Beer Information
Beer Information
History Of Brewing
Before 6000 BCE, beer was made from barley
in Sumer and Babylonia. Reliefs on Egyptian tombs dating
from 2400 BCE show that barley or partly germinated barley
was crushed, mixed with water, and dried into cakes. When
broken up and mixed with water, the cakes gave an extract
that was fermented by microorganisms accumulated on the
surfaces of fermenting vessels.
Types Of Beer
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In Europe the properties of the water used for brewing, the
types of malt, the brewing practices, and the yeast strains
have contributed to traditional distinctions between beers.
Early British beers were made from successive extracts of a
single batch of brown malt in a top-fermentation process. The
first and strongest extract gave the best-quality beer,
called strong beer, and a third extract yielded the poorest-
quality beer, called small beer. In the 18th century, London
brewers departed from this practice and produced porter.
Made from a mixture of malt extracts, porter was a strong,
dark-coloured, highly hopped beer consumed by the market
porters in London. Brewers in Burton upon Trent, using the
famous hard waters of that region and pale malts roasted in
coke-fired kilns, created pale ales, also called best bitter. Pale
ale is less strong, less bitter, paler in colour, and clearer than
porter. Mild ales—weaker, darker, and sweeter than bitter—
are a common variation; more colour is obtained by special
malts, roasted barley, or caramels, less hops are used, and
cane sugar is added to impart sweetness and aid
maturation. Stouts are stronger versions of mild ale; some,
such as milk stouts, contain lactose (milk sugar) as a
sweetener. Beers with alcohol content well in excess of 5
percent are produced in the United Kingdom (barley
wines), Belgium, and the Netherlands (for example, Trappist
beers).
Malting
Malting modifies barley to green malt, which can then be
preserved by drying. The process involves steeping and
aerating the barley, allowing it to germinate, and drying and
curing the malt.
Steeping
Malting begins by immersing barley, harvested at less than 12
percent moisture, in water at 12 to 15 °C (55 to 60 °F) for 40
to 50 hours. During this steeping period, the barley may be
drained and given air rests, or the steep may be forcibly
aerated. As the grain imbibes water, its volume increases by
about 25 percent, and its moisture content reaches about 45
percent. A white root sheath, called a chit, breaks through the
husk, and the chitted barley is then removed from the steep
for germination.
Germination
Activated by water and oxygen, the root embryo of the
barleycorn secretes a plant hormone called gibberellic acid,
which initiates the synthesis of α-amylase. The α- and β-
amylases then convert the starch molecules of the corn into
sugars that the embryo can use as food. Other enzymes, such
as the proteases and β-glucanases, attack the cell walls
around the starch grains, converting insoluble proteins and
complex sugars (called glucans) into soluble amino acids and
glucose. These enzymatic reactions are called modification.
The more germination proceeds, the greater the modification.
Overmodification leads to malting loss, in which rootlet growth
and plant respiration reduce the weight of the grain.
Kilning
Green malt is dried to remove most of the moisture, leaving 5
percent in lager and 2 percent in traditional ale malts. This
process arrests enzyme activity but leaves 40 to 60 percent in
an active state. Curing at higher temperatures promotes a
reaction between amino acids and sugars to form
melanoidins, which give both colour and flavour to malt.
Modernization
Mashing
After kilning, the malt is mixed with water at 62 to 72 °C (144
to 162 °F), and the enzymatic conversion of starch into
fermentable sugar is completed. The aqueous extract (wort) is
then separated from the residual “spent” grain.
Milling
For efficient extraction with water, malt must be milled. Early
milling processes used stones driven manually or by water or
animal power, but modern brewing uses mechanically driven
roller mills. The design of the mill and the gap between the
rolls are important in obtaining the correct reduction in size of
the malt. The object is to retain the husk relatively intact while
breaking up the brittle, modified starch into particles.
Mixing the mashThe milled malt, called grist, is mixed with wat
er, providing conditions in which starch, other molecules, and
enzymes are dissolved and rapid enzyme action takes place.
The solute-rich liquid produced in mashing is called the wort.
Traditionally, mashing may be one of two distinct types. The si
mplest process, infusion mashing, uses a well-modified malt, t
wo to three volumes of water per volume of grist, a single ves
sel (called a mash tun), and a single temperature in the range
of 62 to 67 °C (144 to 153 °F). With well-modified malt, breakd
own of proteins and glucans has already occurred at the malti
ng stage, and at 65 °C (149 °F) the starch readily gelatinizes a
nd the amylases become very active. Less-well-modified malt,
however, benefits from a period of mashing at lower temperat
ures to permit the breakdown of proteins and glucans. This re
quires some form of temperature programming, which is achie
ved by decoction mashing. After grist is mashed in at 35 to 40
°C (95 to 105 °F), a proportion is removed, boiled, and added
back. Mashing with two or three of these decoctions raises the
temperature in stages to 65 °C (149 °F). The decoction proces
s, traditional in lager brewing, uses four to six volumes of wate
r per volume of grist and requires a second vessel called the
mash cooker.
Boiling
After separation, the wort is transferred to a vessel called the
kettle or copper for boiling, which is necessary to arrest
enzyme activity and to obtain the bitterness value of added
hops.
Hops
Several varieties of the hop (Humulus lupulus) are selected
and bred for the bitter and aromatic qualities that they lend to
brewing. The female flowers, or cones, produce tiny glands
that contain the chemicals of value in brewing. Humulones are
the chemical constituents extracted during wort boiling. One
fraction of these, the α-acids, is isomerized by heat to form the
related iso-α-acids, which are responsible for the
characteristic bitter flavour of beer.
Fermentation
In this most important stage of the brewing process, the
simple sugars in wort are converted to alcohol and carbon
dioxide, and green (young) beer is produced. Fermentation is
carried out by yeast, which is added, or pitched, to the wort at
0.3 kilogram per hectolitre (about 0.4 ounce per gallon),
yielding 10,000,000 cells per millilitre of wort.
Yeast
Yeasts are classified as fungi; those strains used for fermentat
ion are of the genus Saccharomyces (meaning “sugar fungus”
). In brewing it is traditional to refer to ale yeasts used predomi
nantly in top fermentation as top strains of S. cerevisiae and t
o lager yeasts as bottom strains of S. carlsbergensis. Modern
yeast systematics, however, classifies all brewing strains as S
. cerevisiae, and many ales are made by bottom fermentation
with what were originally top strains.
Many hundreds of simple organic compounds have been
characterized in beer and many more identified, and the
majority of these are produced by yeast. The bitter
substances of hops, ethyl alcohol, and carbon dioxide have
the greatest effects on the senses of taste and smell. Other
compounds giving a beer its character include: esters such as
isoamyl acetate (banana), ethyl hexanoate (apple), and ethyl
acetate (solvent); higher alcohols such as isoamyl alcohol and
2-phenyl ethanol; acids such as octanoic, acetic, isovaleric,
butyric malic, and citric; dialkyl sulfides such as dimethyl
sulfide; and diketones such as diacetyl. The ester ethyl
isovalerate and the aldehyde nonenal contribute to stale and
oxidized flavours. The mechanisms of metabolism leading to
the formation of these flavouring agents are neither well
understood nor easily changed. Until new processes (perhaps
genetic engineering) can produce changes in brewer’s yeast,
brewers will attach great value to known yeast strains and will
maintain selected strains for brewing particular beers.
Fermenting methods
Brewing is unique among the beverage fermentation
industries in that yeast from one fermentation is used to pitch
the next. This means that hygienic conditions and rigorous
quality control are necessary. A high proportion of live cells
and freedom from bacteria and other yeasts are important
quality considerations.
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