CHEMISTRY

Crash Course for

JEE Main 2020

ATOMIC STRUCTURE

www.etoosindia.com
Plot No. 46, In front of Skyline Apartments, Corner Building,
Rajeev Gandhi Nagar, Kota, (Rajasthan) Pin code : 324005.
Help Desk : 09214233303 | 09214233343 |
ETOOSINDIA
India’s No.1 Online Coaching ATOMIC STRUCTURE
EXERCISE - 1
1. The distance of closest approach of an -particle projected towards a nucleus with momentum p is r.
What will be the distance of closest approach, when the momentum of projected -particle is 2p?
r r
(A) 2r (B) 4r (C) (D)
2 4

2. The energy of electron is maximum at

(A) Nucleus (B) Ground state
(C) First excited state (D) Infinite distance from the nucleus

3. Which electronic level would allow the hydrogen atom to absorb a photon but not to emit a photon

IA
(A) 3s (B) 2p (C) 2s (D) 1s

4. Orbital angular momentum associated with 2p - electron is :

2h h h

D
(A) (B) 0 (C) 6 (D)
 2 2

5. The angular momentum of an electron in a certain orbit of Li+2 ion is 3.15 × 10–34 (in SI units). What
will be the potential energy of electron in that orbit ?
(A) –13.6 eV (B) –27.2 eV N
(C) + 13.6eV (D) –53.4 eV
SI
6. The shortest wavelength of He atom in Balmer series is x, then longest wavelength in the Paschen
series of Li+2 is
36 x 16 x 9x 5x
(A) (B) (C) (D)
O
5 7 5 9
7. An electron, a proton and an alpha particle have kinetic energies of 16E, 4E and E respectively. What
is the qualitative order of their de Broglie wavelengths?
O

(A) e > p =  (B) p =  > e (C) p > e >  (D)  < e » p

8. The ratio of difference in wavelengths of 1st and 2nd lines of Lyman series in H–like atom to difference
ET

in wavelength for 2nd and 3rd lines of same series is:

(A) 2.5 : 1 (B) 3.5 : 1 (C) 4.5 : 1 (D) 5.5 : 1

9. X-rays are emitted as the electrons deep within atoms having many electrons fall to lower energy
states. What is the difference in energy between two levels if a transition between them gives rise to 0.5
Å X-ray?
(A) 24.8 eV (B) 24.8 KeV (C) 24.8 MeV (D) none of these

10. If radius of second stationary orbit (in Bohr's atom) is R. Then radius of third orbit will be
(A) R/3 (B) 9R (C) R/9 (D) 2.25R

11. Wavelength of radiations emitted when an electron jumps from state A to C is 3000 Å and it is 6000 Å
when the electron jumps from state B to state C. Wavelength of the radiations emitted when an electron
jumps from state A to B will be
(A) 6000 Å (B) 3000 Å (C) 4000 Å (D) 2000 Å
www. e t o o s in d ia . c o m
2 Plo t No . 46 , In fro nt o f Skyline Apar tme nts, Cor ne r Building , Raje e v Gandhi ETOOSINDIA
Nagar, Kota, (Rajasthan) Pin co de : 324 00 5. India’s No.1 Online Coaching
Help Desk : 09214233303 | 09214233343 |
ETOOSINDIA
India’s No.1 Online Coaching ATOMIC STRUCTURE
12. The ratio of wave length of photon corresponding to the -line of Lyman series in H-atom and -line
of Balmer series in He+ is
(A) 1 : 1 (B) 1 : 2 (C) 1 : 4 (D) 3 : 16

13. Three energy levels P, Q, R of a certain atom are such that EP < EQ < ER. If 1, 2 and 3 are the wave
length of radiation corresponding to transition R  Q ; Q  P and R P respectively. The correct
relationship between 1, 2 and 3 is
1 1 1 2 1 1
(A) 1 + 2 = 3 (B)      (C) 3 = 1 2 (D)     
3 1 2 3 1 2

14.  
The value of (n2 + n1) and n 22  n 12 for He+ ion in atomic spectrum are 4 and 8 respectively. The

IA
wavelength of emitted photon when electron jump from n2 to n1 is
32 9 9 32
(A) R (B) R (C) 32 R (D) 9 R
9 H 32 H H H

D
15. Number of possible spectral lines which may be emitted in bracket series in H atom, if electrons
present in 9th excited level returns to ground level, are

16.
(A) 21 (B) 6 N
(C) 45 (D) 5

An electron in an atom jumps in such a way that its kinetic energy changes from x to
x
9
. The change
SI
in its potential energy will be-
x 16 x 9
(A) (B) (C) 9x (D) x
9 9 16
O

17. The potential energy of an electron in He+ ion is –12.09 eV. Indicate in which excited state, the electron
is present –
(A) First (B) Second (C) Third (D) Fourth
O

–1
18. An electron has velocity x ms . For a proton to have the same de-Broglie wavelength, the velocity
will be approximately –
ET

1840 x
(A) (B) (C) 1840x (D) x
x 1840
19. Photoelectric emission is observed from a surface for frequencies 1 and 2 of incident radiations
(1 > 2). If the maximum K.E. of photoelectrons in two cases are in the ratio of 2 : 1, then
threshold frequency 0 is given by -
 2  1 2 1   2 2 2   1
(A) (B) (2  1) (C) (2  1) (D)  2  1
2
20. The amount of energy required to remove the electron from a Li2+ ion in its ground state is how many
times greater than the amount of energy required to remove the electron from an H-atom in its ground
state :
(A) 9 (B) 2 (C) 3 (D) 5

www. e t o o s in d ia . c o m
3 Plo t No . 46 , In fro nt o f Skyline Apar tme nts, Cor ne r Building , Raje e v Gandhi ETOOSINDIA
Nagar, Kota, (Rajasthan) Pin co de : 324 00 5. India’s No.1 Online Coaching
Help Desk : 09214233303 | 09214233343 |
ETOOSINDIA
India’s No.1 Online Coaching ATOMIC STRUCTURE
21. The difference in angular momentum associated with the electron in two successive orbits of hydrogen
atom is :
(A) h/ (B) h/2 (C) h/2 (D) (n –1)h/2

22. Magnetic moment of Fea+ (Z = 26) is 24 BM. Hence number of unpaired electrons and value of ‘a’
respectively are :
(A) 4, 2 (B) 2, 4 (C) 3, 1 (D) 0, 2
Rch
23. Number of degeneracy in a level of H-atom having En = –
9
(A) 3 (B) 6 (C) 9 (D) 14

24. The velocity of an electron having its wavelength being equal to velocity can be given by :

IA
h m h h
(A) (B) (C) p (D)
m h 2KE

D
25. Predict the total spin in Ni2+ ion :
(A) ± 5/2 (B) ± 3/2 (C) ± 1/2 (D) ± 1

26.

(A)
1 h
(B)
h
N
If uncertainty in position and momentum are equal then uncertainty in velocity is :

(C)
1 h
(D)
h
SI
m   2m  2

27. Which one represents an impossible arrangement

n  m s
O

(A) 3 2 –2 1/2
(B) 4 0 0 1/2
(C) 3 2 –3 1/2
O

(D) 5 3 0 ½
ET

28. The circumference of nth orbit in H-atom can be expressed in terms of de-Broglie wavelength  as
(A) n (B) n (C) 0.529 n (D) 13.6 

29. Which electronic level would allow a H-atom to absorb a photon but not to emit a photon :
(A) 3s (B) 2p (C) 1s (D) 3d
30. Which of the following graphs is incorrect ?

v v v v
(A) (B) (C) (D)
n 1/n z n

31. Maximum value (n + l + m) for unpaired electrons in second excited state of chlorine 17Cl is :
(A) 28 (B) 25 (C) 20 (D) None of these
www. e t o o s in d ia . c o m
4 Plo t No . 46 , In fro nt o f Skyline Apar tme nts, Cor ne r Building , Raje e v Gandhi ETOOSINDIA
Nagar, Kota, (Rajasthan) Pin co de : 324 00 5. India’s No.1 Online Coaching
Help Desk : 09214233303 | 09214233343 |
ETOOSINDIA
India’s No.1 Online Coaching ATOMIC STRUCTURE
32. In which of the following pairs is the probability of finding the electron in xy-plane zero for both
orbitals ?
(A) 3d yz , 4d x2 – y2 (B) 2p z , d z 2 (C) 4dzx, 3pz (D) None of these

33. A compound of vanadium has a magnetic moment of 1.73 BM. The electronic configuration of
vanadium ion in the compound is :
(A) [Ar]3d2 (B) [Ar]3d14s0 (C) [Ar]3d3 (D) [Ar]3d0 4s1

34. If the kinetic energy of a particle is doubled, de-Broglie wavelength becomes :

1
(A) 2 times (B) 4 times (C) 2 times (D) times
2

IA
35. The radii of any two first four Bohr orbits of the hydrogen atom are in the ratio 1 : 4. The energy
difference them may be :
(A) either 12.09 eV or 3.4 eV (B) either 2.55 eV or 10.2 eV
(C) either 13.6 eV or 3.4 eV (D) either 3.4 eV or 0.85 eV

D
36. The measurement of the electron position is associated with an uncertainty in momentum, which is equal
to 1 × 10–18 g cm s–1. The uncertainty in electron velocity is : (mass of an electron is 9 × 10–28 g)

38.
(A) 1 × 105 cm s–1 (B) 1 × 1011 cm s–1 N (C) 1 × 109 cm s–1

According to Bohr theory, the angular momentum of electron in 5th orbit is :

(D) 1 × 106 cm s–1
SI
h h h h
(A) 25 (B) 1 (C) 10 (D) 2.5
   

39. The number of photons of light having wave number ‘x’ in 2J of energy source is -
O

hc 2 2x
(A) 2hcx (B) (C) (D)
2x hcx hc
O

40. A near ultraviolet photon of 30 nm is absorbed by a gas and then re-emitted as two photons. One
photon is red with wave length 760 nm. What would be the wavelength of the second photon in Å -
(A) 4950Å (B) 4960Å (C) 2475 Å (D) None of these
ET

41. If each hydrogen atom is excited by giving 8.4 eV of energy, then the number of spectral lines emitted
is equal to -
(A) None (B) Two (C) Three (D) Four

42. Photons having energy equivalent to binding energy of 4th state of He+ ion is used the metal surface of
work function 1.4 eV. If electrons are further accelerated through the potential difference of 4 V then
the minimum value of de-Broglie wavelength associated with the electron is-
(A) 1.1 Å (B) 9.15 Å (C) 5 Å (D) 11 Å

43. What will be the maximum spin multiplicity for 4d-orbital ?

(A) 4 (B) 6 (C) 5 (D) 10

www. e t o o s in d ia . c o m
5 Plo t No . 46 , In fro nt o f Skyline Apar tme nts, Cor ne r Building , Raje e v Gandhi ETOOSINDIA
Nagar, Kota, (Rajasthan) Pin co de : 324 00 5. India’s No.1 Online Coaching
Help Desk : 09214233303 | 09214233343 |
ETOOSINDIA
India’s No.1 Online Coaching ATOMIC STRUCTURE
44. The ionization energy of hydrogen like atom (in the ground state) is x kJ. The energy required for an
electron to jump from 2nd orbit to the 3rd orbit will be :
(A) x/6 (B) 5x (C) 7.2x (D) 5x/36

45. If the shortest wavelength of H atom in Lyman series is x. then longest wavelength in Balmer series of
He+ is -
9x 36x x 5x
(A) (B) 5 (C) (C)
5 4 9

46. If 0 be the permittivity of vaccum and r be the radius of orbit of H-atom in which electron is revolving
then velocity of electron is given by :

IA
e 4 0 rm 4 0 rm
(A) v  4 rm (B) v  e  4 0 rm (C) v  (D) v 
0 e e2

47. Be3+ and a proton are accelerated by the same potential, their de-Broglie wavelengths have the ratio

D
(assume mass of proton = mass of neutron) :
(A) 1 : 2 (B) 1 : 4 (C) 1 : 1 (D) 1 : 3 3

48.
N
According to Einstein’s photoelectric equation, the graph between the kinetic energy of
photoelectrons ejected and the frequency of incident radiations is –
SI
Kinetic energy
Kinetic energy

Kinetic energy
Kinetic energy

O
(A) (B) (C) (D)
Frequency Frequency Frequency
Frequency
O

49. The angular wave function of which orbital will not disturb by the variation with azimuthal angle only
(A) 1s and 2s (B) 2pz and 2dz2 (C) 2px and 3dz2 (D) 2px and 2s
ET

50. Let 1 be the frequency of the series limit of the Lyman series, 2 be the frequency of the first line of
the Lyman series, and 3 be the frequency of the series limit of the Balmer series :
(A) 1 – 2 = 3 (B) 2 – 1 = 3 (C) 3 = 1/2 (1 – 3) (D) 1 + 2 = 3

51. An electron in a hydrogen like atom makes transition from a state in which its de-Broglie wavelength
is 1 to a state where its de-Broglie wavelength is 2 then wavelength of photon () generated will
be

4mc  21 22 

(A)  = 1 – 2 (B)  =  2 
h  1  22 

21 22 2mc  21 22 

(C)  = (D)  =  2 
21  22 h  1  22 

www. e t o o s in d ia . c o m
6 Plo t No . 46 , In fro nt o f Skyline Apar tme nts, Cor ne r Building , Raje e v Gandhi ETOOSINDIA
Nagar, Kota, (Rajasthan) Pin co de : 324 00 5. India’s No.1 Online Coaching
Help Desk : 09214233303 | 09214233343 |
ETOOSINDIA
India’s No.1 Online Coaching ATOMIC STRUCTURE
52. In a sample of H-atoms, electrons de-excite from a level ‘n’ to 1. The total number of lines
belonging to Balmer series are two. If the electrons are ionised from level ‘n’ by photons of
energy 13 eV. Then the kinetic energy of the ejected photoelectrons will be
(A) 12.15 eV (B) 11.49 eV (C) 12.46 eV (D) 12.63 eV

53. Spin angular momentum for unpaired electron in sodium (Atomic No. = 11) is
3 3 h
(A) (B) 0.866 h/2 (C) – (D) None of these
2 2 2

54. The wave function () of 2s-orbital is given by :

3/2
1  1  r  r / 2a0
2s =   2 – e . At r = r0, radial node is formed.
32  a0   a 0

IA
Then which of the following is correct :
(A) r0 = a0 (B) r0 = 2a0 (C) r0 = 3a0 (D) None of these

D
N
SI
O
O
ET

www. e t o o s in d ia . c o m
7 Plo t No . 46 , In fro nt o f Skyline Apar tme nts, Cor ne r Building , Raje e v Gandhi ETOOSINDIA
Nagar, Kota, (Rajasthan) Pin co de : 324 00 5. India’s No.1 Online Coaching
Help Desk : 09214233303 | 09214233343 |
ETOOSINDIA
India’s No.1 Online Coaching ATOMIC STRUCTURE
EXERCISE - 2
PART - I - PREVIOUS YEAR QUESTIONS (JEE-MAIN/AIEEE)
1. The wavelength of the radiation emitted, when in a hydrogen atom electron falls from infinity to stationary state
1, would be (Rydberg constant = 1.097  107 m–1) [AIEEE 2004]
(A) 91 nm (B) 192 nm (C) 406 (D) 9.1  10–6 nm
2. Which of the following set a of quantum numbers is correct for an electron in 4f orbital? [AIEEE 2004]
(A) n = 4, l =3, m = +4, s = +1/2 (B) n = 4, l = 4, m = –4, s = –1/2
(C) n = 4, l = 3, m = +1, s = +1/2 (D) n = 3, l=2, m =–2, s = +1/2
3. Consider the ground state of Cr atom (Z = 24). The numbers of electrons with the azimuthal quantum numbers,
 = 1 and 2 are, respectively [AIEEE 2004]
(A) 12 and 4 (B) 12 and 5 (C) 16 and 4 (D) 16 and 5
4. Which of the following statements in relation to the hydrogen atom is correct ? [AIEEE 2005]

IA
(A) 3s, 3p and 3d orbitals all have the same energy
(B) 3s and 3p orbitals are of lower energy than 3d orbital
(C) 3p orbital is lower in energy than 3d orbital
(D) 3s orbital is lower in energy than 3p orbital

D
5. In a multi-electron atom, which of the following orbitals described by the three quantum numbers will have the
same energy in the absence of magnetic and electric field ? [AIEEE 2005]
(i) n = 1, l = 0, m = 0 (ii) n =2, l = 0, m = 0 (iii) n = 2, l = 1, m = 1 (iv) n = 3, l = 2, m =1
(v) n = 3, l = 2, m = 0
(A) (iv) and (v) (B) (iii) and (iv)
N
(C) (ii) and (iii) (D) (i) and (ii)
SI
6. Uncertainity in the position of an electron (mass = 9.1  10–31 Kg) moving with a velocity 300 m.sec–1, Accurate
upto 0.001%, will be : (h = 6.63  10–34 J-s) [AIEEE 2006]
(A) 19.2  10–2 m (B) 5.76  10–2 m (C) 1.92  10–2 m (D) 3.84  10–2 m
7. According to Bohr’s theory, the angular momentum to an electron in 5th orbit is : [AIEEE 2006]
O

h h h h
(A) 25 (B) 1.0 (C) 10 (D) 2.5
   
O

8. The ‘spin-only’ magnetic moment [in units of Bohr magneton ()] of Ni2+ in aqueous solution would be (Atomic
number : Ni = 28) [AIEEE 2006]
(A) 2.84 (B) 4.90 (C) 0 (D) 1.73
ET

9. Which of the following nuclear reactions will generate an isotope ? [AIEEE 2007]
(A) Neutron particle emission (B) Positron emission
(C) -particle emission (D) -particle emission
10. The ionisation enthalpy of hydrogen atom is 1.312  106 J mol–1. The energy required to excite the electron in the
atom from n1 = 1 to n2 = 2 is [AIEEE 2008]
(A) 8.51  105 J mol–1 (B) 6.56  105 J mol–1 (C) 7.56  105 J mol–1 (D) 9.84  105 J mol–1
11. Which of the following set of quantum numbers represents the highest energy of an atom ? [AIEEE 2008]
1 1
(A) n = 3, l = 0, m = 0, s = + (B) n = 3, l = 1, m =1, s = +
2 2
1 1
(C) n = 3, l = 2, m = 1, s = + (D) n = 4, l = 0, m = 0, s = +
2 2
–1
12. The energy required to break one mole of Cl – Cl bonds in Cl2 is 242 kJ mol . The longest wavelength of light
capable of breaking a single Cl – Cl bond is [AIEEE 2010]
(c = 3 × 108 m s–1 and NA = 6.02 × 1023 mol–1)
(A) 594 nm (B) 640 nm (C) 700 nm (D) 494 nm
www. e t o o s in d ia . c o m
8 Plo t No . 46 , In fro nt o f Skyline Apar tme nts, Cor ne r Building , Raje e v Gandhi ETOOSINDIA
Nagar, Kota, (Rajasthan) Pin co de : 324 00 5. India’s No.1 Online Coaching
Help Desk : 09214233303 | 09214233343 |
ETOOSINDIA
India’s No.1 Online Coaching ATOMIC STRUCTURE
13. Ionisation energy of He+ is [AIEEE 2010]
–18 –1 2+
19.6 × 10 J atom . The energy of the first stationary state (n = 1) of Li is :
(A) 4.41 × 10–16 J atom–1 (B) – 4.41 × 10–17 J atom–1 (C) – 2.2 × 10–15 J atom–1 (D) 8.82 × 10–17 J atom–1
14. A gas absorbs a photon of 355 nm and emits at two wavelengths. If one of the emission is at 680 nm, the other is at
[AIEEE 2011]
(A) 1035 nm (B) 325 nm (C) 743 nm (D) 518 nm
15. The frequency of light emitted for the transition n = 4 to n = 2 of He+ is equal to the transition in H atom corresponding
to which of the following? [AIEEE 2011]
(A) n = 2 to n = 1 (B) n = 3 to n = 2 (C) n = 4 to n = 3 (D) n = 3 to n = 1

16. The electrons identified by quantum numbers n and  : [AIEEE 2012]

(A) n = 4,  = 1 (B) n = 4,  = 0 (C) n = 3,  = 2 (D) n = 3,  = 1
can be placed in order of increasing energy as :

IA
(A) (C) < (D) < (B) < (A) (B) (D) < (B) < (C) < (A) (C) (B) < (D) < (A) < (C) (D) (A) < (C) < (B) < (D)
17. The correct set of four quantum numbers for the valence elections of rubidium atom (Z = 37) is : [JEE MAIN 2014]
1 1 1 1
(A) 5, 1, 1, + (B) 5, 0, 1, + (C) 5, 0, 0, + (D) 5, 1, 0, +

D
2 2 2 2
18. Which of the following is the energy of a possible excited state of hydrogen? [JEE MAIN 2015]
(A) –3.4 eV (B) +6.8 eV (C) +13.6 eV (D) –6.8 eV
19. N
A stream of electrons from a heated filament was passed between two charged plates kept at potential difference V
esu. If e and m are chage and mass of an electron respectivelly, then the value of h/ (where  is wavelength
associated with electron wave) is given by : [JEE MAIN 2016]
SI
(A) 2meV (B) meV (C) 2meV (D) me V

20. P is the probability of finding the 1s electron of hydrogen atom in a spherical shell of infinitesimal thickness, dr,
at a distance r from the nucleus. The volume of this shell is 4r2dr. The qualitative sketch of the dependence of P on
O

r is
[JEE MAIN 2016]
O

P P

(A) (B)
ET

0 r 0 r

P P

(C) (D)

0 r 0 r
21. The radius of the second Bohr orbit for hydrogen atom is :
(Plank’s Const. h = 6.6262 × 10–34 Js ; mass of electron = 9.1091 × 10–31 kg; charge of electron e = 1.60210 × 10–19
C; permittivity of vaccum0 = 8.854185 × 10–12 kg–1 m–3A2) [JEE MAIN 2017]
(A) 1.65 Å (B) 4.76 Å (C) 0.529 Å (D) 2.12 Å

22. Among the following, the energy of 2s orbital is lowest in : [JEE MAIN 2019]
(A) K (B) Na (C) Li (D) H

www. e t o o s in d ia . c o m
9 Plo t No . 46 , In fro nt o f Skyline Apar tme nts, Cor ne r Building , Raje e v Gandhi ETOOSINDIA
Nagar, Kota, (Rajasthan) Pin co de : 324 00 5. India’s No.1 Online Coaching
Help Desk : 09214233303 | 09214233343 |
ETOOSINDIA
India’s No.1 Online Coaching ATOMIC STRUCTURE
23. The electrons are more likely to be found : [JEE MAIN 2019]

(A) in the region a and b (B) in the region a and c (C) only in the region c (D) only in the region a

24. Heat treatment of muscular pain involves radiation of wavelength of about 900 nm. Which spectral line of H-atom
is suitable for this purpose ? [RH = 1 × 105 cm–1, h = 6.6 × — 10–34 Js, c = 3 ×108 ms–1] [JEE MAIN 2019]
(A) Paschen, 5  3 (B) Paschen, Â Â3
(C) Lyman, Â Â 1 (D) Balmer, Â Â 2

IA
25. The de Broglie wavelength () associated with a photoelectron varies with the frequency () of the incident
radiation as, [0 is thrshold frequency] : [JEE MAIN 2019]
1 1 1 1
(A)   (B)   1 (C)   1
(D)  
3

D
(v  v 0 ) 2 4 (v  v0 )
(v  v 0 ) 2 (v  v 0 )
26. For any given series of spectral lines of atomic hydrogen, let v  vmax  vmin be the difference in maximum and

(A) 27 : 5 (B) 4 : 1
N
minimum frequencies in cm–1. The ratio v Lyman / v Balmer is :
(C) 5 : 4
[JEE MAIN 2019]
(D*) 9 : 4
SI
27. Which one of the following about an electron occupying the 1s orbital in a hydrogen atom is incorrect ? (The Bohr
radius is represented by a0) [JEE MAIN 2019]
(A) The electron can be found at a distance 2a0 from the nucleus
(B) The probability density of finding the electron is maximum at the nucleus.
(C) The magnitude of potential energy is double that of its kinetic energy on an average.
O
(D) The total energy of the electron is maximum when it is at a distance a0 from the nucleus.

28. The quantum number of four electrons are given below - [JEE MAIN 2019]
I. n = 4, l = 2, ml = –2, ms = – ½ II. n = 3, l = 2, ml = 1, ms = + ½
O

III. n = 4, l = 1, ml = 0, ms = + ½ IV. n = 3, l = 1, ml = 1, ms = –½
The correct order of their increasing energies will be -
(A) IV < III < II < I (B) IV < II < III < I (C) I < II < III < IV (D) I < III < II < IV
ET

29. If p is the momentum of the fastest electron ejected from a metal surface after the irradiation of light having
wavelength l, then for 1.5 p momentum of the photoelectron, the wavelength of the light should be:
(Assume kinetic energy of ejected photoelectron to be very high in comparison to work function)
[JEE MAIN 2019]
1 3 2 4
(A)  (B)  (C)  (D) 
2 4 3 9
30. The ratio of the shortest wavelength of two spectral series of hydrogen spectrum is found to be about 9. The
spectral series are: [JEE MAIN 2019]
(A) Paschen and P fund (B*) Lyman and Paschen (C) Brackett and Piund (D) Balmer and Brackett
31. The graph betweeen ||2 and r(radial distance) is shown below. This represents :- [JEE MAIN 2019]

(A) 3s orbital (B) 1s orbital (C) 2p orbital (D) 2s orbital

www. e t o o s in d ia . c o m
10 Plo t No . 46 , In fro nt o f Skyline Apar tme nts, Cor ne r Building , Raje e v Gandhi ETOOSINDIA
Nagar, Kota, (Rajasthan) Pin co de : 324 00 5. India’s No.1 Online Coaching
Help Desk : 09214233303 | 09214233343 |
ETOOSINDIA
India’s No.1 Online Coaching ATOMIC STRUCTURE
PART - II - PREVIOUS YEAR QUESTIONS (JEE ADVANCED)
1. The orbit having Bohr radius equal to 1st Bohr orbit of H–atom is [JEE 2004]
(A) n = 2 of He+ (B) n = 2 of B+4 (C) n = 3 of Li+2 (D) n = 2 of Be+3
2. (A) The wave function of an electron in 2s orbital in hydrogen atom is given below : [JEE 2004]
3/2
1  z   r 
2s =   2  
4( 2)1/ 2  
 a0 

 a 0  exp (– r/2a 0)
where a 0 is the Bohr radius. This wave function has a radial node at r = r 0. Express r 0 in terms of a 0.
(B) Calculate the wavelength of a ball of mass 100 g moving with a velocity of 100 ms –1.
–8 
(C) 238   Y. Find out atomic number, mass number of Y and identify it.
92X – 6

3. (A) Using Bohr’s model for hydrogen atom, find the speed of electron in the first orbit if the Bohr’s radius is
a0 = 0.529 × 10–10 m. Find deBroglie wavelength of the electron also. [JEE
2005]

IA
h
(B) Find the orbital angular momentum of electron if it is in 2p orbital of H in terms of .
2
4. According to Bohr’s theory,
En = Total energy , Kn = Kinetic energy

D
Vn = Potential energy, rn = Radius of nth orbit
Match the following: [JEE 2006]
Column I Column II
(A) Vn / Kn = ?
(B) If radius of nth orbit  Enx , x = ?
(C) Angular momentum in lowest orbital
N (p) 0
(q) – 1
(r) – 2
SI
1
(D)  Zy , y  ? (s) 1
rn
The hydrogen-like species Li2+ is in a spherically symmetric state S1 with one radial node. Upon absorbing light the
O

ion undergoes transition to a state S2. The state S2 has one radial node and its energy is equal to the ground state
energy of the hydrogen atom.
5. The state S1 is : [JEE 2010]
O

(A) 1s (B) 2s (C) 2p (D) 3s

6. Energy of the state S1 in units of the hydrogen atom ground state energy is : [JEE 2010]
(A) 0.75 (B) 1.50 (C) 2.25 (D) 4.50
ET

7. The orbital angular momentum quantum number of the state S2 is : [JEE 2010]
(A) 0 (B) 1 (C) 2 (D) 3
8. The work function () of some metals is listed below. The number of metals which will show photoelectric effect
when light of 300 nm wavelength falls on the metal is [JEE 2011]
Metal Li Na K Mg Cu Ag Fe Pt W
 (eV) 2.4 2.3 2.2 3.7 4.8 4.3 4.7 6.3 4.75
9. The maximum number of electrons that can have principal quantum number, n = 3, and spin quantum number,
ms = –1/2, is [JEE 2011]
10. The kinetic energy of an electron in the second Bohr orbit of a hydrogen atom is [a0 is Bohr radius] : [JEE 2012]

h2 h2 h2 h2
(A) 4 2ma 2 (B) 16 2ma2 (C) 322ma2 (D) 64 2ma2
0 0 0 0

www. e t o o s in d ia . c o m
11 Plo t No . 46 , In fro nt o f Skyline Apar tme nts, Cor ne r Building , Raje e v Gandhi ETOOSINDIA
Nagar, Kota, (Rajasthan) Pin co de : 324 00 5. India’s No.1 Online Coaching
Help Desk : 09214233303 | 09214233343 |
ETOOSINDIA
India’s No.1 Online Coaching ATOMIC STRUCTURE
11. Bombardment of aluminum by -particle leads to its artificial disintegration in two ways, (I) and (ii) as shown.
Products X, Y and Z respectively are,

[JEE 2011]

(A) proton, neutron, positron (B) neutron, positron, proton

(C) proton, positron, neutron (D) positron, proton, neutron
12. The periodic table consists of 18 groups. An isotope of copper, on bombardment with protons, undergoes a nuclear
reaction yielding element X as shown below. To which group, element X belongs in the periodic table?
63 1
29 Cu 1 H  610 n    211H  X [JEE 2012]

IA
13. In an atom, the total number of electrons having quantum numbers n = 4, | m | = 1 and ms = – 1/2 is [JEE 2014]
14. Not considering the electronic spin, the degeneracy of the second excited state (n=3) of H atom is 9, while the
degeneracy of the second excited state of H– is [JEE 2015]
Answer Q.15 to Q.17 by appropiately matching the information given in the three columns of the following table.

D
The wave function,  n,l ,m1 is a mathematical function whose value depends upon spherical polar coordinates
(r, ) of the electron and characterized by the quantum numbers n, l and m1. Here r is distance from nucleus,  is

Column 2 Column 3
N
colatitude and  is azimuth. In the mathematical functions given in the Table, Z is atomic number a0 is Bohr radius.
Column I [JEE 2017]
SI
n,l,m1(r)

3
 Zr 
 Z  2  a 
(I) 1s orbital (i)  n,l,m1   e  0 (P)
 a0 
O
0
r/a0

1
(II) 2s orbital (ii) One radical node (Q) nucleus per probability density 
O

a 30
5
 Zr 
 Z  2  2a 
(iii)  n,l,m1    re  0  cos 
ET

(IIII) 2pz orbital (R) nucleus per probability density is maximum

 a0 
(IV) 3dz2 orbital (iv) xy-plane is a nodal plane (S) Energy needed to excite electron from n = 2
state to n = 4
27
state is times the energy needed to excite
32
electron from n = 2 state to n = 6 state
15. For He+ ion, the only INCORRECT combination is
(A) (I) (i) (S) (B) (II) (ii) (Q) (C) (I) (iii) (R) (D) (I) (i) (R)
16. For the given orbital in Column I, the only CORRECT combination for any hydrogen - like species is
(A) (II) (ii) (P) (B) (I) (ii) (S) (C) (IV) (iv) (R) (D) (III) (iii) (P)
17. For hydrogen atom, the only CORRECT combination is
(A) (I) (i) (P) (B) (I) (iv) (R) (C) (II) (i) (Q) (D) (I) (i) (S)

www. e t o o s in d ia . c o m
12 Plo t No . 46 , In fro nt o f Skyline Apar tme nts, Cor ne r Building , Raje e v Gandhi ETOOSINDIA
Nagar, Kota, (Rajasthan) Pin co de : 324 00 5. India’s No.1 Online Coaching
Help Desk : 09214233303 | 09214233343 |
ETOOSINDIA
India’s No.1 Online Coaching ATOMIC STRUCTURE
18. The ground state energy of hydrogen atom is –13.6 eV. Consider an electronic state  of He+ whose energy,
azimuthal quantum number and magnetic quantum number are –3.4 eV, 2 and 0 respectively. Which of the following
statement(s) is(are) true for the state ? [JEE 2019]
(A) It has 2 angular nodes
(B) It has 3 radial nodes
(C) It is a 4d state
(D) The nuclear charge experienced by the electron in this state is less than 2e, where e is the magnitude of the
electronic charge.

19. Answer the following by appropriately matching the lists based on the information given in the paragraph“Consider
the Bohr's model of a one-electron atom where the electron moves around the nucleus. In the following List-I
contains some quantities for the nth orbit of the atom and List-II contains options showing how they depend on n.
List-I List-II
(I) Radius of the nth orbit (P)  n–2

IA
(II) Angular momentum of the electron in the nth orbit (Q)  n–1
(III) Kinetic energy of the electron in the nth orbit (R)  n0
(IV) Potential energy of the electron in the nth orbit (S)  n1
(T)  n2
(R)  n½

D
Which of the following options has the correct combination considering List-I and List-II? [JEE 2019]
(A) (II), (R) (B) (I), (P) (C) (I), (T) (D) (II), (Q)

20.
N
Answer the following by appropriately matching the lists based on the information given in the paragraph“Consider
the Bohr's model of a one-electron atom where the electron moves around the nucleus. In the following List-I
contains some quantities for the nth orbit of the atom and List-II contains options showing how they depend on n.
SI
List-I List-II
(I) Radius of the nth orbit (P)  n–2
(II) Angular momentum of the electron in the nth orbit (Q)  n–1
O

(III) Kinetic energy of the electron in the nth orbit (R)  n0

(IV) Potential energy of the electron in the nth orbit (S)  n1
(T)  n2
O

(R)  n½
Which of the following options has the correct combination considering List-I and List-II ? [JEE 2019]
(A) (III), (S) (B) (IV), (Q) (C) (IV), (U) (D) (III), (P)
ET

www. e t o o s in d ia . c o m
13 Plo t No . 46 , In fro nt o f Skyline Apar tme nts, Cor ne r Building , Raje e v Gandhi ETOOSINDIA
Nagar, Kota, (Rajasthan) Pin co de : 324 00 5. India’s No.1 Online Coaching
Help Desk : 09214233303 | 09214233343 |
ETOOSINDIA
India’s No.1 Online Coaching ATOMIC STRUCTURE
ANSWER KEY

EXERCISE - 1
1. D 2. D 3. D 4. D 5. B 6. B 7. A
8. B 9. B 10. D 11. A 12. A 13. B 14. C
15. B 16. B 17. B 18. B 19. C 20. A 21. B
22. A 23. C 24. A 25. D 26. C 27. C 28. B
29. C 30. D 31. B 32. C 33. B 34. D 35. B
36. C 38. D 39. C 40. B 41. A 42. C 43. B
44. D 45. A 46. A 47. D 48. C 49. A 50. A
51. D 52. A 53. B 54. B

IA
EXERCISE - 2 : PART # I
1. A 2. C 3. B 4. A 5. A 6. C 7. D

D
8. A 9. A 10. D 11. C 12. D 13. B 14. C
15. A 16. B 17. C 18. A 19. C 20. C 21. D
22. A 23. B 24. B 25. B 26. D 27. D 28. B
29. D 30. B 31. D

PART # II N
SI
1. D 2. (a) r = 2a0 (b)  = 6.66 × 10–25 Å (c) 82Y206 ; (Atomic no. 82, Mass no. 206)

 h 
3. (a) 2.18 × 106 m/s, 3.2 × 10–10 m ; (b) 2   4. [A – r]; [B – q]; [C – p] ; [D – s]
 2 
O

5. B 6. C 7. B 8. 4 9. 9 10. C 11. A
12. 8 13. 6 14. 5 15. C 16. A 17. D 18. A,C
O

19. C 20. D
ET

www. e t o o s in d ia . c o m
14 Plo t No . 46 , In fro nt o f Skyline Apar tme nts, Cor ne r Building , Raje e v Gandhi ETOOSINDIA
Nagar, Kota, (Rajasthan) Pin co de : 324 00 5. India’s No.1 Online Coaching
Help Desk : 09214233303 | 09214233343 |