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Thermo Hidro K5 New

The document describes several equations of state (EOS) used to model the thermodynamic behavior of gases and liquids, including ideal gas, van der Waals, Redlich-Kwong, Peng-Robinson, and Benedict-Webb-Rubbin. Each EOS relates pressure, volume, temperature, and other properties using constants fitted for different substances. The EOS can be expressed in terms of the compressibility factor Z and used to calculate other thermodynamic properties.

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Alia Damar A
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54 views

Thermo Hidro K5 New

The document describes several equations of state (EOS) used to model the thermodynamic behavior of gases and liquids, including ideal gas, van der Waals, Redlich-Kwong, Peng-Robinson, and Benedict-Webb-Rubbin. Each EOS relates pressure, volume, temperature, and other properties using constants fitted for different substances. The EOS can be expressed in terms of the compressibility factor Z and used to calculate other thermodynamic properties.

Uploaded by

Alia Damar A
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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EQUATIONS OF STATE

Ideal Gas

(Only valid for gas at low pressure conditions)

Pv  RT

Van der Waals

 a
or  P  2 v  b   RT
RT a
P  2
v b v  v 

Relation with Z = compressibility factor:

Pv b a
Z  1 
RT v  b RTv

27 R 2Tc2 RTc
a and b
64 Pc 8Pc

For mixtures:

a   xi ai and b   xibi
Van der Waals EOS, in term of Z:

Z 3  B  1Z 2  AZ  AB  0

bP aP
B and A
with RT RT 2

Redlich-Kwong

RT a
P  0.5
v  b T vv  b 

Relation with Z = compressibility factor:

Pv 1  a / R 2T 2.5  b / v
Z    
RT 1  b / v  b / RT  1  b / v

0.4278R 2Tc2.5 0.0867 RTc


a and b
Pc Pc

For mixtures:

a   xi ai and b   xibi
Redlich-Kwong EOS, in term of Z:

 
Z 3  Z 2  A  B 2  B Z  AB  0

bP aP
B and A
with RT RT 2

Peng-Robinson

RT aT 
P 
v  b vv  b   bv  b 

Relation with Z = compressibility factor:

Pv 1 aT 
Z  
RT 1  b / v v  b   b1  b / v RT

0.45724 R 2Tc2
aT    T 
0.0778RTc
and b
Pc Pc

 
 T 1 / 2  1  0.37464  1.54226  0.26992 2 1 
T 
Tc 
 
For mixtures:

a   xi ai and b   xibi

Peng-Robinson EOS, in term of Z:

  
Z 3  B  1Z 2  A  3B2  2B Z  B2  B3  AB  0 

bP aP
B and A
with RT RT 2

Benedict-Webb-Rubbin (BWR)

3 1  d
 Co  2
 
2
P  RTd   Bo RT  Ao  2 d  bRT  a d  ad  cd
3 6
exp  d 2
 T  2
T

Relation with Z = compressibility factor:

 2 a 5 2 1  d
Pv  C  
 
2
A a
Z   Bo  o  o 2 d   b  d  d  cd exp  d 2
RT  RT RT   RT  RT RT 3

where
1
d ; Bo, Ao, Co, b, a, c, ,  are emphirical constants
v

for each substances.

For mixtures, use appropriate mixing rules such as:

Bo   xi Boi b  x b  
i i
1/ 3 3
  x   
i i
1/ 3 3
Calculations of other properties from EOS
Assignment

1)Use NIST software to calculate Z for Natural Gas as examples’ conditions

(pseudocritical method). Compare with these two methods and PR-EOS

method.

2)Use NIST software, and PR-EOS method to calculate density of LNG as

an example above. Discuss the results !

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