Unit 3 Solid Waste Management NOTES
Unit 3 Solid Waste Management NOTES
NOTES
UNIT III: WASTE MANAGEMENT
Solid Waste Management-Sources & Classification –Solid Waste Disposal Options - Toxic Waste
Management.
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Solid waste management should be embraced by each and every household, including the business
owners across the world. The industrialization has brought a lot of good things and bad things as
well. One of the adverse effects of industrialization is the creation of solid waste.
Solid-waste management, the collecting, treating, and disposing of solid material that is discarded
because it has served its purpose or is no longer useful. Improper disposal of municipal solid waste
can create unsanitary conditions, and these conditions in turn can lead to pollution of the
environment and to outbreaks of vector-borne disease—that is, diseases spread by rodents and
insects.
Organic waste: Kitchen waste, waste from food preparation, vegetables, flowers, leaves, fruits,
and market places.
Combustibles: Paper, wood, dried leaves, packaging for relief items etc. that are highly organic
and having low moisture content.
Toxic waste: Old medicines, paints, chemicals, bulbs, spray cans, fertilizer and pesticide
containers, batteries, shoe polish.
Ashes or Dust: Residue from fires that are used for cooking.
Hazardous waste: Oil, battery acid, medical waste, industrial waste, hospital waste.
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Soiled waste: Hospital waste such as cloth soiled with blood and other body fluids.
1. Residential
Residences and homes where people live are some of the major sources of solid waste. The garbage
from these places includes food wastes, plastics, paper, glass, leather, cardboard, metals, yard
wastes, ashes and special wastes like bulky household items such as electronics, tires, batteries,
old mattresses and used oil.
2. Industrial
Industries are known to be one of the biggest contributors to solid waste. They include light and
heavy manufacturing industries, construction sites, fabrication plants, canning plants, power and
chemical plants.
These industries produce solid waste in the form of housekeeping wastes, food wastes, packaging
wastes, ashes, construction and demolition materials, special wastes, medical wastes as well as
other hazardous wastes.
3. Commercial
Commercial facilities and buildings are yet another source of solid waste today. Commercial
buildings and facilities, in this case, refer to hotels, markets, restaurants, godowns, stores and office
buildings.
Some of the solid wastes generated from these places include plastics, food wastes, metals, paper,
glass, wood, cardboard materials, special wastes and other hazardous wastes.
4. Institutional
The institutional centers like schools, colleges, prisons, military barracks and other government
centers also produce solid waste. Some of the common solid wastes obtained from these places
include glass, rubber waste, plastics, food wastes, wood, paper, metals, cardboard materials,
electronics as well as various hazardous wastes.
Construction and demolition sites also contribute to the solid waste problem. Construction sites
include new construction sites for buildings and roads, road repair sites, building renovation sites
and building demolition sites.
Some of the solid wastes produced in these places include steel materials, concrete, wood, plastics,
rubber, copper wires, dirt and glass.
6. Municipal Services
The urban centers also contribute immensely to the solid waste crisis in most countries today.
Some of the solid waste brought about by the municipal services include street cleaning, wastes
from parks and beaches, wastewater treatment plants, landscaping wastes and wastes from
recreational areas, including sludge.
Among the wastes produced by these plants, there are industrial process wastes, unwanted
specification products, plastics, metal parts, just to mention a few.
8. Agriculture
Crop farms, orchards, dairies, vineyards and feedlots are also sources of solid wastes. Among the
wastes they produce are agricultural wastes, spoiled food, pesticide containers and other hazardous
materials.
9. Biomedical
This refers to hospitals and biomedical equipment and chemical manufacturing firms. In hospitals,
there are different types of solid wastes produced.
Some of these solid wastes include syringes, bandages, used gloves, drugs, paper, plastics, food
wastes and chemicals. All these require proper disposal or else they will cause a huge problem for
the environment and the people in these facilities.
Typical waste
Source Types of solid wastes
generators
Food wastes, paper, cardboard, plastics, textiles,
leather, yard wastes, wood, glass, metals, ashes,
Single and multifamily
Residential special wastes (e.g., bulky items, consumer
dwellings
electronics, white goods, batteries, oil, tires), and
household hazardous wastes.).
Stores, hotels,
Paper, cardboard, plastics, wood, food wastes,
Commercial restaurants, markets,
glass, metals, special wastes, hazardous wastes.
office buildings, etc.
Schools, hospitals,
Institutional prisons, government Same as commercial.
centers.
Street cleaning,
landscaping, parks,
Street sweepings; landscape and tree trimmings;
beaches, other
Municipal services general wastes from parks, beaches, and other
recreational areas, water
recreational areas; sludge.
and wastewater
treatment plants.
Crops, orchards,
Spoiled food wastes, agricultural wastes,
Agriculture vineyards, dairies,
hazardous wastes (e.g., pesticides).
feedlots, farms.
1. Litter Surroundings
Due to improper waste disposal systems, particularly by municipal waste management teams,
wastes heap up and become a menace. While people clean their homes and places of work, they
litter their surroundings, which affect the environment and the community.
3. Disease-causing Pests
This type of dumping of waste materials forces biodegradable materials to rot and decompose
under improper, unhygienic and uncontrolled conditions. After a few days of decomposition, a
foul smell is produced, and it becomes a breeding ground for different types of disease-causing
insects as well as infectious organisms. On top of that, it also spoils the aesthetic value of the area.
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4. Environmental Problems
Solid wastes from industries are a source of toxic metals, hazardous wastes, and chemicals. When
released to the environment, the solid wastes can cause biological and physicochemical problems
to the environment that may affect or alter the productivity of the soils in that particular area.
There are different methods of solid waste management. The following are some of the recognized
methods:
1. Sanitary Landfill
This is the most popular solid waste disposal method used today. Garbage is basically spread out
in thin layers, compressed and covered with soil or plastic foam. Modern landfills are designed in
such a way that the bottom of the landfill is covered with an impervious liner, which is usually
made of several layers of thick plastic and sand. This liner protects the groundwater from being
contaminated because of leaching or percolation. When the landfill is full, it is covered with layers
of sand, clay, topsoil and gravel to prevent seepage of water.
Advantage: If landfills are managed efficiently, it is an ensured sanitary waste disposal method.
2. Incineration
This method involves the burning of solid wastes at high temperatures until the wastes are turned
into ashes. Incinerators are made in such a way that they do not give off extreme amounts of heat
when burning solid wastes.
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Incinerators that recycle heat energy through furnace and boiler are called waste-to-energy plants.
These waste-to-energy systems are more expensive to set up and operate compared to plain
incinerators because they require special equipment and controls, highly skilled technical
personnel, and auxiliary fuel systems. This method of solid waste management can be done by
individuals, municipalities and even institutions. The good thing about this method is the fact that
it reduces the volume of waste up to 20 or 30% of the original volume.
Advantage: The volume of combustible waste is reduced considerably by burning waste. In the
case of off-site pits, it is an appropriate method to minimize scavenging.
Constraint: It can cause smoke or fire hazard and also emits gaseous pollutants.
Constraint: It is expensive to set up, and in most emergencies, there is limited potential.
4. Composting
Due to a lack of adequate space for landfills, biodegradable yard waste is allowed to decompose
in a medium designed for the purpose. Only biodegradable waste materials are used in composting.
It is a biological process in which micro-organisms, specifically fungi and bacteria, convert
degradable organic waste into substances like humus. This finished product, which looks like soil,
is high in carbon and nitrogen. Good quality environmentally friendly manure is formed from the
compost that is an excellent medium for growing plants and can be used for agricultural purposes.
Constraint: It requires intensive management and experienced personnel for large scale operation.
5. Pyrolysis
This is a method of solid waste management whereby solid wastes are chemically decomposed by
heat without the presence of oxygen. It usually occurs under pressure and at temperatures of up to
430 degrees Celsius. The solid wastes are changed into gasses, solid residue of carbon and ash and
small quantities of liquid.
Advantage: This will keep the environment clean and reduce health and settlement problems.
Constraint: The systems that destroy chlorinated organic molecules by heat may create incomplete
combustion products, including dioxins and furans. These compounds are highly toxic in the parts
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per trillion ranges. The residue it generates may be hazardous wastes, requiring proper treatment,
storage, and disposal.
Wastes considered hazardous are those which are ignitable, corrosive, reactive, and toxic.
Hazardous waste can be categorized into waste from non-specific sources and waste from specific
sources
USEPA has established four characteristic tests to determine whether a waste is hazardous or not.
Ignitability
• Wastes that pose a fire hazard during routine handling, storage, processing, transport, or
disposal
• If a solid waste possesses any of the following properties:
o Liquid containing less than 24% alcohol by volume and has flash point less than 60oC
o Liquid capable of causing fire through friction under standard temperature and
pressure
o Is an ignitable compressed gas
o Is an oxidant
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o Examples – paint thinners and paint removing compounds, solvents used for cleaning
parts and degreasing
Flammability
• Vapors of volatile organic compounds can ignite in the presence of a spark
• Lower Flammability Limit (LFL) and Upper Flammability Limit (UFL) of mixture:
o =1Σ 1 1 =1
o =1Σ 1 1 =1
o Where 1= , =
Corrosivity
• Corrosive wastes occur at extreme pH
o ≤2.5, ≥12.5
o Liquid corrodes steel at a rate greater than 6.35 mm per year and at a temperature of
55oC
o Examples – battery acid, phenol wastes, acidic wastes from metal plating industries
Reactivity
• Unstable waste
• Reacts violently with water
• When mixed with water, generates toxic gases/ vapours/ fumes
• Cyanide or sulphide bearing wastes
• Can pose sufficient danger to human health or environment
Toxicity
• Toxicity Characteristic Leaching Procedure (TCLP) to simulate environmental conditions
in landfill
o Intent of test is to determine whether toxic components of waste could leach to
groundwater and soil if exposed to acidic precipitation
• Examples – paint waste containing metals (Pb, Ag, Cd, Cr), mercury waste, oily wastes
and sludge from petroleum industry, waste containing tetrachloroethylene
Effective Solubility
It is the true solubility of a compound in mixture, denoted by Sie.
=
Where = ( ), = ,
= ( ), =
Vapour Pressure
Vapour pressure of a liquid is the pressure exerted by the liquid at equilibrium. When a liquid is
in contact with air, molecules of the liquid leave as Vapour and reach an equilibrium (rate of
volatilization is equal to the rate of molecules dissolving).
Sorption
Properties of the phase as well as properties of the contaminant affects sorption into soil. Sorption
controls the rate at which the contaminants move across media.
Oxidation-Reduction Potential
Used to determine the oxidation state of water
Controls concentration of ions present in oxidized/ reduced forms
Oxidized species – positive ORP, Reduced species – negative ORP (on a relative basis)
Coulombic forces
Volatilization
Volatilization refers to the mass transfer of a contaminant from liquid to gaseous phase. It is
important to monitor the migration of hazardous chemicals from waste sites and storage facilities
(both above and below ground).
Factors contributing to concentration of contaminant in air:
Vapour pressure and Henry’s Law (decides volatilization rate)
Temperature
Mixing (for e.g., fans/ blowers)
Contact area (within the storage container)
Ventilation rate (mixing from outside the room/ system)
Rate limited mass transfer and dilution will play an important role
Humans, plants and animals can come into contact with hazardous waste by either inhalation,
ingestion, or dermal exposure.Exposure can be acute or chronic.
• Gamma decay: After a nucleus undergoes alpha or beta decay, it is often left in an
excited state with excess energy. An atomic nucleus loses energy by emitting a gamma
ray. Gamma radiation is the most penetrating of the three.
Like with other hazardous chemicals, exposure to radioactive material occurs through different
means: inhalation, ingestion and direct exposure – with different effects for each of these exposures.
Inhalation
Occurs when people breathe in radioactive materials
Sources: contaminated dust, smoke, gaseous nuclides
Ingestion
Occurs when radioactive materials are swallowed
o Drinking contaminated radioactive ground water
o Farming on land with contaminated soil
o Use of contaminated water for irrigation
o Consumption of fish from contaminated waters
o Bathing or swimming in contaminated waters
Ingested radionuclides expose entire digestive system – can be absorbed by kidneys and
other organs, as well as bones
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Direct Exposure
Depends on duration the person is exposed to radiation, distance from source, presence of
shielding (for instance, gamma rays can travel long distances and penetrate through the
human body)
Radiation dose is measured in rem. Rem is a unit of radiation dosage, such as from X-rays, applied to
humans. It is the dosage in rads that will cause the same amount of biological injury as one rad of X-
rays or gamma rays. Rad is the unit of absorbed dose of ionizing radiation and is equal to the amount
of radiation that releases an energy of 100 ergs per grams of matter.
70 Vomiting
75 Hair loss 2-3 weeks
90 Diarrhea
100 Hemorrhage
400 Possible death Within 2 months
1000 Destruction of intestinal lining, internal bleeding and death 1-2 weeks
2000 Damage to central nervous system, loss of consciousness Minutes/ hours to days
and death
Source: USEPA|Radiation Protection www.epa.gov
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Used fuel gives rise to HLW – which contains recoverable elements such as uranium and plutonium.
If used reactor fuel is not reprocessed, it will still contain highly radioactive isotopes, and in that case,
the entire fuel assembly is treated as HLW for direct disposal. The waste generates a lot of heat and
requires cooling before disposal. After storage for about 40-50 years, the radioactivity of the used fuel
would have fallen. The fuel assemblies are then ready for encapsulation or loading into casks and made
ready for permanent disposal underground. HLW from reprocessing must be solidified. In order to
ensure that no significant releases occur in the future, a “multiple barrier” geological disposal is
necessary. The main barriers are:
Immobilize waste in an insoluble matrix such as borosilicate glass or synthetic rock
Seal it inside a corrosion-resistant container – such as stainless steel
Locate it deep underground in a stable rock structure
Surround containers with impermeable backfill such as bentonite clay if the repository is
wet
environmental studies). Such discharges must be regulated and controlled, and the maximum dose
anyone receives from these discharges is a small fraction of natural background radiation. Nuclear
power stations and reprocessing plants release small quantities of radioactive gases (e.g. krypton-85
and xenon-133) and trace amounts of iodine-131 into the atmosphere. However, they have short half-
lives and do not have large impacts. The US Nuclear Regulatory Commission classifies LLW into four
categories based on radioactivity
Class A
o Lowest radioactivity level, decays to background level after ~100 years
o Includes contaminated paper, clothing, rags, mops, equipment, tools
Classes B and C
o Decay after 300 and 500 years, respectively
o Includes filter, resins, irradiated hardware
Greater than class C
o Greater radionuclide concentration than classes above
In summary, some of the available means of disposal for radioactive waste are:
Delay and decay: If the concentrations of radioactive elements are mostly short-lived, they
can be released in small amounts over long periods of time.
Dilute and disperse: This is useful in minimizing the hazard posed to the environment.
Concentrate and contain: For HLW, radioactive material that has a long half-life, and so on;
it is important to make sure that the waste is contained to a space marked for the purpose.
REFERENCE:
[1] Source: What A Waste: Solid Waste Management in Asia. Hoornweg, Daniel with Laura Thomas.
1999. Working Paper Series Nr. 1. Urban Development Sector Unit. East Asia and Pacific Region. Page 5.