(B) vo;o B vf/kdre izR;kLFk fLFkfrt ÅtkZ j[krk gSA

(C) rajx ds dkj.k vo;o A dh izR;kLFk fLFkfrt ÅtkZ 'kwU; gSA

(D) le; ds lkFk fdlh Hkh vo;o dh dqy ÅtkZ vifjofrZr (fu;r) jgrh gSA

dPps dk;Z ds fy, LFkku

fp=kkuqlkj ,d fçTe ABCD ds AB ry ij 'kh"kZ B ds ikl çdk'k dh ,d ,do.khZ fdj.k OP 60º vkiru dks.k

HkkSfrd foKku
24.
ij vkifrr gSA ;fn fçTe ds inkFkZ dk viorZukd 3 gS, rks fuEufyf[kr esa ls dkSu lk ¼dkSu ls ½ dFku lgh
gSa \

(A) fdj.k dk CD ry ls iw.kZ vkUrfjd ijkorZu gks tkrk gS

(B) fdj.k AD ry ls ckgj vk tkrh gSa

(D) fuxZr fdj.k vkSj vkifrr fdj.k ds chp ds dks.k dk eku 120º gS

dPps dk;Z ds fy, LFkku

HkkSfrd foKku
[kaM 2 : (vf/kdre vad : 24)
 bl [kaM esa vkB iz'u gSaA
 izR;sd iz'u esa ik¡p fodYi (A), (B), (C), (D) rFkk (E) gSaA bu ik¡pksa fodYiksa esa ls dsoy ,d fodYi lgh gSaA
 izR;sd iz'u esa] lgh fodYi ds vuq:i cqycqys dks vks- vkj- ,l- esa dkyk djsaA
 vadu ;kstuk :
+3 ;fn flQZ lgh fodYi ds vuq:i cqycqys dks dkyk fd;k tk,A
0 ;fn dksbZ Hkh cqycqyk dkyk u fd;k gksA
–1 vU; lHkh voLFkkvksa esa

25. ,d vuqizLFk rjax +x fn'kk eas lapfjr gSA t = 2 sec rFkk x = 4m ij d.k y = 2 mm ij gSA le; c<+us ij y
funsZ'kkad c<+rk gS rFkk vf/kdre 4 mm rd igq¡prk gSA rjax dh lehdj.k gS ( o k dk lkekU; vFkZ gSA)

 
(A) y  4sin[(t  2)  k(x  2)  ] (B) y  4sin[(t  2)  k(x)  ]
6 6

5 
(C) y  4sin[(t  2)  k(x  4)  ] (D) y  4sin[(t  2)  k(x  4)  ]
6 6

(E) buesa ls dksbZ ugha

dPps dk;Z ds fy, LFkku

,d f=kT;k R1 rFkk ,d leku vkos'k ?kuRo dk xksykdj vkos'k ewy fcUnq O ij dsfUnzr gSA blesa ,d R2 f=kT;k

HkkSfrd foKku
26.
rFkk P ij dsfUnzr ,d xksykdkj xqfgdk (cavity), tgk¡ OP = a = R1 – R2 gS] cukbZ tkrh gSA (fp=k ns[ksa)A ;fn
 
xqfgdk ds vUnj fLFkfr r ij fo|qr {ks=k E( r ) gS] rc lgh dFku gS ¼gSa½

(A) E ,d leku gS] bldk ifjek.k R2 ij fuHkZj ugha djrk gS ysfdu bldh fn'kk r ij fuHkZj djrh gSA

(B) E ,d leku gS] bldk ifjek.k R2 ij fuHkZj djrk gS ysfdu bldh fn'kk r ij fuHkZj djrh gSA

(D) E ,d leku gS] ,oa ifjek.k rFkk fn'kk nksuksa a ij fuHkZj djrs gSaA

(E) buesa ls dksbZ ughas

dPps dk;Z ds fy, LFkku

27. fdlh vkn'kZ xSl ds fuf'pr nzO;eku dk V–T oØ fp=k esa iznf'kZr gSA fuEu izØe ds nkSjku xSl dk nkc

HkkSfrd foKku
(A) igys c<+sxk fQj de gksxk (B) yxkrkj ?kVsxk

(C) yxkrkj c<+sxk (D) igys ?kVsxk fQj c<+sxk

(E) buesa ls dksbZ ugha

28. fp=k esa ,d fizTe n'kkZ;k x;k gS] ftlds lHkh Qyd ok;q }kjk ifjc) gSA n'kkZ;suqlkj ,d fdj.k ekfu,sa tks
Qyd AB ij vkifrr gksrh gS] rFkk blds i'pkr~ Qyd AC ij vkifrr gksrh gS] blds i'pkr~ ok;q esa nqckjk
fuxZr gksus ij fdj.k }kjk mRiUu dqy fopyu gksxk –
A

AIR
30º AIR

30º = 3 60º
B C
AIR

(A) 90º (B) 60º (C) 30º (D) 0º (E) 10º

dPps dk;Z ds fy, LFkku

,d f}mÙky ySal dh ok;q esa Qksdl nwjh 40 cm gSA ySal dh ikuh esa Qksdl nwjh 120 cm gSA ;fn ikuh dk

HkkSfrd foKku
29.
4
vkorZukad gS, rc ySal ds inkFkZ dk viorZukad D;k gksxk?
3

(A) 1.4 (B) 1.5 (C) 1.6 (D) 1.7 (E) 1

30. ;fn vkUrfjd dks'k dk fo|qr foHko 10 oksYV o cká dks'k dk 5 oksYV gS rc dsUnz ij foHko gksxk ¼dks'k ,d
leku :i ls vkosf'kr gS½ &

(A) 10 volt (B) 5 volt (C) 15 volt (D) 0 (E) 2 volt

31. fp=k esa fn[kk;s vuqlkj ,d /ofu L=kksr iFk A rFkk B ds vuqfn'k nks T;koØh; rjaxs mRlftZr djrh gS nksuksa dh
rjaxnS/;Z  gSA iFk B ds vuqfn'k xfr djus okyh /ofu fp=k esa fn[kk;s vuqlkj ik¡p lrgksa ls ijkofrZr gksrh gS
rRi'pkr~ fcUnq Q ij U;wure rhozrk iznku djrh gqbZ ,d lkFk feyrh gSA  ds inksa esa 'd' dk U;wure eku
gksxk&

dPps dk;Z ds fy, LFkku

  3 
(A) (B) (C) (D) (E) buesa ls dksbZ ugha
8 4 8 2

Space for Rough Work

Corp. Reg. / Office: CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)- 324005
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HkkSfrd foKku
32. rki  ij /kkrq dh nks NM+ks dh yEckbZ;ka LA o LB rFkk js[kh; çlkj xq.kkad Øe'k% A o B gSa] ;fn fdlh Hkh rki

HkkSfrd foKku
ij budh yEckbZ;ksa es vUrj fu;r jgs ] rc

(A) LA/LB=A/B (B) LA/LB=B/A (C) A=B (D) AB=1

(E) buesa ls dksbZ ugha

[kaM 3 : (vf/kdre vad : 12)

 bl [kaM esa nks vuqPNsn gSaA

 izR;sd vuqPNsn ij nks iz'u gaSA

 izR;sd iz'u esa pkj fodYi (A), (B), (C) rFkk (D) gSaA bu pkj fodYiksa esa ls dsoy ,d fodYi lgh gSA

 izR;sd iz'u ds fy,] lHkh lgh fodYi ¼fodYiksa½ ds vuq:i cqycqys ¼cqycqykas½ dks vks- vkj- ,l- esa dkyk djsaA

 vadu ;kstuk :

+3 ;fn flQZ lHkh lgh fodYi ¼fodYiksa½ ds vuq:i cqycqys ¼cqycqykas½ dks dkyk fd;k tk,A

0 ;fn dksbZ Hkh cqycqyk dkyk u fd;k gksA

–1 vU; lHkh voLFkkvksa esa

Space for Rough Work

dPps dk;Z ds fy, LFkku

Corp. Reg. / Office: CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)- 324005
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HkkSfrd foKku
iz'u 33 ls 34 ds fy, vuqPNsn

HkkSfrd foKku
,d yEch jLlh ftldk vuqçLFk dkV 0.80 mm2 rFkk ?kuRo 12.5 gm/cm3 gS] esa x–v{k ds vuqfn'k ruko 64N
gSA bl Mksjh dk ,d fljk] vuqçLFk nksyu djrs gq, 20 Hz dh vko`fÙk ls xfreku nksfy=k ls tqM+k gSA t = 0 ij
nksfy=k vf/kdre foLFkkiu y = 1.0 cm ij gS rks fuEu ç'uksa dk mÙkj nsaos &

33. lgh fodYiksa dk p;u dhft, %

(A) jLlh ij xfr'khy rjax dh pky 80 m/sec gSA

(B) jLlh ij xfr'khy rjax dh pky 8 m/sec gSA


(C) jLlh ds vuqfn'k xfr'khy rjax dh lehdj.k y = (1.0 cm) cos[20t – x] gSA
2

(D) jLlh ds vuqfn'k xfr'khy rjax dh lehdj.k y = (1.0 cm) sin[20t – x] gSA

34. lgh fodYiksa dk p;u dhft, %

40
(A) x = 50 cm ij fLFkr d.k dh pky t = 0.05 sec ij cm/sec gSA
2

(B) x = 50 cm ij fLFkr d.k dh pky t = 0.05 sec ij 20 2 cm/sec gSA

KW
(C) vkSlr rhozrk 200 gSA
sec.

KW
(D) vkSlr rhozrk 1600 gSA
sec.

dPps dk;Z ds fy, LFkku

Corp. Reg. / Office: CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)- 324005
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HkkSfrd foKku
iz'u 35 ls 36 ds fy, vuqPNsn

HkkSfrd foKku
ux.; m"eh; /kkfjrk ds ,d ik=k esa 0° dh 200 xzke cQZ rFkk 100°C dh 100 xzke ok"i dks 55°C rki ds
200 xzke ikuh ds lkFk fefJr fd;k tkrk gSA okrkoj.k esa m"ek {k; ux.; ekusa rFkk ik=k esa nkc 1.0
ok;qe.Myh; fLFkj jgrk gSA

35. fudk; dk vfUre rki D;k gS &

(A) 48°C (B) 72°C (C) 94°C (D) 100°C

36. fudk; esa cph ok"i dh ek=kk cjkcj gS &

(A) 16.7 gm (B) 12.0 gm

dPps dk;Z ds fy, LFkku

Hkkx % III jlk;u foKku

jlk;u foKku
Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27, Si = 28,
P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5, Zn = 65, As = 75,
Br = 80, Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207]

[kaM 1 : (vf/kdre vad : 24)

 bl [kaM esa N% iz'u gSaA
 izR;sd iz'u esa pkj fodYi (A), (B), (C) rFkk (D) gSaA bu pkj fodYiksa esa ls ,d ;k ,d ls vf/kd fodYi lgh gSaA
 izR;sd iz'u esa] lHkh lgh fodYi ¼fodYiksa½ ds vuq:i cqycqys ¼cqycqykas½ dks vks- vkj- ,l- esa dkyk djsaA
 izR;sd iz'u ds fy, vad fuEufyf[kr ifjfLFkfr;ksa esa ls fdlh ,d ds vuqlkj fn;s tk;saxs %
 iw.kZ vad : +4 ;fn flQZ lgh fodYi ¼fodYiksa½ ds vuq:i cqycqys ¼cqycqyksa½ dks dkyk fd;k gSA
vkaf'kd vad : +1 çR;sd lgh fodYi ds vuq:i cqycqys dks dkyk djus ij] ;fn dksbZ xyr fodYi dkyk
ugha fd;k gSA
'kwU; vad : 0 ;fn fdlh Hkh cqycqys dks dkyk ugha fd;k gSA
_.k vad : –2 vU; lHkh ifjfLFkfr;ksa esa
 mnkgj.k % ;fn ,d ç'u ds lkjs lgh mÙkj fodYi (A), (C) rFkk (D) gSa] rc bu rhuksa ds vuq:i cqycqyksa dks
dkys djus ij +4 vad feysaxs flQZ (A) vkSj (D) ds vuq:i cqycqyksa dks dkys djus ij +2 vad feysaxs rFkk
(A) vkSj (B) ds vuq:i cqycqyksa dks dkys djus ij –2 vad feysaxs D;ksafd ,d xyr fodYi ds vuq:i cqycqys
dks Hkh dkyk fd;k x;k gSA

dPps dk;Z ds fy, LFkku

Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
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jlk;u foKku
37. dksbZ foy;u tks 0.3198 g tfVy CrCl3. 6H2O j[krk gS dks /kuk;u fofue; dkjd esa ls xqtkjk tkrk gS o

jlk;u foKku
ckgj izkIr gksus okys foy;u dks 28.8 ml, 0.125 M NaOH }kjk mnklhu fd;k tkrk gSA tfVy dk lgh lw=k
gS&
(A) [Cr(H2O)6]Cl3 (B) [Cr(H2O)5Cl]Cl2.H2O
(C) [Cr(H2O)4Cl2]Cl . 2H2O (D) [Cr(H2O)3Cl3] . 3H2O

38. fuEu esa ls dkSu B2O3 mRikfnr dj ldrk gS \

(A) cksjsDl dks H2SO4 ds lkFk mipkfjr djuk (B) tyh; NaBO2 esa ls CO2 xqtkjuk
(C) MkbZcksjsu B2H6 dk ngu (D) H3BO3 fØLVyksa dks jDr yky gksus rd xeZ djuk

39. ljy ?kuh; ,dd dksf"Bdk dk voyksdu dhft, tks n'kkZ, vuqlkj nks cjkcj Hkkxksa esa foHkkftr gS&

;fn ,d Hkkx dk dqy i`"Bh; {kS=kQy 16Å2 gS] rks lgh fodYi gS@gSa &
(A) dksj yEckbZ = 2Å
(B) d.k dk O;kl = 2Å
(C) ,d Hkkx esa d.kksa dh izHkkoh la[;k = 0.5
(D) ,dd dksf"Bdk dh ladqyu n{krk = 52% (yxHkx)

dPps dk;Z ds fy, LFkku

Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
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jlk;u foKku
40. vuvknZ'k foy;u ¼/kukRed fopyu½ ds fy, fuEu esa ls dkSulk@dkSuls fodYi lgh gS@gSa\

jlk;u foKku
(A) Sifjos'k = +ve (B)Sifjos'k = –ve

(C) GfeJ.k = –ve (D) HfeJ.k = +ve

41. fuEu esa ls dkSulk@dkSuls ,d bysDVªkWuLusgh ugha gS@gSa\

(A) H2O (B) NH3

(C) CH3OH (D) AlCl3

42. ukfHkdLusgrk dk lgh Øe dk p;u dhft, &

   
(A) F(DMSO) > Cl(DMSO) > Br(DMSO) > I(DMSO)

   
(B) F(aq) > Cl(aq) > Br(aq) > I(aq)

   
(C) I(aq) > Br(aq) > Cl(aq) > F(aq)

   
(D) I(DMSO) > Br(DMSO) > Cl(DMSO) > F(DMSO)

dPps dk;Z ds fy, LFkku

jlk;u foKku
[kaM 2 : (vf/kdre vad : 24)
 bl [kaM esa vkB iz'u gSaA
 izR;sd iz'u esa ik¡p fodYi (A), (B), (C), (D) rFkk (E) gSaA bu ik¡pksa fodYiksa esa ls dsoy ,d fodYi lgh gSaA
 izR;sd iz'u esa] lgh fodYi ds vuq:i cqycqys dks vks- vkj- ,l- esa dkyk djsaA
 vadu ;kstuk :
+3 ;fn flQZ lgh fodYi ds vuq:i cqycqys dks dkyk fd;k tk,A
0 ;fn dksbZ Hkh cqycqyk dkyk u fd;k gksA
–1 vU; lHkh voLFkkvksa esa

43. 298 K ij ty esa CO2 ds fy, gsujh fu;e fu;rkad 2.5 × 108 Pa gSA 298 K rki ij o 2.5 atm nkc ij
144 g ty esa ?kksys x;s CO2 ds feyheksy ifjdfyr dhft, [yhft, 1 atm = 105N/m2 ;k Pa]
(A) 8 (B) 4 (C) 0.8 (D) 0.04 (E) 0.4

44. fp=k esa n'kkZ;s '1' o '2' ds f}vaxh vkn'kZ nzo feJ.k ds fy, izkoLFkk js[kkfp=k dk voyksdu dhft,A

P10
P 1
ok"i nkc

M
R A

0
S
P2
2 T
la?kVu

rc fcUnqvksa dk dkSulk ;qXe] ,d nwljs ds lkFk lkE; esa fHkUu izkoLFkk dks iznf'kZr djrk gS \
(A) P o T (B) S o M (C) A o S (D) A o M (E) A o T

dPps dk;Z ds fy, LFkku

Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
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jlk;u foKku
45. ,d cQj foy;u cuk;k tkrk gS ftlesa NH3 dh lkUnzrk 0.30 M gS rFkk NH4+ dh lkUnzrk 0.20 M gSA ;fn

jlk;u foKku
NH3 ds fy, lkE; fu;rkad, pKb 4.74 ds cjkcj gS] rks bl foy;u dh pH D;k gS ?

(log 2 = 0.30, log 3 = 0.48)

(A) 9.08 (B) 9.44 (C) 11.72 (D) 8.73

(E) 10.44

7
46. = eku j[kus okyh ,d eksy vkn'kZ xSl ds ,d izkn'kZ dks fu;r nkc ij xeZ fd;k tkrk gS o xSl }kjk
5

vo'kksf"kr Å"ek 21J gSA xSl }kjk fd;s x;s dk;Z dk fu/kkZj.k dhft,A

(I) 6 J (II) 9 J (III) 25.20 calorie (IV) 37.62 calorie

(A) dsoy I (B) dsoy II (C) I, III (D) II, IV

(E) buesa ls dksbZ ugha

47. [Co(H2O)6]3+ rFkk [PdBr4]2– ladqy vk;u Øe'k% gS &

(A) U;wu pØ.k] mPp pØ.k (B) mPp pØ.k] U;wu pØ.k

(C) nksuks U;wu pØ.k (D) nksuksa mPp pØ.k

(E) nksuksa mPp pØ.k rFkk vuqpqEcdh; gSA

dPps dk;Z ds fy, LFkku

jlk;u foKku
CH3–CH2 CH2–OH CH3 OH
(A) C=C E (B) C=N Anti
CH2=CH CN H
CH3
CH3 CH2–CH3
(C) C=C  Z (D) H NH2  L
H CH3
COOH
CHO

CH2OH D
(E) H
OH
CHO

H2N H
49. fn;s x;s ;kSfxd dk fujis{k foU;kl gS is
H OH

CH3
(A) (1S, 2R) (B) (2S, 3S) (C) (2S, 3R) (D) (1R, 2S) (E) (2R, 3R)
50. fuEu esa ls dkSulk Øe lgh ugha gSA

(A) NH2 < N2 (SN vfHkfØ;k esa fu"dklu ;ksX;rk okyk lewg) (B) F < I (ukfHkd Lusghrk)

(C) < ({kkjdrk) (D) < (LFkkf;Ro)


(E) NH2 > N2 (ukfHkd Lusghrk)

dPps dk;Z ds fy, LFkku

jlk;u foKku
[kaM 3 : (vf/kdre vad : 12)
 bl [kaM esa nks vuqPNsn gSaA
 izR;sd vuqPNsn ij nks iz'u gaSA
 izR;sd iz'u esa pkj fodYi (A), (B), (C) rFkk (D) gSaA bu pkj fodYiksa esa ls dsoy ,d fodYi lgh gSA
 izR;sd iz'u ds fy,] lHkh lgh fodYi ¼fodYiksa½ ds vuq:i cqycqys ¼cqycqykas½ dks vks- vkj- ,l- esa dkyk djsaA
 vadu ;kstuk :
+3 ;fn flQZ lHkh lgh fodYi ¼fodYiksa½ ds vuq:i cqycqys ¼cqycqykas½ dks dkyk fd;k tk,A
0 ;fn dksbZ Hkh cqycqyk dkyk u fd;k gksA
–1 vU; lHkh voLFkkvksa esa

iz'u 51 ls 52 ds fy, vuqPNsn

la;kstdrk ca/k fl)kUr esa] d{kdksa dk ladj.k ca/k fuekZ.k dk ,d egRoiw.kZ Hkkx gSA ladj.k esa **'kq)** ijekf.o;
d{kdksa dk lfEeJ.k vFkok js[kh; la;kstu bl izdkj gksrk gS fd ftlds }kjk u;s lad fjr d{kd curs gSa] tSls
sp, sp2, sp3, sp3d, sp3d2 bR;kfnA
vc fuEufyf[kr iz'uksa ds mÙkj nhft, %

51. fuEu esa ls dkSulk@dkSuls ijekf.o; d{kd f=kdks.kh; f}fijkfefM; ladj.k vFkkZr~ sp3d ladj.k esa Hkkx ysrs
gS@gSa \
(I) dZ2 (II) d (III) dxy (IV) pz
x2 –y2
(A) II, IV (B) III, IV (C) I, IV (D) dsoy II

52. fuEu esa ls dkSuls ijekf.o; d{kd [Pt(NH3)4]+2 ds lkFk&lkFk [Cr(CN)6]3– ds ladj.k esa Hkh Hkkx ysrs gSa \
(I) s (II) d (III) d (IV) px
x2 –y2 z2
(A) III, IV (B) I, III, IV (C) I, II, III, IV (D) I, II, IV

dPps dk;Z ds fy, LFkku

jlk;u foKku
dkcksZfuy ;kSfxd] tks ,YQk gkbMªkstu ije.kq j[krs gS( tyh; foy;u es j[kus ij pyko;ork n'kkZrs gSA

OH–/H2O
CH3–CH2–CHO CH3–CH=CH–OH

mRikn bZukWy T;kfefr; leko;ork n'kkZ ldrs gSaA

CH3 OH CH3 H
C=C C=C
H H OH
H
(lei{k) (foi{k)

53. fuEu es ls dkSulk ;kSfxd tyh; foy;u es nks bZukWy nsxk\

(A) CH3–CHO (B) Ph–C–CH2–CH3

(C) CH3–C–CH3 (D) CH3–CH–CHO

O CH3

54. dqy fdrus bZukWfyd :i ¼f=kfoe leko;oh lfgr½ C;wVsukWu ds fy, lEHko gSa\

(A) 1 (B) 2 (C) 3 (D) 4

dPps dk;Z ds fy, LFkku

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ADVANCED PATTERN
PART TEST-1 (APT-1)
TARGET : JEE (MAIN + ADVANCED) 2021
DATE : 03-05-2020 SET/CODE-1 COURSE : VIJETA (01JPA)
la d s r ,oa gy
 (a, b) vkSj (b, a) nksuksa R esa lefer gSA
PAPER-1  (2, 1) (1, 3)  R
ijUrq (2, 3)  R blfy, ;g lefer gSA
PART-I MATHEMATICS
1. leqPp; X = .................... 8. ;fn x  R+ rc.................
7
Sol. C3 + 2 × 7C2 + 7C1 = 9C3 .
 1  x  x 2  x 4  1 
Sol. f(x) =   2 
2. ;fn f : [–1, 5] ....................  x  x 
Sol. g(x) = [–1, 5] dk ifjlj
  
(g(x))2 + 2g(x) + 3 = (g(x) + 1)2 + 2  1  2 1 
 f ( x )   x   1 x  2 
(g(x))2 + 2g(x) + 3 = [2, 38] dk ifjlj x x 
 

log 1 g(x))2  2g(x)  5 dk ifjlj gSA  1
2  x   2  2  R+
x
   
log 1 38, log 1 2 = log 1 38,–1  1   1
f ( x )   x    1 x 2  2   (2  1)(2)
 2 2   2  x x
   
3. ;fn 1 > 2 .......................  f(x)  6,  f(x) dk ifjlj [6, )
Sol. 1 2 = – 1
1 > 0 and2 < 0 9. ekuk f(x) = 1 + 9x ....................
Sol. f(x) = 1 + 9x + 36x2 + 84x3 + 126x4 +
1  126x5 + 84x6 + 36x7 + 9x8 + x9
tan–11 + tan–1 = = (1 + x)9
1 2
f(– 0.99) = (1 – 0.99)9 = (0.01)9 = 10–18
1 
tan–12 + tan–1 =– 10. ;fn (y2 – y + 1)[x – 2] ................
2 2
y2  y  1
tan–1 1 – tan–1 2 Sol. [x – 2] <
y2 – y  1
= tan–1 1 – tan–1
 1 
  1 y2  y  1 1
 1   2
3 y – y 1
 3, [x – 2] <
3
1  [x – 2]  0
= tan–11 + tan–1 = x<3
1 2
4. lehdj.k x + y + z.................... 11. ;fn x  [0, 6], y[0, 6] .................
Sol. /kukRed iw.kk±d gyksa dh la[;k = 19 – 1C4 – 1 = 18C3
= (x + x2 + x3 + ....... + x19)4 esa x19 dk xq.kkad

Sol. max sin–1 sinx =
15 le:i oLrqvksa dks 4 O;fDr;ksa esa ck¡Vus ds rjhdksa dh la[;k 2
= 15 + 4 – 1C15 = 18C15 = 18C3 max cos–1 cosy = 
lehdj.k j[krh gS ;fn nksuksa vf/kdre gSA
5. ;fn 4 iw.kZ la[;k;sa......................... vr% sin x = 1, cos y = –1
Sol. fdlh la[;k ds bdkbZ LFkku ij 10 lEHko vad gS n (S) = 10 ×   5 9 
10 × 10 × 10 xq.kuQy dk vafre vad 1, 3, 7 ;k 9 rHkh laHko x   , , , y  {, 3, 5}
gS] tc lHkh la[;k dk vafre vad 1, 3, 7 ;k 9 gh gSA 2 2 2 
Øfer ;qXeksa dh la[;k = 9
44
 n (E) = 44 P=
10 4  3x  1 , x  1
12. ;fn f(x) =  ................
6. 6 fookfgr ;qxy ................ 2x  3 , x  1
6 6
C1.10 C1.8 C1 C2 12
C1.10 C1.8 C1 Sol. x  2–  3 – x  1+ i.e. g(x)  1+
Sol. (i) (ii) (iii) x  2+  2x – 3  1+ i.e. g(x)  1+
12 12 12
C4 .2! C4 C4 .3!  x  2  g(x)  1+
lim f(g(x)) = lim f(g(x))
7. ekuk A = {1, 2, 3, 4} ................. x2 g(x) 1
Sol. A = {1, 2, 3, 4}
R = {(1, 1) (2, 2) (3, 3) (4, 4) (1, 2) (2,1) (1, 3) (3, 1)} = lim f(x) = lim (3x – 1) = 2
x 1 x 1
 (a, a)  R  a  A
blfy, LorqY; gSA
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13. (1 + x + y – z)9 ds ............... n2 n2  n1 n1
 
Sol. (1 + x + y – z)9 = {(1 – z) + (x + y)}9 v R u
= 9C0 (1 – z)9 + 9C1 (1 – z)8 (x + y) + 9C2 (1 – z)7 (a) ;fn n1 > n2  v is – ve  (a)
(x + y)2 +....+ 9C7 (1 – z)2 (x + y)7 +....... 2n1 n1 n1 2 1 1
(b)   ;  
(x + y)7 esa dsoy x3y4 gksxkA v R u v R u
blfy, vHkh"V xq.kkad ;fn R > u  v is -ve
= 9C7 (–2) . 7C4
20. t =0 ij fudk; lkE;koLFkk dh fLFkfr esa gS rFk ljy vkorZ
14. ,d ijh{kk esa] ,d ......................... 2m
Sol. mlds vlQy gksus ds rjhdksa esa og ;k rks ,d fo"k; esa ;k nks xfr dk vkorZdky = T = 2
3K
fo"k; esa ;k rhu fo"k; esa ;k pkj fo"k;ksa esa vlQy gks ldrk
T 5T
gks] vr% dqy rjhdksa dh la[;k = 4C1 +4C2 + 4C3 +4C4 , ........... ij fLiazx dh yEckbZ U;wure~ gksxhA
4 4
= 24 – 1
3T 7T
, ........... ij fLiazx dh yEckbZ vf/kdre~ gksxhA
15. fog dkizkUr .............. 4 4
16. gof dkizkUr .................... T 3T
t = 0, , ........... ij fLiazx dh yEckbZ ewy yEckbZ gksxh
1 x2 2 2
Sol. f(x) = x + , g(x) =
x 2x  1 rFkk bldk Roj.k 'kwU; gksxkA
 1
f dk izkUr R – {0} gS rFkk g dk izkUr R –    21.
 2
x2
15. g(x) = = 0 ;fn vkSj dsoy ;fn x = – 2
2x  1
 1 
 fog dk izkUr R –  ,  2 gSA
 2 
1 1 (i) fp=k ls fdlh lkekU; fLFkfr x ij Q ij cy
16. f(x) = x + =– ;fn vkSj dsoy ;fn 2x2 + x + 2 =
x 2 kQqx
0 ds okLrfod gy ugh gSA Fnet = – 2F cos  = – ewy fcUnw dh vkSj
(a2  x 2 )3 / 2
gof dk izkUr R – {0} gSA
(ii) tc vkos'k (2a, 0) ls ewy fcUnq O rd xfr djrk gS, Q ij
17. fdrus rjhdksa .................... cy yxrk jgrk gS ,oa O ij 'kwU; gks tkrk gS
Sol. Øekxr LVs'kuksa ds f=kiysVksa dh la[;k (iii) vR;Yi foLFkkiu ds fy, xfr ljy vkorZ gSA pwafd 2a
S1S2S3, S2S3S4, S3S4S5, … Sn – 2Sn – 1Sn is (n – 2) vY;Yi ugha gS blfy, xfr nksyu xfr gksxh ljy vkorZ
xfr ughaA
18. mijksDr iz'u esa .................... 22.
Sol. LVs'kuksa ds Øekxr ;qXeksa dh dqy la[;k
S1S2, S2S3, … Sn – 1Sn
mijksDr ;qXe ds izR;sd dks rhljs LVs'ku ls fy;s tkus ds rjhds
(n – 2) gS vr% LVs'kuksa ds ;qXe rFkk rhljs LVs'ku dks pquus ds
rjhds (n – 1) (n – 2) gSA rc mijksDr dks rhu Øekxr LVs'kuksa
dh fLFkfr esa fy;k tk, fQj Hkh ge ns[krs gS fd izR;sd bl
fLFkfr esa nks ckj pquk tkrk gSA mnkgj.k ds fy, ;qXe S4S3
la;qDr gS] S6 ds lkFk rFkk ;qXe S5S6, S4 ds lkFk la;qDr gSA fcUnq P ij
vr% vfrfjDr gks ?kVkus ij] Øep;ksa dh la[;k ftlesa rhu ;fn ifj.kkeh oS|qr {ks=k 'kwU; gS rc
LVs'kuksa dks pquk tkrk gS ftlesa ls de ls de nks Øekxr gSA KQ1 KQ2
 R
= (n – 1) (n – 2) – (n – 2) = (n – 2)2 4R2 8R3
1
PART-II PHYSICS 2
=4
n2 n n  n1
19.  1  2 fcUnq Q ij
v ( u) R ;fn ifj.kkeh oS|qr {ks=k 'kwU; gS rc
A
KQ1 KQ2
 0
i r 4R2 25R2
1 32
O u P C =– (1 _.kkRed gksuk vko';d gS )
2 25
n2
n1
B

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23. D fp=kkuqlkj uhps dh vksj xfr'khy gSA dP nRC

dT (KT  C)2
fp=k ls C < 0 gS
dP
 < 0 , lHkh T ds fy,  P yxkrkj ?kVsxk.
dT
28.

ek/; fLFkfr ij [khaph gqbZ yEckbZ vf/kdre gS vr% izR;kLFk

60º 30º
fLFkfrt ÅtkZ Hkh vf/kdre gksxhA 30º
60º 60º
60º

45º Q
24.  = 1 + 2 = 30º + 60º = 90º.

1     1 1
29.   1    
f  0   R1 R2 
60º

ry AB ij viorZu ls  = ifjos'k dk viorZukad

1.sin60º = 3 . sinr1
fw  1

r1 = 30º fa 
vr% 1
;g crkrk gS fd viofrZr fdj.k] fizTe dh Hkqtk BC ds lekUrj w
gks tkrh gSA Hkqtk 'CD' ds fy;s vkiru dks.k 45º, gks tkrk
3=
   1
gS tks fd prqHkqZt PBCQ ls x.kuk dh tk ldrh gSA
 3 
lrg CD ij viorZu ls  4  1
3 sin45º = 1 sinr2
9
3  3   1
vr% sin r2 = 4
2 5 8
tks fd vlEHko gS vr% lrg CD ij T.I.R. gksxk  2 =
4 5
vc] T;kferh ls AD ij vkiru dks.k 30º gksxkA vr% fuxZr
dks.k 60º gS 30. ekuk q1 = vkUrfjd xksys ij vkos'k
vr% vkifrr fdj.k vkSj fuxZr fdj.k ds e/; dks.k 90º gksxkA q2 = ckg~; xksys ij vkos'k
C = mHk;fu"B dsUnz
25. x = 4 ij d.k dh ljy vkorZ xfr dh lehdj.k gS
kq1 kq2 kq1 kq2
 + = 10, VC = + = 10 Ans. (A)
y = 4 sin((t – 2) + ) a b a b
6
  x  4  31. iFkkUrj= Path B – Path A
 t dks  t     ls foLFkkfir djus ij rjax = 7d – 3d = 4d
  v  [niZ.k ls /ofu ds ijkorZu ij dyk esa dksbZ ifjorZu ugha vkrk]
lehdj.k gS] dyk ls ckgj gksus ds fy;s:
  (x  4)    3
y = 4 sin   t   2   x = 4d = ; ; ................
  v  6 2 2
 
= 4 sin ( (t – 2) – k (x – 4) + ) fufEu"B ds fy;s , 4d =
6 2
xqfgdk esa fo|qr {ks=k 
26.  d= Ans.
OP 8
E = 32. LA esa ifjoZru = LB esa ifjoZru
3 0
i.e. LA = LB
a  AT LA = BTLB
OP = R1 –- R2 =
3 0 or ALA = BLB .
27. V = KT + C
nRT nRT T
33. v= ,  = A = 0.80 × 10–6 × 12.5 × 103 = 10–2 kg/m.
P=  P= 
V KT  C
 = 2f = 40

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y  44. rc fcUnqvksa dk dkSulk ;qXe………….
34. vp = = –40sin[40t – x] Sol. fcUnq A rFkk M nzo o ok"i ds lkE; feJ.k dks iznf'kZr djrk
t 2
gSA
 40
= –40sin[2 – ] = cm/sec.
4 2 45. ,d cQj foy;u cuk;k tkrk………….
Sol. [NH3] = 0.3M [NH4+] = 0.2 M
Kb = 1.8 × 10-5
35–36. rqyukRed :i esa ok"i esa xqIr Å"ek ds :i esa T;knk m"ek
gksrh gSA vc ge irk djrs gS fd ikuh rFkk cQZ dks salt   yo.k  0.2
POH = Pkb + log = 4.74 + log
100°C, rd igqapus ds fy, fdruh m"ek dh vko';drk base   {kkj  0.3
gksxh & = 4.56
(mi L + mi Sw T) + mw. Sw . T PH = 14 -4.56 = 9.44
= [(200 × 80) + (200 × 1 × 100)] + (200 × 1× 45)
= 45,000 cal. 7
46. = eku j[kus okyh ,d………….
tks fd m nzO;eku dh ok"i }kjk nh tkrh gS] rc & 5
ms.L = 45,000 Sol dq = 21J = H = nCP dT (fu;r P ij)
45,000 500 E = nCVdT
ms = = = 83.3 gm
540 6 nCV 1
vr% 83.3 xzke ok"i 100°C ds ikuh esa cny tkrh gSA = . CPdT = H
CP 
dqy ikuh = 200 + 200 + 83.3 = 483.3 gm
1
cph ok"i = 16.7 gm. E =  21 = 15J
7/5
E = dq + dw
PART-III CHEMISTRY 15 = 21 + dw
37. dksbZ foy;u tks 0.3198 g tfVy…………. dw = –6 J or –6 / 4.2 = –1.42 calorie
Sol. Cl– ds eksy = HCl ds eksy = NaOH ds eksy
47. [Co(H2O)6]3+ rFkk [PdBr4]2– ladqy………….
0.3198
ladqy ds eksy = = 0.0012 mol Sol. [Co(H2O)6]3+  t 62 g e 0g (U;wu pØ.k)
266.5
28.8  0.125 [PdBr4]2–  dsp2 (U;wu pØ.k)
iz;qDr NaOH ds eksy =  0.0036
1000
50. fuEu esa ls dkSulk Øe lgh………….
0.0036
 1 eksy ladqy j[krk gS = Cl– ds eksy
0.0012
 Cl– ds 3 eksy
Sol. > (–NO2 lewg ds –m izHkko ds dkj.k
38. fuEu esa ls dkSu B2O3 ………….
Sol. Theory based

39. ljy ?kuh; ,dd …………. _.kk;u LFkk;h gks tkrk gSA)
Sol. i`"Bh; {ks=kQy = 4a2 = 16, a = 2Å = 2R
52. fuEu esa ls dkSuls ijekf.o; d{kd………….
40. vuvknZ'k foy;u ¼/kukRed fopyu½…………. Sol. (Q.51 to 52)
Sol. /kukRed fopyu ds fy, foy;u esa vUrj vkf.od vUrfØ;k ladj.k ijekf.od d{kd ca/k dks.k T;kferh
fdlh Hkh 'kq) ?kVd esa mifLFkr vUr%fØ;k ls nqcZy gksrh gSA sp s + LoSfPNd pn 180º js[kh;
sp2 s + LoSfPNd pn 120º f=kdks.kh;
42. ukfHkdLusgrk dk lgh Øe…………. sp3 s + LoSfPNd pn 109.5º prq"Qydh;
Sol. /kzqoh; izksVhd foyk;d dh vis{kk vizksfVd foyk;d es Nu sp3d d z 2 + s + px + py + pz 90º, 120º f=kdks.kh; f}fijkfeMh;
c<+rk gSA
sp3d2 dz 2  d x 2  y 2 + s + px + py + pz 90º v"VQydh;
43. 298 K ij ty esa CO2 ds
nCO2 nCO2 PAPER-2
Sol. PCO2 = KH. x CO2 = KH ×
nCO2  nwater nCO2  nty PART-I MATHEMATICS
nCO2 nCO2 1. ekuk Qyu f(x) ....................
= KH = KH x xQ
nwater n ty Sol. f(x) = 
 ;
 x
1– xQ
nCO2
2.5 × 105 = 2.5 × 108 ×  f(x) f(x)  Q
fof(x) = 
144 /18 1– f(x) f(x) Q

nCO2 = 8 × 10–3
 x xQ x x Q
=  = 
1– (1– x) 1– x  Q  x x Q
 f(f(x)) = x ; a = 0 ; b = 1

sin(a  1)x  sin x 7. ;fn cot ..........................

 lim f(x) = lim
x 0 x 0 x Sol. cot (sin–1 1  x2 )
x
= lim  sin(a  1)x  sin x  1  x2
x  0  x x 
x 6
= lim  sin(a  1)x  . (a  1) + lim sin x sin (tan–1 x 6 )=
x 0
 (a  1)x  x 0 x 6x 2  1
= ( a + 1) + 1 = a + 2
6 1
x  bx 2 – x    12x2 = 5
= lim f(x) = lim 6x  1
2
1 x 2
x 0 x 0 bx 3 / 2
1 5
x  1  bx – 1 x=±
= lim 2 3
x  0 bx x 1 5
blfy, x =
[ 1  bx  1] 1  bx  1 2 3
= lim ×
x 0 bx 1  bx  1 ijUrq x /kukRed gksxkA)
bx  p = 2, q = 5, r = 3
= lim
x 0 bx( 1  bx  1) pqr 253
blfy,  =2
p 2
1 1 1
 lim = =
x  0 1  bx  1 11 2 8. ,d chek dEiuh..........................
1 Sol. ekukfd E1, E2 rFkk E3 Øe'k% chfer ds ,d LdqVj ,d dkj]
a+2= =c vkSj ,d Vªd pkyd gksu fd ?kVuk,¡ gSaA ekukfd A ?kVuk
2
chfer ds nq?kZVuk xzLr gksus fd ?kVuk,sa gSA
1 –3 1
a+2= a = ,c= 2000 2000 1
2 2 2 P(E1) = = =
vr% x = 0 ij f(x) lrr~ gksus ds fy, 2000  4000  6000 12000 6
–3 1 4000 1 6000 1
P(E2) = = ; P(E3) = =
a= ,c= gksuk pkfg, rFkk b dksbZ Hkh okLrfod eku 12,000 3 12000 2
2 2
gksuk pkfg,A rFkk
1 3 3
P(A/E1) = ; P(A/E2) = ; P(A/E3) =
100 100 20
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Bayes' çes; ls 13. ;fn a, b, c ..........................
P(E1/A)

=
P(E1 ).P(A / E1 )
P(E1 ).P(A / E1 )  P(E2 ).P(A / E2 )  P(E3 ).P(A / E3 ) c
a
[Baye's çes; ls] Sol.

1 1
 b
6 100 1
= = a2 + b2 = c2
1 1 1 3 1 3 52
     ;fn a  fo"ke (1 dks NksM+dj)
6 100 3 100 2 20 2
a 1 a2  1
b= ; c=
9. fHkUu fHkUu la[;k,¡ .................... 2 2
Sol. m + 2n + 1 blfy, a, b, c esa ls vf/kd ls vf/kd gks fo"ke gSA
= (3 – 1)m + (3 – 1)n + 1 = 3 (iw.kkZad) + (– 1)m + (– 1)n + 1 blfy. a, b, esa ls de ls de ,d le gks ldrk gS a. b. c 3
vc m vkSj n le gksuk pkfg,] 2m + 2n + 1 ds fy,] 3 ls 32 4
foHkkftr gksA ls foHkkftr gS 
2 5
50
C2
vFkkZr~ P(E) =
100
C2 25 4
5
10. C0. Cn – C1........................
n 2n n
2 5
Sol. = nC0 (1 + x)2n – nC1 (1 + x)2n–1 + ........ + (–1)n nCn (1 + x)n esa a2 + b2 = c2
xn dk xq.kkad gSA
a2  1 a2  1
= (1 + x)n [nC0 (1 + x)n – nC1 (1 + x)n–1 + ........ + (–1)n nCn] n ;fn a  fo"ke b = , c=
esa xn dk xq.kkad gSA 2 2
= (1 + x)n xn = 1 esa xn dk xq.kkad gSA blfy, a, b, c esa ls vf/kd ls vf/kd 2 gS rFkk a, b, c esa ls
n de ls de ,d le gSA
 x 2
11. ;fn    ........................
5 5 14. ;fn f: R  [  1, 1] ........................
Sol. T10 < T9 > T8 Sol. f : R  [–1, 1]

 1  2 
n–9
 1
9 n – 8
2
8  –1 , –1  x  0
n
C9  n   
5   5  < C8  5  5 f(x) = sin  [x]  =  0 , 0  x  1
        2  
n
 2   1  1 , 1  x 2
C9   < nC8  
5 5 cgq,sdh Qyu gSA
vUr{ksZih Qyu
2n! n!
<    
(n – 9)! 9! (n – 8)! 8! lkFk gh f(x + 4) = sin  [x  4] 
2 
2 1
 <  n < 12.5     
9 n8 = sin  2  [x]  = sin  [x] 
n–8 8 n–7 7  2  2 
n
 1  2  n  1 2 = f(x) vr% ;g vko`fÙk Qyu gSA
C8     > C7  5  5
5 5    
15. ;fn f(x) = x2, ..........................
n
2 1 n Sol. gof(x) fo|eku gS tcfd f(x)  1 vkS j x [–1, 4]
C8   > C7
5 5 x2  1  x  (–, –1]  [1, )
2 . n! n!   x  [1, 4]  {–1}
>
(n – 8)! 8! (n – 7)! 7! gof(x) dk ifjlj = [0, sec–1 16]
2 1 3
16. P(A) = ; P(B) ..........................
 >  n > 11 8
8 (n – 7)
Sol. P(A  B) = P(A) + P(B) – P(A  B)
n = 12

jsyxkMh ds rhu.......................... 5 3 4 2 1
12. =  – P(A  B)  P(A  B) = =
15! 15! 8 8 8 8 4
.  3!  3!  (15 P10 )3
Sol.
5! 5! 5! 3! 5! 5! 5! 3! 
P Ac  B 
2 3 5

vc P A B = c
 P(B)
(15! )  15!  (15! )
  
6
(5! )  5!  (5! )9 P(B)  P  A  B  2 8 1
= =1– · =
P(B) 8 4 2

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
2P A  Bc  
2 P(A)  P  A  B   PART-II PHYSICS
2P A B  c
= P(B ) c
=
1  P(B) 19.  =  ( – 1) A
= (1.5 – 1) 1 + (2 – 1) 2 = 0.5 + 2 = 2.5
3 2 1
= 4   =  (A)
8 8 2 hi fv v
20.   hi = - h0  h0
h0 f f
P(A  B) 1 2 1
P  A B = = · = = P(B) v
P(B) 4 1 2  |hi| =  h0  h0 -   v  f
 (B) f

P A c  Bc  = 1 P  A  B v
|hi| = h0  h0 f  v  –

iqu% P Ac Bc =  P(B ) c
1  P(B)
f
So h2 = h0 = 1 cm
From second eq. v2 = 2f
 5 3
= 2 1   = Or When v  0, u  0 & hi  h0 so h2 = h0 = 1 cm
 8 4 Image of same height is obtained when
c v = 2f so v2 = 2f
 A ) P(B)  P(A  B)

P B Ac  = P(B
1  P(A)
=
58 21.
1 1

1 8 2
= 2 4 = · =
5 4 5 5
8 E1sin 30 + E1 + E1sin 30 = E0
vr% 8 P A B  c c
  15 P B A  c 2E1 = E0

 (C) is not correct E0

E1 =
1 2
iqu% 2P A Bc =   2
from (1)
E0
vr% 'ks"k {ks=k =
1 2
 
P A Bc = 4
= P(A  B)

vr% (D) lgh gS ] 1 Qr r

22. E 
4 0 R3 0
17. 'kCn INVOLUTE ..........................
Q = 4R3 = 12
Sol. 4 O;atu NVLT ,oa 4 Loj IOUE .
3 Lojksa ,oa 2 O;atuksa ds p;u ds rjhds 4C3 × 4C2
C 
vc ,sls 'kCnksa dh la[;k 4C2 × 4C3 × 5! 23. nCP 30 = nCVT T = 30  P   42 Ans.
= 2880 = 26 32 51  CV 
 4
18. (x sin p + x–1 cos p) ................... 24. 1 = 10 log 2 = 10 log
Sol. Tr+1 = 10Cr(x sin p)10–r(x–1cos p)r 0 0
= 10Cr x10–2r(sin p)10– r (cos p)r
x ds LorU=k in ds fy,
2 – 1 = 10 log4
10 – 2r = 0  r = 5 2 = 10 + 10 log4 = 10 + 6 = 16
 T6 = 10C5 (sin p)5 (cos p)5
25. vk;ke dyk vkjs[k }kjk
(sin2p)5 1
10
= C5 . 5
 T6 = dk vf/kdre eku = 10C5. 5
2 2
vc T6 dk U;wure eku gksxk ;fn sin 2p = – 1
  
 2p = 2n –
2
 
 p = n –  p = (4n – 1) , n 
4 4
 xq.kkadks dk ;ksxQy = (sin p + cos p)10
= (1 + sin 2p)5

Least greatest  ifj.kkeh vk;ke = 6 2

5
0 2
 26. ;kaf=kd ÅtkZ laj{k.k ls
KQq 1
 mv 2
R 2
eku j[kus ij V = 30m/s

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 2 x 2  1 34. nzO;eku dsUnz dk foLFkkiu 'kwU; gS] vr% nzO;eku dsUnz dks ewy
27. U = mgy = mg   = kx2 fcUnq ij ysrs gSA rc lHkh fcUnqvksa dk foLFkkiu Kkr
 50g
  2 djrs gSA
mπ 2 35. y = 3sin(100t) + 4(1 – cos (100t)) – 6
m
 K= T = 2 = 10 unit
25 k vr% vk;ke = 3 2  4 2 = 5
28. 2T cos37°
= Mg rFkk t = 0 ij, y = – 2
 1 T V  Vs V  V / 5 4V
izs{kd O1 ds fy,, 1 = = 
  25
3  36.
 2d   f f 5f
O1 ds fy, ek/;e cny tkrk gS blfy, ikuh ds ry ij
vko`fÙk dks vifjofrZr j[kus ij
29. can fljs ls vizxkeh rjax dk lehdj.k = a sink x cos t
V 4V 16V
  w = 4a =
Now at x = a  w 5f
7

W 4V

iz{ksd ds lkis{k rjax V

4V 
dk osx 5 = 21V . 5 f
f = =
w w 5 16V
21 f
7 =
= 16
4
2 PART-III CHEMISTRY
vk;ke = a sin kx = a sin
 7 37. ZnS lajpuk¼ftad CysaM½………….
2 7  gy- dk; fod.kZ ds vuqfn'k  A+ = 1 (T.V.)
= a sin = a sin =a
 47 2 1 1
 B –   2 ¼dksuk½ 
d.k dk vf/kdre osx A 8 4
30. (b) = = kA = 500 × 2 × 10–2
rjax osx /k 3 1
= 10 +ve vkos'k dh vko';drk gksrh gS] vr% C+3 =
4 4
31. can fljs ij foLFkkiu fuLin nkc izLian lw=k  A dh la[;k = 3
  15
32. lery lrg ij vkiorZu ds fy,] 2  1 dk mi;ksx B dh la[;k =
v u 4
djus ij
1
ekuk x = ikuh dh lrg ds Åij i{kh dh Å¡pkbZ C dh la[;k =
i{kh ls eNyh dh vksj lapfjr izdk'k ds fy,] 4
1 = 1, 2 =  (ikuh dk viorZukad), u = x.  A 3B15 C 1  A12 B15 C1
4 4
 1 So x = 12, y = 15 & z = 1

v x
38. tfVy Na4[Fe(CN)5(NOS)] ij………….
;k v = x ;k v  x  x.
Sol. EAN of Fe = 26 – 2 + 6 × 2 = 36 .
i{kh dh pky = x, i{kh dh vkHkklh pky = v  x. Fe dk EAN = 26 – 2 + 6 × 2 = 36 .
33.
39. MkbZcksjsu veksfu;k ls vfHkfØ;k………….
P Monoatomic
2NH
,dijek.kqd Sol. B2H6 
3
 2BH3.
NH3 

 B3N3H6  3H2 
Pr essure
(Borazole )

B3N3H6  BN  H2 
(Borazole ) ( White graphite )
V
V0
40. fuEu ;kSfxdksa esa ls ,sls………….
Sol. d 2 2 d{kd dsp2 o sp3d2 /d2sp3 ladj.k ls lEcfU/kr gSA
x y

,d ijek.kqd xSl ds fy, nkc vf/kd gksxk blfy, rki Hkh (1) [Pt(NH3)Cl (H2O)Br]  dsp2
mldk T;knk gksxkA (2) SF4  sp3d
(3) [Cu(NH3)4]2+  dsp2
(4) [XeO3F2]  sp3d
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(5) [XeO2F2]  sp3d O3/Zn
48. …………. –
(6) [Co(en)3] 3+
 d2sp3 isUVk-1,3-MkbbZu
(7) [Ni(CO)4]  sp3
Sol. CH3–CH=CH–CH=CH2  CH3–CHO + OHC–CHO +
(8) POCl3  sp3
HCHO (3)
(9) PCl5  sp3d CH3
C=O+NH2–OH  (2)
(10) XeO64–  sp3d2 H
H
41. v)Z&ikjxE; f>Yyh esa Hkjs…………. C=O+NH2–OH  (1)
Sol.  = CRT = 0.2 × 0.0821 × 300 H
= 4.926 atm = 5 atm
OHC–CHO+ NH2–OH  (3)
42. 0.01 eksyy tyh; ………….
Sol. ;wfj;k ds fy, , Tf = Kf × m 49. fofHkUu rki ij fofHkUu………….
Tf 1.8 Sol. Values of Henry's Law Constant for Some
  Kf = = = 1.8 Selected Gases in Water
m 1
G Temper KH/k Gas Temper KH/k
vc] CH3COOH ds fy, as ature/K bar ature/K bar
Tf = i × Kf × m H 293 144. Argon 298 40.3
 i = 1.1 e 97
H2 293 69.1 CO2 298 1.67
bl izdkj, i = 1 +  vr%  = 0.1 6
vc, [H+] = C = 0.01 × 0.1 = 10–3 M N2 293 76.4 Formald 298 1.83
8 ehyde ×10-
 pH = 3 5

N2 303 88.8 Methan 298 0.41

43. HCl rFkk CH3COOH dk…………. 4 e 3
Sol. HCl ds feyheksy = 0.1 × 20 = 2 O 293 34.8 Vinyl 298 0.61
CH3COOH ds feyheksy = 0.1 × 20 = 2 2 6 chloride 1
O 303 46.8
NaOH }kjk HCl ds vuqekiu ds i'pkr~ 2 2
2 1
[CH3COOH] =  M 50. ,d foy;u dks Ag2CrO4………….
40 20
1 1 1 Sol. 
Ag2C2O4  2Ag  C2O24

 pHvfUre = (pKa – log C) = [5 – log 2 – log ( )]  2x  2y  x
2 2 20
=3 
Ag2CrO4  2Ag  CrO24

pHvfUre = 1  2x  2y  y
pH = 3-1 = 2 K sp  Ag2C2O4  x 1
  
43. ikWVys.M lhesUV esa fuEu esa…………. K sp  Ag2CrO4  y 2
Sol. MgO, CaO, SiO2, Fe2O3, Al2O3 , SO3
So y  2x
45. fuEu ;kSfxd ds fy, lEHko…………. Ksp (Ag2C2O4) = (2x + 2y)2 x = 10–12
1 2 3 4 = 36x3 = 10–12
Sol. CH=CH–C=CH–CH=CH–C=CH–CH2OH x = 0.3 × 10–4 M & y = 0.6×10–4 M
[Ag+] = [2x + 2y] = 1.8 × 10–4 M
CH3 CH3
51. fuEu esa ls dksSulk@dkSuls………….
f=kfoe bdkbZ dh la[;k = 4
dqy f=kfoeleko;oh = 24 = 16 Sol. (A) [Fe(CN)6]4–  d2sp3, izfrpqEcdh;
(B) [Ni(NH3)6]2+  sp3d2, vuqpqEcdh;
47. fyokWuksjtsLVªy ,d lkekU; iz;qDr………….
Sol. fdjSy dsUnzks dh la[;k 6 gSA (C) [Cr(NH3)6]3+  d2sp3, vuqpqEcdh;

CH (D) [Co(NH3)6]3+  d2sp3, izfrpqEcdh;

OH
C 52. fuEu esa ls dkSulk@dkSuls………….
* * Sol. lS)kfUrd
*
* *
* 54. ukfHkdLusghrk dk lgh Øe………….
O Sol. _.kkosf'kr ukfHkdLusgh muds mnklhu Lih'kht ls izcy gksrs
gSaA
fyokWuksjtsLVªy

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ADVANCED PATTERN
PART TEST-1 (APT-1)
TARGET : JEE (MAIN + ADVANCED) 2021
DATE : 03-05-2019 SET/CODE-1 COURSE : VIJETA (01JPA)
ANSWER KEY
CODE-1
PAPER-1
PART-I MATHEMATICS
1. (AD) 2. (B) 3. (CD) 4. (A) 5. (AB) 6. (ABC) 7. (A)
8. (B) 9. (B) 10. (A) 11. (D) 12. (B) 13. (D) 14. (D)
15. (D) 16. (C) 17. (C) 18. (C)

PART-II PHYSICS
19. (A) (B) 20. (A) (D) 21. (B) (D) 22. (B) (D) 23. (A)(B) (C) 24. (A)(B)(C)
25. (D) 26. (D) 27. (B) 28. (A) 29. (C) 30. (A)
31. (A) 32. (B) 33. (A) 34. (A) 35. (D) 36. (A)

PART-III CHEMISTRY
37. (A) 38. (CD) 39. (ABCD) 40. (BCD) 41. (ABCD) 42. (AC) 43. (A)
44. (D) 45. (B) 46. (A) 47. (C) 48. (E) 49. (C) 50. (D)
51. (C) 52. (D) 53. (B) 54. (C)

PAPER-2
PART-I MATHEMATICS
1. (20) 2. (35) 3. (35) 4. (14) 5. (01) 6. (16) 7. (02)
8. (04) 9. (02) 10. (01) 11. (04) 12. (04) 13. (ABCD) 14. (BCD)
15. (AC) 16. (ABD) 17. (ABCD) 18. (ABC)

PART-II PHYSICS
19. 25 20. 10 21. 20 22. 12 23. 42 24. 16 25. 24
26. 30 27. 10 28. 16 29. 13 30. 10 31. (A) (D)
32. (A)(C) 33. (B) (D) 34. (A) (B) (D) 35. (A) (B) (C) 36. (A) (C)(D)

PART-III CHEMISTRY
37. (28) 38. (36) 39. (00) 40. (06) 41. (05) 42. (03) 43. (02)
43. (24) 45. (16) 46. (30) 47. (06) 48. (36) 49. (ABC) 50. (AD)
51. (AD) 52. (CD) 53. (ABD) 54. (BC)

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