Solution of Multiple Effect Evaporator Problems
Solution of Multiple Effect Evaporator Problems
Chapter 3
The computer solution to such problems can follow exactly the usual
manua1 method, and involves solution of simultaneous equations,
coupled with an iterative procedure (1), (2), (3), (4).
Assumptions: The method to be described rests upon the
following assumptions:
all effects are of the same area ;
heat losses are negl 1gi b1e ;
no carry over of 1 i quJ d i nto the vapour phase occurs.
In the example which follows, {urther simplifications are
made: boiling point elevations are ignored;
only forwdrd feed systems are
considered; thermal recompression is
not included.
Obviously, none of these assumptions are fundamental, and they can be
omitted if desired. Figure 3.1 shows the arrangement and nomenclature for
a forward feed system. Details of specific evaporation
problems can be found in specialist texts (5), (6) (7).
Procedure: The following values must be known or calculable:
overall heat transfer coefficient in edch effect;
temperature of the heating medium;
pressure and hence temperature of saturated vapour from the last
effect (presumed to be governed by conditions at the
condenser);
feed flowrate, temperature and concentration;
desired product concentration.
Obviously, enthalpy data and boiling point elevation data (if
applicable) must also be employed. The calculation procedure then involves
the following steps:
Fx F • L x
(3.1)
Knock ng x , product f1oWra te Ln Can be cal cu1ated .
F = L « + V , + V ,...........V «
(3.*)
Figure 3.1. Flow diagram for Forward Feed Multiple Effect Evaporator System
Condensate Condensate
Nomenclature: S,F - flowrates of steam, feed
V , , \/a , ...Y» - vapour f1oWra tes from is t, 2nJ , effect
...nth efJ ect
L ›, L „ ...L p - 11quor f1oura tes from 1st, 2nd , ... nth
X„ X„ ... x, - wt. fraction of solute in liquor
... nth 1st, 2nd,
fromeffect
xy - wt. fraction of solute in feed
79
= V, + V, +. . . .V, (3.3)
n
F = V, + L, Hence L, is obtained
IT Q g ' Ts Tg - \ ( 6T ) R
(3. 4)
T s- T# - \ IT) p 1 . e.
( 3. 8)
6T ,“ ' IT -¥- (Ts - Tq - Z (IT )p )
zdT‘
g. From the new AT values new effect temperatures are obtained and fresh
calculation of evaporation from each effect is made (step c).
If necessary, new boiling point rise values can be incorporated.
Steps c. to f. are repeated until the effect areas are the same within
suitable limits.
EXAMPLE 3.1
Use the method outlined above to solve the following problem:
Solution
O
From steam tables, the temperature in the last effect is found to be 65.9
C.
The temperature driving force available therefore =
TS - Tn ( st nce there are no BPt r1ses ) , = 12 1.8 - 65. 9 = 55. 9OC ' sT
.“. dT , = 55. 9 x
1/3000 O
1/3000 + 1/2000 + = 12.4 C
1/5000
8
1/2000
dT, = 55. 1/3000 + 1/2000 + 1/ 1500 = 18. 6 C
9
Similarly:
Fx r -- x
6 x 0.1 = L, a 0.3. Hence weight of product = 0.6 = 2.0 Kg/s.
0. 3
Total evaporation = 6.0 - 2.0 = 4.0 Kg/s.
Evapora t i on and heat load i n each effect are now cal cut a ted us ng heat and
ma terl a1 ba1ances as lollows :
2n d effect
V , ( H - h , ) + L , h , ' L a h z + V , H, but
L , = V ,+ L , .”. L , = L , - V, ° F - V , - Y,
8
(3. 9)
( 3. 9a )
( 3. 10)
liquid at 90.8OC, h, =
380.0KJ/kg; vapour at 90.8OC, H,
= 266lKJ/kg.
Heat loads and requJ red areas n each effect are now ready 1y ca1 cu1 ab1 e:
1st effect heat load = Sl, = ( 3. 12)
2. 1*9 2198 = 4. 68 x 10 ^ KJ/ s
required area =
4.68 to°
3000 -x- 12.4 = 126m’
2nd effect head load = V, (H, - h,) =
1.202 (2690 - 458. 4) = 2. 682 x 10’ KJ/ s
requJ red area =
2. 682 10°
2000 x 18. = 72. 1ri’
6
3rd effect head load = V, (H, - h, ) =
1.34 (2661 - 360) = 3. 05 x 10° KJ/ s
required area =
3.05 x IO’
1500 < 24. 9 = 81.
6m*
126 + 72.1 + 81. 6 = 93.2m’
#m- 3
Corrected values of driving forces and temperatures in the affects are:
IT, = 12. 4 126
93.2 = 16.7
72.4
6T, = 18. 6 x 0
93.2 = 14. 4
dT, = 24. 9 81.6 = 21. 80
93.2 fi2. 9^
The ca1cu1a tJ on \ s now repeated using the foll ow ng values adjus ted to gJ ve
6T = 55. 9 .
n- 1
TABLE 3.2 Vector and Matrix Values for the Final Effect
The Values listed are
foralternatives
the ni row of Table 3.1
0 2h ,- H ,- H,
h•- H h •- H• 2h•-H- H H •+h H•+
•- H •+ xr ( H h- )) h )
h •- H • h •- H 2h •- H •- 0
x r’ (H •- ( H • -
86
EVAP1. BAS
Process
Proc.ess
Process
Repeat
Process
Differen
O E ffectś
?W
End
lo gEM s «+»»ess es v»ss «+«s ss «s«»+es»»»++s» e»ss»»»»sss «›c
20 REM — PROGRAM EVAP 1 . BAS TH I S PROGRAM SOLVES
30 REM - FORWARD FEED HULT I -EFFECT EVAPORATOR PROBLEMS
40 REH — UP TO 10 EFFECTS
60 REH — PRO*RAH NOMENCLATURE
60 REM - A(J) - Heat trw•eer area, Jth effect, sg m
70 REM - B(J) - Intermediate values used in
80 REM correction of temperature differences
90 REM - D(J) - Temperature difference across effect,
100 REM Deg C
110 REM - H(J) - Heat load across effect, KJ/s
120 REM - L(J} - Liguid flowrate from effect, kg/s
130 REM - P(J) - Vectors for matrix calculations
140 REM - R(J) - Thermal resistance, used in
150 REM calculation of D(J) values
160 REM - T(J) - Temperature in effect, DEG C
170 REM - U(J) - Overall heat transfer coefficient
180 REM in effect, W/sg m,K
190 REM - V(J) - Yapour rate from effect, kg/s
200 RfiH - W(J) - Previously oalculated values of Y(J)
210 REM - X(J) - Vapour enthalpy. KJ/kg
220 REM - Y(J) - Liguid enthalpy, KJ/kg
230 OEM - M(J,J) - Mntrix of enthalpy values
240 REM - NiJ,J) - Inverse matrix of enthalpy values
250 REM - PROGRAM DESCRIPTION
260 REM - LINES 1000 - 1320 Array dimensions are declared,
270 REM — arid choice of solution method is made. The
?80 REM - relevant data concerning flows, temperatures, etc,
2SU REM - a‹e then input to the program
30U REM - LINES 1330 - 1450 Driving forces and
310 h£M - temperatures ir the effects are calculated
320 REM - using eQuations 3.4 and 3.5
330 OEM - LINEG l2?O, 1460 - 1500 The properties of rure
340 REM - water have been assumed for the process fluid.
350 REM - Enthalpies of saturated liquid and vapour, taken
360 REN - from steam tables over a limited temperature range
37† REM - have bees fitted to linear equations using
S0 H?M - regression snslysis (see example 2. 1;
39† RKM — LINES lti† - l56U Calculations are performed for
400 REM - a single effect system, using equations 3. 1, 3.2,
4i0 ?tEM - ?J.2. eirid 3. *
é2† SEP LIWES 1570 1600. 2140 — ?56O, and 2t80 - 2960
4:O REM - For two or more effects it is necessary to write
440 RAM - General equntions for the first, intermediate. wad
45a h£M - f:na- e-fects. The simultaneous liiieai’
eguatiorin
460 HEN - gonernted nre then solved ty aither matrix algebra
47† NEW - cr Ly Sez3el iteration. Subroutines to do this
:1b† hEM - are accessed at lines 1570 — 1600
49G REM - SUBROUTINE FOB o0LJTION OF VAPOUR QUANTITIES BY
†% RzM — !VTBIK ALGEBRA LINES 2140 - ?560
510 REM - Li:res 21%0 to 2150 establish the required matrix
’2' BEM - dbr‹er:sire:=i lines 2?OU tc 241t) ascribe the
matrix h30 8YN - vsluos from tables 3.1 arid 3.2 to the
matrix M;
540 kEM lines 2420 to ?470 ascribe tho vsctor values from
55† REM - Tables 3. 1 and 3. 2 to the matrii: P. Solution
of E60 REM - khe uriknowns (steam supply rate S8,
vapourisation 97C REM — from each effect V(J)) is obtained
by
hBO SIM - multiplication of the inverse matrix by the vector
°9† REV - at lines 248† snd ?4g0
* GO REM — 3UTROR'" I N* *"OR YOU T ISH 0? \*APOUR QUAIL TI T YES B’*
i O ITEM — BE i*DE* I TEMA'I' I Oh L I NES 2580 — 2960
620 REM - First a set of duplicate values of V(J) are
630 REM - established as W(J) (lines 2600 to 2660). If a
640 REM — double effect solution is required, then direct
650 REM - solution is possible, wi€hout iteration. This
G60 REM - is doric usir‹g equation 3.17a (lines 2840 and
2850)
670 REM - a1;d equation 3. 15 (line 2860). Determination of
%80 REM — vapour from the last effect is not carried out
690 REM - within the subroutine.
700 REM - For cases involving more than two effects, first
710 REM - effect vapour is calculated using equation 3. 16a
720 REM - (lines 2680 and 2690). Yapour rates from
730 REM - intermediate effects are calculated using
740 REM - equations 3. 16b, c etc (lines 2710 to 2770).
750 REM - Yapour from the last but one effect is calculated
760 REM - using equations 3. 17b,c etc (lines 2780 to 2830).
770 REM - Steam rate is then calculated, as for the double
780 REM - effect case, at lins 2860. A test is then made
790 REM - to determine whether the values of V(J) and
8OU REM - W(J) agree within preset limits. If thcy do
510 REM - riot, another iteration is carried out (lines
5zG REM — 2920 to 2950)
830 REM - LINES 1610 - 1710 Vepour flowrate from the last
840 REM - effect is calculated, then for each cffect, liguor
050 REM - flawreto, heat load, and required area for heat
8G0 REM - trar:sfer, are calculated.
970 2EM - LUES 17 0 - 1d7O Values calculated fr,l eech
880 REM - effect are printed.
S9O OEM - UMES 1890 — 2C0O If inspection ot the areas
SOfi REM - oaloulatod for tho effects shows thest to differ
9iO RAM - bevor,d acceptable limits, then the calculation
920 PEW - is repeated. Lines 1930 to 2040 recalculate
03U OEM - tmmperat,ure driving fo:’ces usi:a6 equations 3.6
04† REN - and 3.7;lines 20tG to 2070 correct these new
950 R2?1 - v:,lust uuir‹g equation 3.'
060 REM - LINEG 2090 - 2120 Provide ar opportunity to
97O PLM - roruri using a different numLer of effects arid/or
266G NEXT J
26 70 IF N1=2 'I'HEN 28 40
2 b" 9O V( 1 ) =FI ( Y( I ) —Y t2 ) —V ( 2 ) V ( X ( 2 j —Y( 2 ) )
* 690 V \ 1 ) =’7( 1 ) / ( 2 BY( 1 ) —X( 1 ) —Y ( ? } }
2700 IF N1-3 THEN 2790
2710 FOR J:2 TG Nl-2
2’/ 2 0 V( .I ) =F 1* I Y( J ) —Y ( J +1 ) ) —V( J +1 ) * ( X( J+ 1 ) —Y( J+ 1 ) )
2730 FOR K=1 TO J - 1
27 40 V( J ) -V( I ) —V I K ) * ( Y( J I —Y ( J +1 ) )
27 so Nxy.T K
2 7 G 0 V ( J ) -V( J ) / ( 2 BY( J ) X ( J ) -Y ( J+ 1 ) )
277O NEX7 J
2780 V( N1 —1 ) =F 14 ( Y( N1— 1 ) —X ( N1 ) + ( C 1/C2 ) * ( X( N1 ) —Y ( N1 ) ) )
2790 FOR K= 1 TO N 1 --2
2300 V( N1— 1 ) —V ( N1 — 1 ) —V( K ) * ( Y( N I— 1 ) —X ( N1 ) )
2810 NEXT K
2820 V(N1-1)-V(N1-1)/(2*Y(N1-1)-X(N1-1)-K(N1)}
2930 GITO 2860
2840 V(1)=F1*(Yt1)-X(2)+(C1/C2)*(X(2)-Y(2}))
2850 Y(1)=V(1)/(2*Y(1)-X(1)-X(2))
2860 S3-(Y(1)*(X(1)-Y(1))-F1 (4.1868*T1-Y(1)))/S2
2870 V1=O
2880 FOR J=1 TO N1-1
28go vi=vi+V(J)
2900 NEXT J
2910 IF N1-2 THEN 2960
2920 FOR J-1 TO N1-1
2930 IF V(J)/W(J)>1.001 THEN 2600
2940 IF W(J)/V(J)>1.001 THEN 2600
2950 NEXT J
2960 RETURN
2970 END
EXAMPLE 3.2
Use the computer program to repeat Example 3.1 It will be seen
that the first computer iteration gives results closely similar to
those obtained by the manual calculation. After a further two
iterations, closely similar valJes
are obtained for the required heat transfer
areas. LOAD”A:E‹APl
NUNBER OF EFFECTS
U 'VALUES , H/SQ M, 1 E fI
U(1,
"' 15OO
EFFECT TEMP DEL . T HEAT AREA VAPN
DEc C DEG C 8 /S sa M G, s
1 65 . S 55 . 9 9 361 . 9 1 11 . 7 4. 0
STEAM TO F I RET EFFECT 4 . 262322 UG /S
NUMBER OF EFFECTS
? 3
U VALUES,W/S8 M,DEG K
tT( 1 )
? 3000
U( 2 }
? 20G0
U( 3 1
? 1500
EFFECT TEMP DEL . 7 HEAT AREA VAPN
DEG C DEG C CJ/S SP N KG,*S
1 109. 4 12 . 4 4C7 9. 2 125. 6 1.2
2 90. 7 18. 6 26 73. 9 71 . 8 1. 3
3 65 9 24.8 3050.5 81.9 1.5
STEAM TO FIRST EFFECT 2.130355 MG/S
DO YOU iiANT TO RERUN? TYPE Y OR N
?Y
EFFECT TENP DEL . T HEAT AREA VAPN
DEG C DEG C US /S SQ M KG
/S
1 104. 1 17 . 7 4608 . 8 86 . S 1.2
2 89.0 15.2 2738.3 90.3 1.3
3 65.9 23.1 3043.3 88.0 1.4
STEAM TO yIRST EFFECT 2. 0983 1 3 VG/S
D0 YOU WANT TO RERUN? TYPE Y GR N
EFFECT TEMP DEL . T HEA'T AREA VAPN
1 DEG C DEG C KJ/S S8 M KG/S
1 04. 4 17. 4 46 1 1 . 2 8 8. 3 1.2
96. S 15. 5 2?33. 7 88 . 1 1. 3
3 bt.9 23.0 8045.9 88.3 1
4 STEAM TO FIRST EFFECT 2 099899 K0/S
PROBLEMS - CHAPTER 3
1. A forward feed evaporator system has three effects each of 80m’
heat transfer surface. Heat transfer coefficients in successive effects
are 3000, 2500 and 2000 W/m’K. Steam enters the calandria of the
first effect at a presume of 320kPa; the pressure above the liQuor in
the final effect is l8kPa. The feed enters effect one at a concentration
of 3 wt% solids and a temperature of 40 C i product leaves the flna1 effect at a
concentra tJ on of 32 stS so1Jds .
Use the program to determine the feed and flna1 product rates , as sunni ng the
so1ut\ on to have the properti es of water.
HP nt: Assume a va1ue for feedra te and use thls to run the program; s cale
thls f1gure up or down as requJ red to sa t1s fy the area requJ rement.
2. An evaporator sy s ten 1 s to be install ed for the concentra t on of an aqueous
so1u tion of an organs c materi at. I t i s desk red to make an estJrate of the
number of effects •hJ ch should be employed n order to gJ ve the l o•est annual
tota1 costs (operating p1us fixed costs) .
Pi1 ot p1ant work has es tab1J shed that the overa11 coeffJ ci ent of heat
transfer i n the evaporator, us1ng low pressure steam for heatl ng , 1s corre1a ted
approxJ mately by the lolloring s imp1e rel a t ionsh p:
U = 2500 - 2000C V/m* K where C = so1utJ on concentra t on , •t fractl on.
Assuming a forward feed system is to be employed, use the program, and
the
data below, to estimate the optimum number of effects to be used:
REFERENCES
1 C.J. Geankoplis, Transport Processes and Unit Operations, Allyn and
Bacon, Boston, U.S.A. 1978.
2 C.O. Bennett, J. E. Nyers , Momentum Hea t and Mass Transfer, McGraw-Hill
Interna ti onal, Tokyo, Japan , 1983.
3 D. Azbel , Heat Trans fer App1 J cations n Process Eng i neer1ng , Noyes
Pub1 ca tJ ons , New Jersey, U . S.A. , 1984.
4 J. N. Cou1 son , J.F. RJ cha rdson , Chemx ca1 Engineer ng , Volume I I , 3rd Eds tJ
on ,
Pergamon Press, Oxford, 1978.
5 A. Nisenfeld, Industrial Evaporators, Principles of Operation &
Control, Instrument Society of America, 1985.
6 F. Bosnjakovic, P.L. Blackshear, Technical Thermodynamics, Holt,
Rinehart
and Winston, Eastbourne, U.K., 1965.
7 G.P. Meade, Cane Sugar Handbook, 10th Edition, John Wiley & Sons,
New York, U.S.A., 1977.
8 C.D. Holland, Fundamentals and Modelling of Separation Processes,
Prentice Hall International, New Jersey, U.S.A., 1975.