SAFETY DATA SHEET

1. Identification
Product identifier E5Z02Series
Other means of identification Not available.
Recommended use Inkjet printing
Recommended restrictions None known.
Company identification HP Inc.
1501 Page Mill Road
Palo Alto, CA 94304-1112
United States
Telephone 650-857-5020

HP Inc. health effects line

(Toll-free within the US) 1-800-457-4209
(Direct) 1-760-710-0048
HP Inc. Customer Care Line
(Toll-free within the US) 1-800-474-6836
(Direct) 1-208-323-2551
Email: [email protected]

2. Hazard(s) identification
Physical hazards Not classified.
Health hazards Not classified.
Environmental hazards Not classified.
OSHA defined hazards Not classified.
Label elements
Hazard symbol None.
Signal word None.
Hazard statement Not available.
Precautionary statement
Prevention Not available.
Response Not available.
Storage Not available.
Disposal Not available.
Hazard(s) not otherwise Carbon black is classified by the IARC as a Group 2B carcinogen (the substance is possibly
classified (HNOC) carcinogenic to humans). Carbon black in this preparation, due to its bound form, does not present
this carcinogenic risk. Potential routes of overexposure to this product are skin and eye contact.
Inhalation of vapor and ingestion are not expected to be significant routes of exposure for this
product under normal use conditions. Complete toxicity data are not available for this specific
formulation. None of the other ingredients in this preparation are classified as carcinogens
according to ACGIH, EU, IARC, MAK, NTP or OSHA.
Supplemental information This product is not classified as hazardous according to OSHA CFR 1910.1200 (HazCom 2012).

3. Composition/information on ingredients
Mixtures
Chemical name Common name and synonyms CAS number %
Water 7732-18-5 70-80
1,5-pentanediol 111-29-5 <7.5
2-pyrrolidone 616-45-5 <7.5
Carbon black 1333-86-4 <5

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Composition comments This ink supply contains an aqueous ink formulation.
This product has been evaluated using criteria specified in 29 CFR 1910.1200 (Hazard
Communication Standard).

Carbon black is present only in a bound form in this preparation.

4. First-aid measures
Inhalation Move to fresh air. If symptoms persist, get medical attention.
Skin contact Wash affected areas thoroughly with mild soap and water. If irritation persists get medical
attention.
Eye contact Do not rub eyes. Immediately flush with large amounts of clean, warm water (low pressure) for at
least 15 minutes or until particles are removed. If irritation persists get medical attention.
Ingestion If ingestion of a large amount does occur, seek medical attention.
Most important Not available.
symptoms/effects, acute and
delayed

5. Fire-fighting measures
Suitable extinguishing media CO2, water, dry chemical, or foam
Unsuitable extinguishing None known.
media
Specific hazards arising from Not applicable.
the chemical
Special protective equipment Not available.
and precautions for
firefighters
Specific methods None established.

6. Accidental release measures

Personal precautions, Wear appropriate personal protective equipment.
protective equipment and
emergency procedures
Methods and materials for Dike the spilled material, where this is possible. Absorb with inert absorbent such as dry clay, sand
containment and cleaning up or diatomaceous earth, commercial sorbents, or recover using pumps.
Environmental precautions Do not let product enter drains. Do not flush into surface water or sanitary sewer system.

7. Handling and storage

Precautions for safe handling Avoid contact with skin, eyes and clothing.
Conditions for safe storage, Keep out of the reach of children. Keep away from excessive heat or cold.
including any
incompatibilities

8. Exposure controls/personal protection

Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components Type Value

Carbon black (CAS PEL 3.5 mg/m3

1333-86-4)
US. ACGIH Threshold Limit Values
Components Type Value Form

Carbon black (CAS TWA 3 mg/m3 Inhalable fraction.

1333-86-4)
US. NIOSH: Pocket Guide to Chemical Hazards
Components Type Value

Carbon black (CAS TWA 0.1 mg/m3

1333-86-4)
Biological limit values No biological exposure limits noted for the ingredient(s).

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Exposure guidelines Exposure limits have not been established for this product.
Appropriate engineering Use in a well ventilated area.
controls
Individual protection measures, such as personal protective equipment
Eye/face protection Not available.
Skin protection
Hand protection Not available.
Other Not available.
Respiratory protection Not available.
Thermal hazards Not available.
General hygiene Handle in accordance with good industrial hygiene and safety practice.
considerations

9. Physical and chemical properties

Appearance
Physical state Not available.
Color Black.
Odor Not available.
Odor threshold Not available.
pH 7-8
Melting point/freezing point Not available.
Initial boiling point and Not determined
boiling range
Flash point > 200.0 °F (> 93.3 °C) Pensky-Martens Closed Cup
Evaporation rate Not determined
Flammability (solid, gas) Not available.
Upper/lower flammability or explosive limits
Flammability limit - lower Not determined
(%)
Flammability limit - Not available.
upper (%)
Explosive limit - lower Not available.
(%)
Explosive limit - upper Not available.
(%)
Vapor pressure Not determined
Solubility(ies)
Solubility (water) Soluble in water
Partition coefficient Not available.
(n-octanol/water)
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity >= 2 cp
Other information
Specific gravity 1 - 1.2
Other information For other VOC regulatory data/information see Section 15.
VOC (Weight %) < 146 g/L

10. Stability and reactivity

Reactivity Not available.
Chemical stability Stable under recommended storage conditions.
Possibility of hazardous Will not occur.
reactions

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Conditions to avoid Not available.
Incompatible materials Incompatible with strong bases and oxidizing agents.
Hazardous decomposition Upon decomposition, this product may yield gaseous nitrogen oxides, carbon monoxide, carbon
products dioxide and/or low molecular weight hydrocarbons.

11. Toxicological information

Symptoms related to the Not available.
physical, chemical and
toxicological characteristics
Information on toxicological effects
Acute toxicity Based on available data, the classification criteria are not met.
Skin corrosion/irritation Based on available data, the classification criteria are not met.
Serious eye damage/eye Based on available data, the classification criteria are not met.
irritation
Respiratory or skin sensitization
Respiratory sensitization Based on available data, the classification criteria are not met.
Skin sensitization Based on available data, the classification criteria are not met.
Germ cell mutagenicity Based on available data, the classification criteria are not met.
Carcinogenicity Based on available data, the classification criteria are not met.

Carbon black is classified as a carcinogen by the IARC (possibly carcinogenic to humans, Group
2B) and by the State of California under Proposition 65. In their evaluations of carbon black, both
organizations indicate that exposure to carbon black, per se, does not occur when it remains
bound within a product matrix, specifically, rubber, ink, or paint. Carbon black is present only in a
bound form in this preparation.
IARC Monographs. Overall Evaluation of Carcinogenicity
Carbon black (CAS 1333-86-4) 2B Possibly carcinogenic to humans.
Reproductive toxicity Based on available data, the classification criteria are not met.
Specific target organ toxicity Based on available data, the classification criteria are not met.
- single exposure
Specific target organ toxicity Based on available data, the classification criteria are not met.
- repeated exposure
Aspiration hazard Based on available data, the classification criteria are not met.
Further information Complete toxicity data are not available for this specific formulation
Refer to Section 2 for potential health effects and Section 4 for first aid measures.
Components Species Test Results
2-pyrrolidone (CAS 616-45-5)
Acute
Oral
LD50 Guinea pig 6500 mg/kg
Rat 6500 mg/kg
Carbon black (CAS 1333-86-4)
Acute
Oral
LD50 Rat > 8000 mg/kg

12. Ecological information

Aquatic toxicity Not expected to be harmful to aquatic organisms.

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Ecotoxicity
Product Species Test Results
E5Z02Series (CAS Mixture)
Aquatic
Acute
Fish LC50 Fathead minnow (Pimephales promelas) > 750 mg/l, 96 hours
Components Species Test Results
2-pyrrolidone (CAS 616-45-5)
Aquatic
Crustacea EC50 Water flea (Daphnia pulex) 13.21 mg/l, 48 hours
Persistence and degradability Not available.
Bioaccumulative potential Not available.
Partition coefficient n-octanol / water (log Kow)
2-pyrrolidone -0.85
Mobility in soil Not available.
Other adverse effects Not available.

13. Disposal considerations

Disposal instructions Do not allow this material to drain into sewers/water supplies.
Dispose of waste material according to Local, State, Federal, and Provincial Environmental
Regulations.

HP's Planet Partners (trademark) supplies recycling program enables simple, convenient recycling of
HP original inkjet and LaserJet supplies. For more information and to determine if this service is
available in your location, please visit http://www.hp.com/recycle.

14. Transport information

DOT
Not regulated as dangerous goods.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
ADR
Not regulated as dangerous goods.
Further information Not a dangerous good under DOT, IATA, ADR, IMDG, or RID.

15. Regulatory information

US federal regulations US TSCA 12(b): Does not contain listed chemicals.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - No
Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 No
Hazardous chemical

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Other federal regulations
Safe Drinking Water Act Not regulated.
(SDWA)
US state regulations
US. Massachusetts RTK - Substance List
2-pyrrolidone (CAS 616-45-5)
Carbon black (CAS 1333-86-4)
US. New Jersey Worker and Community Right-to-Know Act
Carbon black (CAS 1333-86-4)
US. Pennsylvania Worker and Community Right-to-Know Law
2-pyrrolidone (CAS 616-45-5)
Carbon black (CAS 1333-86-4)
US. California Proposition 65
US - California Proposition 65 - CRT: Listed date/Carcinogenic substance
CARBON BLACK (AIRBORNE, UNBOUND PARTICLES Listed: February 21, 2003
OF RESPIRABLE SIZE [<= 10 MICROMETERS]) (CAS
1333-86-4)
Other information VOC content (less water, less exempt compounds) = < 781 g/L (U.S. requirement, not for
emissions)
VOC data based on formulation (Organic compounds minus solids)

Regulatory information All chemical substances in this HP product have been notified or are exempt from notification under
chemical substances notification laws in the following countries: US (TSCA), EU (EINECS/ELINCS),
Switzerland, Canada (DSL/NDSL), Australia, Japan, Philippines, South Korea, New Zealand, and
China.

16. Other information, including date of preparation or last revision

Issue date 29-Jan-2015
Revision date 08-Feb-2016
Version # 04
Disclaimer This Safety Data Sheet document is provided without charge to customers of HP. Data is the most
current known to HP at the time of preparation of this document and is believed to be accurate. It
should not be construed as guaranteeing specific properties of the products as described or
suitability for a particular application. This document was prepared to the requirements of the
jurisdiction specified in Section 1 above and may not meet regulatory requirements in other
countries.
Manufacturer information HP Inc.
1501 Page Mill Road
Palo Alto, CA 94304-1112 US
Direct 1-650-857-5020

Material name: E5Z02Series SDS US

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Explanation of abbreviations

ACGIH American Conference of Governmental Industrial Hygienists

CAS Chemical Abstracts Service
CERCLA Comprehensive Environmental Response Compensation and Liability Act
CFR Code of Federal Regulations
COC Cleveland Open Cup
DOT Department of Transportation
EPCRA Emergency Planning and Community Right-to-Know Act (aka SARA)
IARC International Agency for Research on Cancer
NIOSH National Institute for Occupational Safety and Health
NTP National Toxicology Program
OSHA Occupational Safety and Health Administration
PEL Permissible Exposure Limit
RCRA Resource Conservation and Recovery Act
REC Recommended
REL Recommended Exposure Limit
SARA Superfund Amendments and Reauthorization Act of 1986
STEL Short-Term Exposure Limit
TCLP Toxicity Characteristics Leaching Procedure
TLV Threshold Limit Value
TSCA Toxic Substances Control Act
VOC Volatile Organic Compounds

Material name: E5Z02Series SDS US

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