Sepro 1 Appendix PDF
Sepro 1 Appendix PDF
1
Fundamental Constants
and Conversion Factors
A.1-3 Length
1 in. 2.540 em
100 em = 1 m (meter)
850
1 micron = 10 - (, m = 10 - 4 cm 10 -:; mm 1 pm (micrometer)
1 A (angstrom) = 10 10 m 10- 4 Ilm
1 mile = 5280 ft
1 m 3.2808 ft = 39.37 in.
A.l-4 Mass
1 Ibm 453.59 g = 0.45359 kg
1 Jb m = 16 oz = 7000 grains
1 kg 1000 g = 2.2046 Ibm
1 ton (short) 2000 Ibm
1 ton (long) = 2240 Ibm
1 ton (metric) = 1000 kg
A.1-6 Volume
1 L (liter) 1000 cm:> 1 m:; = 1000 L (liter)
1 in.:; 16.387 em 3 I U.S. gal 4 qt
1 ft 3 = 28.317 L (liter) I U.S. gal = 3.7854 L (liter)
1 ft 3 = 0.028317 m 3 1 U.S. gal = 3785.4 cm 3
1 ft3 7.481 U.S. gal 1 British gal 1.20094 U.S. gal
1 m 3 = 264.17 U.S. gal 1 m3 35.313 ft 3
A.1-7 Force
1 g' cm/s2 (dyn) 10- 5 kg· m/s 2 = 10- 5 N (newton)
1 g' cm/s 2 7.2330 x 10- 5 Ibm' ft/S2 (poundal)
1 kg· m/5 2 = 1 N (newton)
1 Ib r = 4.4482 N
1g' cm/s2 = 2.2481 x 10- (,lb r
A.l-8 Pressure
1 bar = 1 x 10 5 Pa (pascal) 1 x 10 5 N/m2
2
1 psia = 1Ibr/in.
1 psia = 2.0360 in. Hg at ooe
1 psia 2.311 ft H 2 0 at 70°F
I psia = 51.715 mm Hg at ooe (PHs = 13.5955 gjcm 3 )
1 atm = 14.696 psia = 1.01325 x 10 5 N/m 2 = 1.01325 bar
1 atm 760 mm Hg at O°C 1.01325 x 10 5 Pa
I atm = 29.921 in. Hg at ooe
1 atm = 33.90 ft H 2 0 at 4°C
AppenduA.l 851
1 psia = 6.89476 x 104 g/cm' S2
1 psia 6.89476 x dyn/cm2
1 dyn/cm2 2.0886 x 10- 3 Ibrlft2
1 psia = 6.89476 x 10 3 Nlm 2 6.89476 x 10 3 Pa
2
1 Ibr/ft = 4.7880 x 102 dyn/cm2 = 47.880
1 mm Hg (O°C) 1.333224 x 10 2 N/m2 = 0.1333224 kPa
A.l-9 Power
1 hp = 0.74570 kW 1 watt (W) 14.340 cal/min
1 hp = 550 ft ·Ibr/s I btu/h = 0.29307 W (watt)
I hp 0.7068 btu/s I J/s (joule/s) 1W
A.1-13 Viscosity
I cp 10 2 g/cm . s (poise)
1 cp = 2.4191Ib.Jft· h
1 cp = 6.7197 x 1O- 4 Ib;;jft's
lcp 1O- 3 Pa's=10 3kg/m's=1O- 3 N's/m 2
1 cp = 2.0886 x 10- 'lb e ' S/ft2
1 Pa' s = 1 N· s1m 2 = 1 kg/m· s 1000 cp 0.67197 Ib m lft· S
23.75 44 020 kJ/kg mol, 10.514 kcal/g mol, 18925 btu/lb mol
760 44 045 kJ/kg mol, 10.520 kcaljg mol, 18936 btuflb mol
854
A.2-3 Density of Water
Source: R. H. Perry and C. H. Chilton, Chemical Engineers' Handbook, 5th ed. New York:
McGraw-Hill Book Company, 1973. With permission.
ViscosilY ViscosilY
TemperalUre [(Pa· s) 10 3 , T emperalllre [(Pa· s) J03,
(kg/m's) 10J, (kg/m s) 10 3 ,
K "C or cp] K cC or cp]
Source: N. S. Osborne, H. F. Stimson, and D. C. Ginnings, Bur. SWlldards J. Res., 23, 197
(1939).
Heat of
Temperature VapoT Pressure Sublimation
Temperawre cp Temperature cp
of K bill/Ibm' F
0 kJ/kg' K of K btu/Ibm .oF kJ/kg'K
Source: Adapted from ASHRAE, Handbook of Fundamentals. New York: ASHRAE, 1972.
Source: Abridged from J. H. Keenan, F. G. Keyes, P. G. Hill, and 1. G. Moore, Steam Tables-Metric Units. New
New York: John WlIey & Sons, Inc., 1%9. Reprinted by permission of John Wiley & Sons, Inc.
Source: Abridged from J. H. Keenan, F. G. Keyes, P. G. Hill, and J. G. Moore, Steam Tables-Eng/ish Units.
New York: John Wiley & Sons, Inc., 1%9. Reprinted by pennission of John Wiley & Sons, Inc.
Absolute
Pressure,
kPa
(Sat. Temperature (0C)
Temp.,
0C) JOO 150 200 250 300 360 420 500
Source: Abridged from 1. H. Keenan, F. G. Keyes, P. G. Hill, and 1. G. Moore, Sream Tables-Merrie Unirs. New York: John
Wiley & Sons, Inc., 1%9. Reprinted by permission of John Wiley. & Sons, Inc.
Absolute
Pressure,
psia (Sat. Temperature (OF)
Temp.,
oF) 200 300 400 500 600 700 800 900 1000
Source: Abridged from J. H. Keenan, F. G. Keyes, P. G. Hill, and J. G. Moore. Sream Tables-Merric
·hn Units. New York: John Wiley & Sons, Inc., 1969. Reprinted by permission of John Wiley & Sons, Inc.
Jl x 10 3 (gfJp2I p l)
T T P Cp (Pa ·s, or k p x 10" X 10- 8
(0C) (K) (kg/m 3 ) (kJ/kg'K) kg/m's) (W/m'K) N p , (11K) (I/K ·m 3 )
p cp Jl X 10 3 k
(gPp2Ipl)
T ( btu ) fJ X 104 X 10- 6
("F) Ibm·oF hIt·oF N p, (ltR) (It R It 3)
p x 10 5
T T P Cp (Pa's,or k fJ x 10 3 gf3p2/p2
(0C) (K) (kg/m3) (kJ /kg· K) kglm' s) (Wlm·K) N pr (11K) (ilK m 3 )
p cp J-l. x 105 k
T
(F)
('fb
l3
m
) ( bIll
h-Jt·oF
)
N pr
fJ X 10 3
(JtR)
gfJ p 2/ p 2
(itR .p)
Source: D. L Timrot and N. B. Vargaftik, J. Tech. Phys. (U.S.S.R.}, 10, 1063 (1940); R. H.
Perry and C. H. Chilton, Chemical Engineers' Handbook, 5th ed. New York: McGraw-Hili
Book Company, 1973; J. H. Keenan. F. G. Keyes, P. G. Hill, and J. G. Moore, Steam
Tables. New York: John Wiley & Sons, Inc., 1969; National Research Council, Internation-
al Critical Tables. New York: McGraw-Hill Book Company, 1929; L. S. Marks, Mechani-
cal Engineers' Handbook, 5th ed. New York: McGraw. Hill Book Company, 1951.
A.3-1 Standard Heats of Formation at 298.15 K (25°C) and 101.325 kPa (1 Atm
Abs), (c) crystalline, (g) = gas, (I) = liquid
flU; flH;
Compound (kJJk{1 moT)lO- J kealJg mol Compound (kJ /kg mol)lO- 3 keal/g mol
Source: J. H. Perry and C. H. Chillon. Chemical Engineers' Handbook, 5th ed. New York: McGraw·HiII Book
Company, 1973; and O. A. Hougen. K. M. Watson, and R. A. Ragalz, Chemical Process Principles, Pan I. 2nd cd.
New York: John Wiley & Sons. Inc., 1954.
864
A.3-2 Standard Heats of Combustion at 298.15 K (2S°C) and 101.325 kPa (1 Atm Abs)
(g) == gas, (I) == liquid, (s) = solid
(J.:.J /kg
Compound Combustion Reaction kcai/g mol mol)10- 3
SOl/ree: R. H. Perry and C. H. Chilton. Chemical Engineers' Handbook, 51h ed, New York: McGraw·HiII Book
Company, 1973; and O. A. Hougen. K. M. Watson, and R. A. Ragatz, Chemical Process Principles, Part I. 2nd ed.
New York: Jonn Wiley & Sons, Inc., 1954.
fc J
16 C2 H 6
J S03
15
J 2 4 /
/ II /
-
I
13 II / /
/cH4 I I
:.---
I- i--
,... 12 1// / -
S02
--- C0
;::/V
--
E 'I /
c. 0 21
<.J
11
. II /'
--
0
::l
0 l--
..a E 10 L--"
:9
9
8
P"'"' --- Cl 2
O2
air
N2
K H2
T T P cp
Jl x JOS
(Pa's,ar k - fJ X ]0> gfJp l l/12
('e) (K) (kgjm» (kJ /kg' K) kg/m s) (W/m' K) N p, (ilK) (i/K 'm»
p cp k
T
rF)
('bII)m) ( Ibm'bIU)
C
J1 (bW)
F (cenripoise) h"/I" F N p'
{J X
(J/"R)
10 3 9{JP2/112
(l;oR "/t)
Source: National Bureau of Standards, Circular 461C, 1947; 564, 1955; NBS-NACA,
Tables of Thermal Propeflies of Gases, 1949; F. G. Keyes. Trans. A.S.M.E., 73,590,597
(1951); 74, 1303 (1952): D. D. Wagman, Selected Values of Chemical Thermodynamic
Properties. Washinglon, D.C.: National Bureau of Standards., 1953.
Temperalllre
K of °C 11 z
°2 N2 CO CO 2
Source: National Bureau of Standards, Circular 461C, 1947; SM, 1955; NBS-NACA,
Tables oj Thermal Properties oj Gases, 1949; F. G. Keyes, Trans. A.S.M.E., 73, 590, 597
(1951): 74. 1303 (1952); D. D. Wagman, Selecred Values oj Chemical Thermodynamic
Properries. Washington, D.C.: National Bureau ofSlandards, 1953.
).. H, 0, N, CO
Telllpera/llre
)..
1...., K "C OF W/m·K h.!t of W/m'K II'!I·oF W/m·K h-ji·oF W/m·K h·!t·oF
255.4 -17.8 0 0.1592 0.0920 0.0228 0.0132 0.0228 0.0132 0.0222 0.0128 0.0132 0.0076
273.2 0 32 0.1667 0.0963 0.0246 0.0142 0.0239 0.0138 0.0233 0.0135 0.0145 0.0084
283.2 10.0 50 0.1720 0.0994 0.0253 0.0146 0.0248 0.0143 0.0239 0.0138 0.0152 0.0088
311.0 37.8 100 0.1852 0.107 0.0277 0.0160 0.0267 0.0154 0.0260 0.0150 0.0173 0.0100
338.8 65.6 150 0.1990 0.115 0.0299 0.0173 0.0287 0.0166 0.0279 0.0161 0.0190 0.0110
.....,'" 366.5 93.3 200 0.2111 0.122 0.0320 0.0185 0.0303 0.0175 0.0296 0.0171 0.0216 0.0125
394.3 121.1 250 0.2233 0.129 0.0343 0.0198 0.0329 0.0190 0.Q318 0.0184 0.0239 0.0138
422.1 148.9 300 0.2353 0.136 0.0363 0.0210 0.0348 0.0201 0.0338 0.0195 0.0260 0.0150
.....
::s
Cl 449.9 176.7 350 0.2458 0.142 0.0382 0.0221 0.0365 0.0211 0.0355 0.0205 0.0286 0.0165
ci;l 477.6 204.4 400 0.2579 0.149 0.0398 0.0230 0.0382 0.0221 0.0369 0.0213 0.0308 0.0178
;::,
::.
n' 505.4 232.2 450 0.2683 0.155 0.0422 0.0244 0.0400 0.0231 0.0384 0.0222 0.0334 0.0193
t:>
::. 533.2 260.0 500 Q.2786 0.161 0.0438 0.0253 0.0419 0.0242 0.0407 0.0235 0.0355 0.0205
1:1..
C Source: National Bureau of Standards, Circular 461C. 1947; 564,1955; NBS-NACA, Table of Thermal Properties of Gases, 1949; F. O. Keyes, Trans. A.S.M.E.,
ci;l
;::, 73. 590, 597 (1951); 74, 1303 (1952); D. D. Wagman, Selecred Values of Chemical Thermodynamic Properries. Washington, D.C.: National Bureau of Standards.
::.
i";' 1953.
Cl
t::
::.
!:}
, .. .. ;;,,,.
'I:l
'"t).
;:,
>;.
l...
A.3-6 Heat Capacity of Gases at Constant Pressure at 10 1.325 kPa (l Atm Abs)
co CO 2
------
kJf btu/ kJf btu/
K "C OF kl/·K Ib .OF kg' K Ib m. OF kg'K Ibm' OF kg· K Ibm' OF kg· K Ibm' OF
255.4 -17.8 0 14.07 3.36 0.909 0.217 1.034 0.247 1.034 0.247 0.800 0.191
273.2 0 32 14.19 3.39 0.913 0.218 1.038 0.248 1.038 0.248 0.816 0.195
283.2 10.0 50 14.19 3.39 0.917 0.219 1.038 0.248 1.038 0.248 0.825 0.197
311.0 37.8 100 14.32 3.42 0.921 0.220 1.038 0.248 1.043 0.249 0.854 0.204
338.8 65.6 150 14.36 3.43 0.925 0.221 1.038 0.248 1.043 0.249 0.883 0.211
366.5 93.3 200 14.40 3.44 0.929 0.222 1.043 0.249 1.047 0.250 0.904 0.216
394.3 12l.! 250 14.44 3.45 0.938 0.224 1.043 0.249 1.047 0.250 0.929 0.222
422.1 148.9 300 14.49 3.46 0.946 0.226 1.047 0.250 1.051 0.251 0.950 0.227
449.9 176.7 350 14.49 3.46 0.955 0.228 1.047 0.250 1.055 0.252 0.976 0.233
477.6 204.4 400 14.49 3.46 0.963 0.230 1.051 0.251 1.059 0.253 0.996 0.238.
505.4 232.2 450 14.52 3.47 0.971 0.232 1.055 0.252 1.063 0.254 1.017 0.243
533.2 260.0 500 14.52 3.47 0.976 0.233 1.059 0.253 1.068 0.255 1.030 0.246
or
S""rn:: National Bureau Sta",larcis. Cire"!,,, 46lC, 1947; 564, 1955; NBS-NACA, Tubles o/Thermal Proper/ies 0/ Guses, 1949; F. G.
Tru/lS. A.S.M .E., 73, 590, 5')7 (1951); 74, 130J (1952); D. D. Wagman, Sclecled Va/ues oj Chemku/ Thermudy,wmic ['ruperties.
Washington, D.C.: Nationul13urcau or Standards, 1953.
A.3-7 Prandtl Number of Gases at 101325 kPa (1 Atm Abs)
T emperat ure
°C OF K H2
°2 N2 CO CO 2
Source: National Bureau of Standards, Circular 461C. 1947; 564,1955; NB5-NACA, Taoles of
Thermal Propenies of Gases, 1949; F. G. Keyes, Trans. A.S.M.E., 73,590,597 (1951); 74, 1303
(1952): D. D. Wagman, SeleCTed Values of Chemical Thermodynamic Properries. Washington,
D.C.: National Bureau of Standards, 1953.
0.07
0.06
o
o 0.05
30
100
28
26
t± #
0.04
200
100 24 I
i I 0.03
22
300 ! I
i
20
200 , !
400 ! !
18
I I ! : I
I , 0.02
500 16
i I
i i
! !
Y I !
300 ! i I !
600 14 i !
-
I
i-
700 12
i i I [ i- -
400
i i ! ! :
800 10 I i : ! i i
I I i I
I
900 I : i
500 8 ,
I i i :
1000 I I I 0.01
6 I I
I 0.009
600 1100
4 i I
1200 I II 0.008
700 1300 2 1
1400 0.007
I
800 1500 8 10 12 14 16 18
1600 x 0.006
1700
1800
FIGURE A.J-2. Viscosities of gases at 101.325 kPa (l atm abs). (From R. H. Perry and C. H. Chilcon,
Chemical Engineers' Handbook, 5th ed. New York: McGraw-Hill Book Company,
1973. With permission.) See Table A.3-8 for coordinates for use with Fig.
A.3-2.
2
o 3.0
Temperature
2.0
(0C) (OF)
0
100
100 200
300
200 400
500 7 1.0
300 0
600 3 5 0.9
0 6 80
700 40 0 9 0
400 0.8
800 o 11 12 &13
900 1000 0 14 0.7
500
1000 0 0.6
15 016
600 1100
017
1200 0.5
700 1300 17A
1400 o 17C 18 20 0.4
800 17BOo o
1500 o 19 21 0
1600 17D o 0
900
1700 22 230 240 26 28 0.3
1800 o o COg
1000 25 27
1900 29
30
1100 2000
2100 '6 0.2
32 31
1200 2200 o
2300
1300 2400 33
0
2500
1400 340
35
0 0.1
0.09
0.08
36
0 0.07
0.06
0.05
FIGURE A.3:3. Heal capacifY of gases at constant pressure at 101.325 kPa (1 aIm abs). (From R. H.
Perry and C. lI. Chi/con, Chemical Engineers' Handbook, 5th ed. New York:
McGraw-Hill Book Company, 1973. Wilh permission.) See Table r1.3-9 for lise
with Fig. A3-3.
10 Acetylene 0-200
15 Acetylene 200-400
16 Acetylene 400--1400
27 Air 0-1400
12 Ammonia 0-600
14 Ammonia 600--1400
18 Carbon dioxide 0-400
24 Carbon dioxide 400--1400
26 Carbon monoxide,
0-1400
32 Chlorine 0-200
34 Chlorine 200--1400
3 Ethane 0-200
9 Ethane 200--600
8 Ethane 600--1400
4 Ethylene 0-200
11 Ethylene 200--600
13 Ethylene 600--1400
17B Freon-ll (CCI 3 F) 0-150
17C Freon-21 (CHClIF) 0-150
17A Freon-22 (CHCIF 2) 0-150
17D Freon-l13 2) 0-150
Hydrogen 0-600
2 Hydrogen 600--1400
35 Hydrogen bromide 0-1400
30 Hydrogen chloride 0-1400
20 Hydrogen fluoride 0-1400
36 Hydrogen iodide 0-1400
19 Hydrogen sulfide 0-700
21 Hydrogen sulfide 700--1400
5 Methane 0-300
6 Methane 300--700
7 Methane 700--1400
25 Nitric oxide 0-700
28 Nitric oxide 700--1400
26 Nitrogen 0-1400
23 Oxygen 0-500
29 Oxygen 500--1400
33 Sulfur 300--1400
22 Sulfur dioxide 0-400
31 Sulfur dioxide 400-1400
17 Water 0-1400
Source: (I) Moser. dissertation, Berlin, 1913; (2) F. G. Keyes, Tech. Rep!. 37, Project Squid,
Apr. 1. 1952; (3) W. B. Mann and B. G. Dickens. Proe. Roy. Soc. (London), A134, 77 (1931): (4)
InrermHional Crilical Tables. New York: McGraw-Hili Book Company. 1929; (5) T. H.
Chilton and R. P. Genereaux, personal communication. 1946; (6) A. Eucken, Physik, Z., 12.
1101 (1911); 14, 324 (1913); (7) B. G. Dickens, Proe. Roy. Soc. (London), At43, 517 (1934).
Liquid K cp Liquid K cp
Acetic acid 273 1.959 Hydrochloric acid (20 mol %) 273 2.43
3 II 2.240 293 2.474
Acetone 273 2.119 Mercury 293 0.01390
293 2.210 Methyl alcohol 293 2.512
Aniline 273 2.001 313 2.583
323 2.18 I Nitrobenzene 283 1.499
Benzene 293 1.700 303 1.419
333 1.859 363 1.436
Butane 273 2.300 Sodium chloride (9.1 mol %) 293 3.39
i-Butyl alcohol 303 2.525 330 3.43
Ethyl alcohol 273 2.240 Sulfuric acid (100%) 293 1.403
298 2.433 Toluene 273 1.616
Formic acid 273 1.825 323 1.763
289 2.131 o-Xylene 303 1.721
Glycerol 288 2.324
.... 305 2.412
Source: N. A. Lange, Handbook ojChemislry. 10th ed. New York: McGraw-Hill Book Company,
National Rcs.:arch Council, Inlemlllional Crirical Tables, Vol. V. New York: McGraw-Hill Book
Company, 1929; R. H. Perry and C. H. Chilton, Chemical Engineers' Handbook, 5th ed. New York:
McGraw-Hill Book Company, 1973.
Appendix A3 875
Temperature Viscosity
(0C) (OF)
[(kg/m • S)]03 or cp]
200 390
190 380 F
370 F
180 360 f-
350 l-
f- 60
170 340 l-
330 f- 50
t;-
160 320
150
310 rI'- 40
300 E--
290 30
140 280 i=-
270 20
130 260
f-
,
120 250 l-
240
110 230
30 I
100
220
210
I I ._- rl=- 10
9
I 1
t
200 28 I
, F 8
I
l- I 7
90 190 26 I
i
I f- i f- 6
180 i, !
l-
-
80 I
I
, f- 5
170 24 ,I
I \ ·'1
I I , i ! .! '!
4
70 160 I
I
,
, ,
I I i i l:-
150 22 i ,
I I I F- 3
60
50
140
130 iFR
20
i
i
i . ! !
i
I,
F-- 2
120 18 ,i i
!
110 ,
I
40 i , I I r
100 16
y ,
i ... ! i
90 I ' , I I i
30 14 ,
80
,1
I .
f-f-;
!: ;
I
i
r I
0.9
20 70 12
i i i I l=-
l-
0.8
0.7
60 10 I I ,I I
i
i
i I --
l-
0.6
10 50 I , J
,-- 0.5
8
40 : I l':-- 0.4
: i
0 30 6
i
, E-
I i ; i E-- 0.3
20 ; i
i i I
!
-10 4
;R=ffi
I ! i
i
10 !
I
,, r-- 0.2
2
I
I I I
0 I I ! l - I-
-20 \ I I I I
-10 o0 2 4 6
\
8 10 12 14 16 18 20
I-
- 20 x
30 '-- 0.1
FIGURE A.3-4. Viscosities of liquids. (From R. H. Perry and C. H. Chilron, Chemical Engineers'
Handbook,5lh ed. New York : McGraw-Hili Book Company, 1973. With permission.)
See Table A.3-i2 for use with Fig. A.3-4.
Liquid X Y Liquid X Y
Appendix A3 877
A.3-12 Viscosities of Liquids, Continued
Liquid X Y Liquid X Y
50
o
0.4
4
21 -ao. 25
6A Oic1llofOftth.lne -30· 60
5 Ok;hlmometh.na -40· 50
15 Olphenyl eO'120
,.I.
22 D'phenylm&thJlno
CHph.nyt Oxide
Oowthefm A
30·100
0- 200
0- Zoo
4.
24 Ethyl Acet .. to -50· 25
42 •• AlCOhol 100')1. 30· 80
95" 20· 80
50 20 - BO
25
1
Senzene
8romid.
0- 1(}0
5· 25
0.5
13 eh-torle'll!! ·30· 40
30°26
36
7
Ether ·100 - 25
0·100
27
°
39 Ethylene Glycol -40 - 200
150 28_0
350 33
41
8
3 6 3&39 36 0.6
100
42
CD 44°
43
45
°
48 °
40
0
46 047
0 49
50 No Uqu!d 0.7
2A Freon·ll (CCIJF) -20 70
6 •• -12(CC1ZF2) -40· 15
4A •• -Zl(CHCI 2 F ) -20· 70
7A •• -22tCHCI F 2) ·20 60
3A .. -11J(CC t 2F-CCIF 2) ·20· 70
o 38
28
Gly<.ero1
Kephnli
.40 - 20
o· 60
35 Hi:.l<)Ol!! ·80· 20
48
41
f-tyd,<xh1orlc Add. 30%
ho.amyl Alcohol
20· 100
}O 100 050 51 0 0.8
43 llobutyl Ah;ohoJ o· 100
<7 hopropyl Akohol ·20· 50
31 I$.o!l,opyl EUuu ·ao· 20
-50 40
13A
Methyl AI<.ohol
Methyl Chloride
-40 - 20
-80- 20
14 N.aph\hlileoe 90 ;zoo
II 0- 100
34 Noo.ane -50· 25
33 Ocune ·50· 25-
Perchlo(ethyhme ·30 1.40
J
45 Propyl Alcohol ·20·100 0.9
-100 20
9
PyrldlOfl
Sulfuric Acid 98%
·50 #
10· 45
25
,.
53
18
Watet'
Xylene
••
)0·200
o 100
0·100
17 "",. 0·100
53
52
o
° 1.0
F1GURE A.3-5_ Heat capacity of liquids. (From R. If. Perry and C. H. Chillon, Chemical Engineers'
If andbook. 5th ed. New York,' McGraw-Hill Book Company, /973. With permission.)
• A linear variation with temperature may be assumed between the temperature limits given.
Source: R. H. Perry and C. H. Chilton. Chemical Engineers' Handbook, 5th ed. New York:
McGraw-Hili Book Company, 1973. With permission.
Solid K cp Solid K cp
Alumina 373
0.84 Benzene 273 1.570
1773
1.147 Benzoic acid 293 1.243
Asbestos 1.05 Camphene 308 1.591
Asphalt 0.92 Caprylic acid 271 2.629
Brick, fireclay 373 0.829 Dextrin 273 1.218
1773 1.248 Formic acid 273 1.800
Cement, portland 0.779 Glycerol 273 1.382
Clay 0.938 Lactose 293 1.202
Concrete 0.63 Oxalic acid 323 1.612
Corkboard 303 0.167 Tartaric acid 309 1.202
Glass 0.84 Urea 293 1.340
Magnesia 373 0.980
1773 0.787
Oak 2.39
Pine, yellow 298 2.81
Porcelain 293-373 0.775
Rubber, vulcanized 2.01
Steel 0.50
Wool 1.361
Source: R. H. Perry and C H. Chilton. Chemical Ellgineers" Handbook, 5th ed. New
York: McGraw-Hili Book Company. 1973; National Research Council, In/emotional
Critical Tables, Yol. Y. New York: McGraw-Hili Book Company, 1929; L. S. Marks,
,>."techanical Engineers" flandbook. 5th ed. New York: McGraw-Hili Book Company,
1951; f. Kreith, Principles of fleat Transfer, 2nd ed. Scranton, Pa.: International
Textbook Co .. 1965.
Material (:;) I·
(0G) k(W/m·K)
p cp
t
Material (0C) k(W/m K)
Source: L. S. Marks, Mechanical Engineers' Handbook, 5th ed. New York: McGraw-Hill Book
Company, 1951; E. R. G. Eckert and R. M. Drake, Heat and Mass Transfer, 2nd ed. New York:
McGraw-Hill Book Company, 1959; R. H. Perry and C H. Chilton. Chemical Engineers' Handbook,
5th ed. New York: McGraw-Hii] Book Company, 1973; National Research Council, International
Critical Tables. New York: McGraw-Hili Book Company, 1929.
Appendix A3
A.3-17 Normal Total Emmissivities of Surfaces
Surface K G Surface K G
Source: R, H. Perry and C. H. Chilton, Chemical Engineers' Handbook, 5th ed. New York:
McGraw·Hill Book Company, 1973; W. H. McAdams, Heat Transmission, 3rd cd. New York:
McGraw-Hili Book Company, 1954; E. Schmidt, Gesundh.-Ing. Beihefr, 20, Reihe 1,1 (1927).
0 0 0
0.05 25.0 50
0.10 46.0 102
0.15 66.5 151
Appendix A3 885
A.3-21 Equilibrium Data for Acetone-Water System
at 20"C (293 K)
o o
0.0333 30.0
0.0720 62.8
0.117 85.4
0.171 103
0 0 0 0 0
0.0126 11.5 0.0151
0.0167 15.3 0.0201
0.0208 12 19.3 0.0158 0.0254
0.0258 15 24.4 0.0197 0.0321
0.0309 18.2 29.6 0.0239 0.0390
0.0405 24.9 40.1 0.0328 0.0527
0.0503 31.7 51.0 0.0416 0.0671
0.0737 50.0 79.7 0.0657 0.105
0.0960 69.6 110 0.0915 0.145
0.137 114 179 0.150 0.235
0.175 166 260 0.218 0.342
0.210 227 352 0.298 0.463
0.241 298 454 0.392 0.597
0.297 470 719 0.618 0.945
Source: 1. H. Perry, Chemical' Engineers' Handbook, 4th ed. New York: McGraw-Hili Book Company,
1963. With permission.
100.0 212 0 0 81.0 177.8 0.600 0.794 100.0 212 0 180.1 1150 418.9 2675
98.1 208.5 0.020 0.192 80.1 176.2 0.700 0.822 91.8 197.2 0.1 159.8 1082 371.7 2517
95.2 203.4 0.050 0.377 79.1 174.3 0.800 0.858 84.7 184.5 0.3 135.0 943 314.0 2193
91.8 197.2 0.100 0.527 78.3 173.0 0.900 0.912 82.0 179.6 0.5 122.9 804 285.9 1870
87.3 189.2 0.200 0.656 78.2 172.8 0.940 0.942 80.1 176.2 0.7 111.1 664 258.4 1544
84.7 184.5 0.300 0.713 78.1 172.7 0.960 0.959 78.3 173.0 0.9 96.6 526 224.7 1223
83,2 181.7 00400 0.746 78.2 172.8 0.980 0.978 78.3 173.0 1.0 89.0 457.5 . 207.0' 1064
82.0 179.6 0.500 0.771 78.3 173.0 1.00 1.00
H2O cp
Material (we %) (kJ/kg'K)
H 2O cp
Material (wt %) (kJjkg' K)
Ice cream
Fresh 58-66- 3.27t
Frozen 58-66 1.88t
Lamb 70 3.18*
Macaroni 12.5--13.5 1.84-1.88
Milk, cows'
Whole 87.5 3.85
Skim 91 3.98-4.02:
Olive oil 2.01 **
Oranges
Fresh 87.2 3.77t
Frozen 87.2 1.93t
Peas, air-dried 14 1.84
Peas, green
Fresh 74.3 3.31 t
Frozen 74.3 l.76t
Pea soup 4.10
Plums 75--78 3.52
Pork
Fresh 60 2.85t
Frozen 60 l.34t
Potatoes 75 3.52
Poultry
Fresh 74 3.31t
Frozen 74 l.55t
Sausage, franks
Fresh 60 3.60t
Frozen 60 2.35t
String beans
Fresh 88.9 3.81t
Frozen 88.9 1.97t
Tomatoes 95 3.98t
Veal 63 3.22
Water 100 4.185**
• 32.S0C
t Above freezing.
t Below freezing.
§ 24,4°C
4.4°C
II -20°C
.. 20°C
Source: W. O. Ordinanz., Food Ind., 18, 101 (1946); G. A.
Reidy, Department of Food Science, Michigan State Uni-
versity, 1968; S. E. Charm, The of Food Engin-
eering, 2nd ed. Westport, Conn.: Avi Publishing Co., Inc.,
1971; R. L. Earle, Unit in Food Processing.
Oxford: Pergamon Press, 1966; ASHRAf, Handbook
of Fundamentals. New York: ASHRAE, 1972, 1967; H. C
Mannheim, M. P. Steinberg, and A. I. Nelson, Food
Technol., 9, 556 (1955).
Temp-
Ii 20 erature k P J1.
Material (wt 01.,) (K) (W 1m . K) (kglm 3 ) [(Pa's)10 3 ,
or cp]
Source: R. C. Weast, Handbook of Chemistry and Physics, 48th ed. Cleveland: Chemical
Rubber Co., Inc., 1967; c. P. Lentz, Food Technol., 15, 243 (1961); G. A. Reidy, Department of
Food Science., Michigan State University, 1968; S. E. Charm, The Fundamentals of Food
Engineering, 2nd ed. Westport, Conn.: Avi Publishing Inc., 1971; R. Earle, Unit Operarioru
in Food Processing, Oxford: Pergamon Press. 1966; R. H. Perry and C. H. Chilton, Chemical
Engineers' Handbook, 5th ed. New York: McGraw-Hili Book Company. 1973; V. E. Sweat, 1.
Food Sci., 39, 1080(1974).
Appendix AA 891
APPENDIX A.S
Properties of Pipes,
Tubes, and Screens
"8
I
0.405 10.29 40 0.068 1.73 0.269 6.83 0.00040 0.3664
80 0.095 2.41 0.215 5.46 0.00025 0.2341
4'
I
0.540 13.72 40 0.088 2.24 0.364 9.25 0.00072 0.6720
80 0.119 3.02 0.302 7.67 0.00050 0.4620
3
"8 0.675 17.15 40 0.091 2.31 0.493 12.52 0.00133 1.231
80 0.126 3.20 0.423 10.74 0.00098 0.9059
2:
I
0.840 21.34 40 0.109 2.77 0.622 15.80 0.00211 1.961
80 0.147 3.73 0.546 13.87 0.00163 1.511
3
4' 1.050 26.67 40 0.113 2.87 0.824 20.93 0.00371 3.441
80 0.154 3.91 0.742 18.85 0.00300 2.791
1.315 33.40 40 0.133 3.38 1.049 26.64 0.00600 5.574
80 0.179 4.45 0.957 24.31 0.00499 4.641
1-'4 1.660 42.16 40 0.140 3.56 1.380 35.05 0.01040 9.648
80 0.191 4.85 1.278 32.46 0.00891 8.275
11 1.900 48.26 40 0.145 3.68 1.610 40.89 0.01414 13.13
80 0.200 5.08 1.500 38.10 0.01225 11.40
2 2.375 60.33 40 0.154 3.91 2.067 52.50 0.02330 21.65
80 0.218 5.54 1.939 49.25 0.02050 19.05
?-'
-2 2.875 73.03 40 0.203 5.16 2.469 62.71 0.03322 30.89
80 0.276 7.01 2.323 59.00 0.02942 27.30
3 3.500 88.90 40 0.216 5.49 3.068 77.92 0.05130 47.69
0.300 7.62 2.900 73.66 0.04587 42.61
31 4.000 101.6 40 0.226 5.74 3.548 90.12 0.06870 63.79
80 0.318 8.08 3.364 85.45 0.06170 57.35
4 4.500 114.3 40 0.237 6.02 4.026 102.3 0.08840 82.19
80 0.337 8.56 3.826 97.18 0.07986 74.17
5 5.563 141.3 40 0.258 6.55 5.047 128.2 0.1390 129.1
80 0.375 9.53 4.813 122.3 0.1263 117.5
6 6.625 168.3 40 0.280 7.11 6.065 154.1 0.2006 186.5 "
:{
80 0.432 10.97 5.761 146.3 0.1810 168.1
8 8.625 219.1 40 0.322 8.18 7.981 202.7 0.3474 322.7 ".'
80 0.500 12.70 7.625 193.7 0.3171 294.7 .'' ;>
"f
i
892 App. A.5 Properties of Pipes, Tubes, and Screens
:
L':
to'
A.5-2 Dimensions of Heat-Exchanger Tubes
5
"3 15.88 12 0.109 2.77 0.407 10.33 0.000903 0.8381
14 0.083 2.11 0.459 11.66 0.00115 1.068
16 0.065 1.65 0.495 12.57 0.00134 1.241
18 0.049 1.25 0.527 13.39 0.00151 1.408
1
4 19.05 12 0.109 2.77 0.532 13.51 0.00154 1.434
14 0.083 2.11 0.584 14.83 0.00186 1.727
16 0.065 1.65 0.620 15.75 0.00210 1.948
18 0.049 1.25 0.652 16.56 0.00232 2.154
7
"3 22.23 12 0.109 2.77 0.657 16.69 0.00235 2.188
14 0.083 2.11 0.709 18.01 0.00274 2.548
16 0.065 1.65 0.745 18.92 0.00303 2.811
18 0.049 1.25 0.777 19.74 0.00329 3.060
25.40 10 0.134 3.40 0.732 18.59 0.00292 2.714
12 0.109 2.77 0.782 19.86 0.00334 3.098
14 0.083 2.11 0.834 2Ll8 0.00379 3.523
16 0.065 1.65 0.870 22.10 0.00413 3.836
1:t 31.75 10 0.134 3.40 0.982 24.94 0.00526 4.885
12 0.109 2.77 1.032 26.21 0.00581 5.395
14 0.083 2.11 1.084 27.53 0.00641 5.953
16 0.065 1.65 1.120 28.45 0.00684 6.357
It 38.10 10 0.134 3.40 1.232 31.29 0.00828 7.690
12 0.109 2.77 1.282 32.56 ' 0.00896 8.326
14 0.083 2.11 1.334 33.88 0.00971 9.015
2 50.80 10 0.134 3.40 1.732 43.99 0.0164 15.20
12 0.109 2.77 1.782 45.26 0.0173 16.09