12.project Report I
12.project Report I
CHAPTER 1
INTRODUCTION
1.1 GENERAL
Initiatives are emerging worldwide to control and regulate the management of sub-
products, residuals and industrial wastes in order to preserve the environment from
contamination. A good solution to the problem of recycling agro industrial residue would
be by burning them in a controlled environment and use the ashes (waste) for more noble
means. Utilization of such wastes as cement and fine aggregate replacement materials
may reduce the cost of concrete production and also minimize the negative environmental
effects with disposal of these wastes.
Sugarcane is one of the major crops grown in over 110 countries and its total
production is over 1500 million tons. After the extraction of all economical sugar from
sugarcane, large fibrous residue is obtained. When bagasse is burnt in the boiler of
cogeneration plant under controlled conditions, reactive amorphous silica is formed due
to the combustion process and is present in the residual ashes known as Sugarcane
Bagasse Ash. This amorphous silica content makes bagasse ash a useful cement
replacement material in concrete. Each ton of sugarcane generates approximately 26% of
bagasse (at a moisture content of 50%) and 0.62% of residual ash. The residue after
combustion presents a chemical composition dominates by silicon dioxide (SiO2). From
the past researches it is found that the bagasse ash consists of the properties of nature
sand.
But these ashes are produced under uncontrolled and non-uniform burning
conditions with temperatures rising above 1000°c resulting in a crystallization of the
matter
.In this study the bagasse ash is planned to use as the partial replacement for cement and
fine aggregate in-order to utilize the wastages and to protect the environment from the
hazards. Sugarcane bagasse ash is normally used as fertilizer in sugarcane plantation.
1.2 REASON FOR ALTERNATE RESOURCES
Ordinary Portland cement is recognized as a major construction material
throughout the world and in terms of its per capita consumption, it is second most
consumed material in the country, next only to water. However, the production of
Portland cement, an essential constituent of concrete, leads to the release of significant
amount of CO2, a greenhouse gas (GHG); production of one ton of Portland cement
produces about one ton of CO2.
In addition to natural resources issues, it play a leading role in the sustainable
development of the cement and concrete industry during this century. Currently, there has
been an attempt to utilize the large amount of bagasse ash, the residue from an in-line
sugar industry and the bagasse-biomass fuel in electric generation industry. This bagasse
ash has been chemically and physically characterized replaced in different proportion
with cement and incorporated in concrete.
The most commonly used fine aggregate is natural river or pit sand. Fine and
coarse aggregate constitute about 75% of total volume. It is therefore, important to obtain
right type and good quality aggregate at site.
The demand of natural sand is quite high in the developing countries due to the
rapid infrastructural growth. In this situation developing country like India is facing
shortage of good quality natural sand. In India natural sand deposits are being depleted.
Increasing extraction of natural sand from river beds causes many problems such as
loosing water retaining sand strata, deepening of the river courses and causing bank
slides, loss of vegetation on the bank of rivers, exposing the intake well of water supply
schemes, disturbance to the aquatic life and affecting agriculture due to lowering of
underground water table. In the past decade variable cost of natural sand used as fine
aggregate in concrete has increased the cost of construction many folds.
Some alternative materials have already been used as a part of natural sand and
cement. Fly ash, slag, limestone and siliceous stone powder were used in concrete
mixtures as a partial replacement of natural sand and cement. However, scarcity in
required quality is the major limitation in some of the above materials. Now a day’s
sustainable infrastructural growth demands the alternative material that should satisfy
technical requisites of fine aggregate and at the same time it should be available
abundantly.
1.3 NEED OF SUGARCANE BAGASSE ASH (SCBA) USAGE
Each ton of cement produces approximately about one ton of CO2 and cement
industry is responsible for the emission of about 5% of CO2 worldwide.
Brings positive effect to the environment.
When used as replacement for cement in concrete, it reduces the problem
associated with their disposal.
Decrease in the emission of greenhouse gases.
1.4 PROCESS OF EXTRACTION OF SCBA
To obtain Sugarcane Bagasse ash (SCBA), burning was carried out in two stages-
open burning followed by controlled burning at 600°C for 5 hours (actual procedure), but
the SCBA used for our thesis is collected from Sugarcane factory where the burning
temperature of SCBA was around 900-1100°C. SCBA so obtained was not fine enough to
be blended with the cement; therefore to achieve fineness compared to OPC, the ash
obtained after burning was grounded in a ball mill and subsequently screened through
45μ sieve.
In the present study, increasingly high volumes of BA waste obtained from the
sugar industry were used as fine aggregate replacement materials in the production of
high- performance SCC, which was obtained by adding LS powder waste obtained from
the stone-crushing industry. The goal was to maximize the amount of unprocessed or as-
received BA content as a new fine aggregate. For the performance of SCC with
controlled flow ability conditions (slump flow diameter of 70 + 2.5 cm or -2.5cm), there
were advantages to using BA and LS powder in the workability of the concrete. For
instance, SCC mixtures containing LS and BA required lower w/c ratios than SCC
containing only BA, leading to higher flow ability. However, some blocking occurred in
mixtures containing 40% LS and 40% BA (“high-volume” BA content) during V-funnel
and J-ring tests. The unit weight of the SCC decreased with increasing BA content and
increased with increasing LS content, allowing a type of lightweight SCC to be obtained.
The resulting concrete structure had a decreased weight and low long-term maintenance
costs. In terms of the hardened properties of SCC combinations, BA and LS could be
employed to decrease the w/c ratio by more than 24%. The compressive strength of SCCs
comprised of BA and LS mixtures increased when lower w/c ratios were used, compared
to SCCs mixed with BA alone. Incorporation of suitable levels of BA and LS improved
the early-stage compressive strength development, due to filling effects and pozzolanic
reactions. The optimal SCC, which contained 20% LS and 20% replacement of the fine
aggregate by BA, showed improved properties compared to normal SCC and met the
requirements of the European Federation of National Associations Representing
Producers and Applicators of
Specialist Building Products for Concrete (EFNARC) guidelines. To conform to the
performance-based design of SCC, future studies should systematically investigate the
effects of LS powder use on the durability of SCC incorporating large amounts of BA
waste.
Introduction
Literature review
Mix design
Casting of specimen
Slump Flow Compaction factor Compressive strength Split tensile strength Flexural strength
Vee bee consistometer Durability
4.1 CEMENT
The cement used in this study was OPC 53 grade from KCP Cement
Company which is widely used in the construction industries. The chemical properties of
cement are shown in Table 4.1(a) which is given by the supplier. The physical properties
of cement was determined by testing the cement as per IS 12269:1987 (reaffirmed 2004)
using pycnometer and vicat’s apparatus and the test results are shown in Table 4.1(b)
Component %
Sio2 21.8
Al2O3 4.8
Fe2O3 3.8
CaO 63.3
SO3 2.2
MgO3 0.9
Na2O 0.21
K2 O 0.46
Cl 0.04
P2O5 <0.04
Loss of ignition 2
W3 − W1
Specific gravity of kerosene, (𝐠)
= W2 − W1
= 758/847
= 0.8949
W5
Specific gravity of cement, Xg
(𝐆 ) = W5 + W3 − W4
200
= X 0.8949
200 + 1370.5 −
1509
G = 2.910
3. Setting time
4. Fineness 2.5%
Fig 4.2.1 Sugarcane Bagasse Ash Fig 4.2.2 specific gravity test
Cumulative
Sieve Weight Cumulative %
Sl.no Weight % finer
size retained retained
retained
1 10 0 0 0 100
2 4.75 12.5 12.5 2.5 97.5
3 2.36 42.5 55 11 89
4 1.18 65 120 24 76
5 0.6 60 180 36 64
6 0.3 102.5 282.5 56.5 43.5
7 0.15 117.5 410 82 18
8 Pan 90 500 100 0
Table 4.2.1 Sieve analysis for SCBA as per IS: 383- 1970
Fineness modulus of SCBA = ∑F/100 = 2.12
G = 1.78
Its physical and chemical properties are given in Table 4.2(a) & 4.2(b)
Property Value
SCBA MASS %
Oxides
Silica (Sio2) 68
Fig 4.3.2 Determination of Specific gravity Fig 4.3.3 Aggregate Impact value
Sl Sieve size Weight of Cumulative Cumulative Cumulative 19
No materials weight % retained % of Passing
Retained (Kg) retained (Kg)
1 80mm - 0 0 100
2 40mm - 0 0 100
3 20mm - 0 0 100
4 12.5mm 2.186 2.186 72.867 27.133
5 10mm 0.674 2.860 95.333 4.634
6 4.75mm 0.140 3.000 100 0
7 PAN 0 0 - -
1 10 0 0 0 100
2 4.75 10 10 2 98
3 2.36 50 60 12 88
4 1.18 50 110 22 78
5 0.6 95 205 41 59
6 0.3 175 380 76 24
7 0.15 85 465 93 7
8 0.075 30 495 99 1
9 Pan 5 500 100 0
Table 4.4.1 Sieve analysis for sand as per IS: 383- 1970
Fineness modulus of Coarse Aggregate = ∑F/100 = 2.46
Fig 4.4.1 Graph showing Sieve Analysis
Specific gravity of FA
Weight of the empty pycnometer, W1 = 612.5 gm
Weight of the empty pycnometer + sand, W2 = 1656 gm
Weight of the empty pycnometer + sand + water, W3 = 2078 gm
Weight of the empty pycnometer + water, W4 = 1445.5 gm
W2 − W1
Specific gravity of cement, (𝐆) =
(W2 − W1) − (W3 −
W4)
= 1656 − 612.5
(1656 − 612.5) − (2078 −
1445.5)
G = 2.54
4.5 WATER
Water is an important ingredient in cement paste, as it chemically participates in
the reactions with cement to form the hydration product, C-S-H gel. The strength of
cement mortar depends mainly from the binding action of the hydrated cement paste C-S-
H gel. For high performance concrete it is important to have the compatibility between
the given cement and the chemical and mineral admixtures along with water used for
mixing. Quality and quantity of water is required to be looked very carefully.
CHAPTER 5
CONCRETE MIX DESIGN
5.1 INTRODUCTION
5.5.3 DESIGN
= 25 + 1.65x5.3
= 33.75 N/mm2
Where
Step 3: Adjustment
From Table 2 of IS 10262 - 2009, maximum water content is 186 litre for 20 mm
aggregate (for 25 to 50 mm slump range)
3
Estimated water content for 75 mm slump = [186 X ] + 186
100
= 191.58 l/m3
As super plasticizer is used, the water content can be reduced up 20 percent and above.
Based on trials with super plasticizer water content reduction of 6 % has been achieved.
Hence, the arrived water content =191.58 x 0.94 =180 litre/m3
Step 4: Determination of cement content
Water cement ratio = 0.40
Cement content = 180/0.40
= 450 kg/m3
From Table 5 of IS: 456, minimum cement content for severe exposure condition
= 300 kg/m3
450 kg/m3 > 300 kg/m3, hence ok
Step 5: Determinate of coarse and fine aggregate contents
From Table 3 of IS 10262 – 2009, volume of coarse aggregate corresponding to 20
mm size aggregate and fine aggregate (Zone II) for water-cement ratio of 0.50 = 0.62. In
the present case water-cement ratio is 0.40. Therefore volume of coarse aggregate is
required to be increased to decrease the fine aggregate content. As the water-cement ratio
is lower by 0.10 the proportion of volume of coarse aggregate is increased by 0.02 (at the
rate of -/+ 0.01 for every ± 0.05 change in water-cement ratio).
Therefore corrected proportion of volume of coarse aggregate for the water/
cement ratio of 0.40 = 0.64.
Volume of fine aggregate content =1 - 0.64 =0.36.
The mix calculations per unit volume of concrete shall be as follows:
a) Volume of concrete = 1m3
Mass of cement
b) Volume of cement =[ ]
Specific gravity of cement x 1000
450
= [2.91 x 1000 ]
= 0.155m3
Mass of water
c) Volume of water =[ ]
Specific gravity of water x 1000
180
= [1 x 1000 ]
= 0.180m3
Mass of admixture
d) Volume of chemical admixture = [ ]
Specific gravity of admixture x 1000
= 0.008m3
From Table 3, for the specified maximum size of aggregate of 20 mm, the amount of
entrapped air in the wet concrete is 2 percent. Taking this into account,
e) Volume of all in aggregate = [a-0.2- (b +c +d)}
= 0.98-(0.155 +0.180+0.008)
= 0.637 m3
f) Mass of coarse aggregate = e x Volume of coarse aggregate x specific
Gravity of coarse aggregate x 1000
= 0.637 x 0.64 x 2.68 x 1 000
=1092.58 kg = 1093kg
g) Mass of fine aggregate = e x volume of fine aggregate x Specific
Gravity of fine aggregate x 1000
= 0.637 x 0.36 x 2.56 x I 000
= 587.01kg = 587 kg
Step 6: Mix Proportion
Where,
C – Cement,
FA – Fine Aggregate,
CA – Coarse Aggregate,
SCBA – Sugarcane Bagasse Ash,
SP – Super plasticizer.
CHAPTER 6
TESTING ON CONCRETE
The ingredients needed for the concrete were weighed and taken as per the mix
proportions arrived from the mix design. Pan mixer of 40litres capacity is used for mixing
of M25 grade of concrete in fig 6.1&6.2. Before start the work super plasticizer should be
added with 6% of total water taken. Then aggregates are mixed in pan mixer for some
time and cement is added with the mixed aggregate in the mixer. Then remaining 94% of
water are mixed with aggregate and cement mixer. Finally, super plasticizer which is
mixed with water are added with concrete and mixed for 1mins. To impart additional
workability a super plasticizer (Rheobuild 1100) 2% by weight of cement was used. It
is based on sulphonated naphthalene polymers with following properties as per I.S. –
9103-1999.
Vee-Bee consistometer test is more reliable as results of this test are not influenced
by personal factors. This test is more suitable for stiff concrete mixes having low and
very low workability and slump value of such mixes cannot be determined by slump test.
Moreover, this test is advantageous as compared to slump or compaction factor test in the
sense that in this test the treatment given to concrete is very close to the actual treatment
provided in the field. The test setup of Vee-Bee consistometer is shown in Figure 6.2.3.1.
For carrying out the test, first of all slump test is performed by placing the slump cone
inside the cylindrical pot. After removing the slump cone mould the glass disc is turned
and placed over the top of the concrete mass. Now, controlled vibrations are started
through electric vibrator and simultaneously the stopwatch is started. The vibrations are
continued till the conical shape of concrete assumes the cylindrical shape and time is
noted. This can be observed by viewing through the glass disc. The time required for
complete remoulding of concrete (i.e. from conical to cylindrical shape) in seconds is
expressed as the number of Vee-Bee seconds or Vee-Bee Degree. This test is not suitable
for highly workable mix (generally if slump > 75 mm or so) because for such mix the
remoulding is so quick that time cannot be measured.
Figure 6.2.3.1 Vee-bee consistometer
For the compression strength test of concrete 150 x 150 mm cubes were used and
it’s tested as per BIS: 516-1959. For each trail mix combination, three cubes were tested
at the age of 7, 14 and 28 days of curing using 3000KN capacity AIMIL compression
testing machine in Figure 6.4.1.1. The specimens shall be tested with the moulded sides
in contact with the plates. The load shall be applied without shock and increased
continuously at a rate of approximately 140 kg/sq cm/min until the resistance of the
specimen to the
increasing load breaks down and no greater load can be sustained. The maximum load
applied to the specimen shall then be recorded and the appearance of the concrete and any
unusual features in the type of failure shall be noted. The compressive strength is
determined by following formula:
𝑢𝑙𝑡𝑖𝑚𝑎𝑡𝑒 𝑙𝑜𝑎𝑑
Fck =
𝑎𝑟𝑒𝑎 𝑜𝑓 𝑠𝑝𝑒𝑐𝑖𝑚𝑒𝑛
Where,
B= measured width in cm of the specimen,
D= measured depth in cm of the specimen at the point of failure,
L= length in cm of the span on which the specimen was supported,
P= maximum load in kg applied to the specimen.
2P
Fct=
𝜋LD
Where,
Where,
Ws= weight of specimen at fully saturated condition.
Wd= weight of oven dried specimen.
6.5.2 POROSITY
The porosity of concrete is a measure of the pore volume in hardened concrete,
which is occupied by water in saturated condition. It denotes the quantity of water, which
can be removed on drying a saturated specimen. The porosity obtained from absorption
tests is designated as effective porosity. It is determined by using the following formula
volume of voids(Vv)
Effective porosity (n) = ∗ 100
bulk volume of cube
specimen(V)
The volume of voids is obtained from the volume of water absorbed by an oven dry
specimen or the volume of water lost on oven drying a water saturated specimen at 105
degree centigrade to constant mass. The bulk volume of the specimen is given by the
difference in mass of the specimen in air and it’s mass under submerged condition in
water.
(Ws−Wd) ∗ 100
n =(Ws−Wsub
)
where,
W sub=weight of specimen submerged in water.
6.5.3 IMPACT RESISTANCE
The impact resistance tests were carried on concrete specimens of size 150mm
diameter and 63mm thickness after 28 days of water curing, using a drop weight testing
machine. Drop weight test, which was originally devises by Schrader, yields the number
of blows necessary to cause prescribed level of distress in the test specimen. This number
serves as a quantitative estimate of the energy absorbed by the specimen as that distress
level.
DESCRIPTION
The equipment consists of standard manually operated 45N compaction hammer
with 457mm drop; a 152.4mm diameter hardened steel ball and a flat base with
positioning brackets. The weight of the hammer is 45N. The number of blows required by
dropping the hammer through a height of 457mm, to cause the first visible crack and to
cause ultimate failures are recorded. Each blow of the hammer is 20.2Nm of energy.
TESTING PROCEDURE
Thickness of the specimens were measured to the nearest millimetre at its centre
and at the ends if the diameter prior to the test. The specimens were coated on the bottom
with a thin layer of grease and placed on the base plate with the finished face up and
positioned within four legs of the impact testing equipment in Figure 6.5.3.1. The bracket
with the cylindrical sleeve was fixed in place and the hardened steel ball was placed on
the top of the specimens within the bracket. Elastomeric pads were placed between the
specimen and positioning legs to restrict movement of the specimen during testing to the
first visible crack. The drop hammer was then placed with its base upon the steel ball and
held vertically. The hammer was dropped repeatedly and the number of blows required
for the first visible formed at the top surface of the specimen and the ultimate failure were
recorded. To carry out the test satisfactorily, the base plate needs to be rigidly and this
was achieved by anchoring it to the test bed. The first crack was based on the visual
observation. Painting the surface of the test specimen facilitated the identification of this
crack. The number of blows required to cause the concrete specimens to fracture into
separate pieces were noted.
CHAPTER 7
RESULTS AND DISCUSSIONS
7.1 INTRODUCTION
The results of the tests that were carried out on the trial mixes of M25 grade
concrete with partial replacement of sugarcane bagasse ash to determine their
workability, strength and durability related properties are presented in this chapter.
79
77
76
75
70
B0 B1 B2 B3 B4
% of SCBA partial replacement
0.9
0.88
0.87
0.85
0.81
B0 B1 B2 B3 B4
% of SCBA partial replacement
5.06
4.56
3.93
3.21
B0 B1 B2 B3 B4
25
20
15
10
0
C-0% FA-0% C-10% FA-10%C-10% FA-20%C-10% FA-30%C-10% FA-40%
7 days16.77 16.9817.0317.1616.53
14 days23.23 23.4723.5423.7722.8
28 days25.8 26.126.226.425.4
% of replacement of SCBA
2.5
1.5
0.5
0
C-0% FA-0%C-10% FA-10%C-10% FA-20%C-10% FA-30%C-10% FA-40%
7 days1.891.911.921.951.9
14 days2.252.2662.2732.282.23
28 days2.3682.3762.3862.42.353
% of replacement of SCBA
Chart 7.3.2.1 Comparison of split tensile strength of cylinder for different % of SCBA
3.5
2.5
1.5
0.5
0
C-0% FA-0%C-10% FA-10%C-10% FA-20%C-10% FA-30% C-10% FA-40%
7 days2.862.882.892.92 2.84
14 days3.383.43.413.42 3.34
28 days3.563.573.583.6 3.53
% of replacement of SCBA
B0 B1 B2 B3 B4
From the experiments and investigation in this research work, we documented the
following facts.
1. Due to non-availability of natural sand at sensible cost as fine aggregate and cement
in concrete for various motives, search for alternate material like SCBA which
succeeds itself as a suitable standby for sand and cement at low cost.
2. Since the physical properties of SCBA matches very nearly with natural sand and the
presence of silica content in SCBA makes it effective replacement for both fine
aggregate and cement.
3. SCBA have its place to zone lV as per IS code. Water constraint increased as the
percentage of SCBA increased. However it could be easily overcome with the
application of chemical admixtures.
4. As per the experimental analysis, concrete with its 30% of fine aggregate and 10% of
Cement replaced with SCBA gives competitive physical strength to the conventional
concrete with 0% replacement.
5. Compressive strength of 26.4 N/mm2, split tensile strength of 2.4 N/mm 2 and flexural
strength of 3.6 N/mm2 at 28 days is achieved for M25 grade concrete with total
SCBA content of 40%.
6. Therefore, concluded that bagasse ash can increase the complete strength of the
concrete when used up to a 10% cement and 30% fine aggregate replacement level
with w/c ratio of 0.40.
7. Bagasse ash is a valuable pozzolanic material and it can possibly be used as a partial
replacement of both fine aggregate and cement. This could reduce the ecological
complications and minimalize the requirement of land seal area to dispose SCBA.
CHAPTER 9
REFERENCES
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