Thermal State of The General Time-Dependent Harmonic Oscillator
Thermal State of The General Time-Dependent Harmonic Oscillator
Abstract. Taking advantage of dynamical invariant operator, we derived quantum mechanical solu-
tion of general time-dependent harmonic oscillator. The uncertainty relation of the system is always
larger than ~=2 not only in number but also in the thermal state as expected. We used the diagonal
elements of density operator satisfying Leouville–von Neumann equation to calculate various ex-
pectation values in the thermal state. We applied our theory to a special case which is the forced
Caldirola–Kanai oscillator.
1. Introduction
Vibration may be one of the most dominant physical aspect that we come upon in everyday
life [1]. For small oscillation, it can be approximated to the motion of harmonic oscillator.
Harmonic oscillator that has time-dependent mass or frequency may be a good example of
time-dependent Hamiltonian systems. Although a large number of dynamical systems have
been investigated using approximation and perturbation method in the literature [2,3], we
confine our concern to the exact quantum solution of the time-dependent system. There
are about three kinds of methods to solve the quantum solution of time-dependent har-
monic oscillator. These are propagator method [4–6], unitary transformation method [7–9]
and invariant operator method [10–16]. We will use invariant operator method and uni-
tary transformation method together to evolve the quantum theory and investigate thermal
state of the general time-dependent harmonic oscillator. The time-dependent harmonic
oscillator has several applications such as electrical behavior of LC-circuit that has time-
dependent parameter [17] and/or RLC-circuit [18], path-integral formulation of real-time
finite-temperature field theory [19–21], dissipative quantum tunnelling effect in macro-
scopic system [22–25] and quantum motion of an ion in a Paul trap [7,26,27].
When a system interacts with environment, its coupling parameters may explicitly de-
pend on time. Even if the system is closed so that it is conserved as a whole, its subsystem
7
Jeong-Ryeol Choi
may implicitly depend on time through interaction with the remnant of the system. The
main purpose of this paper is to evolve the thermal state of the general time-dependent
harmonic oscillator. The Liouville–von Neumann equation [28,29] for non-equilibrium
dynamics can be applicable to both time-dependent harmonic and unharmonic oscillator.
The density operator of the system can be obtained using the wave function satisfying
Schrödinger equation and can be used to derive various expectation values of variables in
the thermal state.
In x2, we investigate quantum mechanical solution of the general time-dependent har-
monic oscillator. The thermal state of the system is discussed in x3 on the basis of
Liouville–von Neumann approach. In x4, we will apply our theory for a special case which
is the forced Caldirola–Kanai oscillator. Finally, x5 summarizes this paper and concludes
about some physical results of the system.
Ĥ (x̂; p̂; t ) = A(t ) p̂2 + B(t )(x̂ p̂ + p̂x̂) + C(t ) p̂ + D 2 (t )x̂2 + D1 (t )x̂ + D0 (t ); (1)
The introduction of invariant operator may save the labor of finding quantum mechanical
solution of the system. We let the trial invariant operator as the form
dIˆ(t ) ∂ Iˆ(t ) 1 ˆ
= + [I (t ); Ĥ ] = 0: (4)
dt ∂t i~
Substituting eqs (1) and (3) in the above equation gives
α2 (t ) =
1
4A
f4[c1ρ12 (t ) + c2ρ1(t )ρ2 (t ) + c3ρ22 (t )]B
[2c1 ρ1 (t )ρ̇1 (t ) + c2 ρ̇1 (t )ρ2 (t ) + c2 ρ̇2 (t )ρ1 (t ) + 2c3 ρ2 (t )ρ̇2 (t )]g; (6)
where c1 –c3 are constants and ρ̈1;2 (t ) are two independent solutions of the following dif-
ferential equation
Ȧ 2ȦB
ρ̈1;2 (t ) ρ̇1;2 (t ) + 2Ḃ 4B 2
+ 4AD2 ρ1;2 (t ) = 0: (8)
A A
Ût = Û
00Û 0Û ; (9)
i i
Û = exp x p p̂ exp p p x̂ ; (10)
~ ~
α2 2
Û 0 = exp i x̂ ; (11)
2α1 ~
00
Û = exp
i
(x̂ p̂ + p̂x̂) ln(2α 1 ) : (12)
4~
We can transform the invariant operator using the above operator as
These satisfy the boson commutation relation [ b̂; b̂† ] = 1. In terms of these operators, eq.
(14) can be simplified to
Substituting eqs (9) and (20) into the above equation gives
1 r
ω 4
=
ω
hx̂jn(t )i = 2α1 ~π
Hn p 1n 2α1 ~
(x̂ x p ) exp
i
~
p p x̂
2 n!
1 ω
exp 2α1 ~ 2
+ iα2 (x̂ x p )2 : (22)
The x̂ space Schrödinger solution hx̂jψ n i of the Hamiltonian, eq. (1), is the same as the
ˆ except for some time-dependent phase factor, ε n (t ) [30]
eigenstate of I,
Inserting the above equation into Schrödinger equation, we derive the relation
∂
~ε̇n (t ) = hn(t )j i~ Ĥ jn(t )i : (24)
∂t
where H p (x p (t ); p p (t ); t ) is defined as
Substituting eq. (25) into (23), we can obtain the exact wave function as
Z
A(t 0 ) 0
hx̂jψn(t )i = hx̂jn(t )i exp 1 t
iω n + dt
2 0 α1
Z
H p (x p (t 0 ); p p (t 0 ); t 0 )dt 0
i t
: (27)
~ 0
The p̂ space wave function is related to the x̂ space by the Fourier transformation
Z∞
h p̂jψn (t )i = p 1
hx̂jψn (t )i exp i ~ dx̂:
p̂x̂
(28)
2π ~ ∞
Using (28), the above equation can be calculated as
1 1
2ωα1 4
=
(ω 2iα2 )n 2
=
h p̂jψn(t )i = ( i)n
~π
p 1n (ω + 2iα2 )n+1
2 n!
"s #
2α1 ω
Hn ~(ω 2 + 4α22 )
( p̂ p p)
exp ~ x p( p̂ p p) ~α(1ω( p̂+ 2ipαp) )
2
i
Z t 0 2
A(t ) 0
exp iω n + 2 0 α dt 1
Z
1
i t 0 0 0 0
H p (x p (t ); p p (t ); t )dt : (29)
~ 0
These operators also satisfy [â; â † ] = 1. In terms of eqs (30) and (31), (3) can be expressed
as
1
Iˆ(t ) = ~ω â â + †
: (32)
2
From eqs (30) and (31), we can confirm that the coordinate and the momentum can be
expressed as
r
~α1 †
x̂ = (â + â ) + x p ; (33)
ω
s
~ h ω ω i
p̂ = i + iα2 ↠iα2 â + p p: (34)
α1 ω 2 2
Using eqs (27), (33) and (34), we can calculate the following expectation values
∆x̂∆ p̂ = [hψn jx̂2 jψn i ( hψnjx̂jψn i)2 ]1 2 [hψn j p̂2jψn i (hψnj p̂jψn i)2 ]1 2
= =
~q 1
= ω 2 + 4α22 n + : (40)
ω 2
This is always larger than ~=2 as expected. The uncertainty relation of q-deformed har-
monic oscillator also differs from the uncertainty relation for the simple harmonic oscillator
[31].
By performing a similar procedure, we obtain the expectation value of Hamiltonian as
3. Thermal state
We consider an ensemble of particles that satisfies the given general time-dependent har-
monic oscillator motion. Let us assume that these particles conform to the Bose–Einstein
distribution function.
Density operator of the system may satisfy Liouville–von Neumann equation as
∂ ρ̂ (t ) 1
+ [ρ̂ (t ); Ĥ ] = 0: (42)
∂t i~
Then, we can express the density operator in x̂ space as
1 ∞ ~ω
ρ̂ (x̂; x̂0 ; t ) = hx̂jψn (t )i exp hψn (t )jx̂0 i
1
Z (t ) n∑
n+ ; (43)
=0
kT 2
where k is the Boltzmann constant and T the temperature of the system at initial time.
The partition function of the system can be given by
∞
Z (t ) = ∑ hψn (t )je Iˆ(t )=(kT )
jψn (t )i : (44)
n=0
Using eq. (27), the partition function, eq. (44) and the density operator, eq. (43) can be
calculated as
1
Z (t ) = ; (45)
2 sinh[~ω =(2kT )]
If the difference between x̂ and x̂ 0 are sufficiently small compared to (2~α 1 =α2 )1=2 and
~= p p , and 1=(kT ) approaches zero, the density operator may be simply represented as
~ω
ρ̂ (x̂; x̂0 ; t ) ' δ (x̂ x̂0 ): (48)
kT
On the other hand, at low temperature, it becomes
1
ω = 2
ρ̂ (x̂; x̂0 ; t ) ' p p (x̂ x̂0 )
i
exp
2π ~α1 ~
(
iα2 2
exp [x̂ x̂02 2(x̂ x̂0 )x p ]
2~α1
)
ω 02
2 2
(x̂ + x̂ + 2x p 2x̂x p 2x̂0 x p ) : (49)
4~α1
The diagonal element of the density operator, eq. (46), can be written as
1
ω ~ω = 2
ω ~ω 2
f (x̂) = tanh exp tanh (x̂ x p) :
2π ~α1 2kT 2~α1 2kT
(50)
The above equation represents the probability that the mass of the oscillator reside at x.
ˆ As
temperature increases, it becomes
ω ω2
f (x̂) '
1 2
exp (x̂ x p) : (51)
2 (πα1 kT )1=2 4kT α1
Equation (50) can be used to calculate the expectation value in coordinate space as
Z∞
hx̂l iT = x̂l f (x̂)dx̂: (52)
∞
When considering eq. (44), the expectation value of Iˆ in the thermal state can be derived
from
Using the same procedure in the xˆ space, the p̂ space representation of the density operator
can be obtained as
1
2α1 ω ~ω =2
ρ ( p̂; p̂0 ; t ) = x p ( p̂ p̂0 )
i
tanh exp
~π (ω + 4α2 )
2 2 2kT ~
( (
α1 ω 2iα2 2
exp [ p̂ p̂02 2p p( p̂ p̂0 )]
~(ω 2 + 4α22 ) ω
" #))
1 0 2 ~ω 0 2 ~ω
( p̂ + p̂ 2p p) tanh + ( p̂ p̂ ) coth :
2 2kT 2kT
(57)
At high temperature, the above equation becomes
1 2
α1 ω 2
=
The probability that the mass of the oscillator resides at p̂ is obtained taking the diagonal
elements of eq. (57) as
1
2α1 ω ~ω =2
f ( p̂) = tanh
~π (ω + 4α2 )
2 2 2kT
2α1 ω ~ω
exp ~(ω + 4α2 )
2 2
tanh
2kT
( p̂ p p)2 : (60)
Then, the expectation value of the Hamiltonian, eq. (1), can be calculated as
hĤ iT = ω~ (α3 A 2α2B + α1 D2 ) coth
~ω
2kT
+ H p (x p (t ); p p (t ); t ) (65)
~ q ~ω
= ω 2 + 4α22 coth : (66)
2ω 2kT
By comparing the above equation with eq. (40), we can confirm that the uncertainty rela-
tion in thermal state varies as time goes by, with the same fashion in number state.
βt p̂2 βt 1
Ĥ = e +e mω02 x̂2 eβ t F (t )x̂; (71)
2m 2
where m is the mass, β the damping constant and F (t ) the arbitrary time-dependent driving
force. Equation (8) becomes
ρ̈1;2 + β ρ̇1;2 + ω02 ρ1;2 = 0: (72)
The two classical solutions of the above equation can be written as
β t =2 iω t
ρ1 (t ) = ρ1 (0)e e ; (73)
β t =2 iω t
ρ2 (t ) = ρ2 (0)e e ; (74)
where ω is given by
r
β2
ω= ω02 : (75)
4
We choose c1 –c3 in eqs (5)–(7) as
1
c2 = ; c1 = c3 = 0: (76)
2mρ1 (0)ρ2 (0)
The particular solutions x p and p p satisfy the following relations:
F (t )
ẍ p + β ẋ p + ω02x p = ; (77)
m
p̈ p β ṗ p + ω02 p p = eβ t Ḟ (t ): (78)
The solutions of the above equations depend on F (t ). If, we choose F (t ) as
F (t ) = F0t ; (79)
the solutions of eqs (77) and (78) will be
F0 β F0
x p (t ) = t ; (80)
mω02 mω04
F
p p (t ) = 02 eβ t : (81)
ω0
We will also investigate the system driven by the exponentially decaying force:
γt
F (t ) = F0 e ; (82)
where γ is an arbitrary real constant. In this case, the particular solutions are given by
F0 =m
x p (t ) = e γt ; (83)
γ2 β γ + ω02
γ F0
p p (t ) = e(β γ )t
: (84)
γ 2 β γ + ω02
(a) (b)
Figure 1. Ground state (a) and first excited state (b) probability density in number state
for the forced Caldirola–Kanai oscillator that the driving force is given by eq. (79), as a
function of position x̂ and time t. We used F0 = 1, ω0 = 1, β = 0:4, ρ1 (0) = ρ2 (0) = 1,
m = 1 and ~ = 1.
The system, we finally consider is the one driven by the periodic force
F (t ) = F0 cos(ω1t + φ ); (85)
where ω1 is a real driving force and φ an arbitrary phase. Equation (85) has the classical
particular solutions which are given by
F0 =m
x p (t ) = q cos(ω1t + φ δ ); (86)
(ω02 ω12 )2 + β 2 ω12
F0 ω1
p p (t ) = q eβ t sin(ω1t + φ δ ); (87)
(ω02 ω12 )2 + β 2ω12
where
β ω1
δ = tan
1
: (88)
ω02 ω12
We depicted ground state and first excited state probability densities in figures 1–3 for eqs
(79), (82) and (85). The center of probability densities shifted from zero point along x̂-axis
with time according to the magnitude of the driving force.
We will investigate the system driven by the periodic force, eq. (85), in more detail.
For this case, the expectation value of the Hamiltonian, eq. (65), in thermal state can be
evaluated as
where
1 2 2
Θ(t ) = [ω sin (ω1 t + φ δ) ω02 cos2 (ω1 t + φ δ )]: (90)
2 1
We can confirm that eq. (89) oscillate with time.
(a) (b)
Figure 2. Ground state (a) and first excited state (b) probability density in number state
for the forced Caldirola–Kanai oscillator that the driving force is given by eq. (82), as a
function of position x̂ and time t. We used F0 = 2, ω0 = 1, β = 0:4, ρ1 (0) = ρ2 (0) = 1,
m = 1, γ = 1 and ~ = 1.
(a) (b)
Figure 3. Ground state (a) and first excited state (b) probability density in number
state for the forced Caldirola–Kanai oscillator that the driving force is given by eq.
(85), as a function of position x̂ and time t. We used F0 = 1, ω0 = 1, ω1 = 1:5, β = 0:4,
ρ1 (0) = ρ2 (0) = 1, m = 1, φ = 0 and ~ = 1.
In general, the mechanical energy is somewhat different from the Hamiltonian for the
time-dependent system such as Caldirola–Kanai oscillator [34]. For the case driven by
eq. (85), the mechanical energy expectation values in the thermal state can be calculated
as [34]
hÊ iT = e 1 2
2β t
2m
h p̂ iT + 12 mω02hx̂2 iT
β t ~ω0 ~ω p2 1
2
2β t p
+ mω 0 x p :
2 2
=e coth +e
2ω 2kT 2m 2
β t ~ω0 ~ω
2
F02
=e coth +
2ω 2kT 2m[(ω02 ω12)2 + β 2 ω12 ]
[ω12 sin2 (ω1t + φ δ ) + ω02 cos2 (ω1t + φ δ )]: (91)
Thus, we see that eq. (91) also oscillates with time since the system exchanges the energy
with the surroundings. However, at ω 1 = ω0 , the energy does not oscillate and becomes
(in the limit t ! ∞):
F02
hÊ iT = 2m[(ω 2 ω 2:
ω12)2 + β 2 ω12 ] 0
(92)
0
(a) (b)
Figure 4. Hamiltonian (a) and quantum-mechanical energy (b) expectation values for
the forced Caldirola–Kanai oscillator in the thermal state as a function of time t. The
q
solid line is for ω1 = 0:5, the long dotted-line for ω1 = ω0 = 1 and the short dotted line
for ω1 = ω02 β 2 =2 ' 0:959. We used F0 = 1, ω0 = 1, β = 0:4, ρ1 (0) = ρ2 (0) = 1,
m = 1, φ = 0 k = 1, T = 300 and ~ = 1.
There are two resonant frequencies for this system [35]. One is the velocity resonant
frequency which is same as the natural frequency ω 0 and the other is the amplitude resonant
q
frequency which is given by ω02 β 2 =2. In figure 4, we depicted the Hamiltonian and
the mechanical energy expectation values for these two resonant frequency in the thermal
state. Even if the mechanical energy far from the resonance points in frequency gradually
disappears with time, the mechanical energy near the resonance points remained the same.
5. Summary
Taking advantage of the invariant operator, we obtained the solution of the Schrödinger
equation for the general time-dependent harmonic oscillator. We assumed that an ensemble
of particles that satisfies the general time-dependent harmonic oscillator motion conform
to the Bose–Einstein distribution function at equilibrium temperature. We investigated
uncertainty relation in number and thermal states. Comparing eqs (40) and (66), we can
confirm that the uncertainty relation in the thermal state varies in the same manner as in
the number state.
The uncertainty relation is always larger than ~=2 in both number and thermal states. We
determined density operators satisfying the Leouville–von Neumann equation and used it
to calculate various expectation values of the variables in the thermal state.
We applied our theory to a special case which is the forced Caldirola–Kanai oscillator.
The center of probability densities in number state shifted from zero point along the x-axis
ˆ
with time according to the magnitude of the driving force. Even if the mechanical energy
far from the resonance points in frequency gradually disappears with time, the mechanical
energy near the resonance points remained the same.
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