George Sidebotham (Auth.) - Heat Transfer Modeling - An Inductive Approach-Springer International Publishing (2015) PDF
George Sidebotham (Auth.) - Heat Transfer Modeling - An Inductive Approach-Springer International Publishing (2015) PDF
Sidebotham
Heat
Transfer
Modeling
An Inductive Approach
Heat Transfer Modeling
George Sidebotham
vii
viii Preface
meantime, put on a sweater.” An hour later, the house is toasty. But in my head,
I might say “You’re right. There is technically no heat in this house. But the air
temperature is sufficiently low relative to your body temperature that the rate at
which you are losing heat is uncomfortable to you. Turning up the thermostat will
send a signal for a fuel valve to open and a spark to ignite a flame in the boiler,
where chemical energy will be converted to thermal energy. Then heat will be
transferred from the hot gases to the water in the boiler, which will create steam that
will flow into the radiators (which should be called convector/radiators) throughout
the house. Then heat will be transferred to the air in the room, raising its internal
energy, and thereby the air temperature to the new set point.” I guess it’s easier to
just say “There’s no heat in this house.”
Modeling involves the creation of a simplified view of a complex system.
In general, mathematical modeling (of anything, not just heat) involves two main
steps: model development and its subsequent solution. They are not always purely
sequential, and feedback from one to the other and an iterative solution is usually
required for a good engineering solution. Modeling becomes a design tool when
that solution leads to a decision that addresses the original problem statement, such
as “what material and what dimensions should that heat sink be to keep the
motherboard from overheating?”
Model development involves a derivation of governing equations from the
application of fundamental laws of nature to a defined system, a specific limited
portion of the universe. The art of this stage of modeling is to choose clear system
boundaries and to make simplifying assumptions that ease the subsequent solution,
while still capturing the “controlling physics.” Frequently, complex systems are
controlled by a simple balance between two or three “things.” A determination of
the extent to which that model captures reality is context-specific and a major part
of engineering decision-making. Creation of the model is not the end, it is the start.
The input is a word problem statement, and the output is a mathematical problem
statement.
The next step is to solve the mathematical problem. This step can be trivial, easy,
hard, or impossible, and there may be multiple approaches. It is good design to invoke
a feedback response, a return to the model development with an eye toward either
making additional simplifications or relaxing others, and ultimately arrive at a
solution that is deemed adequate to address the original word statement. It is common
to lose sight of the original problem statement once a detailed analysis is initiated.
The approach of this book is to start with a word problem statement (often with
specific parameter values) and to develop A modeling strategy in detail. Not THE
modeling strategy. A patient and resourceful reader will develop alternative models
to the same initial problem statement, solve those, and then compare (qualitatively
and quantitatively) to the examples given in this text.
Once they are implemented (and generally not before), models can be tested and
then defined as being simple, simplistic, or complex. The testing criterion depends
on the problem at hand and may involve comparison with experiment, parametric
study (observe the effect of various parameters), or testing assumptions after the
fact. Generally, a simple model is most desirable. It does the job with the least effort
x Preface
NOTE TO STUDENTS
This book is written for you. My hope is that many of you will gain confidence and
apply the techniques developed here to situations that you define. You can have fun
and challenge yourself at the same time.
NOTE TO INSTRUCTORS
My challenge to you is to draw from your experience and apply it using principles
developed in this text. If you have taught Heat Transfer many times before, maybe
you will see some things in a new light. The only missing technical element is the
case of thermal radiation between opaque surfaces, which I never really can get to
in a first course. I do emphasize radiation concepts throughout, however. My advice
is to create in-class and homework-based group activities that use numerical
methods early, even before students may have reached those topics in a straight
reading of the text.
1 Thermal Circuits . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
1.1 RC Circuit Driven by a Temperature Source . . . . . . . . . . . . . . 3
1.2 RC Circuit Driven by a Current Source . . . . . . . . . . . . . . . . . . 9
1.3 RC Circuit Driven by Multiple Sources . . . . . . . . . . . . . . . . . . 10
1.4 Resistors in Series . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
1.5 Resistors in Parallel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15
1.6 Iterative Solution Methods . . . . . . . . . . . . . . . . . . . . . . . . . . . 17
1.7 Numerical Solution 1: Forward Explicit Formulation
(Euler Method) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18
1.7.1 Variable Step Size Explicit Methods . . . . . . . . . . . . . . 19
1.8 Numerical Solution 2: Backward Implicit formulation . . . . . . . 20
1.9 Numerical Solution 3: Central Implicit formulation
(Crank–Nicolson Method) . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21
Workshop 1.1: Numerical Solution of First-Order RC Circuit . . . . . . . 22
Workshop 1.2: Numerical Solution of RC Circuit
with Time Varying Ambient Temperature . . . . . . . . . . . . . . . . . . . . . 28
2 Lumped Capacity Systems and Overall Heat
Transfer Coefficients . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31
2.1 A Cooling Mug of Coffee . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32
2.1.1 Problem Statement . . . . . . . . . . . . . . . . . . . . . . . . . . . 32
2.1.2 Experimental Solution . . . . . . . . . . . . . . . . . . . . . . . . 32
2.2 Lumped Capacity Model Development . . . . . . . . . . . . . . . . . . 36
2.2.1 Conservation of Energy . . . . . . . . . . . . . . . . . . . . . . . 36
2.2.2 Lumping the Stored Energy into a Single Node . . . . . . 37
2.2.3 Thermodynamic Analysis of Mug Heating Phase . . . . . 39
2.2.4 1-Node Lumped Capacity Model . . . . . . . . . . . . . . . . 41
2.2.5 Overall Heat Transfer Coefficient:
Empirical Value . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 42
2.3 A Melting Cup of Ice/Water . . . . . . . . . . . . . . . . . . . . . . . . . . 47
2.3.1 Problem Statement . . . . . . . . . . . . . . . . . . . . . . . . . . . 47
2.3.2 Experimental Solution . . . . . . . . . . . . . . . . . . . . . . . . 48
xiii
xiv Contents
This introductory chapter develops the concept of a thermal circuit and analytical
and numerical methods used to analyze simple circuits. Subsequent chapters will
apply and build on them using heat transfer examples from common experience.
Table 1.1 introduces key elements, namely, resistors, capacitors, batteries, and
current sources. Resistive/capacitive (RC) network diagrams are used as modeling
tools to visualize the flow of heat, an abstract massless quantity. Hence, the term
“thermal circuit.” The focus of this book is to develop heat transfer modeling as a
design tool, rather than as a pure science. The principles apply to other areas in
engineering (and life) practice. Specific tools are developed in this textbook that
pertain to heat transfer phenomena, most of which can be captured in thermal
circuits.
The discharge of a capacitor through a resistor is modeled by the circuit of Fig. 1.1.
This circuit is a model for the heating or cooling of an object placed suddenly into
an environment at a different temperature, like a hot mug of coffee placed on a
table, or a warm beverage placed in a refrigerator.
An electrical capacitor stores electrical charge (Q) on two plates. The capaci-
tance (C) relates stored charge to voltage between the plates (Q ¼ C(V Vref),
where Vref is a reference voltage, typically ground). A thermal capacitor stores
thermal energy. For systems that do not experience phase change or chemical
(or nuclear) reactions, the thermal capacitance relates the stored energy to the
temperature (E ¼ C(T Tref)), where the stored energy is set to zero at some
reference temperature, Tref. An electrical resistor provides a pathway for charge
to flow, driven by a voltage difference across it. The larger the resistance value, the
larger the voltage difference required to move a given quantity of charge. Thermal
resistors provide a pathway for heat to flow, heat being a specific form of energy
that crosses a system boundary, driven by a temperature difference.
Table 1.1 Circuit components and associated units in electrical and thermal applications
Component Symbol Electrical SI unit Thermal SI unit
Resistor Ohm C
Watt
Capacitor Farad Joule
C
Battery Volt C
In this text, a large filled “node” is generally used to indicate a temperature value
that is fixed by a battery of known temperature (which may change with time in a
prescribed way). The battery symbol will generally not be shown. For transient
problems, an open “node” is one to which thermal capacitance is assigned, while
small filled symbols (none in this case) indicate nodal temperatures that can be
determined based on neighboring capacitive-carrying and fixed nodal temperatures.
The fundamental law of nature governing this case is the conservation of charge
for the electrical case (the net flux of current into a node is zero: Kirchhoff’s current
law) and the First Law of Thermodynamics for the thermal case (developed
formally in the next chapter). Figure 1.2 shows the circuit after the starting point,
with current (q, with units of energy per unit time in the thermal case) assumed to
flow into the node from both the capacitor and the resistor.
Mathematically, this charge balance, or Kirchhoff’s current law, is:
qR þ qC ¼ 0
The current through the resistor is related to the voltage (T) by Ohm’s law, namely:
ðT 1 T Þ
qR
R
The current is driven by the voltage difference across the resistor. The larger the
resistance, the lower the current. The (perhaps) familiar equation V ¼ IR is Ohm’s
Law, written in the form here of I ¼ V/R, which is really an unfortunate misrepre-
sentation of the relationship between voltage and current across a resistor. It should
be ΔV ¼ IR, where ΔV is the voltage difference across the resistor, not the absolute
value of the voltage at one specific point.
To establish the relationship between capacitor voltage and charge, consider an
event of time duration Δt, during which time a quantity of charge, Qexit, flows out.
Conservation of charge stated in words is:
dQ
qc
dt
The total charge stored in the capacitor is related to the temperature by:
Q C T T ref
Taking the derivative and assuming the capacitance does not change with time:
dQ dT
C
dt dt
The conservation of charge applied to a thermal capacitor is therefore:
dT
C ¼ qc
dt
Care has been taken in defining the signs. For the capacitor, a positive qc represents
current leaving the capacitor (and entering the node) which results in a decrease in
temperature, accounted for by the negative sign. For heat to flow into the resistor,
the temperature difference is expressed as that of the neighbor (T1) subtracted from
the capacity-carrying nodal value (T). If that nodal temperature is higher than its
neighbor, this term will have a negative value.
Inserting these component laws into the charge balance yields the governing
first-order ordinary differential equation (ODE) for the circuit:
dT ðT 1 T Þ
C þ ¼0
dt R
with an initial condition T ð0Þ ¼ T 0 .
This governing equation (and its initial condition) is the result of the model, yet
it is not the solution to the problem. Some calculus (and the assumptions that R, C,
and T1 are constant) is needed to solve it.
It is not necessary, but can be helpful, to define a dimensionless variable for
temperature that starts at a value of 1 and approaches a value of 0 at equilibrium
(when T ¼ Teq).
1.1 RC Circuit Driven by a Temperature Source 7
T T eq
θ
T 0 T eq
Since R and C are finite, the equilibrium temperature is therefore equal to the source
T1. For more complicated circuits, it may be more difficult to solve for an
equilibrium value.
A dimensionless time can be defined by normalizing the time by a characteristic
time constant (τ*), whose value will be determined shortly:
t
^t
t*
Inserting these variables into the governing ODE and rearranging:
C d T eq þ T 0 T eq θ T 1 T eq þ T 0 T eq θ
þ ¼0
t* d^t R
Since Teq is constant, its time derivative is zero, and T eq ¼ T 0 so the governing
differential equation becomes:
dθ t*
þ θ¼0
^
dt RC
t* RC
The values of R and C have been assumed to be constant (technically, their product
is constant). There are situations where R and/or C may vary with time, and
therefore this model would not apply.
The governing equation becomes devoid of all parameters:
dθ
þθ ¼0
d^t
with initial condition θð0Þ ¼ 1.
In a first-order system (i.e., governed by a linear first-order differential equa-
tion), the rate of change of some quantity is proportional to the negative of itself.
The solution to this linear first-order differential equation, plotted in Fig. 1.3, is
^
θ ¼ e t
8 1 Thermal Circuits
T T1 t
¼ eRC
T0 T1
Alternatively, this equation can be expressed in terms of the time by taking the
natural logarithm of both sides and rearranging:
T T1
t ¼ RC ln
T0 T1
Example
Q: How much time is needed for the temperature to drop from an initial value of
100 C to a final value of 70 C, given that the ambient (T1) is at 25 C and the
time constant RC has a value of 1.613 h?
h i 7025
A: time ¼ RC ln TTT 1
0 T 1
¼ 1:613 ln 10025 ¼ 0:819 h
In this case, the dimensionless temperature has a value of 0.6, and, referring to
Fig. 1.3, the corresponding dimensionless time is approximately ½.
To generalize, in one time constant, the dimensionless temperature drops to
within 1/e ¼ 0.368 of its initial value, or it is about 2/3 of the way to equilibrium.
After two time constants, it is close to 10 % of its equilibrium value. A value of
5 time constants is a generally accepted value to indicate that equilibrium has been
reached, for most engineering purposes.
1.2 RC Circuit Driven by a Current Source 9
Figure 1.4 shows an RC circuit driven by a current (heat) source. This circuit is a
model for an object, initially at equilibrium with its environment, suddenly exposed
to a radiant heat source, like parking a car in the sun.
In contrast to a voltage source (battery) which fixes the voltage regardless of the
current flow in (or out), a current source fixes the current (heat transfer rate)
regardless of the voltage (temperature). Initially, with the switch open, the voltage
(T) is at the fixed value T1 (fixed by a battery, not shown, but implied by the filled
symbol). At some initial time, the switch is held closed, and current from the source,
Q_ ¼ qs as indicated, flows steadily into the node. Current sources in thermal
systems can include chemical reactions, certain forms of radiation (i.e., solar
radiation) or dissipation of electrical energy.
Kirchhoff’s current law for this circuit is:
q S þ qR þ qC ¼ 0
T1 T dT
Q_ þ C ¼0
R dt
with an initial condition T(0) ¼ T1.
As before, a dimensionless temperature can be defined that starts at an initial
value of unity, and is driven toward an equilibrium value:
T T eq
θ
T 0 T eq
The equilibrium value is obtained by setting the time derivative equal to zero:
dT T 1 T eq
C ¼ þ Q_ ¼ 0
dt eq R
T eq ¼ T 1 þ RQ_
R and Q_ are inherently positive quantities, and therefore the equilibrium tempera-
ture is above ambient. A dimensionless time can be defined by normalizing the time
by a characteristic time (t*), whose value will be determined shortly:
t
^t
t*
Inserting these variables into the governing equation and rearranging:
C T 0 T eq dθ T T T T θ
¼ Q_ þ
1 eq 0 eq
¼0
t* d^t R R
The term in brackets is identically zero from the definition of the equilibrium
temperature, and therefore, upon further rearrangement:
dθ t*
þ θ¼0
d^t RC
t* RC
dθ
þθ ¼0
d^t
with initial condition θð0Þ ¼ 1.
This governing equation is exactly the same as for the voltage source. The only
difference is in the value of the equilibrium temperature. The underlying physics of
a voltage source and current source are very different, however.
Figure 1.5 shows an RC circuit in which a node (at T) is driven by a current source
and two separate voltage sources (at T1 and T2, with resistance R1 and R2).
Kirchhoff’s current law for this circuit is:
qS þ qR1 þ qR2 þ qC ¼ 0
1.3 RC Circuit Driven by Multiple Sources 11
T1 T T2 T dT
Q_ þ þ C ¼0
R1 R2 dt
with an initial condition T(0) ¼ T0, where T0 can be taken to be any initial
temperature. If, as suggested by Fig. 1.5, the switch is initially open for a suffi-
ciently long time prior to closing, the initial temperature will be between T1 and T2.
Precisely where depends on the relative values of R1 and R2, as will be clear in the
next section.
A general form of Kirchhoff’s current law for a node “i” in thermal contact with
multiple neighbors “j” and a current source is:
dT i X Tj Ti
Ci ¼ Q_ i þ
dt j
Rij
where Rij is the thermal resistance between node “i” and “j”. As before, a dimen-
sionless temperature can be defined that starts at an initial value of unity, and is
driven toward an equilibrium value:
T T eq
θ
T 0 T eq
The equilibrium value is obtained by setting the time derivative equal to zero:
dT _ T 1 T eq T 2 T eq
C ¼Qþ þ ¼0
dt eq R1 R2
12 1 Thermal Circuits
T1 T2
Q_ þ þ
R1 R2
T eq ¼
1 1
þ
R1 R 2
A general form of the equilibrium temperature for a node “i” in thermal contact
with multiple neighbors “j” and a current source is:
X Tj
Q_ i þ
j
Rij
T i, eq ¼ X 1
j
Rij
t
^t
t*
Inserting these variables into the governing equation and rearranging:
C T 0 T eq dθ _ T 1 T eq T 2 T eq 1 1
¼ Qþ þ þ T 0 T eq θ ¼ 0
t* d^t R1 R2 R 1 R2
The term in brackets is identically zero from the definition of the equilibrium
temperature, and therefore, upon further rearrangement:
dθ t* 1 1
þ þ θ¼0
d^t C R 1 R2
C
t*
1 1
þ
R1 R2
1 1 1
¼ þ
R R1 R2
1.4 Resistors in Series 13
Then
t* RC
Notice that the time constant does not involve the current source. The governing
equation becomes:
dθ
þθ ¼0
d^t
In heat transfer, adding layers of insulation adds thermal resistance in series. For
example, putting on a sweater introduces an additional barrier to heat flow from the
torso and arms to the environment. Figure 1.6 shows a simple circuit, called a
voltage divider, in which two resistors are wired in series, separated by two
temperature sources (batteries).
An equivalent circuit with a single resistor (R) between the two batteries is also
shown. The relationship between R and the individual resistors R1 and R2 is sought.
There is only one channel for current to flow from T1 to T2 (if T1 is greater than
T2, otherwise the direction is reversed). Conservation of charge dictates that the
current flowing through both resistors must be the same.
For the equivalent circuit, the current through the equivalent resistor (R) must
equal the current entering R1, consistent with the directions of the arrows. That is,
for resistors added in series:
q12 ¼ qR1 ¼ qR2
where q12 represents the current from T1 to T2. Inserting the component laws for R1
and R2 separately, making the signs consistent with Fig. 1.6:
T1 T
qR1 ¼ q12 ¼
R1
Fig. 1.6 A channel with two resistors in series, and the equivalent circuit
14 1 Thermal Circuits
T T2
qR2 ¼ q12 ¼
R2
Expressing these equations in terms of the intermediate temperature (T) between
the two resistors:
T ¼ T 1 R1 q12
T ¼ T 2 þ R2 q12
0 ¼ T 1 T 2 ðR1 þ R2 Þq12
T1 T2
q12 ¼
R1 þ R2
For the equivalent circuit:
T1 T2
q12 ¼
R
The equivalent resistance is therefore:
R ¼ R1 þ R 2
The equivalent resistance of resistors in series is the sum of the resistances. The
currents are equal through the resistors. The intermediate temperature can be
expressed in a number of ways. Rearranging for the intermediate temperature
three different (but equivalent) ways:
T1 T2
þ
R R2
T¼ 1
1 1
þ
R1 R2
R1
T ¼ T1 ðT 1 T 2 Þ
R1 þ R2
R2
T ¼ T2 þ ðT 1 T 2 Þ
R1 þ R2
Adding resistors in series impedes current flow. The voltage in between the two
resistors is intermediate. If the resistors are equal in value, the intermediate temper-
ature will be halfway between T1 and T2. If R1 is greater than R2, a larger voltage
drop will be required across R1 than across R2, and the intermediate temperature
will be closer to T2 than to T1.
1.5 Resistors in Parallel 15
T 1 T 2 100 25
q12 ¼ ¼ ¼ 1:875 W
R1 þ R 2 10 þ 30
(c) The intermediate temperature is
R1 10
T ¼ T1 ðT 1 T 2 Þ ¼ 100 ð100 25Þ ¼ 81:25 C
R1 þ R2 10 þ 30
In winter, heat loss through an exterior wall takes places across its windows and the
remainder of the wall simultaneously. The rate of heat loss through the windows is
different than that through the solid wall, even though the air temperatures are the
same inside and outside. The total heat loss across the wall is the sum of these two
“thermal channels,” and these channels act in parallel.
Figure 1.7 shows two resistors wired in parallel between two batteries, and an
equivalent circuit with a single resistor, whose relationship to R1 and R2 is sought.
Unlike the series circuit, there are two distinct channels through which current can
flow. In a heat transfer application, heat lost through a wall of a building takes place
through two parallel channels, through the windows and through the remainder of
the walls.
A nodal balance at either side of the circuit states that the total current entering
(or leaving) the circuit is the sum of the currents flowing through each resistor, and
the voltage drop is the same across both resistors:
T1 T2 T1 T2 T1 T2
¼ þ
R R1 R2
16 1 Thermal Circuits
Fig. 1.7 RC channel with two resistors in parallel, and the equivalent circuit
1 1 1
¼ þ
R R1 R2
1
R¼ 1
R1 þ R12
or
R1 R2
R¼
R1 þ R2
The equivalent resistance is less than the smaller of the two resistances. In heat
transfer, heat flows through a wall in a house through parallel channels, i.e., across
solid walls and across windows. The inside and outside temperatures are the same
for windows and solid walls, and the total heat transfer rate is the sum of the heat
through these parallel channels.
R1 R2 ð10Þð30Þ
R¼ ¼ ¼ 7:5 C=W
R 1 þ R2 10 þ 30
1.6 Iterative Solution Methods 17
The resistance is less than the smaller of the two, while the resistance of the
series circuit was 40 Ω, greater than the larger of the two.
(b) The current is
T 1 T 2 ð100 25Þ C
q12 ¼ ¼ ¼ 10 W
R 7:5 C=W
This current is much larger than the 1.875 W for the series circuit.
Iterative procedures are quite common in heat transfer applications. There are
formal methods that will be introduced for specific types of problems, and iterative
procedures can by “invented” as needed to solve problems for which a direct
solution is not possible. You’ll see.
There is a fundamental difference between an iterative and predictive method. In
an iterative method, guesses are made, based on feedback, and hopefully the
algorithm works in the sense that the desired final solution is obtained. The
“trajectory” of the guessed solutions is really not important. It is the final result
that matters. In a predictive method, each step in time is a prediction of what the
actual temperature is. The prediction of the temperature after a finite time step is not
a “guess,” it is a simulation based on the model. Some important predictive
numerical methods are introduced next.
A few techniques for solving transient problems numerically are introduced in this
introductory chapter, using the basic first-order system to demonstrate the pros and
cons of each method, namely,
dT ðT 1 T Þ
¼
dt RC
Initial Condition : T ð 0Þ ¼ T 0
with initial condition T ð0Þ ¼ T 0 . In effect, this method extrapolates the slope
forward into time by a finite step (the numerical parameter Δt), without any
adjustments during that step. Notice that in the limit of Δt going to zero, the
Euler method becomes the definition of the first derivative.
The unit of the RC combination is time, and is a characteristic time constant of
the problem. Engineering decisions can often be made knowing no more than that.
This Euler method is called an “explicit” method because the future predicted
value is expressed explicitly in terms of present values, which are known, starting
with the initial condition. Such will also be true for more complicated models (with
more than one unknown nodal temperature). It is easy, and somewhat intuitive, to
implement, and is very powerful. It can run into problems as systems become more
complex, but a legitimate strategy is to implement the method, and if it fails to
produce acceptable results, it can dictate an appropriate “Plan B.”
“If you know the present, you can tell the future.” Of course, you only ever know
so much of the present.
The step size (Δt) is a numerical parameter. It is relatively easy to incorporate logic
that calculates a new value for the step size at every step. Three variations of this
method are:
ΔtðpÞ ¼ Δt
This method seems to be the most obvious and is recommended as the methods are
being learned, yet it can have its drawbacks in practice. The change in the indepen-
dent variable is held constant in this method.
T ðpþ1Þ T ðpÞ ¼ ΔT
This method works well if it is known that the temperature change will monotoni-
cally change from beginning to end, which is often the case in heat transfer. The
step size at each step is given by:
20 1 Thermal Circuits
RðpÞ CðpÞ ΔT
ΔtðpÞ ¼
T ð1pÞ T ðpÞ
Absolute values are needed to guarantee a positive step size. For the RC circuit
studied for now, R and C are constants, and the equilibrium value for T is T1,
making the temperature ratio equal to unity. Therefore, this method will result in a
fixed step size for this case, but not in general.
Also, this method works best, conceptually, for dependent variables that are
inherently positive, like absolute temperature, as opposed to temperature expressed
in Celsius. For example, a 1 C change in a temperature of 100 C is a 1 % change,
whereas the same 1 C change in a temperature of 10 C is a 10 % change. What if
the temperature were 0 C? or 10 C?
“The present is a result of the past.” But we want to predict the future! Let the
past become the present, and the present the future by updating “p” to “p + 1”;
RC ðpÞ
T1 þ T
Δt
T ðpþ1Þ ¼
RC
1þ
Δt
It is not clear why this method is called an implicit method in this “1-node” example
because the future predicted value (p + 1) is expressed explicitly in terms of present
values (p). That will not be true for more complicated models (with more than one
unknown nodal temperature).
This method is introduced here, but it is not recommended that it be used in heat
transfer applications, because it violates the Second Law of Thermodynamics for
large step sizes, whereas the backward method yields correct equilibrium values.
There are other applications in numerical analysis for which the improved accuracy
of this method are advantageous.
Express the derivative in the governing equation as a central finite difference
approximation by taking a half finite step in time (Δt/2), and introduce a superscript
to represent time as p 1/2 (past) or p + 1/2 (future). There is no present, yet. . .
¼
Δt RC
There are three times depicted, past, present and future. To reduce that to two,
approximate the present as the average of the past and future:
T ðpþ 2 Þ þ T ðp 2 Þ
1= 1=
Tð pþ =2
1
Þ Tð p =2
1
Þ T1
¼ 2
Δt RC
Let the past become the present, and the future further into the future by updating “p” to
“p + 1/2”. Rearranging and solving for the future temperature in terms of the present:
T ðpþ1Þ þ T ðpÞ
T ðpþ1Þ
T ðpÞ T1
¼ 2
Δt RC
22 1 Thermal Circuits
RC 1 ðpÞ
T1 þ T
Δt 2
T ðpþ1Þ ¼
1 RC
þ
2 Δt
Note: A detailed solution follows. It is advised that this solution not be consulted
prior to doing this workshop yourself. The intent is for as much “self-discovery” to
occur as possible.
Numerical Stability 23
Numerical Accuracy
The three numerical methods are compared with the exact solution in Figs. 1.8, 1.9,
and 1.10 for fixed numerical time steps of 1.0 s, 0.5 s, and 0.1 s, respectively. The
numerical methods are applied to the RC model problem, with a time constant
(RC) of 1 s. The exact solution is shown as a solid line. For the case where the step
size of the numerical approximation equals the physical time constant of the system
(Δt ¼ 1 s here), the explicit method achieves equilibrium in a single step, and then
stays there. The backward implicit method decays too slowly, and the central
method is the most accurate. The accuracy of all methods increases as the step
size decreases. For practical purposes, a step size of 10 % of the underlying time
constant can be considered sufficiently small to simulate the model accurately for
all methods.
Numerical Stability
Figure 1.11 shows the effect of time step on numerical stability for the Euler
method (explicit forward difference method) for step sizes between one and two
time constants. The method involves calculating the initial slope, and extrapolating
forward at that slope for a full step. As shown previously, a step size of 1.0 will
bring the temperature to ambient (0 C here) in a single step. For a larger step, the
Fig. 1.8 Comparison of three numerical techniques on the transient model problem. The time
constant (RC) has a value of 1 s for all three numerical techniques. The exact solution is shown as a
solid line, and straight dashed lines between points are drawn for the explicit and backward
implicit method
24 1 Thermal Circuits
solution after one step will overshoot its equilibrium value. The next step will
evaluate a positive slope, and will overshoot its equilibrium. The temperature will
resemble a decaying periodic function, and eventually settle to the correct equilib-
rium value. This behavior is numerically stable (the function remains finite), but in
Numerical Stability 25
Fig. 1.11 Explicit forward difference method for step sizes between one and two time constants
a heat transfer context, each step in time violates the Second Law of Thermody-
namics: a warm object cooling to a cold environment cannot become colder than
that environment without some other agent (such as evaporation). Therefore, a step
size of 1 time constant is considered to be the maximum step size allowable for the
explicit Euler method.
Figure 1.12 shows the behavior of the Euler method for a step size of 2 time
constants and a slightly larger value (2.01). For a step size of 2, the solution bounces
back and forth between +100 and 100 C, and will do so indefinitely. For a step
size of 2.01, the solution grows in absolute value with each step, and will eventually
grow to infinity (resulting in a computer error once the size limit of the program
being used is reached). A step size of 2 time constants is therefore shown to be the
maximum step size for numerical stability for the Euler method. This instability can
be seen in the mathematics of the recursion relation for the Euler method, namely,
Δt
T ðpþ1Þ ¼ T ðpÞ þ T 1 T ðpÞ
RC
in which the absolute value of the future temperature increases with step size (Δt).
The limit for the Euler method is:
lim T ðpþ1Þ ¼ 1
Δt¼1
Fig. 1.12 Explicit forward difference method for step sizes of 2.00 and 2.01
Figure 1.13 shows the behavior of the backward and central implicit methods for
a step size of 10 (which would be wildly unstable for the forward method). These
methods are shown to be inherently stable, numerically, meaning that their solution
will not increase indefinitely, but rather will approach equilibrium no matter how
large a step size is taken. For the backward method, the recursion relation is
RC ðpÞ
T1 þ T
Δt
T ðpþ1Þ ¼
RC
1þ
Δt
Its limit is
lim T ðpþ1Þ ¼ T 1
Δt¼1
This limit shows that for large step sizes, the solution approaches the equilibrium
value in a single step. On the other hand, for the central method, the recursion
relation is
Numerical Stability 27
Fig. 1.13 Implicit methods (backward and central difference) with a step size of 10 time
constants
RC 1 ðpÞ
T1 þ T
Δt 2
T ðpþ1Þ ¼
1 RC
þ
2 Δt
Its limit is
There is no real physical meaning that can be attributed to this limit. For very large
step sizes, the central method will eventually settle to equilibrium, but will do so as
a decaying periodic function. Its behavior violates the Second Law, and in no way
resembles the true behavior of a first-order system.
In future chapters, when multi-node systems are considered, it is possible that
the inherent time constant of one or more nodes is much smaller than all the others,
the so-called stiff numerical problem. In these cases, an implicit method, which is
harder to implement than the explicit method, might be advantageous. While the
central difference method might appear to have better accuracy for step sizes less
than the inherent time constant of the system, the backward difference method is
arguably preferred when the numerical step size is much larger than the inherent
time constant of the most rapidly changing nodal temperature.
28 1 Thermal Circuits
Consider the RC circuit shown (with R ¼ 1 C/W and C ¼ 1 J/ C as defaults), after
activation of an initial state by the switch (T0 ¼ 0 C). In this circuit the ambient
temperature varies with time in a prescribed way. Specifically,
Write an Excel workbook or program code that implements the Euler method and
plots T and T1 vs. time (on the same axes) over enough cycles to reach a “steady-state”
(in which there is no cycle to cycle temperature variation). Complete the Results table
in order to investigate the system amplitude and phase response to source frequency.
An analytical solution to this problem can be developed for those so inclined.
Model Development
An energy balance applied to the temperature node is:
dT T 1 T
C ¼
dt R
The Euler method uses a forward finite difference approximation to the first
derivative:
dT T ðpþ1Þ T ðpÞ
dt Δt
where Δt is the numerical step size, the superscript (p) is an index referring to the
present time, and (p + 1) is one step into the future. Inserting and rearranging for the
future temperature in terms of the present:
ðpþ1Þ ðpÞ Δt T ð1pÞ T ðpÞ
T ¼T þ
C R
For numerical accuracy, the step size should be much smaller (say 10 %) than the
smaller of the inherent response time (RC), or the cycle time (1/N).
Workshop 1.2: Numerical Solution of RC Circuit with Time. . . 29
RESULTS (run cases with different step sizes to observe the effect, but don’t
report them)
This chapter introduces two practical heat transfer concepts; lumped capacity and
overall heat transfer coefficients. The term “lumped capacity system” means that a
finite region of space is considered to be at some average temperature, even though
there could be hot or cold spots in it. The example of a cooling mug of coffee will be
used extensively in subsequent chapters, in which case an analysis of the average
temperature will be conducted, even though the coffee is somewhat hotter than the
mug, and there are cold spots of coffee near the mug wall. In numerical analysis,
subdivisions of a physical object can be made, treating each subdivision as a
lumped capacity element.
The “overall heat transfer coefficient, U” is a parameter that captures the basic
idea of heat transfer, namely, energy transfer that is driven by a temperature
difference. For example, “R value” is the metric used to rate the thermal perfor-
mance of insulating materials, and it is the inverse of an overall heat transfer
coefficient, U. Applied to a wall on a cold day, heat must flow from the inside air
to the inner surface of an exterior wall, then through the wall, which has paint, sheet
rock, studs, insulation, sheathing, vapor barrier, shingles, paint, and then from the
outer surface of the wall to the cold air outside. This textbook builds theoretical
tools for estimating all these effects. The R value is a measure of the overall heat
transfer coefficient (actually, its inverse) and includes all the complicated details
into a single metric.
The focus of this chapter is on the thermal capacity of systems, which depends
on the material properties of density and specific heat. The next chapter will focus
on the thermal resistances of systems, where thermal conductivity and emissivity
are key material properties. The remaining chapters will build analysis tools for a
widening range of applications.
In dealing with complicated situations that involve heat transfer, the approach
will be to start with as global a picture as is reasonable, generally called a 1-node
model, in which all the material in question is lumped into a single “node,” and an
overall heat transfer coefficient between this system and its environment estimated
(which can be rather involved). This first step is the ultimate in the process of
I, like many, NEED a cup of coffee as soon as possible when I wake up. It takes a
few minutes to prepare the coffee maker and run it through its cycle. Then I pour hot
coffee into a mug. It’s TOO HOT! Grrrrrr. . . So maybe I drop a few ice cubes in it so
I can get a good gulp to start my day. Diluting the coffee is not ideal, but it’s worth it
for that first cup. I wonder if I can predict how long it would take to just wait for
it. A goal of this book is to satisfy that curiosity.
An experiment was conducted using a ceramic mug which closely approximates the
mug defined in the problem statement. The actual mug tested has rounded edges, a
handle, and other deviations from the schematic. The idealizations implied in the
schematic diagram represent an early modeling step. Water was brought to a rolling
boil on a stovetop and quickly poured into the mug. A handheld infrared thermom-
eter was used to measure the free surface and the outside wall temperatures as
functions of time. The raw data are plotted in Fig. 2.2 for the entire cooling event,
the end of which, after some 4 h, is defined by the coffee reaching ambient. After an
initial adjustment period, the top and side temperatures fall more or less together
and asymptotically approach ambient. The event will be broken down into distinct
stages in the following paragraphs. The raw data is reported in Appendix 1.
It is emphasized that this experiment was conducted with a handheld device that
measures surface temperature only and was not in a controlled laboratory
2.1 A Cooling Mug of Coffee 33
environment, nor with a detailed error analysis. There is much to be said, but not
here, about the experimental uncertainty in this experiment that would raise into
question many fine details of these temperature curves, especially during the initial
period as the mug is heated. Readers of this text are encouraged to conduct their
own experiments, and apply the theoretical methods developed in this text to those
situations.
Figure 2.3 shows the first 10 min of the cooling event. At the start (immediately
after pouring the coffee), the mug is at ambient temperature and the top surface is
near the boiling point of water at atmospheric pressure. Note that the IR tempera-
ture sensor measures the surface temperature of the water, and strong evaporative
effects of water near its boiling point likely produce temperatures noticeably below
that of the interior. There is an initial phase, called the “mug heating phase” which
34 2 Lumped Capacity Systems and Overall Heat Transfer Coefficients
Fig. 2.2 Temperature of the free surface (top) and middle of the outer side wall (side) as a
function of time for the entire cooling event
Fig. 2.4 Temperatures for the first hour of the cooling event
will be investigated in some detail in future chapters. This phase lasts about 3 min,
during which time the side temperature rises to a peak, and the top (surface)
temperature drops quickly to a slightly lower temperature than the side. At the
end of the mug heating phase, the two temperatures are close to each other at
approximately 72 C.
Figure 2.4 shows the first hour of the event, during which time the coffee passes
between practical drinking stages. For the first 16 min, the coffee is too hot to drink.
The subjective definition of “too hot” at 60 C was determined by testing with small
sips (in a separate experiment). The temperature falls after the mug heating phase as
intuition would suggest. During the subsequent cooling phase, the indicated tem-
perature of the free surface is slightly lower than that of the sides of the mug most of
the time. Between 16 and 41 min, the coffee is drinkable, but not tepid. The
sampling rate was changed during this time, and by the end, the temperature
indicated by the IR detector of the top surface is slightly higher than that of the
side wall.
So we’re done, right? After pouring the coffee, I need to wait about 15 min
before I can start sipping, and then 25 min later (40 min after pouring), it’ll be too
late. But what if I put a lid on it, or was using a travel mug, or had a paper cup, or a
bigger mug, or was really interested in a much larger (or smaller) scale type of
practical problem? The main point of this example is to use a simple experiment to
compare to theoretical predictions. The skill of making such a prediction from “first
principles” is the main objective of this text, to which we now turn.
36 2 Lumped Capacity Systems and Overall Heat Transfer Coefficients
The first step of a thermodynamic analysis (of which heat transfer is a subset) is
generally to split the universe into two parts, system and surroundings. Doing so
produces a control volume (the region of space that encompasses the system) and a
control surface (the boundary between the system and its surroundings). A lumped
capacity heat transfer model captures the global transient response of the average
temperature of a system to its surroundings at a different temperature. Many
practical problems fall into this category. Furthermore, the basic concepts devel-
oped here form a basis for more complicated analyses when more detail is required.
It is easy, but wrong, to conclude that the lumped capacity approximation means
that the temperature of an object is uniform. Proper application of heat transfer
methods (next chapter) allow for significant spatial variation in temperature, while
still maintaining a lumped capacity model.
ΔE ¼ Qin W out
traditional heat transfer analysis, where the details of the process as it occurs are
often the objective, a rate basis is generally more advantageous. Dividing the
energy balance by the elapsed time between states (Δt):
ΔE Qin W out
¼
Δt Δt Δt
Consideration of the process that takes place over a “short” time interval produces
the illusion of a snapshot (rather than a process, with a before and after), in which
the rate of change of energy is related to the rate of heat and work exchange. Taking
the limit Δt ! 0 and defining a nomenclature q ¼ Qin/Δt and w ¼ Wout/Δt which
have units of energy per unit time (or J/s ¼ Watt in SI units, or Btu/h in English
units), the First Law for closed systems on a rate basis becomes the following first-
order ordinary differential equation:
dE
¼ qin wout
dt
Note that thermodynamics texts tend to use Q_ for q and W_ for w.
In general, stored energy can be in the form of kinetic energy, potential energy,
and/or internal energy (u). Each element of mass (dm ¼ ρdV) within the defined
control volume has, in general, a different specific energy, the word “specific”
meaning per unit mass. The total stored energy is the sum of the energy of all the
elemental masses. Expressed as an integral:
ððð 2
V
E ρ þ gH þ u dV
2
CV
In this expression, the triple integral is evaluated over the control volume
(CV) defined within the system boundary by differential (i.e., vanishingly small)
volume elements (dV). In general, the density (ρ), velocity (V with a line through it
to distinguish from volume), height (H ) in a gravitational field (g) and internal
energy (u) can all vary with position.
For the problem at hand, the kinetic energy associated with motion of the liquid
and any changes in its potential energy as it rises and falls are assumed from the
outset to be negligible in comparison to the changes in internal energy that arise
during the event. There is motion of the liquid, even if it is not being stirred due to
mild density variations, but it seems plausible that the energy associated with that
motion is not important. Without a much more detailed analysis, the neglect of
kinetic and potential energy cannot be further evaluated, but kept in the back of the
38 2 Lumped Capacity Systems and Overall Heat Transfer Coefficients
mind. The heat transfer principles developed in this text can be applied to those
situations, where kinetic and/or potential energy are important.
In general, the internal energy of a system consists of its nuclear, chemical, latent
(i.e., phase change), and sensible (thermal, or that energy associated with its
temperature) components. However, if nuclear or chemical reactions are absent
and there is no phase change within the system boundary, the only energy form
which changes is the sensible component which relates internal energy to the
temperature through the specific heat (cv, in J/kg/K), a thermodynamic function
defined as:
∂u
cv
∂T v
where the partial derivative is taken at constant specific volume and indicates that
the internal energy can be expressed as a function of two other thermodynamic
variables (i.e., specific volume and temperature), in general. Note that lower case
“c” is used to denote specific heat (with units of J/kg/K), while upper case “C” is
used to denote total capacitance (J/K). However, for solids and liquids that are not
undergoing phase change, it is generally acceptable for engineering purposes to
assume that the internal energy depends solely on temperature (not pressure, or
volume, or any other thermodynamic variable), and therefore the partial derivative
becomes a total derivative, and the subscript “v” is no longer required:
ðu ðT
du ¼ u uref ¼ cdT c T T ref
uref T ref
The last expression defines formally this temperature averaged specific heat (which,
in general, still varies with temperature).
In the present case, with the control volume consisting of two very different
substances (mug and coffee), the spatial triple integral that expresses the total
energy stored can be split into two:
ððð ððð
E ρc T T ref dV þ ρc T T ref dV
coffee mug
There are two material properties (density and specific heat) that vary with position
because the temperature varies with position, and these integrals cannot be further
2.2 Lumped Capacity Model Development 39
The combination ρcV for a given subsystem has units J/K and is given the shorthand
nomenclature of a capital C, with an appropriate subscript. That is:
and similarly for the coffee. It is understood that the density and specific heat are
assumed constant with respect to space, yet could still be functions of temperature
(an effect which could be modeled if required).
Numerical values of specific heat can be estimated in a number of ways, but
generally can be searched for on the Internet or in tables from textbooks to obtain
reasonable approximations. Whenever possible, a careful measurement of an actual
sample (Appendix 2) and/or a value obtained from a manufacturer’s specification
sheet for an actual material in an application is the best practice.
At the start of the event, the mug and coffee have very different temperatures.
Empirically (Fig. 2.3), after a few minutes, they are at nearly the same temperature.
A demonstration of why the mug temperature and coffee temperatures are so close
to each other is delayed until more heat transfer tools have been developed. The
thermodynamic tools are in place to predict the value of the temperature at the end
of the mug heating phase. Recalling the basic First Law expression:
Having defined the system to be the coffee plus mug, and the process to start at an
initial temperature where the mug is at ambient temperature and the coffee is at the
temperature it is poured into the mug (near the boiling point of water):
Cmug þ Ccoffee T final T ref Cmug T mug, initial T ref þ Ccoffee T coffee, initial T ref
¼ Qin W out
The coffee and mug are assumed to be at the same final temperature (which is the
initial temperature of the main cooling of the coffee and mug together). All the
terms with the reference temperature cancel, and the First Law can be rearranged to
solve for the final temperature:
40 2 Lumped Capacity Systems and Overall Heat Transfer Coefficients
The combined system exchanges heat with the environment (Qin) but the primary
heat exchange takes place internally between the coffee and mug, which does not
appear directly here because the system boundary does not include it. It is plausible
that the heat loss to the environment is negligible in the relatively short time (3 min)
of the mug heating phase (compared to the 4 h cooling event). The work exchange is
identically zero in this case. Assuming, therefore, an overall adiabatic process
(Qin ¼ 0), the First Law reveals the final temperature of the mug heating phase to
be a capacitance-weighted average temperature:
Table 2.1 shows property values assumed for the heat capacitance. Coffee is
assumed to have thermal properties of liquid water at nominal room conditions.
The mug values are typical of a ceramic material. In Appendix 2, a rough measure-
ment of the specific heat of the actual mug used is described. A majority, 85.5 % of
the total capacitance is associated with the coffee. The heat capacity of the mug
itself is therefore considered to be small but not negligible, and it is easy to account
for this “thermal mass.” Note that the mass of the mug itself is comparable to that of
the coffee, yet its capacitance is small because its specific heat is less than a quarter
of that of the coffee. Liquid water (and therefore coffee) has an exceptionally high
specific heat value, one of the many unique features of water.
Inserting values for this case:
Consider the experimental value (from Fig. 2.3) of approximately 75 C for the
peak side wall temperature (the top surface temperature is a few degrees lower). Is
this good agreement or bad? It could be argued both ways. There is uncertainty in
the experimental temperature values, and these values are taken at two places on the
defined control surface. The theoretical temperature calculated is an average tem-
perature of the system. The temperature of the liquid in the interior is expected to be
at a somewhat higher temperature (how much higher will be investigated in
2.2 Lumped Capacity Model Development 41
subsequent chapters from a theoretical, not experimental, point of view). This trend
is consistent with the discrepancy of the measured and predicted temperatures.
What theory and experiment agree on is the qualitative comparison, namely, that
the final temperature of the mug/coffee combination is much closer to the initial
coffee temperature than the initial mug temperature. The theory explains the
observed result because the capacitance of the coffee is roughly six times that
of mug.
By the way, my Mom likes really hot coffee, so when I make her a cup, I pour
boiling water into a mug first to preheat it, then dump that water out (after about
3 min) before filling it with coffee. The final temperature for the mug heating phase
(initial temperature for the mug/coffee cooling phase) is then much closer to the
boiling point of water, the way she likes it.
dE dT
¼C
dt dt
where C ¼ Cmug + Ccoffee is the total thermal capacitance of the combined coffee/
mug system. The temperature is best thought of as an average temperature of the
system, not necessarily that the mug and coffee are at the same temperature. The bar
over the temperature will be dropped from here on, keeping in mind that T means
“average temperature.”
42 2 Lumped Capacity Systems and Overall Heat Transfer Coefficients
Modeling, in this case, means expressing the almost infinite complexity implied
by the imposing triple integral in a much simpler (but not simplistic) mathematical
expression. As a result, clarity is gained at the expense of detail.
ððð 2
d
V Modeling dT
ρ þ gH þ u dV ! C
dt 2 dt
CV
The other two terms of the First Law, namely, heat and work, are now addressed.
Work represents mechanical energy transfer across the boundary, such as from
expanding pistons, rotating shafts, electrical input and the like, which do not exist
here, so the work is identically zero. Heat represents the flow of thermal energy
across the system boundary, driven by a temperature difference. The rate of heat
transfer between the coffee (at its average temperature value) and the ambient can
be expressed in the form of Ohm’s Law:
T1 T
qin ¼
R
This model states that the rate of heat transfer is proportional to the temperature
difference driving it and inversely with a property of the system called the thermal
resistance (R). The thermal resistance represents the barrier to heat flow between
the system and surroundings that is NOT accounted for in the temperature differ-
ence driving the heat. The thermal resistance can vary with temperature, in general,
although a suitably chosen average value is frequently justified.
Alternatively, the heat transfer rate from a system to its surroundings can be
modeled as being proportional to the driving temperature difference and to the total
area of the control surface, A. The proportionality factor (not necessarily a constant)
is thus defined as an effective overall heat transfer coefficient, U. Note that there is a
nomenclature problem in that U is used to represent both internal energy and overall
heat transfer coefficient, which mean very different things. In heat transfer:
qin ¼ UA T 1 T
The “R value” of building materials (given the symbol ℜ to distinguish it from the
thermal resistance R) is the inverse of U, which is the thermal resistance times the
system surface area:
R ¼ 1=U ¼ RA
2.2 Lumped Capacity Model Development 43
dT T 1 T
C ¼
dt R
which is the same differential equation obtained for the electrical circuit, with the
same solution if, and it can be a big “if,” R, C, and T1 are constant:
T T1 t
¼ eτ
T0 T1
where T0 is the initial temperature and τ is a time constant, defined by:
C
τ¼
UA
The response time of a lumped capacity system increases with its total capacitance
(or thermal mass), and decreases with its surface area, and with the overall heat
transfer coefficient, U. In the present example, estimates of the capacitance and
surface area are possible. Therefore, by measuring the time constant from an
analysis of the cooling curve, an empirically determined value of the overall heat
transfer coefficient (U ) can be obtained by comparing the prediction of this lumped
capacity model for different values of U. The capacitance has already been calcu-
lated, and the total surface area of the control surface is calculated from the
geometry of Fig. 2.1 as shown in Fig. 2.5. More than half of the surface area is
found on the side wall, and the remainder is distributed between the bottom, the
inner rim (i.e., the area above the liquid on the inside surface, which obviously
depends strongly on how much liquid is poured in the mug), the top free surface,
and the top edge (assumed to be squared off). The heat transfer process is quite
different on all these surfaces, as will be explored in subsequent chapters, but the
global view taken at this point does not distinguish that detail.
Figure 2.6 shows the measured free surface temperature (taken to be the best
representation of the average coffee temperature available experimentally) and
predictions of the cooling curve for three input values of the overall heat transfer
coefficient (U ). The initial temperature is taken to be that predicted for the end
of the mug heating phase (81.7 C). After the first 10 min, the data is reasonably
banded between U values of 10 and 20 W/m2/ C. A U value of 15 W/m2/ C
yields a reasonable agreement over the entire event, giving a time constant of
τ ¼ 45.1 min from:
J min
ð1, 792 þ 272Þ
C C 60 s
τ¼ ¼ ¼ 45:1 min
UA J m2
15 2 ð495:6 cm2 Þ
sm C 10, 000 cm
2
Since the data points do not fall exactly on any line, the response is not truly first
order which could be due to a variation in the parameters (R, C, or T1) during the
44 2 Lumped Capacity Systems and Overall Heat Transfer Coefficients
Fig. 2.5 Surface area of system boundary broken into regions. For the bottom surface, the small
extra area inside the outer rim is obtained assuming the trapped air gap height is the same as the
mug thickness
Fig. 2.6 Empirical determination of the overall heat transfer coefficient, U for the entire event.
Experimental points for the free surface are shown as markers
2.2 Lumped Capacity Model Development 45
Fig. 2.7 Dimensionless temperature vs. time on semi-logy axes. Initial time in this plot is 3 min
into the cooling event, beyond which time the coffee and mug temperatures are observed to fall
together
event (R being the most likely candidate) or phenomena neglected (like evapora-
tion) may be noticeable. Also, a constant reminder that the experimental data is of
the free surface of the coffee, and the lumped model is of an average temperature of
the system.
There are more sophisticated ways to analyze or test for first-order behavior than
this admittedly brute force approach. However, those methods do not necessarily
improve the basic understanding. Brute force is often acceptable, if not preferable,
to getting side-tracked by unwarranted analysis. That is an engineering
judgment call.
A more sophisticated way to present the same data is to plot the dimensionless
temperature vs. time on semi-logy axes, as in Fig. 2.7. Here the initial time is reset
to zero at 3 min into the cooling event because prior to that mug heating makes a
lumped capacity model unreasonable, during which time the coffee and mug do not
fall together; rather, the coffee is heating the mug. Investigation of those effects
require separating the mug and coffee into separate subsystems, as is considered in
a subsequent chapter. The line on the plot shows an exponential curve fit of the
entire event, with the initial value forced to unity. For a pure first-order response, all
data points would fall on this line. The experimental curve initially falls faster than
the overall response, and slower near the end of the event, as thermal equilibrium is
approached. The R2 value of 0.98 suggests that despite these deviations, this event
is reasonably characterized by a first-order event, with a time constant of the inverse
of the number in the exponential of the curve fit:
46 2 Lumped Capacity Systems and Overall Heat Transfer Coefficients
Fig. 2.8 Dimensionless temperature vs. time on semi-logy axes considering only the first hour of
the event. Initial time in this plot is 3 min into the cooling event at which time the measured surface
temperature is 74.0 C, beyond which time the coffee and mug temperatures are observed to fall
together
C 1
τFullEvent ¼ ¼ ¼ 67:3 min
UA 0:014851
The time constant obtained from Fig. 2.7 is targeted toward a simulation of the
entire cooling event, from hot coffee poured into the mug, until the mug and coffee
reach thermal equilibrium with their environment. In practice, the objective is to
understand when the coffee is within an acceptable range of temperature for
drinking, not once it has become tepid. Figure 2.8 shows a semi-logy plot for the
first hour of the event. The time constant during the first hour of the cooling event is
shorter than the time constant that characterizes the entire event:
C 1
τ1stHour ¼ ¼ ¼ 52:3 min
UA 0:0191
The time constant for the first hour is 22 % shorter than that of the full event. That’s
a big difference, despite the fact that the “R2” value was 98 % for the full event.
That suggests the high R2 values can give a rather misleading sense of confidence.
The final result sought from the engineering problem statement, namely, the
time it takes for the coffee, once poured, to cool first to 60 C, and then to 45 C,
thereby defining a window of opportunity. Expressing the first-order cooling curve
in terms of the time:
2.3 A Melting Cup of Ice/Water 47
T T1
t ¼ τ ln
T0 T1
The initial temperature (T0) is taken to be the equilibrium temperature the mug and
hot coffee come to during the mug heating phase (81.7 C), and the time constant is
the experimentally based value of 45.1 min. Therefore, the time to reach 60 C is:
60:0 21:0
t60 C ¼ ð45:1 minÞln ¼ 13:8 min þ 3 min offset ¼ 16:8 min
74:0 21:0
Of course, this window of opportunity agrees with the direct data plots (Fig. 2.4)
because the time constant was empirically determined, not developed from first
principles. The next chapter introduces the main theoretical heat transfer tools that
can be used to predict this behavior from first principles.
A word about units and absolute temperature is in order. Several quantities have
temperature as one of the units, and those units can be specified as either C or K
because the quantity itself is based on a temperature difference. For example, the
units of cv are J/kg/K or J/kg/ C because cv is the change in energy divided by the
change in temperature. This author prefers writing these units in the “code” version
J/kg/K rather than the J/kg·K version (which looks like K is in the numerator) or the
J/(kg·K) version. As another example, the overall heat transfer coefficient U is
based on the driving temperature difference, and therefore it is W/m2/K or equiva-
lently W/m2/ C. Some quantities require absolute units, such as the universal gas
constant whose units must be J/kmol/K and not J/kmol/ C.
At times, I like a nice tall glass of iced coffee. Everyone knows that if you place a
cup of iced coffee on a table top, the ice will eventually melt, diluting the coffee in
the process. The question is, how long does that take? This problem involves heat
transfer, where phase change occurs in the system. In addition, it is another scenario
where an overall heat transfer coefficient can be measured.
An ice/water slurry is prepared by filling a plastic cup with 0.295 kg of ice and
adding liquid water to completely fill the cup. Solid (ice) and liquid are initially at
the melting point (0 C). The cup is placed on a table in a still room at 18 C.
48 2 Lumped Capacity Systems and Overall Heat Transfer Coefficients
Determine the time it takes for half of the ice to melt, and the overall heat transfer
coefficient, U, based on the exposed surface area of the cup plus slurry to the
environment. The cup has an inner diameter D ¼ 0.074 m, inner height H ¼ 0.144 m,
outer height Ho ¼ 0.166 m, and nominal wall thickness w ¼ 0.0038 m.
In the experiment conducted, after 3.5 h (210 min), the remaining ice and liquid
were separated and the mass of ice remaining was measured to be 0.125 kg (42.3 %
of original).
While the percentage of liquid and solid changes continually, the temperature of the
slurry does not change with time, as a first approximation. In practice, since ice has
a lower density than liquid water, as ice melts, the slurry will separate into two
parts; an ice/liquid slurry in good contact floating above a single phase liquid below.
The liquid on the bottom portion of an ice/water slurry is not constrained to the
melting point. In fact, for an undisturbed scenario like this, the liquid water will
tend to stabilize at 4 C, the temperature where the liquid water density is maxi-
mum. Assuming a constant system temperature makes theoretical modeling simpler
than the cooling mug of coffee. Since the rate of heat transfer is driven by the
temperature difference, it remains constant, unlike the hot coffee cooling where the
heat transfer rate decreases as the coffee approaches ambient temperature.
Defining the cup and slurry (solid and liquid) as a closed system, an energy
balance is:
dE d Ecup þ dEsolid þ dEliquid
¼ ¼ Q_ in W_ out
dt dt
The work done by the system on the surroundings is identically zero. The heat
transfer rate can be expressed as before with an overall heat transfer coefficient,
Q_ in ¼ UAðT 1 T Þ where U is an overall heat transfer coefficient, A is the surface
area of the system, T1 is ambient temperature, and T is the average system
temperature. In this model, the system will be assumed to remain at the melting
point as long as some ice remains.
The energy (E) of each component in general consists of three components:
internal, kinetic, and potential energy. There is little motion in this example, and the
energy of each component is therefore the internal energy per unit mass, u. For the
cup, which does not change phase, there is only sensible internal energy. That is:
Ecup ¼ mcup ccup T T ref
Since nothing in this equation is changing with time, the first term of the energy
equation will be zero when the time derivative is applied. The thermal capacitance
of the cup is not involved in this constant temperature model.
The internal energy of the solid and liquid water have different specific internal
energies, given by uL for the liquid and uS for the solid. Their difference is the heat
of fusion (or heat of melting): uL uS ¼ uLS ¼ umelt which for water at 0 C has a
value of 330 kJ/kg. The internal energy of the system is thus:
50 2 Lumped Capacity Systems and Overall Heat Transfer Coefficients
Ecup ¼ mcup ccup T cup T ref þ mliquid uL þ msolid uS
dmsolid
umelt ¼ UAðT 1 T Þ
dt
Every parameter can reasonably be modeled as being constant during this event,
and therefore a simple integration, with the initial mass of ice being mICE,0 yields:
UAðT 1 T MP Þ
msolid ¼ mICE, 0 t
umelt
Note that the system temperature has been set equal to the melting point of the
slurry (TMP ¼ 0 C). The mass of ice decreases linearly with time, and it is an easy
matter to calculate the time it takes to melt the ice to any value. In particular, the
total melting time of the ice (tmelt) is determined by setting mice ¼ 0 and solving for
the time:
mICE, 0 umelt
tmelt ¼
UAðT 1 T MP Þ
The only difficult parameter to evaluate is the overall heat transfer coefficient.
2.3.4 Results
The results are reported in Fig. 2.9 (spreadsheet structure) and Fig. 2.10 (plot of
theory and experiment). For the calculation (Fig. 2.9), the surface area was taken to
be the sum of the side surface and the top surface. The bottom surface was assumed
to be well insulated, as attempts to do so were made. The initial ice fraction (0.522)
was determined using “goal seek” to set the known initial mass by changing the ice
fraction. The worksheet was copied twice and values entered in the overall heat
transfer coefficient to encompass the experimental result (Fig. 2.10).
2.3 A Melting Cup of Ice/Water 51
Fig. 2.10 Model predictions for several values of heat transfer coefficient and experimental
results for the melting cup of ice
(continued )
Time (min) Top ( C) Side ( C)
15 61 61
16 60 60
17 60 59
18 59 58
19 58 58
20 57 57
21 57 56
22 56 56
23 57 56
24 56 55
25 55 55
30 52 51
35 49 48
40 46 45
45 44 43
50 42 42
55 41 40
60 40 39
70 36 35
80 35 34
90 33 33
100 32 31
110 30 30
125 28 28
140 27 27
165 25 25
180 24 24
210 23 23
250 22 22
54 2 Lumped Capacity Systems and Overall Heat Transfer Coefficients
Problem Statement
Analysis
The First Law of Thermodynamics is applied to a system that consists of the mug
and water poured into it:
ΔE ¼ Q W
The heat Q represents heat exchange between the mug/water and the environment
during the 2 min settling period, and while not zero, is assumed to be negligible.
There is no work exchange, and evaporation effects are neglected. Therefore, the
change in energy is zero, or the initial energy equals the final energy:
Einitial ¼ Efinal
Considering the energy of the two components (water and mug) relative to any
reference temperature, Tref, and assuming constant specific heats:
mmug cmug T mug T ref þ mwater cwater T water
T ref
¼ mmug cmug T final T ref þ mwater cwater T final T ref
The terms involving the reference temperature all cancel, and the energy balance
can be solved for the specific heat of the mug:
mwater T final T water
cmug ¼ cwater
mmug T mug T final
Inserting numerical values, using the density of water to be 1,000 kg/m3 and the
specific heat of liquid water to be 4,200 J/kg/K:
0:5 17:5 14:5
cmug ¼ 4200 J=kg=K
0:335 41:0 17:5
In a rough experiment, hot coffee was poured into a room temperature ceramic mug
located on a table in a still room. A handheld infrared temperature sensor was used
to measure the temperature of the free surface (top) of the coffee, and the outer side
wall temperature (side) as a function of time. The data is contained in an excel
file (CoffeeData.xlsx, listed also in Appendix 1) which has columns for time, top
surface temperature, and side wall temperature.
Model Development
The First Law of Thermodynamics applied to the system defined by coffee plus
mug (neglecting evaporation, making it a closed system with no mass flows across
the boundary) is:
dE
¼ Q_ in W_ s
dt
Upon rearrangement:
dT ðT 1 T Þ ðT 1 T Þ
¼ ¼
dt ðC=UAÞ τ
The combination C/UA must have units of time for dimensional consistency, and
that is defined as the time constant for this problem, τ ¼ C/UA. Note that the rate of
change of temperature is proportional to the temperature difference driving the heat
transfer, which decreases with time, whether it is a heating event (a cold beer) or a
cooling event (hot coffee).
Numerical Solution
Forget that this first-order ODE with an initial condition has a simple closed-form
(i.e., analytical) solution. The goal of the workshop is to develop a powerful
numerical technique that will be applied to problems for which an analytical
solution is impossible.
The Euler method “discretizes” time and expresses first derivatives as forward
difference approximations with a small but finite step in time (Δt), namely,
Solving for the temperature one step into the future yields the Euler formula for
this case:
" #
ðpþ1Þ ðpÞ T 1 T ðpÞ
T ¼T þ Δt
τ
Notice that on the right hand side, the temperature has been given a superscript
(p) because it is changing with each step. The ambient temperature and time
constant are not changing, so they do not need superscripts. They are fixed input
parameters. The time step is a numerical parameter that can be changed by the user.
A simulation is considered accurate if the predicted results are insensitive to the
choice of time step.
58 2 Lumped Capacity Systems and Overall Heat Transfer Coefficients
All physical (as opposed to optical) temperature measuring devices are subject to
both static and dynamic errors. A static error occurs when the sensor is in thermal
equilibrium with its environment, but its temperature is different than the object or
Workshop 2.3. Floating Thermometer Response Time 59
In designing the experiment, the temperature of the fluid should not change
substantially in the time it takes for equilibrium to be achieved, which can require
patience. It is important to know the final equilibrium temperature to determine the
true response time.
A response time experiment was conducted with a floating thermometer, an
inexpensive liquid-in-glass sensor designed to measure the temperature of con-
sumer aquariums. The construction consists of a glass cylinder of length 10.8 cm
and outer diameter 1.1 cm (with rounded ends). Tiny balls made of lead are located
at one end which causes the thermometer to float vertically in water, with approxi-
mately 10.0 cm submerged (0.8 cm above the surface). Above the lead balls is a
reservoir of sensing liquid and a smaller cylinder in which the thermometer fluid
rises and falls with temperature. A calibrated scale placed adjacent to this inner
cylinder allows for measurement. For thermal modeling purposes, the mass of the
whole system can be considered to be dominated by the lead.
The response was determined for two different fluid environments: ambient air and
nominally room temperature water. In both cases, the thermometer was
preconditioned to a lower temperature by allowing it to equilibrate with a cold
water bath. The raw data is given in Fig. 2.11. Blank columns are left for the
calculation of the dimensionless temperature and the response time, which can be
calculated for each individual data point. Note that the initial temperature is the first
data point. The fluid temperature (Tinf), reported at the top of each table, was
determined after approximately five times longer than the last reported data point.
In addition to calculating the response time associated with each point, prepare
plots of the raw data (temperature vs. time) and a plot of the dimensionless
60 2 Lumped Capacity Systems and Overall Heat Transfer Coefficients
Fig. 2.11 Spreadsheet templates and raw data for dynamic response of a floating thermometer
temperature vs. time on semi-logy axes. An exponential fit (with the x-intercept
forced to a value of unity) can be added to each curve. The degree to which the
system obeys a first-order response is determined by the consistency of the individ-
ual response times, or equivalently from the linearity of the exponential fit.
The overall heat transfer coefficient (U) for the two cases can be determined from
the definition of the response time, namely, τ ¼ RC ¼ C/(UA). An estimate of
the total capacitance (C) can be made by assuming that the thermal properties
(i.e., specific heat) is approximately that of the lead used to weigh it down. The
mass of the thermometer can be determined by measuring the fraction of the length
that is above water when floating, and using Archimedes’ principle (the weight of
an object equals the weight of the displaced fluid).
Heat Transfer Modes: Conduction,
Convection, and Radiation 3
On the north side of a building, (so that there is no solar gain), a single-paned glass
window (shown schematically in Fig. 3.1) of thickness Δx ¼ 0.012 m, height
H ¼ 2 m, and width W ¼ 8 m (into the page) is exposed on the inside to room air
maintained at TH ¼ 25 C. The outside of the window is exposed to a crosswind of
10 miles per hour (¼4.47 m/s) and an outside air temperature of TC ¼ 0 C.
Estimate the rate of heat transfer through the window (in Watts), the temperature
of the inside and outside surfaces of the glass (T1 and T2) and the daily energy
cost associated with heat loss through the window, assuming the price of heating to
be p ¼ $20/GJ.
The three modes of heat transfer used in engineering practice are introduced in this
section. A brief definition of the modes is followed by the development of a thermal
channel and its representation as a resistance network, and finally the mathematical
models used for the modes are defined.
Conduction: Heat transfer through a solid is called conduction, and is governed by
Fourier’s Law, defined shortly. In the window problem, conduction heat transfer
takes place between the inner and outer surfaces of the glass of a known thickness
Δx. In the mug of coffee example, conduction occurs across the mug wall.
Convection: Heat transfer between a fluid (gas or liquid) and a solid surface is called
convection and is governed by Newton’s Law of Cooling. There are two convective
3.2 Heat Transfer Modes and Thermal Channels 63
surfaces in the window problem, the inside surface, which is exposed to room air,
and the outside surface, which is exposed to outside air (with a crosswind). In
reality, the physical mechanism of convection is conduction across a thin layer of
fluid, called a thermal boundary layer, shown with thicknesses δ1 and δ2 in Fig. 3.1.
However, the thickness of these layers is unknown, and they are heavily influenced
by the motion of the fluid.
Radiation: Heat transfer between two solid surfaces that “see” each other and
thereby exchange electromagnetic energy, or radiation, is governed by the Stefan–
Boltzmann Law. Like convection, radiation is associated with a specific surface,
and there are two of them in the window problem. However, the physical mecha-
nism of heat transfer is very different from that of convection. Accelerating charged
particles (electrons and protons) in the solid emit photons (or electromagnetic
waves) that carry energy with them. Simultaneously, photons that emanate from
other surfaces that impinge on a surface can be absorbed. Therefore, a net exchange
of energy occurs. Radiation is much more difficult to model than conduction and
convection, in general. Good engineering judgment, from experience, dictates
when it is essential to include it, and how to do so in an approximate way.
Mass Transfer: In addition to the three modes of heat transfer, energy flows
associated with mass crossing the boundary can be important. There are two
mechanisms for mass transfer effects: advection and diffusion. Advection (often
called “convection” but with a very different meaning than the mode of convection
between a fluid and solid surface) is the energy associated with bulk fluid flow across
a boundary. The enthalpy is the natural thermodynamic property that accounts for
both internal energy flowing in and the work required to do so (the “flow work”). For
example, fluid flowing into a heat exchanger carries energy with it, and exits the heat
exchanger at a different energy level. The other way energy crosses the boundary is
by molecular diffusion (driven by concentration gradients). Evaporation effects fall
into this category. These effects are developed in Chapter 13, and results will be
discussed in relation to the cooling mug of coffee problem.
As will be seen, conduction and convection are naturally expressed in an Ohm’s
Law form, where the heat transfer rate (current) is proportional to a temperature
difference (voltage drop), and inversely with a thermal resistance (which may be a
variable). There are important practical cases where radiation can be modeled in
Ohm’s Law form as well and others where it can be modeled as a current source.
These cases are developed in this chapter. Cases where these models do not
capture the controlling physics are left to other textbooks. Mass transfer by advec-
tion can be modeled as a dependent current source (i.e., the current source depends
on the enthalpy values entering and exiting, developed in Chapters 11 and 12).
Mass transfer by diffusion can be modeled either as a current source, or in an Ohm’s
Law fashion, but with effective R values that are extremely temperature dependent.
A lumped capacity (or 1-node) thermal resistance model of the single-paned
window is shown in Fig. 3.2. All the capacitance of the window ðC ¼ ρcV ¼
ρcΔxHwÞ has been lumped into a single node, placed at the midway point of the glass,
and given a temperature with a bar over it to indicate that it is an average window
64 3 Heat Transfer Modes
temperature, and it varies with time, in general. This node is represented with an open
circle, indicating that it carries capacitance and is governed by a differential equation,
in the general case. Nodes are placed at the inner and outer surfaces of the window
because these locations are discontinuous in space (air on one side, glass on the other),
and there is a distinct change in heat transfer mode from one side to the other. These
temperatures are unknown (prior to analysis), but can be related to the capacitive node
through algebraic manipulation and are therefore represented by filled circles.
There are four fixed temperatures represented by batteries; fluid and far wall, on
each side of the window. The fluid (air) in the immediate vicinity of the window
exchanges heat by the mode of convection, and a thermal resistance with a subscript
“h” is used (because “h” will be used in defining a convection coefficient). In addition,
each surface exchanges heat with “walls” that can be far removed from the window.
The average temperature of these walls is treated as fixed. The window surfaces
exchange heat with these removed surfaces through the mode of radiation, and a
thermal resistance with a subscript “r” is used for these modes. For example, the outer
window surface “sees” anything that an observer inside the building looking outside
would see; other buildings, the street, the sky. The inner window surface “sees” what
someone would see looking in: ceiling, floor, walls, furniture, people, etc. In general,
the fluid temperature in the vicinity of the window and the far wall temperatures
could be different from each other. A wisely chosen average value is required if the
floors, ceilings walls, and occupants are at widely different temperatures.
The mode of heat transfer between the inner and outer window surfaces and the
midpoint of the window is conduction, and conductive thermal resistances (Rk/2)
are placed between each surface node and the interior node. The total conductive
resistance between the inner and outer surface (Rk) has been split into two equal
resistance values.
The RC network of Fig. 3.2 has four thermal channels; from each of the four
fixed ambient temperatures to the average temperature of the window itself. After
setting up the general transient solution, this problem will be reduced to a single
thermal channel from inside to outside by considering only the steady-state solu-
tion, and setting the fluid and radiation wall temperatures equal to each other.
Then heat will flow from inside to outside through a single thermal channel.
3.2 Heat Transfer Modes and Thermal Channels 65
Each of the four heat transfer rate terms on the right side model the four thermal
channels. If the five thermal resistances are treated as constants, this equation can be
recast into a general first-order system with a steady-state temperature and an
effective RC time constant. Alternatively, the energy balance can be solved numer-
ically, and that would allow for models for which the thermal resistances depend on
temperature.
The temperatures of the two window surfaces (T1 and T2) are not directly solved
for in the governing equation. However, they are interior temperatures within
thermal channels and, as derived in Chap. 1, they can be expressed in terms of
their neighbors as:
However, the window problem at hand is really a quasi-steady state problem. The
problem statement states that the inside and outside temperatures are fixed. Even if
the inside or outside temperatures were changing with time, in practice, it is
expected that they would do so gradually, and the window would maintain the
quasi-steady temperature obtained by setting the time derivative to zero. Formally,
it would have to be shown that the rate of heat flowing into the capacitor is small
compared to the rate of heat that flows from the inside surface (T1) to the outside
surface (T2). Here is a case that could certainly be tested by running a transient
simulation as outlined, and then neglecting the capacitance effects. The problem
statement would be modified to specify the manner in which either the hot or cold
ambient temperatures varied with time.
At steady-state, then, heat does not flow into or out of the capacitor, and in
representing the network, the capacitor can be removed. In this case, heat from the
inside window surface to the outside surface takes place through two series resistors
of Rk/2. The average temperature of the window (by a voltage divider) equals the
geometric average of the inside and outside temperatures. The simplified thermal
resistance network that carries no capacitance is shown in Fig. 3.3. In general, for
problems that are considered to be at steady-state, RC networks need not show the
inherent capacitances associated with material because there is no change in energy
stored, as is assumed in this case.
A further simplification can be made if it is reasonable to assume that the fluid
temperatures and the radiation wall temperatures are equal. That is, if
Fig. 3.4 Single-paned window resistance network for steady-state conditions, with equal fluid
and wall temperatures, and shown in terms of a single equivalent resistance
then only a single battery on either side can be used, and the simplified resistance
network is shown in Fig. 3.4. Notice now that radiation and convection act in
parallel with each other, and in series with conduction (and the convection/radiation
on the other side). Care must be taken in assuming that these two driving
temperatures are the same. There are important practical cases where an object
exchanges heat with a radiation partner at a very different temperature than the fluid
in the immediate vicinity of the object.
This problem has been reduced to a model of heat flow through a single thermal
channel from one temperature source to another. Within this channel, all three
modes of heat transfer are involved, with distinct temperature drops along the way.
3.3 Fourier’s Law of Conduction 67
The heat transfer rate through the window, as sought from the original problem
statement, is expressed in terms of the overall temperature drop and thermal
resistances and, equivalently, in terms of an overall heat transfer coefficient (U):
TH TC
q¼ ¼ UAðT H T C Þ
Req
The basic laws that govern the modes of heat transfer, and methods for estimating
resistance values, are developed in the following sections.
Focusing first on the conductive heat transfer that takes place across the window
itself between the inner and outer surfaces of the glass, Fig. 3.5 shows a schematic
of a solid wall consisting of two surfaces (1 and 2) with solid material between them
that are maintained at different average temperatures. It is emphasized that these
surface temperatures are not generally equal to their adjacent fluid temperatures.
Conduction through the wall is governing by Fourier’s Law, which states that, at
steady-state, the rate of heat transfer between two surfaces (1 and 2) with solid
material between them is proportional to the area of the surfaces (A12, which can be
an average area if they are different), the temperature difference between them
(T1 T2), and inversely with the distance between them (Δx12, which can be an
average distance). The proportionality factor (not necessarily a constant) is a
material property called the thermal conductivity (k12), which has SI units W/m/K.
Fourier’s Law of Conduction is expressed mathematically as:
k12 A12 ðT 1 T 2 Þ T 1 T 2
qconduction, 1!2 ¼ ¼
Δx12 R12
Δx12
R12 ¼
k12 A12
In general, since the area of the two surfaces can be different, and the distance
between them might vary somewhat, these expressions are approximate for a more
general geometry than a plane wall.
Figure 3.6 shows the thermal conductivity of a variety of materials (solids,
liquids, and gases) at nominal room temperature (25 C). The thermal conductivity
of most materials is a mild function of temperature, but a suitably chosen average
value can be used for most engineering applications.
For the window problem, the conductive resistance between in inner and outer
surfaces is:
Δx12 0:012 m 1, 000 W
R12 ¼ ¼ ¼ 0:781 C
k12 A12 ð0:96 W=m= CÞð2 m 8 mÞ kW kW
Alternatively, Fourier’s Law can be expressed in terms of the heat flux crossing a
given area at a location x (A(x), where the area is normal to and can vary with x) by
postulating that the rate of heat transfer is proportional to the surface area, as before,
and to the temperature gradient perpendicular to the area. The thermal conductivity
is the proportionality factor. That is:
∂T
qconduction, x ¼ kAðxÞ
∂x
The minus sign accounts for the direction of heat flow from high to low tempera-
ture, according to the Second Law of Thermodynamics. That is, if the temperature
increases in the direction of x (dT/dx > 0), then heat will flow in the negative
x direction.
The Appendix contains a derivation of the thermal resistance for a general
geometry in which the area can be expressed as a function of a single dimension.
The result for the general formula is:
xð2
1 dx
R12 ¼
k12 AðxÞ
x1
r2
ln r1
R12 ¼ for a cylindrical shell
2πk12 L
For a spherical shell, with outer radius r2 and inner radius r1, the thermal
resistance is:
1 1 1
R12 ¼ for a spherical shell
4πk12 r 2 r 1
For any other geometry, an approximate model can be used, which involves first
defining two surfaces, calculating an average distance between them, and an
average area. A general approach is:
The mode of heat transfer between a solid surface and an adjacent fluid is termed
convection. It is governed by Newton’s Law of Cooling, which states that the rate of
heat transfer between a surface and an adjacent fluid is proportional to the surface
area and to the temperature difference between the surface and the fluid just outside
a thermal boundary layer (a region of influence within which the temperature
changes from the surface temperature to the free stream fluid temperature). The
proportionality factor (not necessarily a constant) is termed the convection coeffi-
cient, with the symbol “h” (not enthalpy, a totally different quantity). Newton’s
Law of Cooling is expressed mathematically as:
T surface T fluid
qconvection ¼ hAsurface T surface T fluid ¼
Rconvection
A thermal resistance associated with a convection boundary has been introduced,
which is inversely proportional to the convection coefficient and the surface area. In
some models, the convection coefficient can be a function of temperature (and thus
variable) and the surface area could change with time (i.e., a moving piston changes
the area of the cylinder wall exposed to the gases it contains).
The mechanism of convection is actually conduction. Heat flows by conduction
across the thermal boundary layer, which is usually thin compared to the size of the
3.4 Newton’s Law of Cooling 71
1 δ
Rconvection ¼
hAsurface kfluid Asurface
That is:
kfluid
h
δ
As might be intuitive, the thermal conductivity of the fluid is directly linked to the
convection coefficient (a measure of the effectiveness of the heat transfer between
the fluid and an adjacent solid). In addition, the thinner the thermal boundary layer,
the higher the convection coefficient. This thickness is influenced by the fluid
motion, as well as fluid properties (thermal conductivity, density, and specific
heat) and will be explored more fully later.
Chapter 9 develops a procedure for estimating convection coefficients using
dimensionless quantities (Nusselt number correlations) that characterize the flow
and temperature fields. Until then, appropriate values (or formulas) for convection
coefficients will be given in problem statements. Table 3.1 shows the order of
magnitude range expected for convection coefficients in SI units. These rules of
thumb can be used as a first guess, or as a reality check for a detailed calculation.
The art of making appropriate choices for numerical values for convection
coefficients and/or whether they are treated as variables (in space and/or tempera-
ture) is developed with experience.
For the window problem as stated, the inside window surface is exposed to room
air that is nominally still. That is, there is a natural convection with air as the fluid,
and a convection coefficient value between 1 and 10 W/m2/ C is expected. The
outside window is exposed to a crosswind. That is, there is a forced convection with
air as the fluid, and a convection coefficient between 10 and 100 W/m2/ C is
expected.
72 3 Heat Transfer Modes
For the window problem considered here, the ballpark estimates for the window
problem are:
W
h1 ¼ 5:0 for the inside surface (typical of natural convection in air)
m2 K
W
h2 ¼ 15:0 2 for the outside surface (typical of forced convection in air)
m K
The convective thermal resistances in the window problem are therefore:
1 1 1, 000 W
R1, h ¼ ¼ ¼ 12:5 C
h1 A ð5 W=m2 =KÞ ð16 m2 Þ kW kW
1 1 1, 000 W
R2, h ¼ ¼ ¼ 4:17 C
h1 A ð15 W=m2 =KÞ ð16 m2 Þ kW kW
These resistances are significantly larger than the conductive resistance (0.78 C/
W), indicating that there is a larger barrier to heat flow at the two convective
surfaces compared to the conductive resistance across the window itself. However,
radiation acts in parallel, and it must be estimated before a final conclusion can be
made on that score. . .
integration over all wavelengths of light. This law does not depend on the material
in any way, other than its blackness. However, no real bodies are perfectly black,
and they emit less total radiation than a black body. For engineering purposes, the
introduction of the so-called grey body defines a material property, the emissivity
(ε), that represents the ratio of the actual emitted power to what a black body
would emit:
qGreyBody
ε¼
qBlackBody
The emissivity is a crude, but very successful, modeling tool for estimating radia-
tion heat transfer. There is an extremely complex relationship between wavelength
and emissivity, influenced strongly by quantum mechanical effects. The molecules
of a real body tend to emit radiation strongly in localized bands of frequency.
Emissivities of representative material surfaces are shown in Fig. 3.7. Highly
reflective materials tend to have low emissivities (bottom plot). Most other
materials tend to have somewhat higher emissivities.
Not only do surfaces emit radiation, but they can also absorb incident radiation.
The absorptivity (α) is defined as the fraction of incident light that is absorbed by
the material. At a given wavelength of light, the absorptivity equals the emissivity
(Kirchhoff’s Law of Thermal Radiation).
However, the emissivity can be very different at different wavelengths. For
example, glass has a relatively high emissivity (and absorptivity) for infrared
electromagnetic radiation, but a low emissivity (and absorptivity) to visible light.
Therefore, windows are transparent to visible light, but are opaque (with a high
emissivity) to infrared, which is where terrestrial thermal radiation is centered.
To add further to the complexity, while a given surface is emitting radiation
(from the vibration of its molecules), photons that strike it from other sources can
either be transmitted (pass through, like visible light through a window), absorbed
near the surface, or reflected. Keeping track of all these phenomena involves
complicated geometric calculations, and a general treatment of radiation is beyond
the intended scope of this first course in heat transfer.
Fortunately, useful engineering approximations to radiation heat transfer can
often be made, so that radiation can often be included in a thermal resistance model.
In such limiting cases, radiation heat transfer involves heat transfer from (or to) a
surface. Radiation is like convection in that way. However, because the physical
mechanism is entirely different, the net heat transfer rate from (or to) the surface is
the algebraic sum of radiation and convection. That is, radiation and convection act
in parallel, not series. Convection involves thermal contact with the fluid immedi-
ately adjacent to the surface. Radiation involves thermal contact with distant
surfaces as electromagnetic waves travel between them. Two situations allow for
simplified models: an object completely surrounded by a much larger object, and a
radiation source imposed on an object.
74 3 Heat Transfer Modes
Fig. 3.7 Emissivity of various materials. The uncertainty (not shown) of all these values is quite
high. Data adapted from http://www.engineeringtoolbox.com/emissivity-coefficients-d_447.html,
accessed 2/5/2012
3.5 Stefan–Boltzmann and Kirchhoff’s Radiation Laws 75
If two objects, separated by a gas (or vacuum) that does not significantly absorb
radiation, can “see” each other, they exchange heat via radiation. When a convex
object (one that cannot see itself) with a surface temperature of T1 is completely
surrounded by a much larger object with a surface temperature T2 (shown
schematically in Fig. 3.8), the rate of heat transfer due to radiation between them
can be approximated as:
qrad, 1!2 ¼ ε1 σA1 T 41 T 42
where
The heat transfer rate can now be expressed as a thermal resistance between the two
objects:
T1 T2 T1 T2
q12 ¼ ¼
ð1=hr A1 Þ Rrad
Since the rate of heat transfer by radiation is now expressed in terms of a tempera-
ture difference, the temperatures of the nodes in a resistance network need not be in
absolute units, as long as the radiation coefficient (hr) is calculated using absolute
temperature.
50
45 ε1 = 0.8
Radiation coefficient (W/m2/K)
40 T1 = 298K
35 "h2"
30
25
h
20
15
10
5 "h1"
0
300 350 400 450 500 550 600 650 700 750 800
T2 (K)
The radiation coefficient depends strongly on the two surface temperatures, but
only on the emissivity of the smaller, surrounded, object. If these surface
temperatures are not known beforehand, the radiation coefficient cannot be
evaluated initially, and an iterative solution technique is needed. However, an
excellent first (possibly last) approximation can be made by “guessing” the surface
temperatures. To help make an intelligent guess, notice that, for T2 > T1, the value
of hr can be bracketed by:
Figure 3.9 shows these radiation coefficients for a surface 1 maintained at room
temperature for temperatures up to 800 K. For moderate temperature differences
between object 1 and 2, the radiation coefficient can be reasonably assumed to be
constant, on the order of 5–10 W/m2/K.
Since radiation and convection act in parallel, radiation is important when the
radiation coefficient is of the same order or much larger than the convection
coefficient. This situation occurs almost always when the convection environment
is natural convection of a gas (in which case hconvection is of the order of 1–10
W/m2 C). Radiation can be important in other convection environments, especially
at high temperatures, such as in furnaces.
Solar radiation incident on the Earth is approximated by a different model; the sun
does not completely surround the Earth. However, solar radiation can be treated as a
current source (Fig. 3.10).
3.5 Stefan–Boltzmann and Kirchhoff’s Radiation Laws 77
A flat surface held perpendicular to the sun’s rays outside the influence of the
atmosphere receives a solar flux of 1,400 W/m2 (the “solar constant”). This radia-
tion is partially attenuated as it travels through the Earth’s atmosphere. On a bright
sunny day around noon, a flat plate held normal to the sun will receive at most
approximately 1,000 W/m2. Some of this radiation is reflected, some is absorbed,
and the rest is transmitted. How much radiation is absorbed depends on the
material. Black objects absorb a lot; reflective objects absorb a little.
Other radiation sources can be treated as a current source. For example, in a
toaster oven, electrical energy is converted to thermal energy in a resistive element,
creating a glowing hot wire coil. Thermal radiation emitted by the coils is absorbed
by the surface of the toast which warms, dries, chars, and eventually burns.
where α is the net integrated absorptivity of the Earth (equal to approximately 0.9),
Io is the solar constant (1,400 W/m2), Ashadow ¼ πR2E is the shadow area the Earth
(RE ¼ 6.378 km is the Earth’s radius), Asurface ¼ 4πR2E is the surface area of the
Earth, ε is the net integrated emissivity of the Earth (approximately equal to the
absorptivity), TE is the temperature of the Earth in K, and Tspace is the temperature
of outer space (0 K). In this example, the use of the resistance coefficient hr is not
78 3 Heat Transfer Modes
300
295
α = 0.9
TEarth (K)
290
285
α = 0.8
280
275
270
0.7 0.75 0.8 0.85 0.9 0.95 1
Emissivity, ε
really needed because outer space is near absolute zero, and the equation can be
solved directly for the average temperature of the Earth:
0:25
α I0 α 0:25
TE ¼ ¼ 280:1 K
ε 4σ ε
Note that this temperature is independent of the size of the spherical planet, and a
first approximation to other planets can easily be made using the appropriate solar
constant based on the planets distance from the sun.
The temperature of the Earth from this model is plotted in Fig. 3.12 as a function
of emissivity for two values of absorptivity (0.8 and 0.9). As emissivity increases,
the temperature decreases. As absorptivity increases, the temperature increases.
Notice that for α ¼ ε, the predicted temperature of the Earth is 280 K ¼ 7 C ¼ 44 F,
which is about right. This simplified model captures the controlling physics of a
rather complex problem!
Consider two plates that are placed close together so that the gap between them is
much less than the width and height, i.e., a double-paned window. There is thermal
radiation exchange between the two inner surfaces that enclose the gap. However,
these two surfaces that “see” each other do not fit the thermal radiation criterion of
an object completely surrounded by another, case 1. However, the following
derivation yields a simple formula for radiation between these surfaces that can
be cast into an Ohm’s Law form.
Photons are continually being emitted in random directions by both surfaces
(1 and 2) at a rate that is governed by the Stefan–Boltzmann Law. In a short period
of time (Δt), the photon energy that is emitted by surface 1 (the hotter surface, say)
per unit area is:
n1 ¼ ε1 σT 41 Δt
n2 ¼ ε2 σT 42 Δt
For the case of infinitely large plates, all of the photons emitted by 1 will strike
surface 2 and vice versa. That is, the fraction of photons emitted by surface 1 that
strike surface 2 is unity. One of the three things will happen to emitted photons.
A fraction (α2) will be absorbed, a fraction will be transmitted (τ2, i.e., the photon
passes through) and a fraction will be reflected (ρ2). Mathematically:
α2 þ τ2 þ ρ2 ¼ 1
α1 þ τ1 þ ρ1 ¼ 1
q1 to 2 ¼ n1 ðα2 þ α2 ρ1 ρ2 þ α2 ρ1 ρ2 ρ1 ρ2 þ α2 ρ1 ρ2 ρ1 ρ2 ρ1 ρ2 þ Þ
The first term represents the photons emitted by 1 that are absorbed by 2. The
second term represents photons that reflect from 2, then reflect from 1 and are
80 3 Heat Transfer Modes
absorbed by 2 on the second pass. The third term represents those photons that
reflect again. In summation form:
X
1
E1 to 2 ¼ n1 α2 ðρ1 ρ2 Þi ¼ energy absorbed by surface 2 of photons emitted by 1:
i¼0
X
1
E2 to 1 ¼ n2 α1 ðρ1 ρ2 Þi ¼ energy absorbed by surface 1 of photons emitted by 2:
i¼0
X
1
1
ðρ1 ρ2 Þi ¼
i¼0
1 ρ1 ρ2
ð n1 α 2 n2 α 1 Þ
E12 ¼ E1 to 2 E2 to 1 ¼
1 ρ1 ρ2
ε1 ε2
q12 ¼ σ T 41 T 42
1 ρ1 ρ2
Note that if either surface has a low emissivity, the thermal radiation exchange
between surfaces is small. Therefore, in practice, only one surface need be coated
with a “low-e” coating to substantially reduce the radiation exchange across the gap
of a double-paned window.
Opaque surfaces are those which do not allow electromagnetic energy to pass
through them. That is:
For window glass, the transmittance of visible light is very high, by design.
However, the longer wavelength thermal radiation for nominal Earth’s ambient
3.5 Stefan–Boltzmann and Kirchhoff’s Radiation Laws 81
ε1 ε2
q12 ¼ σ T 41 T 42
1 ð 1 ε1 Þ ð 1 ε2 Þ
ε1 ε2
¼ σ T 41 T 42 for opaque surfaces
ε1 þ ε2 ε1 ε2
Expressed in an Ohm’s Law form (by expanding the temperature term twice):
q12 ¼ hrad ðT 1 T 2 Þ
where
ε1 ε2
hrad ¼ σ T 21 þ T 22 ðT 1 þ T 2 Þ
1 ð 1 ε1 Þ ð 1 ε2 Þ
ε1 ε2
hrad ¼ σ T 21 þ T 22 ðT 1 þ T 2 Þ
ε1 þ ε2 ε1 ε2
T H, walls T 1
qH, walls!1 ¼ hr, 1 A1 ðT H, walls T 1 Þ ¼
Rr , 1
82 3 Heat Transfer Modes
T 2 T C, walls
q2!C, walls ¼ hr, 2 A2 ðT 2 T C, walls Þ ¼
Rr , 2
where the radiative coefficient on the outside depends on the outside window
surface temperature (T2) and the outside walls (TC, walls) that the outer window
surface “sees”:
hr, 2 ¼ ε2 σ T 2C, walls þ T 22 ðT C, walls þ T 2 Þ
Notice that the temperature unit for radiative coefficient can be either C or K, since
it was defined from Newton’s Law of Cooling from a temperature difference,
whereas K must be used to evaluate hr. For the outside window surface:
hr, 2ðFIRST APPROXÞ ¼ ε2 σ T 2C, walls þ T 2C, walls ðT C, walls þ T C, walls Þ ¼ 4ε2 σT 3C, walls
hr, 2ðFIRST APPROXÞ ¼ 4ð0:9Þ 5:669ð10Þ8 ð0 þ 273Þ3
Notice that both of these radiative coefficients are of the same order of magnitude as
the convection coefficients. That means that radiation is important and should not
be neglected in this problem. The corresponding radiative resistance values are:
3.6 Single-Paned Window: Results 83
1 1 1, 000 W
R1, r ¼ ¼ ¼ 11:5 C
hr, 1 A ð5:4 W=m2 CÞð16 m2 Þ kW kW
1 1 1, 000 W
R2, r ¼ ¼ ¼ 15:1 C
hr, 2 A ð4:15 W=m2 CÞð16 m2 Þ kW kW
With all the pieces in place, the resistance network, and its reduction to a single
equivalent resistance, is shown with resistance values in ( C/kW) in Fig. 3.13.
Fig. 3.13 Single-paned window resistance values (in C/kW) and its reduction to a single
equivalent resistance. This calculation is the first iteration, in which the surface temperatures
were assumed in order to calculate the radiative resistances
84 3 Heat Transfer Modes
The window surface temperatures can be solved for using voltage divider
formulas. For example, the general formula derived in Chap. 1 for a node “i”
with thermal neighbors “j”:
X Tj
R
j, neighbors ij
Ti ¼ X
1
j, neighbors
Rij
Referring to the middle network of Fig. 3.13 and using a series resistance “jump”
across the immediate neighbor to a known temperature:
TH
=R1, eff þ TC=ðRk þR2, eff Þ =6:0 þ 0=ð0:78þ3:3Þ
25
T1 ¼ ¼ ¼ 10:1 C
=R1, eff þ 1=ðRk þR2, eff Þ
1
=6:0 þ 1=ð0:78þ3:3Þ
1
T2 ¼ 1 ¼ ¼ 8:18 C
=ðR1, eff þRk Þ þ 1=ðR2, eff Þ 1
=ð6:0þ0:78Þ þ 1=ð3:3Þ
Recall that the radiative resistances used a first approximation that the surface
temperatures were equal to the adjacent fluid temperatures. A second approxima-
tion (iteration) uses the temperatures just calculated to give an improved guess at
the surface temperatures, and therefore improved resistance estimates. This itera-
tive procedure is demonstrated in Fig. 3.14, which is a screenshot of a spreadsheet
designed for that purpose. The top block contains input parameters (which can be
simply changed in the spreadsheet to run different scenarios), followed by calcula-
tion of the fixed thermal resistances in the model developed here. Finally, the
iteration table shows the effect of improved “guesses” for this case study. Each
row represents a different iteration (index “k”). The two temperatures are the
“guesses” for the temperatures. The first iteration (k ¼ 0) is an input set equal to
the fluid temperatures (but any values could be manually placed). Then the radiative
coefficients are calculated based on these guesses, followed by the radiative
resistances, effective resistances (convection and radiation in parallel), and finally
the net equivalent resistance. For the next iteration, the two temperatures are
calculated based on the resistance values calculated from the previous iteration,
and therefore are improved “guesses.” It is apparent that only three iterations are
needed to converge to within three significant figures. However, in light of the
uncertainty in the conductive resistances (k value), and both convective resistances,
it can be argued that the first approximation is sufficient for this case.
This general procedure for performing iterative calculations arises frequently in
heat transfer applications, and will be returned too often, in different variations.
Finally, to answer the original question of the problem statement, the rate of heat
transfer through this window (of area 16 m2) is 2.436 kW. The total energy
3.6 Single-Paned Window: Results 85
INPUT PARAMETERS
w= 8 m, window width
H= 2 m, window height
Dx= 0.012 m, window thickness
TH = 25 oC, inside air and wall temperatures
TC= 0 oC, outside air and wall temperatures
k= 0.96 W/m/K, thermal conductivity of glass
h1= 5 W/m2/K, convection coefficient on inside
h2= 15 W/m2/K, convection coefficient on outside
e= 0.9 emissivity of glass
FIXED THERMAL RESISTANCES
Rk= 0.78125 oC/kW
Rh1= 12.5 oC/kW
Rh2= 4.166667 oC/kW
ITERATION TABLE
k T1 T2 h1,r h2,r R1,r R2,r R1,eff R2,eff Req q(kW)
0 25 0 5.40 4.15 11.57 15.05 6.01 3.26 10.05 2.487
1 10.05736 8.114674 5.01 4.34 12.48 14.40 6.25 3.23 10.26 2.437
2 9.779702 7.875645 5.00 4.34 12.50 14.42 6.25 3.23 10.26 2.436
3 9.776913 7.873849 5.00 4.34 12.50 14.42 6.25 3.23 10.26 2.436
4 9.776881 7.873826 5.00 4.34 12.50 14.42 6.25 3.23 10.26 2.436
5 9.776881 7.873826 5.00 4.34 12.50 14.42 6.25 3.23 10.26 2.436
6 9.776881 7.873826 5.00 4.34 12.50 14.42 6.25 3.23 10.26 2.436
Fig. 3.14 Worksheet designed for single-paned window with iteration procedure to calculate
radiative coefficients. The values for the first iteration (k) differ from the calculations in the text
because of round-off error in those hand calculations
transferred is the rate multiplied by the time, and the energy cost is the energy price
multiplied by the total energy transferred:
$20 2:436 kJ GJ 103 J 3, 600 s 24 h
Energy Cost ¼ 9
GJ s 10 J kJ h day
$4:21
¼
day
This energy cost estimate scales with the total surface area of window (a parallel
heat transfer concept). It may not seem like a lot, but it can add up over the course of
a year, and over a building that has many windows.
Engineering Significance: Notice that since the conductive resistance is much
smaller than the effective resistances on both sides of the window, increasing the
thickness of the window is not an effective means to reduce heating costs associated
with windows. On the other hand, introducing a second pane of glass with an air gap
86 3 Heat Transfer Modes
(or other gas) between them has the effect of introducing more convective/radiative
thermal resistances to the thermal channel. Indeed, double-paned windows very
effectively reduce the heat transfer rate. Workshop 3.1 develops simplified models
for analyzing double-paned windows.
Consider the cylindrical shell of inner radius r1, outer radius r2, and length L (into
the page) shown schematically in cross-section in Fig. 3.15. The inner surface is
maintained at a temperature T1 and the outer at T2. Conceptually, the shell can be
represented in rectangular coordinates by “cutting” the projection at a random
place, and straightening it out to reveal the projection shown of a wall of constant
thickness (Δr ¼ r2 r1), but with a cross-sectional area that varies from 2πr1L on
one side to 2πr2L on the other. The coordinate “r” on the original view will be
replaced by the coordinate “x” in the projection.
At steady-state, the heat transfer rate crossing the inner surface must equal the
rate crossing the outer surface. Furthermore, the heat transfer rate at any surface in
between must be equal. Invoking Fourier’s Law, in which the conductive heat
transfer rate in the x direction is proportional to the area normal (i.e., perpendicular)
to the heat flow and to the temperature gradient (with the thermal conductivity, k,
being the proportionality factor):
dT
qx ¼ kAðxÞ ¼ constant @SS
dx
The goal of the analysis is to express the conduction between the two surfaces in
terms of an Ohm’s Law form:
T1 T2
q12 ¼
R12
In general, the thermal conductivity is a mild function of temperature. Separating
the variables (T and x) in the Fourier’s Law expression:
dx
kdT ¼ qx
AðxÞ
Integrating from inner to outer surface (where the position goes from x1 to x2 and
the temperature from T1 to T2, and noting that qx is a constant):
Tð2 xð2
dx
kdT ¼ qx
AðxÞ
T1 x1
Tð2
kdT kðT 2 T 1 Þ
T1
kðT 2 T 1 Þ T 1 T 2
qx ¼ q12 ¼ xð2
R12
dx
AðxÞ
x1
xð2
1 dx
R12 ¼
k A ð xÞ
x1
xð2 ðr2
1 dx 1 dr 1 r2
R12 ¼ ¼ ¼ ln
k A ð xÞ k 2πrL 2πkL r1
x1 r1
The latter form (in terms of the ratio of radii) is obtained by dividing numerator and
denominator by r1. A plot of this ratio is shown in Fig. 3.16. It is clear that the
approximate value underestimates but approaches the exact value when the ratio of
radii approaches unity, the thin shell approximation. However, the error is less than
10 % up to r2/r1 ratios of 3.
1.5
Ratio of Exact to Approximate Thermal
1 r2 ln r2
Resistances: Cylindrical Geometry
R12,EXACT r1 r1
1.4
R12,APPROX r
2 2 1
r1
1.3
1.2
1.1
1
1 2 3 4 5 6 7 8 9 10
r2/r1
Fig. 3.16 Comparison of exact thermal resistance to approximate thermal resistance for a
cylindrical shell
Workshop 3.1. Double-Paned Window Models 89
• A spherical shell with inner radius r1 and outer radius r2 (see how the floor
conductive resistance is treated in Appendix 1 of Chapter 4. . .)
• A rectangular duct of aspect ratio (width to height) AR, length L, with inner
width w1, and thickness Δx
• A truncated cone with smaller area A1, larger area A2, and a distance L between
them (with insulated sides). . .
In an attempt to reduce the heat loss across a window, the single-paned window
from the opening example of this chapter is replaced with a double-paned window
in which a second pane of glass is added, with a gap between the plates (g). Estimate
the rate of heat loss and the energy cost as a function of gap width, and compare to
the single-paned window result. Compare the effects of typical window glass (with
an emissivity of 0.93 on both surfaces) and the performance with one of the inner
surfaces coated with a “low-e coating” (emissivity of, say 0.3). Also, compare the
replacement of air with argon.
It is a good idea to stop reading and think about this problem first and draw your
own thermal resistance network before going on.
Model Development
Heat transfer across the window is still a single thermal channel, but inclusion of a
second pane with a gap introduces additional thermal resistances. There is radiation
exchange between the two gaps (modeled as case 3: radiation between infinite
plates), and there is a parallel heat exchange mechanism by conduction and/or
convection. Two models for the latter are considered at this point: narrow gap and
wide gap.
g
Rk, gap ¼
kgas A
90 3 Heat Transfer Modes
Fig. 3.17 Thermal resistance network for a double-paned window with the narrow gap model
TH TC
q12 ¼ ¼ UAðT H T C Þ
Req
1 1 1
Req ¼ þ Rk þ 1 þ Rk þ 1
1
Rr , 1 þ R h, 1
1
Rrad, gap þ Rk, gap
1
R r , 2 þ R h, 2
1
The equivalent gap resistance increases with the gap width. Conceptually, the gap
acts like an insulating layer of material added, and since the thermal conductivity of
air (0.023 W/m/K) is much lower than that of glass (0.96 W/m/K), this added layer
is more effective than simply making the glass thicker. However, the radiation
channel across the gap reduces the effective insulating property (notice the dimen-
sionless parameter in the denominator). Given an effective radiation coefficient of
hrad,gap ¼ 6 W/m2/K, from experience, and kair ¼ 0.023 W/m/K, the value of the gap
width where the conduction and radiative resistances are equal (setting the dimen-
sionless parameter to unity) is g ¼ kair/hrad,gap ¼ 0.0038 m ¼ 3.8 mm. That is, for
gaps below this, radiation is dominant, and conduction dominates for wider gaps.
Since manufactured double-paned windows set the gap spacing to be typically
10–20 mm, this comparison suggests, tentatively, that radiation effects are minor
in comparison to straight conduction for actual windows. However, the assumption
that air in the gap does not move must be questioned. The air in the gap does not
remain stationary, and an additional convective-like mode of heat transfer occurs,
and described in the following wide gap model.
Workshop 3.1. Double-Paned Window Models 91
Fig. 3.18 Thermal resistance network for a double-paned window using the wide gap model
1 1 1
Req ¼ þ Rk þ 1 þ Rk þ 1
1
Rr , 1 þ Rh1, 1 Rrad, gap þ 1
RH, gap þRC, gap Rr, 2 þ 1
Rh, 2
The gap resistance consists of two convective resistances in series, and a reducing
factor due to radiation. Notice that the size of the gap does not affect the prediction
of this model.
Conceptually, and in practice, the conductive resistance across the glass itself
was shown to be negligible for the single-paned window, so that the heat transfer
92 3 Heat Transfer Modes
introduce important concepts of thermal boundary layers and thermal lengths that
will be useful in subsequent chapters, particularly in gaining a fundamental
understanding of boundary layer phenomenon in fluids that form the basis for
estimation of convection heat transfer coefficients.
The applications developed in this chapter correspond to cases that are devel-
oped in traditional textbooks, with exact solutions. The methods developed here can
be extended to a much broader set of problems.
In this section, the lumped capacity model is applied to the coffee/mug problem. All
of the capacitance of the system (mug plus coffee) is lumped into a single capacitor.
A thermal resistance network of multiple channels (top, side, and bottom) is
developed to model parallel paths for heat to flow from the coffee interior to the
ambient. A first model includes all convection and conduction modes (Model 1).
Then effects of radiation on the outer surfaces are included (Model 2). Finally, the
effect of evaporation at the coffee-free surface is included (Model 3). In all these
models, the resistance values are treated as constants, suitably chosen to represent
an average value during the cooling event. Use of constant resistances results in a
first-order system, and the entire event is characterized by a single overall heat
transfer coefficient (U) and a time constant (RC).
Figure 4.2 shows a resistance network that breaks down the total heat flux from the
hot coffee (at T, representing an average temperature of the interior of the coffee) to
ambient (at T1) into three parallel channels (top, side and bottom), each of which
consists of several resistances in series. Each individual resistance represents a
mode of heat transfer between one identifiable surface or fluid and another, with
nodes to identify each surface. Appendix 1 details the calculation of the individual
resistance values.
In this model, all the capacitance of the system (coffee plus mug) has been
lumped into a single node, and therefore the smaller filled nodal temperatures can
be related to the main capacity-carrying node, T, and the known ambient tempera-
ture through the methods developed in Chap. 1. To reiterate, open symbols are
4.1 Lumped Capacity Model for Coffee/Mug Problem 99
Top View
D W
L
V H
coffee H0
mug
Side View
reserved for nodes for which capacitance has been attributed, and therefore their
temperature is governed by a differential equation, not an algebraic relationship
between neighbors. At times, big filled symbols (rather than a battery symbol) will
be used to represent known temperatures. Small filled symbols represent unknown
intermediate temperatures of nodes that have no capacitance assigned to them.
The results of this model will be compared to the experimental data from
Chap. 2. It is noteworthy that the experimental method (an IR detector) gave direct
measurements of the outer surface of the side wall (Tos) and of the free surface (Ts),
not of the bulk average.
For the side channel, heat must first be transferred from the interior of the liquid to
the inner surface of the mug side wall. The resistor Rcs (for coffee/side) represents
that convection heat transfer mode. Next, the heat must cross the side wall through
the mug, from the inner surface to the outer surface, and that conduction mode is
represented by the resistor Rws (wall/side). Finally, heat must flow from the outer wall
to the ambient fluid, and that is a convective mode represented by Ras (ambient/side).
These three thermal resistances act in series, and therefore the total resistance of the
side channel is their algebraic sum. Once numerical values are estimated, judgments
about their relative importance can be made.
For the bottom channel, heat must flow from the interior of the coffee to the inner
surface of the bottom, or floor through a convective resistance (Rcb for coffee/
bottom). Heat must then cross through the mug wall through a conductive resis-
tance (Rwb for wall/bottom). Heat flows from the bottom of the mug across an air
gap then into the floor through a conductive path (Rfb for floor/bottom).
100 4 1-Node Transient Models
T∞
ct at
T(t) top
cs ws as T∞
side
cb wb fb
C bottom
top
T(t)
side T∞
bottom
C
T(t)
R
T∞
C
For the top channel, the free surface of the coffee does not rigidly fit into the
modes defined in Chap. 3. Convection was defined as heat transfer between a fluid
and a solid surface. However, the coffee-free surface is a boundary between two
fluids (air and coffee). Heat flows from the interior to the surface and then from the
surface to the ambient above it, and so two resistances in series that are like
convection resistances are introduced for the top channel (Rct for coffee/top and
Rat for air/top).
4.1 Lumped Capacity Model for Coffee/Mug Problem 101
Fig. 4.3 Spreadsheet implementation of extended lumped capacity Model 1: neglect radiation
and evaporation
Figures 4.3 and 4.4 show results from a spreadsheet implementation of the
model. The block of input quantities represents input values. Several of these inputs
have been calculated in other spreadsheets (and future chapters) and manually
input into this spreadsheet. The values chosen for the convection coefficients
(6.8 W/m2/ C for air/surface and 470 for coffee/surface locations) were determined
in a separate spreadsheet (detailed in a future chapter) as a suitable average value
for the entire cooling event.
All quantities in this block are fixed constants. More sophisticated models might
allow for variable coefficients, but then a numerical simulation of the event would
be required. On the other hand, the assumption of constant heat transfer coefficients
(suitably chosen averages) allows for a closed-form solution to the lumped capacity
model, with a net determined time constant and an overall effective heat transfer
coefficient (RC and U, shown in the results block). Figure 4.4 applies to
Model 3 discussed shortly (which includes radiation and evaporation effects).
The effects of radiation and evaporation are “turned off” in Fig. 4.3 by setting the
corresponding “h” values to a small number (a “zero” cannot be used, as the model
divides by this value), resulting in effectively infinite resistance values.
102 4 1-Node Transient Models
Fig. 4.4 Derived parameters used in Models 1, 2, and 3, with the following exceptions: for Model
1, the thermal resistances Rat,evap and Rat,rad evaluate to large (effectively infinite) values by setting
the corresponding heat transfer coefficients to low values (they can’t be zero, since the model
divides through by them). In Model 2, the thermal resistance Rat,evap is large
The plot of temperature vs. time in Fig. 4.3 shows that the predicted cooling is
noticeably slower than the experimental result. Recall that an experimental value of
U was banded between approximately 10 and 20 W/m2/K (the experimental result
being not a pure first-order response). The predicted overall U value of 6.0 W/m2/K
is below that range.
The table of channel resistances reveals more about the controlling routes for
heat to flow from the coffee to ambient. The net channel resistance is much lower
through the side wall than through the bottom channel, which is lower than the top
channel. This effect is largely due to the surface area (recall the side surface area is
more than half the total exposed area). Within the side channel, the resistance is
dominated by the outer equivalent resistance. One result of this effect is that the
outer surface temperature is much closer to the coffee temperature than ambient, as
confirmed experimentally.
4.1 Lumped Capacity Model for Coffee/Mug Problem 103
Radiation effects have not been included in the model of Fig. 4.2. The alternative
model of Fig. 4.5 adds radiation effects. Here, the mug of coffee sits in a room
whose walls and ceiling (the big outer box) may, in general, be at a different
temperature (T1w) than the air in the room. The exposed surfaces on the sides
and top of the coffee/mug system are in direct contact with the air surrounding them
(and modeled as convection), but in addition, these exposed surfaces “see” the walls
of the room it is in. The physical mechanism of this radiation heat transfer is
fundamentally different than the convection. Notice that now there are two
“ambients,” fluid and radiation wall.
Figure 4.6 shows this resistance network recast. At the top and side surfaces
exposed to air, the channels split, or branch. Consider, for example, the side
channel. In order for heat to flow from the coffee ultimately to ambient, it must
first flow from the coffee to the submerged portion of the inner surface of the mug.
From there, heat flows across the mug wall to its outer surface. The outer surface
branches into two channels, one to the fluid immediately adjacent to it (at T1) and
the other to the walls of the room (at T1w). Notice that the temperature at the mug
outer surface is represented by an open symbol. The temperature there cannot be
related to two other known temperatures by a simple voltage divider calculation
(recall Chap. 1). This network cannot be modeled as a simple RC network because
of the branching.
Fig. 4.5 Resistance network superimposed on a mug of coffee schematic that includes radiation
effects
104 4 1-Node Transient Models
top
T(t)
side T∞
bottom
C
R
Figure 4.7 shows the resistance network for the case when the walls of the room
and the air within it are assumed equal. The convective and radiative resistances act
in parallel on the top and bottom surfaces, and the entire network can be reduced to
a single R value, so that a simple RC circuit model can be used. When radiation and
convection act in parallel (to the same ambient temperature), the net heat transfer
coefficient is the sum of the two modes: hequiv ¼ hconvection þ hradiation .
Figure 4.8 shows the spreadsheet results when these radiation effects are
included. The value chosen for the radiation coefficient (6.6 W/m2/ C) was deter-
mined in a separate spreadsheet (detailed in a future chapter) as a suitable average
value for the entire cooling event. The model now shows good agreement between
theory and experiment, with perhaps a slightly slower initial cooling rate. The outer
equivalent resistance value is approximately half of what it was for the model that
neglected radiation.
Figure 4.9 shows the resistance network with evaporation effects included as a third
parallel channel between the free surface of the coffee and ambient. Figure 4.10
shows the spreadsheet result when this effect is included. The energy exchange
associated with the evaporation is modeled with an equivalent convection coeffi-
cient (hevap). While this energy exchange is by a mass heat transfer mechanism, not
a heat transfer mechanism, it can be expressed as being proportional to the temper-
ature difference (with the coefficient having a strong temperature dependence). The
selection of a specific constant value requires judgment, and a formal way of doing
that is the subject of Chapter 13. In the present case, introducing an approximate
4.1 Lumped Capacity Model for Coffee/Mug Problem 105
at,rad
at,evap
at,conv top
T(t)
ct as,rad T∞ = T∞w
side
cs ws as,conv
C bottom
cb wb fb
Fig. 4.9 Resistance network with evaporation included. A valuable exercise is to write in pencil
the values from Fig. 4.4 directly onto this sketch, visualizing the heat transfer being represented
evaporative channel increases the overall heat transfer coefficient from 10.9 to
11.9 W/m2 C, a 9.1 % increase. That is considered to be significant, but not
dominant. The effect of radiation is much more important, especially since radia-
tion acts in parallel with convection on the side wall, with its much larger surface
area than the free surface.
Figure 4.11 shows results (from an analysis in Chapter 13) of the effect of
temperature on the three heat transfer coefficients between the coffee-free surface
106 4 1-Node Transient Models
30
Heat Transfer Coefficient (W/m2/K)
25
20
15 Sum
10 Radiative
5
Convective Evaporative
0
25 35 45 55 65 75 85 95
Fig. 4.11 Results of a more detailed estimate of the heat transfer coefficients on the coffee-free
surface. The ambient temperature is 25 C
4.2 Heisler and Gurney–Lurie Charts from a 1-Node Lumped Capacity Analysis 107
and ambient. For natural convection, the convective heat transfer coefficient is a
function of the temperature difference between the solid and air surface. It is
actually zero when the coffee and ambient are at the same temperature, increases
sharply with temperature difference, then gradually increases. The radiative coeffi-
cient is a function of both coffee and ambient temperatures, and does not show a
sharp drop as the coffee temperature approaches ambient. Radiation becomes the
dominant mode of heat transfer as the coffee approaches thermal equilibrium with
ambient.
The evaporative term increases sharply as the coffee temperature approaches the
air temperature, and is an artifact of the use of the resistance model. In fact,
modeling evaporation as a dependent current source makes more sense in this
case. However, for coffee temperatures above 27 C in this case, the evaporation
coefficient is generally lower than both convection and radiation until approxi-
mately 90 C, above which the evaporation effect increases dramatically. This real
effect is due to the rapid increase in vapor pressure as the boiling point is
approached from below. The main point here is to argue that evaporative effects
are considered secondary to radiation effects, unless the coffee is within a few
degrees of its boiling point. As with radiation, for applications in which evaporative
effects dominate, other resources can be consulted.
Model Development
A general analysis will first be performed, and then applied to the specific case in
question. A thermal RC network superimposed on the sketch lumps the entire heat
capacity into a single node. A conductive resistance between the bulk interior of the
rod and its surface acts in series with a convective resistance between the surface
and the surrounding oil. Note that the capacitive-carrying node (open symbol) is not
placed at the geometric center for conceptual reasons, as the numerator of the
conductive resistance is an average distance between the interior and the surface. A
convective resistance between the surface of the object and the surrounding fluid
takes places at a well-defined surface. If radiation is important, it acts in parallel
with convection, and can be combined into a single convective/radiative resistance
(if the fluid and radiation wall temperatures can be considered to be equal).
For constant resistance and capacitances, the solution for the (dimensionless)
temperature as a function of time is:
T T fluid t
θ ¼ eðRk þRh ÞC
T initial T fluid
This relationship can be used for any object of any shape and construction for which
estimates can be made of the total capacitance (the object need not be uniform), a
conductive resistance between the interior and the surface and a convective resis-
tance at the surface. Conceptually, the temperature represents an average tempera-
ture of the object, and in general, it is recognized that the temperature is not uniform
in the object.
T(t)
T∞
+
Rk Rh
Fig. 4.12 Schematic and C
superimposed RC network for
a solid rod undergoing a
cooling or heating event
4.2 Heisler and Gurney–Lurie Charts from a 1-Node Lumped Capacity Analysis 109
T surface T fluid Rh 1 1
¼ ¼ ¼
T T fluid Rk þ Rh Rk =Rh þ 1 Bi þ 1
where the Biot number is introduced as the ratio of the conductive to convective
resistance. This relationship is independent of time. Rearranging for the surface
temperature:
T T fluid
T surface ¼ T fluid þ
Bi þ 1
The convective resistance is approximated as:
1 1
Rh ¼ ¼
ðConvection Coef:ÞðSurface Area exposed to fluidÞ hAs
This analysis demonstrates that the Biot number yields insight into the spatial
temperature distribution in a solid. All else being equal, small objects tend to heat
or cool uniformly, while large objects tend to have larger thermal gradients
within them.
For a homogeneous object, the total capacitance is C ¼ ρcV, where V is the total
volume of the object and the average temperature can be expressed as:
t
T T fluid ρcVRk
R
1þ h = Rk ðBiþ1
Bi
Þ kAt
θ¼ ¼e ¼e ρcVD
T initial T fluid
θ ¼ eðBiþ1ÞFo
Bi
where the Fourier number (Fo) has been introduced as a dimensionless time:
kAt αt
Fo ¼
ρcVD AD
V
The Fourier number is a measure of how far along a cooling or heating event an
object is. For short time (Fo 1), the dimensionless temperature is close to unity,
or the average temperature is close to the initial temperature. For long time
(Fo 1), the average temperature approaches ambient.
The effect of the shape of the object is manifested in the Biot and Fourier
numbers. There is a certain degree of latitude in precisely defining the average
conduction distance and average conduction area, consistent with lumping the
entire solid into a single node. The Heisler and Gurney–Lurie charts are developed
for the three classic coordinate frames that allow for exact theoretical analysis,
namely, Cartesian (wall), cylindrical and spherical. Interpretations of these cases in
which geometric averages are used are summarized in Fig. 4.13. Notice that the
Cartesian geometry (Fig. 4.14) consists of a wall (surface area of width height)
subjected to the same fluid environment on both sides. The centerline acts as an
insulated boundary, and only half of the wall needs be considered. In the detailed
solution to Workshop 4.1, several different interpretations of the conductive resis-
tance for the cylindrical case are developed.
This dimensionless temperature (θ) vs. dimensionless time (Fourier number) is
plotted in Fig. 4.15 for fixed values of the Biot number. The Heisler and Gurney–
Lurie charts contain plots of the centerline temperature in this form. The spatial
variation is displayed as the dimensionless surface temperature vs. the inverse Biot
number (Fig. 4.16). The Heisler and Gurney–Lurie charts are of similar form, but
show the temperature at various locations relative to the centerline. In this analysis,
only the surface temperature relative to the average temperature is directly avail-
able. Note that these “cooling curves” become independent of Biot number for large
4.2 Heisler and Gurney–Lurie Charts from a 1-Node Lumped Capacity Analysis 111
Fig. 4.13 Biot and Fourier numbers for classic geometries. Note that α = k/ρ/c
L L
T∞ T∞
Ts T(t) T(t) Ts
Rh Rk Rk Rh
Centerline
C C
L
T(t) Ts T∞
Centerline
Rk Rh
C
Solid Fluid
Fig. 4.14 RC network of a wall subjected to the same fluid on both sides. Top network shows a node
on each side, and could be used as a 2-node model (next chapter) if the fluid temperatures were
different on either side. For the symmetric case, the centerline acts as an insulated boundary due to
symmetry and the equivalent RC network (bottom) is considered in this section. The bottom schematic
applies directly to cylinders and spheres, where the centerline is a point (of zero surface area)
Biot number, in which case the surface temperature is close to the fluid temperature,
and therefore the cooling rate is controlled by the rate of conduction to the interior.
Low Biot number (high conductive, relative to convection) events result in uniform
temperatures within the solid, and the cooling or heating is controlled by the
convection.
112 4 1-Node Transient Models
1
0.9 Bi = 0.01
0.8
Dimensionless Temperature
0.7
0.6 Bi = 0.1
0.5
0.4
0.3
Bi = 1
0.2 Bi = 10
Bi = 100
0.1
0
0 2 4 6 8 10
Fourier Number (dimensionless time)
1
Bi = 0.01
Bi = 0.1
Dimensionless Temperature
0.1
Bi = 1
0.01
Bi = 100 Bi = 10
0.001
0.0001
0 2 4 6 8 10
Fourier Number (dimensionless time)
Fig. 4.15 Dimensionless temperature vs. Fourier number for various Biot numbers. Linear axes
(top) and semi-logy axes (bottom)
1
0.9
0.8
(Tsurface-Tfluid)/(Tave-Tfluid)
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
0.001 0.01 0.1 1 10 100 1000
1/Biot #
Fig. 4.16 Dimensionless surface temperature plotted against inverse Biot number
As ¼ πDL
The average distance (for the conduction distance) is taken to be half the radius
(quarter the diameter) and the average area is taken to be the geometric average
between the surface and the centerline:
D ¼ =4
D
1 πDL
A ¼ ðAs þ 0Þ ¼
2 2
A consideration of other conduction models is developed in the detailed solution to
the workshop presented at the end of this chapter.
The Biot and Fourier numbers, therefore, are:
!
Rk hD=4 2As
Bi ¼ ¼
Rh k As þ 0
hD
Bi ¼
2k
kAt ktπDL=2
Fo ¼ ¼
ρcVD ρc πD4 L D4
2
114 4 1-Node Transient Models
8αt
Fo ¼
D2
For the cooling event defined, the dimensionless temperature is specified as:
T T fluid 100 30
θ¼ ¼ ¼ 0:259
T initial T fluid 300 30
ðBi þ 1Þ
Fo ¼ lnθ
Bi
And for the time:
D2 Fo ρcD2 2k
t¼ ¼ ð1 þ BiÞlnθ
8α 8k hD
ρcD hD
t¼ 1þ lnθ
4h 2k
The cooling time increases linearly with diameter for low Biot numbers and
increases with the diameter squared for large Biot number events.
Results for the four diameter cases are summarized in Fig. 4.17. The cooling
time increases strongly with cylinder diameter. The temperature is nearly uniform
for small diameters, and large internal temperature gradients are apparent for large
diameters.
INPUT PARAMETERS
k 16 W/m/K
ρ 7820 kg/m^3
c 490 J/kg/K
h 300 W/m^2/K
Tinitial 300 oC
Tfluid 30 oC
Tfinal 100 oC
DERIVED PARAMETERS
α 4.18E-06 m^2/sec
θ 0.259
RESULTS
D (m) 0.001 0.01 0.1 1
Biot # 0.009375 0.09375 0.9375 9.375
Fourier # 145 15.7 2.79 1.49
cooling time (sec) 4.35 47.1 835 44,722
Surface temperature (oC) 99.3 94.0 66.1 36.7
Fig. 4.17 Spreadsheet solution for the quenching solid cylinder problem
4.3 Thermal Boundary Layers in Thick Walls 115
In the 1-node fixed lumped capacity model considered in the previous section, the
capacitance encompassed the entire solid object. However, at the instant the fluid
temperature is changed, there is a region near the surface that responds immedi-
ately, while the interior is unaffected for a period of time. That is, there is a time
delay between when the thermal signal at the surface occurs and when the interior
responds. This section addresses that deficiency by introducing variable-sized
nodes. The heating or cooling of a finite-sized object subjected to a sudden change
at its surface can therefore be analyzed in two distinct phases: a thermally thick
phase (phase I) and a lumped heating (or cooling) phase (phase II).
This phenomenon introduces the notion of a thermal boundary layer or a
penetration layer. A thermal disturbance at the surface propagates, or penetrates,
into the solid. The size of this boundary layer region grows as time progresses.
A thermally thick wall is defined as one in which the physical thickness of the wall
is larger than the penetration distance. Whether a given wall behaves as thermally
thick or not depends on the time duration after a change at the surface occurs.
While this chapter is focused on thermal boundary layers growing with time in a
solid, the concept of a thermal boundary layer is at the heart of modeling thermal
boundary layers growing in a fluid, and gives rise to an understanding of convection
coefficients. Two combination thermal properties combinations will naturally appear;
thermal diffusivity and thermal inertia. The thermal diffusivity (α ¼ k=ρ=c) determines
pffiffiffiffiffiffiffi
how thick a boundary layer is. The thermal inertia (Γ ¼ kρc ) determines the heat
transfer rate from the surface to the interior.
This section is long, and readers anxious to develop numerical methods can
skip directly to Chap. 5 from here, or skim the remainder of this chapter, especially
the plots.
The first variable-sized node case is one in which the surface temperature of a thick
wall is suddenly changed to a new value by some means and held there. The basic
growth of a penetration layer naturally emerges. An application of this case is the
so-called contact temperature, that is, the temperature that occurs at the interface of
two solid objects at different temperatures when suddenly placed in contact.
Fig. 4.18 1 Node model (with variable R and C) at time t and a short time later, t + Δt
4.3 Thermal Boundary Layers in Thick Walls 117
dE T surface T ave
¼ _ p T initial T ref
þ mc
dt R
which states that the rate of change of energy stored in the node equals the rate at
which heat enters from the surface plus the rate at which energy enters at the leading
edge. The energy stored in the node is changing because of its size (not its
temperature, which is constant). The conductive thermal resistance also changes
with time as the thermal wave propagates into the interior, spreading out. The rate
of change of energy stored is:
0 1
ððð Tðave
dE d B C d
¼ ρ@ ¼
cv dT AdV ρcv T ave T ref Aδ
dt dt dt
CV T ref
For a solid, c ¼ cv ¼ cp. Assuming that the size of the node is proportional to the
penetration distance (δ) and expressing the conductive resistance as the conductive
distance (fδ, where f is constant to be determined) divided by the thermal conduc-
tivity of the solid (ks) and contact surface area (A):
d
T surface T ave dδ
ρc T ave T ref Aδ ¼ fδ
þ ρcp T initial T ref A
dt kA
dt
Recognizing that only the depth δ changes with time, and rearranging and grouping
factors (note that the reference temperature cancels):
dδ k T surface T ave 1
¼
dt ρc T ave T initial f δ
dδ α
¼
dt f δ
where the combined thermal property α ¼ k/ρ/c called the “thermal diffusivity”
with SI units m2/s has been introduced. The left hand side represents the rate of
change of energy stored associated with the growing size of the node. The right
hand side represents the heat transfer rate into the nodal volume and decreases
as the penetration depth increases. As the penetration layer grows, it becomes
self-insulating.
118 4 1-Node Transient Models
ðδ ðt
f δdδ ¼ αdt
0 0
Performing the integration yields a simple (but not simplistic) expression for the
thermal penetration depth:
pffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi
δ¼ ð2=f Þαt
This expression shows that the penetration depth increases with the square root of
time. Also, the higher the thermal diffusivity of the material, the faster it grows. The
penetration depth increases with the square root of the thermal conductivity and
reflects competing effects. The conduction heat transfer rate is proportional to the
thermal conductivity, but the thicker the boundary layer, the greater the self-
insulating effect. The higher the combination ρc (which represents energy required
to change the temperature per unit volume), the harder it is for the thermal
disturbance to penetrate, with a square root dependency.
Expressing the penetration depth in terms of time:
f δ2
t¼
2α
This form shows that the time it takes for a thermal “disturbance” to propagate a
distance δ increases with the distance squared. Doubling the distance from the
surface increases the time it would take for penetration by a factor of four. This
result is due to the self-insulating property of the penetration layer.
Note that the growth of the thermal boundary layer does not depend on the
magnitude of the step change in surface temperature that initiates it. The leading
edge of the boundary layer can be envisioned as a signal that something has
happened at the surface, and it does not matter what that something is.
The rate of heat transfer from the surface to the interior is given by:
T surface T ave kA kA
qc ¼ ¼ T surface T ave ¼ pffiffiffiffiffiffiffiffiffi T surface T ave
R fδ 2f αt
pffiffiffiffiffiffiffi
The material property formed by the combination Γ ¼ kρc is termed the “thermal
inertia” or the “thermal hardness.” The rate of heat transfer decreases with time
(inverse square root dependency), again demonstrating the self-insulating nature.
At the moment the surface temperature changes (t ¼ 0), the heat transfer rate is
infinite, a result of the temporal discontinuity posed in the engineering problem
statement. As time passes, the wave penetrates deeper into the material, reducing
the temperature gradient that drives it.
The exact solution to this problem is given by:
rffiffiffiffiffiffiffi!
1 kρc
qc ¼ pffiffiffi A T surface T initial
π t
This exact solution differs from the 1-node model only in the value of the constant. The
1-node model reproduces the functional dependency on material properties and time
exactly. In this case, the 1-node solution can be “calibrated” against the exact solution
by a suitable choice of the average conductive distance (which defines “f”) such that:
sffiffiffiffiffi
1 1
¼ pffiffiffi
8f π
π
f ¼ ¼ 0:39
8
This value, somewhat less than half the size of the node, reflects that a more exact
solution would not predict a linear temperature distribution, but one skewed toward
the surface.
Table 4.1 shows material properties for several representative materials, sorted
in order of increasing thermal diffusivity. Liquid water and air are included as the
only fluids. A plot of the penetration distance as a function of thermal diffusivity
shown for these representative materials at various elapsed times is shown in
Fig. 4.19. Each boundary layer grows with a square root dependency on time.
The higher the thermal diffusivity (α), the faster it grows.
Results of this model to the cooking hamburger are shown in Figs. 4.20 and 4.21. The
penetration depth is shown as a function of time until it reaches the centerline in
Fig. 4.20, at which point the hamburger can be flipped. Not modeled yet is the
response of the cooked portion after flipping (best done with a more detailed
numerical model), during which time the temperature within the hamburger
redistributes. It is apparent that in the first minute, the thermal wave penetrations
120 4 1-Node Transient Models
Table 4.1 Room temperature thermal properties of selected substances (sorted by thermal
diffusivity)
(kρcp)0.5
Substance ρ (kg/m3) Cp (J/kg/ C) k (W/m/ C) α ¼ k/ρcp (m2/s) (J/m2/ C/s0.5)
Wood 420 2,720 0.11 9.63E08 354
Meat 950 3,520 0.4 1.20E07 1,157
H2O(l) 1,000 4,200 0.57 1.36E07 1,547
Glass 2,700 840 0.78 3.44E07 1,330
Brick 1,600 840 0.69 5.13E07 963
Steel 7,800 465 54 1.49E05 13,995
Cast Iron 7,200 447 52 1.62E05 12,937
Air 1.23 1,005 0.023 1.86E05 5.33
Aluminum 2,707 896 204 8.41E05 22,244
Copper 8,954 383 386 1.13E04 36,383
1000
1 year
H2O(L)
Brick
100 1 month
Glass
Meat
Penetration Distance (m)
1 day
10
1 hour
1
1 min
0.1
1 sec
Aluminum
Copper
0.01
Cast Iron
air
Steel
0.001
1.E-07 1.E-06 1.E-05 1.E-04 1.E-03
2
Thermal Diffusivity (m /sec)
Fig. 4.19 Penetration depths as a function of thermal diffusivity for selected materials
to approximately 0.5 cm. It takes two more minutes to propagate to 1.0 cm, and
almost 6 min to reach the centerline (1.27 cm).
Figure 4.21 shows temperature plotted against position at 1 min intervals. The
vertical dashed line shows the hamburger at the instant it is placed on the grill. After
1 min, the penetration layer has reached 0.5 cm, and the straight line between the
fixed surface temperature and the edge of the penetration layer gives a first approxi-
mation to the temperature distribution in the solid at that time. The penetration layer
4.3 Thermal Boundary Layers in Thick Walls 121
1.4
Centerline
Penetration Depth (cm) 1.2
0.8
Flipping Time
0.6
0.4
0.2
0
0 1 2 3 4 5 6
Time (minutes)
200
180
160
140 time
Temperature (oC)
120
Centerline
100 6 min
Top Surface
80
60 1 min
40
20
0
0 0.5 1 1.5 2 2.5 3
Distance from Cooking Surface (cm)
Fig. 4.21 Temperature profiles for cooking hamburgers. Straight lines from fixed surface tem-
perature to the initial temperature at the penetration depth is shown at 1 min intervals
continues to grow, but the spacing between lines decreases. The temperature gradi-
ent driving the event (Fourier’s law of conduction) decreases with time.
This response, of course, is consistent with experience. If a cooking hamburger
is cut in half at some point to check, there will be a cooked layer near the cooking
surface, and a raw hamburger above it.
122 4 1-Node Transient Models
qA ¼ qB
Applying the result from the suddenly heated wall problem, choosing signs such
that if A is hotter than B, heat flows from the interior of A (at TA) to the contact
point (at Tc) and from the contact point to the interior of B (at TB) or vice versa:
"sffiffiffiffiffi# rffiffiffiffiffiffiffiffiffiffiffiffiffiffi! "sffiffiffiffiffi# rffiffiffiffiffiffiffiffiffiffiffiffiffiffi!
1 k A ρA c A 1 kB ρB cB
Að T A T c Þ ¼ Að T c T B Þ
8f t 8f t
pffiffiffiffiffiffiffi
where the thermal inertia, Γ kρc, naturally appears.
Fig. 4.22 1-Node model for two material (A and B) at different initial temperatures brought into
contact, with variable R and C at two instants of time
4.3 Thermal Boundary Layers in Thick Walls 123
ΓA T A þ ΓB T B
Tc ¼
ΓA þ ΓB
which shows that the contact temperature is an average temperature weighted by
the thermal inertia. The higher the thermal inertia, the harder it is to change its
surface temperature, from which the term “thermal inertia” is based. Notice that
there is no time dependency, and therefore the contact temperature is immediately
established and maintained constant as time progresses, as long as both materials
exhibit thermally thick behavior. The rate of heat transfer from A to B (or vice
versa) decreases with time as a thermal boundary layer grows in both materials
(at different rates due to different thermal diffusivities), but the contact temperature
does not change with time.
The temperature difference ratio on the left hand side indicates that the contact
temperature resides between A and B. Whether it is closer to A or to B depends on
the ratio of the thermal inertia values. Consider the limits. If A has a much higher
inertia than B (ΓA ΓB and the temperature ratio is therefore small), then Tc is
close to TA. If A and B have equal inertias, then Tc is right in the middle.
A table of contact temperatures for a variety of material combinations is shown
in Fig. 4.23. In this case, the hotter material is at 100 C and the colder material is at
0 C. The temperature of the contact point is listed in the corresponding box.
For example, if a hot brick is placed on a cold steel plate, the contact temperature
will be 6.4 C. That temperature is much closer to the steel because the thermal
inertia of steel is more than ten times that of the brick.
A good classroom demonstration is to pass around two room temperature objects
of similar shape but made of materials of very different thermal inertia. The objects
are known to be at the same temperature, say room temperature. Each student (at a
warmer temperature than the objects) will grab the objects, one in each hand, and
will think that one is hotter than the other. The sensation of hot or cold depends
on the contact temperature, which will be different, even though the objects are
known to be at the same temperature. Note that thermal properties of human flesh
are close to that of water, so choosing a brick or other ceramic (a ceramic mug will
do nicely) and a metal will give a good difference.
dE T surface T ave
¼ _ T initial T ref
þ mc
dt Rk
d h i
ρc πR20 π ðR0 δÞ2 L T ave T ref
dt
2πkL T surface T ave dδ
¼ þ ρc2π ðR0 δÞ T initial T ref
ln R0Rf0 δ dt
δ
δ^ ¼
R0
t
^t ¼
t
Inserting these variables into the governing equation and rearranging:
αt
^ ^ ^
1 δ ln 1 f δ dδ ¼ 2 d^t
R0
4.3 Thermal Boundary Layers in Thick Walls 125
It is now possible to define the characteristic time for this problem by setting the
coefficient on the right hand side equal to a numerical value. That is, let
R20
t ¼
2α
Note that the same characteristic time as the finite cylinder is used (with the 2 in the
denominator) to make the dimensionless time the same as the Fourier number
derived previously for a cylinder with a fixed size node.
The governing differential equation for the penetration depth as a function
of time is:
1 δ^ ln 1 f δ^ dδ^ ¼ d^t =2
A good exercise in integrating by parts, not shown, yields the following solution,
with an initial condition that the penetration depth is zero at the initial time:
1 f δ^ 1 3 2
^ ^ ^
2ð1 f Þ ln 1 f δ 1 1 f δ ln 1 f δ 2 þ ¼ ^t
f2 2 2f f
This function is plotted in Fig. 4.24 for two values of f. The value 0.4 is based
on the experience from calibrating the thick wall problem, and the value 0.5
is the geometric average value. This result indicates that the initial thick wall heating
(or cooling) stage of a large Biot number (so that the surface temperature
equals the fluid temperature) solid cylinder will occur until the dimensionless time
0.8 f = 0.4
Penetration depth (d/r0)
0.6 f = 0.5
0.4
0.2
0
0 0.02 0.04 0.06 0.08 0.1 0.12 0.14 0.16
2
Dimensionless time (2at/r0 )
Fig. 4.24 Dimensionless penetration depth as a function of dimensionless time for the suddenly
heated cylinder
126 4 1-Node Transient Models
(Fourier number) equals approximately 0.1. For longer times, the fixed capacity
node is more appropriate as the cylinder gradually warms (or cools) as a lumped
thermal mass.
A variation of a suddenly heated wall is one in which a thick wall (with density ρ,
specific heat c, thermal conductivity k) at an initial temperature Tinitial is suddenly
exposed to a fluid with a constant convective/radiative coefficient h at a
temperature Tfluid. This case is more in line with the cases covered by the Heisler and
Gurnie–Lurie charts than the case where the surface temperature is changed to a known
value. It is more difficult to solve because the average temperature in the penetration
layer changes with time as the layer grows. Another variation (not considered here)
would involve subjecting the surface to a constant heat flux, with or without a simulta-
neous convection to the fluid.
d
T surface T ave
ρcAδ T ave T ref ¼ _ T initial T ref
þ mc
dt Rk
The current source represents the enthalpy flux into the node (the flow of internal
energy plus the flow work). The mass flux is related to the rate of change of the
boundary layer thickness:
dδ
m_ ¼ ρVA ¼ ρ A
dt
128 4 1-Node Transient Models
Fig. 4.26 RC network for a thermally thick wall suddenly subjected to a hot (or cold) fluid
The conductive resistance is equal to the conductive distance divided by the thermal
conductivity and area. The conductive resistance is taken to be a fraction (f) of the
thickness of the boundary layer. Conceptually, f is approximately ½ and could be
set to that value or “calibrated” against the published exact solution for this
problem.
The energy stored in the capacitive-carrying node depends on the size of the
node and its average temperature, both of which change with time in this case.
Using the chain rule and expanding all terms:
dδ dT kA T surface T ave dδ
ρcA T ave T ref þδ ¼ þ ρcA T initial T ref
dt dt fδ dt
The first term represents the change in energy associated with the growing size of
the node, and the second term represents the change in energy due to the gradually
changing surface temperature. Dividing through by the temperature change
(recognizing that the average temperature is midway between the surface and the
initial temperatures), and multiplying through by δ and dt:
d T surface T initial α
δdδ þ δ 2 ¼ dt
T surface T initial f
defined to have a value of unity initially, and to decay to zero as the surface
temperature approaches the fluid temperature as time goes to infinity:
T surface T fluid
θs ¼
T initial T fluid
δ
δ^ ¼
δ
Similarly, time is normalized by a characteristic time (t*) whose value will be
determined:
t
^t ¼
t
The energy balance becomes, after manipulation:
dθs αt
δ^ dδ^ þ δ^ 2 ¼ 2 d^t
1 θs f δ
The dimensionless parameter on the right side can be set equal to unity, revealing
the fundamental relationship between space and time:
αt
¼1
f δ 2
dθs
δ^ dδ^ þ δ^ 2 ¼ d^t
1 θs
Again, both the size and the average temperature of the boundary layer are
changing with time. This equation cannot be integrated, yet, as there are two
dependent variables (penetration distance and surface temperature).
Figure 4.26 shows that the surface temperature represents a voltage divider
between the ambient fluid and the interior:
Rearranging:
Rk T surface T
¼
Rh T fluid T surface
f δ=kA T surface T surface þ T initial =2
¼
1=hA T fluid T surface
Rearranging:
hδ T surface T initial
2f ¼
k T fluid T surface
The parameter hδ*/k is a natural Biot number for this problem, and can be used to
define the characteristic dimension by setting:
hδ
2f ¼1
k
The characteristic penetration distance is therefore naturally defined as:
k k
δ ¼
2f h h
h2
The surface boundary condition yields the following simple relationship
between the penetration distance and surface temperature:
1 θs
δ^ ¼
θs
The rate of change is:
dθs
dδ^ ¼
θ2s
4.3 Thermal Boundary Layers in Thick Walls 131
Integrating:
1
ln θs þ ¼ ^t þ c
2θ2s
The initial condition is that the dimensionless temperature equals unity at time
t ¼ 0, and therefore the constant of integration is c ¼ ½.
The final relationship between surface temperature and time is:
!
1 1
ln θs þ 1 ¼ ^t
2 θ2s
The surface temperature cannot be expressed analytically in terms of time, but the
time is expressed in terms of the surface temperature. Therefore, a closed-form
solution is obtained, and the boundary layer thickness and surface temperature are
simply related. A plot of these functions is given in Fig. 4.27. The linear scale
shows the penetration depth increasing with a vertical slope initially, and a gradu-
ally decaying slope. The surface temperature drops quickly at early time, and
continues to drop (i.e., approach the fluid temperature) with time, but with a
decreasing rate. After one time constant (t ¼ t*), the dimensionless surface
temperature is 0.47. After ten time constants, it is 0.20 and after 100 time constants
it is 0.07.
Temperature profiles (temperature vs. position at various times) are shown in
Fig. 4.28. For each series, a straight line is drawn from the surface temperature to
the penetration distance at that point. The penetration layer grows much like the
case of a fixed surface temperature, but in addition, the surface temperature
gradually approaches the fluid temperature. There is a rapid change initially, and
the spacing between fixed temperature lines decreases as time increases. There is no
steady-state solution for the truly infinitely thick case.
0.4
0.2
0
0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.6 1.8 2
Time (t/t*)
1 10
0.9 9
qs = (Tsurface-Tfluid)/(Tinitial-Tfluid)
0.8 8
Penetration Depth(δ/δ∗)
Surface Temperature
0.7 7
0.6 6
0.5 5
0.4 4
0.3 3
0.2 2
0.1 Penetration Depth 1
0 0
0.0001 0.001 0.01 0.1 1 10 100
Time (t/t*)
Fig. 4.27 Surface temperature and penetration distance as a function of time (all dimensionless).
The top figure is on linear axes and the bottom on semi-log x axes
temperatures are different, namely 100 C for boiling and 177 C for baking.
The dimensionless parameters for these cases are the characteristic time
(t* ¼ 2.7 s for boiling and 2,972 s for baking) and characteristic penetration depth
(δ* ¼ 0.8 mm for boiling and 26.7 mm for baking). These differences are due to the
convection coefficient. The higher convection coefficient for boiling means the
heating of the outer layers takes place quicker, but penetrates a shorter distance.
4.3 Thermal Boundary Layers in Thick Walls 133
1-θs = (Tsurface-Tinitial)/(Tfluid-Tinitial)
0.9
0.8
0.7
0.6
t/t*= 10
0.5
0.4
0.3 1
0.2 0.1
0.1
0.01
0
0 0.5 1 1.5 2 2.5 3 3.5 4
Dimensionless Penetration Depth (δ /δ∗)
1
0.9
1-θs = (Tsurface-Tinitial)/(Tfluid-Tinitial)
2.0
0.8 1.8
1.6
0.7
1.4
0.6 1.2
time
0.5 1.0
0.8
0.4
t/t*= 2 0.6
0.3 0.4
0.2 0.2
0.1 0.2
0
0 0.5 1 1.5 2
Dimensionless Distance (x/δ∗)
Fig. 4.28 Temperature profiles (temperature vs. distance from surface) at various times. The top
plot shows times increasing by an order of magnitude. The bottom plot shows lines with equal
increments (0.2) up to two time constants. The dotted line is for t ¼ t*. The surface temperature is
presented as 1-θs to correspond to a dimensional case in which the fluid temperature is higher than
the initial temperature. For each curve, a straight line from the surface to the leading edge is
shown. More detailed models in future chapters will capture the curvature
The surface temperatures of the two cooking methods are shown in Fig. 4.30 for
20 min of cooking. The safe cooking temperature (165 F ¼ 74.2 C) is indicated as
a dotted line. Boiling causes the surface temperature to rise above the safe cooking
temperature in a very short time, and then gradually approach (the fluid tempera-
ture). On the other hand, with baking, the surface temperature increases slowly and
134 4 1-Node Transient Models
Fig. 4.29 Parameter values for boiling (left) and baking (right)
120
100 Boiling
Surface Temperature (oC)
60
Baking
40
20
0
0 5 10 15 20
Time (min)
after 20 min is near the safe cooking temperature, but still far from the fluid
temperature (177 C). That is, the surface layers are overcooked during boiling,
while the interior is still raw (making the chef cringe).
The corresponding depth of penetration of the surface layer is shown in
Fig. 4.31. The penetration depth grows somewhat faster in the boiling case, but
not dramatically different, since it is the conduction within the solid that is the
primary factor in the propagation of the thermal wave forward. Higher convection
driving the surface does have a noticeable influence on penetration depth, however.
The temperature distribution within the solid is shown in Figs. 4.32 (for boiling)
and 4.33 (for baking) for the early times. Figures 4.34 and 4.35 show the
4.3 Thermal Boundary Layers in Thick Walls 135
0.02 Centerline
0.015
Boiling
Penetration Depth (m)
Baking
0.01
0.005
0
0 5 10 15 20
Time (min)
Fig. 4.31 Penetration depths for boiling and baking chicken. The centerline of a 3.8 cm thick
sample is shown
120
Fluid Temperature
100
Centerline
60
40 time
20 60 sec
10 sec
0
0 0.5 1 1.5 2
Distance from surface (cm)
Fig. 4.32 Temperature distributions for boiling for the first minute of cooking (lines at 10 s
intervals)
temperature distribution for later times. For boiling, the surface temperature
exceeds the safe cooking temperature within the first 10 s of cooking, but does
not penetrate very far. For baking, the temperature is more uniform, but cooking
still proceeds by heating an outer layer inward.
136 4 1-Node Transient Models
200
Fluid Temperature
180
160
Centerline
140
Temperature (oC)
120
100
Safe Cooking Temperature
80
60
time
40
6 min
20
1 min
0
0 0.5 1 1.5 2
Distance from surface (cm)
Fig. 4.33 Temperature distributions for baking for the first 6 min (lines at 1 min intervals)
120
Fluid Temperature
100
80
Temperature (oC)
60
time
40
6 min
20
1 min
0
0 0.5 1 1.5 2
Distance from surface (cm)
Fig. 4.34 Temperature distributions for boiling for 6 min (lines at 1 min intervals)
These results are all consistent with experience, but hopefully now with a deeper
fundamental grasp. The slower something is cooked, which is controlled by the
convection environment, the more uniform the cooking will be, as conduction to the
interior limits how quickly it cooks in the center.
4.3 Thermal Boundary Layers in Thick Walls 137
200
Fluid Temperature
180
160
Centerline
140
Temperature (oC)
120
100
80 Safe Cooking Temperature
60 time
30 min
40
20
5 min
0
0 0.5 1 1.5 2
Distance from surface (cm)
Fig. 4.35 Temperature distributions for baking for 30 min (lines at 5 min intervals)
The focus of this analysis is on the early cooking times, when the cooking object
exhibits thermally thick behavior. When the penetration depth reaches the center-
line, the object is no longer thermally thick, and the fixed size 1-node model
(or more detailed numerical analysis) is more appropriate.
closed-form estimate the response. If it is established that the scenario falls into a
thick wall category, that model can be used. The 1-node model is not restricted to
any geometry, or to homogeneous objects. Informed estimates of conductive and
convective/radiative resistances are needed. The chapters on multidimensional
steady-state conduction will provide additional tools for that. For cases where the
change in the environment is not sudden, or there are additional changes, numerical
methods that address time dependency (i.e., Euler method) can be used.
Two examples that extend the method to situations not covered in the Heisler or
Gurnie–Lurie charts are considered in detail next. In one, an internal heat genera-
tion term is added to the cylindrical geometry case to model the effect of
microwaving. In the other, the cooling mug of coffee is revisited, with a focus on
the initial moments after pouring hot coffee into a room temperature mug.
If it is judged that more detail is needed, then the next step is to begin the process
of breaking physical space into more than 1-node. The next chapters develop that
methodology.
An application that ties together several concepts from this chapter and shows the
versatility of the 1-node models is to analyze the response of a room temperature
mug immediately after hot coffee is poured into it. There is an initial heating phase
during which time the mug acts as a thermally thick wall, followed by a phase
where the mug is simultaneously heated by the coffee and cooled by the air until it
reaches a quasi-steady state temperature.
Imagine it takes no time at all to pour hot coffee into a room temperature mug.
Imagine also that the coffee behaves like a solid, and does not move after it is
poured. The interface between the mug and coffee will immediately attain an
intermediate contact temperature, and a thermal wave will propagate into both
the coffee and the mug (but at different rates, due to different thermal properties).
The outer temperature of the mug remains at its initial temperature during this
phase, and the variable-sized nodal analysis applies. Once the penetration depth
reaches the outer surface of the mug, the fixed size nodal analysis applies. This
behavior is developed in this section.
In this analysis, the average temperature of the coffee is assumed to remain fixed
at the boiling point of water (100 C). This assumption is equivalent to assuming
that the coffee has an infinite capacitance, so the heat transferred to the mug does
not change the coffee temperature. In the next chapter, this assumption will be
relaxed, and the coffee will cool simultaneously with the mug being heated. That
problem, however, cannot be solved in closed form, and a numerical simulation is
developed for that problem.
4.4 Cooling Mug of Coffee Revisited: Mug Heating Phases 139
During the initial phase of heating, the thin-wall approximation (mug thickness
much less than the inner diameter) is invoked, so that the mug behaves like a thick
wall of constant-area. A good exercise would be to apply the cylindrical model
instead. Also, an alternative model to treating the coffee as a solid during this phase
would be to assume a representative value of convection (say, 400 W/m2/K).
Table 4.2 lists thermal properties assumed for a typical ceramic and for coffee at
nominal room temperature values (the thermal properties are assumed to not change
significantly with temperature).
The contact temperature, that is, the temperature that is achieved at the instant of
the event is therefore:
T c ¼ 68:2 C
Notice that this temperature is different than the 87.7 C that was calculated for the
starting temperature of the main cooling event. The latter thermodynamic calcula-
tion depends on the finite amount of coffee and mug and is a fundamentally
different phenomenon than the contact behavior which is independent of
material size.
Immediately after the coffee is poured, the contact temperature of 68.2 C is
established and a thermal boundary layer grows in both the ceramic and the coffee.
The underlying model is valid as long as the material is thermally thick. That
criterion is met as long as the thickness of the growing boundary layer is less than
the physical thickness of the material (w):
δ<w
Inserting the suddenly heated wall result for the boundary layer thickness as a
function of time:
pffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi
δ¼ ð16=π Þαt < w
Table 4.2 Property values for coffee/mug problem at nominal room temperature
Property Symbol Unit Coffee (A) Ceramic (B)
Thermal conductivity k W/m/K 0.6 1.0
Density ρ kg/m3 1,000 1,700
Specific heat c J/kg/K 4,200 800
Thermal diffusivity α k=ρ=c m2/s 1.43(10)7 7.35(10)7
pffiffiffiffiffiffiffi
Thermal inertia Γ ¼ kρc J/s0.5/m2/K 1,587 1,166
140 4 1-Node Transient Models
π w2
t<
16 α
For the coffee mug:
π ð0:00398 mÞ2
t<
16 7:35ð10Þ7 m2 =s
t < 4:2 s
100
90 e
m
Ti
80
Contact Temperature
70
Temperature (oC)
60
50
e
m
40 Ti
30
20
10
Coffee Mug
0
4 2 0 2 4
Distance from Inner Wall (mm)
Fig. 4.36 Temperature profiles for the first 5 s of the coffee cooling example. Temperature is
plotted against position at 1 s increments. Each curve is a parabolic fit (explained in Appendix 2)
4.4 Cooling Mug of Coffee Revisited: Mug Heating Phases 141
mug penetration depths is a direct result of the thermal diffusivity being approxi-
mately four times as great in the mug as in the coffee. The leading edge of the
boundary layer advances with time, but the incremental change (i.e., space between
curves) decreases with time (because the temperature gradient at the wall that
drives the heat decreases).
The coffee in this model is treated as a hypothetical solid. Of course, the coffee
flows, introducing another mechanism for heat transport. There are actually two
distinct mechanisms for liquid movement. The coffee was just poured, so it is
“churning.” Even if that effect settles (but in 10 s, that’s not likely to be complete),
there is a natural convective mechanism. The coffee adjacent to the mug will be
colder, and hence slightly more dense, than the coffee in the middle and will tend to
fall along the wall, to be replaced from the top. A mild circulation pattern will be
induced that profoundly changes the thermal behavior. Convection coefficients
allow engineering models to incorporate these effects. If incorporated, these effects
would increase the effectiveness of heat transfer on the coffee side, and result in a
somewhat higher contact temperature. Also, the contact temperature would drift.
Note that during this initial mug heating phase, the outer wall of the mug remains
at ambient temperature, which means that heat is not being lost by the coffee/mug
combination. This initial phase involves redistribution within the original system
boundary.
The thermally thick variable capacitance 1-node model that produced these results
breaks down as soon as the leading edge reaches the outer wall of the mug. There is
a shift to a new phase, and a new model, occurs. A conventional fixed size model
is shown in Fig. 4.37. Treating the mug itself as a 1-node model in contact
with coffee at a fixed temperature on one side and air on the other, the mug will
continue to warm to an intermediate temperature between the air and the coffee.
This process establishes a quasi-steady balance between the mug and coffee, and
they subsequently cool together in a third phase, namely, the main cooling event
analyzed in Chap. 3.
The solution to this problem, with the coffee (and air) temperature fixed is:
T mug T ss t
¼ eRC
T mug, initial T ss
T coffee
ðRcm þRm =2Þ þ ðRmaTþR
air
m =2Þ
T ss ¼ 1
ðRcm þRm =2Þ þ ðRma þR
1
m =2Þ
C
RC ¼ mug
1
Rcm þRm =2 þ Rm =2þR
1
wa
Input and derived parameter values for the phase II mug heating are listed in
Table 4.3.
The time constant of 23.2 s is long compared to the 4.2 s it took for the initial
thermally thick boundary layer phase, and short compared to the subsequent
cooling of the coffee/mug assembly. Experimentally, the mug temperature peaked
at about a minute, giving good order of magnitude agreement.
The model predicts the temperature of the mug at its centerline (T). The
temperatures at the inner and outer walls (Ti and To) of the mug are related by a
voltage divider-type calculation. The inner wall temperature is obtained by equat-
ing the heat rate from the coffee to the center with the heat rate from the coffee to
the inner wall:
qcoffee>mugcenter ¼ qcoffee>innerwall
T coffee T T coffee T i
¼
Rcm þ Rm =2 Rcm
A similar analysis between the mug center and ambient air yields an expression for
the outer wall temperature:
4.4 Cooling Mug of Coffee Revisited: Mug Heating Phases 143
Rm1
To ¼ T1 þ ðT T 1 Þ
Rm1 þ Rm =2
Figure 4.38 shows temperature profiles during the second phase of heating of the
mug at 10 s increments. The dashed line shows the temperature profile at equilib-
rium. The coffee temperature is fixed in this model at 100 C. Within the mug wall,
straight lines are drawn from the inner surface to the center and from the center to
the outer wall. In moving from phase I to II model, there is a discontinuous jump on
the outer wall surface from ambient (25 C) to the value given by this second phase
of mug heating (38.7 C). There is a similar discontinuous jump from the contact
temperature used in the infinite mug phase (68.2 C) to the value of this model
(69.8 C), but the change there is (coincidentally) less obvious. The thicknesses of
the fluid thermal boundary layers shown are estimates from a future chapter and are
meant to be illustrative. This model indicates that a concave up shape persists for
the temperature profile in the mug wall as the wall heats, and eventually attains a
linear temperature distribution in the mug at equilibrium. The model is focused on
the heating of the mug in the initial stages. The gradual decrease in coffee
temperature with time follows with the next phase of the cooling, which is taken
up further in the next chapter.
144 4 1-Node Transient Models
100
90 equil
60
80
50
70 40
Temperature (oC)
60 30
20
50
10
40 0
30
20
10
Coffee Mug Air
0
-2 -1 0 1 2 3 4 5 6
Distance from Inner Wall (mm)
Fig. 4.38 Phase II heating of mug. Temperatures are plotted against distance from the inner wall
of the mug at 10 s increments of time (from the start of phase II at 4.2 s). The dashed line shows the
temperature profile at quasi-equilibrium (steady-state, with the coffee and air temperatures fixed).
The thermal boundary layer thicknesses in the fluids (coffee and air) are estimates based on models
of future chapters
In this appendix, the formulas used to calculate the individual resistance values are
detailed. Figures 4.1 and 4.9 are repeated here for reference. Input parameter values
were listed in Figs. 4.4 and 4.10. The rationale for choosing values is described,
much of the detail of which is developed in later chapters.
D W at,rad
at,evap
L at,conv top
T(t)
V H
ct at,rad
side
T∞ = T∞w
coffee H0 cs ws as,conv
C bottom
mug cb wb fb
Appendix 1. Detailed Calculation of Individual Coffee Mug Thermal Resistances 145
1 1
Rct ¼ ¼
hcoffee=surface Asurface hcoffee=surface πD2 =4
1 1
Rat ¼ ¼
heffective Asurface heffective πD2 =4
The values chosen (6.8, 6.6, and 10 W/m2/K for convective, radiative, and evapo-
rative) were chosen based on detailed Nusselt number and radiation coefficient
analyses (methods developed in later chapters) for a coffee temperature of 70 C.
1 1
Rcs ¼ ¼
hcoffee=side AInnerSurface hcoffee=side ðπDLÞ
The value for hcoffee/side (470 W/m2/K) was obtained from a Nusselt number
calculation for a coffee temperature of 70 C.
A1 ¼ πDðH LÞ ¼ 0:0198 m2
Surface 2 is defined as the total surface area of the outer wall exposed to air,
including the top rim and the inner surface area above the coffee surface. This 2D
conduction problem is discussed in some detail in a future chapter. The area is:
π
A2 ¼ π ðD þ 2wÞH 0 þ πDL þ ðD þ 2wÞ2 D2 ¼ 0:0372 m2
4
The outer area is 88 % greater than the inner one. The geometric average area is:
The average distance between surfaces 1 and 2 (Δx12) can be taken to be simply the
wall thickness, w, although that underestimates the true distance. The thermal
resistance is:
Δx12 w
Rws ¼ ¼
k12 A12 k12 ðA1 þ A2 Þ=2
The thermal conductivity k12 is something you “look up” for the material in
question, unless there is more specific information available for a material in
question. In this case, an Internet search (January 30, 2011) of “thermal conductivity
of ceramic mug” yielded:
http://www.askmehelpdesk.com/physics/why-ceramic-mug-cools-liquid-faster-
98327.html
k12 ¼ 15 W=m=K
http://www.madsci.org/posts/archives/2004-12/1102383405.Eg.r.html
convection in parallel with radiation with ambient air. Technically, the inner
portion “sees” the coffee and itself in addition to ambient, but this is a small part
of the total exchange so this effect is not considered. The resistances are:
1 1
Ras, conv ¼ and Ras, rad ¼
hair=sides A2 hradiation A2
The values for hair/sides (6.8) and hradiation (6.6) are obtained from a Nusselt and
Kirchhoff analysis for a coffee temperature of 70 C.
1
Rcm ¼
hcm πD2 =4
where hcm is taken as the same natural convection value as between the coffee and
the sides.
Δx12 w
Rwb ¼ ¼
k12 A12 k12 A12
estimated. A radiative channel between flat plates exists between the floor and the
bottom.
Then there is a conductive series resistance from the table surface toward the
interior of the table. To estimate this resistance, assume the table is large and take a
long range view so that the heat transfer emanates outward spherically. The inner
surface (surface 1) is taken to be a hemisphere with a radius such that the surface area
of the hemisphere equals the surface area of the floor underneath the mug. That is:
2πr 21 ¼ π ðD þ 2wÞ2 =4
or
pffiffiffi
r 1 ¼ ðD þ 2wÞ= 8
The rate of heat transfer across a hemispherical shell of inner radius r1 and outer
radius r2 (from 1 to 2) is
dT
q12 ¼ k2πr 2
dr
Separating variables and integrating:
Tð2 ðr2
q12 dr
dT ¼
2πk r2
T1 r1
1 r2
q12 r q12 1 1
T2 T1 ¼ ¼
2πk 1 r1 2πk r 2 r 1
ðT 1 T 2 Þ
q12 ¼
1 1
2πk r1 1
r2
In this case, surface 1 represents the floor surface (subscript “b” for bottom), which
is modeled as a hemisphere of radius r1 (that gives the same area as that of the floor
under the mug), and surface 2 represents infinity (so 1/r2 ! 0 and T2 ¼ T1 is
ambient). The heat transfer rate, defining the conductive resistance, is:
T1 T1
q11 ¼ ¼ 2πkr 1 ðT 1 T 1 Þ
R11
pffiffiffi
1 2
Rb1 ¼ ¼
2πkr 1 πkðD þ 2wÞ
The following table details results for the floor resistance estimate. This analysis
could use a couple of schematics, but the text in the opening paragraph of this
Appendix 2. Parabolic Fits for Plotting Temperature Profiles 149
section contains a word picture. In the end, the result suggests that the total
resistance through the bottom of the mug (40.2 C/W) is much higher than between
the free surface and ambient (8.51 C/W), which is less than that between the side
wall and ambient (2.21 C/W). That means the bottom surface behaves as a nearly
insulated surface.
edge of the boundary layer and forces the slope to be zero at the edge of the boundary
layer. That is, with “x” the distance from the wall, an assumed parabola is:
T ðxÞ ¼ a þ bx þ cx2
where the coefficients (a, b, c) are determined from constraints imposed on the fit.
At the wall surface (x ¼ 0), the temperature is fixed at Tc:
or simply, a ¼ Tc.
At the edge of the boundary layer, x ¼ δ, the temperature is set to ambient:
T ðδÞ ¼ T 1 ¼ T c þ bδ þ cδ2
where the result for coefficient “a” has been inserted. Also, the slope at the edge of
the boundary layer is set to zero:
dT
¼ 0 ¼ b þ 2cδ
dx x¼δ
T ðδÞ ¼ T 1 ¼ T c cδ2
Tc T1
c¼
δ2
Inserting this into the third constraint:
2ðT c T 1 Þ
b ¼ 2cδ ¼
δ
A curve fit that yields an approximate shape for the temperature profile therefore is:
x x 2
T ðxÞ ¼ T c 2ðT c T 1 Þ þ ðT c T 1 Þ
δ δ
A somewhat more compact and dimensionless form of this expression is:
T ðxÞ T 1 xx
¼ 2
Tc T1 δ δ
This formula does not give the exact shape of the temperature profile, but an
approximate fit. The time dependency of the profile is contained in the boundary
layer thickness, δ, which grows with time.
The inner wall of the mug is at the contact temperature, and the temperature falls
within the thermal boundary layer, eventually reaching ambient. There is no single
Appendix 2. Parabolic Fits for Plotting Temperature Profiles 151
where the coordinate x is measured from the inner wall of the mug outward. Within
the boundary layer (x < δm), the temperature profile was fit to a parabola to generate
the plot of Fig. 4.36, and outside the boundary layer (x > δm), the temperature is
ambient. Therefore, the integration can be broken into two pieces:
δðm ðw
T ave w ¼ T ðxÞ dx þ T 1 dx
x¼0 δm
2
The parabolic fit for temperature is: T ðxÞ ¼ T c 2ðT c T 1 Þδxm þ ðT c T 1 Þ x
δm
Performing the integrations:
δ
x2 x3 m
T ave w ¼ T c 2ðT c T 1 Þ þ ðT c T 1 Þ 2 þ T 1 ½x
jδwm
2δm 3δm 0
δm
Doing the algebra: T ave ¼ T 1 þ 3w ðT c T 1 Þ
Inserting the expression for the boundary layer thickness as a function of time:
pffiffiffiffiffiffiffi
4 αm t
T ave ¼ T 1 þ pffiffiffi ðT c T 1 Þ
3w π
Similarly, the average temperature of the coffee can be calculated during this time:
ðR
T ave, coffee πR ¼ 2
T2πrdr
r¼0
where in this case, the cylindrical shape is considered, so the integration is conducted
over a cylindrical shell from the centerline of the coffee (r ¼ 0) to the inner wall of
the mug (r ¼ R). The coordinates r and x are related simply by r ¼ R + x. Breaking
the integral into two parts, inside and outside the thermal boundary layer:
ðc
Rδ ðR
T ave, coffee πR ¼
2
T coffee, init 2πrdr þ T2πrdr
r¼0 Rδc
152 4 1-Node Transient Models
Since the radius (R ¼ 32 mm) is much larger than the maximum thermal boundary
layer thickness (dc,max ¼ 2.7 mm), the average coffee temperature changes very
little during the initial heating, while the mug has increased from ambient (25 C)
to 39.4 C.
h
T(t)
D k T∞
ρ
c
For the convection coefficient, the value for boiling water (800 W/m2/K) is on the
high end of natural convection in liquid water. There is expected to be significant
Workshop 4.1. Cooking 1-Node Hot Dogs 153
fluid motion induced by the boiling process. For baking (at 350 F ¼ 177 C) and
microwaving, a value of 15 W/m2/K is typical of natural convection in air, in parallel
with a radiative coefficient. The value for barbequing (25 W/m2/K) is taken to be
somewhat higher due to the strong updraft caused by the fire.
For the barbequing and microwaving cases, some of these input parameters were
chosen after the fact, to give cooling times consistent with experience. For
barbequing, the fluid temperature is taken to be 500 C. In practice, raising the
distance between the coals and the food lowers the fluid temperature in contact with
the food. There is an important radiation effect from the coals that is not considered
here as it does not fit into either radiation model. For the microwaving case, the
value of the rate of heat generation is given in Watts absorbed per unit volume, and
the value (1(10)7 W/m3) is chosen to be one which gives a cooking time consistent
with empirical experience. That’s cheating, a little. . . Or, rather, it is using experi-
mental results and a theoretical model to evaluate an approximation for the effec-
tive rate of absorption of microwave energy, for which no attempt to model from
first principles is made here.
Note: A detailed model development follows. Conduct your own analysis before
referring to it.
Model Development
A general 1-node model with a heat source (for the microwave case) and a thermal
channel between the capacity-carrying node and ambient with a conductive and
convective/radiative channel in series is shown in Fig. 4.39.
The energy balance applied to this general RC network is:
dT T1 T
C ¼ Q_ þ
dt Rk þ Rh
The solution (with constant parameter values) has been given in Chap. 1:
T T SS t
¼ eCðRk þRh Þ
T 0 T SS
.
Q T∞
T(t) Ts
Rk Rh
Fig. 4.39 General 1-node C
model applicable to hot dog
model
154 4 1-Node Transient Models
The surface temperature is directly related to the average hot dog temperature
through the voltage divider channel between the capacity-carrying node and the
outer hot dog surface:
T T1 Ts T1 T Ts
¼ ¼
Rk þ Rh Rh Rk
Rh ð T T 1 Þ Rk ð T T 1 Þ
Ts ¼ T1 þ ¼T
R k þ Rh Rk þ Rh
While not essential, it is useful to define Biot and Fourier numbers:
C ¼ ρcLπD2 =4
Rh ¼ 1=ðhπDLÞ
D
2
πD
.
Q T
T•
D
Rk Rh
Fig. 4.40 Conceptual model for estimating hot dog conductive resistance
Table 4.4 Summary of conduction models for 1-node hot dog problem
Biot Fourier
Model Node placement Rk number number
1 r¼0 D=2
hD 4t k
kð0þπDLÞ=2 ¼ πkL
1 k
D2 ρc
2 r ¼ D/4 (midway between D=2D=4
¼ 1:5πkL
1 hD 1 4t k 1
πkLðD=2þD=4Þ=2 k 1:5
D2 ρc 1:5
surface and center)
3 r ¼ D/3 (centroid of wedge) D=2D=3
¼ 1 hD 1 4t k 1
kðπLD=3þπLD=2Þ=2 2:5πkL k 2:5
D2 ρc 2:5
D=2
4 r ¼ D/3 (centroid of wedge, ln D=3 ð1:5Þ
hD 1 4t k 1
cylindrical shell) 2πkL ¼ ln2πkL ¼ 4:93πkL
1 k 4:93
D2 ρc 4:93
the other surface being the outer surface of the hot dog, with surface area πDL (with
L the length of the hot dog), a distance D/2 away. The capacity-carrying node is
placed at some radius between the centerline and the surface.
The general form of a conductive resistance is:
xð2
1 dx
Rk ¼
k A
x1
which has the general form of an average distance between surfaces (Δx) divided
by the thermal conductivity, and an average area. A few models (summarized in
Table 4.4) are considered before obtaining results for the base case hot dog.
156 4 1-Node Transient Models
Fig. 4.41 Results of 1-node hot dog workshop for conduction Model 4
100
90
Surface Temperature
80
70
Temperature (oC)
Cooked Temperature
60
50
40
Average Temperature
30
20
10
0
0 0.5 1 1.5 2 2.5 3
time (min)
fluid temperature (100 C) is lower than that in an oven (177 C). But at the time the
hot dog is cooked, the surface temperature in water is 95 C (25 C above the hot
dog average, and only 5 C below the fluid temperature) while the surface temper-
ature is 79 C for baking (9 C above the hot dog, and almost 100 C below the fluid
temperature).
158 4 1-Node Transient Models
100
90
Surface Temperature
80
70
Cooked Temperature
Temperature (oC)
60
50
Average Temperature
40
30
20
10
0
0 2 4 6 8 10 12
time (min)
100
90 Surface Temperature
80
70
Temperature (oC)
Cooked Temperature
60
50
40
30 Average Temperature
20
10
0
0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.6 1.8 2
time (min)
For barbequing, the cooking time is shorter than boiling, because the fluid
temperature (500 C) is so high. Meanwhile, the surface temperature is 125 C.
In this case, despite the low Biot number, the hot dog appears to heat nonuniformly,
but that is merely because the fluid temperature is so high. The surface temperature
is closer to the average hot dog temperature than it is to the fluid temperature.
Workshop 4.2. Beverage Chilling Methods 159
100
90
80
Cooked Temperature
70
Temperature (oC)
e
tur
60 mper
e
eT tur
e
50 v e rag per
A e m
eT
40 fac
Sur
30
20
10
0
0 0.1 0.2 0.3 0.4 0.5
time (min)
The fluid temperature chosen for this case is not well characterized. Nevertheless, it
is well known from experience that it is a function of the vertical distance between
the source of the fire and the hot dog. It burns on the outside if placed too close.
Finally, microwaving yields the shortest cooking times (but to me, a hot dog in a
microwave is too rubbery. . .). The equilibrium (steady-state) temperature of
3,200 C represents the temperature the hot dog would achieve in theory if the
microwave were left on indefinitely. Of course, something would happen to the hot
dog to change the model long before it reached that point.
The surface temperature at the microwave cooking time is lower than surface
temperature. That is, heat flows outward from the core of the hot dog to the surface.
Heat is absorbed uniformly throughout the interior, yet the temperature is not
uniform. In order for heat to flow from the interior to the surface, and ultimately
to the ambient, there must be a temperature gradient driving it. From Fig. 4.45, at
the start of the cooking event, the surface temperature is higher than average. That
is because the hot dog is taken from the refrigerator, and it is being warmed by the
air temperature at the same time it is being heated from within. Once the hot dog
average temperature exceeds the air temperature, the core is hotter than the surface.
Beverages are commonly purchased at room temperature, but are consumed cold.
This workshop develops a means to predict the time it takes to chill a room
temperature beverage to a desirable drinking temperature. A standard beverage
chilling time is defined here as the time it takes to chill a beverage from 25 to 5 C
using a specific cooling method. The Cooper Cooler™ is a consumer appliance
developed at the Cooper Union that is designed to do so rapidly. The user prepares
160 4 1-Node Transient Models
an ice/water slurry in a reservoir and the Cooper Cooler sprays a cold recycled jet of
water on a horizontal beverage while is it rotated along its natural axis. For this
workshop, five different chilling methods are considered: three conventional modes
and two Cooper Cooler modes.
Model Development
All five chilling methods are modeled with the same RC network which the reader
can draw based on the following description. The capacitance of the beverage and
container are lumped into a single node, Tbev. For heat to be transferred from the
beverage to the coolant (at Tcoolant), it must flow from the beverage to the inner wall
of the container (a convective resistance), across the container wall (conductive),
and from the outer wall to the coolant (convective/radiative). In other words, there
is a single thermal channel from the beverage to the coolant with three resistances in
series. The differences in chilling times are due to different values of the various
capacitances (for different beverage types), thermal resistances, and coolant
temperature.
The governing nodal equation is:
dT T coolant T bev
Cbev ¼
dt Req
where Req is the equivalent thermal resistance (sum of three series resistances). The
solution to this now familiar governing first-order equation is:
T bev T coolant t
¼ eRCbev
T initial T coolant
This solution can be used, once estimates of R and C are made, to prepare plots of
beverage temperature vs. time. To determine the standard chilling time (tchill), the
natural logarithm of both sides is taken and the beverage temperature set to the
desired final temperature:
5 T coolant
tchill ¼ RCbev ln
25 T coolant
A spreadsheet template for a specific beverage type is shown in Fig. 4.46. Blocks for
input parameters, derived parameters, and results are shown in which suggested values
Workshop 4.2. Beverage Chilling Methods 161
for the case of a 12 oz. bottled beverage are listed. Input values considered to be
common for different beverage types are listed in the results block. Blank boxes are
left for the formulas needed to implement the method. The beverage is considered to
have a clearly identified outer diameter and treated as an equivalent cylinder to obtain
the length. A thin-wall approximation is suggested in which the inner and outer areas
are treated as approximately equal when thermal resistances are calculated.
The coolant temperatures are taken to be those typical of a refrigerator, freezer,
and the melting point of water for the three conventional cooling methods. For the
Cooper Cooling methods, a coolant temperature of 1 C is suggested for spray only,
and 2 C for spray and spin. In practice, the coolant is recycled from an ice/water
bath, and heat added to the coolant from the beverage warms it somewhat, even as
the ice in the bath cools it. The modeling of this process involves more than one
node and is discussed later. The coolant temperature is warmer for the spray and
spin because of the higher heat transfer rates from the beverage.
162 4 1-Node Transient Models
The value for inner heat transfer coefficient is taken to be a typical value for the
natural convection of fluid with nominal water properties (300 W/m2/K) for all
stationary beverages. When the beverage is rotated, there is mixing inside which
produces a sort of wind chill on the inside and the value used (1,500 W/m2/K) is
representative of a mild forced convection with water. The outer convection/radia-
tive coefficient is taken to be representative of natural convection in air, with a
parallel radiation channel, for the refrigerator and freezer. For the ice/water bath,
the outer coefficient is representative of natural convection in water. A value
representative of a forced convection with water (stronger than for the inside) is
listed for the two cases, where a jet of cold water is sprayed.
For the three conventional cooling methods (refrigerator, freezer, ice/water
bath), the coolant is considered to be in contact with the entire surface area of the
beverage (sides, top, and bottom) whereas for the two Cooper Cooling cases, only
the side surface is considered to be in good thermal contact with the coolant.
It is suggested that the case of a 12 oz. canned beverage be compared with the
12 oz. bottled beverage, in which case the only difference is the thermal resistance
of the container wall. Also, the cases of a 0.5, 1, and 2 L plastic bottles be
considered, where both the thermal capacitance and surface area vary. It is also
suggested that plots of temperature vs. time be prepared with all five cooling
methods on the same set of axes for a given beverage. Include the inner and outer
wall temperatures. A final suggestion is to conduct some experiments and compare
results. Notice that in an experiment, the natural dependent variable to set is the
chilling time, and this analysis can help inform an intelligent choice for that time for
a single experiment. Too short a time, and the temperature difference between
initial and final temperature will be small and experimental uncertainty will be
high. Too long a time, and the beverage will be too close to the final equilibrium to
obtain a reasonable dimensionless temperature.
Few-Node Transient Models
5
Try this experiment. Fill a ceramic mug with boiling water and immediately grab its
side. Close your eyes and concentrate on what it feels like. You’ve just experienced
the mug heating phase, the topic of this chapter.
In the cooling mug of coffee problem, the mug is initially at ambient
temperature when hot coffee is poured into it. Figure 5.1 shows the measured
outside wall and coffee-free surface temperatures (as symbols), and the predic-
tion of the 1-node lumped capacity model for the coffee from Chap. 4 (solid
line), the top surface (dotted line), and the outer side wall (dashed line). The
1-node extended model is capable of distinguishing the temperature of the
coffee (think average bulk coffee temperature) from the various surface
locations (two of which are measured). However, it misses the distinction
between the mug and the coffee during the first few minutes. It predicts that
the outside wall of the mug is hot at the instant the coffee is poured. However, it
takes some time for that to happen.
In the 1-node model (coffee and mug as a single node), the capacitance of the
coffee and mug are lumped together, and their temperatures must rise or fall
together. In essence, the initial thermal mixing of coffee and mug is assumed to
take place instantaneously, and the initial temperature for the ensuing cooling
process is obtained from the energy balance detailed in Chap. 2 (in which only
the capacitances of the mug and coffee come into play). The initial period where the
mug rises as the coffee falls cannot be observed.
In Chap. 4, a variable-sized 1-node model was developed that yielded the basic
response of the mug to being suddenly exposed to a hot fluid. However, the bulk
temperature of the fluid was fixed. The initial cooling of the coffee as the mug is
being heated is not captured in that model.
In order to observe the separate behavior of the coffee and the mug, the capaci-
tance of the coffee and the mug must be treated separately, creating a 2-node model.
The goal of this chapter is to develop a general scheme for doing so, and apply it to
the mug of coffee problem.
100
90
80
70
Temperature (oC)
60
50
Lines Are Theory:
40 solid = coffee
dotted =top surface
30
dashed = outer side wall
20 Markers are Experimental:
open = top surface
10 filled = outer side wall
0
0 2 4 6 8 10
Time (min)
Fig. 5.1 1-Node lumped capacity model predictions during mug heating phase
Figure 5.2 shows an RC network with two nodes that have capacitance associated
with them (T1 and T2). Initially, both nodes are at ambient (T1, held by a battery
above ground). The switch (s) is momentarily closed, long enough to charge
capacitor C1 to a starting point (T0), while T2 is initially undisturbed, and then
released. Subsequently, heat flows directly to ambient through R11 and
5.1 A Generic 2-Node RC Network 165
simultaneously to the second node (T2), whose capacitor begins to charge. As soon
as T2 rises above ambient (if T0 > T1), heat flows from T2 to ambient. If T0 is less
than T1, then everything flows in the opposite direction. Both nodes can also
receive heat from separate heat sources.
This model represents a more complicated model of the cooling mug of coffee.
The difference between this model and the previous lumped model is that instead of
lumping the capacitance of the mug and coffee together, each component is given
its own capacitance. The direct channel from T1 to T1 (through R11) represents the
heat transfer from the coffee to ambient through the free surface. The channel
between T1 and ambient through T2 represents heat transfer from the coffee to the
mug through the sides and bottom.
The three thermal resistances are shown as equivalent resistances of a combina-
tion of series and parallel channels. Through the use of voltage divider type
calculations, intermediate temperatures can be related to the nodal temperatures
as desired. For example, T2 represents the average temperature of the mug, while
the inner wall temperature is between the coffee and mug temperatures, and the
outer wall is between the mug and ambient. As with the 1-node lumped model
approach, more spatial detail can be gleaned by appropriate selection of thermal
resistances.
In this model, the radiation and convection ambient temperatures are considered
equal. It is relatively easy to modify the RC network to account for the effect of
different fluid and radiation wall temperatures if needed, or to introduce a correc-
tion to either radiation or convection as detailed previously.
166 5 Few-Node Transient Models
To solve this system, a nodal balance for both capacitor-carrying nodes is required.
Figure 5.3 isolates node 1. The energy balance for this node, being careful about
signs, is:
0 1 0 1 0 1
Rate of Change Heat Flow into Heat Flow into
@ of Energy Stored A ¼ @ Node 1 from A þ @ Node 1 A
in Node 1 Heat Source 1 from Node 2
0 1
Heat Flow into
þ@ Node 1 A
from Ambient
dT 1 T2 T1 T1 T1
C1 ¼ Q_ 1 þ þ ð5:1Þ
dt R12 R11
This differential equation cannot be integrated directly because it depends on T2,
which is an unknown variable, and therefore is shown with an open symbol.
Figure 5.4 isolates T2. The energy balance for this node is:
0 1 0 1 0 1
Rate of Change Heat Flow into Heat Flow into
@ of Energy Stored A ¼ @ Node 2 from A þ @ Node 2 A
in Node 2 Heat Source 2 from Node 1
0 1
Heat Flow into
þ@ Node 2 A
from Ambient
dT 2 T1 T2 T1 T2
C2 ¼ Q_ 2 þ þ ð5:2Þ
dt R12 R21
Equations (5.1) and (5.2) represent a coupled system of first-order differential
equations. If all resistance and capacitance values are constants, the system is
linear, and there are analytical techniques for solving them (LaPlace transforms,
for example). However, the objective of this text is to build toward more complex
models for which analytic solutions do not exist. Numerical methods, on the other
hand, can treat these more general complex cases, and are developed immediately.
Two-node problems using the explicit method can generally be solved equally well
with spreadsheets or writing code in MATLAB or other programming language.
ðpþ1Þ ðpÞ
dT 1 T 1 T1
¼
dt Δt pÞ
ð
ðpþ1Þ ðpÞ
dT 2 T 2 T2
¼
dt ΔtðpÞ
Inserting these approximations into the two nodal equations and rearranging them:
ðpÞ
ΔtðpÞ ðpÞ T2 T 1 ðpÞ T 1 ðpÞ T 1 ðpÞ
Q_ 1 þ
ðpþ1Þ ðpÞ
T1 ¼ T1 þ þ ð5:3Þ
C1 ðpÞ R12 ðpÞ R11 ðpÞ
ðpÞ
ΔtðpÞ ðpÞ T1 T 2 ðpÞ T 1 ðpÞ T 2 ðpÞ
Q_ 2 þ
ðpþ1Þ ðpÞ
T2 ¼ T2 þ þ ð5:4Þ
C2 ðpÞ R12 ðpÞ R21 ðpÞ
On the right hand side, all variables and parameters are evaluated at the present
time. A superscript “p” has been applied to everything (time step, R and C values)
indicating that all these may change as time marches forward.
There are two underlying time constants for this system, one for each node, that
represent a first-order response of each node to an equilibrium value if the
168 5 Few-Node Transient Models
neighboring nodes were fixed (detailed in Appendix 1). For example, in Fig. 5.3, if
T2 is held fixed, T1 will approach a value that is intermediate to T2 and T1, with an
equivalent resistance resembling a parallel path. That is, a time constant for
node 1 is:
ðpÞ
ðpÞ ðpÞ C1
τ1 ¼ ðRCÞ1, equiv ¼
1 1
ðpÞ
þ ðpÞ
R12 R11
For node 2:
ðpÞ
ðpÞ ðpÞ C2
τ2 ¼ ðRCÞ2, equiv ¼
1 1
ðpÞ
þ ðpÞ
R12 R21
Note that the heat sources are not associated with the inherent response time. A
Second Law limit for the system is defined by limiting the time step taken at each
step to the smaller of the two time constants. If a larger step size is used, the
temperature will overshoot this “meta-equilibrium” value. As was seen in Chap. 1,
there is also a numerical stability limit for the step size, which, if exceeded, would
cause the system temperature to grow without bounds.
A common misuse of this algorithm is to use a different step size for each node, an
egregious conceptual error. The same step size must be used for both nodes when
marching in time. On the other hand, it is possible for either the capacitance or
especially one or more of the thermal resistors to be temperature and/or time depen-
dent (hence the superscripts “p”), and the response time of one or both of the nodes
will change with time. A variable step-size algorithm can be used in those cases.
It may sound confusing, but “the maximum allowable step size for the method is
the minimum time constant.” That is:
ðpÞ ðpÞ
Δtðmax
pÞ
¼ min τ1 ; τ2
To apply this general model to the specific case of a cooling mug of coffee, the three
thermal resistances and the two capacitances must be evaluated. Figure 5.5 shows a
more detailed RC network. The two temperatures (coffee and mug, shown as open
circles) represent the main capacity-carrying nodes. However, using voltage divider
formulas, the temperatures of the free surface, inside wall of the mug and outside
wall of the mug can be determined (shown as small filled circles). The free surface
and outside wall surface are the most closely related conceptually to the measured
temperatures to which the model predictions will be compared. Ambient tempera-
ture is a fixed temperature (large filled circle) that could easily be made to vary with
time in a prescribed way.
Convection and radiation act in parallel at the outer surface of the side wall. For
the free surface, an additional parallel channel is shown, namely, an evaporative
channel. As discussed in Chap. 3, evaporation effects are probably dominant when
the coffee is near the boiling point, but negligible thereafter. A single constant heat
transfer coefficient is chosen to include all these effects. The side and bottom
channels from Chap. 3 are treated as a single channel from the coffee to the outside
surface of the mug. There, a side channel and a parallel bottom channel connect to
ambient. More capacity-carrying nodes would be required to further distinguish the
bottom of the mug from the side.
T∞
evaporation
convertion
radiation
Rsa
Tsurface
coffee Rcs mug
Tinside T2 Toutside T∞
T1 convection
radiation
Rcm Rmug Rmug
2 2 Rma, side
C1 C2
Rma, floor
Fig. 5.5 RC network of mug of coffee detailing thermal channels
170 5 Few-Node Transient Models
Fig. 5.6 Input parameter values for 2-node mug of coffee problem
5.3 Coffee Mug: Explicit Numerical Solution with Constant Coefficients 171
coefficient that represents the sum of the individual coefficients is used. The
values chosen are based on estimates evaluated at a coffee temperature of 70 C
from analyses from future chapters.
In constructing a spreadsheet based on a problem statement, there are generally
fixed input parameters, and then many other parameter values (quantities that do not
change with time) that are obtained from formulas based on them. It is a good
practice to keep the fixed values separate from the derived values, especially for
conducting parametric studies (i.e., changing a fixed input to observe its effect on
the system response). It is easy to tell the difference. Any spreadsheet cell that
contains a number is an input parameter. Any cell that contains a formula is a
derived parameter.
In the same worksheet, quantities derived from the input quantities that do not
change with time are shown in Fig. 5.7 in three different blocks. There are
dimensions, capacitances, and surface areas that will be used as inputs to the
individual thermal resistances, and the individual resistances are combined into
series and parallel channels to form the three main equivalent resistances in the
2-node simulation. Detailed explanations of all these calculations are given in
Appendix 2.
The conductive resistance across the mug wall is taken to be between the surface
area of contact between the coffee and the mug and the surface area of the mug
exposed to ambient (including the bottom, through a different mechanism). As was
Fig. 5.7 Derived parameter values for 2-node mug of coffee problem
172 5 Few-Node Transient Models
done with the 1-node model, the heat transfer from the inside surface area of the
mug above the free surface to ambient is included in the side channel (not the top
channel). The conductive resistance across the mug wall could be further improved
by considering a parallel channel through the rim (a future chapter on heat transfer
fins). Either approach could be used in either the 1-node or 2-node model and
highlights some of the art of heat transfer modeling.
An important feature of the detailed RC network is how the total conductive
resistance across the mug wall is split into two, with the mug capacitance placed in
the middle. This placement allows for spatial detail in the temperature field. It also
adds numerical stability, although that may not be clear at this point.
Much can be inferred from a consideration of the relative magnitudes of the
three model resistances. Heat flows easily between the coffee and mug due to the
low value of R12 compared to the other two resistors. Heat leaves the side wall more
easily than it does through the top, despite the higher net coefficient (reflecting the
inclusion of evaporation), a trend attributed to the larger surface area of the
side wall.
The basic structure of the 2-node simulation is shown in the worksheet “2-
nodeMug” (Fig. 5.8). The top block includes the main inputs to the general 2-node
simulation. These cells refer to the appropriate cells in the “params” worksheet,
except for the cell that contains the user-defined parameter “f”, which has the value
0.2 chosen for this implementation, a choice based on experience from Chap. 1 with
the general consideration of the Euler method for a 1-node problem. This numerical
parameter is used to determine the (constant) step size used in the simulation. An
input value of 1.0 would represent the maximum Second Law step size of the system.
The time constants for nodes 1 and 2 are calculated in a separate block below the
inputs. It is apparent that the characteristic response time of the coffee in this case
(241 s) is about eight times as large as that of the mug (35.6 s). An “if-then-else”
statement is used to calculate the step size (Dt ¼ 7.12 s) used in the simulation, which
is the numerical parameter “f” multiplied by the smaller of the two time constants.
The simulation is implemented in the next block. The first row contains the initial
time (0), and initial coffee and mug temperatures (92 and 21). The next row contains
the recursion formulas for time (add the fixed time step to the previous time and
convert from seconds to minutes), coffee temperature and mug temperature (T1 and
T2, from Eqs. (5.3) and (5.4)), which implement the explicit method. Once written,
this second row is copied down as many additional rows are needed to simulate the
desired total elapsed time. For this case, 2,020 rows are needed to simulate 4 h of
elapsed time. If a smaller step size were chosen (by choosing f ¼ 0.1 instead of 0.2,
for instance), that number of rows would simulate less time (2 h instead of 4).
Another worksheet was written to extract additional information used to analyze
the response of the system. The structure of this worksheet (“2NodeMugDetailed”)
is shown in Fig. 5.9. The top block (not shown) is the same as the top of Fig. 5.8, but
several additional quantities are calculated from the two main capacitive-bearing
nodes (coffee and mug) in the simulation. A row of spatial locations (x) is added.
For the two fluids (coffee and air), a thin boundary layer is added for the purposes of
demonstrating the relationship between surface temperature and fluid temperature
5.3 Coffee Mug: Explicit Numerical Solution with Constant Coefficients 173
Fig. 5.9 Structure of worksheet in which additional detail is extracted (i.e., intermediate
temperatures and heat transfer rates)
174 5 Few-Node Transient Models
100
Top
Coffee
90
Top
80 Side
70 Top Data
Temperature (oC)
Fig. 5.10 2-Node model prediction for entire cooling event on linear axes
across a convective thermal boundary layer. Columns for the inner and outer mug
surface temperatures are added and the voltage divider formulas implemented.
A column for the free surface temperature is added. Finally, the individual heat
transfer rates between nodes are calculated (individual terms from governing
equations).
Figures 5.10 (linear axes) and 5.11 (semi-logx axes) show the temperature vs. time
predictions from the 2-node model (shown as lines) compared to the experimental
data (shown as markers) for the entire cooling event using the parameter values
from the previous section. Figure 5.12 focuses on the mug heating phase (early
time) on linear axes. The line for coffee (solid line) shows node 1 at a slightly higher
temperature than the surface and outer wall. The dotted line which corresponds with
the filled circles shows the free surface temperature. The dashed line which
corresponds with the open circles shows the outer mug wall temperature. The
mug temperature itself (node 2) is not shown in these plots, but only the two non-
capacity-carrying nodes that correspond to the measured quantities.
The linear axes (Fig. 5.10) show the entire event, and the initial mug heating
period is not clearly visible. The coffee, top (free) surface of the coffee, and mug
side wall all fall together. The model prediction lags the experimental for the first
hour or so, but then the final approach to equilibrium gives good agreement
between theory and experiment. However, this model assumes constant
coefficients, and the effect of a variable coefficient cannot be seen. Recall that
the constant values chosen were based on a temperature of 70 C, and more
5.3 Coffee Mug: Explicit Numerical Solution with Constant Coefficients 175
100
90 Coffee
80 Top
Side
70
Temperature (oC)
Top Data
60 Side Data
50
40
30
20
10
0
0.1 1 10 100 1000
Time (minutes)
Fig. 5.11 2-Node model prediction for entire cooling event on semi-logx axes
100
90
80
70
Temperature (oC)
60
50 Coffee
40 Top
Side
30
Top Data
20 Side Data
10
0
0 1 2 3 4 5
Time (minutes)
Fig. 5.12 2-Node prediction for the cooling mug of coffee for the first 5 min
sophisticated models would show the resistance values increasing with time
(as the temperature falls).
The semi-logx axes (Fig. 5.11) show the entire event, but the behavior during the
initial mug heating phase is apparent in this view as well. The focus on the first
5 min of the event on linear axes (Fig. 5.12) shows the undistorted shape of the
temperature response, with the same trends observed on the semi-logx scale. In the
first minute, the model predicts a slower rise of the outer side wall than measured,
and then excellent agreement between 1 and 10 min. The predicted top (free)
176 5 Few-Node Transient Models
1000
Coffee to mug
Mug to Ambient
Heat Transfer Rate (Watts) 100
10
0.1
0.01
0.1 1 10 100
Time (min)
Fig. 5.13 Heat transfer rates between nodes for the entire event (log–log axes)
surface of the coffee is noticeably higher than the experimental value throughout.
Use of a higher value for thermal resistance between the coffee and the free surface
(Rcs) would give better agreement (but not the “dip” in the data, which may or may
not be a repeatable trend, and only a single experiment was conducted). Inclusion of
this resistance represents a deviation from the classic modes of heat transfer
because the free surface represents a boundary between two immiscible fluids,
not between a fluid and a solid. Nevertheless, application of Newton’s Law of
Cooling with a convection coefficient as if the fluid/fluid boundary behaved as a
fluid/solid boundary (on either side) is a plausible modeling tool to reflect a
mechanism for heat transfer from a bulk fluid to an interface.
The heat transfer rates between nodes are shown as a function of time in
Fig. 5.13. During the mug heating phase (the first minute), the rate of heat transfer
from the coffee to the mug is very high. The heat transfer rate from the mug to
ambient rises as the outside wall temperature rises during the first minute or two.
After that, the rate of heat transfer from the mug to ambient is slightly higher than
from the coffee to the mug (the difference is the change in energy stored in the mug
wall). The rate of heat loss through the top surface is always small, and this effect
can be attributed to the smaller surface area, despite the higher effective heat
transfer coefficient value input there. The heat transfer rate between the side and
bottom channel are not distinguished, but the thermal resistance of the bottom
channel is much larger than that of the side wall (due to smaller area and lower
effective heat transfer coefficient).
A main point of presenting this heat transfer plot is to demonstrate how much
more information can be gleaned from a theoretical analysis of a problem (if one
chooses to look for it) compared to experiment. The experiment has the advantage
of being a measurement (keeping experimental errors always in mind), but
5.3 Coffee Mug: Explicit Numerical Solution with Constant Coefficients 177
90 0.952
Time 0.846
80 0.740
Time
70 0.634
Temperature (oC)
0.529
60
0.423
50 0.317
40 0.211
0.106
30 0.000
20
Coffee Mug Wall Ambient
10
0
3.9 4 4.1 4.2 4.3 4.4 4.5 4.6 4.7
Radial Position (cm, from centerline)
Fig. 5.14 Temperature as a function of side wall position for the first minute of the simulation
(mug heating phase)
generally limited information. Theory and experiment make a great team. For
example, an IR detector was used that can only yield surface temperatures, and
the model shows the side and surface temperatures with excellent agreement. This
experiment does not show that the bulk of the coffee is actually slightly higher the
temperature at the free surface and at the mug surface. A thermocouple array might
show that detail (a great project for a course on experimentation). The heat transfer
rates cannot be measured directly at all.
The spatial temperature variation in the side wall as time elapses is demonstrated
in Figs. 5.14 (for the mug heating phase) and 5.15 (for the coffee/mug cooling
phase), which show temperature as a function of radial position at fixed times. The
fluid temperatures (coffee and ambient air) are shown with somewhat arbitrary
0.05 cm thermal boundary layer. Straight lines are drawn between points with
markers that indicate specific locations from the model. Arrows are used to indicate
the trends with time.
The first plot (Fig. 5.14) shows these temperatures for the first ten discrete times
of the simulation which focuses on the first minute of the event. At the initial time,
where the coffee and mug temperatures are set to their initial values (92 C and
21 C, respectively), the model predicts (through the voltage divider calculation)
that the initial temperature on the inner wall surface does not equal the initial mug
temperature, but is between the mug and the coffee. Its value (49.95 from Fig. 5.9)
is roughly halfway between the mug and coffee temperatures because the convec-
tive resistance between the coffee and mug (0.0844 C/W) is coincidentally of the
same order as that of the conductive resistance across the mug wall (0.116/
2 ¼ 0.0553 C/W). After one step in time, the mug temperature rises to about
35 C and the outer surface wall temperature rises with it. The outer surface
178 5 Few-Node Transient Models
100
Time (min)
90
1.069
80 15.0
70 30.1
Temperature (oC)
45.0
60
60.0
50
75.0
40
30
Time
20
10 Coffee Mug Wall Ambient
0
3.9 4 4.1 4.2 4.3 4.4 4.5 4.6 4.7
Radial Position (cm, from centerline)
Fig. 5.15 Temperature as a function of side wall position at 15 min time intervals (after initial
mug heating)
temperature is between the mug and ambient, but is much closer to the mug because
the convective resistance to ambient (2.06 C/W) is much larger than the conduc-
tive resistance across the mug (0.0553 C/W), a Biot number concept. During this
time, the inner wall temperature rises about 5 C as the coffee temperature drops
about 1 C. Each step in time reveals a similar qualitative change, but with reduced
magnitude temperature jumps.
Experience from the variable-sized 1-node model from Chap. 4 would suggest
that it takes approximately 4 s for the initial thermal wave to traverse the mug wall,
and that time is short compared to the step size used in this simulation. Therefore,
the use of a fixed size mug node is justified.
The concavity in the temperature profile across the mug is an indication of the
degree to which it is important to assign separate capacitance to the mug
(as opposed to lumping it together with the coffee). If heat transfer rate from
the inner wall to the mug exceeds that from the mug to the outer wall, the
temperature profile will be concave up. The difference is the rate of change of
the energy stored in the mug. After 1 min, the concavity essentially vanishes (the
temperature is approximately linear across the mug wall), meaning that the NET
heat transfer rate to the mug is negligible. They are not exactly equal, as shown in
Fig. 5.13. A high heat transfer rate enters from the inside and exits the outside at
almost exactly the same rate. This behavior is an example of “quasi-steady state”
behavior, and why it is justified to lump the capacitance of the mug and coffee
together in order to simulate the response AFTER the mug attains this quasi-
equilibrium. The heat transfer rate at any time (after 1 min) is the same as it would
be if the slowly changing coffee temperature were maintained by some means at a
constant value. Recalling Fig. 5.13, these trends are also made apparent by
5.3 Coffee Mug: Explicit Numerical Solution with Constant Coefficients 179
considering the heat transfer rates between the coffee and mug, and between the
mug and ambient.
Once this quasi-steady state equilibrium for the mug is established, the tempera-
ture remains approximately linear across the mug as the coffee and mug cool
(Fig. 5.15). During this time, the coffee and mug respond together, and this
2-node model provides justification for lumping their capacitance together during
the cooling phase. However, the 1-node lumped model is not capable of revealing
the key physics during the mug heating phase. In this particular case, the coffee/
mug cooling phase dominates the entire event, and therefore a 1-node model does a
good job of simulating the main event, while missing detail at the beginning.
A really good problem statement would be to conduct a similar experiment
and analysis with a Styrofoam cup. The main difference would be a lower
mug capacitance and a higher conductive resistance across the mug wall. The
mug outer side wall would be much lower than the coffee-free surface in this case.
Keeping the same geometry, the mug mass (from a measurement), specific heat
and the mug thermal conductivity (from a literature search) could be changed to
their appropriate values. The time constant for the mug will be much smaller
than the ceramic mug, and this problem is becoming numerically “stiff” where
the time step restriction on a fast responding node requires many more time
steps to simulate the overall response than would be required for the slower
responding node.
100 100
90 f = 0.1 90 f = 0.5
80 80
70 70
Temperature (oC)
Temperature (oC)
60 60
50 50
Coffee Coffee
40 40
Mug Mug
30 30
20 20
10 10
0 0
0 0.5 1 1.5 2 2.5 3 0 0.5 1 1.5 2 2.5 3
Time (min) Time (min)
100 100
90 f=1 90
80 80
70 70
Temperature (oC)
Temperature (oC)
60 60
50 50
Coffee
40 40 f = 1.773
Mug
30 30 f=1
f = 0.5
20 20
f = 0.2
10 10 f = 0.1
0 0
0 0.5 1 1.5 2 2.5 3 0 0.5 1 1.5 2 2.5 3
Time (min) Time (min)
Fig. 5.16 Effect of step size (f ¼ fraction of maximum Second Law step size) during the mug
heating phase. The bottom right graph compares the mug temperature for 5 different values of the
step size (as a fraction, f, of the maximum allowable)
compared directly (bottom right), the f ¼ 0.5 case shows a noticeable difference
from f ¼ 0.1. An intermediate value (f ¼ 0.2) is included which shows good
agreement with f ¼ 0.1.
This analysis shows a somewhat informal or brute force test for “grid insensitiv-
ity.” To accurately simulate a given mathematical model numerically, a typical
Question and Answer series might be
200
f = 1.773
150
100
Temperature (oC)
50
0
0 10 20 30 40 50 60
-50
-100 Coffee
Mug
-150
-200
Time (min)
Fig. 5.17 Coffee and mug temperatures for the step size just above a critical value for numerical
stability
It just misses the detail at the beginning. It can be argued that the reason for that
agreement is because it merely finds the right quasi-equilibrium in a few steps.
For a problem for which that quasi-equilibrium is not a good model, all bets
are off.
Numerical stability limits are demonstrated in Fig. 5.17, which shows the mug
and coffee temperatures for an hour with a value f ¼ 1.773. This value (also one of
the cases in the bottom right plot of Fig. 5.16) was chosen by trial and error, and is
considered near, but above the stability limit of this explicit formulation. The mug
temperature would eventually grow without bounds (numerical instability) if
allowed to continue.
There may come a time when the numerical stability limit of an explicit formulation
becomes so restrictive as to make it untenable. For example, in a 2-node system, if
the response time constant of one node is 1,000 times smaller than that of the other,
a minimum of 1,000 time steps would need to be taken just to simulate an amount
of time corresponding to one time constant of the slower responding node. An
implicit method represents another numerical tool that overcomes this problem. It
is introduced in this section, but not implemented, as the explicit method is
considered adequate for this particular job. This method is not readily solved
using a spreadsheet.
As was demonstrated in Chap. 1, a backward difference for the time derivative
brings a quickly responding node to equilibrium if an excessive step size is used. In
182 5 Few-Node Transient Models
this case, the two backward difference approximations (for nodes 1 and 2, coffee
and mug) are:
ðpÞ ðp1Þ
dT 1 T 1 T 1
¼
dt ΔtðpÞ
ðpÞ ðp1Þ
dT 2 T 2 T 2
¼
dt ΔtðpÞ
Updating present to future (p ! p + 1), inserting these approximations into the two
nodal equations yields:
!
ðpþ1Þ ðpÞ ðpþ1Þ
T1 T1 ðpþ1Þ T2 T 1 ðpþ!Þ T 1 ðpþ1Þ T 1 ðpþ1Þ
C1 ðpþ1Þ ¼ Q_ 1 þ þ
Δtðpþ1Þ R12 ðpþ1Þ R11 ðpþ1Þ
!
ðpþ1Þ ðpÞ
T2 T2 ðpþ1Þ T 1 ðpþ1Þ T 2 ðpþ!Þ T 1 ðpþ1Þ T 2 ðpþ1Þ
C2 ðpþ1Þ
¼ Q_ 2 þ þ
Δtðpþ1Þ R12 ðpþ1Þ R21 ðpþ1Þ
All temperature variables and parameters with a superscript “p” are evaluated at the
present time. If the initial condition is known, these are considered to be known
quantities. A superscript “p + 1” is a future value, and is unknown. If the numerical
time step (Δt), R and C parameters are functions are variable, their (unknown)
future value is required. The two nodal equations constitute a system of two
algebraic equations for the future values of T1 and T2.
If the parameters are constants, it is a linear system, and can be solved using
linear algebra. The two governing equations can be written in matrix form for the
two future temperatures, and then solved using Cramer’s rule or Gaussian elimina-
tion, or easily inverted in a MATLAB program.
If the parameters are variables, the system is nonlinear, and an iterative numeri-
cal technique is required (as opposed to a “stepping” technique as with time). The
Jacobi Method (Successive Substitution) and closely related Gauss–Seidel method
are powerful methods, and involve rearranging the governing equations by “solving”
for each nodal future value in terms of its neighbors, making an initial guess, and
iterating until either convergence or failure of the method. If the method fails, then
Newton’s method is a good technique to try next. The recursion equations in the form
for Gauss–Seidel are:
5.4 Coffee JouliesTM: A 3-Node Model 183
ðpþ1Þ
ðpþ1Þ T ðpþ1Þ T 1 ðpþ1Þ ðpÞ
Q_ 2 þ 1
C2 T2
ðpþ1Þ
þ ðpþ1Þ þ Δt ðpþ1Þ
ðpþ1Þ R21 R12
T2 ¼ ðpþ1Þ
1 1 C2
ðpþ1Þ
þ ðpþ1Þ
þ
R21 R12 Δtðpþ1Þ
T∞
evaporation
convection
radiation
Rsa
Tsurface mug
coffee
Rcs
Tjoulies T1 Tinside T2 T T∞
outside convection
radiation
RCJ Rcm Rmug Rmug
2 2
Rma
Cjoulies C1 C2
Fig. 5.18 3-Node model with Coffee Joulies in a single-stage phase of heating or cooling
poured over them. They are constructed with a shell of stainless steel, and filled
with a “phase change material” that is called “wax” in this text. The requirement of
the wax is that its melting point temperature be within the suitable temperature
range. The Joulies store energy in the form of “latent heat.”
To model the cooling of coffee with Joulies, a 3-node model consisting of coffee,
mug, and Joulies captures the key effects (Fig. 5.18). The coffee and mug are the
same as the 2-node model, except that the coffee has an additional thermal partner,
namely, the Joulies. The Joulies are treated as a lumped element. During single
phase stages (i.e., completely solid or liquid), they are modeled with a capacitance,
and a thermal resistance (RCJ) that consists of three resistances in series: conduction
through the wax, conduction across the shell, and convection between the Joulie
and the coffee.
When undergoing phase change (Fig. 5.19), the temperature remains fixed at the
melting point, but the fraction of wax that is liquid and the fraction that is solid
changes. There is a “quality” (x) of the solid/liquid mixture that changes. The
quality, defined as the mass fraction of liquid, is analogous to the quality used in
liquid/vapor phase change in traditional thermodynamic analysis. The quality is
only defined during phase change, when the Joulie contains a mixture of saturated
solid (further heating would cause melting) and saturated liquid (cooling would
cause freezing) in equilibrium. If the Joulie is below the melting point, the solid is
not saturated and the quality is not applicable (x ¼ NA). Similarly, for temperatures
above the melting point the liquid is not saturated (and x ¼ NA).
The Coffee Joulie node is represented in Fig. 5.19 as a “rechargeable battery”
given the symbol of a battery with an arrow through it. The node is filled, indicating
that the temperature of the node is fixed at the melting point of the wax, but the
arrow indicates that the degree of battery “charge” varies. When the wax is
5.4 Coffee JouliesTM: A 3-Node Model 185
T∞
evaporation
convection
radiation
Rsa
Tsurface mug
coffee
Tjoulies, MP Rcs T2
T1 Tinside T outside convection
T∞
radiation
RCJ Rcm Rmug
2
Rmug Rma
C1 2
C2
Fig. 5.19 3-Node model with Coffee Joulies undergoing phase change (melting or freezing)
completely solid, the battery is discharged, and when liquid it is fully charged. The
quality “x” monitors the degree of charge.
When placed in sufficiently hot coffee, the Joulies will go through five distinct
stages.
1. Heating stage: The Joulies will be heated (by the coffee) to the melting point of
the wax. Meanwhile the coffee is also heating the mug wall and is being cooled
itself. If the Joulies reach the melting point with the coffee still above it, the wax
will become a saturated solid and stage 2 will begin.
2. Melting stage: The Joulies will continue to absorb heat from the coffee but
remain at the melting point temperature of the wax. The quality (mass fraction of
vapor) will increase until all the solid is melted, and the wax is a saturated liquid.
If melting is complete, the coffee temperature remains above the melting point,
and stage 3 will begin.
3. Superheating stage: The temperature of the Joulies rises above the melting point,
and will tend to approach the coffee temperature, then fall back with it as the
coffee cools. When the Joulies cool back to the melting point, the liquid will be
saturated and stage 4 will begin.
4. Freezing stage: The coffee temperature drops below the Joulies and the wax
begins to freeze. Heat is now transferred from the Joulies to the coffee, helping
delay the coffee from cooling below a suitable drinking temperature. Once the
wax has completely solidified, the final stage begins.
5. Cooling stage: The coffee, mug, and Joulies cool together, eventually attaining
thermal equilibrium with ambient. Unless the coffee has been drunk by now. . .
186 5 Few-Node Transient Models
Table 5.1 Joulie energy, relative to a reference temperature below the melting point, stored in a
Joulie and its rate of change for different temperature ranges
Temperature dEJoulie
range EJoulie ¼ Eshell þ Ewax dt
TJoulie < TMP ðmcÞshell þ ðmcÞwax, s T Joulie T ref ¼ Csolid T Joulie T ref dT Joulie
Csolid
dt
TJoulie ¼ TMP ðmcÞshell T MP T ref þ mwax ½us þ xuLS dx
mwax uLS
j k dt
TJoulie > TMP ðmcÞshell þ ðmcÞwax, l ðT Joulie T MP Þ þ mwax uL Cliquid dTdt
Joulie
5.4 Coffee JouliesTM: A 3-Node Model 187
The nodal equations (in the form for the Euler method) are therefore:
ðpÞ
!
ðpÞ ðpÞ
ΔtðpÞ T 1 T mug T coffee T mug
T ðmug
pþ1Þ
¼ T ðmug
pÞ
þ þ
Cmug RM1 RCM
The nodal equation for the Joulies depends on whether it is in the single or mixed
phase. When in the single phase (solid or liquid):
ðpÞ ðpÞ
!
ðpþ1Þ ðpÞ ΔtðpÞ T coffee T Joulie
T Joulie ¼ T Joulie þ
CJoulie RCJ
When in the mixed phase, the temperature of the Joulies is fixed at the melting
point, and an Euler formula for the quality is:
ðpÞ
!
ΔtðpÞ T coffee T MP
xðpþ1Þ ¼ xðpÞ þ
mwax uLS RCJ
As always with the Euler method, there is a maximum time step for numerical
stability that must be carefully monitored.
A variable time step algorithm is used during the melting and freezing stages, as
indicated by a superscript (p) for the time step. Rather than input a time step to
march, a step in quality (Δx) is made. Rearranging the governing equation for
quality gives the required time step (which must be less than the maximum time
step for the coffee and mug).
Δxm u R
ðpÞ
wax LS CJ
Δt ¼
ðpÞ
coffee T MP
Fig. 5.20 Detail of RCJ, the thermal resistance between the Joulies and coffee
to volume ratio of a manufactured Joulie is different than the one used in this
simulation. The total mass (mass of the wax plus the mass of the shell) and volume
are easily measured, and the equivalent shell thickness can be estimated given
assumed density values. The mass-averaged specific heat is similarly estimated.
The outer resistance is modeled as a convective resistance:
1
Ro ¼
ho πd2
ðd d wax Þ=2
Rw ¼
kshell πd 2
d=4
Rw ¼ 2 ða first approximation, not used in simulationÞ
kwax πdwax =2
Here, the numerator is the average distance between the center and the inner
shell surface, and the denominator is taken to be the average area of those surfaces.
5.4 Coffee JouliesTM: A 3-Node Model 189
When evaluated (Appendix 3), the value of this resistance is much larger than the
two others in this series channel. Therefore, in practice, the shell temperature will
change first, and the surface of the wax will follow, then quickly enter into a stage
where the wax melts. This behavior requires the shell and wax to be treated as
separate nodes. However, that approach will not be pursued here (a good workshop
assignment!) in the interest of gaining a reasonable prediction of the system
response with Joulies. The modeling compromise is to treat the inner thermal
resistance as a convective resistance:
1
Ri ¼
hi πd 2wax
The worksheet used to calculate various parameter values that are inputs to the
simulation is shown in Fig. 5.21. Many of these parameters were determined from a
separate spreadsheet detailed in Appendix 3 based on basic measurements (volume
and mass) and assumptions about a single Joulie. A total of 3 Joulies are added to
the same mug. The mass of the wax (40.6 g for 3 Joulies) is approximately half of
the total Joulie mass (86 g), the remainder being the shell. The 3 Joulies displace
62 mL of volume. Note that the capacitance of the Joulies during the heating phase
(Csolid ¼ 123 J/K) is less than half that of the mug (Cmug ¼ 268 J/K), so it is expected
that the main effect of the Joulies on coffee temperature will be due to phase change
(latent heat), not the sensible energy effect that adding more thermal mass would have.
Five different “simulation” spreadsheets are written, one each for each stage of
the event (Joulie heating, melting, superheating, freezing, cooling), and these sheets
are linked so that the time and temperatures at the end of one stage are referenced as
the initial condition of the subsequent stage. The structures of two of these sheets
are shown in Figs. 5.22 and 5.23 for the heating and melting stages, respectively.
Each sheet marches forward a total of 100 steps (arbitrarily chosen, and not tested to
yield a time step smaller than that required of the other two nodes, mug and coffee).
During heating (Fig. 5.22), the quality is set to a value “NA,” and the Joulie
temperature varies. The numerical simulation marches in time, with a fraction of
the maximum allowable step size (f ¼ 0.0218. . ., small enough for excellent Euler
accuracy) determined using “goal seek” to the value that results in the temperature
190 5 Few-Node Transient Models
INPUT PARAMETERS
n 3 Number of Joulies
Djoulie 0.034 m Diameter of Joulie
rhojoulie 1360 kg/m3 density of Joulie
csolid 1461 J/kg/K specific heat of solid Joulie
cliquid 1461 J/kg/K specific heat of liquid Joulie
rhocoffee 1000 kg/m3 coffee density
ccoffee 4200 J/kg/K coffee specific heat
uLS 210000 J/kg heat of fusion of Joulie
Tmp 60 C melting point of Joulie
Tinf 25 C ambient
Vtotal 4.10E-04 m^3 total volume (coffee plus Joulies)
DERIVED
Ajoulie 0.0109 m^2 total surface area of Joulies
Vjoulie 6.17E-05 m^3 total volume of Joulies
mjoulie 0.0840 kg total joulie mass
mwax 0.0406 kg mass of wax
Esat,Solid 4294 J Joulie energy at saturated solid
Esat,Liquid 21926 J Joulie energy at saturated liquid
Coffee Volume 3.48E-04 m^3 coffee volume
RC VALUES
Rcj 0.86 oC/W bet. Coffee and Joulie
Rcm 0.15 bet Coffee and mug
Rminf 1.74 bet. Mug and ambient
Rcinf 6.63 bet. Coffee and ambient
Cmug 268 J/K mug capacitance
Ccoffee 1463 J/K coffee capacitance
Cjoulie,solid 123 J/K Joulie solid capacitance
Cjoulie,liquid 123 J/K Joulie liquid capacitance
at the last step equal to the melting point. The maximum step size (inherent time
constant) is controlled by the mug (dtmax,mug ¼ 37.2 s) which is smaller than the
time constant for the Joulies (dtmax,Joulies ¼ 105.2 s). Even though the capaci-
tance of the Joulies is half that of the mug, the thermal resistance is almost six times
as large between the Joulies and coffee (RCJ ¼ 0.86 C/W) as it is between the
coffee and the mug (RCM ¼ 0.15 C/W). This effect is one of contact area.
During melting, the Joulie temperature is set to the melting temperature and the
quality varies with time. The time step (dt) varies according to the governing
equation for quality and is confirmed to be lower than the inherent time constant
of the mug at all times.
This workbook is not completely automatic. Any time a parameter value is
changed, it is necessary to adjust the time step (through “f”) at each stage to
transition from stage to stage.
JOULIE HEATING PHASE VALID SIMULATION
dtmax,Joulie 105.1924716 sec
dtmax,Coffee 184.0242627 sec
dtmax,mug 37.18518815 sec
f= 0.021782786 fraction of max step size
dt 0.80999699 sec
time (min) Tcoffee Tmug Tjoulie x dTc/dt dTmug/dt dTJ/dt dx/dt Ejoulie
0 100 25 25 NA -0.40755 1.855774 0.712979 NA 0
0.01349995 99.66988171 26.50317 25.57751 NA -0.39849 1.807182 0.704351 NA 70.84444
0.0269999 99.34710938 27.96698 26.14803 NA -0.38964 1.75983 0.695859 NA 140.8315
0.040499849 99.03150161 29.39244 26.71168 NA -0.38101 1.713687 0.6875 NA 209.9748
0.053999799 98.72288158 30.78052 27.26855 NA -0.3726 1.668721 0.679272 NA 278.2876
0.067499749 98.42107692 32.13218 27.81876 NA -0.36439 1.624904 0.671173 NA 345.7828
0.080999699 98.12591956 33.44835 28.36241 NA -0.35639 1.582206 0.663199 NA 412.4733
0.094499649 97.83724568 34.72993 28.89959 NA -0.34858 1.540598 0.655348 NA 478.3713
0.107999599 97.55489558 35.97781 29.43042 NA -0.34097 1.500053 0.647617 NA 543.4893
0.121499548 97.27871353 37.19285 29.95499 NA -0.33354 1.460544 0.640005 NA 607.8392
0.134999498 97.00854776 38.37589 30.47339 NA -0.32629 1.422045 0.632509 NA 671.4327
0.148499448 96.74425028 39.52774 30.98572 NA -0.31923 1.384529 0.625126 NA 734.2813
0.161999398 96.48567683 40.6492 31.49207 NA -0.31233 1.347972 0.617854 NA 796.3963
0.175499348 96.23268675 41.74105 31.99253 NA -0.30561 1.312349 0.610692 NA 857.7888
Fig. 5.22 Spreadsheet simulation during the initial Joulie heating phase. Similar sheets are used
for Joulie superheated and cooling phases. A fixed time step based on a fraction of the maximum
allowable step size is used. “Goal seek” is used to calculate the correct time step so that the Joulie
temperature equals the melting point at the end of the stage (100 steps chosen). An “if-then-else”
statement is placed in the first row that checks, and returns “VALID SIMULATION” if the last
row for Joulie temperature matches the melting point. If not, the formula returns “SIMULATION
NOT VALID”
Fig. 5.23 Spreadsheet simulation during melting phase of Joulie. A similar sheet is used for the
Joulie freezing stage. The numerical step is taken with a fixed change in quality, “x”, and the
required time step “dt” is calculated from the governing equation for the quality. The initial
conditions (time, temperatures) refer to the last row from the heating phase
192 5 Few-Node Transient Models
100
Coffee without Joulies
90
Coffee with 3 Joulies
80
Temperature (oC)
70 Mug
60
50
40 Joulies
30
20
0 10 20 30 40 50 60 70 80 90
Time (min)
Fig. 5.24 Temperatures as a function of time for the case of a mug of coffee with 3 Joulies. A
2-node simulation (with additional coffee replacing the volume occupied by the Joulies) was
conducted as a control with the same conditions
100
Coffee without Joulies
90
Coffee with 3 Joulies
80
Mug
Temperature (oC)
70
60
50
Joulies
Superheating
40
Freezing
Heating
Cooling
Melting
30
STAGE:
20
0.01 0.1 1 10 100
Time (min)
Fig. 5.25 The same data as Fig. 5.24 plotted on semi-logx axes. The boundaries for the stages
undergone by the Joulies are shown as vertical dotted lines
Plots of temperature vs. time are shown in Figs. 5.24 (linear axes) and 5.25
(semi-logx axes). The 2-node coffee/mug model is shown as the control case. The
mug curve is shown only during the Joulie heating and melting stages to reduce
clutter in the plots. The mug follows the coffee (a few degrees lower) after that.
Appendix 1. Nodal Response Time 193
During the Joulie heating phase, the mug and Joulie temperatures rise quickly, the
mug rising faster owing to its smaller time constant. The Joulies then reach
the melting point and stay there until melting is complete. Thereafter, in the
superheating phase, the Joulie temperature increases (as a liquid) toward the
coffee, and then decay as the coffee continues to cool. The peak in the Joulie
temperature coincides with the point where the coffee temperature equals the
Joulie temperature, as there is no heat transfer during this time. After the peak, the
coffee is colder than the Joulie, and heat flows from the Joulie to the coffee,
returning energy stored to the coffee. Once the Joulie cools to its melting
temperature, the liquid freezes to a solid until phase change is complete. The
Joulie cools with the coffee after that.
Compared to the control curve (coffee without Joulies), the coffee cools quickly
with Joulies, reaching a drinking temperature in a noticeably shorter time. The heat
is retained for a slightly longer time, yielding a much longer time window.
For me, it’s being able to drink hot coffee much sooner that sold me on the
product. As I said “I like Joulies so much, I wrote a book about it!”
Figure 5.3, reproduced here, shows a node with a capacitance, two neighbors and
heat generation. The inherent response time of this node is established by deter-
mining its response assuming its neighbors are fixed, not variable. In this case, T1
will approach an equilibrium value that will depend on its two neighbors and the
heat generation.
dT 1 T2 T1 T1 T1
C1 ¼ Q_ 1 þ þ
dt R12 R11
A dimensionless temperature (ψ 1) that starts at a value of unity (1) and approaches a
value of zero at equilibrium, and a dimensionless time defining a response time for
node 1 (τ1 ¼ RC1equiv, to be determined) are defined:
194 5 Few-Node Transient Models
T 1 T 1eq
ψ1 ¼
T 0 T 1eq
t t
^t ¼ ¼
τ1 RC1equiv
The term in brackets [ ] is identically zero because the equilibrium value for T1 is
defined by setting the time derivative of the nodal equation to zero:
Then the factor (T0 T1eq) cancels and the dimensionless equation is:
dψ 1 τ1 1 1
¼ þ ψ
d^t C1 R12 R11 1
C1
τ1 ¼ ¼ R1equiv C1
1
R12 þ R11
1
dψ 1
¼ ψ 1
dt
with solution:
ψ 1 ¼ e^t
Figures 5.6 and 5.7 (repeated side by side) shows the input parameters
(left) and derived quantities (right) from the “params” worksheet from
“Ch5_2Node_Transient.xls.” The formulas used in the tables on the right side
(that reference the cells in the input quantities block) are detailed in this appendix.
196 5 Few-Node Transient Models
Appendix 2. Detailed Thermal Resistance Formulas for Coffee Mug Problem 197
V H
coffee H0
mug
V
HL¼
πD2 =4
The area of contact between the coffee and the mug is the sum of the bottom and
sides:
Ainside ¼ πD2 =4 þ πDðH LÞ
The total outside surface area of the mug (exposed to ambient) includes the outside,
bottom (neglecting the bottom ridge area), the top rim surface, and the inside mug
surface above the coffee level:
The average mug surface area (used in the mug-conductive resistance) is the
geometric average of the inside and outside areas:
Individual Resistances
T∞
evaporation
convection
radiation
Rsa
Tsurface
coffee Rcs mug
Tinside T2 Toutside T∞
T1 convection
radiation
Rcm Rmug Rmug
2 2 Rma, side
C1 C2
Rma, floor
1
Rcs ¼
hcoffee=surface Atop
The value chosen for the equivalent heat transfer coefficient (hcoffee/surface ¼ 470 W/m2/K)
is representative of a natural convection between a liquid with water properties
and a solid surface.
The equivalent convective/radiative/evaporative resistance between the coffee
surface and ambient is:
1
Rsa ¼
hair=top Atop
The value chosen for the equivalent heat transfer coefficient is built on values of
6.8, 6.6, and 10 W/m2/K for convection, radiation, and evaporation, respectively.
The convective resistance between the coffee and the mug inner surface is:
1
Rcm ¼
hcm Ainside
The value chosen for the convection coefficient (470 W/m2/K, with radiation
considered negligible in comparison) is representative of natural convection
between a liquid with water properties and a vertical surface.
Appendix 3. Joulie Property Estimation 199
w
Rm ¼
kmug Aaverage
This resistance is split into two equal parts between the capacity-carrying mug node
and the mug surfaces. This model is considered reasonable for nearly full mugs. A
detailed analysis of nearly empty mugs is deferred to a later chapter.
Heat transfer from the outer surface of the mug to ambient is split into two
parallel channels: side and bottom. For the side, a convective/radiative equivalent
resistance for those portions exposed to air is:
1
Rma, sides ¼
hair=sides Aoutside π ðD þ 2wÞ2 =4
The area is the outside area subtracted by the surface area of the bottom. The
equivalent heat transfer coefficient is the sum of the convective and radiative
portions (8.8 and 8.6 W/m2/K, respectively). For the heat transfer through the
bottom:
1
Rma, floor ¼
hfloor π ðD þ 2wÞ2 =4
The effective heat transfer coefficient (hfloor ¼ 4.7 W/m2/K) is detailed in Chap. 4,
and reflects heat that flows from the bottom of the mug to the floor it is placed on,
and then conducted outward into the floor.
Resistance and capacitance value estimation requires assumptions about the con-
struction of the Joulie, detailed in this appendix, and calculated in a separate
worksheet (Fig. 5.26). The mass and volume of Joulies are easily measured
(34.0 g and 20.6 mL). Thermal properties are obtained online (accessed 1 February
2014), with convection coefficients inside and outside entered as representative
values.
The Joulies are modeled as equivalent spheres. That is, the equivalent outer
diameter is calculated from the measured volume as:
1=3
6V
d¼
π
200 5 Few-Node Transient Models
MEASURED VALUES
mass 0.028 kg Single Joulie mass
Vtotal 2.06E-05 m^3 Single Joulie volume
Fig. 5.26 Input spreadsheet focused on property values for a single Joulie used as inputs to the
simulation input sheet
The diameter of the wax (and thereby the wall thickness) is determined by summing
the total mass from wax core plus shell:
mTotal ¼ ρshell V shell þ ρwax V wax ¼ ρshell ðV Total V wax Þ þ ρwax V wax
¼ ρshell V Total V wax ðρshell ρwax Þ
6V wax 1=3
dwax ¼
π
Workshop 5.1. A Batch Mode Solar Water Heater 201
For the resistances, there are two separate entries for Rwax, representing the thermal
resistance between the wax and the inner shell wall. The first is a pure conduction
value and the second is assuming a convective mode. The conduction value is much
larger than the convective one and also large compared to the outer convection plus
conduction across the shell wall (which is negligible). That means that the Biot
number of the wax is large, and during heating, the center of the wax will respond
much more slowly than its outer layers. Use of the convection resistance is
considered a better way to estimate the rate at which heat is absorbed by the Joulie.
A more detailed spatial model would be the way to address this issue (and a great
assignment!).
These calculations are for a single Joulie. Note that when multiple Joulies are
used, the total capacitance is proportional to the number of Joulies, while the
thermal resistance is inversely proportional. Adding more Joulies increases the
total surface area, reducing the resistance of heat flow. That is:
1
C3 Joulies ¼ 3Csingle Joulie while R3 Joulies ¼ Rsingle Joulie
3
I’d bet that lots of people would not think that through and assume R3 Joulies ¼
3R1 Joulie, and in so doing confuse a parallel heat transfer concept with a series
effect.
An alternative to burning fossil fuels to produce hot water for domestic needs is to
heat water using solar energy. It is a common experience that placing a garden hose
in direct sunlight can produce hot water. It is also a common experience that
sunlight can be focused using a magnifying glass. Alternatively, a reflecting mirror
can be used to focus sunlight. This workshop applies these principles to a specific
arrangement in which a “solar pipe” is filled with initially cold water and placed in
focused sunlight. The water is heated (without a flow of water) until the water
reaches a target temperature, at which point a pump is activated (say by a solar
202 5 Few-Node Transient Models
photovoltaic cell) and the hot water is pumped out of the pipe into a separate tank,
and the pipe is filled with a fresh batch of cold water, completing the batch cycle.
The time it takes to complete a cycle depends on the angle and intensity of sunlight
which varies throughout the course of a day.
An alternative mode, called continuous mode, is to use the same arrangement but
with a continuous flow of water through the solar pipe. That problem will be studied
much later, after the effects of advective flows are developed.
Problem statement: In a solar thermal application (Fig. 5.27), black polypropylene
tubing (kp ¼ 0.15 W/m/ C, ρp ¼ 1,400 kg/m3, cp ¼ 1,600 J/kg/ C) of length L ¼ 3 m,
outer diameter (D0) of 0.040 m, and wall thickness t ¼ 0.0028 m is subjected to
focused sunlight distributed evenly on the outer surface (concentrated with a
parabolic mirror). The intensity of sunlight that enters the top plane (the solar
insolation) has a maximum value of I0,max ¼ 800 W/m2 (on a clear day at noon)
and a solar collection width to rod diameter ratio (n) to be determined as a design
parameter. An optical efficiency ηopt ¼ 0.9 (defined as the ratio of the solar radiation
that strikes the pipe to the collected radiation) accounts for collected solar energy
not absorbed by the pipe. In the end view, the angle of the sun remains perpendicu-
lar to the collecting plane through proper orientation of the mirror (and changes
gradually through the course of a year). From the side view, the angle between the
incoming solar rays and the perpendicular to the pipe varies through the course of a
day, from θ ¼ 90 at sunrise to 0 at noon to 90 at sunset. The absorption
coefficient of incident radiation is α ¼ 0.85 (85 % of the radiation that strikes the
pipe is absorbed, 15 % is reflected). At the start of a cycle, the tube is filled with
liquid water (ρw ¼ 1,000 kg/m3, cw ¼ 4,200 J/kg/K) at a temperature T0 ¼ 15 C.
The tube is exposed to ambient at T1 ¼ 25 C. The objective is to raise the
temperature of the water to a target of Tfinal ¼ 50 C before pumping it into a
separate collection tank and starting a new cycle.
Fig. 5.27 Schematic of a solar pipe placed at the focal point of a parabolic mirror
Workshop 5.1. A Batch Mode Solar Water Heater 203
Note: A specific 2-node model is developed on the next page. It is advised that you
develop your own model first before consulting that model. Then decide which
model to implement.
Model Development
The 2-node thermal RC network shown in Fig. 5.28 treats node 1 as the water and
node 2 as the pipe. The pipe node (2) is placed in the middle of the pipe wall. The
solar absorption is modeled as a heat source absorbed on the surface (not directly on
the capacity-carrying node). The surface node is in thermal contact with ambient
(through a parallel convective/radiative channel with an assumed constant effective
heat transfer coefficient) and the pipe center (through a conductive channel). The
pipe is in thermal contact with the water (through a series conductive/convective
resistance).
T1 Ti T2 Tabs T∞
R1i Ri2 R2a Ra∞
C1
C2
.
Qabs
The nodal equations are (water ¼ 1, pipe ¼ 2, pipe outer surface ¼ abs):
dT 1 T2 T1
C1 ¼
dt R1i þ Ri2
dT 2 T 1 T 2 T abs T 2
C2 ¼ þ
dt R1i þ Ri2 R2a
The solar flux is absorbed at the outer surface, not at the center, and a nodal balance
on the surface node is:
T 2 T abs T 1 T abs
0 ¼ Q_ abs þ þ
R2a Ra1
Expressing the time derivatives with a forward difference approximation and
rearranging for the recursion relations, the future values (superscript “p + 1”, after
a time step Δt) are explicitly expressed in terms of present values (superscript “p”):
!
ðpÞ ðpÞ
ðpþ1Þ ðpÞ Δt T 2 T 1
T1 ¼ T1 þ
C1 R1i þ Ri2
" ! !#
ðpÞ ðpÞ ðpÞ ðpÞ
ðpþ1Þ ðpÞ Δt T1 T2 T abs T 2
T2 ¼ T2 þ þ
C2 R1i þ Ri2 R2a
The time constants for the two nodes are given by:
and
C2
τ2 ¼
1 1
þ
R1i þ Ri2 R2a þ Ra1
The time step can be chosen to be a fraction of the smallest of these.
The rate of heat absorption is defined by:
0 10 10 1
fraction of fraction of Rate of Solar
Q_ abs ¼ @ collected radiation A@ radiation that strikes A@ Radiation A
that strikes pipe pipe that is absorbed Collected
Q_ abs ¼ ηopt ðαÞðnDLI 0 cos θÞ
Workshop 5.2. Cooper Cooling with a Finite Reservoir 205
25
Jet
20 Temperature
Bev
Q
Temperature (C)
15
Ice
10
5
Cold Water
0
0 100 200 300 400 500 600 700 800
Time (seconds)
Fig. 5.29 Schematic of Cooper Cooling with a Finite Reservoir. The data shows the measured
temperature of the water jet before it is used to chill a horizontal rotating beverage. A warm
beverage is added every 60 s (copyright Wei Dai, reproduced with permission)
206 5 Few-Node Transient Models
Note: A specific 3-node model is developed on the next page. It is advised that you
develop your own model first before consulting that model. Then decide which
model to implement.
Model Development
It is good practice to draw a thermal resistance network for this problem in which
capacitance is assigned to the beverage and reservoir, and a rechargeable battery at
the melting point of the reservoir (Tmp) is used to represent the ice. The mass of the
ice, but not its temperature, changes as it melts. Notice that if a reservoir fluid other
than water is used (like salt water), the melting point can differ from that of water.
Also, the capacitance of the reservoir changes with time in a predictable way as ice
melts. The composition of the reservoir might change if a reservoir other than water
were used.
The governing equation for the beverage is the same as that in Workshop 4.2,
namely:
dMice T res T mp
Lf ¼
dt Rice
Lf is the heat of fusion of ice (330 kJ/kg) and the thermal resistance between the ice
and the reservoir (Rice) is one of external flow forced convection on a surface area
that changes with time.
Explicit Formulation
The nodal equations written in the form of an explicit formulation are with
superscripts used to indicate all values that change with time:
Workshop 5.2. Cooper Cooling with a Finite Reservoir 207
!
ðpÞ
ðpþ1Þ ðpÞ ΔtðpÞ T ðres
pÞ
T bev
T bev ¼ T bev þ
Cbev Rbev
!
ðpÞ
ΔtðpÞ T bev T ðres
pÞ
T mp T ðres
pÞ
T 1 T ðres
pÞ
T ðres
pþ1Þ
¼ T ðres
pÞ
þ ðpÞ þ ðpÞ
þ þ VI pump
Cres Rbev Rice R1
!
ðpþ1Þ ðpÞ ΔtðpÞ T ðres
pÞ
T mp
Mice ¼ Mice þ ðpÞ
Lv Rice
The reservoir capacitance equals the specific heat of the reservoir times the mass of
the reservoir, which equals the initial mass of the reservoir (Mres,0) plus the mass of
ice that has melted (the initial mass of ice less the remaining ice, Mice,0 – Mice):
ðpÞ
Cðres
pÞ
¼ cres Mres, 0 þ Mice, 0 Mice
The thermal resistance that models the melting of the ice requires an assumption
about the shape of the ice, and how that changes. For example, if ice cubes (actual
cubes of dimension “w”) are used, and it is assumed that they remain as cubes (even
though in practice the edges become rounded), then the surface area can be related
to the mass. That is, if a total of ncubes are added initially of dimension w0, the initial
mass of ice is given by:
As the ice melts, the number of cubes does not change, but their size does, so that
the remaining mass of ice can be related to the ice cube size by:
Mice ¼ ncubes w3
The thermal resistance between the ice and the reservoir is given by:
ðpÞ 1 1
Rice ¼ ðpÞ
¼ 2
hice Aice hice ncubes 6ðwðpÞ Þ
Notice that the thermal resistance increases as the ice cubes become smaller. A value
of 1,500 W/m2/K would be reasonable for the convection coefficient in this case.
The values for the beverage capacitance and thermal resistance can be taken from
Workshop 4.2, and simulations with different beverages can be conducted. The
electrical input to the pump can be varied, but VIpump ¼ 20 W is a good starting place.
There are a variety of scenarios that can be used to run a simulation. For
example, a prechilling period can be conducted in which case a number of ice
cubes are placed into an input mass of reservoir at an initial temperature, without
actively chilling a beverage, and letting the initial ice/water reservoir come to
208 5 Few-Node Transient Models
equilibrium before adding beverages. A decision about how long to chill each
individual beverage can be made and that simply involves resetting the temperature
of the beverage. Chilling consecutive beverages can be simulated by either fixing
the chilling time or allowing the system to operate until the beverage reaches a
target temperature. In the former case, the final temperature of each beverage will
be different. In the latter case, the total time required to chill each beverage will be
different. Eventually, the reservoir will not be able to chill a beverage to that target.
Workshop 5.2: Solve the 2-node mug of coffee problem using a variable step-size
algorithm that fixes the maximum change in temperature (absolute value) of either
the mug or coffee.
Workshop 5.3: Solve the 2-node mug of coffee problem using a variable step-size
algorithm that fixes the maximum fractional change in temperature of either the
mug or coffee.
Workshop 5.4: Solve the 2-node mug of coffee problem using the backward
implicit method with a fixed time step.
Workshop 5.5: Solve the 2-node mug of coffee problem using a Styrofoam cup.
Workshop 5.6: Solve the 2-node mug of coffee problem using the explicit numeri-
cal scheme with variable thermal resistances on the side channel. Assume an
emissivity of 0.9 for the radiation coefficient, and use the following formulas
(derived in a future chapter) for the convection coefficients. For convection
between the outer surface of the mug and ambient:
0:25
T mug T ambient
where Tfilm,air is the average of the mug and ambient. For convection between the
inner surface of the mug and the coffee:
T
0:25
coffee T mug
hcoffee ¼ 32:38T film, coffee
0:441
0:25
H0
where Tfilm,coffee is the average of the coffee and mug. Compare this model with the
model any of the constant convection coefficient models (and the data).
Workshop 5.7: A hybrid implicit method
For a stiff problem (τ2 τ1), a legitimate approach is to use a forward difference
approximation for the node with the larger response time (i.e., coffee) and a
backward difference for the node with the shorter response time (mug). The future
value of T1 is obtained (from before) as:
Additional Workshop Ideas 209
ðpÞ
ΔtðpÞ ðpÞ T2 T 1 ðpÞ T 1 ðpÞ T 1 ðpÞ
Q_ 1 þ
ðpþ1Þ ðpÞ
T1 ¼ T1 þ þ
C1 ðpÞ R12 ðpÞ R11 ðpÞ
The backward difference equation for T2 is rearranged as:
!
C2 ðpþ1Þ 1 1 ðpþ1Þ C
ðpþ1Þ ðpÞ
T T 1 ðpþ1Þ T 1 ðpþ1Þ
¼ Q_ 2
ðpþ1Þ
T2 þ þ þ 2 ðpþ12Þ þ þ
Δtðpþ1Þ R12 ðpþ1Þ R21 ðpþ1Þ Δt R12 ðpþ1Þ R21 ðpþ1Þ
ðpþ1Þ ðpÞ
Since T1 changes slowly compared with T2, then for one time step, T 1 T1 .
Furthermore, when the coefficients vary with time, they will do so slowly, and the R
and C values can be evaluated at the present, not the future time. Therefore, a
legitimate explicit prediction of the future temperature of T2 that is inherently stable
numerically (let Δt ! 1) is:
ðpÞ ðpÞ
ðpÞ C2 T 2 T 1 ðpÞ T 1 ðpÞ
¼ Q_ 2 þ
ðpþ1Þ
T2 þ þ
Δt ð pÞ
R12 ðp Þ
R21 ðpÞ
C2 ðpÞ 1 1
þ þ
ΔtðpÞ R12 ðpÞ R21 ðpÞ
For this scheme, the time step can be chosen to be a value greater than the Second
Law restriction on a full explicit scheme.
Workshop 5.8: 2-node Electric Water Heater:
An electrically resisting element made of nichrome (thermal conductivity
kelement ¼ 11.0 W/m/K, density relement ¼ 8,400 kg/m3, specific heat
celement ¼ 450 J/kg/K) of diameter d ¼ 0.015 m with a total length to be determined
is designed to be immersed in 1.0 L of liquid water in a cylindrical container of
inner diameter D ¼ 0.15 m with a thin wall (negligible thermal capacity and
conductive resistance). The water is initially at 15 C and electrical power at the
rate of Q ¼ 1,000 W is delivered to the heating element.
Conduct a 2-node analysis (element and water). Assume that the heat transfer
coefficient between the element and the water, and between the water and the
container is helement,water ¼ hwater,container ¼ 400 W/m2/K, the convective/radiative
coefficient between the outer wall and ambient is hcontainer,air ¼ 15 W/m2/K.
Determine:
1. The length of the heating element needed so that the water temperature is 90 C
at the point the water starts to boil (i.e., reaches 100 C) in the thermal boundary
layer between the element and the water and the corresponding time required to
boil. Note: if heated beyond this point, most of the heat will go toward boiling
the water in that boundary layer, and not to raising the temperature of the bulk of
the liquid. That is to say, it is difficult to obtain water hotter than 90 C for this
heating element at this heating rate.
2. The time to start to boil and the final water temperature obtained for this length
heating element, but with a heating power of 500 W.
3. The minimum power that would yield 90 C water and the corresponding time
and the temperature of the element at that time.
Multi-Node Transients
6
This chapter builds on the few-node numerical approach, detailing the side wall of
the mug of coffee problem, which is where the majority of heat is lost (60 % of the
surface area exposed to ambient). Results are generated only for the mug heating
phase, as computationally, simulation of the entire cooling event would require
several large spreadsheets. Conceptually, multi-node problems involve a simple
extension of the principles developed for the 2-node mug of coffee model. For
example, adding Coffee Joulies™ added a third node. This type of problem is
generally solvable with a spreadsheet approach for an explicit formulation (but not
for an implicit one).
However, a subtle distinction is made between a few-node and a multi-node
problem. In programming a multi-node simulation, some or all of the recursion
formulas can be written in terms of an input numerical parameter, say “n”. For
example, the mug side wall will be split into “n” nodes. The governing equations
will be derived in terms of “n”. However, for spreadsheet solutions, as detailed in
this chapter, a commitment to a specific number must be made at the outset (set up
the number of columns). Technically, then, this is a “few-node” approach, but a
spreadsheet implementation is developed here to demonstrate the details of the
method.
Numerical modeling in heat transfer involves discretization of both space and
time. In the 1-node model, space was discretized by lumping all the mass of the
coffee/mug system into a single node. If the thermal resistances are taken as
constants, the governing ODE is easy to integrate and it is not necessary to
discretize time. For variable resistances (natural convection and radiation
boundaries, developed in future chapters), time can be discretized by turning the
time derivative into an approximate algebraic expression using finite difference
approximations, and the transient problem can be simulated by appropriately
stepping forward in time. In the 2-node model, space was discretized into two
lumped pieces; coffee and mug. Time was discretized using a finite difference
approximation. This chapter introduces a more general approach by breaking space
into many discrete nodes.
Problem Statement
The first part of the problem statement, the description of the mug of coffee and its
dimensions, is exactly the same as the original one. The objective stated is different:
A volume V ¼ 0.41 L of coffee at 1 atm, 92 C is quickly poured into a room
temperature (23 C) ceramic mug with mass of mmug ¼ 0.335 kg, inner diameter
D ¼ 0.083 m, inner height H ¼ 0.098 m, and nominal wall thickness w ¼ 0.0040 m.
The mug of coffee is placed on a table in a still room. Determine the temperature
distribution in the mug side wall as a function of time.
Figure 6.1 shows an RC network for the mug of coffee. The coffee itself is modeled
with a single node, with three parallel channels for heat flow: top (free) surface,
bottom, and side wall. The side wall has been broken up into a total of “n” nodes,
where n will be set to 8 for the case study of the mug of coffee implemented in an
Excel file. Each node represents a cylindrical shell and has a capacitance associated
with it. The sum of all “n” capacitances is the total capacitance of the side wall of
the mug. Heat transfer out of the top rim and bottom of the side wall is neglected.
Thermal resistances between each node represent a conductive thermal channel
between them. The coffee (at temperature T(t)) has a capacitance C that consists of
the capacitance of the coffee plus the capacitance of the bottom wall lumped into
it. This portion of the mug capacitance is easy to account for by lumping it with the
coffee, rather than including it with the mug capacitance as was done in the 2-node
mug of coffee example.
6.2 Defining the Grid (i.e., Discretization of Space) 213
Fig. 6.1 RC network for the mug side wall discretized into n-nodes
The two end nodes (1 and n) are not placed on the mug surface, but rather are
placed inside the volume of the section of the mug it represents. Therefore, the inner
and outer surfaces of the mug are shown as filled circles. These are surfaces, not
volumes, and therefore have no capacitance associated with them. Node 1 has two
parallel channels: one between the node and the coffee and the other between the
node and the air inside the rim. Each of these channels consists of a convective and
a conductive resistance in series. This detail is a result of a “define volumes, then
place nodes” or finite volume approach, as opposed to a “place nodes, then define
volume” approach typical of a finite difference method. It gives additional infor-
mation (really the accuracy of n + 2 nodes) plus added numerical stability for the
explicit method to be used. Notice that the distance between the inner surface and
node 1 is approximately half the distance between node 1 and 2, so these resistance
values differ by a factor of about 2. It is not exactly 2 due to the radial geometry.
The last node (n) has a conductive resistance to the outer surface in series with a
convective/radiative parallel channel.
There are different ways that the nodal volumes can be defined. There is not
necessarily a “right” way to do it, although the method should be self-consistent.
The approach taken here is to define all the nodes as cylindrical shells of equal
height (from the floor to the rim, H0) and equal capacitance. As a result, the spacing
between nodes decreases from the inside to the outside due to the radial geometry.
An alternative approach would be to space the nodes equally, and then their
volumes would increase with radial position. In this control volume approach to
the spatial discretization, the locations of the element boundaries are first defined by
the chosen volumes, and then each node is placed in the center of the volumes
214 6 Multi-Node Transients
inside. Conceptually, the node could be placed at the centroid of the nodal element
(for non-square elements).
Figure 6.2 shows a top view of a cylindrical shell imagined to be cut and
opened up to as a wall of uniform thickness (Δr) and a width that varies from 2πr
to 2π(r + Δr). The height (into the page) is also uniform (H0).
Figure 6.3 defines the geometry for node 1. The distances to the radial position of
the boundary of the element are shown above (r1 and r1+), and the distance to the
node is shown below (r1). The distance to the inner boundary is simply the radial
distance from the centerline to the inner surface of the mug:
D
r 1 ¼
2
In this particular approach, the volumes of each element are constrained to be equal
to each other, namely the total volume of the mug side wall divided by the number
of nodes (n):
h i
π ðD þ 2wÞ2 D2 H 0
V node ¼
4n
The height of the node is taken to be the measured outer height of the mug (H0).
Conceptually, that would be the inner height plus the mug thickness if the mug were
uniformly thick. However, the actual mug under investigation has a bottom rim, and
the exterior height is therefore a little larger. The distance to the outer boundary of
node 1 is also the inner boundary of node 2 and is determined by defining its
volume:
6.2 Defining the Grid (i.e., Discretization of Space) 215
T∞ Ras,i R1s,a
r1−
r1+ = r2−
T Rcs R1s 1
R12 2
C1
r1
V node ¼ π r 22 r 21 H o
Solving for the radial position of the boundary between node 1 and 2:
rffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi
V node
r 2 ¼ r 21 þ
πHo
The node itself is placed at the centroid of the volume, defined by:
rð
2 rð
2 2
r3 2π 3
r1 A ¼ rdA ¼ r ð2πrdr Þ ¼ 2π ¼ r 2 r 31
3 r1 3
r1 r1
2 r 32 r 31
r1 ¼ 2
3 r 2 r 21
Alternatively, simply placing the node halfway between would actually be just
as good. . .
216 6 Multi-Node Transients
Consider next node 2. Its volume is the same as node 1 (Vnode) and is defined by:
V node ¼ π r 23 r 22 H o
For the last node, n, the distance to the outer boundary is the outer radius of
the mug:
D
r nþ ¼ þw
2
6.3 Nodal Equations for Explicit Method (Euler) 217
1 2 3 4 5 6 7 8
Fig. 6.4 Locations of nodes and boundaries for an 8-node model applied to mug of coffee
problem
Figure 6.4 shows the precise radial locations of all boundaries of each nodal
element (to scale, horizontally) as dotted lines, except for the inner and outer
surfaces (shown as solid lines) for the 8-node case applied to the mug of coffee
problem. The length of each vertical line is proportional to the surface area of the
boundary. The area increases with radial position because of the increasing circum-
ference. The height of each “wall” is the same, however. To the naked eye, the
nodes may appear equally spaced, but they are in fact closer together as the distance
from the mug center increases. In this case, the mug wall thickness (0.004 m) is
small compared to the inner radius (0.041 m), making a thin-wall approximation
(not taken here) reasonable. The surface area of inner boundary (line length)
increases slightly with radial distance.
In general, the transient thermal energy balance for a fixed volume element “i” in
thermal contact with neighbors “j” is:
dT i X Tj Ti
Ci ¼ Q_ i þ
dt j
Rij
218 6 Multi-Node Transients
Q_ i represents heat generation, which could come from an internal chemical reaction
(conversion of chemical to thermal energy), from the absorption of radiation, from
I2R heating (conversion of electrical to thermal energy), from microwaving, etc. In
the problem at hand, there are no heat sources. Rij represents the thermal resistance
between node “i” and its neighbor in question “j”. The detailed engineering work is
in estimating the resistance values (which may be variable).
Discretizing time using a forward finite difference approximation:
Ti
ðpþ1Þ
Ti
ðpÞ
ðpÞ X T ðj pÞ T ði pÞ
¼ Q_ i þ
ðpÞ
Ci
ΔtðpÞ j
ðpÞ
Rij
For a system with n total capacity-carrying temperature nodes (as opposed to nodes
fixed by a battery, or a surface node), there are n equations. Starting with an initial
temperature, a numerical step size is chosen, and all future temperatures are calculated.
Recall from Chap. 1 that the explicit formulation places a strict limit on the
numerical step size chosen. Each node has a different time constant associated with
it which represents how quickly it responds to its immediate neighbors. From
Chap. 1, the time constant for a node toward an equilibrium value with its neighbors
at a fixed temperature is given by:
ðpÞ
ðpÞ C
τi ¼ Xi
1
ðpÞ
j Rij
The maximum step size for the system that can be used in an explicit formulation is
the smallest of these:
ðpÞ
Δtðmax
pÞ
¼ minτi
If a step size larger than this limit is used, the node with the minimum time constant
will overshoot its equilibrium value.
The nodal equations for all nine variable temperature nodes (coffee plus node
1, six interior nodes, and node 8) are:
For the coffee:
For node 1:
ðpÞ ðpÞ
!
ðpÞ ðpÞ ðpÞ
ðpþ1Þ ðpÞ ΔtðpÞ T coffee T 1 T T1 T1 T1
T1 ¼ T1 þ þ 2 þ
C1
ðpÞ Rcs þ Rs1 R12 Ras, i þ Rs1, a
ðpÞ ðpÞ
!
ðpÞ ðpÞ
ðpþ1Þ ðpÞ ΔtðpÞ T i1 T i T Ti
Ti ¼ Ti þ ðpÞ þ iþ1
C R i, i1 Ri, iþ1
i
For node 8:
!
ðpÞ ðpÞ ðpÞ
ðpþ1Þ ðpÞ ΔtðpÞ T7 T8 T1 T8
T8 ¼ T8 þ þ
C8
ðpÞ R78 R8s þ Rs1
T coffee T 1 T coffee T 0
qcoffee, 1 ¼ ¼
Rcs þ Rs1 Rcs
Solving for the surface temperature:
Rcs
T 0 ¼ T coffee T coffee T 1
Rcs þ Rs1
For the outer surface:
T8 T1 T9 T1
q81 ¼ ¼
R8s þ Rs1 Rs1
Rs1
T9 ¼ T1 þ ðT 8 T 1 Þ
R9s þ Rs1
The final step before implementing the method in a computer simulation is to define
the capacitances and thermal resistances in terms of system parameters, detailed in
the following paragraphs. Results for the coffee/mug problem are listed in Table 6.1,
and the various entries are discussed as they arise.
220 6 Multi-Node Transients
Table 6.1 Nodal geometry, capacitance, resistance, and step-size restriction at the start of the
simulation
Varies with time. Initial value is shown, which yields a minimum step size
The shaded cells indicate that these step sizes vary with time and must be confirmed to not control
the system at a later time
6.3.1 Capacitances
Each node has a capacitance of 29.2 J/ C, and the total capacitance of the mug
side wall is 8(29.2) ¼ 234 J/ C, which is 87.3 % of the total capacitance of the
mug (the remainder at the bottom which is lumped with the coffee).
The capacitance for the coffee is that calculated for the 1-node cases, plus the
capacitance of the bottom of the mug:
Ccoffee ¼ ρcoffee ccoffee V coffee þ mmug cmug V mug n Cnode
The capacitance of the coffee, 1,757 J/ C, is (not surprisingly) much larger than the
capacitance of each node in the mug wall. Inclusion of the bottom of the mug has a
small (2.9 %) effect on the coffee capacitance for this case study and could be
neglected. However, it is easy to incorporate it, and it might be more important for
other applications, so it is included.
6.3.2 Resistances
All the resistance values are shown in Table 6.1 (except for the resistance between
node 1 and the air inside the rim of the mug, which is treated separately). They are
derived one at a time, from left to right. Starting with the convective thermal
resistance between the coffee and the inner wall of the mug:
1 1
Rcs ¼ ¼
hcs Ar1 hcs πDðH LÞ
In this expression, H is the depth of the coffee on the inside and L is the vertical
distance of the air column on the inside of the mug, making H L the vertical
dimension of the contact area between the coffee and the inner surface of the mug.
6.3 Nodal Equations for Explicit Method (Euler) 221
The convection coefficient, hcs, results from a natural convection process between
the coffee and the inner wall of the mug. From the Nusselt number correlation of a
future chapter:
T 0:25
coffee T 1
hcs ¼ 32:38T film
0:441
0:25
ðH LÞ
r 1 r 1 r 1 r 1
Rs1 ¼ ¼
kmug Ar12þAr1 πkmug ðr 1 þ r 1 ÞðH LÞ
The numerator is the spacing between nodes 0 and 1, and the area is the geometric
average between the two. This thermal resistance is in series with the convective
resistance, and it is conceptually half that of a thermal resistance between two
interior nodes (from Table 6.1, R01 ¼ 0.0094 C/W, while R12 ¼ 0.0185 C/W).
For the resistance between node 1 and ambient through the inner surface of the
mug rim:
1 r 1 r 1
Ras, i þ Rs1, a ¼ þ
heff πDL πkmug ðr 1 þ r 1 ÞL
In this expression, heff represents the sum of the convective and radiative coefficients
between the surface and the ambient. The same value as calculated for the outer
surface will be used. There are admittedly several inconsistencies in how this thermal
channel is treated. The philosophy is that the exposed surface area in question is a
significant (but not dominant) channel for heat loss, and it is accounted for in a
reasonable approximation by the approach taken. Modeling is an art.
Continuing left to right, the conductive resistance between nodes 1 and 2 is:
r2 r1
R12 ¼
kmug 2πr 2 H 0
r iþ1 r i
Ri, iþ1 ¼
kmug 2πr ðiþ1Þ H 0
It would be just as easy to use the exact conductive formula for a cylindrical
geometry, but the more general approach is taken here. From Table 6.1, the
conductive resistance between adjacent interior nodes decreases with radial posi-
tion. There are two reasons for this trend. First, the nodes are closer together, easing
conduction. Second, the surface area across which heat is conducting is larger,
again easing conduction.
222 6 Multi-Node Transients
The conductive thermal resistance between the last element node (“n” in general,
“8” in this implementation) and the surface node (“s” in general, “9” for this
implementation) is:
r9 r8 r9 r8
Rs , n ¼ R9 , 8 ¼ Ar8þ þAr8 ¼
kmug 2
πkmug ðr 9 þ r 8 ÞH 0
Finally, the convective resistance between the outer wall surface (“s” ¼ “9”) and the
ambient air is:
1 1
Rs, 1 ¼ ¼
hs1 Ar9 hs1 π ðD þ 2wÞH 0
The 1-node models taught that the overall system response is very sensitive to the
choice of convection and radiation coefficients between the outer wall and ambient.
This sensitivity is due to the large surface area (a parallel resistance concept), and
because this combined resistance is the largest resistance in the side channel
(a series resistance concept). Therefore, extra attention is warranted in modeling
these parameters. In this numerical simulation, it is relatively easy to account for
heat transfer coefficients that vary with temperature (and therefore time) by calcu-
lating them at each time step. Conceptually, the temperature used should be for the
slightly different node 9, not 8, but that would require an iterative loop, making a
spreadsheet simulation impossible.
For parallel convective and radiative resistances acting on a surface of area A,
with coefficients hconv and hrad, the equivalent resistance is:
1 1 1
¼ þ ¼ hconv A þ hrad A ¼ heff A
R Rconv Rrad
That is, the convective and radiative coefficients add together to form an effective
heat transfer coefficient. If the ambient air immediately adjacent to the mug and
the walls of the room are at significantly different temperatures, then the model
would have to be adjusted by adding a separate channel for radiation and
convection.
The convective coefficient in this case is modeled as a natural convection of air
for a vertical cylinder of height H0, with fluid properties evaluated at the film
temperature. The simplified formula for has from the Nusselt number correlation
(with temperature in C and height in m) is:
jðT 8 T 1 Þj0:25
hair ¼ 1:5646 0:0015T film
H 0:25
o
The leading term represents the combined fluid properties and their relatively mild
temperature dependency.
6.3 Nodal Equations for Explicit Method (Euler) 223
where the temperatures are in Celsius. Again, technically speaking, the surface
temperature (T9) should be used. However, that would require an iterative solution
for each time step, and that would make a spreadsheet implementation problematic.
The computations per step is a fixed number of times the total number of nodes.
That is:
Computations
n
Step
Computations
ðnÞ n2 ðtsimulation Þ
Simulation
That is, if the number of nodes is doubled, the computational requirement increases
by a factor of 8.
This model was implemented into a spreadsheet simulation (Table 6.2) using a
9-node model (eight nodes in the mug, plus the coffee) and stepping in time with the
maximum step size of 0.238 s. Initial conditions and fixed parameters are shaded.
The maximum step size (dtMax) refers to the appropriate cell in Table 6.1, and the
numerical input parameter “f”, set to 1, is the fraction of the maximum step size
used to define dt, the step size taken. It will be demonstrated why a smaller step
size than that is not required for numerical accuracy for this case. In this model,
three heat transfer coefficients depend on surface temperature (hcoffee, hconv, air, and
hrad, air) and therefore must be calculated at each time step. They are placed to the
right, and then the appropriate thermal resistance values are calculated. In the
second row, the Euler formulas are entered (for coffee and nodes 1–8), and then
all equations are copied down for as many rows as is desired.
Temperature/time plots are presented followed by a series of plots of tempera-
ture vs. radial position at fixed times. The heat transfer coefficients are plotted to
The shaded cells contain initial conductions and formulas are embedded in all other cells
6.6 Radial Temperature Profiles 225
observe both their values as well as their change over time. Finally, a consideration
of the numerical issues is presented, demonstrating both spatial and temporal grid
effects.
The workbook written is rather large (15 MB) and it only simulates 36 min of the
entire event. The number of time steps required to simulate 36 min is:
Time elapsed 36 min 60 s
Number of steps ¼ ¼ ¼ 9, 075
Step size 0:238 s min
63,025 steps would be required to simulate the entire 250 event, resulting in a
spreadsheet of over 100 MB. In short, this simulation taxes the limit of spreadsheet
applications, and a shift to a computer program may be warranted.
The input and derived parameters are listed in Fig. 6.5.
Figure 6.6 shows the predicted temperature vs. time for locations that correspond to
the measurements at the mug-free surface and mug side wall during the first 10 min.
The predicted rise of the outer side wall temperature and fall of the free surface both
lag from the measured values, somewhat, but in general, the agreement is consid-
ered to be quite good. The 2-node model (which used fixed resistance values) gave
similar results. However, the 9-node model gives more detail, as shown in the
following paragraphs.
A plot of all nine nodal temperatures, plus the inner and outer surface
(non-capacitive nodes) vs. time is presented in Fig. 6.7, without the experimental
data. The closer each node is to the inner surface, the earlier its temperature rises.
The same plots are shown in Fig. 6.8 on semi-logx axes. This plot more clearly
shows how it takes time before the first “signal” that the inner wall has been
exposed to hot liquid reaches a given location. That is, a thermal “wave” propagates
outward from the inner wall. The initial conditions cannot be shown on the latter
plot (time equals zero cannot be plotted on a logarithmic scale).
A series of similar plots that show the temperature vs. radial position at fixed times
is presented in Figs. 6.9, 6.10, 6.11, 6.12. On the coffee and air side, hypothetical
thermal boundary layers are shown using several columns and an exponential fit for
illustrative purposes.
The first plot shows the first 3 s, during which time the outer wall never
experiences a change. During this period of time, the wall of the mug behaves as
if it were infinitely thick. In traditional heat transfer texts, analytic solutions of heat
transfer into an infinitely thick wall are presented. Those solutions are for flat walls
with constant convection coefficients, whereas this one is for a radial geometry with
226 6 Multi-Node Transients
100
90
80
Temperature (oC)
70
60
50 coffee
40 top
side
30
Top Data
20 Side Data
10
0
0 1 2 3 4 5
Time (min)
100
90
80
70
Temperature (oC)
coffee
60 top
side
50
Inner Surface
Radial Position Node 1
40
Node 2
Node 3
30
Node 4
Node 5
20
Node 6
10 Node 7
Node 8
0
0 0.5 1 1.5 2
Time (min)
Fig. 6.7 Nodal temperatures vs. time for the first 2 min
during the first 30 min. This behavior maintains itself until the entire event is over,
when the mug reaches equilibrium. During this period, there a very mild tempera-
ture drop from the coffee to the inner surface, another mild drop across the mug
wall, and then a large drop from the outer surface to ambient. This behavior is due
to the relative resistance values of the side channel.
What this behavior suggests, rather strongly, is that using eight nodes in the
coffee mug is total overkill to do this particular job. The main objective here is to
228 6 Multi-Node Transients
100
90
Temperature (oC) 80
70
coffee
60 top
side
50
Inner Surface
Node 1
40
Node 2
Node 3
30
Radial Position Node 4
Node 5
20
Node 6
10 Node 7
Node 8
0
0.001 0.01 0.1 1 10
Time (min)
Fig. 6.8 Nodal temperatures vs. time for the first 10 min on semi-logx axes
90 Nodes
2.85
80
2.38
Temperature (oC)
70 1.90
60 1.43
50 0.95
0.48
40
0.00
30
20
10
0
0.03 0.035 0.04 0.045 0.05
Radial Position (m)
Fig. 6.9 Temperature vs. radial position for the first 3 s. Symbols shown for the latest curve to
indicate nodal positions
teach the method, but good engineering judgment would suggest that the 2-node
model (with the finite volume approach to yield surface behavior) is adequate for
this application. And the extended lumped model is sufficient for the entire event
(but not for the early mug heating phase).
6.6 Radial Temperature Profiles 229
16.15
60
10.69
50
5.46
40 0.00
30
20
10
0
0.03 0.035 0.04 0.045 0.05
Radial Position (m)
Fig. 6.10 Temperature vs. radial position for the first 30 s. Symbols shown for the latest curve to
indicate nodal positions
Time (minutes)
100
Nodes
90
3.19
80 2.66
70 2.13
Temperature (oC)
1.60
60
1.06
50 0.53
40 0.00
30
20
10
0
0.03 0.035 0.04 0.045 0.05
Radial Position (m)
Fig. 6.11 Temperature vs. radial position for the first 3 min. Symbols shown for the latest curve to
indicate nodal positions
230 6 Multi-Node Transients
Time (minutes)
100
5.32
90
10.63
80 15.94
70 21.25
Temperature (oC)
26.57
60
31.88
50 Nodes
40 0.00
30
20
10
0
0.03 0.035 0.04 0.045 0.05
Radial Position (m)
Fig. 6.12 Temperature vs. radial position for the first 30 min. Symbols shown for the latest curve
to indicate nodal positions
20
Heat Transfer Coefficient (W/m2/ oC)
18 Net
Radiation
16 convection
14
12
10
8
6
4
2
0
0 1 2 3 4 5
Time (min)
Fig. 6.13 Heat transfer coefficients on the outer surface of the mug vs. time for the first 5 min. If
simulated for the entire cooling event, the convection coefficient will go to zero, while the
radiation coefficient will remain finite
The heat transfer coefficients are shown as functions of time for the first 3 min on
the air side in Fig. 6.13 and on the coffee side in Fig. 6.14. At time zero, when
the outer wall is at ambient, the natural convection coefficient is zero, according to
6.8 Numerical Stability and Accuracy 231
1200
800
600
400
200
0
0 1 2 3 4 5
Time (min)
Fig. 6.14 Heat transfer coefficients on the inner surface of the mug vs. time for the first 5 min
the model. However, the radiation coefficient is not zero initially, and would control
the overall heat transfer rate during periods of time where the solid surface
temperatures are nearly equal to the adjacent fluid. This behavior emphasizes the
importance of including radiation when natural convection predominates. As the
outside surface wall temperature rises in the first 30 s, the convection coefficient
rises and becomes almost equal to the radiative. The effective heat transfer coeffi-
cient is the sum of the two and equals approximately 14 W/m2/ C.
In contrast, the convection coefficient on the water side starts high because the
mug and coffee are at very different temperatures early. The inner mug wall surface
temperature rises rapidly initially, and therefore the temperature difference driving
the natural convection inside decreases. The convection coefficient inside therefore
starts at a value just above 1,000 W/m2/ C and falls rapidly to a value of approxi-
mately 500 W/m2/ C.
As time proceeds, the two natural convection coefficient values gradually fall as
both the mug and coffee approach ambient. The model should really build in a
lower cap to the convection coefficients.
Figures 6.15 and 6.16 show the same plots as Figs. 6.8 and 6.9, respectively, but
with the step size chosen to be only 10 % larger than the minimum step size (0.262 s
as opposed to 0.238 s). It is apparent that an instability arises, and it starts at node
7, and emanates from there. This instability reveals the biggest problem with an
explicit formulation, especially as the spatial grid is made finer.
On the other hand, a comparison of the model prediction for node 7 is made
when the step size is reduced by an order of magnitude in Fig. 6.17. There are
232 6 Multi-Node Transients
100
90
80
coffee
70 top
Temperature (oC)
side
60 Inner Surface
Node 1
50 Node 2
10
0
0 0.5 1 1.5 2
Time (min)
Fig. 6.15 Simulation with a step size of 1.1 times the maximum allowable step
Time (seconds)
100
Nodes
90
35.27
80 29.26
70 23.51
Temperature (oC)
17.77
60
11.76
50
6.01
40 0.00
30
20
10
0
0.03 0.035 0.04 0.045 0.05
Radial Position (m)
Fig. 6.16 Radial profile for first 30 s with a step size 1.1 times the minimum
actually two indistinguishable curves plotted, one when f ¼ 1 and the other for when
f ¼ 0.1, a reduction in step size of an order of magnitude. This plot demonstrates
temporal grid insensitivity exists when the maximum allowable step size is used in
this case.
6.8 Numerical Stability and Accuracy 233
100
90
80
Node 7 Temperature (oC)
70
60
50
f=1
40
f = 0.1
30
20
10
0
0 0.2 0.4 0.6 0.8 1
Time (sec)
Fig. 6.17 Effect of step size on node 7. The two curves are indistinguishable
ðpþ1Þ
Ti Ti
ðpÞ
ðpþ1Þ X T ðj pþ1Þ T ði pþ1Þ
Ci ¼ Q_ i þ
ΔtðpÞ j
ðpþ1Þ
Rij
Isolating all terms for node “i” evaluated in the future (p + 1):
ðpþ1Þ X T ðj pþ1Þ Ci T i
ðpÞ
Q_ i þ ðpþ1Þ
þ
j Rij
ΔtðpÞ
ðpþ1Þ
Ti ¼
Ci X 1
þ
Δt j R
ðpþ1Þ
ij
Write a spreadsheet or program code to simulate the thermal response when the
component is powered on, allowed to reach an effective steady-state, and then
turned off and allowed to cool until it is effectively back to ambient. Treat the base
plate as a uniform temperature lumped node (neglect its conductive resistance) that
receives the generated heat and transfers it to the fins, which are assumed to behave
identically. Analyze a single fin by breaking it into “n” equal sized nodes and
g/2 g/2
t
L Fin
W
Base plate
base plate b
W electronic component
b
Fig. 6.18 Schematic of heat sink (left) and an end view of an isolated fin (right)
Workshop 6.1. Transient Heat Transfer Fins 235
performing a transient analysis using the explicit method. Assume the fin (and base
plate) is exposed to ambient with a fixed heat transfer coefficient h. Radiation is
neglected in this case because the fins “see” each other.
The main objectives of this exercise are to successfully implement an “n-node”
transient analysis, and to gain an understanding of the transient and steady-state
response of heat transfer fins. At a minimum, prepare and discuss well-formatted
plots of base plate temperature vs. time (with all materials on the same plot), steady-
state temperature vs. position (distance from the base plate, all three materials).
Also, consider temperature vs. position at fixed times for aluminum. Conduct a
study of the effect of h (range from 10 to 100 W/m2/K to simulate natural
convection to a “strong crosswind” using aluminum.
Note: A specific 5-node model is developed on the next pages. It is advised that you
develop your own model first before consulting that model. Then decide which
model to implement.
Model Development
A 5-node RC network (base plate segment plus n ¼ 4 equal sized nodes of the fin) is
shown in Fig. 6.19 for a single fin. The term “longitudinal” will be used to designate
a distance along the fin length (L or Δx), and “lateral” will refer to across the fin (t).
Fig. 6.19 Schematics for 5-node transient fin problem. The top figure defines the nodal volumes
used. The bottom shows the RC network (the light lines define the nodal volumes)
236 6 Multi-Node Transients
The fin is broken into “n” (4 in this schematic) equally sized longitudinal elements, with
a recognized symmetry so that only half of the fin need be considered. The base plate
node is just that section associated with the fin being analyzed. Capacitances are
assigned to each node and thermal channels between them are shown in the RC network.
The symmetry has been used on the fin, accounting for the “q/2” being delivered to
each fin, with M being the total number of fins and q the total heat dissipated.
The equations will be developed with a general form with the fin being broken
into “n” equally sized nodes. Therefore, the length of each node, which also equals
the distance between them is given by Δx ¼ L=n. The distance between the base
plate (node 0) and node 1 of the fin is Δx/2.
The capacitances are all equal to
t t L
Ci ¼ ρcw Δx ¼ ρcw
2 2 n
The resistance between the base plate directly to the air is by:
1
R01 ¼
hwg=2
The conductive resistance between the base plate and node 1 is:
Δx=2
R01 ¼
kwt=2
Notice that the distance from the base plate to node 1 is half of element length. The
conductive resistances between the other nodes are:
Δx
Ri, iþ1 ¼
kwt=2
The resistances between each node and ambient is given by a series conduction and
convection resistance. For interior node “i”:
1 t=4 1 ht=4 1
Ri, iþ1 ¼ þ ¼ 1þ ¼ ð1 þ BiÞ
hΔx kΔx hΔx k hΔx
where a Biot number has been introduced (the ratio of lateral conductive to
convective resistance). The end node (“n”) has a different surface area, and its
resistance consists of two parallel channels (lateral and longitudinal) each of which
has a conductive and convective resistance in series:
1 1 1
¼ þ
Rn1 1
hΔx þ t=4
kΔx
1
ht=2 þ Δx=2
kt=2
Workshop 6.1. Transient Heat Transfer Fins 237
This resistance could be expressed in terms of the Bi defined above and the ratio of
fin thickness to element length. It is common in fin analysis to neglect the heat
going out the end in comparison to that going out the sides, but is included for
completeness, and practice in defining resistance values.
Using the explicit numerical method, the nodal equations are:
Base Plate:
" #
ðpÞ ðpÞ ðpÞ
ðpþ1Þ ðpÞ Δt q T1 T0 T1 T0
T0 ¼ T0 þ þ þ
C0 2M R01 R01
Node i ¼ 1 to n1:
" ðpÞ ð pÞ
#
ðpÞ ðpÞ ðpÞ
ðpþ1Þ ðpÞ Δt T i1 T i T iþ1 T i T1 Ti
Ti ¼ Ti þ þ þ
Ci Ri, i1 Ri, iþ1 Ri1 ð1 þ Bii Þ
Node n:
" #
ðpÞ
Δt T n1 T ðnpÞ T 1 T ðnpÞ
T ðnpþ1Þ ¼ T ðnpÞ þ þ
Cn Rn1, n Rn1 ð1 þ Bin Þ
In these expressions, the Biot numbers represent the ratio of the conductive to
convective resistance in the direction perpendicular to the direction of the primary
heat flow and can be shown to be negligible for these cases. The time constants are:
1 1
τ0 ¼ C0 þ
R01 R01
1 1 1
τi ¼ Ci þ þ
Ri, i1 Ri, iþ1 Ri1 ð1 þ Bii Þ
1 1
τ n ¼ Cn þ
Rn, n1 Rn1 ð1 þ Bin Þ
The maximum step size for numerical stability is the smallest time constant. Choose
the step size to be a fraction (f) of this limit.
Part III
Steady-State Conduction
Heat Transfer Fins (and Handles)
7
Extended surfaces are widely used as either heat transfer fins (devices designed to
increase the overall rate of heat transfer between a solid and a fluid) or handles
(something you can grab without burning your hand). For fin applications, since the
rate of heat transfer by convection (and possibly radiation in parallel) is propor-
tional to the exposed surface area, the basic idea is to increase that exposed surface
area, as suggested in Fig. 7.1. However, because the temperature in the fin decreases
with the distance from the wall (x), there is a limit to how far the fin can extend and
still be effective. A “perfect” fin is one in which the temperature of the fin is the
same everywhere as its base. In a real fin, the average temperature of the fin exposed
to the fluid will be less than that, and therefore the fin transfers heat at a lower rate.
If the fin is long enough, the temperature at the end of the fin approaches the
ambient temperature. That’s a handle you can grab.
An exact analysis of the steady-state 1D heat transfer associated with an
“extended surface” is included in virtually all heat transfer textbooks for the case
where the cross-sectional area is constant with distance from the wall (i.e., the area
of the fin base (t*d) is projected outward from the base). The result for the more
general transient case (the steady-state being a limiting case of the transient
solution) is summarized in Appendix 1. This analysis also includes the inherent
2D lateral heat transfer that is required for heat to flow from the interior of the fin
toward the surface. Appendix 2 develops the governing differential equation that
could be the starting point for a finite difference numerical method for the more
general case with a non-constant-area fin. This method is not formally developed
here, however.
The approach taken in the main body of the chapter is to develop a finite element
approach. First, the fin is considered as a single lumped element, a 1-node model.
This approach yields a simple closed-form solution that is surprisingly versatile and
captures all the key functional dependencies of the exact solution. Next, a multi-
element approach (“few node”) is developed considering the fin broken into three
equal elements. This method is easily extended to two or three dimensions. Finally,
a detailed methodology of the 1-node model is applied to the case of the rim of a
mug of coffee.
By specifying k and especially h and implying that the fluid temperature is not
affected by the fin (outside a thermal boundary layer), the accuracy of this model to
a “real life” fin will always be suspect. The main goal here is to compare the
accuracy of the numerical methods on a problem statement that is well posed so a
comparison with an exact solution is possible. The main advantage of the numerical
method will be in addressing problems that do NOT have an exact solution.
7.2 1-Node Fin Analysis 243
The heat transfer rate from a perfect fin, in which the temperature of the fin equals
the base temperature everywhere, is governed by Newton’s Law of Cooling:
P is the perimeter of the fin, PL is the area of the sides, and A is the area of the
exposed end (and is the base area projected a distance L from the wall). Note that a
constant-area fin can be any shape (area and perimeter) and is not restricted to a
rectangular geometry.
In a fin, heat flows out the sides and out the end. In most cases, the heat out the sides
is dominant and inclusion of the end complicates the mathematics. Therefore, it is
common to define a corrected length in which the heat out the end is accounted for
in the term PL, as suggested in Fig. 7.3. The added length adds the same area as the
end. That is, PΔL ¼ A, and the corrected length is Lc ¼ L + ΔL ¼ L + A/P. Therefore,
the heat transfer rate from a perfect fin with a corrected length is
qperfect ¼ hðPLc ÞðT 0 T 1 Þ.
Two 1-node models will be developed; one for fins, and one for handles. The
concepts of “thermally short” for fins and “thermally long” for handles will
naturally emerge.
244 7 Heat Transfer Fins (and Handles)
Fig. 7.3 Schematic of corrected length. The top fin has heat transfer out the end. The bottom fin
has an added length (ΔL) that adds surface area to the sides and has an insulated (adiabatic) end.
It’s not that insulation is placed on the end; it is that heat out the end of the longer fin is neglected
T∞
qfin Rh
T0
Tfin
Rk
Cfin
qfin (L/2) 1
T0 Tfin T∞
kA hPL
Cfin
Fig. 7.4 Schematic and thermal resistance network of a thermally short fin represented by a single
node. This model is called the “thermally short” fin model, for reasons which will become
apparent. The top network is expressed in general terms of conductive and convective resistances.
The bottom network is defined for a constant-area fin
The resistance network of Fig. 7.4 considers the fin as a single element, represented
by a node. This simple network captures the fundamental heat transfer process
associated with fins. Heat (shown as a current source) must flow from the base (at a
temperature T0) into the fin by conduction and from the fin to the fluid by
convection (and radiation in parallel). Alternatively, a battery could be used to
maintain a fixed To, as is conventionally presented. However, since the heat transfer
rate into the fin is the key objective of the analysis, a current source that supplies
that heat is more appropriate. Also, fins are often called “heat sinks” and a current
source fits that language better than a battery.
7.2 1-Node Fin Analysis 245
The average temperature of the fin is represented by Tfin. In this model, the
distance used in the conductive resistance is the half length (the distance between
the two nodes), while the surface area of the convection is based on the full length
(times the perimeter P). To be complete, the corrected length could be used in the
convective resistance (but conceptually, not in the conduction), but is excluded here
to keep the final result cleaner. A thermal capacitance is shown, but at steady-state,
the net heat flow rate into the capacitor is zero. A good review exercise is to analyze
a transient fin using a 1-node lumped transient. For a fin undergoing a transient
heating or cooling (an important practical case when there is a cycling on and off of
some device, for example), a closed-form transient solution using the previous
1-node methods works fine. The objective here is to introduce steady-state analysis
techniques, however.
At steady-state, the rate of heat transfer is determined in one step, namely:
T0 T1
qss ¼
Rk þ R h
If a given application is posed with a specified base temperature (the conventional
approach), then this form can be used to determine the heat transfer rate. If a given
problem is posed with a specified heat transfer rate (for example, to “dissipate” heat
from a computer chip), then this equation can be rearranged to solve for the required
operating temperature of the base:
T 0 ¼ T 1 þ ðRk þ Rh Þqss
A perfect fin will have no conductive resistance, and therefore the fin efficiency can
be expressed as:
T 0 T 1
qss R þR Rh 1
η¼ ¼ T 0kT 1h ¼ ¼R
qperfect Rh
Rk þ R h k = Rh þ 1
The ratio of the conductive and convective resistances is shown to be the key to the
thermal parameter of a fin. The average fin temperature can be expressed using a
voltage divider analysis:
T Fin T 1 Rh
¼ ¼η
T0 T1 Rh þ Rk
For fins with high efficiency, the fin temperature is close to the wall temperature.
For fins with low efficiency, the fin temperature is close to ambient.
The thermal resistances can be estimated for a wide variety of complicated
shapes, generally by placing the node at the centroid of the fin. For the case of
the constant-area fin defined by a base area A, and base perimeter P:
For L^ 1, T fin ¼ T 0
that is, if the actual length of the fin (L) is much less than the thermal length of the
fin (L*), then the fin temperature equals that of the base. Such a fin can be called a
“thermally short” fin, and will behave well as a fin, but lousy as a handle (you’ll
burn your hand if you grab the end). Conversely:
For L^ 1, T fin ¼ T 1
That is, if the actual length is much longer than the thermal length, the fin will be at
the ambient fluid temperature. Such a “thermally long” fin will be a lousy fin, but an
excellent handle. An alternative 1-node model will be developed for thermally long
fins shortly.
That is, the fin temperature is the average of the base and ambient temperature. In a
revised model tailored to thermally long fins, this result is used to determine the
distance over which the temperature actually changes.
The fin efficiency is:
qss hPLðT 0 T 1 Þ= L^ 2 þ 1 1
η¼ ¼ ¼ 2
qperfect hPLðT 0 T 1 Þ ^
L þ1
The fin efficiency equals 1 for thermally short fins and decreases monotonically
with fin length.
7.2 1-Node Fin Analysis 247
The fin model just developed can be applied to a fin of any length. However, if the
fin is long compared to its thermal length (L > L*), then the area near the end is not
thermally involved, and defining the convective resistance based on the total
surface area is problematic, conceptually. An alternative thermal resistance
model, shown in Fig. 7.5, recognizes that there is a region adjacent to the base
whose average temperature is known to be halfway between the base and ambient
temperature. The size of that region is not known a priori, however, and is to be
determined.
In this model, it is recognized that the actual temperature at the end of the fin is
closer to the fluid temperature than the base temperature. Therefore the fin is broken
into two segments. The segment adjacent to the wall (on the left) is fixed at a
temperature midway between the wall and fluid temperatures. The boundary
between this segment and the rest of the fin is considered to be adiabatic.
That is, heat flows into the fin from the base, and out to the fluid through
the sides of the first segment, but not further out along the fin. The distance from
the wall to the first node is left unknown, and expressed as a fraction, f, of the
T∞
Rh
T0
Tave
qfin Rk
Fig. 7.5 Schematic and fL
thermal resistance network
for a thermally long fin at T0+T∞
(fL/2) 1
steady-state. The factor “f” is qfin T0 T∞
a fraction of the total length, kA 2 hP(fL)
whose value is solved for
248 7 Heat Transfer Fins (and Handles)
total length. The temperature of the fin will be midway between the wall and the
fluid when the convective and conduction resistances are equal. That is:
fL 1
¼
2kA hPfL
Solving for “f”:
rffiffiffiffiffiffiffiffi
1 2kA L 1
f ¼ ¼ ¼
L hP L L^
The heat transfer rate, recognizing the two resistances are equal, is:
pffiffiffiffiffiffiffiffiffiffiffi
T0 T1 T0 T1 hPkA
qss ¼ ¼ pffiffiffiffiffiffi ¼ pffiffiffi ðT 0 T 1 Þ
2 2 hP 2
hPfL pffiffiffiffiffiffiffiffi
hP 2kA
The exact solution for a long fin has exactly the same functional dependency, but
without the factor 21/2 in the denominator. It would be relatively easy to “adjust” the
1-node model to make the agreement exact.
The 1-node model captures the right physics, and the characteristic length L* is
the same as that in the exact solution. Furthermore, if the basic logic is understood,
it is easy to solve for fins with non-constant-area or other complicated geometry.
Notice that the heat transfer rate is independent of the actual fin length. Adding
length to a thermally long fin will merely add material that is already close to
ambient. That’s why a thermally long fin is a good handle. The fin efficiency is:
pffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi rffiffiffiffiffiffiffiffi
hPkA=2ðT 0 T 1 Þ 1 2kA 1
η¼ ¼ ¼
hPLðT 0 T 1 Þ 2L hP 2L^
Both thermally short and thermally long models yield a fin efficiency of 0.5 when
the dimensionless fin length equals unity, so the two models smoothly transition
with length.
The exact solution (Appendix 1) for a constant-area fin, with a corrected
length, is:
pffiffiffi
tanh L^ 2 tanhðmLÞ
ηExact ¼ pffiffiffi ¼
L^ 2 mL
where the factor “m” found in traditional heat transfer literature has been
introduced and is the inverse of L* (with a factor of 21/2).
The efficiency for both the long and short fin model results are plotted versus
dimensionless length and compared to the exact solution in Fig. 7.6. The functional
dependency (shape of the curve) is basically right, although the predicted heat
transfer rates are somewhat less than the exact result (lower by 21/2 to be precise).
7.2 1-Node Fin Analysis 249
1.0
0.9
0.8
0.7
exact
0.6
Fin Efficiency
0.5
0.4
0.2
0.1
Short Fin Model
0.0
0 1 2 3 4 5
L/L*
Fig. 7.6 Fin efficiency as a function of dimensionless fin length for the two 1-node models
compared to the exact solution
Of most importance, the emergence and meaning of “m” is apparent in the simple
1-node model. A sound understanding of this parameter is all that is really needed
for fin design. It is tempting to use this feedback to alter the model to give better
quantitative agreement. However, the definition of Rk and Rh used here seems the
most conceptually correct.
Figure 7.7 shows a spreadsheet programmed to solve for the 1-node rectangular
fin. The numerical results are those of the problem statement given at the start of
this section. An “if-then-else” statement is used for the heat transfer rate and fin
efficiency to select the appropriate model (thermally short or thermally long). The
user can change any of the seven input parameters, and an approximate solution for
any rectangular fin follows.
The basic flow path of heat in a fin is by conduction from the base of the fin to the
interior of the fin, and lateral convection to the environment. However, a thick fin is
defined as one in which the lateral conduction from the interior to the convective
surface is important. In this case, a series resistance can be added to the convective
fin resistance. That is, for a rectangular fin:
250 7 Heat Transfer Fins (and Handles)
1 ðt=4Þ 1 1 ht=4 1
Rh ¼ þ ¼ þ1 ¼ ð B þ 1Þ
2 kwL hwL 2Lw k 2Lw
A lateral Biot number (B ¼ ht/4/k) has been defined and shown to give a correction
to the convective resistance. A similar procedure can be conducted for alternative
shapes. Note that the lateral conduction distance of t/4 has been used. Conceptually,
the centerline of the fin is an insulated surface, by symmetry, and the node is placed
at the centroid of one half of the fin. The factor ½ reflects that there are two surfaces.
When a fan or some other means of forcing a fluid flow across a fin, the orientation
of the fin is not generally important. However, when there is no imposed flow
(natural convection), the performance of a fin can be greatly affected by its
orientation. For example, for a heat sink with many rectangular fins attached to a
base plate, there is only one orientation that will work well without a forced
convection, namely, the one with the base plate vertical and the fins oriented
vertically, as shown in Fig. 7.8. For all the other orientations, the flow will not
effectively be generated for the interior fins (Fig. 7.9).
7.3 Half a Mug of Coffee 251
Fig. 7.9 Ineffective orientations of heat sinks with natural convection. Vertically induced flows
are blocked for inner fins
Here’s another coffee story twist. My mom not only likes her coffee as hot as you
can get it, she usually says “just half a cup,” or “just an inch.” This section considers
the effect of coffee volume on the cooling time with a 1-node lumped transient
analysis, but with a fin analysis applied to that portion of the mug wall that is above
the coffee level.
The spreadsheet used for the 1-node lumped capacity model from Chap. 4 gives
a first approximation by simply changing the input coffee volume. However, the
model for the side channel was developed with the tacit understanding that the
surface area exposed on the inside of the mug was small compared to the total
exposed surface area. Therefore, a more detailed resistance model is developed here
for the 1-node mug of coffee in which the exposed rim is treated like a heat
transfer fin.
The main point of this chapter has already been made. Therefore, the next
section, and the detailed appendices, provides detailed numerical and analytical
applications, but those can be skipped if that level of detail is not of interest. The
final results are worth reviewing, however, if all the details are not of interest.
252 7 Heat Transfer Fins (and Handles)
L
H H0
V
coffee
mug
The computer programs written to solve the lumped capacity model can handle this
scenario by merely changing a single input parameter, the volume of coffee. The
thermal resistance between the system boundary (the mug outer surface plus the
free surface of the coffee) and ambient air (Rs1) is defined, using a heat transfer
coefficient (h) applied to the entire surface, as:
1
R¼
hAsurface
The capacitance is the sum of the coffee and mug. Table 7.1 compares the full, half,
and quarter mug cases for the pure lumped model, in which an effective heat
transfer coefficient has ¼ 15 W/m2/K is applied to the entire exposed surface area.
The exposed area increases (and thermal resistance decreases) as the volume of
coffee is reduced from a full cup to a half to a quarter due to the inner surface of the
rim. The capacitance (mug plus coffee) decreases. Therefore, the time constant is
reduced due to both a smaller thermal mass and an enhanced surface heat transfer.
The initial temperature (after the coffee and mug come to thermal equilibrium)
decreases as well due to a higher percentage of capacitance being attributed to the
initially cold mug. In fact, for a quarter mug, the coffee temperature after pouring is
below 70 C as soon as the mug and coffee thermally equilibrate.
The pure lumped model assumes that the entire surface of the mug is at the bulk
temperature of the coffee. Is that a good model? For the full cup, it seems a
reasonable first approximation, since the external resistance was shown to dominate
7.3 Half a Mug of Coffee 253
Table 7.1 Effect of coffee volume on cooling time: pure lumped capacity analysis with
h ¼ 15 W/m2/K applied to entire exposed surface
Quarter
Quantity Symbol Unit Full mug Half a mug mug
Coffee volume V L 0.500 0.250 0.125
Total exposed surface area Asurface cm2 452.2 573.3 633.9
Resistance R C/W 1.47 1.16 1.05
Capacitance C J/ C 2,392 1,342 817
Time constant τ ¼ RC min 58.6 25.9 14.3
Initial temperature Τ0 C 83.3 76.6 66.6
Time to cool to 70 C ttoo hot min 14.6 3.4 NA
Time to cool from 70 C topportunity min 32.5 14.4 6.85
(or initial temperature) to 50 C
the side channel. Furthermore, probing a hot mug of coffee with your fingertips
confirms it to be uniformly hot. This situation would not exist for a Styrofoam mug,
in which case the conductive resistance across the wall could not be considered a
secondary effect. But for half a mug, the very top rim feels a little cooler than the
side. For a quarter cup, the top of the rim feels like it might not even be warm. So
something very different is happening in the mug above the level of the coffee
compared to what is below it. Heat flows directly across the mug wall where it is
exposed to coffee. Above that, heat must be flowing upward into the portion of the
rim exposed to air, and then transferring heat to the air on both sides. The rim is
acting like a fin.
For the purposes of the following series of analyses, the mug is divided into two
parts. The “rim” of the mug is defined to be that portion of the mug above the level
of coffee. The “mug” is what is left below. The heat transfer physics that takes place
in the rim portion is very different than the conduction across the mug portion. Heat
is transferred to the air by the rim, but in order to do so, heat must first conduct into
the rim, parallel to the wall of the rim. It is intuitive that there is a vertical
temperature gradient in the rim.
The lumped capacity model developed in Chap. 4 accounts for the rim effect in an
approximate way. In that model, the surface area in Ras (between the mug outer
surface and air) includes the inner surface exposed to air. Also, the conductive
resistance between the inner mug wall and outer wall (a portion of which includes
the inner wall above the level of the coffee) uses the geometric average of these two
areas. Conceptually, this model is reasonable when the rim effects are small, that is,
when the mug is nearly full.
Figure 7.11 shows a modified 1-node RC network designed for partially full mugs.
The top and bottom channels for heat flow are the same as before. The side channel,
254 7 Heat Transfer Fins (and Handles)
k, rim
T cm ma
T∞
mug
Ceff
bottom
however, branches into two parallel channels. Heat enters the mug wall along the
submerged surface and is split into a channel directly across the mug wall and a
channel that flows vertically through the mug itself into the rim, and from the rim to
ambient. The rim, while not necessarily designed this way, acts like a heat transfer fin.
The effective capacitance of the system is modified to account for the fact that
the rim is not fully involved. The total capacitance in the model is the sum of the
coffee capacitance, the mug capacitance below the level
of the coffee,
and a
fraction, f, of the capacitance of the rim: Ceff ¼ Ccoffee þ Cmug Crim þ ðf Crim Þ
The value of “f” is determined from a subsequent analysis of the rim branch,
where two different models are developed, depending on the thermal length of
the rim.
The equivalent resistance of the entire system is given by a parallel network with
three branches:
1
R¼ 1
Rtop þ Rside þ Rbottom
1 1
1
Rside ¼ Rcm þ 1
Rma þ Rk, rkm þR
1
h, rim
The resistance between the coffee and the non-rim portion of the mug consists of a
convective resistance between the coffee and the mug inner wall in series with a
conductive resistance between the mug inner surface and center of the wall of the mug:
1 ðw=2Þ
Rcm ¼ þ
hcoffee πDðH 0 LÞ kmug π ðD þ w=2ÞðH 0 LÞ
7.3 Half a Mug of Coffee 255
In this expression, the height of the area is taken to be the outside mug height
(H0) minus the rim height (L), which seems “wrong” but is used to account for edge
effects on the floor. It is instructive to express this resistance and those to follow in
terms of the convective resistance and a factor that has the ratio of conductive to
convective resistance, a form of Biot number:
1 hcoffee ðw=2ÞD
Rcm ¼ 1þ
hcoffee πDðH 0 LÞ kmug ðD þ w=2Þ
Defining a Biot number to account for the inner portion, Bcoffee ¼ hcoffee(w/2)/kmug:
1 Bcoffee
Rcm ¼ 1þ
hcoffee πDðH 0 LÞ ð1 þ w=2DÞ
The geometric factor in the denominator of the Biot number arises from the
different area associated with the convective resistance and the conductive resis-
tance. Defining a modified Biot number (B0 ) that incorporates the geometric factor:
0 Bcoffee
Bcoffee ¼
ð1 þ w=2DÞ
Similarly, the resistance between the non-rim portion of the mug and ambient
consists of a conductive resistance between the mug wall center and the outer
surface in series with a convective/radiative resistance between the outer surface
and ambient:
ðw=2Þ 1
Rma ¼ þ
kmug π ðD þ 3w=2ÞðH 0 LÞ hma π ðD þ 2wÞðH0 LÞ
In terms of the Biot number for the outer portion, Bair ¼ hair(w/2)/kmug:
1 Bair ð1 þ 2w=DÞ
Rma ¼ 1þ
hair π ðD þ 2wÞðH 0 LÞ ð1 þ 3 w=2D Þ
0 Bair ð1 þ 2w=DÞ
Bair ¼
ð1 þ 3w=2DÞ
256 7 Heat Transfer Fins (and Handles)
Since the mug and rim capacitances have been lumped into the coffee, the initial
mug heating process cannot be observed in this model. In effect, the mug and the
rim are both considered to be in a quasi-steady state equilibrium. They are changing
with time, but not independently from the coffee temperature. The emphasis in this
model is on estimating the effective thermal resistances associated with the rim,
which involves the following complex web of individual conductive and convective
resistances in series and parallel channels.
Fig. 7.12 Schematic showing the use of a corrected length to account for heat transfer from the
top surface of the rim by attributing it to the sides
7.3 Half a Mug of Coffee 257
1
Rh, rim ¼ 1
RInnerSurface þ ROuterSurface þ RTopSurface
1 1
There are several subtle differences between the inner and outer surfaces:
• The convective coefficient can be different due to the different type of natural
convection taking place.
• The air temperature inside the mug is warm (and humid), and not at ambient
temperature as implied by the resistance network, in which all the rim surface
effects are combined into a single resistance.
• The radiative coefficient can be different since the inner wall “sees” a hot coffee
surface looking down, the mug inner wall looking across and ambient temperature
looking up.
In this model, all of these effects could be accounted for, however, by suitable
choice of the inner convective/radiative coefficient (and/or a modified resistance
network).
For thin walls (2w D), the analysis yields a simpler result from which the
controlling physics is clearer:
Area Added Area Added
ATop ¼ þ
to Inner Wall to Outer Wall
w
ΔLThinWall ¼
2
It is much easier to see the controlling physics in this thin wall limit than for the
thick wall.
The thin-wall approximation and equal convection coefficients (hma) on the
inside and outside surfaces will be used going forward. Lateral conduction effects
could be included, giving rise to a form of Biot number as a correction factor to the
convective resistance term.
The convective resistance for a thin-walled rim is given by:
1 1
Rh, rim ¼ ¼
hma ARimSurface hma 2πDLc
The “2” arises in the denominator because there are two surfaces, inner and outer.
The determination of whether a given rim has thermally short or long behavior can
be made by comparing the magnitude of the conductive thermal resistances
between the base of the rim and the bulk of the rim (Rk,rim) with the convective/
radiative resistance between the surface of the rim and the air (Rh,rim). For thermally
short fins, the conductive resistance is less than the convective, and the average
temperature of the rim is closer to the mug than to ambient. The thermal length is
defined by equating the convective and conductive resistances:
ðL =2Þ 1
¼
kmug πDw hma 2πDL
L ¼ 0:017 m ¼ 1:7 cm
If the actual length of the rim is shorter than the thermal length, then the rim is
thermally short, otherwise, it is thermally long. The appropriate thermal resistances
to use are summarized in the following table:
Rim resistance Thermally short rim: L < L* Thermally long rim: L > L*
Rk,rim ðL=2Þ pffiffiffiffiffiffiffiffiffiffiffiffiffi
1 ffi
kmug πDw 2πD kmug whma
Rh,rim 1
hma 2πDLc
pffiffiffiffiffiffiffiffiffiffiffiffiffi
1 ffi
2πD kmug whma
T rim T 1 1
f short ¼ ¼
T mug T 1 R k , rim
þ1
Rh, rim
For thermally long fins, the capacitance fraction “f” is defined by the ratio of half
the thermal length divided by the actual length:
260 7 Heat Transfer Fins (and Handles)
L
f long ¼
2L
In summary, the method outlined above for the “1-node Fin” is a versatile technique
that can be used to approximate heat transfer rates and temperatures from any
so-called extended surface. The mathematics is algebra based, and often yields
simple closed-form relationships between geometric properties and thermal
properties (k and h). The tricky part is in identifying resistances, and relating
them to system parameters. This general method can be useful as a design tool to
help assess performance of engineered heat transfer devices.
The coffee/mug problem is revisited as a 1-node transient solution but with the rim
treated as a fin, using the resistance network of Fig. 7.11. In coding this problem, the
thin-wall approximations are used, as is justified in this case (hw/k ~ 0.05 1). The
thin-wall approximations yield simple closed-form expressions that more clearly
highlight the underlying physics in the model. A main spreadsheet was used to
perform the calculations, and a separate spreadsheet was used to produce results for
the full range of coffee volume. Table 7.2 lists the input parameters used. The
coffee volume was changed to generate a table of results. Table 7.3 lists all derived
quantities, including individual resistances that make up the three thermal channels
(not all of which are shown explicitly in Fig. 7.11), the three channel equivalent
resistances, and the final results for effective capacitance, equivalent resistance, and
the time constant. Note that there is an “if-then-else” statement for the fin resistance
that uses either the short fin or long fin model as needed. The long fin model is used
for this set of input parameter values because the actual rim length (L ¼ 6.06 cm) is
longer than the thermal length of the rim (L* ¼ 1.7 cm)
The behavior of the rim as a fin is demonstrated in Fig. 7.13 which shows the
thermal resistance of the fin (the sum of the conductive and convective resistances in
series) and the fin efficiency as a function of coffee volume. When the mug is nearly
full, there is a high thermal resistance due to the low exposed surface area (the top edge
is always present, even when filled to capacity). As the coffee volume is reduced, the
thermal resistance drops rapidly as more surface area is exposed, and the conduction
resistance into the rim is lower than the convective resistance (the short fin model).
Below approximately 0.45 L volume, the rim resistance remains constant because the
conductive resistance exceeds the convective, and the long fin model applies. The fin
efficiency drops continuously as coffee volume is reduced. The efficiency is used to
calculate the effective capacitance of the rim, considered next.
Figure 7.14 shows the thermal capacitance of the coffee, the mug, and the
calculated initial temperature of the coffee/mug combination after the mug heating
phase (during which time “thermal mixing” of the mug and coffee occur). The
coffee capacitance is proportional to coffee volume, while the effective mug
capacitance depends on the portion of the rim that is involved as a fin. This effective
7.3 Half a Mug of Coffee 261
Table 7.2 Input parameters used for partially filled mug 1-node analysis
Input quantities
D 0.08255 m Mug inner diameter
H 0.098 m Mug inner height
H0 0.106 m Mug outer height
V 2.00E04 m3 Coffee volume
w 0.003975 m Mug thickness
mmug 0.335 kg Mug mass
kmug 1 W/m/K Mug thermal conductivity
rhomug 1,700 kg/m3 Mug density
cmug 800 J/kg/K Coffee density
rhocoffee 1,000 kg/m3 Mug-specific heat
ccoffee 4,200 J/kg/K Coffee-specific heat
hair/outside 13.9 W/m2/K Outside convection coefficient
hair/top 20 W/m2/K Convection coefficient between free surface and
ambient
hcoffee/mug 400 W/m2/K Convection coefficient between coffee and mug
hcoffee/surface 400 W/m2/K Convection coefficient between coffee and free
surface
hfloor 10 W/m2/K Effective coefficient of table
Tcoffee, init 95 C Initial coffee temperature
Tmug,initial 23 C Initial mug temperature
Tambient 23 C Ambient temperature
mug capacity is simply the total capacitance of the rim multiplied by the fin
efficiency, plus the capacitance of the mug below the coffee level.
The initial coffee/mug temperature after the mug heating phase remains high as
the coffee volume is decreased and decreases markedly below approximately 0.2 L
as the effective capacitance of the mug becomes comparable to that of the coffee.
The thermal resistances of the three main channels are shown in Fig. 7.15. The
top and bottom resistances are independent of the coffee volume because the top
and bottom surface areas do not change. On the other hand, the side channel
equivalent resistance decreases sharply with coffee volume, the primary cause of
which is the increase in surface area across the sides. The parallel channel of heat
into the rim reduces the equivalent side resistance somewhat, but since the rim
resistance is always greater than approximately 16 C/W (Fig. 7.13), the rim heat
transfer does not have a dominant effect. Overall, the net equivalent resistance has a
mild dependency on coffee volume.
Finally, the response time of the partially filled mug with the rim treated as a heat
transfer fin, the time needed for the coffee to cool to drinkable temperature (70 C)
and the time to cool to a tepid temperature (50 C) are shown in Fig. 7.16.
262 7 Heat Transfer Fins (and Handles)
Table 7.3 Derived quantities and final results for partially filled mug 1-node model
Derived quantities
H-L 0.0374 m Depth of coffee
L 0.0606 m Rim length
Crim 89.1 J/ C Total capacitance of rim
Crim,effective 6.4 Effective capacitance of rim
Cmug 178.9 J/ C Capacitance of mug (below rim)
Ccoffee 840 J/ C Capacitance of coffee
Atop,bottom 0.0054 m2 Top and bottom surface area
Aoutside 0.0106 m2 Outside surface area below coffee level
Amiddleside 0.0102 m2 Average surface area below coffee level
Ainside 0.0097 m2 Inside surface area below coffee level
Tinitial 82.0 C Initial temperature (after mug heating)
rim conduction area 0.0011 m2 Base area of rim (as fin)
rim surface area 0.0340 m2 Convection area of rim (as fin)
L* 0.0169 m Fin thermal length
fin efficiency 0.0722 Fin efficiency
Individual resistances
Rtop,innerconv 0.47 C/W Between coffee and free surface
Rtop,outerconv 9.34 C/W Between free surface and ambient
Rbottom,innerconv 0.47 C/W Between coffee and bottom surface
Rbottom, wall 0.74 C/W Across bottom wall
Rbottom,floor 18.68 C/W Between bottom and table
Rcoffee, innersurface 0.26 C/W Between coffee and inner side surface
Rsidewall 0.39 C/W Across side wall (below coffee level)
Rside,outerconv 6.77 C/W Between ambient and outer side wall
(below coffee)
Rcm 0.45 C/W Coffee to mid plane of side wall
Rma 6.97 C/W Mid plane of side wall to ambient
Rk,rim SHORT 28.06 C/W Conduction into rim
Rh,rim SHORT 2.11 C/W Convection from rim to ambient
Rh,rim ¼ Rk,rim_LONG 8.20 C/W Long model resistances
Rfin 16.40 C/W Long fin model resistance
Channel resistances
Rtop 9.81 C/W Equivalent top channel resistance
Rbottom 19.89 C/W Equivalent bottom channel resistance
Rside 5.34 C/W Equivalent side channel resistance
Results
Ceff 1,025.3 J/ C Effective total capacitance
Requiv 2.95 C/W Effective resistance
RC 3,021.5 s Time constant
RC 50.4 min Time constant
7.3 Half a Mug of Coffee 263
70 1
Fig. 7.13 Thermal resistance of the rim (acting as a fin) and the efficiency of the rim as a function
of coffee volume
3000 100
90
2500
80
Initial Temperature
Total Capacitance (J/oC)
Fig. 7.14 Thermal capacitance of coffee and mug and initial temperature (after mug heating
phase) as a function of coffee volume. 0.525 L constitutes a mug filled to capacity
The response and therefore cooling times increase with coffee volume. The
increased capacitance has a stronger effect than the decrease in thermal resistance,
since the capacitance increases with the volume, while the thermal resistance
decreases with the surface area.
264 7 Heat Transfer Fins (and Handles)
25
15
Top Channel
10
5 Side Channel
Equivalent Resistance
0
0 0.1 0.2 0.3 0.4 0.5 0.6
Coffee Volume (liters)
Fig. 7.15 Equivalent resistance of the three main thermal channels. The side channel includes the
rim as a fin in series with the channel across the wall
90
80
70 )
iv
C equ
e (R
60 Tim
ponse
Time (min)
50 Res
°C
50
to
40
C ool
e to
30 Tim
20
°C
o 70
10 to C ool t
Time
0
0 0.1 0.2 0.3 0.4 0.5 0.6
Coffee Volume (liters)
Fig. 7.16 Thermal response time for 1-node partially filled mug, and time to cool to drinking and
tepid temperatures
7.4 3-Node Fin Analysis 265
L/3
Size of
L/3 L/3
Nodal
qfin
T0 Elements
T1 T2 T3
Distance
between
L/6 L/3 L/3 Nodes
Fig. 7.17 Grid for 3-node
network using the “define qfin R1∞ R2∞ R3∞ T∞
volumes, then place nodes” T0
1 2 3
method (top) and resistance
network (bottom) R01 R12 R23
Distance
L/3 L/3 L/3
Between
Nodes
0 1 2 3
Size of
Fig. 7.18 3-Node grid using
Nodal
the “place nodes, then define L/6 L/3 L/3 L/6
volumes” method Elements
266 7 Heat Transfer Fins (and Handles)
(as is done here), these three equations constitute a closed set of linear algebraic
equations that can be solved using a variety of methods (i.e., linear algebra).
However, the objective here is to develop a numerical approach to solving
steady-state problems, so this approach is not developed. Rather, the three nodal
equations will be written directly into a form suitable for the Gauss–Seidel iteration
method, a Method of Successive Substitution method, described in Appendix 3.
In general, as derived in Chap. 1, for a node “i” in thermal contact with neighbors
“j”, a nodal balance rearranged for node “i” in terms of its neighbors (some of which
are also unknown) is:
000 X T ðj k, kþ1Þ
Q_ i þ
Rij
ðkþ1Þ j
Ti ¼ X 1
j
Rij
Input
Parameters
"k" T1 T2 T3
For this 3-node problem, the nodal equations will be implemented in the order
1, 2, 3. For the problem at hand, there are no heat sources. The base of the fin (fixed
temperature T0) receives a heat source, so a nodal balance there will yield the
required value of the heat source (qfin) once T1 is solved for. The equation for node
1 is:
ðk Þ
T
ðkþ1Þ
T0
R01 þ R212 þ RT11
1
T1 ¼ 1
R01 þ R112 þ R11
1
Notice that the superscripts on the right hand side of the first equation used are all
“k”, representing a “guess” for that temperature. There is only one of them in this
case, but a more complicated network would have more. Nodal equation 2 is:
ðkþ1Þ ðk Þ
T1 T
ðkþ1Þ R12 þ R323 þ RT21
1
T2 ¼ 1
R12 þ R123 þ R21
1
Here, an improved guess (k + 1) for T1 is used in the recursion relation for T2 since it
is available. Nodal equation 3 is:
ðkþ1Þ
T2
ðkþ1Þ R23 þ RT31
1
T3 ¼ 1
R23 þ R31
1
L=6 L=3
R01 ¼ and R12 ¼ R23 ¼
kA kA
Notice that the distance from the wall to node 1 is half that between node 1 and 2, or
between 2 and 3. The convective resistances are:
x11 1 x31 1
R11 ¼ R21 ¼ þ and R31 ¼ þ
kA11 hPðL=3Þ kA31 h½PðL=3Þ þ A
The surface area associated with node 3 contains the sides, and the end of the fin.
The first term represents the lateral conduction across the thickness of the fin, and is
neglected here, but it could be easily included, approximated in a similar manner to
the conduction across a cylinder or sphere in the 1-node transient analysis.
268 7 Heat Transfer Fins (and Handles)
The Gauss–Seidel iteration table contains a first guess (set to be equal to the fluid
temperature, but anything could be placed here), and the second row contains the
recursion formulas. Ten iterations are shown, and then the 99th and 100th iterations
are shown as a check for convergence. In this case, convergence to within seven
significant figures is demonstrated. Between the 10th and 99th iteration, there are
7.4 3-Node Fin Analysis 269
100
90
80
70
Temperature (oC)
60
50
40
30
20
10
0
0 0.02 0.04 0.06 0.08 0.1
Distance from Wall (m)
Fig. 7.21 Temperature vs. distance from the wall for the exact solution (solid line) and the 3-node
model ( filled circles)
Table 7.4 Comparison of the numerical models and the exact solution
Model Heat transfer rate (W) Percent error
1-Node 79.2 27.7
3-Node 102.4 6.5
Exact 109.6 –
changes to the fourth significant figure. In a computer program, a while loop test for
convergence is usually a better practice than a “for loop,” but spreadsheets really
only allow the effect of a “for loop.” When a test for convergence is made, it is
important to test all nodes for convergence, not just one. It is common that a given
node may not change for a particular iteration, but some of its neighbors will. At the
next iteration, that given node will change, and a different one may not.
A comparison of the results of the 3-node model with the exact solution (using a
corrected length) is made in Fig. 7.21 which shows the temperature and Table 7.4,
which shows the heat transfer rate which is simply q3‐node ¼ ðT 0 T 1 Þ=R01 . The
temperature predicted by the 3-node model is somewhat below the exact solution,
but the agreement is really remarkable. The error in the heat transfer rate is 6.5 %,
considered quite a good agreement for such a coarse grid. A more general “n-node”
model would be straightforward to implement if improved accuracy were needed.
Be ever mindful, however, that the underlying uncertainty in the inherent
assumptions of the problem statement (especially the convection coefficient)
completely dwarf those made here. The comparison of the numerical model with
the “exact” model does not mean the “exact” model captures the real problem
accurately. For example, the convection coefficient is highly uncertain, and may
270 7 Heat Transfer Fins (and Handles)
vary with position. The fluid temperature might not really be uniformly ambient,
depending on the location of other fins. And so on. . .
Figure 7.2 shows an extended surface (fin) that has a base area A and perimeter
p. The shape of the surface remains constant in the x direction, perpendicular to the
base. The total length of the surface is L, and the material has a thermal conductiv-
ity k. The fin is exposed to a fluid at temperature T1 with an effective heat transfer
coefficient, h. The fin is initially at the fluid temperature, and the base temperature is
suddenly changed and maintained at a temperature T0.
Model Development
A detailed derivation of the governing PDE for this case is developed for a general
transient fin case, including lateral conduction. A cross-section of a differential
slice of thickness dx at an arbitrary distance x placed at the center of the element is
shown in Fig. 7.22. Heat enters the left face (at x – dx/2) by conduction, and splits
into two channels, one leaving the surface into the fluid, and the other by conduction
(at x + dx/2) into the adjacent slice.
A verbally stated energy balance applied to the slice, consistent with the
assumed directions shown by the arrows of Fig. 7.22, is:
Rate of Change of Rate of Conduction Rate of Conduction
¼
Energy Stored in slice into left face out of right face
Rate of Convection
out of sides
Fig. 7.22 Energy flows in a differential element in an extended surface. The right sketch shows
the element in a resistance network, which allows conductive resistance between the center and the
surface exposed to the fluid
Appendix 1. Constant-Area Fins: Differential Solution 271
Expressed mathematically:
∂T ∂T ∂T
ρcAdx ¼ kA kA hpdx T surface T 1
∂t ∂x xdx=2 ∂x xþdx=2
In the transient and conduction terms, the temperature, T, represents the average
temperature of the cross-section. In the convection term, the temperature is the
surface temperature.
The conduction at x + Δx (where Δx ¼ – dx/2 or + dx/2) can be related to that at
the center (x) using a Taylor expansion:
∂T ∂T ∂ ∂T
kA ¼ kA þ kA Δx þ
∂x xþΔx ∂x x ∂x ∂x x
∂T ∂T ∂ ∂T
kA kA ¼ kA dx
∂x xdx=2 ∂x xþdx=2 ∂x ∂x x
The surface temperature can be related to the average temperature using a voltage
divider branch between the center of the fin and its surface:
T T 1 T surface T 1
¼
Rk þ Rh Rh
The resistances are in the lateral direction (y and z). Solving for the surface
temperature:
Rh T T1
T surface T 1 ¼ T T1 ¼
R h þ Rk 1 þ Rk = Rh
ðA=pÞ=2
Rk ¼
kðpΔx=2Þ
The numerator, (A/p)/2, is half of the characteristic half thickness of the section,
which is the average conduction distance from the surface to the center. The area in
272 7 Heat Transfer Fins (and Handles)
the denominator is the average between the area at the center (zero) and at the
surface. The convective resistance is straightforward:
1
Rh ¼
hpΔx
The ratio is:
Rk hðA=pÞ
¼ B
Rh k
The governing partial differential equation (energy balance) is therefore:
∂T ∂ ∂T hp
ρcA ¼ kA T T1
∂t ∂x ∂x x 1 þ B
The factor “B”, a Biot number, accounts for temperature variation in the lateral
direction, an effect that is usually neglected (and justifiably so) for fins.
For a rectangular fin, with w t:
A tw t t
¼ ¼
Introducing a dimensionless temperature that has a value of zero at the base, and
approaches unity as it approaches ambient:
T T0
θ¼
T1 T0
Introducing a dimensionless time and distance with normalization constants to be
determined shortly:
t x
^t ¼ x^ ¼
τ Lt
2
ρcAðT 1 T 0 Þ ∂θ kAðT 1 T 0 Þ ∂ θ hp
¼ ðT 0 þ θ ðT 1 T 0 Þ T 1 Þ
τ ∂^t L2t ∂^
x2 1 þ B
2
ρcL2t ∂θ ∂ θ hpL2t
¼ þ ð1 θ Þ
kτ ∂^t ∂^
x 2 ð1 þ BÞkA
Appendix 1. Constant-Area Fins: Differential Solution 273
The time constant and characteristic dimension can be defined by setting the
coefficients to unity. For the convection term:
sffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi
ð1 þ BÞkA
Lt ¼
hp
ρcL2t
τ¼
k
The governing partial differential equation becomes:
2
∂θ ∂ θ
¼ θþ1
∂^t ∂^
x2
Since the governing equation is first order with respect to time, a single initial
condition must be specified, for problems that are in fact transient. For example, in
the problem statement, the fin is initially at the fluid temperature (T1), and the base
temperature is suddenly changed and maintained at T0. Therefore, the initial
condition (in dimensions) is:
T ðx; 0Þ ¼ T 1
In dimensionless variables:
θð^x ; 0Þ ¼ 1
The governing equation is second order with respect to x, and therefore two
conditions are required. One condition is that the base temperature is specified:
T ð0; tÞ ¼ T 0
In dimensionless variables:
θð0; ^t Þ ¼ 0
The second condition on x is trickier. The precise statement of it is that the rate of
heat conduction to the end (at x ¼ L) must equal the rate of convection away from
the end:
∂T
kA ¼ hA T ðL;tÞ T 1
∂x x¼L
274 7 Heat Transfer Fins (and Handles)
∂θ hLt
¼ θðL;
x x^ ¼L^
^ ^t Þ
∂^ k
Lc ¼ L þ ΔL
The area added onto the sides by the added length (the perimeter times the added
length ΔL) is the same as the end of the fin. That is:
pΔL ¼ A
A
Lc ¼ L þ
p
The boundary condition on the end of the extended fin is determined by an energy
balance at the end, in which heat conducted to the end from the left is set to the heat
convected away, which is set to zero:
∂T
kA ¼0
∂x x¼Lc
To restate the result of the model development, the governing equation and initial
and boundary conditions are:
2
∂θ ∂ θ
Governing Equation : ¼ θþ1
∂^t ∂^x2
Initial Condition : θð^x ; 0Þ ¼ 1
Boundary Condition at base : θð0; ^t Þ ¼ 0
∂θ
Boundary Condition at end : ¼0
∂^x x^ ¼Lc =Lt
The governing equation is a linear partial differential equation with three terms
(transient, conduction, convection) and no parameters (they are “buried” in the
dimensionless variables). The second boundary condition does contain a parameter
(its location, namely the dimensionless thermal length of the fin). The use of
dimensionless variables has reduced the number of parameters in the system from
seven (A, p, L, k, h, T0, T1) to one.
As is often the case in heat transfer applications, it is not so much the tempera-
ture that is sought, but the heat transfer rate. For a fin, the rate at which heat transfer
enters the base of the fin is:
∂T
qfin ¼ kA
∂x x¼0
In dimensionless variables:
kAðT 1 T 0 Þ ∂θ
qfin ¼
Lt x x¼0
∂^
The general solution can be expressed as the sum of a transient and steady-state
solutions:
The transient solution involves all three terms and requires a lot of work to develop
a complete solution that satisfies the initial and boundary conditions. The full
solution is developed here, mainly to demonstrate the basic method of solving
linear partial differential equations. The steady-state solution is much easier to
obtain, and if the problem can be effectively modeled as being at steady-state, it can
be used without bothering with the transient case.
In practice, however, the transient response of a heat fin may be important, for
example, for electronic equipment that is cycled on and off. During the initial start-
up period, the rate of heat transfer into a fin can start high, as heat is going to change
the energy stored, and gradually decay to its steady-state response and dissipate
heat to ambient. A good design might take advantage of that behavior.
Transient Solution
2
∂θtransient ∂ θtransient
¼ θtransient
∂^t ∂^x2
Note that the term “1” in the governing equation will be grouped into the steady
state solution. Using the separation of variables technique, the solution is assumed
to be expressible as two separable functions: one depending on position, and the
other on time:
In this expression, the term on the left is a function of time only, the term in the
middle is a function of position only, and it is recognized that that can only be
possible if they are both equal to at most a constant, called a separation constant,
and given the symbol λ, whose value will be determined by application of the initial
and boundary conditions. The negative sign avoids complex numbers and squaring
makes for a cleaner final solution (not obvious why at this point).
The time-dependent equation is:
dT
þ λ2 T ¼ 0
d^t
Appendix 1. Constant-Area Fins: Differential Solution 277
T ¼ c0 eλ ^t
2
d2 X
þ λ2 X ¼ 0
x2
d^
The general solution is:
X ¼ c1 sin λ^
x þ c2 cos λ^
x
The values of A, B, and λ are determined by application of the initial and boundary
conditions. First, applying the boundary condition at the base of the fin, θð0; ^t Þ ¼ 0
The only way this condition can be satisfied is if the coefficient B is set to zero. The
general solution, after application of boundary condition at the wall, has been
reduced to:
2^
θtransient ¼ Aeλ t sin λ^
x
∂^
x x^ ¼L^ ¼Lc =Lt
Where a dimensionless length (the thermal length of the fin) has been defined as:
Lc
L^ ¼
Lt
The only way this boundary condition can be met (without setting A or λ to zero,
which would make satisfying the subsequent initial condition impossible) is to set
the separation constant to specific values, namely:
cos λL^ ¼ 0
278 7 Heat Transfer Fins (and Handles)
This constraint is true for the following infinite number of discrete values of the
separation constant, namely:
π 3π 5π ð2n þ 1Þπ
λL^ ¼ , , , ..., , ...
2 2 2 2
These “quantized” values of l are called eigenvalues.
The solution can now be expressed as the sum of all possible solutions (prior to
satisfying the initial condition) for these discrete values of λ, with a different
coefficient (A) possible for each term:
π^x 3π x^
θtransient ¼ A0 eð2L^ Þ t sin þ A1 eð2L^ Þ t sin
2 3π 2 ^
π ^
þ
2L^ 2L^
ð2πþ1Þ 2 ð2n þ 1Þπ^ x
þ An eð 2L^ Þ t sin
^
þ
2L^
Expressed in terms of an infinite series:
X
1
2πþ1 ^t ð2n þ 1Þπ x^
θtransient ¼ An e 2L^ 2 sin
n¼0 2L^
Notice that the transient solution decays to zero as time goes to infinity. Last, but
not least, the initial condition must be satisfied:
θð^x ; 0Þ ¼ 1
X1
ð2n þ 1Þπ^
x
1¼ An sin
L^
n¼1
To determine the coefficients An, the final step in this tortured affair, multiply both
sides by a sin term with an integer “m” as a frequency, and integrate over the range
of x:
2 3
ZL^ X
1 ZL^
ð2m þ 1Þπ^
x 6 ð2m þ 1Þπ^
x ð2n þ 1Þπ^
x 7
sin x¼
d^ 4 An sin sin x5
d^
^
2L ^
2L ^
2L
n¼1
x^ ¼0 x^ ¼0
The integral on the right is zero (sketch two sinusoids of different frequencies, and
look at their areas) when m is not equal to n. That is, for every value of n, all but one
of the terms in the infinite series are identically zero. Therefore:
ZL^ ZL^
ð2n þ 1Þπ^
x x 2
ð2n þ 1Þπ^
sin x¼
d^ An sin d^
x
2L^ 2L^
x^ ¼0 x^ ¼0
Appendix 1. Constant-Area Fins: Differential Solution 279
ZL^ ^
ð2n þ 1Þπ^
x 2L^
x L
ð2n þ 1Þπ^
sin x¼
d^ cos
2L^ ð2n þ 1Þπ 2L^
0
x^ ¼0
2L^ ð2n þ 1Þπ 2L^
¼ cos 1 ¼
ð2n þ 1Þπ 2 ð2n þ 1Þπ
The right hand side, with the help of a trigonometric identity for sin2x ¼
(1 cos x)/2, evaluates to a single number (noting that the second term involves a
cosine integrated over a full cycle, and its integral is thus zero):
ZL^ ZL^
x 2
ð2n þ 1Þπ^ 1 2ð2n þ 1Þπ x^ An L^
An sin x ¼ An
d^ 1 cos dx ¼
2L^ 2 2L^ 2
x^ ¼0 x^ ¼0
4
An ¼
ð2n þ 1Þπ
X
1
4 ð2nþ1Þπ 2 ð2n þ 1Þπ^
x
eð 2L^ Þ t sin
^
θtransient ¼
ð2n þ 1 Þπ 2 ^
L
n¼0
¼
∂^ x x^ ¼0 n¼0
The heat transfer rate associated with the transient solution is therefore:
rffiffiffiffiffiffiffiffiffiffiffiffi
hpkA X1 ð2nþ1Þπ 2
2eð 2L^ Þ t
^
qfin, transient ¼ ðT 0 T 1 Þ
1þB n¼0
280 7 Heat Transfer Fins (and Handles)
Steady-State Solution
The steady-state solution is much easier, especially with the corrected length
boundary condition. The governing equation (a linear ordinary differential equation
with constant coefficients) and boundary conditions are:
d2 θss
θss ¼ 1
d^x2
∂θ
¼0
x ^
∂^ x^ ¼L
The homogeneous solution is that with the right hand side set to zero, and the
solution is:
θss, P ¼ K
Substitution of these expressions into the governing equation yields K ¼ 1, and the
general solution is therefore:
0 ¼ c1 þ c2 þ 1
^ ^
0 ¼ c1 eL þ c2 eL
Combining them:
^ ^
0 ¼ ðc2 þ 1ÞeL þ c2 eL
^
eL
c2 ¼
eL^ þ eL^
Appendix 1. Constant-Area Fins: Differential Solution 281
And
^ ^ ^
eL^ e L e L þ e L eL
^
c1 ¼ 1¼ ¼
eL^ þ eL^ eL^ þ eL^ eL^ þ eL^
The steady-state solution is therefore:
! !
eðL ^x Þ þ eðL ^x Þ
^ ^ ^ ^
eL e^x þ eL ex^
θss ¼ 1 ¼1
eL^ þ eL^ eL^ þ eL^
ey þ ey
coshðyÞ ¼
2
ey ey
sinhðyÞ ¼
2
sinhðyÞ ey ey
tanhðyÞ ¼ ¼
coshðyÞ ey þ ey
cosh L^ x^
θss ¼ 1
cosh L^
Returning to dimensions:
T ss T 0 cosh LcLx
¼1
t
T1 T0 cosh Lc
Lt
where the first bracketed term is the transient solution, and the second is the steady-
state solution. The heat transfer rate is:
rffiffiffiffiffiffiffiffiffiffiffiffi " X #
1
hpkA Lc ð2nþ1Þπ 2
ð 2L^ Þ ^t
qfin ¼ ðT 0 T 1 Þ tanh þ 2e
1þB Lt n¼0
hðA=pÞ
where a transverse Biot number is defined as B ¼ , the corrected length is
k ffi
sffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi
ð1 þ BÞkA
Lc ¼ L þ A=p , and the thermal length is Lt ¼ .
hp
Personal comments: I consider this really elegant mathematical solution to the
transient rim problem to be “Good Mathematics” and “Bad Engineering.” Engi-
neering is about addressing a human need. To make this value judgment about
whether the method is good or bad engineering requires me to revisit, and perhaps
modify, the problem statement, an iteration of the modeling process. If the objective
is to merely find the heat transfer rate, then the 1-node solution is really simple
mathematically, and yields the same physics as the PDE solution.
The big problem I have with the PDE solution is not that it requires a sophisti-
cated mathematical excursion. If that’s what it takes, then so be it. My problem is
that the solution ties me to some tight restrictions. The base wall temperature must
be fixed in time. The initial condition must be that the fin is entirely at ambient, etc.
The 1-node model gives all that. An extension to an n-node solution requires some
more work, but that numerical method can be applied to much more general
situations quite easily, once the technique is mastered. For example, suppose a fin
is designed to dissipate heat from a motor that turns on and off intermittently, but
has a clear maximum time it is on. A fin might be designed that takes advantage of
high initial heat rates (where heat goes in part to changing the energy stored, and the
rest transferred to the fluid).
In short, the 1-node model teaches the essential physics and yields key design
parameters. The multi-node numerical method yields more detail and is arguably
more quantitatively accurate than the 1-node model. On the other hand, there is so
much uncertainty in convection coefficient values that accuracy can be misleading.
Heat transfer modeling is indeed an art.
Ñ
X
effective heat transfer coefficient, h. The fin is initially at the fluid temperature, and
the base temperature is suddenly changed and maintained at a temperature T0.
Model Development
The governing differential equation was derived in the previous appendix by
application of the energy balance to a differential element:
∂T ∂ ∂T hp
ρcA ¼ kA T T1
∂t ∂x ∂x x 1 þ B
With an initial condition and two boundary conditions (at the base and end of the
fin). The difference between this case and the constant-area is that the area cannot
be taken out of the conduction derivative term. Assuming constant thermal conduc-
tivity, using the chain rule for the conduction term and rearranging:
∂T ∂ T
2
1 ∂A ∂T hp
¼α 2 þα T T1
∂t ∂x A ∂x ∂x ρcAð1 þ BÞ
• Many different algorithms have been “invented.” Heat transfer problems are
generally solvable using the Method of Successive Substitution. It is easy to
implement and usually works. It can easily be extended to systems of equations.
Newton’s method is another, and will be introduced for a single nonlinear
algebraic equation and outlined for systems of nonlinear equations. It is much
harder to implement with systems (with more than one unknown) and is occa-
sionally necessary in heat transfer problems.
• There is no guarantee that a given method will work, that is, find the desired
solution to the problem.
• If an iterative procedure converges, it does so to a correct solution of the system
of equations. However, that solution may make no physical sense (i.e., a
negative absolute temperature).
• If an implementation diverges, it might converge for another initial guess.
Solution of a single nonlinear algebraic equation is the natural place to start. The
methods can be extended to systems of equations (with more than one unknown).
The quadratic equation will be used to demonstrate how to implement the methods
and to compare the response on a system that has an analytical solution. In addition,
if the goal is not to solve the equation, but to study CHAOS, iterative techniques on
the quadratic equation are a great place to start.
Quadratic equation:
ax2 þ bx þ c ¼ 0
The quadratic equation is about the simplest nonlinear algebraic equation there
is. As a nonlinear equation, it has the rare distinction of having an exact solution. It
has two solutions, its two roots x1 and x2:
Appendix 3. Iterative Solutions of Nonlinear Algebraic Equations 285
pffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi pffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi
b þ b2 4ac b b2 4ac
x1 ¼ x2 ¼
2a 2a
Keep in mind that in what follows, the objective is to learn new techniques that can
be implemented to solve more difficult nonlinear equations, not to solve the
quadratic equation. . .
xkþ1 ¼ gðxk Þ
where the subscript “k” refers to the iteration number. There are an infinite number
of ways this rearrangement can be done. For example, the quadratic equation
written in its conventional form is:
ax2 þ bx þ c ¼ 0
Three equivalent forms of the quadratic equation (with subscripts showing the
iteration number) are:
1
Form 1 : xkþ1 ¼ c þ ax2k isolating the 2nd term
brffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi
1
Form 2 : xkþ1 ¼ ½c þ bxk ðisolating the 1st termÞ
a
Form 3 : xkþ1 ¼ ax2k þ ðb þ 1Þxk þ c ðadding x to both sidesÞ
1.6
1.4
1.2
1
xk+1=g(xk)
Form3
0.8 Form2
Form1
0.6
0.4
0.2
0
0 2 4 6 8 10 12 14 16 18
Iteration Number
10
6
xk+1=g(xk)
4 Form3
Form1
0
0 2 4 6 8 10 12 14 16 18
-2
Iteration Number
2.5
2.0
1.5
1.0
0.5
X
0.0
0 5 10 15 20
-0.5
-1.0
-1.5
x0 = 1.000000
-2.0
x0 = 1.000001
-2.5
Iteration Number
2.5
2.0
1.5
1.0
0.5
0.0
X
0 10 20 30 40 50
-0.5
-1.0
-1.5
-2.0 x0 = 1.000000
x0 = 1.000001
-2.5
Iteration Number
2.5
2.0
1.5
1.0
0.5
0.0
X
-1.0
-1.5
-2.0 x0 = 1.000000
x0 = 1.000001
-2.5
Iteration Number
ax2 + bx + c = 0
c= -0.2
Exact Solution
x1= 0.14792
x2= 1.35208
ax2 + bx + c = 0
c= -0.2
Exact Solution
x1= 0.123212
x2= -1.623212
f(x)
f(x0)
f(x1)
X
X2 X1 X0
Appendix 3. Iterative Solutions of Nonlinear Algebraic Equations 291
f ðx 0 Þ
x1 ¼ x0
df
dx x0
f ðx k Þ
xkþ1 ¼ xk
df
dx xk
To implement the method, an initial “guess” is made, and the recursion relation is
used in an iterative fashion.
f 1 ðT 1, T 2 , . . . , T n Þ ¼ 0
f 2 ðT 1, T 2 , . . . , T n Þ ¼ 0
f n ðT 1, T 2 , . . . , T n Þ ¼ 0
The method involves making an initial guess for all unknown temperatures, and
then making an improved guess based on how the function is changing. The initial
guess is given a superscript “k” and the improved guess the superscript “k + 1”. The
total derivative of each nodal equation consists of the contribution from each
unknown variable:
292 7 Heat Transfer Fins (and Handles)
The right hand side represents an approximation to the total change. The zero
reflects that the function evaluated at the next iteration is supposed to be zero, but
it should be closer to zero than the previous iteration. Since all the functions and
their derivatives (possibly by numerical approximation) can be evaluated at the “k”
iteration, this represents a system of linear algebraic equations that can be solved
for the temperatures at the next iteration.
Compare the steady-state performance of triangular fins with rectangular fins with
the same base thickness (t) and the same total mass of material. Assume that the
depth of the fins (not shown) are large compared to the thickness. Think about it
before analyzing it.
L
k
t
Rectangular Fin
T0 h
T¥
2L
k
t Triangular Fin
h T¥
T0
Level 1: Develop a 1-node analysis for the triangular fin (place the node at the
centroid), and develop an expression for the ratio of the heat flow from the
rectangular fin to that of the corresponding triangular fin. Is there a key dimension-
less parameter to plot against?
Level 2: Develop a few-node model for both in spreadsheets, and compare the
results with the 1-node model.
Level 3: Develop an “n” node model for both using a program code, and
compare with the 1-node model.
Workshop 7.2: Circumferential Rectangular Fin 293
tfin
Dtube
Wfin
ΔX
After the initial mug heating phase when hot coffee is poured into a ceramic mug,
the coffee and mug gradually cool together. During this time, the rate of heat
transfer from the coffee to the inner wall of the mug is approximately equal to
the rate of heat transfer from the outer wall to ambient. That near balance defines a
quasi-steady state situation for the mug itself, and is why the lumping of its capacity
with the coffee is reasonable. For problems that are steady-state in nature (or quasi-
steady state), a transient model can be developed and then run to equilibrium to
obtain the steady-state solution. However, it is possible to solve directly for the
steady-state solution, which involves somewhat different mathematics to execute.
Methods for doing so were initiated in the previous chapter on fins, and elaborated
on in this chapter. Furthermore, the mathematics involved is similar to that required
to execute a step forward using an implicit transient. The method is first developed
and applied to the mug of coffee, and then to a classic 2D problem. Extension to
3D is straightforward.
In general, heat transfer problems are transient and three dimensional. That is,
the temperature varies with time and position. Many heat transfer applications are
inherently constant in time, or are best modeled as such. The objective of this
chapter is to develop a numerical method for problems that are inherently steady-
state. The method is developed in a simple 2D (x,y) space, and the extension to 3D
is straightforward, conceptually.
In classic heat transfer texts, conduction shape factors (S) are introduced for
conduction in purely 2D geometries of homogeneous materials. The heat transfer
rate per unit depth (q/P, in W/m, where P is the depth, or the dimension into the
page) between two surfaces separated by a homogeneous material of thermal
conductivity k and with temperatures maintained at T1 and T2 can be expressed as:
q=P ¼ kSðT 1 T 2 Þ
of the 2D object. Note that the conductive thermal resistance can be expressed in
terms of the shape factor, namely,
1
Rk ¼
kS
Tables of conduction shape factors are available in classic heat transfer texts and on
the Internet. A conduction shape factor workshop is included at the end of this chapter.
The treatment of the rim as a fin with a 1-node analysis in the previous chapter
allowed for a good prediction of the overall behavior of the cooling mug of coffee.
The focus of this chapter will be on inherently 2D detail that the 1-node model
cannot reveal. Focusing on the mug wall, there is a discontinuity in the type of fluid
at the free surface of the coffee. There is hot coffee on the inside surface up to the
coffee level, and warm, humid air above that. However, the temperature cannot be
discontinuous in either a solid or fluid.
Outside of the thermal boundary layer, the temperature of the fluid adjacent to
the mug surface is different than the temperature of the mug surface temperature.
Since the convection coefficient between coffee and surface is much higher than
that between air and the surface, the temperature of the mug inner surface exposed
to coffee is close to the coffee temperature, while a big drop in temperature occurs
between the outer surface and air. To make an extreme case, in this chapter one
hypothetical scenario is analyzed in which the convection on both air and coffee
contact surfaces are so large that the surface temperature is fixed by the fluid
temperature. A discontinuity in surface temperature is imposed, even though that
would be impossible to achieve experimentally. In reality, the temperature gradient
can be very steep, but never discontinuous. Mathematically, a discontinuous surface
temperature is frequently prescribed in the literature.
The following “warm-up” exercise outlines a procedure for solving for the tempera-
ture field and heat transfer rates in a 2D steady-state conduction situation, where the
temperature is fixed along key surfaces. The application is modeled after the mug of
coffee problem. There are two important ways this model differs from the actual
experiment. First, the boundary conditions are of a fixed temperature type, not
convection/radiation. That is, the mug surfaces are fixed at the fluid temperatures.
Second, these “fluid” temperatures are fixed at values of 0 and 100 C. This method
can be used to estimate the conductive resistance between two surfaces that are NOT
maintained at fixed temperature, to be used in a 1D approximation to a 2D problem.
The general steps of the graphical method are:
The following warm-up exercise breaks these steps into a detailed procedure.
Warm-up
1. On a piece of paper, draw two vertical lines across the entire page (Fig. 8.1
shows steps 1–6). These lines represent the walls of a solid material, with a
dimension W (¼πD) into the page.
2. Draw a thicker line on the left line from somewhere in the middle to the bottom.
The surface represented by the thick line is the “coffee” and has been
maintained at 100 C for a long time. The other surfaces (both walls) have
been maintained at 0 C.
3. Near the bottom of the page, place a dot where you think the temperature would
be 50 C. Place another dot about a centimeter higher up.
4. Place a dot near the coffee surface where you think it would be 50 C. Place
another dot about a centimeter away.
5. Alternate between the two ends until the entire curve is traced out. If a dot is
placed where you wished you hadn’t, just leave it, and place other dots where
you think they should be.
6. Define the 50 C isotherm by adding more dots in between others.
7. Near the bottom of the page, place a dot where you think the temperature would
be 25 and 75 C (Fig. 8.2 shows steps 7–9). Add two more dots, about a
centimeter away.
8. Near the coffee surface, place dots at 25 and 75 C. Add two more dots, about a
centimeter away.
9. Add more dots to define the 25 and 75 C isotherms.
10. Draw a horizontal line near the bottom of the page from the hot wall to the cold
wall (Fig. 8.3 shows steps 10–12). The line just drawn is a heat flux line. As
additional heat flux lines are drawn, observe the following three rules: each line
starts at the 100 C isotherm and ends at the 0 C isotherm, each “pseudo box”
(called an element) created should be nominally square (Fig. 8.4), and each line
must be perpendicular to any isotherm it crosses.
11. Draw a heat flux line around the coffee surface, keeping each element approxi-
mately square.
12. Return to the bottom and add another heat flux line. Alternate between top and
bottom until the web is complete. It is possible that the final heat flux lane will
not have square elements.
ΔT element
qelement ¼
R
298 8 Steady-State Conduction
Fig. 8.1 Placement of 50 C isotherm. Steps 1–6 of the warm-up exercise. The two vertical lines
represent the surfaces of a solid in between. The temperature of the right face is maintained at 0 C.
The left face is maintained at 0 C on the top, and the bottom (the thicker line) is maintained at
100 C. The dots on the left sketch are best guesses as to where the temperature is 50 C.
Additional dots are added to the sketch on the right in order to define the 50 C isotherm
Fig. 8.2 Placement of 25 and 75 C isotherms. Steps 7–9 of the warm-up exercise
8.1 Graphical Method 299
Fig. 8.3 Placement of heat flux lines. Steps 10–12 of the warm-up exercise
Fig. 8.4 Demonstration of “skewed” and “squarish” mesh elements, which can take some
practice to achieve
Here ΔTelement is the temperature difference between the two isotherms (25 C in
this example, which is the overall temperature difference divided by the number of
temperature increments). Expressing the conductive resistances in terms of the
dimensions of the cell, where Δx is the average distance between the isotherms,
Δy is the average distance between the heat flow lines, and P is the depth of the wall
(into the page) so that ΔyP is the area of an isothermal surface:
ΔT element
qelement ¼
Δx
kΔyP
If the intent to keep each cell square was successfully followed, then the distance
between isotherms (Δx) is nominally the same as the distance between heat flux
lines (Δy), and they cancel each other. Therefore:
At steady-state, the rate at which heat enters an element equals the rate it leaves.
Adjacent elements along the same heat flow path (called a heat flow “lane”)
experience the same rate of heat flux. That is:
qelement ¼ qlane
The temperature drop across an element is simply related to the over-all temper-
ature drop by the number of temperature increments, Nincrements:
ΔT overall
qlane ¼ kP
N increments
Each lane acts in parallel with the others in transferring heat from the hot surface to
cold. There is nothing to distinguish one lane from another, so each lane contributes
the same rate of heat transfer. That may seem surprising. However, where isotherms
are close together (steep gradients), the heat flux lines will also be close together, so
the same rate of heat transfer occurs in a narrow lane. The total heat transfer rate is
simply the sum of all the lanes created in the drawing, or the number of lanes, Mlane,
which can be a fraction for the last lane drawn and the web closes on itself. The total
heat transfer rate is therefore:
PMlanes ðT H T C Þ
qtotal ¼ k ðT H T C Þ kSðT H T C Þ ¼
N increments RHC
N increments
RHC ¼
kPMlanes
The values for M and N will depend on the specific drawing. For the drawing of
Fig. 8.3, there are four temperature increments (N ¼ 4), and a little more than six
heat flow lanes (M ¼ 6.2, say).
Figure 8.6 shows another sketch of a similar problem. It is a side view, to scale,
but considered infinite in extent below the coffee level, and this problem will be
solved with a numerical method in the next section. The isotherms and heat flux
lines were constructed according to the procedure in the warm-up exercise. There
are four temperature increments (Nincrements) and 23 heat flow lanes generated
(Mlanes). Therefore, the heat transfer rate is:
PMlanes
qtotal ¼ k ΔT overall
N increments
The shape factor is:
PMlanes Pð23Þ
S¼ ¼ ¼ 5:75P
N increments 4
302 8 Steady-State Conduction
The heat transfer rate for the coffee mugproblem (P¼ πD, k ¼ 1.0 W/m/K, when
PMlanes
TH ¼ 70 C and TC ¼ 23 C) is: qtotal ¼ k ðT H T C Þ
N increments
W ð0:25 mÞð23Þ
qtotal ¼ 1:0 ð70 23Þ C qtotal ¼ 67:6 W
m C ð 4Þ
The method reveals a region of high activity near the coffee surface, where heat
enters the mug wall from the left (coffee side) and exits to the right (to the air just
above the coffee surface). Above a distance of a couple wall widths from the coffee
surface, the temperature is nearly ambient, and below a couple wall widths, the heat
transfer is 1D (straight isotherms and heat flow lanes). The graphical method quickly
provides an excellent feel for this problem, and it can be amazingly accurate.
The solution from the up and coming finite element solution is 69.84 W when the
mug surface temperatures are artificially set equal to the adjacent fluid temperatures.
This “graphical method” of estimating heat transfer rates in a 2D solid can be a
valuable-modeling tool in helping to understand the temperature field in a compli-
cated shape. It can often be enough to help an Engineer make a design decision. If a
more detailed analysis is considered necessary, the graphical method can help
pinpoint regions of high action (where a fine grid would help) and regions of low
action (where a coarse grid is sufficient).
The method can also be used to turn an inherently 2D problem into a 1D
approximation when two surfaces can be identified. Heat flows from one surface
to the other, without branching that gives rise to more complicated 2D mathematics.
To reiterate, a caveat on the method is that the drawing on which isotherms and
then heat flow lanes are drawn must be to scale. Try a quick analysis on another
drawing with a different spacing between the walls. If the walls are farther apart, the
elements will be bigger, making fewer lanes, increasing the thermal resistance.
The finite element method provides a more detailed analysis than the graphical
method. In it, the physical space is broken into discrete elements, each represented
by a node. Thermal resistances between nodes and boundaries are defined. Each
node has a capacitance associated with it, but can be omitted from drawings with
the understanding that there is no change in energy stored in a steady-state problem.
The elements can be any shape, with care being made to account for all thermal
resistance. Finer grids near regions of high gradients can be considered.
The method will be developed with a specific problem statement as a base case
defined to focus on the wall of the mug of coffee problem, and several scenarios will
be run to explore the response. In the following problem statement, the side wall of
the mug is treated as a rectangular prism (making a thin-wall approximation), with
one side exposed to ambient air, and the other side exposed to hot coffee at a fixed
temperature (the quasi-steady approximation) below the free surface and ambient
8.2 Numerical Method for 2D Steady-State Conduction 303
above it. The top is exposed to ambient, and the bottom is exposed to a floor with an
effective heat transfer coefficient (Ub). The height of the wall (2.2 cm) is much
shorter than the wall of the mug investigated in earlier chapters in order to focus on
the thermal response in the vicinity of the coffee surface. The treatment of the
bottom surface is included for the purpose of introducing a variety of 2D responses.
• Fixed boundaries: set the two convection coefficients to sufficiently high values
that the surface temperatures are approximately equal to the fluid temperatures.
Compare the graphical method with the numerical one for this case. Define a
“Shape Factor” and overall thermal resistance for this geometry defined by:
TH TC
qtotal ¼ kSΔT overall ¼
RHC
A finite element approach to modeling this problem with a relatively coarse grid
will be developed, and implemented in an Excel Workbook. One version contains a
MACRO that allows easier implementation of different scenarios.
304 8 Steady-State Conduction
8.2.1.1 Grid
The wall is broken up into the rectangular grid shown in Fig. 8.7. The first step is to
break the region into elements. In this case, three “columns” are chosen, three
“rows” are chosen for above the coffee level and eight “rows” below the coffee
level. These two choices define the size of the elements, Δx ¼ w/3 (¼1 mm for
the base case) and Δy ¼ L/3 (¼2 mm for the base case). The location of the
free surface coincides with the boundary between two elements. The total height
of the wall is 11*Δy (¼22 mm). Nodes represented by open circles are placed in
the center of each element. Filled circles show known fluid temperatures. The
nodal temperatures represent average temperatures in a finite region. Surface
temperatures can be determined from voltage divider calculations once the nodal
temperatures are determined.
8.2 Numerical Method for 2D Steady-State Conduction 305
dT i X Tj Ti
Ci ¼ qgen, i þ
dt j
Rij
Rearranging and recognizing that the temperature Ti is common to each term in the
summation:
dT i X Tj X 1
Ci ¼ qgen, i þ Ti
dt j
Rij j
Rij
dT i X Tj
Ci þ qgen, i þ
dt j
Rij
Ti ¼ X 1
j
Rij
At steady-state, the transient term is identically zero, and the steady-state tempera-
ture of node i in terms and its neighbors is:
X T j, SS
qgen, i þ
j
Rij
T i, SS ¼ X 1
j
Rij
Δy
RNorth ¼ RSouth ¼
kΔxP
Δx
REast ¼ RWest ¼
kΔyP
If the thin-wall approximation were relaxed, the East and West conductive
resistances would vary with radial position in the wall.
8.2 Numerical Method for 2D Steady-State Conduction 307
Boundary elements, those that have at least one face exposed to a fluid, have a
similar form, but one (or two, for corners) of the temperatures is the fluid, and the
thermal resistances between the fluid and boundary node consist of a convective
resistance in series with a conductive resistance (over half the element).
Top boundary: For the nodal element on the top row in the middle (top of the
mug), the resistance channel to the north is modified:
The thermal resistance for elements exposed to the top surface is a convective
resistance in series with a conductive resistance between the node and the surface:
=2
ðΔyÞ
1
RTop ¼ þ
kΔxP hC ΔxP
Rearranging:
1 hC Δy Btop þ 1
RTop ¼ þ1 ¼
hC ΔxP 2k hC ΔxP
This form reveals a Biot number for the element, Btop ¼ hCΔy/2/k, whose value
yields insight into the temperature of the surface. For the base case, in SI units,
ð13:9Þð0:002Þ
Btop ¼ ¼ 0:014
ð2Þð1Þ
The Biot number for this node being much less than 1 means that the temperature
in the element will be effectively uniform. In other words, the surface temperature
of the nodal element will be closer to the nodal temperature than to the fluid
temperature. Yet another way to say it, it is easier for heat to flow by conduction
inside the element than it is for heat to leave the surface into the fluid.
Right boundary: Elements that are exposed to the fluid on the right (ambient air)
experience a different resistance channel to the east:
The resistance between the element and the fluid is a conductive resistance over half
the element in series with a convective resistance:
=2
ðΔxÞ
1
RRight ¼ þ
kΔyP hC ΔyP
Rearranging:
1 hC Δx Bright þ 1
RRight ¼ þ1 ¼
hC ΔyP 2k hC ΔyP
The Biot number here is different from the top one because the distance from the
center of the node to the surface is the horizontal distance, whereas it was the
vertical distance for the top boundary. For the base case:
ð13:9Þð0:001Þ
BRight ¼ ¼ 0:007
ð 2Þ ð 1Þ
This value is half that for the top boundary (because the horizontal grid spacing Δx
is half that of the vertical spacing Δy).
Bottom boundary: Elements that are exposed to the “fluid” on the bottom
(simulated floor) experience a different resistance channel to the south:
=2
ðΔyÞ
1
RBottom ¼ þ
kΔxP Ub ΔxP
Rearranging:
1 UB Δy Bright þ 1
RBottom ¼ þ1 ¼
U B ΔxP 2k U B ΔxP
For the base case, with a simulated adiabatic bottom (low UB):
ð1E 6Þð0:002Þ
BBottom ¼ ¼ 1E 9
ð 2Þ ð 1Þ
8.2 Numerical Method for 2D Steady-State Conduction 309
Left boundary, below coffee level: Elements that are exposed to the fluid on the left
below the coffee line (coffee) experience a different resistance channel to the west:
The resistance between the element and the fluid is a conductive resistance over half
the element in series with a convective resistance:
=2
ðΔxÞ
1
RLeft, H ¼ þ
kΔyP hH ΔyP
Rearranging:
1 hH Δx Bleft, H þ 1
RLeft, H ¼ þ1 ¼
hH ΔyP 2k hH ΔyP
ð420Þð0:001Þ
BLeft, H ¼ ¼ 0:21
ð 2Þ ð 1Þ
Due to the much higher convection coefficient between the coffee and surface, this
value is larger than the air-based Biot numbers. It is still less than 1, however.
Left boundary, above coffee level: Elements that are exposed to the fluid on the
left above the coffee level (humid air inside rim) experience a different resistance
channel to the west:
The resistance between the element and the fluid is a conductive resistance over half
the element in series with a convective resistance:
=2
ðΔxÞ
1
RLeft, C ¼ þ
kΔyP hC ΔyP
Rearranging:
1 hC Δx Bleft, C þ 1
RLeft, C ¼ þ1 ¼
hC ΔyP 2k hC ΔyP
310 8 Steady-State Conduction
ð13:9Þð0:001Þ
BLeft, C ¼ ¼ 0:007
ð 2Þ ð 1Þ
Corner Nodes
The four corner nodes experience two modifications from the general NESW form,
but all resistances have been defined already. The energy balance equations are, for
the top left:
TC T East T South TC
qgen, i þ þ þ þ
RTop REast RSouth RLeft, C
T TopLeft ¼
1 1 1 1
þ þ þ
RTop REast RSouth RLeft, C
TC TC T South T West
qgen, i þ þ þ þ
RTop RRight RSouth RWest
T TopRight ¼
1 1 1 1
þ þ þ
RTop RRight RSouth RWest
T North TC TC T West
qgen, i þ þ þ þ
RNorth RRight RBottom RWest
T BottomRight ¼
1 1 1 1
þ þ þ
RNorth RRight RBottom RWest
T North T East TC TH
qgen, i þ þ þ þ
RNorth REast RBottom RLeft, H
T BottomLeft ¼
1 1 1 1
þ þ þ
RNorth REast RBottom RLeft, H
Surface Temperatures
Once the nodal temperatures are determined, the surface temperatures can be
inferred from them using a voltage divider analysis. In general, for a boundary
element (at temperature Ti) in thermal contact with a fluid (at temperature T1), the
voltage divider equation can be expressed as:
ðT i T 1 Þ ðT S, i T 1 Þ
qi1 ¼ ¼
Rk þ Rh Rh
8.2 Numerical Method for 2D Steady-State Conduction 311
In this expression, TS,i is the surface temperature of node i, and the conductive (Rk)
and convective (Rh) thermal resistances are defined appropriately for the element in
question. Rearranging for the surface temperature:
Rh
T S, i ¼ T 1 þ ðT i T 1 Þ
Rk þ Rh
1
T S, i ¼ T 1 þ ÞðT i T 1 Þ
=Rh þ 1
Rk
The ratio of the conductive to convective resistance is a Biot number. For example,
for the top middle node:
ðΔy=2Þ
Rk hC Δy
¼ kΔxP ¼ ¼ BTop
Rh 1 2k
hC ΔxP
Corner Surface Temperatures
The corner surface temperatures are a little different, and can be handled by an
energy balance on a resistance network defined at the corner of the corner elements.
Figure 8.9 shows the bottom left corner element. The corner is in thermal contact
with the surface “node” to the north (a distance Δy/2 away, across a conductive area
PΔx/4), to the east with the surface “node” (a distance Δx/2 away, across a
conductive area PΔy/4), to the south with the cold fluid (across a convective area
PΔx/4), and to the east with the hot fluid (across a convective area PΔy/4).
The bottom left corner surface temperature, paying close attention to how the
resistances are defined, is related to its four neighbors by:
T S, above T S, right TC TH
ðΔy=2Þ
þ ðΔx=2Þ
þ 1
þ 1
kðΔx=4ÞP kðΔy=4ÞP UB ðΔx=4ÞP hH ðΔy=4ÞP
T BottomLeftSurface ¼
1 1 1 1
ðΔy=2Þ
þ ðΔx=2Þ
þ 1
þ 1
kðΔx=4ÞP kðΔy=4ÞP U B ðΔx=4ÞP hH ðΔy=4ÞP
TC T S, right T S, below TC
1
þ ðΔx=2Þ
þ ðΔy=2Þ
þ 1
hC ðΔx=4ÞP kðΔy=4ÞP kðΔx=4ÞP hC ðΔy=4ÞP
T TopLeftSurface ¼
1 1 1 1
1
þ ðΔx=2Þ
þ ðΔy=2Þ
þ 1
hC ðΔx=4ÞP kðΔy=4ÞP kðΔx=4ÞP hC ðΔy=4ÞP
TC TC T S, below T S, left
1
þ 1
þ ðΔy=2Þ
þ ðΔx=2Þ
hC ðΔx=4ÞP hC ðΔy=4ÞP kðΔx=4ÞP kðΔy=4ÞP
T TopRightSurface ¼
1 1 1 1
1
þ 1
þ ðΔy=2Þ
þ ðΔx=2Þ
hC ðΔx=4ÞP hC ðΔy=4ÞP kðΔx=4ÞP kðΔy=4ÞP
T S, above TC TC T S, left
ðΔy=2Þ
þ 1
þ 1
þ ðΔx=2Þ
kðΔx=4ÞP hC ðΔy=4ÞP UB ðΔx=4ÞP kðΔy=4ÞP
T BottomRightSurface ¼
1 1 1 1
ðΔy=2Þ
þ 1
þ 1
þ ðΔx=2Þ
kðΔx=4ÞP hC ðΔy=4ÞP U B ðΔx=4ÞP kðΔy=4ÞP
Once all the temperatures are known, the total heat transfer rate from the coffee to
the side wall can be calculated by adding the contributions at each node exposed to
coffee. A good debugging tool is to also calculate the total heat transfer rate out of
all other faces, which should be equal and opposite at steady-state. If not, there is a
bug somewhere.
All the pieces are now in place, and it is time to put them all together.
Model Implementation
An iterative procedure can be applied to a system of N algebraic equations in N
unknowns by guessing a solution, followed by repeated application of a recursion
8.2 Numerical Method for 2D Steady-State Conduction 313
relation formed from the governing equations. The nodal equations developed in
the previous section define a particular set of recursion relations. This form, where
for node i, Ti is expressed in terms of its neighbors, that is, the Method of
Successive Substitution (MOSS). Depending on the system, this iteration procedure
will result in either convergence to a correct mathematical solution (which might be
an unphysical solution), or divergence (chaos or numerical instability), which
means the particular method used has failed. It is possible that the same method
would work with a different set of initial guesses, or that the recursion relations can
be expressed differently.
A strongly diagonal linear system of equations is one in which all the diagonal
elements of each row are greater than or equal to the sum of the absolute values of
off-diagonal elements. For strongly diagonal linear systems, the MOSS will con-
verge to the correct solution. Heat conduction problems with constant thermal
energy production and resistances are strongly diagonal and therefore the MOSS
will work. However, if the thermal energy production and thermal resistances are
variable (for example, with radiation coefficients), making it a nonlinear system,
the method may work, and is generally worth trying. If not, the recursion relations
for nodes that have a high degree of nonlinearity (radiation coefficients are likely
culprits) can be written in another form. If that fails, then other iterative methods,
particularly Newton’s method, are possible. However, setting up a transient prob-
lem and allowing it to reach equilibrium is a legitimate approach if the MOSS fails
after a little tweaking.
A word of caution is in order. Implementation of the MOSS appears to give a
“transient solution” if guessed temperatures are plotted against iteration number.
It is not a transient solution, however, especially if the response time of nodal
elements varies significantly. If a transient solution is desired, set up and solve it as
a transient problem.
Superscripts “k” and “k + 1” are used to identify iteration numbers. In the Jacobi
form, the general equation for node i with superscripts is:
ðkÞ
X T ðj,kSS
Þ
qgen, i þ ðkÞ
ðkþ1Þ j Rij
T i, SS ¼ X 1
ðk Þ
j Rij
Superscripts have to be assigned to all factors on the right hand side, which
indicates thermal energy production and resistances are evaluated at the local
“guessed” temperature, at iteration “k”. The Gauss–Seidel method could alterna-
tively be used in which each nodal temperature is updated to “k + 1” as soon as
available. The order in which the calculations are performed is important in this
method. Systems converge with fewer iterations, generally, but the computational
savings is not dramatic, so the Jacobi method is implemented here.
314 8 Steady-State Conduction
Fig. 8.10 Screenshot of the “Params” worksheet of the excel workbook used to solve the quasi-
steady state mug side wall problem
Fig. 8.11 Worksheet showing the “k” iteration number. The cells are arranged in a 2D grid like
the resistance network
compares that change with the user-defined convergence criterion. If the change is
greater than the criterion, the cell returns “Not Converged” as shown here. Other-
wise, it returns “Converged.” The comment by the author will be discussed in the
next sheet.
Below that comment is a test for overall heat balance. The total heat flux from
the hot fluid into the wall is calculated by adding up all the individual heat fluxes.
The total heat flux out is the heat flux from the cold fluid into the wall (with the
bottom considered part of the cold fluid). This value is negative, meaning that heat
is actually leaving the wall. The sum of the two is the net heat flux into the wall,
which when properly balanced, should equal zero. This overall balance is more of a
check on the overall implementation of the model. A system can converge to a set
of temperatures, but if there are errors in incorporating the model, an imbalance in
the heat flux may be revealed, without necessarily pinpointing precisely where it is.
The next worksheet, “k + 1”, shown in Fig. 8.12, is where the recursion relations
are enacted. The structure of the temperature table is the same as for worksheet “k”
except that the recursion relations are implemented in all 33 nodal cells, which refer
to the temperatures “guessed” in worksheet “k”. At the point shown, after one
iteration, the boundary cells have changed. The table on the right calculates the
difference between k and k + 1 for each node. Notice that the temperatures in the
middle of the wall have not changed (because all the neighbors were at the same
temperature), but the difference between “k” and “k + 1” iterations is 1.42(10)16,
an indication of the precision of the particular computer being used. At the bottom,
the maximum from each column is determined, and the maximum of these is what
is determined in worksheet “k”.
316 8 Steady-State Conduction
-7 70 68.0 67.63 66.87 66.18 65.9 23 HEAT FLUX OUT (Watts)= -4.18125
Fig. 8.14 Contour plot of converged solution showing just the 33 nodal elements
across the mug over most of the surface. This 1D behavior was inherently assumed
in the lumped model, and also was revealed by the graphical analysis (where
isotherms were vertical and heat flux lanes horizontal).
On the other hand, the 2D analysis reveals details near the coffee-free surface.
Figure 8.16 shows the boundary heat fluxes along the inner and outer walls (the top
and bottom not shown). Along the inner surface, the heat flux from the coffee to the
mug increases dramatically as the coffee surface is approached from below, and
then suddenly switches to a heat flux from the mug to the air immediately above the
surface. This effect was predicted by the graphical solution which shows heat flux
line spacing decreasing as the coffee surface is approached and the flux line turning
318 8 Steady-State Conduction
Fig. 8.15 Converged solution of the 33 nodal elements plus the surface nodes plus the fluid nodes
6
4
2
Vertical Position (mm)
0
−0.4 −0.2 −2 0 0.2 0.4 0.6 0.8 1 1.2
Inner Surface
−4
Outer Surface
−6
−8
−10
−12
−14
−16
Surface Heat Flux Into Wall (Watts)
Fig. 8.16 Surface heat fluxes into the wall (x axis) as a function of vertical position. The total heat
transfer rate between the submerged surface and that exposed to air (inside and out) is 4.18 W
back on itself. Heat that enters near the coffee-free surface must transfer across the
mug wall (as everywhere below it) but also must transfer vertically into the rim,
resulting in a high heat flux near the surface. Also, the heat loss from the top corners
is higher than from lower nodes due to the heat transferred vertically to the top
surface (in parallel with the horizontal heat flux). The heat flux on the inner and
8.2 Numerical Method for 2D Steady-State Conduction 319
outer surfaces of the rim are essentially equal and closer to the mug temperature
(at the coffee surface) than ambient, indicating that the rim behaves like a thermally
short heat transfer fin.
Each case study from the original problem statement is introduced, followed by its
converged solution, then the contour plot and heat flux plot.
-7 70 70.0 62.14 46.48 30.83 23.0 23 HEAT FLUX OUT (Watts)= - 69.8399
Fig. 8.17 Converged results for the case of fixed surface temperatures (achieved by setting the
convection coefficients to sufficiently high values)
320 8 Steady-State Conduction
70
Temperature (oC)
60-70
60
50-60
50 40-50
30-40
40 20-30
30
20 Coffee
Inner Surface
0.5
-16
1.5 Horizontal
-15
-13
-11
Outer Surface
-3
-1
1
Ambient
3
5
6
6
4 Inner Surfaace
2 Outer Surface
0
Vertical Position (mm)
−10 −5 0 5 10 15
−2
−4
−6
−8
−10
−12
−14
−16
Surface Heat Flux Into Wall (Watts)
Fig. 8.18 Contour and heat flux plot for the case of fixed boundary temperatures. The x-scale was
increased from 1.2 to 15 compared to the base case. The total heat transfer rate between the
submerged surface and ambient air is 69.84 W
0
-0.4 -0.2 0 0.2 0.4 0.6 0.8 1 1.2
Vertical Position (mm)
-2
Inner Surface
-4
Outer Surface
-6
-8
-10
-12
-14
-16
Surface Heat Flux Into Wall (Watts)
Fig. 8.20 Contour plot and surface heat flux for a Styrofoam mug. The scale on the surface flux is
that same as the base case, revealing the lower heat transfer rate across the mug wall
322 8 Steady-State Conduction
Fig. 8.21 Converged solution for the case of a highly conductive (i.e., copper) floor
8.2 Numerical Method for 2D Steady-State Conduction 323
60-70
70 50-60
Temperature (oC)
60 40-50
50 30-40
20-30
40
30
-15 -13 20 0.5
-11 -9
-7 1.5
-5 -3 Horizontal
-1 1 2.5
Vertica 3 Position (mm)
l Positio 5
n (mm)
0
-2 -1 0 1 2
Vertical Position (mm)
-2
-4
Inner Surface
-6
Outer Surface
-8
-10
-12
-14
-16
Surface Heat Flux Into Wall (Watts)
Fig. 8.22 Contour plot and heat flux plots when the floor is highly conductive (i.e., copper floor).
The x-scale was increased from 1.2 to 2 in order to observe the floor effects
8.2.3.4 Fan
The effectiveness of the heat transfer from the outer surface to the ambient can be
enhanced by blowing across it (Fig. 8.23). This effect can be simulated by increas-
ing the value of the convection coefficient on the outside. Changing it to a value of
50 W/m2/ C (a factor of 3.5 greater than the base case) results in the contour and
heat flux plots of Fig. 8.24. The heat flux increases by a factor of 2.4, and there is a
greater drop in temperature across the mug wall. Recall that the outer convective
resistance dominates the total resistance from coffee to ambient in the lumped
model, and therefore lowering that resistance has a large effect. Also, the rim as a
fin is thermally longer than the base case, as the temperature at the top of the rim is
closer to ambient than the rim base.
y(mm) x (mm)= 0 . . . 3 Test for Convergence
23 23 23 23 23 23 23 MAXIMUM FRACTIONAL CHANGE
6 23 36.1 36.5 36.7 36.4 36.1 23 9.53685E-07
5 23 36.8
.
.
. 36.8 23 Converged
3 23 40.0 .
. . 39.8 23 Author:
Run MACRO shortcut key
1 23 45.6 . . .
44.8 23 CTRL-i
to execute an iteration
-1 70 59.1 .
. . 51.2 23
-3 70 62.5 . . . 55.4 23 Overall Heat Flux Test
-5 70 64.0 . . . 57.6 23 HEAT FLUX IN (Watts)= 10.52989
-7 70 64.8 . . . 58.8 23 HEAT FLUX OUT (Watts)= -10.5303
-9 70 65.2 . . .
59.4 23 FRACTIONAL DIFFERENCE= -3.6E-05
-11 70 65.4 . . . 59.7 23
-13 70 65.5 . .
. 59.8 23
-15 70 65.5 . . .
59.9 23
-16 70 65.5 64.6 62.7 60.8 59.9 23
70 23 23 23 23 23 23
Fig. 8.23 Converged solution for the case of a fan blowing across the side wall
60-70
70
Temperature (oC)
50-60
60 40-50
50 30-40
20-30
40
30
-15 -13 20 0.5
-11 -9
-7 -5 1.5
Vertica -3 Horizontal
l Positio -1 1 2.5
n (mm) 3 Position (mm)
5
0
-2 -1 -2 0 1 2 3
Vertical Position (mm)
-4
-6
-8 Inner Surface
Outer Surface
-10
-12
-14
-16
Surface Heat Flux Into Wall (Watts)
Fig. 8.24 Contour and surface heat flux plots for the case of an enhanced convection on the outer
surface of the mug (i.e., a fan blowing on it). Again, the x-scale is changed compared to the
base case
8.3 Classic 2D Problem Statement 325
As with transient problems, the region of interest can be divided into discrete
elements. Each element is represented by a node. Rather than think of each
element as having a uniform temperature, the nodal temperature represents an
average temperature of the element. That way, boundary temperatures between
nodes can be approximated through voltage divider relations, giving more infor-
mation. The accuracy of the model improves as the region is divided up into
smaller and smaller elemental sizes, at the cost of initial setup work, and
computational effort.
Fig. 8.25 Cross-section (left) and oblique projection (right) of 2D rectangular member
326 8 Steady-State Conduction
Fig. 8.26 Thermal resistance network for a 1 1 model of the classic 2D problem. The surface
temperatures specified are for the classic 2D problem
8.3.2 1 1 Model
A lumped capacity thermal resistance network is shown in Fig. 8.26 for a more general
case, where the temperatures of all four faces can be set to different values and there is
internal heat generation generated. The thermal capacitance (C ¼ ρc*(wHL)) of the
system is shown, along with the internal heat generation (qgen being the volumetric
heat addition, that is, heat added per unit volume). The nodal temperature is given a
subscript 1,1, in anticipation of generalizing to a finer grid, and represents the average
temperature in the member. The node is in thermal contact with the four sides through
conductive resistances (north, east, south, and west). The three sides can be at different
temperatures, but for the classic problem are set to be the same temperature. It is
relatively easy to extend the problem further, by specifying convective boundary
conditions, a good workshop problem.
An energy balance applied to the single node is:
dT 1, 1 T N T 1, 1 T E T 1, 1 T S T 1, 1 T W T 1, 1
C ¼ qgen wHL þ þ þ þ ¼ 0 @ SS
dt RN RE RS RW
Recognizing that the four conductive resistance terms have the nodal temperature in
common, this expression can be written (now at steady-state) as:
8.3 Classic 2D Problem Statement 327
TN TE TS TW 1 1 1 1
0 ¼ qgen wHL þ þ þ þ T 1, 1 þ þ þ
RN RE RS RW RN RE R S RW
ðH=2Þ
RN ¼ RS ¼ Rvert ¼
kwL
ðw=2Þ
RE ¼ RW ¼ Rhoriz ¼
kHL
TN TE TS TW
qgen wHL þ þ þ þ
R Rh Rv Rh
T 1, 1 ¼ v
2 2
þ
Rv Rh
H
qgen wHL þ ðT N þ T S þ H=w ðT E þ T W ÞÞ
2kwL
T 1, 1 ¼
2ð1 þ H=w Þ
qgen H 2 T N þ T S þ ðH=wÞðT E þ T W Þ
T 1, 1 ¼ þ
4kð1 þ H=wÞ 2ð1 þ H=wÞ
The rate of heat transfer from the bottom (south) surface is:
T s T 1, 1
q¼
Rs
This channel splits into three parallel channels to the other three surfaces. In terms
of a conduction shape factor (which does not apply if there is heat generation):
328 8 Steady-State Conduction
qgen H 2 1
T 1, 1 ¼ þ ðT N þ T S þ T E þ T W Þ
8k 4
For the classic problem stated (no heat generation, three sides fixed at equal
temperatures), the temperature of the node is the geometric average of its four
neighbors:
1
T 1, 1 ¼ 0 þ ð0 þ 100 þ 0 þ 0Þ ¼ 25 C
4
The heat transfer rate is:
T s T 1, 1 100 25
q¼ ¼ ¼ 150kL ¼ 1:5kLΔT overall
Rs H=2
kwL
The last expression defines the shape factor to be 1.5, by inserting the overall
temperature drop between surface 1 (the floor at 100 C) and surface 2 (the other
three sides at 0 C).
Example 3 For the problem statement (H ¼ 1.3 m, W ¼ 4.2 m, and Tmax ¼ 200 C)
4kð1 þ H=wÞ T N þ T S þ H=wðT E þ T W Þ
qgen ¼ T 1, 1
H2 2ð1 þ H=wÞ
A good check on the execution is to see whether the net heat flux out of all four
sides equals the total heat generation rate.
8.3 Classic 2D Problem Statement 329
qgen wHL TN TE TS
þ þ þ
2 Ra Rb Ra
T0 ¼
2 1
þ
R a Rb
Note that these resistances differ from the previous model (distances and area) and
are given different subscripts (a and b) to distinguish. A good practice exercise is to
compare the results of this model with the previous, and with the more detailed
models that follow. It is emphasized that the 1-node model yields closed-form
solutions, while the detailed models require iterative calculations.
It is hopefully obvious that breaking the region into a finer grid will yield more
detail. A “few-node” model is defined here as one which is readily solved in a
spreadsheet, where each node can be listed as its own column. A fun classroom
exercise (Workshop 8.3) that clearly demonstrates the nature of the iterative
calculation is to assemble the class into a grid pattern, and treat each person as a
node. Figure 8.27 shows the right half broken into four equal sized nodes, with the
centerline as an insulated boundary, and each node labeled as both a person, and in a
Cartesian (xy) indexing scheme (discussed further in the next section). Horizontal
resistances are not shown, as heat does not flow across the centerline. Also, the heat
generation sources are shown, but each node receives ¼ of the total heat generated
in the right half (which is half of the total heat generated). It is a common error to
330 8 Steady-State Conduction
forget that symmetry has been used. For example, the total heat transfer from the
south to the three other sides equals twice the heat leaving the south side of the right
half, an easy calculation, but one which might slip by with being done.
A spreadsheet implementation of this 4-node model is shown in Fig. 8.28. In the
derived parameters block, the horizontal and vertical resistances are those between
nodes. The resistances between the nodes and their associated boundaries are half
since the distance is half, and accounted for when the formulas are entered into the
iteration table, which uses the Gauss–Seidel method. The table to the right of the
iteration table shows the absolute value of the change between iterations. Only
10 iterations are shown, but 100 iterations are conducted to produce the final results
(but as shown here, 10 iterations are sufficient for convergence to 5 decimal places
in temperature change).
The converged temperature results reported in Fig. 8.29 are oriented in the
original grid pattern, and both sides of the rectangle are shown. The heat balances
show that the heat entering the two bottom nodes is equal and opposite to the heat
leaving the top and right faces, a good check for consistency. The net heat flux in is
8 orders of magnitude lower than the heat flux from the bottom surface, and is
considered to be a demonstration of computer precision.
The same spreadsheet is used for the case of a non-zero internal heat generation,
specifically one that yields a maximum temperature of 200 C, and is shown in
Fig. 8.30. The heat generation (qgen) is an input parameter to this problem, but its
value is not specified beforehand. Rather, an iterative solution (on top of the Gauss–
Seidel iteration) is needed. A guess to the heat generation is made, and the
Gauss–Seidel iteration is executed until it converges. Then another guess for
qgen is made. In this case, the “goal seek” feature of MS-Excel was used rather
than a brute force entry of qgen values. The final result is that a heat generation rate
of 12,555.32 W/m3 yields a maximum temperature of 200 C.
The converged temperature results are reported in Fig. 8.31. The heat balances
show that heat leaves all surfaces, and that the total rate of heat loss equals the total
internal heat generation rate.
8.3 Classic 2D Problem Statement 331
INPUT PARAMETERS
k 20 W/m/K thermal conductivity
W 4.2 m full width
H 1.3 m Height
Tsouth 100 oC Base temperature
Teast 0 oC side temperature
Tnorth 0 oC top temperature
qgen 0 W/m^3 volumetric heat generation rate
DERIVED PARAMETERS
Dx 1.05 m horizontal distance between nodes
Dy 0.65 m vertical distance between nodes
Rh 0.080769 horizontal resistance between nodes
Rv 0.030952 vertical distance between nodes
qgen,node 0 heat generation per node
Fig. 8.28 Spreadsheet implementation of 4-node 2D classic problem, with heat generation set
to zero
8.3.4 n m Model
SHAPE FACTOR
4.42
INPUT PARAMETERS
k 20 W/m/K thermal conductivity
W 4.2 m full width
H 1.3 m Height
Tsouth 100 oC Base temperature
Teast 0 oC side temperature
Tnorth 0 oC top temperature
qgen 12555.32 W/m^3 volumetric heat generation rate
DERIVED PARAMETERS
Dx 1.05 m horizontal distance between nodes
Dy 0.65 m vertical distance between nodes
Rh 0.080769 horizontal resistance between nodes
Rv 0.030952 vertical distance between nodes
qgen,node 8569.007 heat generation per node
Fig. 8.30 Spreadsheet implementation of 4-node 2D classic problem, with heat generation set to
a value that yields a maximum nodal temperature of 200 C. The “goal seek” feature of MS-Excel
was used for this purpose
8.3 Classic 2D Problem Statement 333
Indexing Confusion
There are two common ways to index a 2D variable, and it is easy to introduce bugs
in codes by confusing them, as demonstrated in Fig. 8.32. In matrix indexing (the
natural mode in MATLAB), the grid is considered to be row/column, that is, the
first number is the row, the second the column. Cell 1,1 is in the top left corner and
cell n,m is in the bottom right of a grid. In Cartesian indexing (x/y), the first number
is the x position and the second is the y position. Cell 1,1 is at the origin of a
Cartesian grid (bottom left corner) and cell n,m is at the top right. For the general
node i,j, the relationship between the immediate neighbors is different, as shown in
the isolated i,j nodes with their neighbors.
i-1, j i, j+1
i, j-1 i, j i, j+1 i-1, j i, j i+1, j
i+1, j i, j-1
The nodal equation for node i,j in the form suitable for the Jacobi iteration
scheme (with superscripts “k” or “k + 1” for iteration number) is:
The heat generation rate is given a superscript “k” to indicate that it may depend on
temperature. It is also possible for some or all of the thermal resistances to be
temperature dependent, and these therefore would be recalculated at each iteration,
but the superscripts are left off for brevity. Notice that 16 elementary operations
(+, , *, /) are needed to execute one of these expressions. It is possible to reduce
that number for the case of equal spacings (when Reast ¼ Rwest, for example).
A pseudo-code (MATLAB based) for the n m problem that solves for the heat
generation rate required for the maximum temperature to be 200 C using the
Gauss–Seidel iteration with Cartesian indexing is presented in the Appendix to
this chapter. The Gauss–Seidel iteration method will yield faster convergence than
the Jacobi method and requires careful consideration of the order in which the
computer code calculates the next iteration values. Results from modifications of
this program are presented in this section. Figure 8.33 shows the temperature profile
for the base case of a 4.2 m wide 1.3 m high rectangle, with the bottom surface set
to 100 C and the three sides set to 0 C. The centerline (at x ¼ 0) is an insulated
1.2
10 10
10
1 20 20
20
30
y position (m)
30
0.8
40 40
10
0.6 50 50
20
30
60 40
60 50
0.4 70 60
70
70
0.2 80
80
1002000
345
90 90 90 78060
0 0
0 0.5 1 1.5 2
x position (m)
Fig. 8.33 Contour plot of the right half of the 4.2 m 1.3 m rectangle (using a 100 100 grid)
8.3 Classic 2D Problem Statement 335
1.E+10
1.E+09 y = 44.861x1.9327
1.E+08
1.E+07
y = 34.418x1.9158
1.E+06
Count
1.E+05
y = 5.1732x0.928
1.E+04
1.E+03 y = 3.969x0.9111
1.E+02
1.E+01
1.E+00
1 10 100 1000 10000
Number of Nodes
Fig. 8.34 Computational requirements for the 4.2 1.3 rectangle. The convergence criterion
(defined as the maximum change of any node from one iteration to the next) is set to be 1(10)6 C.
The solid symbols are for the Jacobi method and the open symbols are for the Gauss–Seidel method
surface. This figure shows what a well-constructed graphical analysis would show.
The heat transfer is effectively 1D over the left half of the space.
The computational requirements for this case are shown in Fig. 8.34, on a log–
log scale for a 2 2 up to a 100 100 grid. The number of iterations required for
the solution to converge to the defined convergence criterion and the total number
of elementary operations required are shown for both the Jacobi (filled symbols)
and Gauss–Seidel (open symbols) as a function of number of nodes (n ¼ m for all
cases). These values are determined by adding simple counter statements (i.e.,
iter ¼ iter + 1) at appropriate places in the code (not shown in the Appendix code
for brevity). Power law fits to each curve are shown. The results show that the
number of iterations required to converge increases almost linearly (to the 0.9
power approximately) with the number of nodes. That is, the more nodes, the
more iterations are required for the mathematical system to converge to a solution.
Then, since one nodal equation is needed for each node, the number of elementary
operations is proportional to the total number of nodes. The elementary operations
are not exactly a power of 1 higher than the iterations because the centerline nodes
have fewer elementary operations required than interior nodes, and the percentage
of these changes with the number of nodes. The main point is that the computational
requirements increase dramatically with the number of nodes taken, and is a
fundamental challenge of computational methods in general. A good understanding
and experience aimed at addressing specific questions using a minimum number of
nodes is an important and valuable asset.
336 8 Steady-State Conduction
10 43
9 42.8
8 42.6
6 42.2
5 42
4 41.8
3 41.6
2
Average Temperature 41.4
1 41.2
0 41
1 10 100 1000 10000
Number of Nodes
Fig. 8.35 Calculated shape factor as a function of number of nodes for the base case (semi-logx axes)
Grid Insensitivity
A formal way to determine the minimum number of nodes needed to attain a certain
degree of accuracy is to demonstrate grid insensitivity. The general concept is that
the results of a numerical calculation should be independent of the size of the grid,
which is a numerical parameter, not a physical one. That can only be obtained if the
calculation is done at least twice with two grid sizes. If the results agree sufficiently,
then the coarser grid is shown to be sufficient.
Demonstration of grid insensitivity requires that something specific be compared
at different grid sizes. There is, however, some art required to appropriately define a
specific outcome, such as a temperature at a specific location, or an average
temperature, or a heat transfer rate (which is generally a good global measure).
For example, Fig. 8.35 shows two different measures for this case study; the
predicted shape factor (heat transfer rate from the bottom surface to the other
three surfaces) and the average temperature as a function of the number of nodes
(using semi-logx axes). This plot suggests that the shape factor does NOT show grid
insensitivity. As the number of nodes increases, the heat transfer rate continues to
increase, with no sign of leveling off. However, the temperature (which is plotted in
a narrow 2 C temperature band) shows a leveling off to a value of 41.6 C. The
1-node model actually gives a better agreement than the 2 2 model.
The exact solution to this problem involves solving a boundary-value type partial
differential equation, resulting in an infinite series solution for the temperature field.
8.3 Classic 2D Problem Statement 337
Evaluation of the heat transfer rate between the bottom and side surfaces yields a
non-converging power series. That is, the heat transfer rate is infinite, due to the
discontinuity in temperature that occurs at the corner. The mathematical statement
of the classic problem is a physical impossibility, however elegant.
h i
X
1 ð1Þnþ1 þ 1 cos ðnπ 1Þ
q¼
n¼0
n tanhðnπw=H Þ
Even though the magnitude of successive terms decreases with n (becoming 1/n for
large n), this series fails the formal testing for convergence. The culprit for this
behavior is the physically unattainable discontinuous temperature jump at the
corner, which results in locally infinite heat transfer rates. This result explains
why the numerically predicted shape factor increased with the number of nodes,
as smaller and smaller nodes were placed in the corner.
The same system was solved with an internal heat generation rate (qgen), specifically,
that value that yields a maximum temperature of 200 C. The code (reported in the
Appendix) was written with a Regula-Falsi scheme in which a high and low value of
heat generation was initially selected (assisted by 1-node results). Use of the low value
(0 initially) results in a maximum temperature below the target, and use of the high
value (twice the 1-node prediction was sufficient) results in a maximum temperature
above the target. An iteration loop was implemented in which the next “guess” for heat
generation was taken to be the average of the high and low values (a Golden Ratio
algorithm would be a little faster, but requires more explanation). If the maximum
temperature attained at this average value exceeded the target, then the high value is
replaced by this new value, and vice versa if the maximum temperature is too low. A
Gauss–Seidel iteration loop is used for each “guessed” value of qgen.
The code for this problem has three nested loops. The outer loop simply runs the
algorithm for increasing number of horizontal nodes (n, with vertical nodes, m, set
equal to n). The next loop executes the Regula-Falsi method in which a value of
heat generation is “guessed.” The inner loop executes the Gauss–Seidel iteration
scheme with this selected value.
Temperature contour results for a 100 100 grid are shown in Fig. 8.36. There
are strong temperature gradients toward the three isothermal surfaces as heat
generated in the interior must conduct to these surfaces. The peak temperature is
located on the centerline, and somewhat closer to the hotter bottom surface.
The effect of grid size is shown in Fig. 8.37 in which the internal heat generation
rate required to achieve a maximum temperature of 200 C is plotted against the
number of nodes. Grid insensitivity is demonstrated above approximately
100 nodes (a 10 10 grid). However, even the 2 2 model gives a predicted heat
generation rate that is within 10 % of the grid insensitive value. The 1-node model
338 8 Steady-State Conduction
20 20
1.2 40 40 20
60 60 40
80 80
100 100 80 60
1 120 120 100
140 140 12
0
160
y position (m)
0.8 160
180
80
20
140
18
40
100
0
60
0.6
200
120
160
0.4
180 180
0.2 160 0
80
160 14
20 0
100
4 60
140 140
120 120 120
0
0 0.5 1 1.5 2
x position (m)
Fig. 8.36 Temperature contour for the case with internal heat generation that yields a maximum
temperature of 200 C. A 100 100 grid was used for this plot
16000
14000
14050.20551
14049.45736
14045.98868
14048.36914
14048.84524
14042
14037
14026
14002
13990
13977
13893
Heat Generation Rate (W/mX
)
13717
13383
13249
12000
12555
to achieve Tmax = oC
10000
8915
8000
6000
4000
2000
0
1 10 100 1000 10000
Number of Nodes
Fig. 8.37 Internal heat generation rate required to achieve a maximum temperature of 200 C as a
function of number of nodes. Values are shown to ten decimal places to demonstrate computer
precision issues
exhibits a large deviation, but places the system in the right neighborhood. Any
input parameter value can be changed to a vastly different problem, and the 1-node
model will find an excellent first approximation.
The numerical values are shown (to ten significant figures) in Fig. 8.37 for the
cases that appear from the plot to be equal. These values are not monotonically
Workshop 8.1. Graphical Method on Classic 2D Problem 339
increasing (which would suggest the result was still sensitive to the grid size), but
rather fluctuate about an average value. This behavior is attributed to perhaps both
computer precision, and that a specific convergence criterion was used (1(10)6) for
both the Regula-Falsi algorithm and the Gauss–Seidel algorithm. There is a curious
bump for the case of 25 nodes (5 5) which is similarly related to computational
issues, but in this case, it is the graininess of the spatial grid at fault. The basic shape
of this curve would be the same, with differences in minor detail if a different
convergence criterion were selected.
The graphical conduction method is a useful tool for helping visualize the flow of
heat and estimating conductive resistances in a complicated 2D solid under quasi-
steady state conditions (the temperature may be slowly changing with time).
It involves first specifying two surfaces (1 and 2) that are set to fixed temperatures,
then sketching isotherms and heat flow lines (analogous to streamlines in fluid flow)
in a prescribed manner. The rate of heat transfer (for a length L into the page)
between the two surfaces is obtained from the sketch. A conduction shape factor
(S) can be defined as: q12 ¼ kLSðT 1 T 2 Þ. Published exact solutions for specific
shapes can be used to compare results of this approximate method.
The base of a long 2 1 m2 rectangular structural member is maintained at
temperature T2 (¼100 C) and the other three sides are maintained at temperature
T1 (¼0 C). The member has a thermal conductivity k, and heat flows between
the base and the three sides at a rate q12. Use the graphical method to estimate the
conduction shape factor, S.
1m
2m
Graphical method
1. Draw object to scale (already done here).
2. Use symmetry to identify any insulated surfaces and “hatch” them (note:
insulated surfaces are also heat flow lines).
3. Carefully sketch the average temperature isotherm, creating two temperature
increments (note: isotherms are perpendicular to insulated surfaces).
340 8 Steady-State Conduction
0.4 m
D = 0.1 m 0.4 m = w
RESULTS:
Method q12 /L(W/m) % Differrence
Exact Conduction Shape Factor:
2p q12 L NA
S= =
ln(1.08w/D) k12 (T2 − T1)
Graphical Method
Conductive Resistance
Conduct a graphical analysis on each of these five 2D shapes. Record the value of
the shape factor next to each.
q Mlanes
Graphical Method : ¼k ðT 1 T 2 Þ ¼ kSðT 1 T 2 Þ
L N increments
Heavy line is T1, light line is T2, hatched lines are insulated
For a class of 24 students, arrange them into a 6 4 system, where each student is
assigned a node. The number of rows and columns can be chosen depending on the
class size (for example, a class of 25 could use a 5 5 grid). The method is applied
to a system where Δx ¼ Δy, so that the iteration formula results in the next guess for
each temperature to be equal to the geometric average of the four neighbors. For
students on the perimeter, one of the neighbors is fixed. For students at the corners,
two are fixed. Each student fills out a Worksheet, which requires verbally obtaining
the current iteration neighbor’s values (and a good ice-breaker, especially for shy
students).
342 8 Steady-State Conduction
0 C 0 C 0 C 0 C 0 C 0 C
0 C • • • • • • 0 C
0 C • • • • • • 0 C
0 C • • • • • • 0 C
0 C • • • • • • 0 C
100 C 100 C 100 C 100 C 100 C 100 C
1. For the first iteration, use engineering judgment to make a guess as to your
temperature based on your location. Enter in “MY GUESS” column, iteration
1 row.
2. Ask your four neighbors what their guesses are and enter them in the appropriate
column for iteration 1.
3. Your next guess (iteration 2) is the average of your neighbors. Iterate until
convergence (or you run out of time).
4. Enter your final results on a grid visible to the entire class.
A pile of material that slowly reacts chemically (i.e., coal dust, fertilizer) is stored in
a long w H (use 2 1 m2 as default) rectangular bin. The base is maintained at
ambient temperature T1 ¼ 25 C and the other three sides are exposed to ambient
air with an effective heat transfer coefficient of U ¼ 1.2 W/m2/K (across a thermal
channel consisting of a conductive wall resistance and a convective/radiative
resistance to ambient in series). The material has a thermal conductivity
k ¼ 0.6 W/m/K, and it generates heat internally at a constant volumetric rate (qgen
with units W/m3, so that the rate of heat generation is qgen times the volume). After
storage for a sufficiently long time for a steady-state to be established, it is found
Workshop 8.5. Storage of Energetic Materials—The Chemically Reacting Pile 343
Fig. 8.38 Photo of results at the end of a “Class Fun” workshop. Approximately 30 min was
allotted for this exercise. The results were tabulated before the system was fully converged as
shown by the asymmetry. Notice that each node is the first name of the student, making this a “few-
node” model
that the temperature at the center of the pile is T0 ¼ 40 C. Determine the heat
generation rate, qgen, and the maximum observed temperature and its location. The
material is known to spontaneous combust if it reaches a temperature
Tignition ¼ 60 C.
344 8 Steady-State Conduction
dT i X Tj Ti
Ci ¼ qgen V i þ ð¼ 0 @ Steady StateÞ
dt j
Rij
Workshop 8.6. Cold Plate 345
where Vi is the volume associated with the nodal element, and Rij is the thermal
resistance between the node “i” and its neighbor “j”. At steady-state, expanding the
summation (noting that Ti is common to all summation terms):
X Tj X 1
0 ¼ qgen V i þ Ti
j
Rij j
Rij
Note that either Celsius or Kelvin temperatures can be used (but consistently)
because in the original energy balance temperature appears as a temperature
difference everywhere. Rearranging for the nodal temperature:
X Tj
qgen V i þ
j
Rij
Ti ¼ X 1
j
Rij
For example:
T1 T 2, 2 T 1, 1
qgen ðH=2Þ ðw=4Þ L þ þ þ
Ra þ Rd 2Rb 2Ra
T 1, 2 ¼
1 1 1
þ þ
Ra þ Rd 2Rb 2Ra
e 1 2 3 4
a b c d
T° = −20°C
Δx = 8.6 cm
Fig. 8.39 Nodal network where the nodes are placed, then the volumes (not shown) are defined
around them
Δy = 5.6 cm
5 6 7 8
1 2 3 4
T° = −20°C
Δx = 8.6 cm
Fig. 8.40 Nodal network where the volumes are defined, then the nodes are placed in the center
Appendix. MATLAB Code for Classic 2D Problem 347
%1-Node Model
Rnorth = height/2/(k*width*length);
Rsouth = Rnorth;
Reast = width/2/(k*height*length);
Qdot_1node = (-Tc/Rnorth - Tc/Reast - Tsouth/Rsouth + ...
Tmax_set*(1/Rnorth+1/Reast+1/Rsouth))/(height*width*length);
It can be argued that the exchange of energy between a solid and a fluid is important
in most, if not virtually all, practical situations for which heat transfer plays a role.
In the mug of coffee problem, the prediction of the cooling rate is most sensitive to
the values of the convection coefficient and radiation coefficient used to model the
heat transfer rate between the outer side wall and the surroundings. The side wall
channel has the lowest thermal resistance of the three parallel channels (because it
has the largest exposed area), but within this channel, the outer resistance is the
largest. The effective Biot number of the combined system (h00 L00 /kf) is low. The
initial mug heating period is most sensitive to the value of the convection coeffi-
cient chosen between the coffee and the mug inner wall.
The goal of this chapter is to determine the convective heat transfer coefficients
between the coffee and the mug and between the mug and ambient that have been
used in the various thermal models. The general approach to using Nusselt number
correlations is developed, and applied to the mug inner and outer walls. Rough
order of magnitude “Rules of Thumb” presented in Chap. 3 are thereby tested for
this case study. The next chapter explores more fundamentally the physics of the
thermal boundary layer.
Nusselt number correlations can be obtained from a variety of printed and online
sources, and only a few relevant examples are introduced here, as needed.
scenario one of internal flow. Internal flows and heat exchangers will be addressed
in separate chapters.
There is also a distinction between local and average heat transfer coefficients.
For the sailor, the human nervous system can discern that the rate of heat loss on the
upwind side is greater than that on the downwind side, and thereby determine the
direction of the wind. Therefore, the local convection coefficient on the upwind side
is different than the downstream value. In fact, the local convection coefficient
varies continuously across the entire surface. However, as is common in engineer-
ing analysis, if the total rate of heat loss is of interest, an averaged heat transfer
coefficient would be used that yields the correct total heat transfer rate, but with no
distinction with position.
Finally, flows can be classified as being forced, natural, or mixed. In forced
convection, there is a discernible relative flow velocity between the solid object and
the fluid that surrounds it (for external flows). Therefore, if the sailor can discern the
wind direction by holding up a moist finger, then there is a significant wind speed,
and the finger experiences a forced convection. Even a gentle breeze can be
discerned this way. On the other hand, if there is a dead calm, the sailor will not
experience a spatial difference and will conclude that there is no wind. However,
“hot air rises.” The sailor’s finger is near body temperature and is warmer (and
therefore less dense) than the surrounding air, so this layer of air will rise like a
helium balloon. The word “convective” implies that there is fluid motion. In forced
convection, the fluid motion is imposed. In natural convection, the fluid motion is
induced by the heat transfer process itself.
Mixed convection flows are for those cases where there is a forced velocity, but
buoyancy effects are strong enough to influence the flow field as well. A legitimate
modeling strategy is to calculate both a forced and a natural convection coefficient,
and use the higher of the two. This approach would underestimate the convection
coefficient. Alternatively, a fourth-order polynomial fit can be made across a
defined transition range that matches the slope and value at locations before and
after the crossing point, where the correlations for natural and forced flow are equal.
Natural convective flows are driven by buoyancy and therefore require a gravi-
tational field. One of the many engineering challenges of space travel is to design
systems that are, for economic reasons, tested on the Earth where natural convective
cooling effects (of electronic components, for example) occur. However, these
systems are intended to be operational on a spacecraft which experiences micro-
gravity. Fire safety is of particular concern because the high gas phase temperatures
due to combustion cause intense upward flows on the Earth, but not on a spacecraft.
For engineering applications, convection coefficients for a variety of flow
geometries have been correlated in terms of the dimensionless Nusselt number,
defined as:
hx
Nux ¼
kf
where h is the convection coefficient, x is the appropriate linear dimension for the
problem in question, and kf is the thermal conductivity of the fluid. Special care
9.1 Flow Classification and Dimensionless Parameters 353
must be taken to ensure that the correct dimension for the published correlation is
used. For example, for a pipe of diameter D, length L, the dimension used differs
depending on the flow situation (D for an external cross-flow, L for a vertical pipe in
a still room). Also, the Nusselt number is not to be confused with the Biot number
(Bi ¼ hx/k, where k is that of the solid), which has an entirely different physical
interpretation, namely, the ratio of a conductive to a convective thermal resistance
associated with a solid. The Nusselt number will be shown in the next chapter to be
the ratio of the conductive to convective thermal resistance across a thermal
boundary layer.
Convection coefficients depend on the nature of the flow field (higher speeds
mean better heat transfer) and the nature of the fluid in question (better conducting
fluids with large thermal masses (ρc) convect better). Therefore, the Nusselt number
depends on two other dimensionless numbers, one characterizing the flow field, the
other characterizing the nature of the fluid.
For forced convection, the flow is characterized by the Reynolds number:
ρVx Vx
Rex ¼ ¼
μ ν
where V is the forced flow velocity, ρ is the fluid density, μ the dynamic viscosity,
ν ¼ μ/ρ is the kinematic viscosity. The other dimensionless number is a fluid
property, the Prandtl number, which is the ratio of the kinematic viscosity to the
thermal diffusivity of the fluid.
ν
Pr ¼
α
For natural convection, there is no forced velocity, but there is a flow. The
temperature differences in the fluid give rise to density differences which, in a
gravitational field, cause buoyant forces that induce fluid flows. The dimensionless
number that characterizes this flow is the Grashof number:
gβjðT w T 1 Þjx3
Gr x ¼
ν2
For an ideal gas, β ¼ 1/T, where T is the absolute temperature (R or K). This relation
can be derived using the ideal gas law, P ¼ ρRT. The absolute value of the
temperature difference between surface and fluid is required to prevent negative
values of an inherently positive quantity.
354 9 Nusselt Number Correlations
Many (if not most) of the natural convection correlations involve yet another
combination dimensionless parameter, the Rayleigh number, defined by:
gβðT w T 1 Þx3
Rax ¼ Gr x Pr ¼
να
A few forced convection scenarios could be imagined for the mug of coffee
problem. During the initial pouring, it could be argued that there is a forced
convection, and a characteristic velocity could be wildly stabbed at by estimating
the time it takes to pour the coffee and distance travelled (like the height of the
mug). Another variation would be to stir the coffee, in which case a velocity could
be defined based on the stirring rate and diameter of the rotation. Yet another would
have the impatient train commuter blowing on the top. Notice, however, that results
from previous chapters suggest that blowing on the sides would actually be more
effective. This result is counterintuitive as the vast majority of people would blow
on the top, not the sides.
In the scenario detailed here, the mug of coffee is simply placed on a table and
allowed to cool without intervention. This case is clearly one of natural convection.
There is no imposed flow velocity, but there is fluid motion induced by gravity.
Another classification that can be made is whether the flow is internal or
external. Internal flows are generally cases where fluid flows in some type of
duct, and would therefore almost always be a forced convection case. In the present
case, it would be easy to at first think that the inner convection environment is an
internal flow, but it really is not a forced flow in a duct. Imagine, rather, that the mug
has a very large diameter.
The schematic of Fig. 9.1 shows the side wall of a mug of coffee as a vertical
wall with two different fluids on either side. On the left, the coffee is hotter than the
wall, and a plunging flow in a thermal boundary layer next to the wall (indicated by
the dashed line) is shown. The fluid near the wall is slightly colder, and therefore
denser, than the bulk of the fluid far from the wall, and gravity induces a
9.2 Nusselt Number Example Calculation 355
downward flow. On the right (air) side, the wall is hotter than the free stream air
temperature, and the air in the thermal boundary layer is less dense than ambient air
far from the mug, and gravity induces an upward flow. Note the no-slip condition,
where the velocity of the fluid in contact with the solid is motionless.
So for modeling purposes, the coffee side (inner surface) can be classified as a
natural convection on a vertical heated plate of height H, and width πD. The air side
(outer surface) can be classified as a natural convection on a vertical cooled plate of
height H0 and width π(D + 2w).
A difficulty with this case is that the temperatures of the two fluids can be
considered to be known (at an instant in time), but the temperatures of the two solid
surfaces that they see are not known. The convection coefficients depend on the
temperatures of the solid surfaces for these natural convection cases. The way
around that circular argument is to develop an iterative procedure, a trial and
error approach, developed later in this chapter. The key step in this iterative
procedure is the calculation of the convection coefficients for an assumed value
of surface and fluid temperatures. The problem will now be recast in a way that
obviates, for now, the need for iteration.
Problem Statement
Calculate the convection coefficient between a vertical solid surface of height
H ¼ 0.098 m maintained at a temperature Tsurface and an adjacent stagnant fluid
maintained at temperature Tfluid. Consider a range of temperatures for air and liquid
water.
Analysis
A power law relationship (y ¼ axb) between the Nusselt number and Rayleigh
number has been shown to correlate a wide range of data for natural convection
situations:
m
NuH ¼ C Gr H Prf
The constants C and m take on different values depending on the value of the
Rayleigh number (Ra ¼ GrHPrf). Table 9.1 lists published values for two ranges
that occur in the case study under investigation. These ranges span nine orders of
magnitude in the Rayleigh number, and thereby cover most practical problems of
interest. For cases where the Rayleigh number is below the lowest range can be
handled approximately by either treating the fluid as non-moving (a solid) or using
the lowest value of Rayleigh number. This table will be modified shortly because it
leads to a discontinuity at the point of transition (at Ra ¼ 109).
356 9 Nusselt Number Correlations
Table 9.1 Published values of constants used in the Nusselt number correlation for natural
convection on vertical plates
Rayleigh number range Flow character C m
(10)4–(10)9 Laminar 0.59 0.25
(10)9–(10)13 Turbulent 0.021 0.40
All the dimensionless parameters depend on fluid properties, whose values depend
to some extent on the value of the temperature. There are a variety of sources of
fluid properties, and care must be taken to properly interpret the units and
exponents. Figure 9.2 lists fluid properties, for saturated liquid water at three
temperature values, taken from an online source.1 The compressed liquid approxi-
mation, namely that thermodynamic properties are generally functions of tempera-
ture only (not pressure), is invoked in using these parameter values (as long as the
pressure is above the saturation pressure for that temperature).
Figure 9.3 lists fluid properties for atmospheric air at the same temperatures.2
The only property value that depends significantly on pressure is the density, and
the ideal gas law can be used when needed for problems at other than atmospheric
pressure.
In both of these tables, the properties listed in the reference source are listed in the
top section, and those properties derived from the others are listed in the “DERIVED”
section. For air, properties were listed only at 60 and 80 C, and the values at 70 C
are from linear interpolations. Different sources may list different properties.
To organize these property values and their combinations, it is possible to
consider five of them as being primary property values (ρ, cp, k, μ, β) and the others
1
http://www.engineeringtoolbox.com/water-thermal-properties-d_162.html. Accessed 10/19/
2010.
2
http://www.engineeringtoolbox.com/air-properties-d_156.html. Accessed 10/19/2010.
9.2 Nusselt Number Example Calculation 357
as derived from them (ν, α, Pr). These property values are shown for air and water
over a temperature range of 0–100 C in Fig. 9.4, designed to compare air against
water values using a semi-logy plot, and Fig. 9.5, which plots air and water on
separate linear y axes to observe the temperature dependence. All the property
values for water exceed those of air, except for the coefficient of thermal expansion.
Notice that liquid water is not truly incompressible in heat transfer applications.
Rather, if significant temperature variation occurs in water, the mild temperature
dependency of density results in a gentle motion which profoundly affects its heat
transfer behavior. A truly incompressible fluid would not experience a natural
convection flow because that flow is due to horizontal density variation in a
gravitational field. A rather interesting situation occurs when water is near its
freezing point because the density of the liquid increases ever so slightly from
0 to 4 C. The temperature dependency varies from property to property and
between air and water. The specific role each property plays on the convection
coefficient will be considered after they are calculated.
For most practical applications, property values are treated as suitably chosen
constants, not functions of temperature, in the evaluation of convection coefficients.
For natural convection problems, the convection coefficient depends directly on the
temperature difference driving the heat because of the Grashof number. For forced
convection, convection coefficients are generally considered to be independent of
temperature in most cases. This practice will be further assessed after all the factors
that contribute to convection coefficients are combined.
Figure 9.6 shows the Rayleigh Number plotted (on semi-logy axes) against temper-
ature difference for liquid water and air. All properties are evaluated at 70 C. The
Raleigh number is some four orders of magnitude larger in water than air. The main
culprits for this difference are the density and thermal conductivity, with a minor
specific heat effect. The coefficient of thermal expansion and dynamic viscosity
358 9 Nusselt Number Correlations
Density (kg/m3)
100
0.1 10
Air Air
1
0.01 0.1
0 20 40 60 80 100 0 20 40 60 80 100
Film Temperature (oC) Film Temperature (oC)
10000 0.01
Viscosity (kg/m/s)
Specific Heat (J/kg/K)
H2O(L)
0.001 H2O(L)
1000
Air
0.0001
Air
100 0.00001
0 20 40 60 80 100 0 20 40 60 80 100
Film Temperature (oC) Film Temperature (oC)
Coefficient of Thermal Expansion (1/K)
0.01
Air
0.001
H2O(L)
0.0001
0.00001
0 20 40 60 80 100
Film Temperature (oC)
Fig. 9.4 Fluid properties for air and water between 0 and 100 C. Semi-logy axes used to compare
individual property values of liquid water and atmospheric pressure air
favor air. These comparisons will be revisited shortly. It is emphasized that the
x-axis represents the difference between the fluid and surface temperature, and not
on their values. A conceptual dilemma arises because the actual temperature of the
fluid in the thermal boundary layer changes from one extreme to the other, and so do
all the property values (some more than others). In practice, all property values are
taken at the film temperature, the geometric average of the surface and fluid
temperatures.
Technically, then, Fig. 9.6 applies to a specific temperature value. For example,
for a temperature difference of 100 C, the surface temperature would be 20 C and
the fluid temperature would be 120 C, or vice versa. In practice however, this
9.2 Nusselt Number Example Calculation 359
800
Liquid Water
0.5 Air
0.02 0.8
600 H2O(L)
0.4
Air
Air
0.015 Air 0.6
0.3 400
0.01 0.4
0.2
0.005 200 0.2
0.1
0 0 0 0
0 20 40 60 80 100 0 20 40 60 80 100
Film Temperature (oC) Film Temperature (oC)
4600 Specific Heat (J/kg/K) 1200 1.6E-03 Viscosity (kg/m/s) 2.5E-05
4100 1.4E-03
1000
Liquid Water
3600 2.0E-05
1.2E-03
Liquid Water
3100 H2O(L) 800
1.0E-03 1.5E-05
2600 Air H2O(L)
600
Air
8.0E-04
Air
Air
2100
6.0E-04 1.0E-05
1600 400
1100 4.0E-04
200 5.0E-06
600 2.0E-04
100 0 0.0E+00 0.0E+00
0 20 40 60 80 100 0 50 100
Film Temperature (oC) Film Temperature (oC)
6.0E-04 3.0E-03
5.0E-04 2.5E-03
Air
4.0E-04 2.0E-03
3.0E-04 H2O(L) 1.5E-03
2.0E-04 Air 1.0E-03
1.0E-04 5.0E-04
0.0E+00 0.0E+00
0 20 40 60 80 100
Film Temperature (oC)
Fig. 9.5 Fluid properties of air and water between 0 and 100 C. Linear axes with air as a
secondary scale
distinction can usually be ignored, provided a reasonable film temperature for the
problem at hand is selected, using sound engineering judgment.
10,000,000,000,000
1,000,000,000,000
Turbulent: 100,000,000,000
C = 0.021 H2O(L)
m = 0.20 10,000,000,000
Rayleigh Number
1,000,000,000
100,000,000
Laminar:
C = 0.59 10,000,000 Air
m = 0.25
1,000,000
100,000
10,000
1,000
0 20 40 60 80 100
Tfluid - Tsurface(°C)
Fig. 9.6 Rayleigh number vs. temperature difference between fluid and surface. Property values
evaluated at 70 C
120
H2O(L)
100
80
60
40 Transition Air
20
0
0 20 40 60 80 100
Tfluid-Tsurface(oC)
boundary layer. Conceptually, the Nusselt number (and thus convection coefficient)
should monotonically increase with temperature difference. It is conceivable that a
discontinuous jump UP could occur at the onset of turbulence, owing to the
enhanced mixing. A transition to turbulence, in any event, is very sensitive to
specific geometries. The intent here is to merely generate a monotonically increas-
ing function for modeling purposes. There is no such jump in air because the
Rayleigh number is always below the transition value for the specific case consid-
ered here.
9.2 Nusselt Number Example Calculation 361
120 H2O(L)
Transition
100
80
60
40 Air
20
0
0 20 40 60 80 100
Tfluid-Tsurface(oC)
To address that problem, the critical transition Rayleigh number can be redefined
so that the transition occurs continuously (with a discontinuous slope). To do so
formally, the critical Rayleigh number can be calculated by setting the Nusselt
number equal using the two cases (1 and 2):
m m
1 1
C2 1 2 0:021 0:250:4
Racrit ¼ ¼ ¼ 4:545ð10Þ9
C1 0:59
Table 9.2 and Fig. 9.8 show the revised table and plot of Nusselt number
vs. temperature difference in which case a mild discontinuous slope is observed
at the transition point, but not a discontinuous jump.
(W/m/K)
(W/m/K)
800 Air 8
600 6
400 4
200 2
0 0
0 20 40 60 80 100
Tfluid - Tsurface (°C)
100
Air
10
1
0 10 20 30 40 50 60 70 80 90 100
Tfluid - Tsurface (°C)
coefficients in liquid water are more than 100 times those of air. The Nusselt
number is eight times bigger, and the thermal conductivity, the last step in the
calculation, is 20 times bigger. In a future chapter, the underlying physics behind
this difference is explored further. This case study adds credence to the rule of
thumb case, except the water goes a bit above the value of 1,000. It is pretty hard to
maintain that temperature difference with water, however. Also, “Rules of Thumb”
are made to be broken.
For both fluids, the value of the convection coefficients drops steeply as the
temperature difference is reduced to zero. This effect is generally not observed for
forced convection situations. For natural convection, it is the temperature difference
which gives rise to a density difference which gives rise to a buoyant flow. The flow
in a forced convection does not require a temperature difference to drive it. This
effect is one reason that radiation (and evaporation, when relevant), becomes an
important, if not dominant, mode of heat transfer as an object cools (or warms) to an
ambient environment.
9.2 Nusselt Number Example Calculation 363
A final step in this process is to develop a simple working formula that combines all
the fluid property values into a single term, except for the vertical height H and the
temperature difference. First, the definition of the Nusselt number is expressed in
terms of the convection coefficient:
kf NuH kf C
h¼ ¼ ðRaÞm
H H
Next, the Rayleigh number is expressed in terms of the primary property values:
β β
Ra ¼ gH 3 ΔT ¼ gH 3 ΔT
να μ k
ρ ρcp
Rearranging:
ρ2 c p β
Ra ¼ gH3 ΔT
μk
Inserting this form of the Rayleigh number into the convection coefficient correla-
tion and grouping property terms into brackets:
" #
k1m ρ2m cpm βm ΔT m
h ¼ Cg m
μm H 13m
The term in brackets is a fluid property (with very strange units) to be evaluated at
the film temperature, and will be referred to as the “film property” for natural
convection on a vertical plate. A similar approach can be taken for other
correlations in other situations. Figure 9.11 shows the value of this property (with
the factor Cgm included) as a function of film temperature (not the difference
between fluid and surface) for the laminar range (C ¼ 0.59, m ¼ 0.25), which covers
the problem in question. The water film property is more sensitive to temperature
than the air property.
Finally, a set of working formulas, strictly in SI units, that was used in the mug of
coffee problem (n-node transient case) are given by:
0:25
T outerSurface T ambient
T
0:25
coffee T innerSurface
hcoffee ¼ 32:38T film
0:441
H 0:25
To compare the relative effects of air and water further, it is useful to take
the ratio of the convection coefficients, and look at all the individual factors that
364 9 Nusselt Number Correlations
300 1 3
250
hnat L0.25
ΔT 0.25
= 0.59g0.25 [ k3r2cp b
m
] 4
H2O(L) 2.5
Liquid Water (W/m1.75/K1.25)
y = 32.381x0.441
AIR (W/m1.75/K1.25)
200 2
Air
150 1.5
y = -0.0015x + 1.5646
100 1
50 0.5
0 0
0 20 40 60 80 100
Film Temperature (∞C)
Fig. 9.11 Natural convection on a vertical plate film property vs. film temperature. Laminar flow
restriction
make it up. Entering values at 70 C from Figs. 9.2 and 9.3, keeping the individual
effects separate:
0:75 0:5 0:25 0:25
kwater ρwater cp, water βwater
hH2O kair ρair cp, air βair
¼ 0:25
hair μwater
μair
hH2O ð10:4Þð30:7Þð1:43Þð0:67Þ
¼
hair ð2:1Þ
hH2O
¼ 145
hair
The natural convection coefficient of water is 145 times as large as that in air,
provided the same temperature difference is maintained (not so when the coffee
mug is revisited) and the wall height is the same. This analysis reveals that the
density difference has the largest effect (factor of 30), followed by the thermal
conductivity (k). The specific heat has a mild effect (1.43), and the thermal
expansion and viscosity favor the air. Further discussion of the underlying physics
behind these effects is deferred until convection coefficients models based on
governing laws are considered, rather than these empirical correlations.
9.3 Application to the Mug of Coffee 365
The combined fluid property effects for natural convection cases (and a similar
analysis could be conducted for forced convection cases) exhibits a strong temper-
ature dependency for liquid water, and a mild temperature dependency for air.
Therefore, the general practice of treating the property values as constants is shown
to be well justified for air (and could be extended to most gases), but care needs to
be taken when doing so with liquid water (or other liquids). For steady-state
applications, it seems reasonable to select a suitable film temperature. However,
for transient cases, recalculation of the convection coefficient as time proceeds may
be needed to obtain precise simulations.
It is apparent that in the coffee/mug problem, there really is no such thing as “A”
convection coefficient because the temperature changes with time, and the natural
convection coefficients depend on the changing temperature differences between
the fluid and the corresponding wall. The convection coefficient rather is changing
with time, as the temperature difference changes. In addition, there are spatial
variations not addressed here. The Nusselt correlation used here give spatially
averaged convection coefficients, that is, averaged over the length of the vertical
plate. In reality, the convection coefficient is high near the leading edge of the flow
(near the top surface on the coffee side, near the bottom on the air side), and
decreases along the plate in the direction of induced flow as the boundary layer
thickens, reducing the local temperature gradient driving the heat.
To further complicate matters, the Nusselt number calculations are based on
steady-state experiments in which, for example, a vertical heated plate is
MAINTAINED at a surface temperature and investigated. The thermal boundary
layer has a thermal response time, and error is introduced if the fluid and/or surface
temperature is changing with time rapidly compared to that response time. It is
conceivable that this time constant can be estimated using methods developed in
this text, once a way to estimate the thickness of the boundary layer is developed.
A quasi-steady equilibrium is therefore implicitly assumed in the use of these
correlations to the coffee/mug problem.
On the other hand, there is no problem thinking about “A” coffee temperature,
even though it is now known that the coffee in the center is at a different tempera-
ture than the coffee right next to the mug. For modeling purposes, the choice of a
single value for convection coefficient simplifies the model implementation.
In the 2-node model of Chap. 4, a single convection coefficient was chosen for both
the coffee/inner mug surface and air/outer surface, even though it is clear that they
are both changing with time. So what value should be chosen? It seems logical to
select a temperature difference that exists during the period of time of most interest
366 9 Nusselt Number Correlations
to the objective of the calculation. For example, if the objective is to calculate the
time it takes for the coffee to cool from an initial temperature (say 82 C) to a
defined drinking temperature (say 70 C), then it makes sense conceptually to
determine convection coefficient values when the coffee is at 76 C, the average
coffee temperature during the event. That convection coefficient will underestimate
its value when the coffee is above it, and overestimate it when the coffee is below,
and a degree of cancellation of errors will occur. On the other hand, if the time to
cool from a drinking temperature to a tepid temperature (say 50 C), then 60 C
would be the average coffee temperature during the event.
Figure 9.12 shows a quasi-steady state resistance network for the side channel
for the 1-node lumped capacity analysis (there is no capacitance attributed to the
mug). The coffee temperature is treated as if it were being maintained at a fixed
temperature, even though in the broader model, it gradually changes with time. At
the outer wall, convection (Rma) is modeled as acting in parallel with radiation
(Rrad.ma).
At any time in the simulation, the difference between the average temperature of
the coffee/mug system and ambient is well characterized (say 45 C, when ambient
is 25 C and the coffee is 70 C) . However, the Nusselt number correlation requires
the temperature difference between the fluid and the solid surface adjacent to it, not
the overall temperature drop from one fluid (coffee) to the other (ambient air). The
1-node lumped model allows the temperature of the two surfaces to be calculated,
but there is a circular argument. The surface temperatures depend on the convection
coefficients which depend on the surface temperatures. What can be done?
Develop an iterative scheme.
That is, make an intelligent guess (or a wild stab, if necessary) of both surface
temperatures. Use the Nusselt number correlation to determine a tentative convec-
tion coefficient based on those guesses. Calculate new inner and outer surface
temperatures based on these convection coefficients. Since these new temperatures
are different than the first guess (i.e., you guessed wrong), the convection
coefficients will be different from the first guess. But now the convection
coefficients can be recalculated based on these updated values. An iterative proce-
dure like this can often be done by hand, or it can be automated in a computer
program.
While there are actually different iterative algorithms that could be
implemented, the Method of Successive Substitution (MOSS), introduced in
Chap. 7, works well with most 2- and 3-dimensional steady-state heat transfer
problems, as already shown for the case where the resistance values are constant.
9.3 Application to the Mug of Coffee 367
The two wall surface temperatures in Fig. 9.12, Tinner and Touter are unknown.
Expressing the nodal energy balances on the inner and outer surfaces in the form
suitable for MOSS (using the Gauss–Seidel scheme where updates are used as soon
as available) yields the two recursion relations:
ðk Þ
T coffee T
ðk Þ
þ outer
ðkþ1Þ R Rwall
T inner ¼ cm NODE AT INNER WALL
1 1
þ
RðcmkÞ Rwall
ðkþ1Þ
T inner
þ ðkTÞ 1
ðkþ1Þ Rwall R
T outer ¼ ma, equiv
NODE AT OUTER WALL
1 1
þ
Rwall RðkÞ
ma, equiv
Superscripts (k + 1) and (k) have been applied to all unknowns that refer to the
iteration number. A subscript (k) means the “guessed” values, and (k + 1) refers to
the next guess. It is easy to confuse these iteration numbers with the “p” and “p + 1”
that refer to present and future in a numerical simulation of a transient behavior, but
they are fundamentally different things. A simulation step is a time prediction. An
iteration is a guess.
The resistor values are evaluated using the following formulas. Across the mug
wall:
w
Rwall ¼
kmug ðAinner þ Aouter Þ=2
where w is the mug thickness, kmug its thermal conductivity, Ainner ¼ πDH is the
inner surface area, and Aouter ¼ π(D + 2w)Ho is the outer surface area. This resis-
tance is a constant.
The inner convective resistance is:
1
Rcm ¼
hcoffee Ainner
where ε is the emissivity of the surface and σ ¼ 5.669(10)8 W/m2/K4 is the Stefan–
Boltzmann constant. The temperatures are input in Celsius, and converted to Kelvin
in this equation, which must be in absolute units.
The equivalent resistance for the parallel convective/radiative channel is:
1
Rma, equiv ¼ 1
Rma þ Rma1, rad
Since the area is the same for the convection and radiation, the equivalent resistance
can be expressed as:
1
Rma, equiv ¼
ðhma þ hma, rad ÞAouter
Figure 9.13 shows a spreadsheet implementation of the MOSS for this problem.
Final converged results are shown in the top section. Fixed parameters are defined
below that. These cells refer to input parameters from a separate sheet (not shown).
The wall resistance and surface areas are from the mug of coffee problem. The outer
area is larger than the inner area because its radius is larger, and its height is higher.
The emissivity is a typical value for ceramic. The effect of radiation can be simply
tested by setting the emissivity to zero.
In the iteration table, the initial row (iteration 0) contains the initial guesses (set
at 50 C) for the inner and outer wall temperatures. On the same row, the film
temperatures (average of fluid and adjacent wall surface) are calculated, followed
by the inner convection, outer convection (from the Nusselt number correlation),
and radiative coefficient, and finally the thermal resistances. These formulas are
written once and copied down. On the iteration 2 row (k + 1), the recursion formulas
are entered for Tinner and Touter, which refer to the resistance values from the
previous row (k) or from the same row (k + 1), depending on the order the
calculations are done. These formulas are copied down. Ten iterations are shown
for this case, which is sufficient for successive values to converge to within 0.01 C.
Formal convergence of the method can be tested since the numbers continue to
change at a significant figure level less than shown.
The first “guess” of 50 C for the surface temperatures yielded a convection
coefficient of 744.5 W/m2/K on the inner (coffee) surface, and 6.028 W/m2/K on
the outer (air) surface. The radiative coefficient on the outer is coincidentally very
Workshop 9.1. Wind Chill Effect 369
RESULT
Rside= 2.63 oC/W
Uside= 12.56 oC/W
Fixed Parameters
emissivity = 0.9 Rrad,ma
Tcoffee (oC) = 70
Tinner Touter
Tamb (oC) = 25 Tcoffee T∞
Rwall (oC/W) = 0.094
Rcm Rwall Rma
Ainner (m2)= 0.0198
Aouter (m2)= 0.0303
Tfilm_outer(oC)
Tfilm_inner(oC)
Touter (oC)
Tinner (oC)
Rma,equiv
iteration
hrad,ma
hma
Rcm
hcm
0 50.00 50.00 60.00 37.50 744.5 6.028 6.119 0.0443 2.717
1 63.58 62.29 66.79 43.64 587.7 6.621 6.502 0.0562 2.515
2 67.11 65.60 68.55 45.30 486.9 6.752 6.608 0.0678 2.470
3 68.15 66.58 69.08 45.79 436.8 6.789 6.640 0.0755 2.457
4 68.47 66.88 69.24 45.94 417.0 6.800 6.650 0.0791 2.454
5 68.57 66.97 69.28 45.98 410.3 6.804 6.653 0.0804 2.452
6 68.60 67.00 69.30 46.00 408.2 6.805 6.653 0.0808 2.452
7 68.61 67.00 69.30 46.00 407.5 6.805 6.654 0.0810 2.452
8 68.61 67.01 69.31 46.00 407.3 6.805 6.654 0.0810 2.452
9 68.61 67.01 69.31 46.00 407.3 6.805 6.654 0.0810 2.452
10 68.61 67.01 69.31 46.00 407.3 6.805 6.654 0.0810 2.452
Fig. 9.13 Iteration table using the mug of coffee problem using the Gauss–Seidel method
close to the convection value. Based on these values, the recursion relations yield
improved “guesses” of 63.58 and 62.29 C for the inner and outer wall surface
temperatures, respectively. The film temperature, convection and radiation
coefficient, and thermal resistances are all recalculated, and the iteration scheme
is repeated for as many rows as desired. It is best to confirm convergence rather than
fixing the number of iterations and “hoping” it worked. This method is not
guaranteed to converge, and chaotic or divergent iteration “trajectories” are con-
ceivable. In that case, it is possible to isolate the unknown temperature in a different
way (i.e., isolate the temperature in the radiation coefficient).
The temperature today is 20 C, but with the wind it feels like 5. What’s up with
that?
Physiologically, the sensation of cold is related more to the rate of heat loss
than directly to the temperature of the fluid that the skin is exposed to. The wind
chill effect (shown schematically) can be modeled by equating the actual rate of
heat loss from a person’s skin on a cold windy day (left sketch, with air
370 9 Nusselt Number Correlations
Note that while the convection coefficient is the primary variable that changes with
the wind, the quantitative determination of wind chill effect involves several factors
and depends on whether exposed skin or clothed skin is to be compared. Radiation
acts in parallel with convection, there are conduction effects from the interior (Biot
number effects). Finally, physiological thermoregulatory responses (i.e., constric-
tion of blood vessels) are important. A good student project is to consider these
effects one by one. The main goal of this workshop is to gain experience in
estimating values of the convective heat transfer coefficient using Nusselt number
correlations. The effect of wind speed, size of the object (extended finger vs. arm),
and fluid type (air vs. water) will be considered.
Problem Statement
• Write a Worksheet or program code that takes as input parameters (in SI units) D
(outer diameter), wind speed V, and fluid properties (k, ρ, cp, μ) and uses the
Hilpert/Knudsen/Katz correlation to return the convection coefficient for forced
convection across a cylinder.
• Write a Worksheet or program code that takes as input parameters (in SI units) D
(outer diameter), surface temperature (Tskin), fluid temperature (T1), and fluid
properties (β, k, ρ, cp, μ) and uses the “Notsurewho” correlation to return the
convection coefficient for natural convection across a horizontal cylinder.
• Use this code to complete the Results table, and notice both the values of
convection coefficient, and the trends associated with size, wind speed, and
fluid type.
ν ¼ μ=ρ, α ¼ k= ρcp ) with a cross-flow velocity (V ) have been correlated using
the Hilpert/Knudsen/Katz equation:
The constants C and N depend on the value of the Raleigh number (GrDPr).
There are many applications that involve the exchange of heat between a fluid
flowing in pipes (or ducts) and the inner walls of the pipe. For engineering
calculations, the rate of heat transfer (q) is determined using Newton’s Law of
Cooling, that is, q ¼ hðπDLÞðT wall T bulk Þ, where D is the inner diameter, L is an
appropriate length of pipe (which could be a differential length, Δx), Twalls is the
temperature of the inner wall surface, and Tbulk is the average fluid temperature
over the length in question. The value of the convection coefficient (h) depends on
both the fluid type (in particular its properties such as thermal conductivity (k),
Workshop 9.2. Forced Convection for Internal Flows 373
density (ρ), specific heat (cp), and viscosity (μ)) and on the character of the flow (the
“wind chill” effect), and cannot be simply looked up in a Table. The goal of this
workshop is to gain experience in using published Nusselt number correlations for
internal, forced convection flow problems.
While many correlations have been published, the Dittus/Boelter equation for
turbulent flow is arguably the most general, and would be a good starting place even
if higher precision is warranted afterward. It is given by:
NuD ¼ 0:023R0:8 n
e, D P r
However, the Nusselt number cannot be less than a value of 3.66, the value obtained
for laminar flow. The exponent “n” equals 0.4 for heating (walls hotter than fluid),
and 0.3 for cooling (walls colder than fluid). Expressing the three dimensionless
variables directly in terms of system parameters:
hD ρVD 0:8 ν n
¼ 0:023
k μ α
where V is the flow velocity and fluid properties (k, μ, ν ¼ μ=ρ, α ¼ k=ρcp ) are
evaluated at the “film temperature,” taken to be the average of the bulk fluid and
wall temperatures. Also, this and even more sophisticated correlations yield
ESTIMATES of the convection coefficient, and this uncertainty must be borne in
mind in any application.
Pressure Drop
While thermodynamic analyses often neglect it, there is always a pressure drop in
internal flows that can be estimated using the Fanning friction factor, f, a nonlinear
function of Reynolds number and the relative roughness
L 1 of2the
pipe. The pressure
drop across a pipe of length L is given by: ΔP ¼ f D 2ρV The pressure drop is
not considered further here, except that it should be borne in mind that factors that
give rise to high convection coefficients (high velocity, small diameter) tend to also
give high pressure drops and therefore higher pumping costs.
Case Study
In a boiler application, liquid water enters a pipe of inner diameter (use D ¼ 0.02 m
as a default) whose inner walls are maintained at a higher temperature (a “heating”
event). At the exit of a preheating section, the fluid is a saturated liquid (x ¼ 0), and
the value of the convection coefficient at that point will be calculated. The fluid
continues to flow and phase change occurs in a boiler section until it is a saturated
vapor (x ¼ 1), and the value of the convection coefficient at that point will be
calculated. The flow continues through a superheating section and exits as a
superheated vapor. In a later chapter, the lengths of the heater sections will be
calculated, for which appropriate convection coefficient values are needed.
374 9 Nusselt Number Correlations
Hot Walls
Modify the 2-node mug of coffee analysis (resistance network repeated here) to
include the effects of variable convection and radiation coefficients. As the mug and
its inner and outer surface temperatures change, so do the convection coefficients.
Use the Nusselt number correlations developed in this chapter (formulas of Fig. 9.9)
to recalculate the convection coefficients at the mug wall at each step. For the
Workshop 9.3. Two-Node Mug of Coffee with Variable Convection Coefficients 375
coffee free surface, use the Nusselt number correlation for a heated horizontal plate
of diameter D (from published or online source).
The simpler way to include these effects for this case study is to use the average
mug temperature to determine the difference between the fluid and solid tempera-
ture, which makes the simulation an explicit one. That is, a closed-form expression
for the future temperature is developed. This method is completely justified after
the mug heating phase for this case because there is very little spatial variation
across the mug wall (a low Biot number concept).
T∞
evaporation
convection
radiation
Rsa
Tsurface
mug
coffee Rcs T2 T∞
Tinside Toutside
T1 convection
radiation
Rcm Rmug Rmug
2 2 Rma,side
C1 C2
Rma,floor
However, during the mug heating phase, the mug surface temperature is sub-
stantially different than the average mug temperature (particularly the inside tem-
perature), and this effect can be accounted for by conducting an iterative scheme at
each time step to determine the surface temperature and convection coefficients.
This is a form of implicit formulation, which is not easily performed in a
spreadsheet.
In addition to the coffee and mug temperatures, plot the convective and radiative
coefficients vs. time, and consider the trends. Then, plot the dimensionless temper-
ature vs. time on semi-log x axes to investigate the overall first-order behavior. A
pure first-order behavior would result in a straight line. However, since the convec-
tion and radiative coefficients change, there will be some curvature. Define dimen-
sionless temperature as:
T coffee T 1 Ccoffee T coffee, initial þ Cmug T mug, initial
θ ¼ T LUMPED T 1 , where T LUMPED ¼ Ccoffee þ Cmug is the adiabatic
temperature after the mug heating phase.
Convection Fundamentals
10
To this point, heat transfer modeling methods have been developed for closed
thermodynamic systems, that is, for systems for which heat and work cross the
system boundary, but mass does not. For applications where fluids (liquids, gases,
slurries, etc.) flow into and/or out of the defined system, the mass that crosses the
system boundary carries its energy (internal, kinetic, and potential) with it. In
addition, a force (pressure times cross-sectional area) acting through a distance
per unit time (velocity) is required to push fluid in or out, called “flow work.” The
term “flow power” is technically more accurate, but that would often be interpreted
as the total head times the mass flow rate, a very different thing. The general mass
balance for an open thermodynamic system with multiple inlets and outlets can be
expressed as:
dMcv X X
¼ m_ m_
dt inlets outlets
where Mcv is the total mass inside the control volume (a triple integral), m_ ¼ ρVA is
the mass flow rate of a stream which could be an inlet or an outlet (a double integral,
with density and velocity being appropriately weighted averages). At steady-state,
the mass in the control volume remains constant, and the net mass flow rate is
balanced by the net mass flow rate out. That is:
X X
m_ ¼ m_ ðat steady stateÞ
inlets outlets
For a pipe or duct with a single inlet and single outlet, the mass flow rate of the inlet
equals that of the outlet. The volumetric flow rate (VA) is only the same if the
density is the same.
The general energy balance for an open thermodynamic system with multiple
inlets and outlets can be expressed as:
dEcv X P
X
P
¼ Q_ in W_ shaft, out þ m_ e þ m_ e þ
dt inlets
ρ outlets
ρ
All cases considered in this text will be at steady-state (the rate of energy stored
remains constant), there will be no mechanical devices exchanging work with the
environment, kinetic and potential energy changes will be considered to be negli-
gible. With these restrictions, the energy balance can be expressed in the form of
Energy In ¼ Energy Out:
X X
Q_ in þ _ ¼
mℏ _ þ W_ shaft, out ðat steady stateÞ
mℏ
inlets outlets
where ℏ ¼ u þ P=ρ is the enthalpy of the streams as they cross the boundary. The
enthalpy is a thermodynamic property that combines the internal energy carried in
or out with the work required to push fluid in or out. A line is drawn through it to
differentiate it from the convection coefficient, a fundamentally different quantity.
U¥ U¥
Freestream
ne
streamli Momentum
boundary d(L)
layer
x
d(x)
Fig. 10.1 Schematic of a momentum boundary layer on a flat plate placed in a uniform stream
the solid surface (the no slip condition at y ¼ 0) and increases to the free stream
velocity at the edge of the boundary layer (at y ¼ δ(L)), with a zero gradient.
The lighter curved lines above and below the plate divide the free stream from
the boundary layer. In the free stream, the flow velocity in the x-direction equals the
free stream velocity. There is, however, a mild cross-stream flow velocity (in the
y-direction) as a consequence of mass conservation.
The dotted line shown on the top surface is a streamline that is coincident with
the edge of the boundary layer at the end of the plate. This streamline defines a
streamtube that has a constant mass flow rate at every cross-section. Since
the average velocity exiting the exit plane is less than the free stream velocity,
the area of the streamtube is larger than at the entrance. On the other hand, the line
that shows the boundary layer is not a streamline, and mass flows into the
boundary layer.
A velocity profile near the midpoint is shown underneath the plate. Here, the
boundary layer is thinner than at the exit, that is, δ(x) < δ(L). Therefore, the boundary
layer is a function of distance and generally increases with x. The velocity depends
on both x and y. The velocity gradient at the wall is higher at the midpoint of the
plate (x ¼ L/2, say), and therefore the local shear stresses on the plate are highest
near the leading edge and decrease with x.
In heat transfer, heat exchange between the solid object and the free stream
occurs across a thermal boundary layer. However, the thermal boundary layer
is influenced by the momentum boundary layer, so an understanding of both is
needed. Figure 10.2 shows a schematic of a thermal boundary layer growing on one
side of a flat plate fixed at a temperature Tw, with a uniform flow (not shown) of
temperature T1 approaching from the left. In this case, the line separating the
boundary layer from the free stream has a similar shape to the momentum boundary
layer, but is not generally coincident with it. Outside the thermal boundary layer,
the fluid temperature equals the free stream temperature. Temperature profiles are
shown at the trailing edge (x ¼ L) and at a midpoint. The temperature of the fluid
gradually changes from its value at the wall (at y ¼ 0), to the free stream value at the
edge of the boundary layer (at δT), with zero slope. The shape of the temperature
profile is similar, but the boundary layer is thicker at the exit than at the midpoint.
The horizontal dashed line in this case represents the boundary of a control volume
that will be used to analyze the thermal boundary layer. Notice that fluid crosses this
control surface with a mass flow rate equal to the difference between the mass
that flows into the control volume at the leading edge and the mass that exits at the
trailing edge. Also the temperature of the fluid that exits the top surface equals
the free stream value.
A powerful traditional method of analysis is the integral method, in which a
polynomial function is used to approximate the temperature and velocity profiles
across a boundary layer (y), and the x dependency is contained in the boundary
layer thickness. In practice, these functions are formally derived assuming a
polynomial fit to the velocity and temperature profiles that satisfy boundary
conditions at the wall and edge of the boundary layer. For a second-order fit,
three conditions are required to determine the coefficients of the function
f ¼ ay2 + by + c. These conditions are the no slip condition and fixed wall
10.1 Boundary Layer Concepts 381
T∞ T∞
dx
y δT @ L
δT @ x
TW x TW
dq
Fig. 10.2 Schematic of a thermal boundary layer on a flat plate in a uniform stream
temperature at the wall (y ¼ 0), and a fixed velocity and temperature with zero slope
at the edge of the boundary layer (x ¼ δ). The results are:
" 2 #
y y
uðx;yÞ ¼ U1 2
δðxÞ δðxÞ
" 2 #
y y
T ðx;yÞ ¼ T wall þ ðT wall T 1 Þ 2
δT ðxÞ δ T ð xÞ
This velocity profile is reasonable for the case of forced convection only, where
there is an imposed free stream velocity, and for laminar flow, a difficult statement
to explain briefly. For natural convection, a third-order polynomial is the minimum
order needed. However, a second-order polynomial fit to the temperature profile is
reasonable for both natural and forced convection environments, with laminar flow.
In what follows, the 1-node boundary analysis is equivalent to the use of a linear
velocity and temperature profiles. That is:
y
uðx;yÞ ¼ U 1
δðxÞ
y
T ðx;yÞ ¼ T wall þ ðT wall T 1 Þ
δ T ð xÞ
Notice that the velocity and temperature within the boundary layer are functions of
both x and y. The streamwise (x) dependency is contained in the boundary layer
thickness (momentum and thermal), and the cross-stream (y) dependency is
expressed as a polynomial approximation.
382 10 Convection Fundamentals
The rate of heat transfer from the solid into the fluid can be evaluated at the solid
surface (on the fluid side of that discontinuity in material property, with solid below
and fluid above) for the differential slice of fluid of thickness dx of Fig. 10.2
extending across the boundary layer. Then, Newton’s Law of Cooling can be
defined for the average heat transfer coefficient. That is, a general expression for
the local heat transfer coefficient is:
∂T
dq ¼ k wdx hðxÞ wdxðT w T 1 Þ
∂y y¼0
In first-order modeling, the temperature gradient at the wall (at an arbitrary distance
from the leading edge, x) is considered to be proportional to the total change in
temperature divided by the local thermal boundary layer thickness:
∂T ðT 1 T w Þ
∂y y¼0 δ T ð xÞ
This slope is what would be obtained for a linear temperature profile. Therefore, the
local convection coefficient is:
k
hðxÞ
δ T ð xÞ
The total heat transfer rate and average convection coefficient are determined by
integrating the differential heat transfer rate across the length of the plate:
ðL
∂T
q¼ k wdx hLwðT w T 1 Þ
∂y y¼0
x¼0
2 3
ðL
∂T
k 6
6 dx7
h¼ 6 ∂y y¼0 7 7
L 4x¼0 5
ðT w T 1 Þ
10.1 Boundary Layer Concepts 383
ðL
∂T ðT wall T 1 ÞL 2ðT wall T 1 ÞL
dx 1 ¼
∂y y¼0 2 0 þ δ T ð LÞ
δT ðLÞ
x¼0
That is, the average gradient over the length of the plate is twice that of the gradient at
the trailing edge. This result will be shown to be true after the boundary layer thickness
variation with x is approximated. The result, then, is that the average convection
coefficient on the plate equals twice its value at the trailing edge of the plate:
2k
h ¼ 2hðLÞ
δT ð@LÞ
hL L
NuL ¼ 2
k δ T ð LÞ
hx x
Nux ¼
k δ T ð xÞ
The Nusselt number is therefore shown to be a measure of the ratio of plate length to
boundary layer thickness. A thin boundary layer results in a large Nusselt number.
The convective thermal resistance is defined as:
1 δT
Rconvective ¼
hA kA
Convection is, at its heart, a conduction process, with a thermal resistance that
looks like the conductive resistance across a wall of thickness δ, and thermal
conductivity k. The boundary layer acts as an insulating barrier to convection.
The thicker the layer, the lower the heat transfer rate. As will be developed,
the thermal boundary layer thickness also depends on thermal conductivity,
so the temptation to say that the convection coefficient is proportional to the
fluid thermal conductivity must be suppressed. The temperature gradient is
steepest near the leading edge, and the local convection coefficient is high. The
temperature gradient, and thus local convection coefficient, decreases with
384 10 Convection Fundamentals
U∞ U∞
tum
momen
thermal δ
δΤ
x
L
Fig. 10.3 Schematic of thermal and momentum boundary layers when the momentum boundary
layer is thicker than the thermal boundary layer
U∞ U∞
al
therm
δΤ
tum
momen
δ
x
L
Fig. 10.4 Schematic of thermal and momentum boundary layers when the thermal boundary
layer is thicker than the momentum boundary layer
distance from the leading edge. This functional dependence will be obtained in a
simplified 1-node analysis of the thermal boundary layer.
The relative thickness of the two boundary layers will be shown to be related to
the ratio between the fluid kinematic viscosity (ν ¼ μ/ρ) and its thermal diffusivity
(α ¼ k/ρ/c). When the kinematic viscosity is greater than the thermal diffusivity, the
momentum boundary layer is thicker, as shown schematically in Fig. 10.3. In this
case, the thermal boundary layer is contained entirely within the momentum
boundary layer, and the velocity at the exit plane (at x ¼ L) is everywhere below
the free stream velocity. In the opposite case, the thermal boundary layer is thicker
than the momentum boundary layer (Fig. 10.4). The exit velocity is uniform over a
portion of the exit plane.
10.2 Forced Convection Across an Isothermal Flat Plate 385
Consider the control volume (CV) defined by the streamtube of Fig. 10.5. The top
surface coincides with the streamline that divides fluid that enters the boundary
layer, and the free stream. The free stream is gently displaced upward, but does not
experience a retarding force. The left (east) face has an unknown height, yeast. All of
the fluid that crosses this plane enters the boundary layer and then exits the CV
through the right (west) face at the exit plane. The velocity varies from zero at the
wall to the free stream velocity at the edge of the boundary layer (at the exit plane).
y
U∞
U∞
line
stream
δ(x) Wall Shear Stress δ(L)
yeast
Fig. 10.5 Control volume (dashed line) used for analysis of momentum boundary layer
386 10 Convection Fundamentals
The bottom surface is coincident with the wall, where there is no flow velocity
(no slip), but a shear stress is exerted by the wall on the fluid.
Mass balance. A mass balance will yield a relationship between the height of the
control volume at the entrance (yeast) and the boundary layer thickness at the exit
(δ). Taking a steady-state mass balance, the mass flux entering the left (east, at
x ¼ 0) plane equals the mass flux exiting the right (west, at x ¼ L) face. Integrating
across these planes:
2 3 2 3
yð
east ðδ
6 7 6 7
4 ρuwdy5 ¼ 4 ρuwdy5
y¼0 y¼0
x¼0 x¼L
The velocity is uniform at the entrance (x ¼ 0), and the integral is easily expressed,
but in terms of the unknown height of the streamtube, yeast :
2 3
yð
east
6 7
4 ρuwdy5 ¼ ρU1 wyeast
y¼0
x¼0
Using the geometric average between the wall and free stream is equivalent to
assuming a linear velocity profile with a discontinuous slope at the edge of the
boundary layer. Putting the pieces together, the mass flux entering equals the mass
flux leaving:
1
ρU1 wyeast ρwU 1 δðLÞ
2
The height of the control volume entering is therefore simply half of the boundary
layer thickness at the exit, that is yeast ¼ δðLÞ =2. The result for a second-order
velocity profile is yeast ¼ 2δ(L )/3, that is, it has the same functional dependency,
but a different coefficient.
x-Momentum balance. An integral force balance in the x direction applied to the
control volume states that the rate of change of momentum stored (which is zero at
steady-state) equals the momentum flux entering minus the momentum flux exiting
plus the sum of the forces acting on the control volume. The only forces acting on
this control volume is the retarding friction at the wall, expressed as an integral
along the length. For flows across objects other than thin flat plates, pressure forces
10.2 Forced Convection Across an Isothermal Flat Plate 387
in the x-direction would also be present. In natural convection, gravity forces also
come into play. The momentum balance is:
2 3 2 3
yð
east ðδ ðL
dðx MomÞ 6 7 6 7
¼4 ρu wdy5
2
4 ρu wdy5
2
τwall wdx ¼ 0@SS
dt
y¼0 y¼0 x¼0
x¼0 x¼L
ðL
τwall wdx τwall Lw
x¼0
1 1
0 ¼ ρU 21 wδðLÞ ρU 21 wδðLÞ τwall Lw
2 4
1 2 δðLÞ
τwall ¼ ρU 1
4 L
This momentum balance relates the average shear stress to the boundary layer
thickness.
For Newtonian fluids, the shear stress exerted by a fluid is proportional to the
velocity gradient, with the proportionality being the dynamic viscosity, a fluid
property. That is, the local shear stress at the wall (y ¼ 0) is:
∂u
τwall ¼ μ
∂y y¼0
388 10 Convection Fundamentals
The average velocity gradient is expected to be higher than at the exit, but to exhibit
the same functional dependency (i.e., the overall change in velocity across the
boundary layer (U1) divided by the geometric average distance across the bound-
ary layer δ(L )). Note that the shear stress at the entrance plane is infinite even in the
exact Blasius solution. In reality, the Blasius solution is the exact solution to
the boundary layer approximation equations, so that is not an exact model. The
functional dependency of the average shear stress is therefore:
1 2 δ U1
τwall ¼ ρU 1 μ
4 L δ
This result has exactly the same functional dependence as more detailed models.
The only difference is the constant, 2, compared to the Blasius solution of 5.0.
This model underestimates the magnitude of the boundary layer thickness and is
consistent with the use of the lower bound for the shear stress on the plate
(i.e., the value at the edge of the plate). In addition, the shear stress using a
linear velocity profile underestimates that of a more detailed model. The main
goal here is to demonstrate the key functional dependencies associated with
boundary layers.
10.2 Forced Convection Across an Isothermal Flat Plate 389
ðL
τwall wdx
1 2 δ ð LÞ
Fdrag ρU1 Lw 1 δ
L ðLÞ
¼4
x¼0
CDrag ¼ ¼ ¼
Pstagnation Aplanform 1 2 1 2 2 L
ρU Lw ρU Lw
2 1 2 1
1
CDrag pffiffiffiffiffiffiffiffi
ReL
A different control volume is used to analyze the thermal boundary layer, shown
in Fig. 10.6. The top (north) surface is horizontal (not a streamline) so mass crosses
this surface, and it carries the enthalpy (internal energy plus flow work) associated
with it. A 1-node model for the boundary layer is shown in which the node represents
an average temperature within the control volume (taken to be the geometric average
T ¼ ðT 1 þ T wall Þ=2). Temperature-dependent current sources (rather than thermal
resistances) are used to represent energy flows that cross the surface of the CV
since these energy flows are not driven by a temperature difference. Fluid enters
390 10 Convection Fundamentals
Fig. 10.6 Schematic of control volume and thermal resistance network for the thermal boundary
layer on an isothermal plate
the left (east) face with a uniform velocity at the free stream temperature (T1). The
fluid that exits the top surface is also at the free stream temperature (T1).
The velocity and temperature of the fluid that exits the right (west) face vary from
their value at the wall to their free stream values. The bottom surface, the wall, is
maintained at a fixed temperature (by unspecified means), Twall.
dM
¼ m_ west m_ north m_ east ¼ 0@SS
dt
Therefore, the mass flowing out the top (north) face is the difference between the
inlet (east) and that exit (west) mass fluxes: m_ north ¼ m_ west m_ east
The velocity is uniform (at U1) as it enters the momentum boundary layer, and
therefore the mass flux into the west plane is:
m_ west ¼ ρU 1 wδT
At the exit plane (east), the velocity changes from zero (no slip) to some non-zero
value at the top edge of the thermal boundary layer. Defining an average velocity in
the thermal boundary layer (whose value depends in part on the relative thickness of
the momentum and thermal boundary layers, yet to be determined):
δðT
This average velocity is given a subscript “T” to distinguish it from the average
velocity in the momentum boundary layer. An energy balance applied to the nodal
network, considered to be in a steady-state is:
dT
C ¼ m_ west cp T 1 T ref ðm_ west m_ east Þcp T 1 T ref
dt
T wall T
m_ east cp T east T ref þ ¼ 0@SS
Rk
T wall T
m_ west cp T T 1 ¼
Rk
This expression shows that the difference between the inlet and outlet enthalpy
flows equals the rate at which heat flows into the control volume from the wall.
Rearranging:
T wall T
m_ west cp Rk ¼ ¼1
T T1
The heat transfer rate from the wall to the fluid is driven by conduction, and can be
expressed using Newton’s Law of Cooling:
k
h2
δT
For a given fluid, the thicker the thermal boundary layer, the lower the convection
coefficient. Expressing the thermal boundary layer and rearranging:
sffiffiffiffiffiffiffiffiffiffiffiffiffi
pffiffiffiffiffiffiffiffiffi UT
h kρcp
L
The convection coefficient increases (to the ½ power) with the thermal conductiv-
ity, density, and specific heat of the fluid. This combination of fluid properties
pffiffiffiffiffiffiffiffiffi
kρcp is the thermal inertia, or thermal hardness of the fluid. The convection
coefficient decreases with the length of the plate (because the boundary layer is
thicker, giving a larger conductive distance). It increases with the average velocity
at the boundary layer exit plane.
The Nusselt number (based on plate length, L) is given by:
ffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi
s sffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi
hL U1 L ν UT UT
NuL ¼ ReL Pr
k ν α U1 U1
where the Prandtl number (ν/α), a combination fluid property, has been
introduced. The average velocity at the exit (east) plane depends on the relative
magnitude of the momentum and thermal boundary layers, but is always less than
the free stream velocity. The Prandtl number is shown for select fluids as a
function of temperature in Fig. 10.7. Air at atmospheric temperature has a
Prandtl number near unity and it is effectively constant. The thermal and
momentum boundary layer thicknesses are approximately the same. The Prandtl
number for liquid water at nominal room temperature is on the order of 10 and
decreases with temperature. The momentum boundary layer is somewhat thicker
10.2 Forced Convection Across an Isothermal Flat Plate 393
100000
10000
Prandtl Number = ν/α ∼ (δ/δΤ)2
1000
Unused Engine Oil
100
10
Sat'd Liquid Water
1
Air @ 1 atm
0.1
0.01
Mercury (a liquid metal)
0.001
0 50 100 150 200 250 300
Temperature (oC)
than the thermal layer. Engine oil has a large Prandtl number and the thermal
boundary layer is thin compared to the momentum boundary layer. These three
cases are investigated in the next section. On the other hand, liquid mercury (and
other liquid metals) has a very low Prandtl number, and the thermal boundary
layer is much thicker than the momentum layer. These fluids are the simplest
because the average velocity in the thermal boundary layer is approximately
equal to the free stream velocity.
The average velocity at the exit plane of the thermal boundary layer is half that:
U 1 δT
UT ¼
2δ
394 10 Convection Fundamentals
rffiffiffisffiffiffiffiffiffiffiffiffiffiffi rffiffiffisffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi
δ 1 ν U 1 δT
¼ ¼ Pr
δT 2 α U1 2 δ
1=3
δ 1 1= 1=
¼ Pr 3 ¼ 0:793 Pr 3
δT 2
hL pffiffiffiffiffiffiffiffi 1=
NuL ¼ ¼ 0:664 ReL Pr 3 for Pr < 1
k
The functional dependency is exactly the same.
The average velocity in the thermal boundary layer is determined by integrating the
velocity profile (for a linear velocity in the momentum boundary layer):
δðT ðδ δðT δ!
U1 y U 1 y2
UT δT ¼ udy ¼ dy þ U 1 dy ¼ þ U1 ðδT δÞ
δ δ 2 0
y¼0 y¼0 y¼δ
δ
¼ U 1 δT
2
Squaring the thermal boundary layer, rearranging and inserting the average
velocity:
δ
U 1 δT δT 4αL
2
1 2 δ 2αL
δ δT ¼0
2 T 4 U1
Solving and recognizing that the thermal boundary layer must be positive:
ffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi
s 2 sffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi3
δ δ 2 4αL δ4 43 αL 5
δT ¼ þ ¼ 1þ 1þ
4 4 U1 4 U 1 δ2
Twall
u(L,y)
T∞ y
Twall
u(x,y) T∞
T∞ L u(x,y)
Twall
y T∞
u(L,y)
Twall
u(L,y)
yer
ary la
stream
bound
L
line
˙
m
induced
Fig. 10.9 Schematic of the flow
boundary layer and
streamline on a hot plate
398 10 Convection Fundamentals
10.3.1 Mass
The mass flow rate exiting the streamtube (which, at steady-state, equals the mass
flow rate entering it in a much larger area) is:
ðδ
m_ ¼ ρuðL;yÞ wdy ρU wδ
y¼0
In this expression, a characteristic flow velocity, U*, has been defined as the mass-
average velocity at the exit plane of the boundary layer, and is to be determined.
10.3.2 x-Momentum
Taking a rectangular control volume that contains the boundary layer, the forces
and momentum fluxes (in the x-direction) are shown in Fig. 10.10. The momentum
flux entering the bottom and side surfaces are neglected in comparison to the
momentum flux exiting, which is shown as a “virtual force” acting downward,
equal to the mass flow rate times the average velocity. The pressure acting on the
top and bottom surfaces are the hydrostatic forces and give rise to a net buoyant
force. The weight of the fluid in the CV is a downward gravity force, and a shear
stress on the wall acts to oppose the motion. This schematic is shown for a hot plate.
For a cold plate, the shear stress would act in the opposite direction, and the exiting
momentum flux would act upward on the bottom surface. The pressure and gravity
forces would be the same as in this schematic.
At steady-state, the sum of the upward forces equals the sum of the downward
forces:
Fpressure Fgravity ¼ FNet ¼ Ffriction }F}momentum
The pressure difference between top and bottom yields a net upward force, which is
the buoyant force (equal to the weight of the displaced fluid, that is, Archimedes’
principle). Gravity acts downward. The net upward force on the fluid in the
boundary layer is the difference between the buoyant and gravity forces. The
friction force and momentum virtual force are upward for a hot plate and downward
for a cold plate. The analysis for a hot plate will be performed (+ signs), and the
results are the same for a cold plate, with the direction of flow reversed.
Expressing each term further:
1
Pbottom Ptop wδ ρgðLwδÞ ¼ τwall Lw þ ρU 2 wδ
2
The pressures are the hydrostatic pressures in the far field that are imposed across
the boundary layer (which could be proven
formally with a dimensional analysis of
the y-momentum equation). That is, Pbottom Ptop ¼ ρ1 gL. The momentum
equation becomes:
1
ρ1 gðLwδÞ ρgðLwδÞ ¼ τwall Lw þ ρU 2 wδ
2
Rearranging:
1
ðρ1 ρÞgδ ¼ ρU 2 ðδ=LÞ þ τwall
2
The average shear stress at the wall is taken to be proportional to the viscosity and
the average velocity gradient taken to be the overall change in velocity over the half
width of the boundary layer:
ðL
1 ∂u U 2μU
τwall ¼ μ μ ¼
L ∂y y¼0 δ=2 δ
x¼0
1 2 δ 2μU
ðρ1 ρÞgδ ¼ ρU þ
2 L δ
The underlying physics of this equation is that there is a net upward buoyant force
(left hand side) that drives the flow. This force gives rise to a change in momentum
of the heated fluid and is opposed by a frictional force on the wall.
400 10 Convection Fundamentals
The temperature for the control volume used is taken to be the geometric average:
T wall þ T 1 1
ρ1 ρ ρβ T 1 ¼ ρβðT wall T 1 Þ
2 2
δ 4μU
ρgβðT wall T 1 Þδ ¼ ρU 2 þ
L δ
There is, in general, a balance of three effects: net buoyancy, momentum change,
and friction. Buoyancy drives the flow, adding momentum, which is opposed
by friction.
10.3.3 Energy
ambient temperature fluid entering the bottom (south) and side (east) surfaces,
modeled as current sources. The mass flow exiting the top (north) does so with an
average temperature (taken to be the geometric average of the wall and ambient).
The wall exchanges heat with the average temperature in the boundary layer
through a conductive resistance.
The steady-state energy balance (energy in ¼ energy out), recognizing the east
and south mass flows both enter the control volume at ambient temperature, and that
their sum equals the mass flowing exiting the top:
T wall T
_ p T 1 T ref þ
mc _ p T T ref
¼ mc
Rk
402 10 Convection Fundamentals
T wall T
_ p T T1
¼ mc
Rk
This expression shows that heat conducted from the hot wall into the boundary
layer equals the change in enthalpy flux between inlet and outlet flows. The
temperature average is midway between the wall and ambient, and therefore the
temperature terms are equal, and the underlying relationship for a natural convec-
tion boundary layer is:
_ p Rk ¼ 1
mc
The energy equation yields a simple relationship between the boundary layer
thickness and the characteristic velocity, namely:
U δ2
¼1
4αL
4αL
gβðT wall T 1 ÞL U2 ¼ 4νU L
U
Rearranging:
gβðT wall T 1 ÞL
U 2 ¼
Pr þ 1
10.3 Natural Convection Across an Isothermal Vertical Plate 403
1=4
pffiffiffi ðPr þ 1ÞL
δ2 α
gβðT wall T 1 Þ
The boundary layer thickness normalized by the plate length (and multiplying and
dividing by the square root of the kinematic viscosity):
rffiffiffi" #1=4 1=
δ α ðPr þ 1Þ ðPr þ 1Þ
4
2 ¼ 2 pffiffiffiffiffi
L ν gβðT wall T 1 ÞL
3
PrðGrÞ
1=
4
ν2
2k
h
δ
The average Nusselt number is:
1 pffiffiffiffiffi
=
hL L GrL4 Pr
NuL ¼ 2
k δ ð1 þ PrÞ1=4
As with forced convection, this model applies as long as the flow remains laminar.
In reality, as the Raleigh number exceeds approximately 109, the flow within the
boundary layer becomes turbulent, and an additional mechanism for the transport of
momentum and energy becomes important. This turbulence mechanism is difficult
to model simply.
404 10 Convection Fundamentals
Calculate the thickness of the boundary layer and the corresponding characteristic
flow velocity on the air and the coffee sides of the mug wall for the base coffee
case at a time when the coffee is at 70 C (results from Chap. 9, Figs. 10.9–10.11).
Compare the boundary layer thickness to the diameter of the mug to determine
whether the boundary layer is truly thin compared to the relevant physical
dimension.
Internal Flows Models
11
The concept of a thermal length is useful for internal heat transfer situations and a
tool for heat exchanger design. Consider Fig. 11.1 in which a fluid enters a pipe of
inner diameter Di with an average flow velocity V (or mass flow rate m_ ¼ ρVA,
where ρ is the fluid density and A ¼ πD2i =4 is the cross-sectional area) at a uniform
temperature Tin. Its environment (the fluid in the outer stream) is maintained at a
temperature T1. If no phase change occurs inside, the fluid exits the pipe of length
L at a different average temperature Tbulk,out. The mass flow rate is the same at any
cross-section, but the flow velocity changes inversely with the fluid density. The
bulk temperature is formally defined shortly.
Fig. 11.1 Schematic of isolated tube of flowing fluid surrounded by a gas (or other fluid) at a
different temperature. End view (left) and side view (right)
Fig. 11.2 Temperature profiles for thermally short (left) and thermally long behaviors (right)
Formally, a thermally short stream can be defined as one in which the exit
temperature is much closer to the inlet temperature than it is to ambient temperature.
That is:
There is heat exchanged, but it does not substantially change the temperature of the
fluid as it passes through the pipe. For example, in a car radiator, the air that is
actively blown through (by a fan and/or the speed of the vehicle) is intended to
behave as a thermally short stream. The inlet air temperature is typically 25 C (Tin),
while the inlet coolant flowing into the heat exchanger is typically 90 C (which is
considered T1 from the perspective of the air). The air exiting is not intended to exit
at a substantially higher temperature and could be maybe 30 C (Tout). So the change
in air temperature as it flows through (Tout Tin) is 5 C, while the temperature
difference driving the heat (T1 Tin) is 65 C at the inlet. The air is intended to act as
close to an infinite reservoir as possible.
On the other hand, a thermally long stream is one in which the temperature exits
much closer to the ambient temperature than to the inlet temperature:
For thermally long streams, the fluid flowing in the pipe attains thermal equilibrium
with the outer fluid.
The “thermal length” of a stream is defined when the change in temperature of
the stream is comparable to the difference between the outlet temperature and the
ambient temperature. That is:
The functional dependency of thermal length can be obtained using a transient heat
transfer analysis, by adopting a Lagrangian viewpoint, that is, one which follows a fluid
element as it passes through. The thermal length (Lt) is defined when the time the fluid
particle spends inside the pipe (its residence time) equals its thermal response time:
ρcp VDi
Lt ¼
4U i
Expressing it in terms of the mass flow rate:
_ p
mc
Lt ¼
πU i Di
Notice that the physical length of the pipe (L) is not involved in the thermal length
(Lt). Rather, a comparison of the actual length of pipe to the thermal length will
determine whether a stream is thermally long, short, or intermediate. If the pipe is
much longer than the thermal length (L >> Lt), the pipe is thermally long. Making it
any longer will not increase the heat transfer rate. Notice that a pipe of a given length
can behave either as a thermally short pipe or a thermally long pipe merely by
changing the flow rate. At low flows, the fluid spends a long time in the pipe and will
reach thermal equilibrium (thermally long behavior) and vice versa at high flows.
The same relationship for thermal length will arise in the subsequent steady-state
(Eulerian) analysis.
Internal flow and heat exchanger design theory involves a combination of basic
open-system energy balances (thermodynamics) and rate equations (heat transfer).
A thermodynamic specification would be, for example, that the fluid entering
should be at a specific temperature, given an input mass flow rate, and should exit
at another specific temperature, and the energy balance would yield the required
heat transfer rate. A heat transfer calculation would be to determine the length of
pipe required for a given pipe diameter, flow rate, and temperature of the ambient
(outer). Alternatively, given the temperature of the ambient and a given pipe length,
the exiting temperature could be sought. There are many different ways problems
can be formulated, and it possible to inadvertently either over-specify or under-
specify a problem.
An overall steady-state energy balance in the form enthalpy flow in ¼ enthalpy
flow out is:
_ hin þ Q_ in ¼ m
m _ hout ðþKE þ PEÞ
Tðin
hin ¼ cp dT ¼ cp T in T ref
T ref
Dð
i =2
_ p T bulk T ref
mc ρucp T T ref 2πrdr
r¼0
Dð
i =2
2πρ
T bulkðxÞ ¼ uðrÞ T ðrÞ rdr for a single phase process
m_
r¼0
The energy balance equation, rearranged for the outlet temperature, becomes:
Q_ in
T bulk, out ¼ T bulk, in þ for a single phase process
_ p
mc
of both fluids and the walls separating them. All of these factors can be boiled down
to a Newton’s Law of Cooling type expression, with an overall heat transfer
coefficient (U ) substituted for a single convection coefficient (h):
ðL
Q_ in ¼ UdA T 1 T bulkðxÞ U i ðπDi LÞ T 1 T bulk
x¼0
The differential area (dA ¼ πDi dx) represents a specific surface area that separates the
two fluids, for example, the inner surface of a differential element. The overall heat
transfer coefficient, U, quantifies the effectiveness of the heat exchange and can be
determined with thermal resistance methods developed in earlier chapters. In the
integral, the bulk temperature, which varies with distance x along the duct, represents
the mass flow weighted average temperature of the fluid at any cross-section.
The main objective of this chapter is to develop a modeling capability to
estimate the rate of heat transfer between a fluid flowing in a duct and the walls
of the duct. The principles will be introduced with a water-tube boiler example
(inspired by Cooper Union student Julien Caubel, who designed and built a steam
boiler for his senior project). A long, straight section of pipe of constant diameter is
considered to be broken up into three sections (Fig. 11.3): a preheater (sometimes
called an economizer) in which feedwater (as a subcooled liquid) is heated to its
boiling point, a boiler section where the phase change occurs, and a superheater
section where the steam is raised above its boiling point. Figure 11.4 shows, to
scale, a plot of the temperature plotted against heat addition (per unit mass) for
water at a pressure of 2.0 bar that enters at 100 C, is heated to its boiling point
(120.2 C), then boiled completely, and finally heated to a target design temperature
of 164 C. This exit condition is that which, if delivered to a turbine or reciprocating
piston, would exit at 1 atm as a saturated vapor, and is calculated assuming an
isentropic expansion of a perfect gas from 2 to 1 bar, with cp ¼ 2.02 kJ/kg/K and gas
constant RH2O ¼ 0.461 kJ/kg/K. Note that the energy required to change the phase is
much larger than that required to change the temperature of the liquid (in the
preheater) and the vapor (in the superheater).
In practice, these three functions are often accomplished with very different
design configurations due in part to the different fundamental heat transfer behavior
and to the large change in fluid density associated with phase change. However, the
response of water in a straight pipe from a compressed liquid all the way to a
Hot “air”
180
170
160
Temperature (oC)
150 Preheater
140
Superheater
130
Boiler
120
110
100
0 500 1000 1500 2000 2500
Heat Transferred to Water (kJ/kg)
Fig. 11.4 Water temperature as a function of heat added to the water (entering at 100 C) at a
constant pressure of 2.0 bar (pressure drop neglected)
superheated vapor is a simple design configuration, and allows for a good example
of the principle objectives of this chapter. The goal of the heat transfer analysis is to
turn the x-axis from one of heat exchanged to physical length.
The first example considered is the boiler section, because the two fluid
temperatures can be taken as the inlet temperatures, and there is no ambiguity
about the average fluid temperature. On the water side, the fluid is changing phase
along the entire length, and therefore does not change temperature as it is heated.
On the air side, the flow is considered as an external flow, where the fluid is heated
in a thermal boundary layer, but outside that layer, the temperature remains equal to
the inlet temperature around the perimeter of the pipe. The cooling experienced by
the air is considered to show up in the wake region. The second and third examples
will treat the preheater and superheater, where the inner fluid temperature changes
with position, while the external fluid (hot “air”) is the same along the length. Given
a boiler length in Example 1, the lengths of the preheater and superheater will be
determined.
The approach to solving internal flow problems depends on how the problem
statement is posed. In the following example, which has several parts, the geometry
of the pipe (length, diameter, and wall thickness) in the boiler section is specified, as
is the thermodynamic state of the entrance and exit. The internal mass flow rate (and
therefore flow velocity) is to be determined. Since Nusselt number correlations will
be used to estimate convection coefficients (rather than specifying them in the
problem statement), an iterative procedure will be required to obtain an estimate of
the mass flow rate. Then, with that mass flow rate, the required lengths of the
preheater and superheater are determined.
412 11 Internal Flows Models
A thermal resistance model for this problem is shown in Fig. 11.5. This model
applies to each section (preheater, boiler, and superheater), provided the enthalpies
and temperatures are suitably chosen. Space has been discretized by considering the
entire inside section of the pipe as a control volume represented by a single node.
The fluid entering the pipe is modeled as a current source, since enthalpy (internal
Fig. 11.5 Resistance network. Top image is superimposed on a side view pipe schematic
11.2 Example: Water-Tube Boiler 413
energy plus flow work) is carried into the control volume with the entering mass.
It is not modeled as a resistance, since the energy crossing the boundary is not
driven by a temperature difference. It is not heat transfer; it is mass transfer of a
bulk flow (as opposed to a diffusional mass flow driven by concentration gradients).
This mechanism of energy transport is termed advection. The fluid exiting is
modeled as an advective current sink.
The main node represents an average temperature of the water inside the pipe (T).
It is in thermal contact with the hot combustion product gases through a series
resistance channel which consists of a convective resistance on the inside (Rinner), a
conductive resistance across the wall of the tube (Rwall), and a convective resistance
on the outside surface (Router). The temperature of the gases will be lower in the wake
region, but that has little influence in the thermal boundary layer region on the
outside of the pipe. There are no capacitors shown in the model because the system is
at steady-state. It would not be difficult to estimate a response time to a sudden
change in inner or outer fluid temperature.
Considering the general nodal equation for the main water node, with E
representing the total energy stored in the control volume:
dE X _
¼ Q in ¼ 0 at Steady State
dt
T1 T
m_ w
hin m_ w
hout þ ¼0
R
Solving for the desired mass flow rate of water:
T1 T
m_ w ¼
R
hfg
1
http://www.engineeringtoolbox.com/saturated-steam-properties-d_101.html.
414 11 Internal Flows Models
The thermal resistance, given an inner convection coefficient hi and inner surface
area Ai, pipe thickness t, thermal conductivity kp, and average area (between inside
and outside), outer convection heat transfer coefficient ho, and outer surface area
Ao, is expressed as:
1 t 1
R¼ þ þ
h i Ai k p A h o Ao
The exact solution for the conduction across the pipe could be used, but the thin-wall
approximation is valid in this case.
It is useful to express the resistance in terms of an overall heat transfer coeffi-
cient (U) based on a particular area. Using the pipe inner surface area as the basis,
the resistance is expressed as:
1 1 1 tAi Ai
R¼ ¼ þ þ
U i Ai Ai h i k p A h o Ao
Ai π ðD 2tÞL 2t
¼ ¼1
Ao πDL D
Ai π ðD 2tÞL 1 2t=D
¼ ¼
A πDLþπ2ðD2tÞL 1 t=D
For a thin-walled pipe (t/D << 1), the overall heat transfer coefficient is:
1 1 t 1
¼ þ þ thin wall pipe
U i hi k p ho
Here, the three terms represent the three resistances in series. If any one of them is
significantly larger than the other two, it will control the heat transfer rate, and the
other two can be neglected, in practice. The conductive resistance is easily calcu-
lated, and in this case is negligible in comparison to both convection coefficients
(but still included in calculations). The outer convection environment is one of a
mildly forced external convection of a gas, and a direct Nusselt number correlation
can be used. The inner convection environment is one of forced internal convection.
However, the inner flow velocity is not known from the problem statement.
In addition, the fluid enters as a liquid, changes phase within the boiler section,
and exits as a vapor (at the same mass flow rate, but very different flow velocity)
with very different thermal flow rate. Therefore, an iterative solution method will
be developed.
11.2 Example: Water-Tube Boiler 415
hD
NuD ¼ ¼ CReDn Pr 1=3
k
The values of the constant “C” and exponent “n” depend on the value of the
Reynolds number of the cross-flow, and are presented in Table 11.1, with a
modification of the published ranges to allow a smooth transition between ranges
(as was done in the Chap. 9).
There are published correlations for a bank of tubes, which are more complicated
once the flow patterns begin to interfere, but modeling the flow as an isolated
cylinder is expected to provide a reasonable first approximation for the problem
at hand.
The relevant properties for air at a film temperature of (Tw + T1)/
2 ~ 400 C ¼ 673 K were obtained online2 and input into the following equations:
The constants from Table 11.1 are C ¼ 0.683 and n ¼ 0.466. The convection
coefficient is therefore:
k 0:0515 W=m=K
ho ¼ C ReDn Pr 1=3 ¼ 0:683 ð123:3Þ0:466 0:681=3
D 0:00772 m
W
ho ¼ 26:7
m2 C
That number should seem reasonable by this time for forced convection of a gas.
2
http://www.engineeringtoolbox.com/air-properties-d_156.html.
416 11 Internal Flows Models
NuD ¼ 0:023Re0:8
D Pr
n
for turbulent flow
The exponent on the Prandtl number (n) is 0.4 for heating and 0.3 for cooling.
For laminar flow, the Nusselt number is a constant:
For the problem as posed, a guess for mass flow rate will be made, which allows the
Reynolds number, hence Nusselt number, hence convection coefficient to be
evaluated. It is intriguing that the Reynolds number depends only on the viscosity
of the fluid for this particular problem (same mass flow and diameter at the entrance
11.2 Example: Water-Tube Boiler 417
and exit). The entering liquid has a much higher viscosity and therefore a lower
Reynolds number than the exiting vapor. Any difference in Reynolds number is not
due to a different velocity.
It is instructive to express the convection coefficient (for turbulent flows)
in terms of the fluid properties, and then determine the major contributing factors
that distinguish liquids from vapor.
" #
k 4m_ 0:8 μcp n k1n cpn m_ 0:8
hinner ¼ 0:023 ¼ 0:028 0:8n
D πμD k μ D1:8
For a fixed mass flow rate, there is no direct dependence of convection coefficient
on density, while it increases with thermal conductivity and specific heat and
decreases with viscosity.
Property values for water for saturated liquid and vapor at 2 bar pressure are
shown in Table 11.2. The ratio of the liquid to vapor values is:
2 1n n 3
kliquid cp, liquid " #
hLiquid 66
kvapor cp, vapor 7
7 ð42:8Þ1n ð2:15Þn
¼ ¼ for turbulent flow in both
hVapor 4 μ 0:8n 5 ð23:5Þ0:8n
liquid
μvapor
streams.
For heating (n ¼ 0.4), the results are (showing effect of each fluid property):
hLiquid ð9:52Þð1:36Þ
¼¼ ¼ 3:66
hVapor ð3:53Þ
That this ratio is precisely equal (to two significant figures) to the laminar Nusselt
number is a complete coincidence. The thermal conductivity effect is almost a
factor of 10, there is a mild specific heat effect, and a stronger viscosity effect
(factor of 3.5). The higher viscosity of the liquid tends to suppress turbulent
fluctuations and thereby reduce the effectiveness of the heat transfer between the
tube inner wall and inner fluid.
Table 11.2 Fluid properties for saturated liquid and vapor water at 2 bar pressure (and their ratio)
H2O properties
Property Sat’d liquid @ 2 bar Sat’d vapor @ 2 bar Ratio (liquid to vapor)
k (W/m/K) 0.685 0.016 42.8
ρ (kg/m3) 959 1.23 779.8
cp (J/kg) 4,248 1,970 2.2
μ (kg/s/m) 2.82E04 1.20E05 23.5
α (m2/s) 1.68E07 6.60E06 0.025
ν (m2/s) 2.94E07 9.76E06 0.030
Pr 1.75 1.48 1.2
418 11 Internal Flows Models
Fig. 11.6 Spreadsheet used to calculate convection coefficients at the entrance and exit of the
boiler tube, and then iteratively determine the mass flow rate
The spreadsheet used to iteratively determine the mass flow rate for the boiler is
shown in Fig. 11.6. Fixed parameter values are compiled at the top. In the iteration
table, the mass flow rate for the first iteration is set to zero. The Nusselt number
correlation is calculated at the entrance and at the exit (vapor), the difference being
in the fluid properties. An if-then-else statement is entered for the Nusselt number
that using the Dittus/Boelter correlation with a lower limit of 3.66, the laminar flow
value. The geometric average of the entrance and exit, and then the overall heat
transfer coefficient (Ui, based on the inner diameter) is calculated. The mass flow is
determined from the 1-node energy balance:
T 1 T w U i D i ðT 1 T w Þ
m_ w ¼ ¼
Rhfg hfg
For the first iteration, where there is no inner flow, the corresponding convection
coefficient values are 325 W/m2/K for the inlet (liquid) and 7.6 W/m2/K for the
outlet (vapor). The average of these (166.2) is approximately six times as large as
the outer coefficient so that the predicted overall heat transfer coefficient is con-
trolled by the external convection. The mass flow rate is calculated using this
overall coefficient for the next iteration. Now, the Reynolds number in the liquid
region is 198, and the corresponding Nusselt number evaluates as the laminar flow
limit (3.66). In the exit region, the Reynolds number is much larger (due to the
lower absolute viscosity), and there is a much larger Nusselt number due to the
strong forced convection. However, the convection coefficient (47.8) is still low
11.2 Example: Water-Tube Boiler 419
800
700 677.0
600
Tube Wall
Temperature (8C)
300
200
120.2
203.5
203.6
100
0
0 2 4 6 8 10 12 14 16
Radial Position (mm)
compared to the liquid side. The overall heat transfer coefficient for the second
iteration differs by only a few percent from the first iteration because the outer
convection dominates and is independent of flow rate inside the pipe. The iterative
system converges very quickly to a self-consistent result with a final flow rate of:
4
3, 600 s
m_ w ¼ 3:44ð10Þ kg=s
¼ 1:24 kg=h
h
This seems like a low practical value (about 1.25 l/h of liquid water fed) and shows
the challenge of designing practical boilers.
The radial temperature profile for the final converged solution is shown in
Fig. 11.7. The thermal boundary layers are shown as straight lines (with a boundary
layer thickness k/h). The conductive resistance across the tube wall is four orders of
magnitude lower than the convective resistances, and therefore there is very little
temperature change across the tube wall, which is maintained at 203.5 C.
The boiling action, conceptually, occurs in the inner boundary layer region, where
the indicated temperature is above the boiling point and is a very complex phenom-
enon. The tube wall temperature is closer to the water temperature because the
thermal resistance on the outside is approximately six times greater than the inside.
As a practical matter, the temperature of combustion product gases is frequently
at a temperature well above the melting temperature of the containing vessel. This
condition is only possible if the walls are cooled by the inner fluid, so that there is a
tremendous jump in temperature across the thermal boundary layer between the hot
gases and the containment wall. If, for some reason, the water flow was interrupted, a
transient heating of the tube wall would occur, and could lead to rupture of the tube.
420 11 Internal Flows Models
An important secondary consideration for internal flows is the pressure drop due to
fluid friction associated with the flow. Generally, the smaller the diameter (for a
fixed mass flow), the higher the convection coefficient, hence heat transfer rates, but
the higher the pressure drop, hence pumping requirements. The trade-off between
pumping costs and heat transfer effectiveness can lead to an economic optimization
problem. A brief outline is presented here of the pressure drop estimation, and fluid
mechanics resources should be consulted if more detail on pressure effects is
needed.
Pressure losses are categorized as major (for losses associated with a straight
section of constant diameter) and minor (associated with changes in flow path area
or direction). Considering the major losses, an overall force balance on a straight
section of pipe (internal hydraulic diameter D and length L) with the inlet at state
1 (pressure P1) and the exit at state 2 (P2) is:
P1 πD2 =4 ¼ τwall ðπDLÞ þ P2 πD2 =4
where τwall is the average shear stress that acts along the inner walls of the pipe
(Fig. 11.8). Rearranging for the pressure drop:
L
P1 P2 ¼ ΔP ¼ 4τwall
D
The shear stress at the wall is expressed in terms of the Fanning friction factor
(f) defined by:
1 2
τwall ¼ f ρV
2
where ρV2/2 is the dynamic pressure (the hypothetical pressure if the fluid were
brought to rest without friction). The friction factor is a function of the Reynolds
number of the flow, for incompressible flows and the relative roughness of the pipe
(ε, the average roughness divided by the diameter). For laminar flows (Reynolds
For fully turbulent flows, the friction factor is a function of the relative rough-
ness and is independent of Reynolds number. An implicit function, the Colebrook
equation, can be used, or the friction factor can be obtained from a Moody chart.
The pressure drop is therefore:
L 32f m_ 2 L
ΔP ¼ 2f ρV 2 ¼ 2 5
D π ρD
The second expression converted the velocity in terms of mass flow rate. The
pressure drop is extremely sensitive to the inner diameter (fifth power).
In the boiler section, the density, velocity, and Reynolds number are very
different at the exit than at the entrance. Therefore, it makes sense to consider the
rate of change of pressure by setting the length L to a differential length (dx) and
letting the finite change in pressure (ΔP) shrink to a differential change (dP).
The rate of change of pressure with x is therefore:
dP 2f ρV 2 32f m_ 2
¼ ¼ 2 5
dx D π ρD
Results of a basic spreadsheet pressure drop calculation for the boiler section are
shown in Table 11.3. The top block shows quantities that are invariant. The bottom
block shows the relevant quantities at the entrance and exit sections. The friction
factor was obtained from the laminar formula for the entrance case and from a
Moody chart online (the Fanning-type, not the Darcy type) for the exit case. The
pressure gradient (dP/dx) in units of Pascals per meter is shown to be higher at the
exit than at the entrance, despite the lower friction factor, ultimately a density
effect. However, when multiplied by the actual length, and converted to units of
atmosphere, the pressure drop is of the order of 103 atm. The conclusion for this
422 11 Internal Flows Models
1
R UA
T∞
case study is that the assumption of negligible pressure drop across the boiler is
justified.
When there are changes in the flow path (turns or diameter changes), minor flow
losses are introduced with a coefficient, K, multiplied by the dynamic pressure entering
the element. Note that the magnitude of the minor losses can be larger than the major
losses in an actual flow path. The total pressure drop is the sum of the pressure drops in
all straight sections (major losses) and flow path elements (minor losses):
X L ρV 2 X ρV 2
ΔP ¼ f þ K
D 2 2
major minor
section element
The minimum input power required to overcome this pressure drop, from an energy
analysis, is:
P 1 P2
W shaft, min ¼ m_
ρ1 ρ2
Figure 11.9 shows a resistance network for the preheater and superheater sections
considered as control volumes. Figure 11.5 also applies to this case. The central
node, at temperature T, represents a suitable average temperature of the water in the
pipe in this section that is needed to calculate the rate of heat transfer between the
outer fluid (hot gases) and inner fluid (liquid water in this section of pipe).
Revisiting the problem statement for this application, water enters the preheater
at 2 bar pressure as a compressed liquid (the inlet temperature, Tin ¼ 100 C, is
below the boiling point at that pressure of 120 C). It carries flow energy into the
pipe at the rate m_ w ð
hin þ KE þ PEÞ, where the enthalpy consists of the internal
energy of the inlet fluid (u) and the flow work (P/ρ) required to push it in. The fluid
11.3 Momentum Considerations: Pressure Loss 423
also has kinetic and potential energy. Since there is no phase change, the enthalpy
(relative to a reference) can be related to the temperature through the specific heat.
Neglecting
kinetic
and potential energy, the rate of energy flow in is
m_ w cp T in T ref . The reference temperature is not shown in Fig. 11.9 as it will
be cancelled by the rate at which this reference enthalpy exits. The rate of energy
flow out is expressed similarly. These energy flows refer to bulk temperatures at
precise locations, where the fluid crosses the defined control volume.
Along the pipe length, heat is transferred from the hot gases outside (at T1)
across the pipe wall through three thermal resistances in series (convection to outer
wall, conduction across pipe, and convection to inner fluid). From a steady-state
energy balance, the rate of energy flow out of the control volume is higher than the
inlet energy flow rate by that amount. Unlike the boiler section, where the water
temperature remains at the boiling temperature, the temperature varies with posi-
tion, and so does the local rate of heat transfer. Treating the entire section as a single
lumped element, the heat transfer rate can be approximated based on a suitably
chosen average temperature.
Formally, the energy balance is:
dEstored T1 Tw
C ¼ m_ w cp T in T ref m_ w cp T out T ref þ
dt R
where C is the total heat capacitance of the system, and Estored represents the energy
stored within the control volume. For steady-state operation, the rate of change of
energy stored is zero (or there is a balance between rates of energy crossing the
boundary), and the energy balance can be rearranged in the following format,
introducing an overall heat transfer coefficient (U):
1 ðT out T in Þ
UA ¼ ¼ m_ w cp
R T1 Tw
The thermal resistance (this time based on the outer area, Ao, for variety) is the sum
of the inner convective, pipe wall conductive (using the exact cylindrical form this
time), and outer convective resistances:
1 lnðDo =Di Þ 1 1 1 Do lnðDo =Di Þ Do
R¼ þ þ ¼ þ þ
ho πDo L 2πkpipe L hi πDi L πDo L ho 2kpipe hi D i
The term in parentheses is the inverse of the overall heat transfer coefficient, based
on the outer surface area.
1 1 Do lnðDo =Di Þ Do
¼ þ þ
Uo ho 2kpipe hi D i
424 11 Internal Flows Models
m_ w cp ðT out T in Þ
L¼
πDo U o T 1 T w
In this expression, for the defined problem, three of the four temperatures are well
defined, while the average fluid temperature along the pipe is not. The fluid
temperature is bound between the inlet and outlet temperatures, however.
Figure 11.10 shows a calculation of the preheater and superheater lengths that
determines a minimum, a maximum, and an average length, depending on what is
chosen for the average water temperature. An underestimate, Lmin, sets the average
water temperature equal to the inlet water temperature. That model uses the largest
possible temperature difference driving the heat all along the pipe length.
An overestimate, Lmax, sets the average temperature to the outlet temperature. An
average length uses the geometric average of the inlet and outlet temperatures.
What is apparent for this case study is that the predicted length changes by only a
few percent from minimum to maximum. That is not always the case.
The only differences between the preheater and superheater sections are that the
inner convection coefficient is substantially lower in the latter (making U lower,
and the length longer), the heat capacity of vapor is approximately half that of liquid
Fig. 11.10 Spreadsheet calculation of preheater (left) and superheater (right) lengths
11.4 Internal Heat Transfer Flow Models 425
(making the length shorter) and the inlet and outlet temperatures are different
(a larger temperature change, making the length longer). The average temperature
difference driving the heat is also lower in this section, since the water temperature
is closer to T1. The lengths of the preheater and superheater are both short
compared to the length of the boiler section (2 m, an input to the problem) and
that is primarily due to the much lower enthalpy change required in these sections
(Fig. 11.4).
The way that open system problems are approached depends on the way a given
problem is formulated. In this case, there were three sections of pipe. The length of
the boiler section (2 m) was an input that was defined by a specific design objective.
The analysis of that section results in a determination of the required mass flow rate.
That flow rate became an input to the other two sections, whose inlet and outlet
temperatures were also defined. Also, all the inlet and outlet temperatures were
specified, and the required lengths determined. It is common for a given length of
pipe and inlet temperature and flow rate to be specified and the resulting exit
temperature determined. This example is intended to show several, but not all
possible, variations.
In this section, a 1D steady-state heat transfer flow situation is defined in which fluid
steadily enters a pipe of constant inner diameter Di, wall thickness t, and length L at
a mass flow rate ṁ and inlet temperature Tin (Fig. 11.11). The pipe is exposed to an
outer fluid at temperature T1 (constant along entire length). The fluid exit temper-
ature is not specified in the problem statement (in contrast to the preheater and
superheater of the previous section). The fluid does not undergo phase change, so
any change in the fluid enthalpy changes its temperature. Posed with these inputs,
there are three unknown quantities: the fluid exit temperature, the total heat transfer
rate, and the average temperature of the fluid in the pipe.
Two of the three required relationships to solve for the three unknowns are an
overall thermodynamic energy balance that relates the energy flows to the total heat
transfer rate, and a heat transfer relationship that relates the total heat transfer rate to
L
Tin Tout = ?
. T=?
m .
Q=?
x
x+dx
T∞
Fig. 11.11 Schematic diagram for internal flow heat transfer models
426 11 Internal Flows Models
the average fluid temperature. The third relationship needed for closure requires an
assumption for the average fluid temperature. Three 1-node models are developed, and
their model predictions are then compared to a differential 1D flow model, which is
considered to be an exact solution for comparison. That model is developed first.
In this expression, T(x) is the bulk temperature at location x (the inlet); T(x+dx)
is the
bulk temperature at the exit of the differential section; T T ðxÞ þ T ðxþdxÞ =2 is the
average temperature of the fluid in the section; and Tref is a reference temperature,
which cancels. The overall heat transfer coefficient is that based on the inner
diameter (unlike the previous example, which based U on the outer diameter).
Expressing the temperature at the exit as a Taylor expansion from the inlet:
dT
T ðxþdxÞ ¼ T ðxÞ þ dx þ . . .
dx
x
Rearranging:
dT 1 UπDi UπDi
1 dx ¼ ðT 1 T Þ
dx _ p
2 mc _ p
mc
The second term on the left hand side (from the expansion of the average tempera-
ture in the heat transfer term) is a higher order term than the other two terms in the
equation and becomes negligible in comparison to unity for a differentially sized
element (i.e., as dx goes to zero). Another way of saying that is that the average
temperature is approximately equal to the incoming fluid, which is going to be
defined in the next section as a “thermally short” section. The preheater and
superheater in the previous section behaved that way because the prescribed change
in temperature through the pipe was small compared to the temperature difference
between T1 and the entrance fluid temperature.
11.4 Internal Heat Transfer Flow Models 427
For the problem as stated, the outer fluid temperature is constant along the entire
length of the duct (as opposed to heat exchangers where this temperature also varies
with position), and therefore dT1/dx ¼ 0, and the energy balance can be expressed
with dT ¼ d(T T1) as:
d ðT T 1 Þ UπDi
¼ ðT 1 T Þ
dx _ p
mc
The term in parentheses has units of inverse length and is defined as the thermal
length, the same expression that was derived with a Lagrangian viewpoint:
_ p
mc
Lt ¼
UπDi
Separating variables and applying limits from the entrance to an arbitrary point x
within the pipe:
ðT ðx
d ðT T 1 Þ dx
¼
ðT T 1 Þ Lt
T in 0
Assuming the thermal length to be constant (the heat transfer coefficients could
vary with position if entrance effects are important or fluid properties change
substantially), the final result for temperature as a function of position (x) is:
T T1 x
¼ e Lt
T in T 1
This solution is considered to be the exact solution of the 1D flow situation, but not
a complete solution to the flow situation. The temperature T represents the average
(bulk) temperature of the fluid at a particular position along the pipe. There must
be 2D effects because this average fluid temperature is different from the tempera-
ture of the inner wall surface in order for heat to flow across the inner resistance.
This expression has a very similar appearance and underlying physics to the lumped
capacity transient temperature, but with time replaced with position, and time
constant replaced with thermal length.
Consider the limits. The exit temperature is obtained by setting x to the pipe
length (L):
T out T 1 L
¼ e Lt
T in T 1
If the pipe length is much shorter than the thermal length (L << Lt), then the exit
temperature is approximately equal to the inlet temperature. There is heat transfer,
but it does not change the temperature of the inner fluid appreciably. That is
428 11 Internal Flows Models
“thermally short” behavior. If the pipe length is much longer than the thermal
length, then the exit temperature approaches the outer fluid temperature (T1). The
fluid has achieved thermal equilibrium with the outer fluid and is considered to be
“thermally long” behavior. These concepts will be applied to the 1-node models in
the next section.
The total heat transfer rate is determined by:
Q_ ¼ mc
L
_ p ðT out T in Þ ¼ mc
_ p T 1 þ ðT in T 1 Þe Lt T in
L
_ p ðT 1 T in Þ 1 e Lt
¼ mc
In order to compare models, it will prove useful to normalize the actual heat transfer
rate by the maximum possible heat transfer rate, which is what would occur if the
inner fluid were everywhere equal to the inlet temperature:
^_ ¼ Q_ ¼ Q_ _ p
mc L
L
t L
Q ¼ 1 e Lt ¼ 1 e Lt
Q_ max UAi ðT 1 T in Þ UAi L
UπDi L UA L
L^ ¼ ¼ ¼
_ p
mc _ p Lt
mc
An expression for the dimensionless heat transfer rate is therefore a function of the
dimensionless length:
^
1 e L
Q^_ ¼
L^
This function, along with the results of the following 1-node models to follow, is
shown in Fig. 11.12 (top figure). The dimensionless temperature is shown in the
bottom figure.
The 1-node resistance model shown in Fig. 11.9 applies to this case. An overall
energy balance is given by:
Q_ ¼ mc
_ p ðT out T in Þ
This thermodynamic relation has two unknowns ( Q_ and Tout). It is useful, and
common, in heat exchanger applications to define the maximum possible heat
transfer rate that could be obtained, and that occurs simply when the fluid exits at
11.4 Internal Heat Transfer Flow Models 429
.
Q
UA (T∞− Tin )
Thermally Long (low flow)
2
1.8
1.6
1.4
1.2 Thermally Short (high flow)
1
0.8
Average Temp. model
0.6 Well-mixed
0.4
Differential
0.2
0
0.01
0.1
100
10
1
UA
L̂ = .
mc p
Tout − T∞ 0.8
Tin − T∞ 0.6 Well-mixed
0.1
100
10
1
−0.2
Thermally Short
−0.6
(high flow)
−0.8
−1
Fig. 11.12 Dimensionless heat transfer rate (top) and exit temperature (bottom) vs. dimensionless
pipe length for several models
the ambient temperature, that is, for thermally long behavior. The maximum
possible heat transfer rate is:
Q_ max ¼ mc
_ p ðT 1 T in Þ
This concept will apply to the “number of transfer units” (NTU) approach in heat
exchanger applications in the next chapter.
430 11 Internal Flows Models
The heat transfer rate between the outer and inner fluids is given by an overall
heat transfer coefficient (U) across a defined surface area (A) as:
Q_ ¼ UA T 1 T
This relation introduces the average temperature of the fluid. In the differential
solution, this temperature was taken to be the geometric average between the inlet
and outlet, but upon Taylor expansion, and shrinking the element size (dx ! 0), the
average temperature becomes approximately equal to the inlet temperature, for
the purposes of calculating the heat transfer rate. In the 1-node model, the entire
pipe length is taken as the element. In other words, the element is not differentially
small, and the average temperature can be treated differently, as is shown in the
following four cases:
Q_ ¼ UAðT 1 T in Þ
Q_ Q_
¼ ¼1
_
Q max UAi ðT 1 T in Þ
Or, simply
^_ ¼ 1
Q
Note that there is in fact a change in fluid temperature predicted by this model.
The average temperature was set equal to the inlet temperature for the purpose of
estimating the heat transfer rate. The thermodynamic relationship yields the exit
temperature:
Q_ UA
T out ¼ T in þ ¼ T in þ ðT 1 T in Þ
_ p
mc _ p
mc
11.4 Internal Heat Transfer Flow Models 431
T out ¼ T in þ L^ ðT 1 T in Þ
T out T 1
¼ 1 L^
T in T 1
Consider the limits. For a pipe length much less than the thermal length (L^ << 1),
the exit temperature approaches the inlet temperature. For a pipe length equal to the
thermal length, the exit temperature equals the outer fluid temperature, and the
model is not expected to be very good. The predicted outlet temperature overshoots
the outer fluid temperature for any pipe length greater than the thermal length. In
short, the thermally short model is expected to be reasonable for situations where the
pipe length is actually short compared to its thermal length, but violates the Second
Law of Thermodynamics for pipe lengths that are longer than the thermal length.
Q_ ¼ mc
_ p ðT 1 T in Þ
In dimensionless terms:
Q_ Q_ _ p
mc
¼ ¼
_
Q max UA ðT
i 1 T in Þ UA
Or simply,
Q^_ ¼
1
L^
The dimensionless heat transfer exceeds the maximum possible for pipe lengths that
are shorter than the thermal length, in violation of the Second Law. For pipe lengths
greater than the thermal length, a reasonable trend is apparent. So the thermally long
model gives reasonable trends for pipes that are long compared to the thermal length.
T in þ T out
UA T 1 _ p ðT out T in Þ
¼ mc
2
Solving for the exit temperature (and skipping details, a good exercise. . .):
L^ T 1 þ T in 1 L^ =2
T out ¼
1 þ L^ =2
T out T 1 2 L^
¼
T in T 1 2 þ L^
For thermally short pipes, the outlet temperature approaches inlet temperature. For
thermally long pipes, the outlet temperature does not approach ambient. That is:
lim T out ¼ 2T 1 T in
L^ >1
The outlet temperature overshoots the outer fluid, but remains finite. The dimen-
sionless heat transfer rate is:
^_ ¼
Q
2
2 þ L^
This model gives good agreement with the exact model across thermally long and
short cases, but does not give a good prediction for the exit temperature for
thermally long cases. This situation is similar to the case in transient numerical
analysis when a central difference approximation is used to express the first
derivative of temperature with time. It is a more accurate numerical approximation
than a backward difference when the numerical step size is sufficiently small, but it
gives wrong limits for large step sizes.
Combining with the thermodynamic balance and rearranging for the outlet
temperature:
_ p T in L^ T 1 þ T in
UAT 1 þ mc
T out ¼ ¼
_ p
UA þ mc L^ þ 1
Expressed as a dimensionless temperature:
T out T 1 1
¼
T in T 1 ^
L þ1
The outlet temperature approaches the outer fluid for long pipes, and the inlet for
short pipes, that is, the temperature exhibits the correct limits.
The dimensionless heat transfer rate is
Q^_ ¼
1
1 þ L^
As shown in Fig. 11.12, this model underestimates the heat transfer rate and
overestimates the dimensionless exit temperature, but gives reasonable trends over
the entire range, and reasonable trends for the exit temperature. It is therefore
considered to be the best general 1-node model to use for internal flow problems.
It also can be advantageous in more detailed numerical simulations, as numerical
stability is assured.
A common internal flow situation is to force heat into a fluid by, for example,
wrapping an electrical heating tape around the outside of the pipe. Electrical energy
is converted to thermal energy and heat is driven into the fluid. The same thermo-
dynamic and heat transfer relations apply, but heat transfer rate is a known input
434 11 Internal Flows Models
quantity. The exit temperature and the temperature of the heating element (the role
of ambient temperature) is unknown (and changes with position).
_ and it is uniformly
The total heat transfer rate forced into the fluid is given by Q,
delivered across the entire length (L) of the pipe. For a differential element of length
dx, a differential heat rate is added ( d Q_ ), which is a constant along the pipe.
It follows that a heating intensity (heat transferred per unit length) is given by:
d Q_ Q_
¼
dx L
The thermodynamic balance for this element is:
d Q_ ¼ mc
_ p T bulkðxþdxÞ T bulkðxÞ
Rearranging:
dT bulk dQ_ 1 Q_
¼ ¼
dx dx mc _ p
_ p Lmc
The rate of change of bulk temperature with distance is a constant, and therefore, on
integration, the bulk temperature increases linearly with x:
_
Qx
T bulkðxÞ ¼ T inlet þ
_ p
Lmc
The overall heat transfer coefficient (Ui) based on the inner diameter (Di) represents
a series thermal resistance channel across any insulation around the heating tape,
the wall of the pipe, and inner convection (assuming the temperature of the element
itself is uniform, although conductive resistance of the heating element could be
included). Solving for the temperature of the heating element:
Q_
T element, ðxÞ ¼ T bulk, ðxÞ þ
LU i πDi
The element temperature is always hotter than the fluid. The more effective the heat
transfer (Ui) and the larger the diameter, the closer the element temperature is to the
fluid temperature.
Workshop 11.1. Finned Pipe 435
Results
Quantity Symbol Value Unit
Overall heat transfer coefficient (based on inner area) Ui W/m2/K
Total heat transfer rate Q_ Watts
Pipe length L m
Number of fins (round up) nfins –
Model Development
Use a 1-node fin resistance model (Fig. 11.14) and a 1-node overall flow model
(Fig. 11.15). Since the inlet and exit temperature are specified (the exit is a saturated
vapor), the average temperature can be set equal to the geometric average for the
most accuracy. A single closed-form expression can be obtained that includes all
the fins acting in parallel, or a more brute force computer simulation that steps
through the pipe fin by fin until the final desired temperature is achieved.
not absorbed by the pipe. The angle between the incoming solar rays and the pipe
is θ ¼ 20 . The absorption coefficient of incident radiation is α ¼ 0.85. The rod
is exposed to air at a temperature T1 ¼ 25 C with a natural convection
coefficient (from a Nusselt number correlation) that has a mild temperature depen-
dency given by:
T T 1 1=4
hc, outer ¼ 1:32 W=m2 =K
D
where T is the surface temperature of the pipe. The emissivity of the rod surface is
ε ¼ 0.9. The average temperature of the walls with which the rod exchanges thermal
radiation is Tw1 ¼ 30 C. The convection coefficient on the inside of the pipe can
be approximated using the larger of Dittus/Boelter correlation or laminar flow
lower limit. That is, the Nusselt number (SI units) is the higher of:
hinner ðD 2tÞ ρV ðD 2tÞ 0:8 μcp 0:4
NuD ¼ ¼ 0:023 OR NuD ¼ 3:66
k μ k
For water properties, use ρ ¼ 1,000 kg/m3, cp ¼ 4,200 J/kg/K, k ¼ 0.6 W/m/K, and
μ ¼ 5.0(10)4 kg/m/s. Assume the system is pressurized sufficiently to prevent
water from changing phase.
Calculate, as a function of volumetric flow rate (AV):
The thermal resistance network shown for this system defines an absorbing surface
node (the outer surface of the pipe, at an average temperature Tpipe), which receives
solar radiation (modeled as a current source). This surface is in thermal contact with
the ambient air surrounding it (at temperature T1) and the surrounding walls
(at Tw1). Note that there are two very different radiation modes at play; the
absorption of solar radiation (modeled as a current source), and thermal radiation
of the pipe surrounded by the local environment (modeled as a resistance). The
absorbing surface is in thermal contact with the fluid flowing through it (at an
average temperature T w ) through a conductive resistance across the pipe in series
with an inner convective resistance. The energy flux associated with the water flow
is modeled as current sources entering and leaving. A nodal energy balance on the
absorbing surface node is:
In the well-mixed flow model (which is numerically stable for all cases, and yields
correct high and low flow limits), the average water temperature for the heat
transfer term is set equal to the exit temperature (T w ¼ T 2 ).
Using Newton’s Law of Cooling and the Stefan–Boltzmann law for radiation
(with σ ¼ 5.669(10)8 W/m2/K4), the thermal resistances are defined as:
1
Rh1 ¼
hc, outer πDL
Workshop 11.2. Solar Pipe in Continuous Mode: 2-Node Model 439
1
Rr1 ¼
hr πDL
1
¼ h 2 i
εσ T pipe þ 273 þ ðT w1 þ 273Þ2 T pipe þ 273 þ T w1 þ 273 πDL
1
Rhinner ¼
hc, inner π D 2tpipe L
t
Rpipe ¼ k pipe
(thin-wall approximation, which is valid here)
ðDtpipe ÞL
pipe π
The nodal equation can be rearranged into a form suitable for the method of
successive substitution, with a “k” superscript to indicate iteration number, noting
that the thermal resistances between the outer pipe wall and ambient are functions
of temperature:
ðk Þ
Q_ abs þ
T
T1
ðk Þ þ T w1
ðk Þ þ R
2
pipe þRh, inner
ðkþ1Þ Rh1 Rr1
T pipe ¼ 1
ðk Þ þ 1
ðk Þ þ Rpipe þR
1
h, inner
Rh1 Rr1
T pipe T w
_ p ðT 2 T 1 Þ ¼
mc
Rpipe þ Rh, inner
where the mass flow is m_ ¼ ρAV. Invoking the well-mixed model (T w ¼ T 2 ), and
rearranging for the exit water temperature in a form suitable for Method of
Successive Substitution (note that the Jacobi method uses “k” and Gauss–Seidel
uses “k + 1”):
ðk Þ or ðkþ1Þ
T
ðkþ1Þ
T1
Rflow þ Rpipe
pipe
þRh, inner
T2 ¼ 1
Rflow þ Rpipe þR
1
h, inner
Heat to Fluid _ p ðT 2 T 1 Þ
mc
ηthermal ¼ ¼
Heat Collected nDLI 0 cos θ
440 11 Internal Flows Models
Workshop
A more complex model is required to account for spatial variations in the pipe
surface temperature. On the one hand, such a variation would seem to be important
for flow rates, where there is a substantial change in water temperature with
position. On the other hand, conduction axially in the pipe would tend to maintain
a constant wall temperature, especially for highly conductive pipes (like copper).
Consider the thermal resistance network shown (larger versions shown subse-
quently), in which the pipe and fluid spaces are broken into discrete elements
(represented by nodes) and connected thermally by appropriate thermal resistances.
Workshop 11.3. Solar Pipe in Continuous Mode: Multi-node Model 441
Each pipe surface node absorbs solar radiation, exchanges heat with the environment
(by convection and radiation acting in parallel), with the adjacent inner fluid (by a
conductive resistance across the pipe in series with a convective resistance inside the
pipe), and with the neighboring pipe nodes (by a conductive resistance through the
pipe wall). The end segments (Tp1, TpN, T1, and TN) differ from the interior nodes
(Tp2. . .TpN and T2. . .TN) in that they communicate with only one neighbor. Each
fluid node is in thermal contact with the pipe outer surface through a series thermal
resistance across the pipe wall and convection on the inner surface. There is an inlet
flow and outlet flow to each fluid node and the well-mixed model sets the average
temperature equal to the outlet temperature. Finally, heat is conducted forward and
backward through an axial conductive resistance (in parallel with the flow). This
latter mechanism can be important for highly conductive pipes like copper.
The forward and backward conduction in the fluid is in parallel with the flow and
is a mechanism whose relative importance will be shown to depend on the size of the
spatial grid.
For a numerical choice of N segments (2N nodes), the grid spacing is given by:
L
Δx ¼
N
All the resistance values and solar absorption term are the same as that in the
2-Node model, except that the dimension L is replaced with the grid spacing, Δx.
The axial pipe resistance and axial resistance for the inner fluid are new to this
model and are given by:
Δx Δx
Rp, axial ¼ 2 ¼
kpipe ðπ=4Þ D D 2tpipe
2 k pipe πDt pipe 1 tpipe =D
Δx
Raxial ¼
kf π ðD 2tÞ2 =4
ΔQ_ abs þ RT 11 þ RT w1
T
þ Rp, p2axial þ RpipeTþR
1
h, i
T p1 ¼ w1
1
R1 þ Rw1
1
þ Rp,1axial þ Rpipe 1þRh, i
ΔQ_ abs þ RT 11 þ RT w1
T
þ Rppð,N1 Þ
þ RpipeTþR
N
h, i
T pN ¼ w1 axial
1
R1 þ Rw1
1
þ Rp,1axial þ Rpipe 1þRh, i
An energy balance on the first fluid node, rearranging into a form suitable for
MOSS, and invoking the well-mixed flow model, with Rflow ¼ 1=mc _ p and:
T
T IN
Rflow þ Rpipe þR
p1
h, i
þ RTaxial
2
T1 ¼ 1
Rflow þ Rpipe 1þRh, i þ Raxial
1
Ti ¼ 1
Rflow þ Rpipe 1þRh, i þ Raxial
2
This system of equations can be programmed into an iterative loop to solve for all
nodal temperatures, and then any desired quantity.
Consider the relative importance of the axial conduction and the axial advection:
Δx
_ p Δx
Raxial kf πðD2tÞ2 =4 4mc
¼ ¼
RFlow =m_ cp
1
πkf D2i
The axial conductive mechanism becomes more important than the advective flow
resistance when the spacing between nodes becomes sufficiently small.
Workshop 11.3. Solar Pipe in Continuous Mode: Multi-node Model 443
Heat Exchanger Fundamentals
12
The previous chapter focused on the flow of a single stream that exchanges heat
with its environment. This chapter considers the exchange of heat between two
streams at different temperatures separated by a solid barrier. The aim is to develop
a simplified modeling approach that can be used as a preliminary design tool. A
closed-form 2-node model is developed that captures the key relationships between
fluid types, their flow rates and temperatures, and the heat transfer surface between
them. A more detailed model of a specific design configuration (a tube in a tube, or
double-pipe) is developed as a case study for a more detailed investigation.
There are many different configurations in engineering practice, and there are
numerous resources available to obtain more comprehensive treatments of heat
exchangers. In the end, practitioners and designers must learn how to interpret
manufacturer specifications, which can be presented in various forms. A good
fundamental understanding of the key principles involved facilitates that practice.
technically not a heat exchanger because its primary function is to convert chemical
energy into mechanical energy, not to transfer heat from one fluid to another. On the
other hand, the heat picked up by the coolant must be “dissipated” somehow, and
therefore the radiator is a true heat exchanger that transfers the heat picked up in the
engine block to ambient air. The hot coolant that leaves the engine block enters the
radiator and passes through a long pipe (not straight but doubled back and forth)
that has heat transfer fins placed on it (to increase the effective overall heat transfer
coefficient). Air is blown across the fins and heat is transferred from the hot coolant,
through the fins and to ambient. The coolant exits the radiator colder than its inlet
(but hotter than ambient) and returns to perform its main function of keeping the
engine block cool.
Other examples include heat exchangers designed to create high pressure steam
from a high temperature source fluid (i.e., from hot combustion products). These are
widely used for the generation of mechanical power (which can be used to drive an
electric generator) or merely as a means of distributing heat to an industrial process.
After passing through a turbine, the low pressure steam must be condensed in
another heat exchanger that uses ambient air, or river water as the second fluid.
Cooling towers involve evaporation of some condensing water.
A schematic of a typical “water in tube” boiler design is shown in Fig. 12.1.
In contrast, a “fire tube” boiler is one in which hot combustion products flow inside
tubes that are surrounded by liquid water which cause boiling on the outside
surface. The left sketch shows an end view, with hot “air” (i.e., combustion
products are hot, and have thermal properties nearly identical to those of air)
entering from below and encountering a bank of tubes that contain water at a
lower temperature. Heat is transferred from the gas to the tubes and the gases exit
the top at a lower temperature. How much lower depends on many factors such as
thermal properties of both fluids, flow rates of both streams, geometry and thermal
properties of the walls that separate the two fluid streams. The right sketch shows a
side view, with water entering each tube row as a liquid and emerging from the right
as a vapor. In practice, each tube could be delivered fluid with the same inlet
conditions (and the tubes are connected in parallel, as shown in Fig. 12.1), or the
tubes could be connected in series into a single long pipe with multiple passes (with
connections outside the field of view).
H2o(L) H2o(V)
H2o(L) H2o(V)
H2o(L) H2o(V)
Hot“Air” Hot“Air”
Fig. 12.1 Schematic of a boiler section consisting of a bank of tubes in a cross-flow of hot gases
12.2 Double-Pipe Heat Exchangers 447
In the boiler example considered in the previous chapter, the outer fluid was
considered to be at a single temperature (T1) along the entire length of the pipe.
The inner fluid enthalpy changed with position. This case is considered a heat
exchanger, in the sense that heat is exchanged from one fluid to another across a
wall. However, the temperature of only one stream changed with position (for the
preheater and superheater), and the outer fluid temperature was constant along the
entire length of the duct. In contrast, both fluids in a heat exchanger often experi-
ence a significant change in temperature with position, each with an inlet tempera-
ture, and a different outlet temperature. This chapter considers means to estimate
the performance of such engineering devices. There are many designs, but most of
them can be analyzed by the methods developed here, at least approximately.
Broadly, heat exchanger problems are often formulated by specifying all four
temperatures (two inlets, two outlets) and the desired heat transfer rate, and then it
becomes a matter of determining required flow rates, or the size of the heat
exchanger. Alternatively, the flow rates, inlet temperatures, and the size of the
heat exchanger can be specified, and the heat transfer rate and exit temperatures
need to be determined. The key parameter that defines the size of the heat exchanger
is the surface area that separates the two fluids. A large surface area will bring one
or both of the fluids to near thermal equilibrium (thermally long behavior). A small
surface area will exchange heat, but not substantially change the temperature
(thermally short behavior).
Fig. 12.2 Schematic representation of co-flow (left) and counter-flow (right) double-pipe heat
exchangers. Representative temperature profiles (temperature vs. position) are shown below each
schematic for non-phase changing operation
In the counter-flow arrangement, fluid B enters where fluid A exits, and vice
versa, and flows in the opposite direction. Assuming A is the hotter fluid, its
temperature must decrease monotonically from entrance to exit (left to right), as
B increases from its entrance to exit (right to left). At every location along the pipe,
A must be at a higher temperature. The Second Law restriction on A is that it must
exit at a temperature above the inlet of B (not the exit, as in the co-flow case).
Similarly, the exit of B must be below the inlet of A. That restriction yields a
temperature profile that is very different from the co-flow arrangement.
In the co-flow arrangement, the local temperature difference between A and B is
a maximum near the entrance, and decreases along the length of the pipe. In the
counter-flow arrangement, the temperature difference changes less, and in fact can
be a constant throughout the entire length of the pipe.
The heat transfer rate (q, in Watts) between the two fluid streams can be expressed
in a Newton’s Law of Cooling form, namely:
q ¼ U i Ai T A T B
In this expression, the overall heat transfer coefficient Ui is based on the inner
surface area (Ai), but could be based on the outer (or any other surface area).
The temperature difference between the fluids is given as averages, and there are
different possible approaches. The most obvious and easily derived is the average
12.2 Double-Pipe Heat Exchangers 449
mean temperature difference (AMTD) in which the geometric average of the inlet
and outlet fluid temperatures are used. That is:
T Ain þ T Aout T Bin þ T Bout
q ¼ U i Ai AMTD ¼ U i Ai
2 2
This result is the same for the co-flow and counter-flow arrangement. In the next
section, 2-node models will be developed that yield closed-form solutions for the exit
temperatures and heat transfer rates. A differential analysis, not developed here, yields
a similar expression for the heat transfer rate, but with a less intuitive expression for
the averaged temperature difference, called the log mean temperature difference
(LMTD). The LMTD is different for the co-flow and counter-flow arrangements:
q ¼ U i Ai LMTD
where
T A T B ¼ LMTDCOFLOW
ðT Ain T Bin Þ ðT Aout T Bout Þ
¼ h i for co‐flow heat exchangers
ln ððTTAout
Ain T Bin Þ
T Bout Þ
T A T B ¼ LMTDCOUNTERFLOW
ðT Ain T Bout Þ ðT Aout T Bin Þ
¼ h i for counter‐flow heat exchangers
ln ððTT Ain T Bout Þ
Aout T Bin Þ
The three different types of averages are shown for a specific case in Fig. 12.3. The
inlet temperature of A is set at 100 C and the inlet of B is set at 0 C. The exit of A
is set at 50 C, and the average temperature from the three forms is shown as a
function of all possible exit temperatures for B. It is apparent that the AWTD and
LMTDCOUNTER-FLOW give similar results, with significant deviations for the
LMTDCO-FLOW case.
For problems in which all four temperatures are specified, the averaged temper-
ature difference can be calculated upfront. Figure 12.3 shows that the AMTD,
which is easily remembered, can be used for counter-flow arrangements, and that
it is generally preferable to use the LMTD for co-flow arrangements.
The following general problem statement is written for those cases, where the inlet
temperatures and flow rates of both streams are specified, as is the effective heat
transfer coefficient Ui. The exit temperatures and heat transfer rates are to be deter-
mined as a function of total effective length (surface area/perimeter) of the pipe.
450 12 Heat Exchanger Fundamentals
100
Average Temperature Difference (oC) 90 TA,in = 100 ⬚C
TA,out = 50 ⬚C
80
TB, in = 0 ⬚C
70
60
50
40
30
AMTD
20
LMTD: COUNTER-FLOW
10
LMTD: CO-FLOW
0
0 20 40 60 80 100
Exit Temperature of B (oC)
Fig. 12.3 Comparison of averaged temperature differences for the case, where fluid A enters at
100 C and exits at 50 C, and fluid B enters at 0 C. The average mean temperature difference
(AMTD) and two log mean temperature difference (LMTD) expressions are shown for all possible
exit temperatures of fluid B. Note that for the co-flow arrangement fluid B cannot exit at a higher
temperature than the exit of A (50 C in this case)
Invoking a 1-node model for each fluid stream, and using a well-mixed model, a
closed-form solution for the exit temperatures can be obtained. A thermal resistance
model (Fig. 12.4) indicates that heat exchange between the two fluids takes place
12.2 Double-Pipe Heat Exchangers 451
Fig. 12.4 Thermal resistance network for the 2-node heat exchanger model
with an overall heat transfer coefficient (U ) based on a defined area of the wall
separating the streams. The overall heat transfer coefficient for the double-pipe
arrangement, referenced to the inner surface area of the pipe is defined by the three
thermal resistances in series between the two fluids (convection at the inner wall,
conduction across the wall of thickness t, and convection at the outer wall):
1 1
Ui πDi L ¼ ¼
Rinner þ Rwall þ Router 1
þ t
þ 1
hinner πDi L kπ ðDi þtÞL houter π ðDi þ2tÞL
where the thin-wall approximation has been used (the exact formula for conduction
across a cylindrical shell could be used instead). Solving for the overall heat transfer
coefficient:
1
Ui ¼ 1
hinner þ tDi
kðDi þtÞ þ houter ðDDi i þ2tÞ
The temperatures in the heat transfer terms represent the average temperatures in
each section. Treating the two inlet temperatures, mass flow rates and specific heats
as inputs, there are four unknown temperatures for these two equations (two exit
temperatures and two average temperatures).
Invoking the well-mixed model, the average temperature of the fluid in the pipe
is set equal to the exit temperature, adding two more equations to close the set. This
model will underestimate the average temperature difference between the
two streams, and therefore the model underestimates the total heat transfer rate.
Dividing each equation by the mass flow rate and specific heat, and rearranging:
U i Ai U i Ai
T Aout 1þ ¼ T Ain þ T Bout
m_ A cpA m_ A cpA
U i Ai U i Ai
T Bout 1 þ ¼ T Bin þ T Aout
m_ B cpB m_ B cpB
U i Ai U i πDi L L
L^ A ¼ ¼ ¼
m_ A cpA m_ A cpA Lt, A
U i Ai U i πDi L L
L^ B ¼ ¼ ¼
m_ B cpB m_ B cpB Lt, B
Notice that there are two thermal lengths, one for each stream. The longer of the two
(with the lower thermal flow rate) is considered the controlling stream because it is
the closest to achieving thermal equilibrium with its partner, and its value is
referred in practice as number of transfer units (NTU). Combining the two nodal
equations:
^
^ T Bin þ L^ B T Aout
T Aout 1 þ L A ¼ T Ain þ L A
1 þ L^ B
Rearranging:
^ L^ B L^ B L^ A
T Aout 1 þ L A ¼ T Ain þ T Bin
1 þ L^ B 1 þ L^ B
12.2 Double-Pipe Heat Exchangers 453
The heat transfer rate between the two streams is obtained from one of three
forms:
The heat exchanger effectiveness is defined as the actual heat transfer rate
normalized by the maximum possible heat transfer rate. The maximum possible
heat transfer rate of either stream is that which would occur if the stream exited at
the inlet temperature of the other stream. That is:
The quantity (ṁcp) is considered to be a thermal mass flow rate. The smaller of
these defines the maximum possible heat transfer rate. A higher heat transfer rate
would cause the other stream to overshoot the inlet of the other, in violation of the
second Law. That is:
_ p min ðT Ain T Bin Þ
qmax ¼ mc
q
ε¼
qmax
This 2-node model can give surprisingly good results, and it can be applied to any
heat exchanger type (when properly interpreted). However, it cannot distinguish
between co-flow and counter-flow behavior. The well-mixed model was used
because it works well across all ranges of flow. If, as is common, the inlet and
exit temperatures and mass flow rates of one stream are specified, then the geomet-
ric average temperature can be used instead, and then the required mass flow of the
other stream and the effective UA required can be determined more directly.
The NTU method is commonly used in design calculations, where NTU is a
dimensionless measure of the effective length of a double-pipe heat exchanger,
defined as the longer of the two thermal lengths:
UA
NTU ¼ ¼ L^ max
_ p min
mc
454 12 Heat Exchanger Fundamentals
1
0.9
(m. cp )min
Heat Exchanger Effectiveness,ε
0.8 C= =0
(m. cp )max
0.7 0.25
0.6 0.5
0.75
0.5
1
0.4
0.3
0.2
0.1
0
0 1 2 3 4 5 6
NTU
Fig. 12.5 Heat exchanger effectiveness vs. number of transfer units (NTU) (longer of the two
thermal lengths) for 2-node well-mixed heat exchanger for selected values of the ratio of the
thermal mass flow rate
The heat exchanger effectiveness is plotted against pipe length (as NTU) in
Fig. 12.5 for fixed ratios of the minimum to maximum thermal flow rates (C) for
the 2-node well-mixed heat exchanger model: Use of this plot will give good initial
estimates of heat exchanger performance, and reveal key trends that can guide
design decisions. For example, for a situation where the thermal mass flow rates of
the two streams are comparable (C ¼ 1), then there is no need to select a heat
exchanger with an NTU of greater than approximately 2. The uncertainty in
estimating UA is generally considerable in any case.
The results and temperature profiles for three cases are considered in which the
temperature of the hotter fluid enters at 100 C and the colder fluid enters at 0 C.
The calculated average temperatures for the appropriate model are shown below the
plot of temperature vs. position. In the first case (Fig. 12.6 with NTU ¼ 1, C ¼ 0),
the effectiveness is 0.5, and the co-flow and counter-flow results are identical. The
cold exhibits high flow, or thermally short, behavior. Its temperature does not
change in the heat exchanger, and the direction of flow does not influence the
response of the hotter fluid. For longer heat exchangers (higher NTU) but with
C ¼ 0, the exit temperature of the hotter fluid will be closer to the cold fluid, but the
shapes will be similar to this case.
Figure 12.7 shows a case with a longer heat exchanger (NTU ¼ 3) and with the
thermal mass flow rate of the hotter fluid half that of the colder fluid (C ¼ 0.5). In
this case, both fluid temperatures change, but the hotter fluid changes more due to
its lower thermal flow rate. The counter-flow temperature profiles are not parallel,
12.2 Double-Pipe Heat Exchangers 455
NTU= 1
C=0
ε= 0.5
CO-FLOW COUNTER-FLOW
x TA (oC) TB (oC) x TA (oC) TB (oC)
0 100 0 0 100 0
1 50 0 1 50 0
100 100
90 CO-FLOW 90 COUNTER-FLOW
Temperature (oC)
Temperature (oC)
80 80
70 70
60 60
50 50
40 40
30 30
20 20
10 10
0 0
0 0.5 1 0 0.5 1
AMTD 75 oC AMTD 75 oC
LMTD 72.13 oC LMTD 72.13 oC
Fig. 12.6 Temperature profiles from the well-mixed 2-node model for the case of NTU ¼ 1
(thermal length of hotter fluid), and C ¼ 0 (infinite thermal flow rate of colder fluid, or thermal
length of zero)
and the restriction of the well-mixed model does not allow the exit of the cold fluid
to exceed the exit of the hotter.
Figure 12.8 shows a case with a very long heat exchanger (NTU ¼ 6) and with
equal thermal flow rates of the two streams (C ¼ 1). In this case, the exit streams of
both streams are close together. In the counter-flow case, the temperature profiles
are parallel (which will be true for all cases with C ¼ 1), and the temperature
difference is the same along the entire length of the pipe. The response of either
stream is that of a constant heat flux.
The well-mixed model forces the outlet temperature of each stream to be equal
to the average temperature. Therefore, the outlet temperature of the hotter stream
must be greater than the outlet temperature of the colder stream. For this reason, for
very long heat exchangers, the well-mixed model is better suited to the co-flow
arrangement than the counter-flow arrangement, in which case the exit of the colder
fluid can exceed the exit of the hotter fluid.
The model considered next is a better model for the counter-flow case, where the
thermal mass flow rates are comparable, but the length is sufficiently long that the
exit of the cold fluid is significantly higher than the inlet of the hotter fluid.
456 12 Heat Exchanger Fundamentals
NTU=3
C = 0.5
ε= 0.545
CO-FLOW COUNTER-FLOW
x TA (oC) TB (oC) x TA (oC) TB (oC)
0 100 0 0 100 27.27
1 45.45 27.27 1 45.45 0
100 100
90 CO-FLOW 90 COUNTER-FLOW
Temperature (oC)
Temperature (oC)
80 80
70 70
60 60
50 50
40 40
30 30
20 20
10 10
0 0
0 0.5 1 0 0.5 1
Fig. 12.7 Temperature profiles from the well-mixed 2-node model for the case of NTU ¼ 3
(thermal length of hotter fluid), and C ¼ 0.5 (thermal flow rate of hotter fluid half that of colder fluid)
The well-mixed model underestimates the heat transfer rate, but has the advantage
of not violating the Second Law of Thermodynamics. It is expected to work better
for co-flow arrangements than counter-flow arrangements. As with the well-mixed
model, the heat transfer rate can be expressed three different ways, based on the
direct heat transfer, or as the thermodynamic change:
_ p A ðT Ain T Aout Þ ¼ mc
q ¼ UA T A T B ¼ mc _ p B ðT Bout T Bin Þ
For the average temperature model, the temperature difference is expressed as the
geometric average of the temperature difference at the inlet and that at the outlet.
Expressing that difference in the form for the counter-flow arrangement:
1
T A T B ¼ ½ðT Ain T Bout Þ þ ðT Aout T Bin Þ
2
Expressing this difference for the co-flow arrangement yields the same result.
Algebraic manipulation (a good exercise) results in the following expression for
12.2 Double-Pipe Heat Exchangers 457
NTU=6
C=1
ε= 0.461
CO-FLOW COUNTER-FLOW
x TA (oC) TB (oC) x TA (oC) TB (oC)
0 100 0 0 100 46.15
1 53.85 46.15 1 53.85 0
100 100
90 CO-FLOW 90 COUNTER-FLOW
Temperature (oC)
Temperature (oC)
80 80
70 70
60 60
50 50
40 40
30 30
20 20
10 10
0 0
0 0.5 1 0 0.5 1
Fig. 12.8 Temperature profiles from the well-mixed 2-node model for the case of NTU ¼ 6 (thermal
length of hotter fluid) and C ¼ 1 (thermal flow rate of hotter fluid equal to that of colder fluid)
the outlet temperature of A in terms of the inlet temperatures and the two thermal
lengths, defined as with the well-mixed model.
2 þ L^ B L^ A T Ain þ 2L^ A T Bin
T Aout ¼
2 þ L^ A þ L^ B þ L^ A L^ B
2 L^ B T Bin þ L^ B ðT Ain T Aout Þ
T Bout ¼
2 þ L^ B
The outlet of B is expressed in terms of the outlet for A, which must therefore be
calculated first. The effectiveness of the heat exchanger as a function of the NTU
(longer of the two thermal lengths) for various ratios of the thermal flow rates (C) is
shown in Fig. 12.9 which exhibits the same general shape as the well-mixed model.
However, for lower values of C, the heat exchanger effectiveness exceeds unity, in
violation of the Second Law. This result should not be surprising, based on the
limiting case for a single stream model from the previous chapter. For that reason,
this model should be used with caution.
One temperature profile case is shown in Fig. 12.10, with NTU ¼ 3 and C ¼ 1.
The exit temperature of the hotter fluid is lower than the exit of the colder fluid. This
behavior violates the second Law for the co-flow arrangement but is acceptable for
the counter-flow arrangement.
1.5
1.4
1.3
.
(m c p)min
Fig. 12.9 Heat exchanger effectiveness vs. NTU (longer of the two thermal lengths) for 2-node
average temperature heat exchanger model for selected values of the ratio of the thermal mass
flow rate. Cases that exhibit an effectiveness greater than unity violate the Second Law of
Thermodynamics
NTU=3
C=1
ε= 0.882
CO-FLOW COUNTER-FLOW
x TA (oC) TB (oC) x TA (oC) TB (oC)
0 100 0 0 100 52.94
1 11.76 52.94 1 11.76 0
100 100
90 CO-FLOW 90 COUNTER-FLOW
Temperature (oC)
Temperature (oC)
80 80
70 70
60 60
50 50
40 40
30 30
20 20
10 10
0 0
0 0.5 1 0 0.5 1
Fig. 12.10 Temperature profiles from the average temperature 2-node model for the case of
NTU ¼ 3 (thermal length of hotter fluid ¼ 3) and C ¼ 1 (thermal flow rate of hotter fluid equal to
that of colder fluid). The co-flow case violates the Second Law of Thermodynamics
12.2 Double-Pipe Heat Exchangers 459
Fig. 12.11 Thermal resistance model for node “i” in the co-flow (top) and counter-flow (bottom)
arrangements. The well-mixed model is used (in which the average temperature of each fluid is set
equal to the exit temperature from that cell)
460 12 Heat Exchanger Fundamentals
equals the average temperature used to calculate the heat exchange between the
corresponding fluid B cell) is:
where Ui is an overall heat transfer coefficient based on the inner surface area.
Rearranging for TAi (a form suitable for Method of Successive Substitution, with
superscript “k” to indicate iteration number):
ðk Þ ðkÞ
ðkþ1Þ m_ A cpA T A, i1 þ U i πDi ΔxT Bi
T Ai ¼
m_ A cpA þ U i πDi Δx
ðkÞ ðkÞ
ðkþ1Þ m_ B cpB T B, i1 þ U i πDi ΔxT Ai
T Bi ¼ ðco‐flow arrangementÞ
m_ B cpB þ Ui πDi Δx
For the counter-flow arrangement, with fluid A flowing left to right and B flowing
right to left, the nodal equation for fluid B must recognize that the flow term
entering the cell comes from the right (TB+1) and the nodal equation is:
ðkÞ ðkÞ
ðkþ1Þ m_ B cpB T B, iþ1 þ Uinner πDinner ΔxT Ai
T Bi ¼ ðcounter‐flow arrangementÞ
m_ B cpB þ U inner πDinner Δx
• In a worksheet entitled “params,” write a separate block for input parameters (from
problem statement) that a user can change, and a block for relevant derived
parameters. Add a block to display final results (that confirms convergence).
Consider inner and outer convection coefficients to be input parameters (but
separate worksheets could be used to calculate them based on Nusselt number
correlations).
Workshop 12.1. Double-Pipe Heat Exchangers 461
• In a worksheet1 entitled “Iterations_co-flow,” for the heat exchanger broken into ten
equal sized sections, define a row with ten columns for fluid A and ten columns for
fluid B. Enter the inlet fluid temperatures as initial “guessed” values (reference to
“params”). In the next row, enter the recursion formulas for the fluid temperatures
that reference the row above it. Add two columns to check for convergence of the exit
streams. Copy this iterative row as far as needed to obtain a reasonable convergence.
• Copy the “Iterations_co-flow” worksheet, rename it “Iterations_counter-flow”
and modify it for the counter-flow arrangement.
• In a worksheet entitled “Results” lay out a block for the heat exchanger with four
rows of temperatures (fluid A, inner wall, outer wall, fluid B) for co-flow.
Reference the fluid temperatures to the final converged values from “iterations”
and enter voltage divider formulas for the wall temperatures. Repeat for counter-
flow. Make well-formatted plots of all four temperatures vs. position for both
arrangements (Figs. 12.12, 12.13, 12.14, 12.15, 12.16, 12.17, 12.18, 12.19,
12.20, 12.21, 12.22, 12.23, 12.24, and 12.25).
• Use the worksheet as a design tool. . .
CO-FLOW ARRANGEMENT
Max Change = 0.00E+00
dx=0.1 m
node 1 2 3 4 5 6 7 8 9 10
x 0 0.05 0.15 0.25 0.35 0.45 0.55 0.65 0.75 0.85 0.95 1
TA 100.00 91.67 84.72 78.93 74.11 70.09 66.74 63.95 61.63 59.69 58.07
Tinner 40.44 42.03 43.36 44.47 45.39 46.16 46.80 47.33 47.78 48.15 48.46
Touter 39.71 41.42 42.85 44.05 45.04 45.87 46.55 47.13 47.61 48.01 48.34
TB 0.00 8.33 15.28 21.07 25.89 29.91 33.26 36.05 38.37 40.31 41.93
COUNTER-FLOW ARRANGEMENT
Max Change = 0.00E+00
dx=0.1 m
node 1 2 3 4 5 6 7 8 9 10
x 0 0.05 0.15 0.25 0.35 0.45 0.55 0.65 0.75 0.85 0.95 1
TA 100.00 95.24 90.48 85.71 80.95 76.19 71.43 66.66 61.90 57.14 52.38 52.38
Tinner 68.80 66.88 62.11 57.35 52.59 47.83 43.06 38.30 33.54 28.78 24.02 24.02
Touter 68.42 66.53 61.77 57.01 52.24 47.48 42.72 37.96 33.19 28.43 23.67 23.67
TB 47.62 47.62 42.86 38.10 33.34 28.57 23.81 19.05 14.29 9.52 4.76 0.00
Fig. 12.12 Worksheet entitled “Results” which checks for convergence, reports the converged
fluid temperatures and calculates the surface temperatures of the inner pipe
A A A A A A A A A A B B B B B B B B B B
check A check B 1 2 3 4 5 6 7 8 9 10 1 2 3 4 5 6 7 8 9 10
100 100 100 100 100 100 100 100 100 100 0 0 0 0 0 0 0 0 0 0
9.092581 9.092581 90.9 90.9 90.9 90.9 90.9 90.9 90.9 90.9 90.9 90.9 9.1 9.1 9.1 9.1 9.1 9.1 9.1 9.1 9.1 9.1
7.43908 7.43908 91.7 83.5 83.5 83.5 83.5 83.5 83.5 83.5 83.5 83.5 8.3 16.5 16.5 16.5 16.5 16.5 16.5 16.5 16.5 16.5
6.086271 6.086271 91.7 84.9 77.4 77.4 77.4 77.4 77.4 77.4 77.4 77.4 8.3 15.1 22.6 22.6 22.6 22.6 22.6 22.6 22.6 22.6
4.979473 4.979473 91.7 84.7 79.2 72.4 72.4 72.4 72.4 72.4 72.4 72.4 8.3 15.3 20.8 27.6 27.6 27.6 27.6 27.6 27.6 27.6
4.073948 4.073948 91.7 84.7 78.9 74.5 68.3 68.3 68.3 68.3 68.3 68.3 8.3 15.3 21.1 25.5 31.7 31.7 31.7 31.7 31.7 31.7
3.333094 3.333094 91.7 84.7 78.9 74.0 70.6 65.0 65.0 65.0 65.0 65.0 8.3 15.3 21.1 26.0 29.4 35.0 35.0 35.0 35.0 35.0
2.726965 2.726965 91.7 84.7 78.9 74.1 70.0 67.4 62.3 62.3 62.3 62.3 8.3 15.3 21.1 25.9 30.0 32.6 37.7 37.7 37.7 37.7
2.231062 2.231062 91.7 84.7 78.9 74.1 70.1 66.6 64.7 60.0 60.0 60.0 8.3 15.3 21.1 25.9 29.9 33.4 35.3 40.0 40.0 40.0
1.82534 1.82534 91.7 84.7 78.9 74.1 70.1 66.8 63.7 62.5 58.2 58.2 8.3 15.3 21.1 25.9 29.9 33.2 36.3 37.5 41.8 41.8
Fig. 12.13 Worksheet entitled “iterations_co-flow” which shows the first few rows of the
iteration. A similar worksheet “iterations_counter-flow” is not shown
1
It is advised to set up this iteration table in the “params” worksheet, and once it is working and
debugged, cut and paste it to its own sheet. Alternatively, name key cells in “params” and use the
named cells in the formulas.
462 12 Heat Exchanger Fundamentals
INPUT PARAMETERS
L= 1 m pipe length
rhoA= 1000 kg/m^3 density of A
cpA = 4200 J/kg/K specific heat of A
rhoB= 1000 kg/m^3 density of B
cpB= 4200 J/kg/K specific heat of B
Dinner = 0.02 m inner diameter of inner pipe
t= 0.005 m pipe thickness
D= 0.2 m inner diameter of outer pipe
k= 40 W/m/K thermal conductivity of pipe
AV,A= 8.91E-06 m^3/s volumetric flow rate of A
AV,B= 8.91E-06 m^3/s volumetric flow rate of B
Tain= 100 oC inlet temperature of A
Tbin= 0 oC inlet temperature of B
hinner = 1000 W/m2/K inner convection coefficient
houter = 1000 W/m2/K outer convection coefficient
DERIVED PARAMETERS
dx= 0.1 m length of numerical segment (for 10 section grid)
Rinner = 0.159155 oC/W thermal resistance between A and inner wall
Rwall= 0.001941 oC/W thermal resistance across pipe wall
Router= 0.106103 oC/W thermal resistance between B and outer wall
Uinner= 595.6416 W/m2/K overall heat transfer coefficient
mdotA= 8.91E-03 kg/s mass flow rate of A
mdotB = 8.91E-03 kg/s mass flow rate of B
(mdot*cp)A= 3.74E+01 oC/W Flow capacitance of A
(mdot*cp)B= 3.74E+01 W/K Flow capacitance of B
LthermalA= 0.999798 m thermal length of A
LthermalB= 0.999798 m thermal length of B
A= 1.000202 L/LthermalA, dimensionless length of A
B= 1.000202 L/LthermalB, dimensionless length of B
qmaxA = 3741.77 W maximum possible heat transfer rate of A
qmaxB = 3741.77 W maximum possible heat transfer rate of B
qmax 3741.77 W maximum possible heat transfer rate
NTU= UA/Cmin 1.00 "Number of Transfer Units" = Longer of the 2 thermal lengths
Cmin/Cmax= 1.00 ratio of thermal lengths
AV,A= 5.35E-01 LPM volumetric flow rate of A
AV,B= 5.35E-01 LPM volumetric flow rate of B
Lt,A= 0.999798 m Thermal length of A
Lt,B= 0.999798 m Thermal length of B
AREA= 0.062832 m^2 Inner Surface Area
Fig. 12.14 Parameters for the base case: 1 m long water to water heat exchanger with thermal
lengths equal unity
Workshop 12.1. Double-Pipe Heat Exchangers 463
120
TA
100 Tinner
Touter
80 TB
Temperature (oC)
60
40
20
0
0 0.2 0.4 0.6 0.8 1
Axial Position (m)
CO-FLOW
120
TA
100
Tinner
Touter
80
Temperature (oC)
TB
60
40
20
0
0 0.2 0.4 0.6 0.8 1
Axial Position (m)
COUNTER-FLOW
Fig. 12.15 Temperature profiles for base case water to water heat exchanger with unity thermal
lengths
464 12 Heat Exchanger Fundamentals
INPUT PARAMETERS
L= 2 m pipe length
rhoA= 1000 kg/m^3 density of A
cpA = 4200 J/kg/K specific heat of A
rhoB= 1000 kg/m^3 density of B
cpB= 4200 J/kg/K specific heat of B
Dinner = 0.02 m inner diameter of inner pipe
t= 0.005 m pipe thickness
D= 0.2 m inner diameter of outer pipe
k= 40 W/m/K thermal conductivity of pipe
AV,A= 8.91E-06 m^3/s volumetric flow rate of A
AV,B= 8.91E-06 m^3/s volumetric flow rate of B
Tain= 100 oC inlet temperature of A
Tbin= 0 oC inlet temperature of B
hinner = 1000 W/m2/K inner convection coefficient
houter = 1000 W/m2/K outer convection coefficient
DERIVED PARAMETERS
dx= 0.2 m length of numerical segment (for 10 section grid)
Rinner = 0.079577 oC/W thermal resistance between A and inner wall
Rwall= 0.00097 oC/W thermal resistance across pipe wall
Router= 0.053052 oC/W thermal resistance between B and outer wall
Uinner= 595.6416 W/m2/K overall heat transfer coefficient
mdotA= 8.91E-03 kg/s mass flow rate of A
mdotB = 8.91E-03 kg/s mass flow rate of B
(mdot*cp)A= 3.74E+01 oC/W Flow capacitance of A
(mdot*cp)B= 3.74E+01 W/K Flow capacitance of B
LthermalA= 0.999798 m thermal length of A
LthermalB= 0.999798 m thermal length of B
A= 2.000404 L/LthermalA, dimensionless length of A
B= 2.000404 L/LthermalB, dimensionless length of B
qmaxA = 3741.77 W maximum possible heat transfer rate of A
qmaxB = 3741.77 W maximum possible heat transfer rate of B
qmax 3741.77 W maximum possible heat transfer rate
NTU= UA/Cmin 2.00 "Number of Transfer Units" = Longer of the 2 thermal lengths
Cmin/Cmax= 1.00 ratio of thermal lengths
AV,A= 5.35E-01 LPM volumetric flow rate of A
AV,B= 5.35E-01 LPM volumetric flow rate of B
Lt,A= 0.999798 m Thermal length of A
Lt,B= 0.999798 m Thermal length of B
AREA= 0.125664 m^2 Inner Surface Area
Fig. 12.16 Parameters and results for a pipe length twice that of the base case
Workshop 12.1. Double-Pipe Heat Exchangers 465
120
TA
100 Tinner
Touter
TB
80
Temperature (oC)
60
40
20
0
0 0.5 1 1.5 2
Axial Position (m)
CO-FLOW
120
100 TA
Tinner
Touter
80
Temperature (oC)
TB
60
40
20
0
0 0.5 1 1.5 2
Axial Position (m)
COUNTER-FLOW
Fig. 12.17 Temperature profiles for a pipe length twice as long as the base case
466 12 Heat Exchanger Fundamentals
INPUT PARAMETERS
L= 0.5 m pipe length
rhoA= 1000 kg/m^3 density of A
cpA = 4200 J/kg/K specific heat of A
rhoB= 1000 kg/m^3 density of B
cpB= 4200 J/kg/K specific heat of B
Dinner = 0.02 m inner diameter of inner pipe
t= 0.005 m pipe thickness
D= 0.2 m inner diameter of outer pipe
k= 40 W/m/K thermal conductivity of pipe
AV,A= 8.91E-06 m^3/s volumetric flow rate of A
AV,B= 8.91E-06 m^3/s volumetric flow rate of B
Tain= 100 oC inlet temperature of A
Tbin= 0 oC inlet temperature of B
hinner = 1000 W/m2/K inner convection coefficient
houter = 1000 W/m2/K outer convection coefficient
DERIVED PARAMETERS
dx= 0.05 m length of numerical segment (for 10 section grid)
Rinner = 0.31831 oC/W thermal resistance between A and inner wall
Rwall= 0.003882 oC/W thermal resistance across pipe wall
Router= 0.212207 oC/W thermal resistance between B and outer wall
Uinner= 595.6416 W/m2/K overall heat transfer coefficient
mdotA= 8.91E-03 kg/s mass flow rate of A
mdotB = 8.91E-03 kg/s mass flow rate of B
(mdot*cp)A= 3.74E+01 oC/W Flow capacitance of A
(mdot*cp)B= 3.74E+01 W/K Flow capacitance of B
LthermalA= 0.999798 m thermal length of A
LthermalB= 0.999798 m thermal length of B
A= 0.500101 L/LthermalA, dimensionless length of A
B= 0.500101 L/LthermalB, dimensionless length of B
qmaxA = 3741.77 W maximum possible heat transfer rate of A
qmaxB = 3741.77 W maximum possible heat transfer rate of B
qmax 3741.77 W maximum possible heat transfer rate
NTU= UA/Cmin 0.50 "Number of Transfer Units" = Longer of the 2 thermal lengths
Cmin/Cmax= 1.00 ratio of thermal lengths
AV,A= 5.35E-01 LPM volumetric flow rate of A
AV,B= 5.35E-01 LPM volumetric flow rate of B
Lt,A= 0.999798 m Thermal length of A
Lt,B= 0.999798 m Thermal length of B
AREA= 0.031416 m^2 Inner Surface Area
Fig. 12.18 Parameter values for a pipe length half that of the base case
Workshop 12.1. Double-Pipe Heat Exchangers 467
120
TA
100 Tinner
Touter
TB
80
Temperature (oC)
60
40
20
0
0 0.1 0.2 0.3 0.4 0.5
Axial Position (m)
CO-FLOW
120
TA
100 Tinner
Touter
TB
80
Temperature (oC)
60
40
20
0
0 0.1 0.2 0.3 0.4 0.5
Axial Position (m)
COUNTER-FLOW
Fig. 12.19 Temperature profiles for a pipe length half that of the base case
468 12 Heat Exchanger Fundamentals
INPUT PARAMETERS
L= 1 m pipe length
rhoA= 1000 kg/m^3 density of A
cpA = 4200 J/kg/K specific heat of A
rhoB= 1000 kg/m^3 density of B
cpB= 4200 J/kg/K specific heat of B
Dinner = 0.02 m inner diameter of inner pipe
t= 0.005 m pipe thickness
D= 0.2 m inner diameter of outer pipe
k= 40 W/m/K thermal conductivity of pipe
AV,A= 8.91E-06 m^3/s volumetric flow rate of A
AV,B= 8.91E-05 m^3/s volumetric flow rate of B
Tain= 100 oC inlet temperature of A
Tbin= 0 oC inlet temperature of B
hinner = 1000 W/m2/K inner convection coefficient
houter = 1000 W/m2/K outer convection coefficient
DERIVED PARAMETERS
dx= 0.1 m length of numerical segment (for 10 section grid)
Rinner = 0.159155 oC/W thermal resistance between A and inner wall
Rwall= 0.001941 oC/W thermal resistance across pipe wall
Router= 0.106103 oC/W thermal resistance between B and outer wall
Uinner= 595.6416 W/m2/K overall heat transfer coefficient
mdotA= 8.91E-03 kg/s mass flow rate of A
mdotB = 8.91E-02 kg/s mass flow rate of B
(mdot*cp)A= 3.74E+01 oC/W Flow capacitance of A
(mdot*cp)B= 3.74E+02 W/K Flow capacitance of B
LthermalA= 0.999798 m thermal length of A
LthermalB= 9.997978 m thermal length of B
A= 1.000202 L/LthermalA, dimensionless length of A
B= 0.10002 L/LthermalB, dimensionless length of B
qmaxA = 3741.77 W maximum possible heat transfer rate of A
qmaxB = 37417.7 W maximum possible heat transfer rate of B
qmax 3741.77 W maximum possible heat transfer rate
NTU= UA/Cmin 1.00 "Number of Transfer Units" = Longer of the 2 thermal lengths
Cmin/Cmax= 0.10 ratio of thermal lengths
AV,A= 5.35E-01 LPM volumetric flow rate of A
AV,B= 5.35E+00 LPM volumetric flow rate of B
Lt,A= 0.999798 m Thermal length of A
Lt,B= 9.997978 m Thermal length of B
AREA= 0.062832 m^2 Inner Surface Area
Fig. 12.20 Parameter values with fluid B having ten times the flow rate of the base case
Workshop 12.1. Double-Pipe Heat Exchangers 469
120
TA
100 Tinner
Touter
TB
80
Temperature (oC)
60
40
20
0
0 0.2 0.4 0.6 0.8 1
Axial Position (m)
CO-FLOW
120
100 TA
Tinner
80 Touter
Temperature (oC)
TB
60
40
20
0
0 0.2 0.4 0.6 0.8 1
Axial Position (m)
COUNTER-FLOW
Fig. 12.21 Temperature profiles with fluid B having ten times the flow rate as the base case
470 12 Heat Exchanger Fundamentals
INPUT PARAMETERS
L= 1 m pipe length
rhoA= 1000 kg/m^3 density of A
cpA = 4200 J/kg/K specific heat of A
rhoB= 1000 kg/m^3 density of B
cpB= 4200 J/kg/K specific heat of B
Dinner = 0.02 m inner diameter of inner pipe
t= 0.005 m pipe thickness
D= 0.2 m inner diameter of outer pipe
k= 40 W/m/K thermal conductivity of pipe
AV,A= 8.91E-06 m^3/s volumetric flow rate of A
AV,B= 8.91E-07 m^3/s volumetric flow rate of B
Tain= 100 oC inlet temperature of A
Tbin= 0 oC inlet temperature of B
hinner = 1000 W/m2/K inner convection coefficient
houter = 1000 W/m2/K outer convection coefficient
DERIVED PARAMETERS
dx= 0.1 m length of numerical segment (for 10 section grid)
Rinner = 0.159155 oC/W thermal resistance between A and inner wall
Rwall= 0.001941 oC/W thermal resistance across pipe wall
Router= 0.106103 oC/W thermal resistance between B and outer wall
Uinner= 595.6416 W/m2/K overall heat transfer coefficient
mdotA= 8.91E-03 kg/s mass flow rate of A
mdotB = 8.91E-04 kg/s mass flow rate of B
(mdot*cp)A= 3.74E+01 oC/W Flow capacitance of A
(mdot*cp)B= 3.74E+00 W/K Flow capacitance of B
LthermalA= 0.999798 m thermal length of A
LthermalB= 0.09998 m thermal length of B
A= 1.000202 L/LthermalA, dimensionless length of A
B= 10.00202 L/LthermalB, dimensionless length of B
qmaxA = 3741.77 W maximum possible heat transfer rate of A
qmaxB = 374.177 W maximum possible heat transfer rate of B
qmax 374.177 W maximum possible heat transfer rate
NTU= UA/Cmin 10.00 "Number of Transfer Units" = Longer of the 2 thermal lengths
Cmin/Cmax= 0.10 ratio of thermal lengths
AV,A= 5.35E-01 LPM volumetric flow rate of A
AV,B= 5.35E-02 LPM volumetric flow rate of B
Lt,A= 0.999798 m Thermal length of A
Lt,B= 0.09998 m Thermal length of B
AREA= 0.062832 m^2 Inner Surface Area
Fig. 12.22 Parameter values with the flow rate of B ten times lower than the base case
Workshop 12.1. Double-Pipe Heat Exchangers 471
120
100
80
Temperature (oC)
TA
60
Tinner
Touter
40 TB
20
0
0 0.2 0.4 0.6 0.8 1
Axial Position (m)
CO-FLOW
120
100
80
Temperature (oC)
TA
60
Tinner
Touter
40 TB
20
0
0 0.2 0.4 0.6 0.8 1
Axial Position (m)
COUNTER-FLOW
Fig. 12.23 Temperature profiles with the flow rate of B ten times lower than the base case
472 12 Heat Exchanger Fundamentals
INPUT PARAMETERS
L= 1 m pipe length
rhoA= 0.946278 kg/m^3 density of A
cpA = 1005 J/kg/K specific heat of A
rhoB= 1000 kg/m^3 density of B
cpB= 4200 J/kg/K specific heat of B
Dinner = 0.02 m inner diameter of inner pipe
t= 0.005 m pipe thickness
D= 0.2 m inner diameter of outer pipe
k= 40 W/m/K thermal conductivity of pipe
AV,A= 3.19E-03 m^3/s volumetric flow rate of A
AV,B= 7.24E-07 m^3/s volumetric flow rate of B
Tain= 100 oC inlet temperature of A
Tbin= 0 oC inlet temperature of B
hinner = 50 W/m2/K inner convection coefficient
houter = 1000 W/m2/K outer convection coefficient
DERIVED PARAMETERS
dx= 0.1 m length of numerical segment (for 10 section grid)
Rinner = 3.183099 oC/W thermal resistance between A and inner wall
Rwall= 0.001941 oC/W thermal resistance across pipe wall
Router= 0.106103 oC/W thermal resistance between B and outer wall
Uinner= 48.35856 W/m2/K overall heat transfer coefficient
mdotA= 3.02E-03 kg/s mass flow rate of A
mdotB = 7.24E-04 kg/s mass flow rate of B
(mdot*cp)A= 3.04E+00 oC/W Flow capacitance of A
(mdot*cp)B= 3.04E+00 W/K Flow capacitance of B
LthermalA= 0.999798 m thermal length of A
LthermalB= 1.000492 m thermal length of B
A= 1.000202 L/LthermalA, dimensionless length of A
B= 0.999508 L/LthermalB, dimensionless length of B
qmaxA = 303.7844 W maximum possible heat transfer rate of A
qmaxB = 303.9953 W maximum possible heat transfer rate of B
qmax 303.7844 W maximum possible heat transfer rate
NTU= UA/Cmin 1.00 "Number of Transfer Units" = Longer of the 2 thermal lengths
Cmin/Cmax= 1.00 ratio of thermal lengths
AV,A= 1.92E+02 LPM volumetric flow rate of A
AV,B= 4.34E-02 LPM volumetric flow rate of B
Lt,A= 0.999798 m Thermal length of A
Lt,B= 1.000492 m Thermal length of B
AREA= 0.062832 m^2 Inner Surface Area
Fig. 12.24 Parameters with air as fluid A, and the flow rate adjusted to achieve a thermal length
of unity in both streams
Workshop 12.1. Double-Pipe Heat Exchangers 473
120
TA
100 Tinner
Touter
TB
80
Temperature (oC)
60
40
20
0
0 0.2 0.4 0.6 0.8 1
Axial Position (m)
CO-FLOW
120
TA
Tinner
100
Touter
TB
80
Temperature (oC)
60
40
20
0
0 0.2 0.4 0.6 0.8 1
Axial Position (m)
COUNTER-FLOW
Fig. 12.25 Temperature profiles with air as fluid A and both flow rates adjusted to achieve a
thermal length of unity
474 12 Heat Exchanger Fundamentals
• The inner and outer convection coefficients for the base case.
• The outlet temperature of the feedwater for the base case.
• The length of the heat exchanger using the well-mixed model and the average
temperature model. Use the latter going forward.
• The filling times (for a 16 oz. coffee) and feedwater exit temperatures required
for the lower coffee serving temperatures.
• Be an entrepreneur and bring this system to market!
Bonus. To tie in concepts from earlier in the course, analyze what happens when the
flow rate is stopped, and the heat exchanger is full of coffee and feedwater. What is
the final equilibrium temperature, and how long does it take to achieve it. Note that
the volume of the annular region (feedwater) was deliberately chosen to be small
compared to the inner region (coffee) so that the coffee would not be TOO cold.
This bonus question should raise a lot of issues with the reliability of the practical
application of this idea.
Evaporation and Mass Transfer
Fundamentals 13
This chapter introduces fundamental mass transfer concepts through the modeling
of the evaporation process that takes place at the free surface of a mug of coffee. An
evaporative heat transfer coefficient, hevap, is defined that can be included in any of
the transient numerical simulations from earlier chapters (i.e., lumped 1-node, few
node, multi-node). Evaporation is driven by concentration gradients, not a temper-
ature difference, and defining an evaporation coefficient this way allows direct
comparison of the relative effects of evaporation, convection, and radiation on the
cooling of the free surface. As will become apparent, this approach makes sense
only for cases when the liquid surface temperature differs significantly from
ambient. The case where the coffee reaches thermal equilibrium with the environ-
ment and the slower evaporation continues is treated differently, and it will be seen
that the coffee attains a temperature below ambient, a form of evaporative cooling.
Specifically, coffee (treated as water and in a quasi-steady state) is at an average
temperature Tcoffee in a cylindrical container of inner diameter D, with a free
surface a distance L below the top rim. Ambient air is at a temperature T1 with a
relative humidity rh. The goal is to estimate the rate of energy transport by the
evaporation process in a Newton’s Law of Cooling form, that is:
where S is the surface area, and Ts is the surface temperature of the water. Compare,
as a function of coffee temperature, the magnitude of this mechanism to the
convection and radiation processes that act in parallel.
13.1 Background
The free surface of the coffee is the only fluid/fluid interface in the cooling mug of
coffee scenario. Something different happens there than at fluid/solid interfaces,
namely, evaporation. Technically, evaporation is not heat transfer; it is mass transfer.
(and rising due to fossil fuel combustion) and many other components in decreasing
concentration.1 These components are considered to be noncondensable, except
under sufficiently low temperatures and/or high pressures, and can be treated
together (in the absence of chemical reactions), with an equivalent molecular
weight of 28.8 kg/kmol.
On the other hand, water vapor is condensable. If humid air is sufficiently cooled
(isobarically), it will condense (at its dew point temperature). The concentration
(expressed as a number per unit volume, mole fraction, or mass fraction) of water
vapor in humid air is variable and limited by the liquid/vapor phase change
properties of water. Dalton’s Law defines partial pressures for gas mixtures, in
which each component of the mixture exerts a pressure on the walls of the vessel as
if the other components did not exist. The total pressure is the sum of the partial
pressures. The partial pressure exerted by water vapor in humid air is shown as a
function of temperature in Fig. 13.2 for several values of the relative humidity. The
partial pressure exerted by water vapor for 100 % relative humidity air corresponds
to the saturation pressure, that is, the pressure at which pure water would boil for a
given temperature. Relative humidity curves are simple fractions of that curve.
For nominal room temperature air (say 25 C at 1 atm total pressure), the partial
pressure exerted by water vapor in 100 % humid air is only 0.025 atm. If a drop of
1
0.9
0.8
Partial Pressure of HOv (atm)
0.7
0.6
0.5 Relative Humidity = 100%
80%
0.4 60%
0.3 40%
20%
0.2
0.1
0
0 10 20 30 40 50 60 70 80 90 100
Temperature (oC)
Fig. 13.2 Saturation (vapor) pressure of water as a function of temperature between the normal
freezing and boiling points (0 and 100 C) for various values of relative humidity. The saturation
curve (100 % relative humidity) is formed from a fit of the form P ¼ AeB/T (consistent with the
Clausius–Clapeyron equation) using tabulated points at 25 and 100 C
1
http://en.wikipedia.org/wiki/Atmosphere_of_Earth, accessed 19 November 2010.
478 13 Evaporation and Mass Transfer Fundamentals
liquid water were added, that drop will simply fall to the floor of the container, and
none of it would evaporate. However, if that initial 100 % relative humidity air at
25 C were heated at constant total pressure to, say, 70 C, it would exert the same
partial pressure, but would now correspond to a relative humidity of less than 20 %.
At the higher temperature, the water vapor is capable of exerting a much higher
partial pressure, but the amount of water vapor is fixed by what was initially
present. If a drop of liquid water were now added, that liquid would evaporate,
raising the relative humidity. More liquid water could be added, and it would
continue to evaporate until the partial pressure of water was 0.3 atm, at which
point the air would be saturated.
Consider the scenario in Fig. 13.3 in which hot coffee is poured into a container
and a lid is suddenly placed on it, trapping room air. The sketch on the left shows
the situation immediately after placing the lid. The sketch on the right shows the
situation after some period of time long enough that the air becomes saturated
(right), but short enough that the coffee is still hot. There is a vent hole that allows
the total pressure to remain atmospheric and therefore room air can flow in, or the
vapor/air mixture inside can flow out, depending on the circumstances. The trapped
air starts with the same humidity as the ambient air, which is less than or equal to
100 %. Inside the mug, there are two regions in different phases, namely, a liquid
(coffee, shown as solid black), and a gas above it, which is a mixture of water
molecules (big dots) and air molecules (small dots). The air will naturally be
warmed to a value between the coffee temperature and ambient. A good exercise
would be to estimate its temperature using a resistance network. If the container and
Fig. 13.3 Schematic representation of a container of liquid water with trapped room air immedi-
ately after a lid is placed (left) and after enough time for equilibrium to be established (right)
13.1 Background 479
lid are well insulated, the air temperature will be close to the coffee temperature.
Given time, presumably short compared to the cooling time, enough liquid will
evaporate until the now warm humid air will become saturated.
Figure 13.4 is a close-up snapshot of the dynamic equilibrium associated with
the coffee-free surface, with two water molecules shown with arrows to indicate
their motion. The molecules in the liquid phase are all vibrating, but are held
together by intermolecular forces. Liquid molecules near the free surface, however,
can occasionally vibrate so hard that they break free from their neighbors, and enter
into the gas phase. The higher the temperature of the liquid, the harder they vibrate,
and the more leave in a given time frame. These molecules are evaporating (going
from liquid to gas phase), and the number of them evaporating in a given period of
time increases strongly with liquid temperature.
The water molecules in the gas phase, by contrast, are not heavily influenced by
intermolecular forces, until they experience a collision. They travel in straight lines
until they encounter either an air molecule, another water molecule, the free surface
or the walls of the container. During collisions between molecules, the intermolec-
ular forces are very high, short duration, and repulsive. The collision serves to
redirect both collision partners. Collisions with the free surface of the liquid are
different, however. A water molecule that collides with the free surface can be
absorbed into the liquid phase. Those molecules condense (going from gas to liquid
phase). The number of molecules that condense in a given period of time, then,
depends directly on the number of collisions with the free surface that take place in
that time. It is generally assumed (and justifiable) that a quasi-equilibrium is
quickly established in the near vicinity of the liquid surface in which the rate of
molecules evaporating equals the rate of molecules condensing. Therefore, the
partial pressure of the water vapor molecules is generally assumed to be equal to
the saturation pressure just on the gas side of the free surface.
480 13 Evaporation and Mass Transfer Fundamentals
Fig. 13.5 Schematic representation after the lid is first removed (left) and the subsequent quasi-
steady scenario, with the migratory path of a target molecule shown in red (right)
Figure 13.5 shows the mug just after the lid is removed. Those vapor molecules
that would otherwise have hit the lid and bounced back inside now escape to the
room. The concentration (number density) therefore decreases near the open top of
the container. Those escaping molecules are replaced by molecules from below,
some of which then escape, and a form of “concentration wave” gradually works its
way down toward the free surface of the coffee. At the free surface, molecules from
the liquid continue to evaporate into the gas phase, while gas phase water molecules
that hit the liquid are reabsorbed. The concentration of vapor molecules just above
the coffee surface is therefore maintained at some level near the saturation condi-
tion associated with the coffee surface.
A quasi-steady state situation is achieved (in short order, in practice, compared
to the cooling rate) in which vapor molecules escape at a steady rate. The right
sketch shows the path of an individual vapor molecule, painted red. It starts out near
the free surface and is intermittently redirected at each collision. The average length
of each straight line, called the “mean free path,” is the average distance of travel
between collisions. Eventually, the molecule works its way up and out. The speed
of the molecules is close to the speed of sound (i.e., fast), but the speed that it moves
in the vertical direction is much slower than that. This migration from regions of
high concentration to low concentration is called diffusion and is the fundamental
mechanism required for evaporation to occur.
13.2 Model Development 481
With this backdrop of the basic physics of vapor pressures and diffusion, some
simplified models aimed at quantifying the evaporation rate, and its thermal
implications, are developed.
Consider the original system used to analyze the cooling mug of coffee. The
boundary was placed on the free surface of the mug, and the mass that crossed it,
hence the evaporation, was neglected. That is, it was treated as a closed system, to
which the conservation laws of mass and energy apply. To address the phenomenon
of evaporation, the system must be treated as an open system, that is, one in which
mass crosses the boundary.
The First Law of Thermodynamics for this particular open system is not derived
in detail here. The result, which adds a simple term to account for evaporation to the
lumped capacity model, is:
dT coffee
ðMcÞCoffeeþMug ¼ Q_ FreeSurface þ Q_ sides þ Q_ floor m_ evap
hfg
dt
The heat transfer rate into the system from the free surface, sides, and floor are
appropriate convection and radiation modes of heat transfer. The free surface term,
however, represents the heat transfer between the free surface and ambient, which
acts in parallel to the evaporation process, and can be considered a convective/
radiative mode. The last term, the evaporative cooling term, is the focus of this
chapter. The rate of evaporation, ṁevap, is the rate of evaporation, in kg/s, and
hfg is
the enthalpy of evaporation of water. Water that evaporates enters the free surface
as a liquid, and exits as a vapor, with a higher specific energy content. The energy
required to change the phase has the effect of reducing the energy stored in the
482 13 Evaporation and Mass Transfer Fundamentals
m_ evap
hfg hevap SðT 1 T S Þ
where S ¼ πD2/4 is the area of the free surface of the coffee. Rearranging to define
the evaporative heat transfer coefficient:
m_ evap
hfg
hevap ¼
Sð T 1 T S Þ
This evaporative heat transfer coefficient model really makes the most sense when a
hot liquid is cooling, and the surface temperature of the liquid is substantially
different than ambient. When the coffee temperature equals ambient, evaporation
is not zero, and the coefficient is undefined (divided by zero).
A traditional way to express the mass transfer process, analogous to Newton’s
Law of Cooling, is to define an evaporative coefficient, γevap, that is the
proportionality factor (not necessarily constant) for evaporation driven by a differ-
ence in concentration of the evaporating species, expressible as the mass fraction, Y:
Here, YS is the mass fraction of the evaporating component (water vapor) just
above the surface, and Y1 is that in the free stream (which is where humidity of the
air comes into play). This latter model is more appropriate for a pure evaporation
process, not one in which cooling of the bulk liquid is taking place simultaneously
with the evaporation. That is, the evaporation process after the coffee cools to
ambient (or very close to it). In practice, correlations similar to Nusselt number
correlations are used to determine mass transfer coefficients.
Something surprising happens at steady-state, namely, the coffee temperature
does not equal ambient temperature:
The energy required for evaporation is supplied by heat transfer from the environ-
ment to the coffee. Using a lumped capacity resistance network, this heat transfer
rate can be expressed in terms of an overall heat transfer coefficient, U, based on the
surface area of the mug of coffee:
Q_ FreeSurface þ Q_ sides þ Q_ floor ¼ UA T 1 T coffee, SS ¼ m_ evap
hfg
m_ evap
hfg
T coffee, SS ¼ T 1
UA
13.2 Model Development 483
The only way heat can be transferred to the coffee is if the coffee is at a lower
temperature than ambient. This phenomenon is difficult to measure, but is real, and
is why we sweat.
To model the rate of evaporation, consider a control volume that consists of the
humid air column between the free surface and the exit plane below the rim, shown
in Fig. 13.6. On the bottom of the control volume, at y ¼ 0, the air is assumed to be
at the temperature of the liquid at the surface (not necessarily equal to the bulk
coffee temperature), and with a mass fraction Yv0. An upper limit to Yv0 would be
to assume the air is saturated there. At the top of the control volume, at y ¼ L, the air
has a mass fraction YvL, which has a lower limit defined by the humidity of ambient
room air. Even if the liquid is at ambient temperature, the concentration of water
vapor at the surface is higher than that in the ambient, and a concentration gradient
exists, unless the room is at 100 % relative humidity and the same temperature as
the liquid. The actual concentration of water vapor at the exit plane is generally
higher than that of the ambient air, but air currents from the room tend to make it
equal, in the limit, especially for large values of L. For liquids colder than ambient,
the concentration is lower and water vapor diffuses in and a net condensation
occurs.
m_ evap ðY v0 Y vL Þ
It is further postulated that the evaporation rate varies inversely with the distance
between the two surfaces, L:
1
m_ evap
L
These two effects together make up a gradient, a change in mass fraction over a
distance.
Furthermore, if the surface area (S ¼ πD2/4) is doubled, the evaporation rate is
expected to double, meaning the evaporation rate is proportional to S:
m_ evap S
Now, the more dense the humid air, the more molecules are packed in a given
volume, all of which are diffusing out:
m_ evap ρ
ρSðY v0 Y vL Þ
m_ evap
L
The proportionality factor includes all other effects, most importantly, how easy it
is for molecules to migrate from the concentrated area to the less concentrated area.
In keeping with convention, a diffusion coefficient Dv is introduced:
ρDv S
m_ evap, MODEL 1 ¼ ðY v0 Y vL Þ
L
The SI units of Dv are m2/s. A literature value for the diffusion coefficient of water
vapor into air (at nominal room conditions) is:
Dv ¼ 25:6ð10Þ6 m2 =s
flow leaving the mug, which complicates matters and is addressed in the next
model. A more general expression in terms of a local concentration gradient is:
∂Y v
m_ diffusion ¼ ρDv S
∂y
The negative sign forces the direction of diffusion to be from high to low
concentration.
In Model 1, the gradient of mass fraction is taken as being the overall change in
mass fraction divided by the overall length. Consider the limits. The mass fraction
of vapor just above the free surface cannot exceed the saturation condition:
Y v0 Y SAT , surface
At the exit plane, the mass fraction cannot be lower than ambient:
Y vL Y 1
Both of these limits work in the same direction, namely, to reduce the value of the
concentration difference from the free surface to the exit plane, and therefore:
Y v0 Y vL Y SAT , surface Y 1
For Model 1, the limiting case is considered, and the inequality is treated as an
equality.
The Appendix details the calculation of mass fractions for this case. The mass
fractions are directly related to the partial pressure exerted by the vapor, and
therefore are very sensitive to temperature.
Model 1 Results
Results of model predictions are presented for a base case, with parameter values
shown in Fig. 13.7. The mug has an 8.93 cm inner diameter (D) and it is filled with
coffee at various temperatures in a room with air at 25 C and a 70 % relative
humidity. The amount of coffee added is also varied, and therefore the distance
from the free surface to the exit plane (the air cylinder height, L, which is the
distance water must diffuse to exit the mug).
The semi-logy plot shows the evaporation rate as a function of instantaneous
coffee temperature for several values of the air cylinder length, L. At a fixed value
of L, the evaporation rate is zero at a temperature somewhat below ambient
(approximately 19 C). This temperature is the dew point temperature and
corresponds to the condition in which the mass fraction of vapor on the free surface
is equal to the mass fraction in the ambient. The evaporation rate increases sharply
as the temperature moves away from the dew point on both sides. At lower
temperatures, however, the evaporation rate is negative (which cannot be plotted
on semi-log axes so the absolute value is shown), indicating that water vapor is
diffusing into the mug and condensing. At ambient temperature, the evaporation
rate is not zero because the room air has a relative humidity less than 100 %.
486 13 Evaporation and Mass Transfer Fundamentals
INPUT PARAMETERS
D 0.0893 m mug inner diameter
L VARY m distance from free surface to exit plane
Pinf 1.013E+05 N/m2 atmospheric pressure
Tinf 25 oC ambient temperature
rh 0.7 relative humidity of ambient
PHYSICAL CONSTANTS
Dv 2.56E-05 m2/s Diffusion coefficient (water vapor into air)
DA 2.06E-05 Diffusion coefficient (air into itself)
hfg 2.33E+06 J/kg Heat of Vaporization of water
A 9.1496E+10 N/m2 CLAUSIUS-CLAPYRON CONSTANTS FOR WATER
B -5.1152E+03 K B
(T + 273)
DERIVED PARAMETERS Psat (T ) = Ae
S 0.00626315 m^2 Free Surface Area
Xinf 0.0222 mol fraction of ambient
Yinf 0.0138 mass fraction of ambient
rho 1.1857 kg/m3 dry air density
X0,sat 0.0317 saturated surface mol fraction at ambient
Y0,sat 0.0199 saturated surface mass fraction at ambient
Dew Point 18.93 oC Dew Point temperature
1.E-04
L = 0.001 m
ambient
1.E-05
0.02
ABS(Evaporation rate) (kg/s)
0.04
1.E-06
0.06
0.08
1.E-07 0.10
1.E-08
1.E-09
1.E-10
0 20 40 60 80 100
Coffee Temperature (oC)
Fig. 13.7 Evaporation rate for Model 1 (pure diffusion) as a function of coffee temperature for
various lengths of the air column above the free surface. Below 18.93 C (the dew point), the
evaporation rate is negative
13.2 Model Development 487
There are two parallel means by which water vapor is transported through the air
column. There is diffusion across the concentration gradient, and simultaneously,
there is a bulk flow that carries it. Model 1 does not account for the bulk flow effect.
To do so, it is insightful (and convenient) to view things from the perspective of the
air. In this two-component gas system (air and water vapor), the local mass
fractions of air and water must everywhere account for all species:
Y v þ Y air ¼ 1
dY v dY air
þ ¼0
dy dy
∂Y air
m_ air ¼ 0 ¼ ρDA S þ m_ evap Y air
∂y
488 13 Evaporation and Mass Transfer Fundamentals
The mole fractions are assumed to be uniform in the horizontal direction, and the
partial derivative can be replaced by a total derivative. Separating variables:
dY air m_ evap
¼ dy
Y air ρDA S
Integrating across the entire control volume (from the free surface to the exit plane),
recognizing that the mass flow rate through the column is the evaporation rate and is
independent of position:
YðAL ðL
dY air m_ evap
¼ dy
Y air ρDA S
Y A0 y¼0
Y AL m_ evap
ln ¼ L
Y A0 ρDA S
Expressing the air mass fraction in terms of the vapor mass fractions (using
YA + YV ¼ 1), and rearranging for the evaporation rate:
ρDA S 1 Y vL
m_ evap ¼ ln
L 1 Y v0
In keeping with tradition, it is useful to define a mass transfer number, B0L, not to be
confused with a Biot number, as follows:
1 Y vL
1 þ B0L
1 Y v0
The two subscripts refer to the two boundaries (coffee surface and exit plane).
Performing some algebra:
1 Y vL 1 Y v0 Y v0 Y vL
B0L ¼ ¼
1 Y v0 1 Y v0 1 Y v0
ρDA S
m_ evap ¼ lnð1 þ B0L Þ
L
where
Y v0 Y vL
B0L ¼
1 Y v0
13.2 Model Development 489
10
1
0.001 0.01 0.1 1 10 100 1000
0.1 B, Mass Transfer Number
0.01
0.001
The mass transfer number is useful since ln(1) ¼ 0, and the evaporation rate is zero
for B ¼ 0, is positive for B > 0, corresponding to evaporation, and negative for
B < 0, corresponding to condensation. Furthermore, there is a useful limit for low
values of B, namely:
lim lnð1 þ BÞ ¼ B
B!0
As shown in Fig. 13.8, this limit is valid for B < 0.1, approximately.
To make quantitative predictions, the mass fractions must be estimated. Consid-
ering the limits, the mass fraction of vapor just above the free surface cannot exceed
the saturation condition:
Y v0 Y SAT , surface
At the exit plane, the mass fraction cannot be lower than ambient:
Y vL Y 1
Both of these limits work in the same direction, namely, to reduce the value of the
transfer number, so it can be stated that:
Y SAT , surface Y 1
B0L
1 Y SAT , surface
A diffusion coefficient for air into humid air is different from the diffusion coeffi-
cient of water vapor into humid air, namely:
DA ¼ 20:6ð10Þ6 m2 =s
490 13 Evaporation and Mass Transfer Fundamentals
100
10
B=0
B<0 B>0
Abs(B0inf) Number
Ambient
0.1
0.01
0.001
0 10 20 30 40 50 60 70 80 90 100
Coffee Temperature (°C)
Fig. 13.9 Mass transfer number (B) as a function of coffee temperature, assuming saturation
conditions at the coffee surface, and ambient conditions at the exit plane
Model 2 Results
The results of Model 2 presented assume the mass fraction limits hold in evaluating
the B number. The accuracy of that assumption is expected to improve as the
distance between the free surface and exit plane (L) increases. Figure 13.9 shows
the absolute value of the mass transfer number (B) as a function of coffee tempera-
ture on a semi-logy scale. At approximately 18.5 C, the B number is zero (as is
ln(1 + B)), corresponding to the mass fraction on the free surface taking on the
ambient value. This temperature corresponds to the dew point temperature of the
ambient air, that is, the temperature at which water would begin to condense
on isobaric cooling. The B number (and therefore ln(1 + B)) is negative below the
dew point, and it is positive above. Negative evaporation rates correspond to
condensation.
The B number increases by over two orders of magnitude between 30 and 90 C.
Above 90 C, it turns sharply upward as the mass fraction at the surface (YSAT,0)
approaches unity, and the denominator goes to zero. In this calculation, the surface
temperature is set at a particular value. The evaporation process has a cooling effect
on the surface of the coffee, and it becomes more difficult to maintain the surface
temperature the closer to the boiling point. To demonstrate that effect, consider the
13.2 Model Development 491
boundary condition at the coffee surface, where the heat transfer to the surface from
the adjacent fluid is modeled with heat transfer coefficients:
hs, coffee S T coffee T S þ m_ evap
hf ¼ hs, air SðT S T ambient Þ
þ m_ evap hg ðsurface energy balanceÞ
Assuming the heat transfer coefficient between the surface and coffee is much
greater than that between the surface and ambient air (hs,coffee hs,air):
m_ evap
hfg
T S ¼ T coffee
hs, coffee S
The source of the energy required for the evaporation process is heat transfer from
the adjacent fluids, and therefore the surface temperature is below what it would be
in the absence of evaporation. As the boiling point is approached, the evaporation
rate increases to very large values (as the mass fraction of vapor approaches unity).
Figure 13.10 compares the evaporation rates for the pure diffusion model with the
advection/diffusion model for the base case (with L ¼ 0.05 m), with the evaporation
1.E-04
1.E-05
ABS(Evaporation Rate) (kg/s)
Advection/Diffusion Model
1.E-06
1.E-07
Pure Diffusion Model
1.E-08
Model 2
1.E-09
Model 1
1.E-10
0 20 40 60 80 100
Coffee Temperature (°C)
Fig. 13.10 Comparison of the evaporation rate from the pure diffusion and advection/diffusion
models
492 13 Evaporation and Mass Transfer Fundamentals
rate plotted against coffee temperature. The comparison is qualitatively similar for
all non-zero values of L (and are indeterminate for L ¼ 0, where the evaporation rate
is infinite). The models agree almost exactly for temperatures below approximately
70 C. Above that, the advection/diffusion model predicts an increasingly higher
evaporation rate than the pure diffusion model. Physically, there are two parallel
mechanisms for the transport of vapor across the air cylinder in Model 2.
Both Models 1 and 2 assume that the condition at the exit plane is that of the
ambient air. This artificial constraint becomes less realistic as L decreases.
It is apparent that the effects of advection are only important as the temperature
approaches the boiling point of the liquid. Returning to the original problem of the
cooling coffee cup, where the coffee starts at a temperature close to its boiling point
and gradually cools, the advection/diffusion model represents a significant
improvement over the pure evaporation model. It has not been demonstrated (yet)
whether the evaporation process has a significant impact on the cooling time and
that will be addressed after the final model has been developed.
The models considered thus far have focused on a control volume about the air
column inside the mug. Evaluation of the evaporation rate requires an assumption
about the value of the water mass fraction at both the free surface (with an upper
limit at the saturation condition) and at the exit plane of the mug (with a lower limit
of the ambient absolute humidity). For the condition at the free surface, it can be
argued that setting the mass fraction (Yv0) to the saturation limit (Ysat,0) is a good
approximation, except perhaps as the boiling point is approached, and the evapora-
tion rate is highest.
On the other hand, to say that the mass fraction of water vapor at the exit plane is
equal to the ambient value seems reasonable for a large value of L, but not when the
mug is nearly full. Visual inspection of the vapors leaving a hot cup of coffee
suggests that there is a significantly higher vapor concentration at the exit plane
than exists in the free stream. Furthermore, for full mugs (L ! 0), the predicted
evaporation rate increases dramatically, making a difference between the exit plane
and ambient even more likely.
In order for water vapor to leave the free surface, it must pass through the air
column to the exit plane, and then pass from the exit plane to the far field away from
the mug. To get a handle on that outer world, a simplified quasi-steady
one-dimensional analysis can be developed. Figure 13.11 shows a schematic that
models the exit plane, at a fixed mass fraction, to be a hemispherical shell of radius
R0. The area of the shell is the same as the area of the exit plane:
πD2 1
¼ 4πR20
4 2
13.2 Model Development 493
D
R0 ¼ pffiffiffi
8
The use of the hemisphere is conceptually accurate if the exit plane is at the same
level as the floor, and not a height H above it. This estimate therefore is an
underestimate of the ability for water vapor to diffuse away. The effects of the
global natural convection have a much larger effect in practice. Therefore, the result
of this model provides a lower limit on the ability for the environment to maintain
the exit plane at ambient conditions.
At an arbitrary radial position from the center line, there is no net mass flux
of air:
dY A 4πr 2
m_ air ¼ 0 ¼ m_ evap Y a þ ρDA
dr 2
Separating variables:
dY A m_ evap dr
¼
YA 2πρDA r 2
Integrating from the exit plane (at R0, where YA ¼ YAL) to “infinity” (where
YA ¼ Y1):
Yð1 1
ð
dY A m_ evap dr
¼
YA 2πρDA r2
Y A ¼Y aL r¼R0
1
Y1 m_ evap 1
ln ¼
Y AL 2πρDA r r¼R0
D 1 Y v1
m_ evap ¼ 2π pffiffiffi ρDA ln
8 1 Y vL
π
m_ evap ¼ pffiffiffi DρDA lnð1 þ BL1 Þ
2
where the transfer number applies between the exit plane (L) and ambient (1):
Y vL Y v1
BL1 ¼
1 Y vL
The major assumption of the point source model is that the only air movement
outside the coffee cup is that due to the evaporation process. In reality, especially
when the coffee is hot, natural convection currents will create a vertical flow that
will bring ambient air closer to the exit plane, and ease the ability for vapor to
diffuse from the exit plane to ambient. Therefore, the point source represents a
conservative prediction for the evaporation rate.
Model 3 Results
Figure 13.12 shows the evaporation rate as a function of coffee temperature on
semi-logy axes for the point source model (Model 3, dotted line) and the advection/
diffusion model (Model 2) for several values of air column lengths (L). The point
source model prediction is independent of the length of the air column (L), so only
1.E-04
L = 0.001 m
ambient
1.E-05
0.02
Point Source Model
Evaporation rate (kg/s)
0.04
1.E-06
0.06
0.08
1.E-07 0.10
1.E-08
1.E-09
1.E-10
0 20 40 60 80 100
Coffee Temperature (oC)
Fig. 13.12 Model 2 (air cylinder with advection/diffusion) and Model 3 (point source) evapora-
tion rates
13.2 Model Development 495
one curve is shown. The shape of the curve is similar for both models because both
are being driven by the same transfer number, B0L.
The evaporation rate predicted by the air column model (Model 2) is greater than
that predicted by the point source model for air column lengths less than approxi-
mately 3 cm. Conceptually, the exit plane is shared by both models, but it
corresponds to the exit plane for the air column and is the inlet plane for the
point source. The point source curve (dotted) line represents the maximum rate at
which vapor can diffuse away from the exit plane into the room (subject to the
major assumptions of the model). For L < 0.03, then, the mass delivered to exit
plane by the air column exceeds the ability for the point source to remove it.
One way around this contradiction in implementing the model would be to
calculate the evaporation rate from both models, and choose the lower of the two
as being controlling. Another, more sophisticated, way around it is to relax the
imposition of the mass fraction at the exit plane to be at one extreme or the other
(ambient in the air column model and surface saturation in the point source model).
That leads to Model 4.
13.2.5 Model 4: Matching the Air Column with the Point Source
This model matches Model 3 (point source) with Model 2. In order to escape from
the free surface to the room, water vapor must first diffuse, with the help of a
convective push, across the air cylinder to the exit plane. From there, it must diffuse
away to ambient. Models 2 and 3 result in simple expressions for the evaporation
rate, but the transfer number depends on the mass fractions at the boundaries of
each model. The two mass transfer regions (inside the air cylinder and the spherical
shell outside) are in series. Expressing the evaporation rate in terms of mass thermal
resistances, first across the air column, and then for the point source outside
the mug:
Y v0 Y vL Y vL Y v1
qevap ¼ m_ evap
hfg ¼ ¼
Rm, 0L Rm, L1
Rearranging for the intermediate mass fraction (YvL) and dropping the “m” from
the subscripts:
RL1
Y vL ¼ Y v1 þ ðY v0 Y v1 Þ
R0L þ RL1
The resistances cannot be evaluated completely from input variables. They depend
on YvL, making the equation nonlinear, and difficult, if not impossible, to solve
analytically. An iterative numerical method is viable, however. Forming a resis-
tance ratio:
496 13 Evaporation and Mass Transfer Fundamentals
1
Y vL ¼ Y 1 þ R0L ðY v0 Y 1 Þ
=RL1 þ 1
LðY v0 Y vL Þ
R0L ρDahfg Slnð1þB0L Þ pffiffiffi L lnð1 þ BL1 Þ Y v0 Y vL
¼ pffiffi ¼ 8
RL1 2ðY vL Y v1 Þ D lnð1 þ B0L Þ Y vL Y v1
πDρDahfg lnð1þBL1 Þ
An implicit expression for the intermediate mass fraction (i.e., at the exit plane) is:
ðY v0 Y 1 Þ
Y vL ¼ Y 1 þ pffiffiffi
lnð1þBL1 Þ Y vL
8 D lnð1þB0L Þ YYvLv0Y
L
v1
þ1
The transfer numbers both depend on YvL, making this equation nonlinear. The
equation in this form is a suitable recursion relation for application of the method of
successive substitution, however, in which case a value for YvL is guessed, followed
by evaluation of the right hand side, whose result is used as the next guess. An
iterative loop is run until the method either converges, or fails. If it fails, another
method can be attempted.
Model 4 Results
Implementation of Model 4, the matched model, requires an iterative solution. It is
cumbersome, though possible, to solve the transient coffee problem using Excel
(with macros and/or user-defined functions) because an iterative loop is required for
each time step. It is easier (but still requiring a macro) to write an excel file that
merely calculates everything as a function of instantaneous coffee temperature.
A macro-enabled excel file was written to do so. A macro was written that performs
the copy and “paste as values” required to conduct an iteration. A test for conver-
gence is conducted. However, the user is required to check to see if the solution is
converged, and run the macro repeatedly until it does. Every time a change is made
to an input variable (i.e., L), the iteration macro must be run.
Figure 13.13 shows the evaporation rate as a function of coffee temperature for
several values of air column length (L) for the matched model (Model 4) and the
point source model (Model 3, which is independent of L). This plot shows the same
cases as for Fig. 13.12, where the air column model was compared with the point
source model. In that latter case, the air column model predicted higher evaporation
rates for nearly full mugs (L < 0.03 m). In the matched model, the point source
model places an upper limit on the air cylinder. The problem from the straight air
column model, where the evaporation increases dramatically L approaches zero is
eliminated.
Model 4 is considered to be the most comprehensive model, yet it must be
emphasized that it is based on a one-dimensional model, and the effects of natural
13.2 Model Development 497
1.E-04
1.E-05
Evaporation Rate (kg/s)
1.E-06
Point Source
1.E-07
0.001
0.02
1.E-08
0.04
0.06
1.E-09
0.08
0.1
1.E-10
0 20 40 60 80 100
Coffee Temperature (°C)
Fig. 13.13 Model 4 evaporation rate predictions for different air column lengths (in m)
To this point, only the evaporation rate has been investigated from a purely mass
transfer point of view. It is clear that the evaporation depends strongly on the
instantaneous temperature of the liquid, driven by the highly nonlinear saturation
pressure. What is not yet clear is whether the evaporation has a significant effect on
the original problem of the cooling of a cup of coffee. From before, an evaporative
heat transfer coefficient can be defined as:
m_ evap
hfg
hevap ¼
Sð T 1 T S Þ
where, again,
Y v0 Y vL
B0L ¼
1 Y v0
498 13 Evaporation and Mass Transfer Fundamentals
100
Point Source
1
0.001
0.02
0.04
0.1 0.06
0.08
0.1
0.01
0 20 40 60 80 100
Coffee Temperature (oC)
Fig. 13.14 Evaporative heat transfer coefficients predicted by Model 3 (point source) and
4 (matched) for various values of L (distance between coffee surface and exit plane)
Figure 13.14 shows the evaporative heat transfer coefficients plotted on semi-logy
axes against coffee temperature for several values of the air column length (L) using
the matched model (Model 4) and the point source model (Model 3). The evapora-
tive heat transfer coefficient is very sensitive to temperature and exhibits some
dramatic behavior when the coffee is close to ambient, to be discussed shortly.
Three parallel mechanisms for energy transfer from the free surface to ambient
(radiation, convection, and evaporation) are compared in Fig. 13.15 for the base
case (L ¼ 0.05 m, a half-mug of coffee). The radiation model used assumes the free
surface is completely surrounded visually by ambient. In reality, the inner walls of
the mug will be somewhat higher, and the effective radiative heat loss will be lower
than predicted by this model, so the radiation curve is an upper estimate. The
convection model shown is based on published Nusselt number correlation for a
heated horizontal plate. That is the model that would seem most applicable if the
free surface were treated as a non-evaporating surface, and the mug were filled to
the brim. The actual heat transfer rate by conduction to the surface would be
lessened somewhat by the evaporative flow (especially near the boiling point),
and also by the free surface being below the rim. So the convection curve is also an
upper limit. On the other hand, the evaporation curve is an underestimate because
use of the point source model as controlling the diffusion away from the mug is the
slowest possible case, particularly when the coffee is hot and generating a strong
vertical natural convective flow.
When the coffee is first poured, the evaporative heat loss is very high, and
dominates the heat loss from the free surface. However, not modeled here, this
effect would tend to lower the free surface temperature below the average coffee
temperature, reducing the effects of evaporation. As the coffee continues to cool,
evaporation effects drop dramatically and becomes a small contributor. The natural
13.3 Evaporation of a Forgotten Cup of Coffee 499
20
0
0 10 20 30 40 50 60 70 80 90 100
Coffee Temperature (oC)
Fig. 13.15 Comparison of the evaporative, natural convective and radiative heat transfer
coefficients associated with the coffee-free surface as a function of coffee temperature
convection and radiation models are equally important, except as the coffee
approaches ambient, where the natural convection drops below to zero if the coffee
temperature equals ambient.
Therefore, for the overall cooling of the coffee, evaporation will contribute to a
high heat loss rate at the very beginning, at the same time the cold mug is being
heated, and subsequently is noticeable, but not dominant until the coffee is nearly at
room temperature.
Mathematically, the evaporative heat transfer coefficient is infinite when the
coffee temperature equals ambient, but the heat flux is finite. Use of an evaporative
heat transfer coefficient is reasonable when the coffee is cooling (or heating), and
when the coffee is near ambient. The energy transfer (not heat) associated with
evaporation is driven by diffusion, not by a temperature difference.
When the coffee is at the dew point temperature, the evaporation rate is iden-
tically zero (no concentration difference) and the evaporative heat transfer coeffi-
cient is zero. On the other hand, when the coffee temperature is precisely equal to
ambient, the evaporation rate is finite, but the temperature difference is zero.
After the coffee cools to room temperature, in several hours, the event is over,
right? Wrong. The cooling event is over, but the coffee continues to evaporate.
Unless the room is at 100 % relative humidity, the concentration of vapor just above
the free surface will be higher than that in the room, and water vapor will continue
500 13 Evaporation and Mass Transfer Fundamentals
to diffuse. Left undisturbed, the liquid will all eventually evaporate into the room.
The goal of this section is to predict the evaporation time and compare it to an
experiment.
13.3.1 Experiment
Figure 13.16 shows a photo of the evaporation experiment. A ceramic mug with an
inner diameter of approximately 6.2 cm and inner height of 10 cm is placed on a
food scale. Empty, the mug weighs 0.210 kg. Two hundred and fifty milliliters of
nominal room temperature water is added, filling the mug to the brim. The mug was
placed in a corner of a room (maintained nominally at 22 C, during winter, when
the inside relative humidity is expected to be low) and forgotten about, except for
occasionally, when a data point (mass and distance) was collected. The ambient
conditions were not well controlled.
The experimental results are shown in Fig. 13.17. The length was measured
periodically for some 63 days. The data is plotted and a power law fit applied. The
fit is extrapolated until the length equals the depth of the cup (0.1 m), which shows
105 days to complete evaporation. Unfortunately, the experimentalist forgot to take
data after day 63. . ..
13.3 Evaporation of a Forgotten Cup of Coffee 501
0.1
Fig. 13.17 Measured distance vs. time. A power law fit is applied, and the dotted line
extrapolates until complete evaporation (L ¼ H ¼ 0.1 m). A total evaporation time of 105 days is
predicted
INPUT PARAMETERS
Pinf 1.01E+05 N/m2 atmospheric pressure
Tinf 22 oC ambient temperature
H 0.1 m inner height of mug
D 0.056 m inner diameter of mug
rh 0.3 -- relative humidity
PHYSICAL CONSTANTS
rholiq 1000 kg/m^3 liquid density
Dv 2.56E-05 m^2/sec mass diffusivity of vapor
hfg 2.33E+06 J/kg heat of vaporization
A 9.1496E+10 N/m2 CLAUSIUS-CLAPYRON CONSTANTS FOR WATER
B
B -5.1152E+03 K
DERIVED PARAMETERS Psat(T ) = Ae (T+273)
rhogas 1.20 kg/m^3 gas density
Xvinf 0.0080 molV/mol mol fraction of vapor in ambient
Yvinf 0.0051 massV/mass mass fraction of vapor in ambient
X0 0.0266 molV/mol mol fraction of vapor on free surface
Y0 0.0167 massV/mass mass fraction of vapor on free surface
B0inf 1.17E-02 Transfer number, surface to ambient
Fig. 13.18 Input and derived parameter values for evaporation experiment
13.3.2 Theory
Three different models will be developed and a case study run based on the input
parameters shown in Fig. 13.18, which correspond loosely to the experimental
conditions. For derived parameters, the gas density is obtained from the ideal gas
502 13 Evaporation and Mass Transfer Fundamentals
law. The mole fraction of vapor in the ambient room is given by the relative
humidity times the saturation pressure (from the Clausius–Clapeyron fit) divided
by the total pressure. The mass fraction is obtained by the conversion derived in the
Appendix. The free surface is assumed to be at ambient temperature for this case.
A calculation will show that the free surface is theoretically colder than ambient
(because of evaporative cooling), but the heat transfer response time is so much
faster than the evaporation time, that an isothermal situation is an excellent approx-
imation. This approximation would have to be revisited if the ambient temperature
were close to the boiling point. The mole and mass fractions of vapor at the free
surface, then, represent the saturation state at ambient temperature. The mass
fraction at the free surface is 0.0167, showing that the partial pressure of water is
only about 1.7 % of the total, the balance being air. This behavior is referred to as
the “dilute gas approximation,” where the partial pressure exerted by the vapor is
much less than the total pressure. This behavior holds when the ambient tempera-
ture is sufficiently far from the boiling point, as in this case.
The overall transfer number, B01, is defined by:
Y0 Y1
B01 ¼
1 Y0
This transfer number represents the maximum it could possibly be and has a value
of 0.0117, which shows that the low B limit model applies, that is, for the transfer
number defined between generic surfaces A and B:
Y0 Y1
lnð1 þ B01 Þ B01 ¼
1 Y0
In addition, the air is always dilute in the vapor (Y
1), and therefore the
denominator is approximately equal to unity. Therefore, the low B number, dilute
system approximation is:
B01 Y 0 Y 1
Different evaporation models are developed shortly that all result in a B number,
but with different assumptions about the mass fraction values.
The goal of this study is to model the receding surface level, and therefore the
distance between the free surface and the exit plane is not a constant. A quasi-
equilibrium approximation is used, however, in which the rate of evaporation is
determined at any time as if that length were constant.
13.3 Evaporation of a Forgotten Cup of Coffee 503
dMcoffee
¼ m_ evap
dt
Expressing the coffee mass as the liquid density (ρLiquid) times the instantaneous
coffee volume (in terms of the length of the air column, L):
d ρLiquid SðH LÞ
¼ m_ evap
dt
Simplifying and rearranging:
dL m_ evap
¼
dt ρLiquid S
The evaporation rate depends on the model used. The rate of change of the coffee
surface is related to the rate of evaporation and depends inversely on the density of
the liquid and the free surface area (S). This expression will be revisited after
developing models for the evaporation rate. From experience, this height should not
change very much during the initial cooling process. It does change if left unat-
tended a few days.
dt ρLiquid S ρLiquid πD 4
2
504 13 Evaporation and Mass Transfer Fundamentals
Rearranging:
pffiffiffi
dL 8ρgas Dv lnð1 þ BL1 Þ
¼
dt ρLiquid D
YL Y1
BL1 ¼
1 YL
YL represents the mass fraction of vapor at the exit plane. When the mug is nearly
full, the free surface is near the exit plane, and the mass fraction at the exit plane is
assumed equal to the mass fraction on the free surface in this model limit:
YL Y0
The transfer number becomes equal to the transfer number applied to the system,
from the free surface to ambient:
Y0 Y1
BL1 B01 ¼
1 Y0
Furthermore, the low B number limit for dilute gas systems is applied and the
differential equation for air column length becomes:
pffiffiffi
dL 8ρgas Dv ðY 0 Y 1 Þ
¼
dt ρLiquid D
The velocity of the receding free surface (dL/dt) is a constant in this model, and the
equation can be integrated directly:
"pffiffiffi #
8ρgas Dv ðY 0 Y 1 Þ
L¼ t þ L0
ρLiquid D
L0 is the length of the air column at the start, which will be taken to be zero (a full
mug). The total evaporation time (tevap) can be calculated by setting the length of
the air column equal to the inner height of the mug (H):
ρLiquid DðH L0 Þ
tevap, LowL ¼ pffiffiffi
8ρgas Dv ðY 0 Y 1 Þ
13.3 Evaporation of a Forgotten Cup of Coffee 505
h day
tevap, LowL ¼ 5:46ð10Þ6 s
3, 600 s 24 h
This model predicts the complete evaporation of water from the mug will be about
2 months. It is about 40 days shorter than measured.
ρgas Dv Slnð1þB0L Þ
dL m_ evap
¼ ¼ L
dt ρLiquid S ρLiquid S
Rearranging:
" #
dL ρgas Dv lnð1 þ B0L Þ 1
¼
dt ρLiquid L
Y0 YL
B0L ¼
1 Y0
YL represents the mass fraction of vapor at the exit plane. When the mug is nearly
empty, the free surface is far from the exit plane, and the mass fraction at the exit
plane is assumed equal to the mass fraction of ambient air in this model limit:
YL Y1
The transfer number becomes equal to the transfer number applied to the system,
from the free surface to ambient:
Y0 Y1
B0L B01 ¼
1 Y0
506 13 Evaporation and Mass Transfer Fundamentals
Furthermore, the low B number limit for dilute gas systems is applied, and the
differential equation for air column length becomes:
" #
dL ρgas Dv ðY 0 Y 1 Þ 1
¼
dt ρLiquid L
In this model, the speed of the receding free surface (dL/dt) depends inversely on
the instantaneous value of the length of the air column (L). As the surface slowly
recedes, the rate of diffusion from the free surface to the exit plane decreases due to
the reduced concentration gradient that drives the mass transfer.
Separating variables (with the factor 2 applied for later convenience) and
applying limits of integration:
ðL ðt " #
2ρgas Dv ðY 0 Y 1 Þ
2LdL ¼ dt
ρLiquid
L¼L0 t¼0
" #
2ρgas Dv ðY 0 Y 1 Þ
L
2
L20 ¼ t
ρLiquid
This model results in the so-called L2 Law, which has an important counterpart in the
evaporation of liquid droplets. L0 is the length of the air column at the start, which will
be taken to be zero (a full mug). The total evaporation time (tevap) can be calculated by
setting the length of the air column equal to the inner height of the mug (H):
ρLiquid H 2 L20
tevap, Large L ¼
2ρgas Dv ðY 0 Y 1 Þ
h
7 day
tevap, Large L ¼ 1:37ð10Þ s
3, 600 s 24 h
This model predicts the complete evaporation of water from the mug will be about
5 months, more than twice that predicted from the point source model.
Matching Model
In both the early and late evaporation models, the mass fraction of water vapor at
the exit plane was assumed to be at one extreme (free surface) or the other
13.3 Evaporation of a Forgotten Cup of Coffee 507
(ambient). In this final model, these assumptions will be relaxed, and an expression
for the evaporation rate that applies for the entire evaporation event is developed.
To do so, the evaporation rate is expressed in both forms:
Notice that in the limit L/D ! 0, the mass fraction at the exit plane is the free
surface value (Y0), and in the L/D ! 1, the mass fraction at the exit plane is the
ambient value (Y1). The evaporation rate, using the air cylinder model with the
low B, dilute gas approximations is:
ρgas Dv SðY 0 Y 1 Þ
D
dL m_ evap =pffi8 þL
¼ ¼
dt ρLiquid S ρLiquid S
508 13 Evaporation and Mass Transfer Fundamentals
Separating variables, and applying integration limits, setting L0 to zero (to simplify
subsequent algebra):
ðL ðt " #
D ρgas Dv ðY 0 Y 1 Þ
=pffi8 þ L dL ¼ dt
ρLiquid
L¼0 t¼0
Performing the integrations results in a quadratic equation for the air cylinder
length (L) as a function of time:
" #
1 2 D ρgas Dv ðY 0 Y 1 Þ
L þ pffiffiffiL t¼0
2 8 ρLiquid
Solving for L:
vffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi
u 2 " #
D uD 2ρgas Dv ðY 0 Y 1 Þ
L ¼ pffiffiffi þ t þ t
8 8 ρLiquid
Rearranging:
ρLiquid H 2 1 þ HDpffiffi2
tevap, Matched ¼
2ρgas Dv ðY 0 Y 1 Þ
h day
tevap, Matched ¼ 1:95ð10Þ7 s
3, 600 s 24 h
Fig. 13.19 Air column length vs. time. Model predictions and experimental data
Figure 13.19 shows the length L as a function of time for the three models, and with
the experimental data. For the point source model, the air cylinder length increases
linearly, while the mass (not shown) decreases linearly. When all of the water is
evaporated (L ¼ H), the event is over. The air diffusion cylinder model predicts an
initial vertical slope and subsequently the slope decreases with time as the concen-
tration gradient weakens. If the mug in question were twice as deep as the one used,
the difference between the point source and air diffusion cylinder would be much
more dramatic. The final model matches the air cylinder to the point source. The
simulation follows the point source model initially, and as time proceeds, gradually
takes the shape of the air cylinder model, shifted in time to account for the initial
period where the model breaks down.
The experimental points appear to follow the air cylinder model most closely.
However, the functional dependence of length with time is different. Figure 13.20
shows the three theoretical curves plotted, and then a power law fit to them. The
point source and air cylinder models exhibit the linear and square root dependencies
as expected. However, the matched model, whose solution does not conform to a
simple power law fit, exhibits a power law exponent of 0.69, which agrees well with
the experimental value of 0.707 (from Fig. 13.17). Therefore, it is concluded that
the more involved matched model exhibits a similar functional dependency as the
experiment, but an overall slower evaporation rate.
Figure 13.21 shows the mass fraction at the exit plane (YL) as a function of time.
The point source model forces the mass fraction to be the saturated surface value.
The air cylinder forces it to be the ambient value. For the matching model, the exit
510 13 Evaporation and Mass Transfer Fundamentals
y = 0.0016x y = 0.0079x0.5
0.1
Length of Air column, L (m)
Matched Model
0.08
y = 0.0025x0.6907
0.06
0.04
0.02
0
0 50 100 150 200 250
Time (days)
Fig. 13.20 Model predictions, with power law fits. For each model, the dashed or dotted line is
the model prediction, the light line is a power law fit, with the equation shown
0.014
0.012
0.01
Matching Model
0.008
0.004
0.002
0
0 50 100 150 200 250
Time (days)
Fig. 13.21 Predicted mass fraction at the exit plane for the three evaporation models as a function
of time
plane is intermediate, and the mass fraction there gradually varies as the instanta-
neous length to diameter ratio changes. The mass fraction drops rapidly and very
gradually approaches the ambient value. Note that this particular mug has a modest
L/D ratio of 1.8.
The experiment shows a more rapid evaporation process than predicted by the
matching model for the assumed experimental conditions. However, the theoretical
13.3 Evaporation of a Forgotten Cup of Coffee 511
400
350
Evaporation Time (days) 0.8
300
250 0.6
0.4
200 0.2
rh = 0
150
100
50
0
10 15 20 25 30 35 40
Ambient Temperature (oC)
Fig. 13.22 Evaporation time as a function of ambient temperature and relative humidity for the
matched model
The final resistance network of this textbook is one that shows that evaporation
causes the surface temperature of the evaporating mug of coffee, left unattended in
a room, to be below the ambient temperature, in apparent violation of the Second
Law. Figure 13.24 shows a resistance network to demonstrate the basic heat and
mass transfer channels. There are no capacitances shown, as this situation is after
512 13 Evaporation and Mass Transfer Fundamentals
the cooling period is over, and any transient effects are considered to be unimpor-
tant, an assertion that could be justified with a full transient analysis.
The free surface of the coffee experiences three heat transfer channels: convec-
tive (Rh) and radiative (Rr) parallel channels directly to ambient and a convective
channel to the bulk of the coffee (Rc,s). The coffee in turn is in thermal contact with
ambient (Rc,1 which is a complex channel through the wall and to ambient). The
evaporation process is shown as a sink, since it is mass transfer driven (not
temperature). It is this evaporation process that acts as a cooling mechanism for
the surface, which must be below ambient in order for heat to flow into it.
A nodal balance on the free surface yields the temperature of the free surface,
noting that the series channel from ambient through the coffee is used:
Workshop 13.1. Evaporation Experiments 513
T1 1
Rrþ R1h þ Rc, 11þRs, c m_ e
hfg
Ts ¼
Rr þ Rh þ Rc, 1 þRs, c
1 1 1
This equation is implicit, since the evaporation rate is a function of the surface
temperature. Once thermal resistances are approximated, this equation is in a form
suitable for the Method of Successive Substitutions.
The coffee temperature, being a voltage divider between the surface and ambient
can be obtained next, as:
TS
R S, C þ RTC1, 1
T coffee ¼ 1
R S, C þ RC1, 1
The effect can be enhanced by using an insulated mug, in which case Rc,1 can be
made large compared to all other thermal resistances. The limit as Rc,1 goes to
infinity is:
T s ¼ T 1 Req, s1 m_ e
hfg
T coffee ¼ T s
where the equivalent resistance between the surface and ambient is:
1 1 1
¼ þ
Req, s1 Rr Rh
During the first week of class, procure samples of clear tubing. Choose samples
with a much larger length to diameter ratio than the value of 1.8 investigated in this
chapter. Mount them vertically with an open end up top, and sealed at the bottom.
Mark them with a scale. Find locations for them where they will not be disturbed,
fill them to the top with water (eliminate all air bubbles trapped), and start recording
L vs. t. Consider using different liquids, and note that if liquid mixtures are used
with components of different volatility (i.e., isopropyl alcohol/water mixtures), that
the composition will change with time. Modeling this effect requires some basic
understanding of distillation-type processes. Compare results to theoretical
predictions by the end of the semester.
514 13 Evaporation and Mass Transfer Fundamentals
Calculate the surface and coffee temperatures for an evaporating mug of coffee as a
function of ambient temperature (assume zero relative humidity). Demonstrate that
the effect becomes very large as the temperature approaches the boiling point of the
liquid. Use the point source model as giving the largest effect modeled here.
Alternatively, use published correlations for the mass transfer coefficients.
Include a lumped capacitance to the coffee node of Fig. 13.24 and include the
effects of evaporation onto the basic cooling response of the coffee. Use a well-
insulated mug and treat the thermal resistance between coffee and ambient (Rc,1)
as a constant. Use either an evaporative heat transfer coefficient (hevap) or directly
include the evaporation as a sink. Implement an implicit Euler method in which the
surface temperature, evaporation rates, radiation, and natural convection are all
calculated (iteratively) at each time step. Start with the coffee at its boiling point,
and notice how much lower the surface temperature is than the average coffee
temperature early on. Plot the dimensionless temperature vs. time on semi-logy
axes to observe deviations from first-order behavior.
pV ¼ r h psat ðT Þ
The relationship between the saturation pressure and the temperature can be
modeled using a curve fit of the form given by the Clausius–Clapeyron relation,
namely:
B
psat ðT Þ ¼ AeT
where A and B are constants for a given species, and T is the absolute temperature.
The values of A and B can be calculated by fitting two points taken from saturation
tables in the vicinity of the problem in question. This curve for water was plotted in
Fig. 13.2.
The partial pressure of water vapor is related to the concentration of water vapor.
For nv moles of water vapor at absolute temperature T occupying a volume V, the
ideal gas law is:
pv V ¼ nv R^ T
J
R^ ¼ 8, 314
kmol K
is the universal gas constant. Multiplying and dividing by the total number of moles
and rearranging:
n nR^ T
v
pv ¼ ¼ Xv P
n V
where P is the total pressure (the sum of all partial pressures). The mole fraction of
vapor, Xv is the number of moles of vapor divided by the total number of moles in
the gas mixture. The mass fraction and mole fractions are related to each other
through the molecular weights of the mixture and vapor by the following word
string:
Mass of Vapor Moles of Vapor Moles of Mixture Mass of Vapor
¼
Mass of Mixture Moles of Mixture Mass of Mixture Molesof Vapor
1
Y v ¼ ðX v Þ MWvapor
MWmix
The molecular weight of the mixture is obtained from the following word string:
Mass of Mixture Mass of Vapor þ Mass of Air
¼
Moles of Mixture Moles of Mixture
516 13 Evaporation and Mass Transfer Fundamentals
Mass of Mixture Moles of Vapor Mass of Vapor
¼
Moles of Mixture Moles of Mixture Moles of Vapor
Moles of Air Mass of Air
þ
Moles of Mixture Moles of Air
1
Yv ¼
1þ 1Xv
Xv
MW air
MW vapor