An Introduction To Iron: Applications
An Introduction To Iron: Applications
An Introduction to Iron
Written by AZoM Jul 30 2001
Iron (Fe) has been known since prehistoric times. It makes up 5% of the Earth's
crust and is second in abundance to aluminium among the metals and fourth in
abundance behind oxygen, silicon, and aluminium among the elements. It is also
found in the sun and many types of stars in considerable quantity. Iron is found
native only in the form of meteorites known as siderites. Its common ores are
magnetic pyrites, magnetite, hematite (Fe2O3) and carbonates or iron.
Iron is obtained from its ores by fusing to drive off the oxygen, sulphur, and impurities.
Melting is carried out generally in a blast furnace, directly in contact with the fuel and with
the limestone as a flux. These combine with the quartz and clay, forming a slag, which is
readily removed. The product is crude pig iron, and further remelting and refining
produces commercially pure iron.
Iron metal is greyish in appearance and is very ductile. Small amounts of carbon will
significantly alter the properties of iron. Iron containing 0.15% of chemically combined
carbon is termed ‘steel’. It is very reactive chemically (it is attacked by most acids),
corrodes readily which is accelerated by the presence of moist air or elevated
temperatures.
Iron in its pure state is allotropic, existing as a solid in two different crystal forms. These
forms and occurrence are outlined below:
From subzero to 700°C iron has a body centred cubic crystal structure, identified as
alpha (α) iron, and is magnetic
From 700°C to 928°C iron changes from alpha (α) iron to beta (β) iron, the crystal
structure remains unchanged but it loses its magnetism
From 928°C to 1530°C iron changes to a face centred cubic crystal structure
identified as gamma (γ) iron
From 1530°C upwards the structure changes back to body centred cubic crystal
structure, identified as delta (δ) iron
Common iron is a mixture of four isotopes, while ten other isotopes are known to exist.
Applications
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An Introduction to Iron
Iron in the metal form is used in:
As the primary constituent of ferrous metals/alloys and steels
When alloyed with carbon, nickel, chromium and various other elements, to form
cast iron or steel, it is the most versatile and popular metal used by mankind
Electronics
Manufacturing
Magnets
Heavy construction and building
Automotive
Fabricated metal products
Industrial machinery
Transportation equipment
Instruments
Toys, sport goods
Carbonyl iron (Fe(CO)5) powder used for magnet core for high frequency
equipment, medical applications
Ferrocene or dicyclopentadienyl iron ((C5H5)2Fe), is used as a combustion control
additive in fuels. It is also used as a heat stabiliser in lubricants and plastics and for
radiation resistance
Iron carbide is used in high wear applications, such as mine processing equipment
Iron shot, peening shot, steel grit, steelblast, trusteel shot, kutsteel, are used as a
replacement for sand in sand blasting operations tumbling operations and for metal
cleaning operations
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