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Atomic Structure: Chemistry DPP 5 by Garima Verma (Chemistry Faculty) - Referral Code: "Cgvmam"

This document contains a chemistry document practice paper (DPP) on atomic structure and the Heisenberg uncertainty principle. The DPP contains 13 multiple choice questions testing concepts such as de Broglie wavelength, photon wavelength and mass, uncertainty in position and momentum, and applying the Heisenberg uncertainty principle. The document also provides the answer key to the 13 questions.

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Tanisha Subudhi
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478 views

Atomic Structure: Chemistry DPP 5 by Garima Verma (Chemistry Faculty) - Referral Code: "Cgvmam"

This document contains a chemistry document practice paper (DPP) on atomic structure and the Heisenberg uncertainty principle. The DPP contains 13 multiple choice questions testing concepts such as de Broglie wavelength, photon wavelength and mass, uncertainty in position and momentum, and applying the Heisenberg uncertainty principle. The document also provides the answer key to the 13 questions.

Uploaded by

Tanisha Subudhi
Copyright
© © All Rights Reserved
Available Formats
Download as PDF, TXT or read online on Scribd
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CHEMISTRY DPP 5

BY GARIMA VERMA (CHEMISTRY FACULTY) | REFERRAL CODE : “CGVMAM”

ATOMIC STRUCTURE

1 If electron, hydrogen, helium and neon nuclei are all moving with the velocity of light,
then the wavelength associated with these particles are in the order
(a) Electron > hydrogen > helium > neon (b) Electron > helium > hydrogen > neon
(c) Electron < hydrogen < helium < neon (d) Neon < hydrogen < helium < electron

2 The de Broglie wavelength of a tennis ball of mass 60 g moving with a velocity of 10


metres per second is approximately
(a) 10−31 m (b) 10−16 m (c) 10−25 m (d) 10−33 m

3 If the energy difference between the ground state of an atom and its excited state is
4.4 × 10−4 𝐽, the wavelength of photon required to produce the transition :
(a) 2.26 × 10−12 𝑚 (b) 1.13 × 10−12 𝑚
(c) 4.52 × 10−16 𝑚 (d) 4.52 × 10−12 𝑚

4 The mass of a photon with a wavelength equal to


(a) 0.8268 × 10−34 𝑘𝑔 (b) 1.2876 × 10−33 𝑘𝑔
(c) 1.4285 × 10−32 𝑘𝑔 (d) 1.8884 × 10−32 𝑘𝑔

5 If the Planck’s constant ℎ = 6.6 × 10−34 Js, the de Broglie wavelength of a particle
having momentum of 3.3 × 10−24 𝑘𝑔 𝑚𝑠 −1 will be
(a) 0.002 Å (b) 0.5 Å (c) 2 Å (d) 500 Å

6 The values of Planck’s constant is 6.63 × 10−34 𝐽𝑠. The velocity of light is 3.0 ×
108 𝑚𝑠 −1 . Which value is closest to the wavelength in nanometres of a quantum of light
with frequency of 8 × 1015 𝑠 −1 ?
(a) 5 × 10−18 (b) 4 × 101 (c) 3 × 107 (d) 2 × 10−25

7 The de Broglie wavelength of a car of mass 1000 kg and velocity 36 km/hr is


(a) 6.626 × 10−34 𝑚 (b) 6.626 × 10−38 𝑚
(c) 6.626 × 10−31 𝑚 (d) 6.626 × 10−30 𝑚
CHEMISTRY DPP 5

BY GARIMA VERMA (CHEMISTRY FACULTY) | REFERRAL CODE : “CGVMAM”

8 Heisenberg uncertainty principle can be explained as


Δ𝑃 × ℎ ℎ
(a) Δ𝜒 ≥ (b) Δ𝜒 × Δ𝑃 ≥
4𝜋 4𝜋
ℎ 𝜋ℎ
(c) Δ𝜒 × Δ𝑃 ≥ (d) Δ𝑃 ≥
𝜋 Δ𝜒

9 Heisenberg’s uncertainty principle is applicable to


(a) Atoms only (b) electron only
(c) Nucleus only (d) any moving object

10 The position of both, an electron and a helium atom is known within 1.0 nm. Further the
momentum of the electron is known within 5.0 × 10−26 𝑘𝑔 𝑚𝑠 −1 . The minimum
uncertainty in the measurement of the momentum of the helium atom is :
(a) 50 𝑘𝑔 𝑚𝑠 −1 (b) 80 𝑘𝑔 𝑚𝑠 −1
(c) 8.0 × 10−26 𝑘𝑔 𝑚𝑠 −1 (d) 5.0 × 10−26 𝑘𝑔 𝑚𝑠 −1

11 Uncertainty in the position of an electron (mass = 9.1 × 10−31 𝑘𝑔) moving with a
velocity 300 𝑚𝑠 −1 , accurate upto 0.001% will be (ℎ = 6.63 × 10−34 𝐽𝑠)
(a) 1.92 × 10−2 𝑚 (b) 3.84 × 10−2 𝑚
(c) 19.2 × 10−2 𝑚 (d) 5.76 × 10−2 𝑚

12 The uncertainty in the position of an electron (mass = 9.1 × 10−28 𝑔) moving with a
velocity of 3.0 × 104 𝑐𝑚 𝑠 −1 accurate upto 0.011% will b e
(a) 1.92 cm (b) 7.68 cm (c) 0.175 cm (d) 3.84 cm

13 The Heisenberg uncertainty principle will be most significant for which of the following
object?
(a) Object A of mass 9.11 × 10−30 𝑘𝑔 (b) Object B of mass 9.11 × 10−28 𝑘𝑔
(c) Object C of mass 9.11 × 10−24 𝑘𝑔 (d) Object D of mass 9.11 × 10−28 𝑘𝑔

ANSWER KEYS
1.A 2.D 3.D 4.C 5.C 6.B 7.B
8.B 9.D 10.D 11.A 12.C 13.B

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