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Tugas Kuliah Online Praktikum Kimia Dasar TAHUN AKADEMIK 2019-2020

The document contains a table summarizing chemical reactions involving various metal ion samples (Fe2+, Fe3+, Zn2+, Al3+, Ba2+, Ca2+, Mg2+, NH4+) with different reagents. The table lists the sample, procedure, observations, and balanced chemical reactions. It was submitted as a chemistry practical assignment by students Surgawati Rusady and Klara Risa Pratama for their Chemistry III lab course in the 2019-2020 academic year.

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surgawati Rusady
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48 views

Tugas Kuliah Online Praktikum Kimia Dasar TAHUN AKADEMIK 2019-2020

The document contains a table summarizing chemical reactions involving various metal ion samples (Fe2+, Fe3+, Zn2+, Al3+, Ba2+, Ca2+, Mg2+, NH4+) with different reagents. The table lists the sample, procedure, observations, and balanced chemical reactions. It was submitted as a chemistry practical assignment by students Surgawati Rusady and Klara Risa Pratama for their Chemistry III lab course in the 2019-2020 academic year.

Uploaded by

surgawati Rusady
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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Nama : Surgawati Rusady ( 03422119292 )

Klara Risa Pratama ( 03422119158 )


Kelas : Reg-1 19B
Tugas : Praktikum Kimia III

TUGAS KULIAH ONLINE PRAKTIKUM KIMIA DASAR


TAHUN AKADEMIK 2019-2020

TUGAS III
1. Mereaksikan prosedur yang terdapat pada tabel berikut:

Sampel Prosedur Pengamatan Reaksi


Fe2+
1. S + NH4OH + NH4Cl + H2S FeSO4 + 2NH4OH Fe(OH)2 ↓ + (NH4)2SO4.
↓ hitam Fe(OH)2 ↓ + 2NH4Cl FeCl2 ↓ + 2NH3 + 2H2O
FeCl2 ↓ + H2S FeS ↓(hitam) + 2HCl.
2. S + NaOH ↓ hijau kotor FeSO4 + 2NaOH Fe(OH)2 ↓ (hijau kotor) + Na2SO4
3. S + K4Fe(CN)6 FeSO4 + K4Fe(CN)6 K2Fe[Fe(CN)6] ↓ biru muda +
↓ biru muda
K2SO4
4. S + K3Fe(CN)6 FeSO4 + K3Fe(CN)6 KFe[Fe(CN)6] ↓ biru tua +
↓ biru tua
K2SO4
Fe3+ 1. S + NH4OH + NH4Cl + H2S FeCl3 + 3NH4OH Fe(OH)3 ↓ + 3NH4Cl
↓ hitam Fe(OH)3 ↓+ 3NH4Cl FeCl3 ↓ + 3H2O + 3NH3
2FeCl3 ↓ + H2S 2FeCl2 ↓ (hitam) + 2HCl + S
2. S + NaOH ↓ orange FeCl3 + NaOH Fe(OH)3 ↓ (orange) + 3NaCl
3. S + K4Fe(CN)6 ↓ biru FeCl3+ K4Fe(CN)6 KFe[Fe(CN)6] ↓ (biru) + 3KCl
4. S + K3Fe(CN)6 ↓ coklat FeCl3+ K3Fe(CN)6 Fe[Fe(CN)6] ↓ (coklat) + 3KCl
5. S + KSCN larutan
FeCl3 + 3KCSN Fe(SCN)3 larutan merah darah +
merah
3KCl
darah
Zn2+ 1. S + NH4OH + NH4Cl + H2S ZnCl2 + 2NH4OH Zn(OH)2 ↓ + 2NH4OH
Zn(OH)2 ↓ + NH4Cl ZnCl2 ↓ + 2NH4OH
↓ hitam
ZnCl2 ↓ + H2S ZnS ↓ (hitam) + 2HCl

2. a. S + NaOH ↓ putih ZnCl2 + 2NaOH Zn(OH)2 ↓ (putih) + 2Na


b. ↓ + NaOH larut Zn(OH)2 ↓ + 2NaOH Zn(OH)4 + 2Na

1
3. S + K4Fe(CN)6 2ZnCl2 + K4Fe(CN)6 Zn2[Fe(CN)6] ↓ (putih)
↓ putih
+4KCl
4. a. S + NH4OH ↓ putih 2ZnCl2 + 2NH4OH Zn(OH)2 ↓ (putih) + 2NH4Cl
b. ↓ + NH4OH larut Zn(OH)2 + 4NH4OH [Zn(NH3)4(OH)2] + 4H2O
Al3+ 1. S + NH4OH + NH4Cl + H2S Al2(SO4) + 6NH4OH 2Al(OH)3 ↓ + 6(NH4) + SO4
↓ hitam Al(OH)3 ↓ + 3NH4Cl ↓ AlCl3 ↓+ 3NH4OH
2AlCl3 ↓+ H2S Al2S3 ↓(hitam) + 6HCl
2. S + Na2CO3 ↓ putih 2AlCl3 + 3Na2CO3 Al2(CO3)3↓ (putih ) + 6NaCl
3. a. S + NaOH ↓ putih AlCl3 + 3NaOH Al(OH)3 ↓ (putih) + 3NaCl
b. ↓ + NaOH larut Al(OH)3 ↓ + 3NaOH Na3AlO3 + 3H2O
4. S + CH3COONa AlCl3 + 3CH3COONa Al(CH3COO)3 # ↓ (putih) +
# ↓ putih
3NaCl
5. a. S + Na3PO4 ↓ putih AlCl3 + Na3PO4 AlPO4 ↓ (putih )+ 3NaCl
b. ↓ + HCl larut AlPO4 ↓ + 3HCl AlCl3 + H3PO4
Sampel Prosedur Pengamatan Reaksi
Ba2+ 1. a. S + NH4OH + NH4Cl + BaSO4 + 2NH4OH Ba(OH)2 ↓ + (NH4)2SO4
(NH4)2CO3 ↓ putih Ba(OH)2 ↓ + 2NH4Cl BaCl2 ↓ + 2NH3 + 2H2O
BaCl2 ↓ + (NH4)2CO3 BaCO3 ↓(putih) + 2NH4Cl
b. ↓ + CH3COOH/ HCl BaCO3 ↓ + 2CH3COOH Ba(CH3COO)2 ↓ + H2O +
CO2
larut atau

BaCO3 ↓ + 2HCL BaCl2 + H2CO3


2. a. S + NaOH ↓ putih BaCl2 + 2NaOH Ba(OH)2 ↓(putih) + 2NaCl
b. ↓ + NaOH # larut Ba(OH)2 ↓ + NaOH 4OH + BaNa2
3. a. K2CrO4 ↓ kuning BaSO4 + K2CrO4 BaCrO4↓ kuning + K2SO4
b. ↓ + HCl larut BaCrO4 ↓ + HCl BaCl2 + H2Cr2O7 + H2O
4. a. S + H2SO4 ↓ putih BaCl2 + H2SO4 BaSO4 ↓ (putih) + 2HCl
b. HCl/ HNO3 BaSO4 ↓ + 2HCl BaCl2 + H2SO4
# larut Atau
BaSO4 ↓ + 2HNO3 Ba(NO3)2 + H2SO4
5. a. S + (COONH4)2 BaCl2 + (COONH4)2 Ba(COO)2 ↓ (putih) +
↓ putih
2NH4Cl
b. ↓ + CH3COOH 4Ba(COO)2 ↓ + 7CH3COOH 4Ba(CH3COO)2 + 6CP2
larut
+ H2O

2
Ca2+ 1. a. S + NH4OH + NH4Cl + CaCl2 + 2NH4OH Ca(OH)2 ↓ + 2NH4Cl
(NH4)2CO3 ↓ putih Ca(OH)2 ↓ + 2NH4Cl CaCl2 ↓ + 2H2O + 2NH3
CaCl2 ↓ + (NH4)2CO3 CaCO3 ↓ (putih) + 2NH4Cl
b. ↓ + HCl larut CaCO3 ↓ + 2HCl CaCl2 + H2CO3
2. a. S + NaOH ↓ putih CaCl2 + NaOH Ca(OH) ↓ (putih) + 2NaCl
b. ↓ + NaOH # larut Ca(OH) ↓+ 2NaOH CaO2 + 2H2O + 2Na
3. a. S + (COONH4)2 CaCl2 + (COONH4)2 Ca(COO)2 ↓ (putih)+ 2
↓ putih
NH4Cl
b. ↓ + CH3COOH Ca(COO)2 ↓ + 2CH3COOH Ca(COOH)2 +
# larut
2COOCH3
c. ↓ + HCl larut Ca(COO)2 ↓ + 2HCl CaCl2 + 2HCOO
4. S + NH4Cl + K4Fe(CN)6 4CaCl + 4NH4Cl + 3K4Fe(CN)6 4Ca(NH4) +
↓ putih
3Fe(CN)6 + 12KCl
5. S + H2SO4 Pekat ↓ putih CaCl2 + H2SO4 pekat CaSO4↓ putih + 2HCl

Sampel Prosedur Pengamatan Reaksi


Mg 2+
MgSO4 + 2NH4OH Mg(OH)2 ↓ (putih) +
↓ putih
1. a. S + NH4OH Pekat (NH4)2SO4
b. ↓ + NH4Cl larut Mg(OH)2 ↓ + 2NH4Cl MgCl2 + 2NH3 + 2H2O
2. a. S + NaOH ↓ putih MgSO4 + 2NaOH Mg(OH)2 ↓ putih + Na2SO4
b. ↓ + NaOH # larut Mg(OH)2 ↓ + 2NaOH Na2MgO2 + H2O
3. S + Na2CO3 ↓ putih MgSO4 + NaCO3 MgCO3 ↓ putih + Na2SO4
4. S + NH4OH + NH4Cl +
Na3PO4 ↓ putih MgSO4 + 2NH4OH Mg(OH)2↓ putih + (NH4)2SO4

5. S + (NH4)2CO3 MgSO4 + (NH4)2CO3 MgCO3 # ↓ (putih) +


# ↓ putih
(NH4)2SO4
NH4+ 1. S + NaOH #↓ NH4Cl + NaOH NaCl + NH+H2O
2. S + dipanaskan a. bau NH4+ + dipanaskan bau

3
b. kertas
lakmus
NH4+ + dipanaskan kertas lakmus merah berubah
merah
jadi biru
berubah
jadi biru
3. S + KOH + K2HgI4 ↓ kuning- NH4+ + KOH + K2HgI4 NH2Hg2I3 + K+ 5KI +
coklat 2H2O
4. S + batang pengaduk
mengandung HCl pekat uap putih NH4+ + HCl NH4Cl + H+

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