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Material Safety Data Sheet: Ingestion

This material safety data sheet provides information on a two-component epoxy resin and hardener product. The resin component is an irritant and hazardous to aquatic life. The hardener component causes burns, is a sensitizer, and is also hazardous to aquatic life. Both components contain substances that require proper personal protective equipment be used and that the product be handled and disposed of carefully due to its hazards.

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216 views4 pages

Material Safety Data Sheet: Ingestion

This material safety data sheet provides information on a two-component epoxy resin and hardener product. The resin component is an irritant and hazardous to aquatic life. The hardener component causes burns, is a sensitizer, and is also hazardous to aquatic life. Both components contain substances that require proper personal protective equipment be used and that the product be handled and disposed of carefully due to its hazards.

Uploaded by

Mainraj
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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MATERIAL SAFETY DATA SHEET

1.IDENTIFICATION OF SUBSTANCE/PREPARATION AND COMPANY


Product Name: RAWL PURE EPOXY
Company: Koelner SA ul. Kwidzyńska 6 51-416 Wrocław
Chemical Name & Synonyms: 2 COMPONENT CHEMICAL ANCHOR GROUT CONTAINING EPOXY RESIN
AND MANNICH BASE EPOXY HARDENER
2.HAZARDS IDENTIFICATION
Resin: Irritating to eyes and skin. May cause sensitisation by skin contact. Toxic to aquatic organisms, may cause long-term adverse effects
in the aquatic environment.
Hardener: Causes burns. May cause sensitisation by skin contact. Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
3.COMPOSITION/INFORMATION ON INGREDIENTS
RESIN
Hazardous Substance CAS Number Concentration Range Warning Symbol Risk Phrases
Bisphenol A/F Epoxy Resin 40216-08-8 50- 70% Xi, N R36/38, R43
1,6-Hexanediolglycidylether 16096-31-4 1 – 10% Xi R36/38, R52/53

HARDENER
Hazardous Substance CAS Number Concentration Range Warning Symbol Risk Phrases
Paratertiarybutylphenol 98-54-4 10 – 30% Xi R36/37/38
Alpha, Alpha-Diamino-m-Xylene 1477-55-0 < 7.95% Xn, C R20/22, R34, R43,
R52/53
Trimethylhexamethylenediamine 25620-58-0 1 – 10% Xn, C R22, R34, R43, R52/53
Nonylphenol Nonylphenol 25154-52-3 1 – 5% Xn, C, N R62, R63, R22, R34,
branched R50/53
2-Piperazin-1-ylethylamine 140-31-8 1 – 5% Xn, C, N R21/22, R34, R43,
R52/53
2,4,6- 90-72-2 1 – 10% Xn. Xi R22, R36/38
Tris(Dimethylaminomethyl)phenol

4.FIRST AID MEASURES Summon immediate medical assistance on contact with skin, eyes, inhalation or
ingestion.
Eye: Irrigate with clean water for at least 15 minutes. Seek immediate medical attention.
Skin: Remove from skin with plenty of soap and water. Remove contaminated clothing. If irritation persists, seek medical advice.
Ingestion: Drink plenty of water. Seek medical attention. DO NOT INDUCE VOMITING.
Inhalation:Move patient to fresh air and allow to rest. If patient is slow to recover or unconscious, obtain medical assistance immediately.
First Aiders should protect themselves from exposure (Ref to Section 8).
5.FIRE FIGHTING MEASURES
Extinguishing Media: Dry powders, CO2 and Foam.
Exposure Hazards: Sealed containers, heated, can pressurise leading to explosion. In combustion emits acrid black smoke and irritating
fumes.
Fire Fighting Equipment: Wear self contained breathing apparatus.

6.ACCIDENTAL RELEASE MEASURES


Do not discharge into sewers. Scrape up and place into a suitable container for disposal. Wash area with water.
Refer to section 5, 8 and 13 for Protective Measures and Disposal.
7.HANDLING AND STORAGE
Resin: Keep away from heat and sources of ignition. Ensure there is sufficient ventilation of the area. Store in cool, well ventilated area.
Hardener: Keep away from heat and sources of ignition. Ensure there is sufficient ventilation of the area. Store in cool, well ventilated area.

8.EXPOSURE CONTROLS/PERSONAL PROTECTION


Workplace exposure limit – Paratertiarybutylphenol WEL (8 Hr exposure limit) 0.08ppm, Alpha, Alpha-Diamino-m-Xylene WEL (8 Hr
exposure limit) 0.1ppm
Respiratory: Ensure good ventilation to minimise exposure to vapours.
Ingestion: Unlikely during normal use.
Skin Protection: Wear gloves and impermeable protective clothing.
Eye Protection: If splashing can occur, goggles should be worn. Ensure eye bath is to hand.
9.PHYSICAL/CHEMICAL PROPERTIES

Resin Hardener
Appearance Thick white Paste Appearance Thick red Paste
Odour Barely perceptible Odour Characteristic ammoniacal
Density 1.20g/cm3 Density 1.50g/cm3
0
Flash Point > 100 C Flash Point > 100ºC)
Explosive properties N/D Explosive properties N/D
Autoflammibility N/D Autoflammibility N/D
Solubility Insoluble in water Solubility Insoluble in water

10.STABILITY AND REACTIVITY


Stability: Stable under normal conditions.
Materials to Avoid - Hardener: Oxidising agents and acids.
Resin: Amines.
Hazardous Decomposition: Emits acrid smoke and irritating fumes of carbon and nitrogen oxides when heated to decomposition.
Hazardous Polymerisations: None.
11.TOXICOLOGICAL INFORMATION
Hardener: contains 2,4,6-Tris(dimethylaminomethyl)phenol. Oral (rat) LD50:1200mg/m3, SKIN (rat) LD50:1280mg/m3
Eye: Causes burns.
Skin: Irritation and redness may occur. The possibility of allergic sensitisation should be considered.
12.ECOLOGICAL INFORMATION
Do not discharge into drains or the environment.
13.DISPOSAL CONSIDERATIONS
In an uncured state, place in a suitable container and dispose as chemical waste in accordance with local regulations. Small quantities of
resin and hardener may be reacted together, allowed to cure and then disposed as solid waste.
14.TRANSPORT INFORMATION
RESIN
UN No: 3077
Packing group: III
ADR Class: 9
LQ: 27
Shipping name:Environmentally hazardous substance, solid, N.O.S. (Bisphenol- A/F-Epoxy resin)
NOTE: According to ADR regulations, shipment that do not exceed quantity of 6 kg per Inner Packaging (LQ 27) is an exempt to
ADR regulations.
HARDENER
UN No: 1759
Packing group: III
ADR Class: 8
LQ: 24
Shipping name: corrosive solid, N.O.S. (Alpha, Alpha-Diamino-m-xylene)
NOTE: According to ADR regulations, shipment that do not exceed quantity of 6 kg per Inner Packaging (LQ 24) is an exempt to
ADR regulations.
15.REGULATORY INFORMATION

RESIN
Irritant, Dangerous for the environment.

Risk Phrases (R36/38) Irritating to eyes and skin.


(R43) May cause sensitisation by skin contact.
(R51/53) Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
Safety Phrases (S2) Keep out of reach of children.
(S24) Avoid contact with skin.
(S37) Wear suitable gloves.
(S61) Avoid release to the environment. Refer to special instructions/safety data sheets.

HARDENER
Corrosive

Risk Phrases (R34) Causes burns.


(R43) May cause sensitisation by skin contact.
(R51/53) Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
Safety Phrases (S1/2) Keep locked upand out of the reach of children.
(S26) In case of contact with eyes, rinse immediately with plenty of water and seek medical
advice.
(S36/37/39)Wear suitable protective clothing, gloves and eye/face protection.
(S45) In case of accident or if you feel unwell, seek medical advice immediately
(show the label where possible)

16.OTHER INFORMATION
Risk phrases used in section 2 and not previously mentioned.:
R36/37/38 - Irritating to eyes, respiratory system and skin.
R20/22 - Harmful by inhalation and if swallowed.
R21/22 - Harmful in contact with skin and if swallowed.
R52/53 - Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R62 - Possible risk of impaired fertility
R63 - Possible risk of harm to the unborn child
R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
The information contained within this document is furnished without warranty of any kind. Users should consider this data only as a
supplement of other information gathered by them and make independent determinations of suitability and completeness of information from
all sources to ensure proper use and disposal of these materials and the safety of employees customers.

KOELNER S.A.
ul. Kwidzyńska 6
51-416 Wrocław
tel. + 48 0(71) 32 60 100
fax + 48 0(71) 37 26 111

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