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Equation of State PDF

The document discusses equations of state and gas laws. It provides definitions and equations for ideal gas law, Boyle's law, Charles' law, and Dalton's law. The ideal gas law combines several gas laws and relates pressure, volume, temperature, and amount of gas. It is only approximately valid for real gases. An ideal gas is a hypothetical gas that perfectly obeys the gas laws and has molecules that occupy no space and do not interact except during collisions.

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83 views

Equation of State PDF

The document discusses equations of state and gas laws. It provides definitions and equations for ideal gas law, Boyle's law, Charles' law, and Dalton's law. The ideal gas law combines several gas laws and relates pressure, volume, temperature, and amount of gas. It is only approximately valid for real gases. An ideal gas is a hypothetical gas that perfectly obeys the gas laws and has molecules that occupy no space and do not interact except during collisions.

Uploaded by

Edward
Copyright
© © All Rights Reserved
Available Formats
Download as PDF, TXT or read online on Scribd
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Equation of state

In physics, equations of state attempt to describe the relationship between temperature,


pressure, and volume for a given substance or mixture of substances. The ideal gas law is one of the
simplest equations of state. Although reasonably accurate for gases at low pressures and high
temperatures, it becomes increasingly inaccurate at higher pressures and lower temperatures.
Despite its shortcomings, the ideal gas law is used extensively in many fields of science and
engineering. Due to its simple form, straightforward solutions to a number of problems involving
the equation of state can be obtained if the system of interest can be assumed to behave as an ideal
gas. The solutions become much more complicated and difficult to use for the cases where more
accurate equations of state must be used.
Using statistical mechanics, the ideal gas law can be derived by assuming that a gas is
composed of a large number of small molecules, with no attractive or repulsive forces. In reality
gas molecules do interact with attractive and repulsive forces. In fact it is these forces that result in
the formation of liquids.
Ideal Gas Law or Universal Gas Equation
The ideal gas law, or universal gas equation, is an equation of state of an ideal gas. It combines
several gas laws (i.e., Dalton’s Law, Boyle’s Law, Charles Laws):

Here p is the pressure of gas;  is the density of the gas equal to m/V; m is the mass of the gas
occupying volume V; V the volume it occupies, R the gas constant for the given gas; and T the
temperature of the gas. In SI units, the pressure is expressed in pascals, the volume in cubic meters,
and the temperature in degrees Kelvin. The ideal gas law generalizes the three classical gas laws.
The equation is valid only for an ideal gas. Real gases obey this equation only approximately,
but its validity increases as the density of the gas tends to zero.
Ideal gas
Ideal gas (also called perfect gas) is a hypothetical gas which obeys the gas laws exactly. An
ideal gas consists of molecules which occupy negligible space and among which negligible forces
exist, except at collisions. All collisions between molecules or between molecules and the walls of
a container are perfectly elastic, as the molecules have no means of storing energy except as
translational kinetic energy. Ideal gas is a good approximation for diluted real gases.
At lower temperatures and higher densities, it may be necessary to treat quantum-mechanical
effects statistics even before those of interactions. In such cases, the concept of an ideal gas is
extended to that of an ideal Fermi gas or Bose gas.
Gas laws
The gas laws are a set of laws that describe the relationship between temperature, pressure and
volume of gases. The laws include Boyle's Law and Charles' Law, and others (e.g., Graham's Law,
Henry's law, and Avogadro's law) and they are collectively generalized by the universal gas
equation, also known as the ideal gas law.
A gas which obeys gas laws exactly is hypothetical, and is known as an ideal gas (or perfect
gas).
Boyle's Law, named after Robert Boyle, states that the volume occupied by a gas at constant
temperature is inversely proportional to the pressure applied:

Charles Law states that the pressure that a gas exerts on the walls of its container is determined
by the momentum of the atoms and molecules of the gas, which in turn is determined by the
temperature. As the temperature increases the atoms and molecules move faster, and so exert a
greater pressure on the walls. For a given mass of gas at constant volume, Charles Law states that
the pressure exerted by it is directly proportional to its temperature:

Dalton's law
In physics, Dalton's law (also called Dalton's law of partial pressure) is a law that states the total
pressure exerted by a gaseous mixture is equal to the sum of the pressures that would be exerted by
the gases if they alone were present and occupied the same volume.
More precisely, the pressure p of a mixture of n gases can be defined as the summation:

This means that each gas in a mixture acts as if the other gas is not present and that the
pressures that come from each gas can simply be added. It is assumed that the gases do not react
with each other.

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