PRO/II Application Briefs

R5 - FCC Main Fractionator

A fluidized catalytic cracker (FCC) operation is being expanded
and modified to increase gasoline production and eliminate
production of heavy cycle oil. You have to adapt an existing main
fractionator column for this new service. The flowsheet for the
column is shown in Figure R5-1.

Process Data
The new operation product slate for the 15,000 barrels/day design
basis charge is shown in Table R5-1 and Table R5-2. The column
feed is the FCC reactor effluent which is synthesized by blending
these product streams together with the 3000 lb/hr of reactor
stripping steam.

Figure R5-1: : Fractionator Column

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Table R5-1: Column Feed Rates (Gas Plant Products) (lb/hr)

 Stream 1A Stream 1B Steaam 1C

Component Off Gas C3’s & C4’s Gasoline
1 H2O 3000
2 H2 120
3 H2S 246
4 CO 317
5 N2 545
6 C1 3935
7 C2= 4218
8 C2 3290
9 C3= 2879 6364
10 C3 1047 2765
11 IC4= 161 2358 324
12 C4= 463 6658 560
13 IC4 586 7191 34
14 NC4 168 2521 451
15 C5= 1793
16 IC5 260 194 8755
17 NC5 104 25 1668
Total 18,336 28,706 13,585

Table R5-2: Assay Cut Temperatures (F) and Data

LV% Stream 1D Stream 1E Stream 1F

C6 plus (D86) Gasoline (D86) Light Cycle (TBP)
0 175 370 483
5 177 470 705
10 179 512 777
30 215 567 879
50 266 601 976
70 322 637 1080
90 441 694 1250
95 492 723 1391
100 537 745 1439
Barrels/hour 258.13 62.67 83.54
API Gravity 47.0 18.40 8.10

The simulation must satisfy the fractionation specifications shown

in Table R5-3 and the column pumparound conditions listed in
Table R5-4.

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Table R5-3: Fractionation Specification

Unit/Stream Property Value

Gasoline D86 End Point 450 F
Light Cycle Oil D86 End Point 740 F
Condenser Temperature 120 F
Pressure Drop 5 psi
Main Column Top pressure 20 psig
Pressure Drop 6 psi
Bottoms 680 F
Temperature 500 lb/hr
Sidestripper Steam feed 500 lb/hr
Steam (saturated) Steam feed 150 psig
Pressure

Table R5-4: Pumparound Information

Pumparound Duty (MM Btu/ Rate (bbl/day) Return Temp (F)

hr)
Top 20 - 225
Middle 10 - 450
Bottom - 1200 -

The main fractionator is sized for single pass valve trays on 24-inch
spacings at 75% of flood. The actual column contains 24 trays, not
counting the baffles in the quench zone.
The sidestripper has eight actual trays and is represented by two
trays for the simulation.

Methods and Data

The BK10 thermodynamic system is used for the K-values,
enthalpies, and vapor densities. This system works well for main
fractionators. The API correlation is used for the liquid viscosity
predictions.
In this simulation, we have a complete distillation profile for the
slurry oil. An accurate characterization of the slurry is important
because its bubble point (column bottom temperature) is normally
used as a control parameter. In operating units, slurry data are often
incomplete, and a shortcut model of the bottom section of the
column may be used to develop the slurry oil data.

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Simulation Model
The details of the simulation model are shown in Figure R5-2.

Figure R5-2: Simulation Model of Fractionation Column

Typical tray efficiencies are used to obtain the number of theoretical

trays from the actual trays. The number of trays used does not have
a critical effect on the simulation results. The quench zone is
represented by a single tray with a pumparound through a cooler.
A MIXED condenser is used, and the desired condensing
temperature is set as a performance specification. The condenser
duty is varied to meet this specification.
The gasoline draw rate is varied to meet the D86 end point
specification. Similarly, in the sidestripper, the cycle oil rate is
varied to meet the specified end point.

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The quench zone cooler duty is calculated to meet the slurry oil rate
specification. The return temperature for this pumparound is
computed from the desired circulation rate. The pumparound side
coolers have cooling duties set with the HEAT statement. The
return temperatures are given and the corresponding circulation
rates calculated.
It is good practice for this type of column to fix the duty of the top
side cooler and calculate the condenser duty. For columns with no
gasoline reflux, the top side cooler must be on the top tray and the
duty calculated to meet a performance specification. The overhead
condenser is then simulated as a separate flash drum.
The bottoms temperature is used as a control variable. Its value is
determined by small amounts of dissolved light material in the
slurry oil. An increased column reflux improves the separation and
produces a heavier slurry with a higher bubble point and, hence, a
higher column bottom temperature. Conversely, a lower reflux
reduces the bottom temperature.
The column is sized for single pass valve trays at 75 percent of
flood. This option automatically rates the column with all trays at
the largest calculated standard size.

Input Data
The program uses English units (default) for all the parameters
except for pressure (psig) and liquid volume units (API barrels). To
change the liquid volume units to US gallons, click the UOM
button on the toolbar and make the required changes.
Figure Figure R5-3 illustrates the data entry window used to specify
these units of measure.

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Figure R5-3: UOM Selection

Component Selection
Click Component to view the SIMSCI - Component Selection
dialog box. Select the components shown in Figure R5-4 (and in
Table R5-1) from the available databanks.

Figure R5-4: Component Selection

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Thermodynamic Methods Selection

Click Thermodynamics on the toolbar. Click Modify... to view
Thermodynamic Data - Modification dialog box and select Braun
K10 thermodynamic method for K values, enthalpy and vapor
density calculations. Use an API correlation for the liquid viscosity
predictions as shown in Figure R5-5.

Figure R5-5: Thermodynamic Data

Stream Composition Data Entry

All the products from the process are defined in the Stream Data
Section and then blended in the flash to obtain the column feed.
To enter data for the streams shown in Table R5-1, double-click a
stream to display the Stream Data dialog, then click the Flowrate
and Composition button to enter the details. See Figure R5-6 for an
example of component flow rate data entry for stream 1C. When
finished entering data for a stream click OK to save the data and exit
the DEW. Repeat for each sfeed stream.

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Figure R5-6: Stream 1C Flowrate and Composition

Stream Assay Data Entry

To enter the assay data listed in Table R5-2, double-click a stream
and select Petroleum Assay from the list box. Click on the Flowrate
and Assay to view Stream Data Flowrate and Assay dialog box.
Click Define/Edit Assay and enter the assay data in Stream Data -
Assay Definition dialog box. D2887 and gravity data are entered as
shown in Figure R5-7 on page 59. Click Molecular Weight and
Lightends and enter the relevant gravity and molecular weight data
given in Table R5-2.
Click OK to exit the data entry windows and return to the PFD. A
dialog box pops up to inform that the assay components have been
generated. Users may verify this by returning to the SIMSCI -
Components Selection dialog box (see Figure R5-4 that appeared
earlier).

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Figure R5-7: Assay Definition

Unit Operation Data Entry

Double-click the column unit operation to view the Column dialog
box. By default, the Inside-Out (IO) solution algorithm is used.
Figure R5-8: Column

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Click the Feeds and Products button to open the data entry window
illustrated in Figure R5-9.

Figure R5-9: Column Feed and Products

All the products from the up stream reactor process are defined in
the Stream Data Section and blended in a flash drum to obtain a
single combined column feed, stream 1, Reactor Eff. The only other
external feed is stream 5, utility steam.
to specify the vapor to be above feed tray and the liquid below feed
tray as shown
Click OK to save the data and exit the data entry window.
In the PRO/II - Column data entry window, click the Convergence
Data button to access the Column - Convergence data entry
window. Enter the damping factor as illustrated by Figure R5-10.

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Figure R5-10: Convergence Data

A value of DAMP=0.6 is recommended for FCC fractionators to

improve the convergence of the calculations. The DAMP option
also is available on key word input PARAMETER statement.
Click the Tray Hydraulics/Packing button and specify the column
trays operating at 82% of flood, with an 18-inch sieve tray spacing
as shown in Figure R5-11. The column is sized for single pass valve
trays at 75 percent of flood. This option automatically rates the
column with all trays at the largest calculated standard size.

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Figure R5-11: Tray Sizing

Return to the Column main window and click the Pumparounds

button to open the data entry window shown in Figure R5-12.
Figure R5-12: Pumparounds

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The return temperatures are given and the corresponding circulation
rates are calculated. The pump-around duties entered in this DEW
are entered on HEAT statements when using keyword input.
Click the Performance Specifications button to enter the
specifications and the variables for the column. The specifications,
condensing temperature, gasoline D86 end point, slurry oil
flowrate, and light cycle oil D86 are defined. The controlling
variables in order to meet the specifications are condenser duty,
gasoline draw rate, and the cooler duty. See Figure R5-13.

Figure R5-13: Specifications and Variables

Column Side-stripper Data Entry

The side-stripper is entered as a separate unit operation, but PRO/II
automatically combines it with the main column and solves both as
if they were a single unit operation. This eliminates external recycle
loops required to converge separate unit operations.
Lay down a side column from the PFD palette and specify two
theoretical trays for the side stripper. Double-click the side column
icon on the flowsheet to open the main data entry window shown in
Figure R5-14.
Enter data for:
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 Pressure Profile
 Feeds and Products

Figure R5-14: Sidestripper

The keyword listing that follows includes all the data necessary to
fully specify the side-stripper used in this example.

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Keyword Input File

TITLE PROJECT=APPBRIEF,PROBLEM=R5R,USER=SIMSCI
DIMEN PRES=PSIG,LIQV=BBL
PRINT INPUT=ALL, STREAM=SUMMARY, TBP
COMPONENT DATA
LIBID 1,H2O/2,H2/3,H2S/4,CO2/5,N2/6,C1 / 7,ETHENE/ &
8,C2 /9,PROPENE /10,C3/11,IBUTENE/12,BUT1/&
13,IC4/14,NC4 /15,PNT1 /16,IC5 /17,NC5, &
BANK = SIMSCI, PROCESS
CUTPOINT CUTSET=SIMSCI
ASSAY CURVEFIT = IMPROVED, CONVERSION = API94

THERMODYNAMIC DATA
METHODS SYSTEM=BK10, COND=PETR, SURF=PETR, &
VISC(V)=PETR, VISC(L)=API, SET=BK1001
STREAM DATA
PROP STREAM=1A, TEMP=980, PRES=35, PHASE=V, &
COMP(W)=1,3000/ 2, 120/ 3, 246/ 4, 317/ 5, 545/ &
6,3935/ 7,4218/ 8,3290/ 9,2876/10,1047/ &
11, 161/12, 463/13, 586/14, 168/16, 260/ &
17, 104
PROP STREAM=1B, TEMP=980, PRES=35, PHASE=V, &
COMP(W)= 9,6364 /10,2765/11,2358/12,6658/ &
13,7191 /14,2521/16, 194/17, 25
PROP STREAM=1C, TEMP=980, PRES=35, &
COMP(W)=11, 324./12, 560/13, 34/14, 451/ &
15,1793 /16,8755/17,1668
PROP STREAM=1D, TEMP=980, PRES=35, PHASE=V, &
RATE(V)=258.13, ASSAY=LV
D86 STREAM=1D, PRES(MMHG)=760, &
DATA= 0,175/ 5,177/ 10,179/ 30,215/ 50,266/&
70,322/ 90,441/ 95,492/100,537
API STREAM=1D, AVG=47
PROP STREAM=1E, TEMP=980, PRES=35, PHASE=V, &
RATE(V)=62.67, ASSAY=LV
D86 STREAM=1E, PRES(MMHG)=760, &
DATA= 0,370/ 5,470/10,512/ 30,567/ 50,601/ &
70,637/90,694/95,723/100,745
API STREAM=1E, AVG=18.4
PROP STREAM=1F, TEMP=980, PRES=35, PHASE=V, &
RATE(V)=83.54, ASSAY=LV
TBP STREAM=1F, PRES(MMHG)=760, &
DATA= 0, 483/ 5, 705/ 10, 777/ 30, 879/ &
50, 976/ 70,1080/ 90,1250/ 95,1391/100,1439
API STREAM=1F, AVG=8.1
PROP STREAM=S1, PRES=150, PHASE=V, & $ water

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RATE(W)=500, COMP=1,100
PROP STREAM=S2, PRES=150, PHASE=V, & $ water
RATE(W)=500, COMP=1,100
NAME S1,MF STEAM/ S2,STRP STEAM/ 1,REACTOR EFF/ &
2,OVERHEAD GAS/ 3,GASOLINE/ 4,OVHD WATER/ &
6,LCO DRAW / 7,LCO / 8,SLURRY OIL
UNIT OPERATIONS
FLASH UID=M1,NAME=FEED MIX
FEED 1A,1B,1C,1D,1E,1F
PRODUCT V=1
ISO TEMP=980, PRES=35
COLUMN UID=T1, NAME=MAIN FRAC
PARAM TRAY=14, DAMP=0.6
FEED 1,14/ S1,14/ 5,6
COND TYPE=MIXE,PRESS=15
PROD OVHD=2, LDRAW=3,1,615/ 6,8,134, &
WATER=4,1,110, BTMS=8,69
HEAT 1,1/2,14,-30/3,10,-10/4,3,-20
PA FROM=14,TO=14,PHASE=L,RATE(V)=500
PA FROM=11,TO=10,PHASE=L,TEMP=450
PA FROM=4,TO=3,PHASE=L,TEMP=225
PSPEC TOP=20,DPCOL=6
PRINT PROP=BRIE
ESTI MODEL=REFINE,REFLUX=500
SPEC COLUMN=T1, TRAY=1, PHASE=L, TEMP, VALUE=120
SPEC STREAM=8, RATE(V), VALUE=83
SPEC STREAM=3, D86(EP), VALUE=450
VARY HEAT=1,2,DRAW=3
TSIZ PASS=1,SPACING=24,FF=75
SIDESTRIPPER UID=T2,NAME=LCO STRP
PARAM TRAY=2
FEED 6,1/S2,2
PROD OVHD=5,BTMS=7,126
PSPEC TOP=23
SPEC STREAM=7,D86(EP),VALUE=740
VARY FEED=6
END

Results
The simulation solution confirms that the column can meet the new
service so long as the pumparound cooler duties shown on the
column summary are available.
The largest tray is the draw tray for the top pumparound at 126
inches diameter. If the existing column is less than this, then the
throughput must be reduced to avoid flooding in the top section.

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Output
Click Generate Report on the toolbar to generate a report for
the entire flowsheet. Alternately, from the Tools menu, select
Spreadsheet and you can generate reports for the unit operations
and streams. The column summaries for the main fractionator and
light cycle oil stripper are shown. The tray sizing results for the
main fractionator show the required diameter of each tray. The
column is rated with the largest required standard tray size, and the
output shows the flooding factor for each tray.
Selections of the stream summary output and the distillation curve
printout are shown.

FCC Fractionator Column Summary

Unit 2, 'T1', 'MAIN FRAC'
TOTAL NUMBER OF ITERATIONS
IN/OUT METHOD 11

COLUMN SUMMARY
---------- NET FLOW RATES ----------- HEATER
TRAY TEMP PRESSURE LIQUID VAPOR FEED PRODUCT DUTIES
DEG F PSIG LB-MOL/HR MM BTU/HR
------ ------- -------- -------- -------- --------- --------- ------------
1C 120.0 15.00 18.8 1520.9V -26.1607
669.2L
133.2W
2 334.5 20.00 5.8 2342.0
3 339.6 20.50 1462.0 2329.0 1095.1P -20.0000
4 403.4 21.00 431.8 2690.1 1095.1P
5 460.9 21.50 407.3 2755.0
6 482.8 22.00 356.0 2730.5 36.0V
7 498.1 22.50 280.8 2643.2
8 516.2 23.00 77.0 2568.0 98.7L
9 543.0 23.50 35.6 2462.9
10 555.0 24.00 474.1 2421.6 355.9P -10.0000
11 598.1 24.50 112.5 2504.1 355.9P
12 629.4 25.00 85.3 2498.4
13 640.9 25.50 36.8 2471.3
14R 655.7 26.00 2422.8 27.8V 407.1P -43.2437
2425.8M 67.6L
407.1P
SIDESTRIPPER T2
1/ 15 513.3 23.00 95.0 98.7L 36.0V
2/ 16 504.1 23.00 32.3 27.8V 90.5L

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Unit 2, 'T1', 'MAIN FRAC' (Continued)

FEED AND PRODUCT STREAMS
FROM TO LIQUID FLOW RATES HEAT RATES
TYPE STREAM PHASE TRAY TRAY FRAC LB-MOL/HR MM BTU/HR
----- ------------ ------ ---- ---- ------ ------------ ------------
FEED 5 VAPOR 6 0.0000 36.00 1.1357
FEED S1 VAPOR 14 0.0000 27.75 0.6005
FEED 1 MIXED 14 0.0006 2425.78 129.5575
PROD 2 VAPOR 1 1520.88 13.3118
PROD 3 LIQUID 1 669.16 2.9265
PROD 4 WATER 1 133.20 0.2110
PROD 6 LIQUID 8 98.72 5.8750
PROD 8 LIQUID 14 67.59 9.5639

SIDESTRIPPER T2
FROM TO LIQUID FLOW RATES HEAT RATES
TYPE STREAM PHASE TRAY TRAY FRAC LB-MOL/HR MM BTU/HR
----- ------------ ------ ---- ---- ------ ------------ ------------
FEED 6 LIQUID 15 1.0000 98.72 5.8750
FEED S2 VAPOR 16 0.0000 27.75 0.6005
PROD 5 VAPOR 15 36.00 1.1357
PROD 7 LIQUID 16 90.47 5.3401

OVERALL MOLE BALANCE, (FEEDS - PRODUCTS) -3.0289E-13

OVERALL HEAT BALANCE, (H(IN) - H(OUT) ) 8.9775E-04

PUMPAROUNDS

TRAY TEMP, DEG F LIQUID FRACTION ------------ RATES -------------

FROM TO FROM TO FROM TO LB-MOL/HR M LB/HR STD BBL/HR
---- ---- ------- ------- ------- ------- ---------- ---------- ----------
14 14 655.7 226.4 1.0000 1.0000 407.14 177.423 500.00
11 10 598.1 450.0 1.0000 1.0000 355.90 107.690 318.86
4 3 403.4 225.0 1.0000 1.0000 1095.13 201.302 651.25

SPECIFICATIONS

SPECIFICATION PARAMETER TRAY COMP SPECIFICATION SPECIFIED CALCULATED

NUMBER TYPE NO NO TYPE VALUE VALUE
------------- --------- ---- ------ ------------- ---------- ----------
1 (ACTIVE) TRAY LIQ 1 TEMPERATURE 1.200E+02 1.200E+02
2 (ACTIVE) STRM 8 14 LV RATE 8.300E+01 8.300E+01
3 (ACTIVE) STRM 3 1 D86 EP 4.500E+02 4.500E+02
4 (ACTIVE) STRM 7 16 D86 EP 7.400E+02 7.400E+02

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Unit 2, 'T1', 'MAIN FRAC' (Continued)

REFLUX RATIOS -------- REFLUX RATIOS --------
MOLAR WEIGHT STD L VOL
--------- --------- ---------
REFLUX / FEED STREAM 1 0.0077 0.0099 0.0088
REFLUX / VAPOR DISTILLATE 0.0124 0.0308 0.0200
REFLUX / DECANTED LIQ. DISTILLATE 0.0281 0.0281 0.0281
REFLUX / TOTAL LIQUID DISTILLATE 0.0234 0.0271 0.0274
REFLUX / TOTAL DISTILLATE 0.0081 0.0144 0.0116

Tray Sizing Mechanical Data

SECTION TRAY TRAY TRAY SPACING SYSTEM TRAY MIN DIAMETER
NUMBERS PASSES IN FACTOR TYPE IN
------- --------- ------ ------------ ------ ----- ------------
1 2 - 13 1 24.00 1.00 VALVE 15.00

Tray Sizing Results

TRAY VAPOR LIQUID VLOAD -- DESIGN -- NEXT SMALLER NEXT LARGER NP
CFS HOTGPM CFS DIA, IN FF DIA, IN FF DIA, IN FF
---- ----- ------ ----- ------- ---- ------- ---- ------- ---- --
2 150.6 11.1 11.06 79.7 75.0 78. 74.1 84. 67.1 1
3 189.2 869.7 14.86 114.1 75.0 114. 75.2 120. 68.8 1
4 206.6 977.8 16.98 122.9 75.0 120. 78.1 126. 71.9 1
5 206.7 271.7 17.12 104.4 75.0 102. 78.2 108. 70.1 1
6 203.3 252.1 16.68 102.8 75.0 102. 75.7 108. 67.9 1
7 194.8 203.0 15.50 98.2 75.0 96. 77.5 102. 69.5 1
8 187.3 114.3 13.74 90.9 75.0 90. 74.4 96. 67.0 1
9 184.0 16.8 13.04 86.6 75.0 84. 75.5 90. 69.2 1
10 195.9 389.8 14.23 99.2 75.0 96. 79.8 102. 71.3 1
11 199.4 403.1 14.58 100.7 75.0 96. 81.8 102. 73.2 1
12 196.8 60.0 14.26 91.4 75.0 90. 74.2 96. 67.8 1
13 193.2 25.1 13.53 88.4 75.0 84. 78.8 90. 72.2 1

Tray Sizing Downcomer Width Calculation

NEXT LARGER ------- DOWNCOMER WIDTHS --------
TRAY DIAMETER SIDE CENTER OFF-CENTER
IN IN IN IN
---- ----------- ------- ------- ----------
2 84. 5.300 N/A N/A
3 120. 15.517 N/A N/A
4 126. 16.067 N/A N/A
5 108. 7.243 N/A N/A
6 108. 7.076 N/A N/A
7 102. 6.765 N/A N/A
8 96. 6.156 N/A N/A
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9 90. 5.795 N/A N/A
10 102. 9.206 N/A N/A
11 102. 9.230 N/A N/A
12 96. 6.145 N/A N/A
13 90. 5.965 N/A N/A

Tray Selection for Tray Rating

VALVE DIAMETER 1.875 IN

DESIGN NUMBER ----- DOWNCOMER WIDTHS -------

SECTION TRAY DIAMETER NP OF VALVES SIDE CENTER OFF-CENTER
NUMBER IN OR CAPS IN IN IN
------- ------ -------- -- --------- ------ ------- ----------
1 4 126. 1 884 16.067 N/A N/A

Tray Rating at Selected Design Tray

PRES DOWNCOMER
TRAY VAPOR LIQUID VLOAD DIAM FF NP DROP GPM/LWI BACKUP, PCT
CFS HOTGPM CFS IN PSI GPM/IN TRAY SPACING
---- ----- ------ ----- ---- ---- -- ------ ------- ------------
2 150.6 11.1 11.06 126. 33.2 1 0.053 0.1 17.14
3 189.2 869.7 14.86 126. 63.2 1 0.120 10.3 48.54
4 206.6 977.8 16.98 126. 71.9 1 0.136 11.6 55.69
5 206.7 271.7 17.12 126. 57.0 1 0.106 3.2 30.41
6 203.3 252.1 16.68 126. 55.3 1 0.102 3.0 29.37
7 194.8 203.0 15.50 126. 50.7 1 0.092 2.4 26.73
8 187.3 114.3 13.74 126. 43.5 1 0.078 1.4 22.53
9 184.0 16.8 13.04 126. 39.3 1 0.066 0.2 18.69
10 195.9 389.8 14.23 126. 50.9 1 0.102 4.6 30.64
11 199.4 403.1 14.58 126. 52.2 1 0.104 4.8 31.39
12 196.8 60.0 14.26 126. 43.8 1 0.078 0.7 21.43
13 193.2 25.1 13.53 126. 40.9 1 0.070 0.3 19.50

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Product Stream Summary

STREAM ID 2 3 7 8
NAME OVERHEAD GAS GASOLINE LCO SLURRY OIL
PHASE WET VAPOR WET LIQUID WET LIQUID WET LIQUID
THERMO ID BK1001 BK1001 BK1001 BK1001
----- TOTAL STREAM -----
RATE, LB-MOL/HR 1520.735 669.565 90.882 67.607
M LB/HR 62.893 69.094 22.187 29.453
TEMPERATURE, F 120.000 120.000 504.520 655.711
PRESSURE, PSIG 15.000 15.000 23.000 26.000
MOLECULAR WEIGHT 41.357 103.192 244.130 435.646
ENTHALPY, MM BTU/HR 13.310 2.927 5.350 9.564
BTU/LB 211.626 42.367 22.187 29.453
MOLE FRACTION LIQUID 0.00000 1.00000 1.00000 1.00000
MOLE FRACTION FREE WATER 0.00000 0.00000 0.00000 0.00000
----- TOTAL VAPOR ------
RATE, LB-MOL/HR 1520.735 N/A N/A N/A
M LB/HR 62.893 N/A N/A N/A
M FT3/HR 318.499 N/A N/A N/A
STD VAP RATE(1), M FT3/HR 577.094 N/A N/A N/A
MOLECULAR WEIGHT 41.357 N/A N/A N/A
ENTHALPY, BTU/LB 211.626 N/A N/A N/A
CP, BTU/LB-F 0.419 N/A N/A N/A
DENSITY, LB/M FT3 197.466 N/A N/A N/A
Z (FROM DENSITY) 0.9998 N/A N/A N/A
THERMAL COND, BTU/HR-FT-F 0.01356 N/A N/A N/A
VISCOSITY, CP 0.00969 N/A N/A N/A
KINEMATIC VISCOSITY, CSTOK 3.0634 N/A N/A N/A
----- TOTAL LIQUID -----
RATE, LB-MOL/HR N/A 669.565 90.882 67.607
M LB/HR N/A 69.094 22.187 29.453
BBL/HR N/A 267.225 81.564 102.293
GAL/MIN N/A 187.057 57.094 71.605
STD LIQ RATE, BBL/HR N/A 257.596 67.601 83.002
MOLECULAR WEIGHT N/A 103.192 244.130 435.646
ENTHALPY, BTU/LB N/A 42.367 241.143 324.733
CP, BTU/LB-F N/A 0.491 0.629 0.672
DENSITY, LB/BBL N/A 258.561 272.020 287.927
Z (FROM DENSITY) N/A 0.0107 0.0184 0.0289
SURFACE TENSION, DYNE/CM N/A 20.8697 16.8006 17.1344
TH COND, BTU/HR-FT-F N/A 0.06902 0.04524 0.03860
VISCOSITY, CP N/A 0.38629 0.33356 0.60125
KINEMATIC VISCOSITY, CSTOK N/A 0.5237 0.4298 0.7319

(1) STANDARD VAPOR VOLUME IS 379.49 FT3/LB-MOLE (60 F AND 14.696 PSIA)

R5 - FCC Main Fractionator Refining 2-71

 PRO/II Application Briefs

Product Stream Summary (Continued)

STREAM ID 2 3 7 8
NAME OVERHEAD GAS GASOLINE LCO SLURRY OIL
PHASE WET VAPOR WET LIQUID WET LIQUID WET LIQUID
THERMO ID BK1001 BK1001 BK1001 BK1001

------ DRY STREAM ------

RATE, LB-MOL/HR 1434.507 667.940 89.299 67.511
M LB/HR 61.340 69.065 22.158 29.451
STD LIQ RATE, BBL/HR 357.305 257.512 67.519 82.997
MOLECULAR WEIGHT 42.760 103.400 248.136 436.240
MOLE FRACTION LIQUID 0.0000 1.0000 1.0000 1.0000
REDUCED TEMP (KAYS RULE) 0.9517 0.5741 0.6599 0.6486
PRES (KAYS RULE) 0.0488 0.0628 0.1274 0.1870
ACENTRIC FACTOR 0.1198 0.2876 0.6323 1.0147
WATSON K (UOPK) 14.991 11.589 10.992 11.125
STD LIQ DENSITY, LB/BBL 171.673 268.201 328.179 354.846
SPECIFIC GRAVITY 0.4903 0.7659 0.9372 1.0134
API GRAVITY 157.118 53.242 19.478 8.132

------ DRY VAPOR -------

RATE, LB-MOL/HR 1434.507 N/A N/A N/A
M LB/HR 61.340 N/A N/A N/A
M FT3/HR 300.503 N/A N/A N/A
STD VAP RATE(1), M FT3/HR 544.372 N/A N/A N/A
SPECIFIC GRAVITY (AIR=1.0) 1.476 N/A N/A N/A
MOLECULAR WEIGHT 42.760 N/A N/A N/A
CP, BTU/LB-F 0.418 N/A N/A N/A
DENSITY, LB/M FT3 204.122 N/A N/A N/A
THERMAL COND, BTU/HR-FT-F 0.01362 N/A N/A N/A
VISCOSITY, CP 0.00968 N/A N/A N/A
KINEMATIC VISCOSITY, CSTOK 2.9592 N/A N/A N/A

------ DRY LIQUID ------

RATE, LB-MOL/HR N/A 667.940 89.299 67.511
M LB/HR N/A 69.065 22.158 29.451
BBL/HR N/A 267.141 81.459 102.284
GAL/MIN N/A 186.998 57.021 71.599
STD LIQ RATE, BBL/HR N/A 257.512 67.519 82.997
SPECIFIC GRAVITY (H2O=1.0) N/A 0.7659 0.9372 1.0134
MOLECULAR WEIGHT N/A 103.400 248.136 436.240
CP, BTU/LB-F N/A 0.491 0.629 0.672
DENSITY, LB/BBL N/A 258.534 272.018 287.934
SURFACE TENSION, DYNE/CM N/A 20.7545 16.6911 17.1525
THERMAL COND, BTU/HR-FT-F N/A 0.06901 0.04522 0.03860
VISCOSITY, CP N/A 0.38593 0.33937 0.60251
KINEMATIC VISCOSITY, CSTOK N/A 0.5232 0.4373 0.7334

2-72 Refining R5 - FCC Main Fractionator

 PRO/II Application Briefs

Product Distillation Curves

STREAM ID 3 7 8
NAME GASOLINE LCO SLURRY OIL
PHASE WET LIQUID WET LIQUID WET LIQUID
TBP AT 760 MM HG
1 LV PERCENT -57.196 421.660 341.684
5 18.092 527.165 673.229
10 67.262 550.713 780.058
30 174.671 597.460 881.008
50 258.881 634.710 978.579
70 327.686 668.434 1074.691
90 413.043 737.485 1253.552
95 485.479 773.344 1379.464
98 525.718 801.266 1426.748
TBP AT 10 MM HG
1 LV PERCENT -174.188 195.018 130.947
5 -118.363 281.105 403.321
10 -81.472 300.567 495.019
30 0.332 339.475 583.534
50 65.659 370.742 670.860
70 119.836 399.251 758.636
90 188.066 458.237 926.815
95 246.876 489.198 1049.141
98 279.912 513.463 1095.950
ASTM D86 AT 760 MM HG
1 LV PERCENT -4.172 433.905 -232.605
5 70.579 545.659 545.436
10 119.398 570.601 796.131
30 193.784 593.892 864.349
50 257.331 616.840 940.728
70 313.530 640.394 1025.204
90 396.339 702.929 1245.817
95 430.836 723.771 1297.919
98 450.000 740.000 1317.485
ASTM D86 AT 760 MM HG WITH CRACKING
1 LV PERCENT -4.172 433.905 -232.605
5 70.579 536.712 536.509
10 119.398 559.174 725.892
30 193.784 579.615 761.181
50 257.331 599.170 793.748
70 313.530 618.576 823.030
90 396.339 666.250 877.548
95 430.836 680.791 887.836
98 450.000 691.646 891.726

R5 - FCC Main Fractionator Refining 2-73

 PRO/II Application Briefs

Product Distillation Curves

STREAM ID 3 7 8
NAME GASOLINE LCO SLURRY OIL
PHASE WET LIQUID WET LIQUID WET LIQUID
ASTM D1160 AT 760 MM HG
1 LV PERCENT 7.101 447.006 99.052
5 55.340 543.954 628.734
10 86.978 565.614 795.186
30 184.900 604.337 888.470
50 258.881 634.710 978.579
70 327.686 668.434 1074.691
90 413.043 737.485 1253.552
95 485.479 773.344 1379.464
98 525.718 801.266 1426.748
ASTM D1160 AT 10 MM HG
1 LV PERCENT -126.563 215.535 -57.436
5 -90.448 294.971 365.710
10 -66.582 312.929 508.168
30 8.210 345.229 590.150
50 65.659 370.742 670.860
70 119.836 399.251 758.636
90 188.066 458.237 926.815
95 246.876 489.198 1049.141
98 279.912 513.463 1095.950
ASTM D2887 AT 760 MM HG
1 WT PERCENT -47.597 346.283 416.494
5 37.381 494.856 712.879
10 92.879 528.016 808.378
30 182.619 587.527 895.412
50 258.881 634.710 978.579
70 324.534 674.125 1061.972
90 400.413 738.536 1196.385
95 540.041 800.897 1459.553
98 570.226 825.979 1492.310
TBP AT 760 MM HG
1 WT PERCENT -45.906 440.705 470.072
5 26.905 529.730 688.346
10 84.859 552.411 788.132
30 193.894 599.031 887.722
50 275.921 636.591 989.236
70 332.718 669.785 1080.201
90 433.443 740.293 1275.403
95 494.917 774.730 1386.136
98 530.516 802.592 1426.748

2-74 Refining R5 - FCC Main Fractionator