Nitinol: by Keshav Jasoriya BARCH/10028/18
Nitinol: by Keshav Jasoriya BARCH/10028/18
By Keshav Jasoriya
BARCH/10028/18
Nitinol
● Nickel titanium, also known as Nitinol, is a metal alloy of nickel and titanium, where the two elements are present
in roughly equal atomic percentages. Different alloys are named according to the weight percentage of nickel,
e.g. Nitinol 55 and Nitinol 60. It exhibits the shape memory effect and superelasticity at different temperatures.
● Shape memory is the ability of nitinol to undergo deformation at one temperature, stay in its deformed shape
when the external force is removed, then recover its original, undeformed shape upon heating above its
"transformation temperature".
● Superelasticity is the ability for the metal to undergo large deformations and immediately return to its
undeformed shape upon removal of the external load.
● Whether nitinol behaves with the shape memory effect or superelasticity depends on whether it is above the
transformation temperature of the specific alloy. Below the transformation temperature it exhibits the shape
memory effect, and above that temperature it behaves superelastically.
Martensitic Transformation
● The lowest temperature phase in Nitinol shape memory alloys with a B19’ (B19 prime) monoclinic crystal
structure.
● A martensitic transformation is a specific type of crystal structure change that occurs when cooling certain
specific metals, including Nitinol.
● The crystal structure found at high temperatures is the parent phase, often referred to austenite, and the
phase that results from a martensitic transformation is called martensite.
● Martensitic transformation can also be driven by the application of a stress, and that doing so gives rise to
superelasticity, but here we confine the discussion to the effects of temperature alone.
● The temperature at which the transformation of martensite from austenite (or R-phase) is completed on
cooling of the alloy is called Martensite finish temperature.
● The intermediate phase which may form between austenite and martensite. The R-phase occurs in Nitinol
alloys under certain conditions. The R-phase has a rhombohedral crystal structure.
Austenite Transformation
● The high temperature parent phase of the Nitinol alloy having a B2 crystal structure.
● Martensite deformation temperature : the highest temperature at which martensite will form from the austenite
phase in response to an applied stress. At temperature above Md the Nitinol shape memory alloy will not exhibit
superelasticity it will rather exhibit a typical elastic-plastic behavior when loaded.\
● In the austenite phase, the memory metal "remembers" the shape it had before it was deformed. From the stress
vs. temperature graph below, one can see that at low stress and low temperature, martensite exists. At higher
temperature and higher stress, austenite exists.
Applications Of Nitinol