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Inorganic Assignment PDF

The document contains an assignment with questions about writing IUPAC names and structural formulas of coordination compounds. It includes 10 coordination compounds with their IUPAC names to write the structural formula for, and 5 compounds with their names to write the structural formulas. The compounds contain common transition metal ions like chromium, iron, cobalt, nickel, and platinum complexed with ligands like chloride, ammonia, carbonyl, and thiocyanate.

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250 views

Inorganic Assignment PDF

The document contains an assignment with questions about writing IUPAC names and structural formulas of coordination compounds. It includes 10 coordination compounds with their IUPAC names to write the structural formula for, and 5 compounds with their names to write the structural formulas. The compounds contain common transition metal ions like chromium, iron, cobalt, nickel, and platinum complexed with ligands like chloride, ammonia, carbonyl, and thiocyanate.

Uploaded by

Sneha Mahar
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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B.Sc.

(Life Science) Semester V

Inorganic Chemistry.
Dharmendra Shishodia

Assignment 1.
ZO-668

Marks 15

Question: Write the IUPAC names of the coordination compounds with structural formula given below:

1.[Cr(en)3]Cl3

Tris(ethane-1,2-diamine)chromium(III) chlorido

2. [Fe(C5H5)2]

Bis(cyclopentadienyl)iron(II)

3. [(CO)3Fe(CO)3Fe(CO)3]

Tri-μ-carbonylbis-[tricabonyliron(0)]

4. [Pt(NH3)4Cl2][PtCl4]

Tetraamminedichloridoplatinum(IV) tetrachloridoplatinate(II)

5. [Co(CO)4]-

Tetracarbonylcobaltate(I) ion

6. [Co(en)2Cl(SCN)]NO2

Chloridobis(ethane-1,2-diamine)thiocyanato-S-cobalt(III) nitrite

7. [(NH3)4Co(NH2)(NO2)Co(NH3)4]4+

μ-Amido-μ-nitrobis[tetraamminecobalt(III)] ion

8. NH4 [Cr((NCS)4(NH3)2]

Ammonium diamminetetrathiocyanato-N-chromate(III)

9. [Ni(CO)2(PPh3)2]

Dicarbonylbistriphenylphosphinenickel(0)

10. K2[Cr(NCS)2(CN)3(H2O)]

Potassium aquatricynido-C-dithiocyanato-N-chromate(III)

Question: Write the structural formula of the complexes whose IUPAC names are given below:
1.Diamidotetraamminecobalt(III) ethanoate

[Co(NH2)2(NH3)4]OOCCH3

2. Ammonium pentafluoridoaquanickelate(II)

(NH4)3[Ni(F)5(H2O)]

3. Hexathiocyanato-N-chromate(III) ion

[Cr(NCS)6]3-

4. μ-Amido-μ-nitritobis{tetraamminecobalt(III)} nitrate

[(NH3)4Co(NH2)(ONO)Co(NH3)4](NO3)4

5. Tetraamminedichloridoplatinum(IV) tetrachloridoplatinate(II)

[Pt(NH3)4Cl2][PtCl4]

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