This document defines key terms related to carbohydrate structure and function, including: monosaccharides like triose, tetrose, aldoses and ketoses; D and L sugars; epimers and anomers; the anomeric carbon and cyclization; alpha and beta anomers; mutarotation; common monosaccharides like glucose, fructose, galactose and mannose; glycoside formation; common disaccharides like sucrose, lactose and maltose; and the three main polysaccharides - cellulose, starches and glycogen - and their functions.
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Carbohydrate Structure and Function Flashcards
This document defines key terms related to carbohydrate structure and function, including: monosaccharides like triose, tetrose, aldoses and ketoses; D and L sugars; epimers and anomers; the anomeric carbon and cyclization; alpha and beta anomers; mutarotation; common monosaccharides like glucose, fructose, galactose and mannose; glycoside formation; common disaccharides like sucrose, lactose and maltose; and the three main polysaccharides - cellulose, starches and glycogen - and their functions.
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Biochemistry – Carbohydrate Structure and Function
What is a 3-carbon sugar called?
Triose Biochemistry – Carbohydrate Structure and Function What is a 4-carbon sugar called? Tetrose Biochemistry – Carbohydrate Structure and Function What is a sugar with an aldehyde group called? Aldoses Biochemistry – Carbohydrate Structure and Function What is a sugar with a ketone group called? Ketose Biochemistry – Carbohydrate Structure and Function What is the difference between D sugars and L sugars? They are enantiomers from each other; in a fishcer projection, more OH on the right is a D-sugar, more OH on the left is a L- sugar Biochemistry – Carbohydrate Structure and Function What is an epimer? Type of diastereomer where exactly one chiral carbon differs Biochemistry – Carbohydrate Structure and Function What is an anomer? Type of epimer that differ at the anomeric carbon Biochemistry – Carbohydrate Structure and Function What is the anomeric Carbon? What does it contain in straight-chain form? The chiral center formed from the ring closure; the carbon containing carbonyl in the straight-chain form Biochemistry – Carbohydrate Structure and Function What is cyclization? The ring formation of carbohydrates from their straight-chain forms Biochemistry – Carbohydrate Structure and Function What is the different between the α-anomer or β-anomer conformation? α-anomer: β-anomer:
The –OH on the anomeric The –OH on the anomeric
carbon is trans to the free – carbon is cis to the free – CH2OH group CH2OH group Biochemistry – Carbohydrate Structure and Function What occurs during mutarotation? One anomeric form shifts to another, with the straight-chain form as the intermediate Biochemistry – Carbohydrate Structure and Function What is the name of the carbohydrate below? D-Fructose Biochemistry – Carbohydrate Structure and Function What is the name of the carbohydrate below? D-Glucose Biochemistry – Carbohydrate Structure and Function What is the name of the carbohydrate below? D-Galactose Biochemistry – Carbohydrate Structure and Function What is the name of the carbohydrate below? D-Mannose Biochemistry – Carbohydrate Structure and Function What are monosaccharides? Single carbohydrate units Biochemistry – Carbohydrate Structure and Function What are the three main reactions monosaccharides can undergo? Oxidation/reduction, esterification, and glycoside formation Biochemistry – Carbohydrate Structure and Function What is glycoside formation? The basis for building complex carbohydrates and requires the anomeric carbon to link to another sugar Biochemistry – Carbohydrate Structure and Function What are common disaccharides? Sucrose (glucose-α-1,2-fuctose), lactose (galactose-β- 1,4,glucose), and maltose (glucose-α-1,4-glucose) Biochemistry – Carbohydrate Structure and Function What are the three polysaccharides and their function? Cellulose – main structural component of plant cell walls; main source of fiber in the human diet Starches (amylase and amylopectin) – main energy storage forms for plants Glycogen – a major energy storage form for animals