Identifikasi dan Pemisahan Kation Golongan III

Cuplikan (larutan dalam air)

+ Larutan HCl 2M

Residu (Endapan ) (Kation golongan I) Filtrat

AgCl; PbCl2; Hg2Cl2 (Kationgolongan II - V)

+ Larutan H2S

Residu (Endapanhitam) (Kationgolongan II) Filtrat

HgS; Bi2S3; CuS; CdS; (Kationgolongan III - V)
As2S3; SnS; Sb2S3
 Filtrat Gol. III, IV, dan, V

Residu Gol. III [+] NH4OH + HCl + H2S

Filtrat Gol IV Al(OH)3;Cr(OH)3;
dan V FeS; MnS; CoS;
NiS [+] Larutan HNO3
[+] Larutan HNO4OH

Gol. III A
Al, Fe, Cr, Mn
Gol III B
[Zn(NH3)4]2, [Co(NH3)6]2+, NH4Cl 1% + 5-10 ml Air +
[Ni(NH3)6]2+ Natrium peroksoborat 1-1,5 gr
+ NaBO3.4H2O + 5ml NaOH +
[+] H2S 5ml H2O2 3% (panaskan)

Filtrat ZnS, MnS, CoS, NiS

Filtrat Cr &
[+] NH4Cl 1% + HCl 2M Residu Fe Al
Dan Mn

Filtrat
Residu CoS, NiS Mn, Zn [+] HCL encer +
(Endapan
beberapa tetes MnO4
hitam) [+] NaOH + 1ml H2O2 [Fe](CN)6]4- (mertua)
KSCN atau
3% (panaskan 3 menit) Fe4[Fe(CN)6]3 (biru) (lembayung)
[+] 1,5 ml K4[Fe(CN)]6
Naocl + 0,5
[+]HNO3 1ML +
ml HCL
H2O2 3-4 TETES +
Filtrat H2SO4 1 TETES +
[+] Amil Residu [Zn(OH)4]2- Natrium bismulat
Alkohol MnO2. XH2O
1ml +
NH4SCN [+] HNO3 5ml
[+]
[Ni(NH)3]6 1:1 + [+] H2SO4 encer +
HCl CH3CO CH3COOH
endapan beberapa kobalt asetat 0,5
Encer + OH +
+
[Co(SCN)4]2- merah tetes H2O2 H2S ml + [Hg(SCN)]
NH3 Timbal asetat
Biru 3% + NaBiO3 0,1 M 0,5 ml
encer
(Panask 0,05 gr
MnO4 ZnS
putih Zn[Hg(SCN)4] PbCrO4 Al(OH)3
ungu
biru Kuning Putih
 Persamaan Reaksi III A

1. Reaksi Mn
MnO2 + H2O2 + 2H++Mn2+ O2+ 2H2O {Larutan Lebayung}
2. Reaksi Fe (1)
Fe2+ + 2CN- Fe(CN)2
Fe(CN)2+ 4CN- [Fe(CN)6]4- {Larutan Merah Tua}
3. Reaksi Fe (2)
Fe2++ [Fe(CN)6]3- Fe3+ + [Fe(CN)6]4-

4Fe3+ + 3[Fe(CN)6]4- Fe4[Fe(CN)6]3 {Endapan Biru}

4. Reaksi Cr (1)
CrO42-+ 2H+ + 2H2O2 CrO5 + 3H2O {Endapan Kuning}
5. Reaksi Cr
CrO42- + Pb2+ PbCrO4

2PbCr4 + 2H+ ⇋ 2Pb2+ + Cr2O72-+ H2O {Lapisan Atas Biru}

6. Reaksi Al
[Al(OH)4]- + NH4+ Al(OH)3 + NH3 + H2O {Endapan Putih}

Persamaan Reaksi III B

1. Reaksi Co
Co2+ + 4SCN [Co(SCN)4]2- {Dalam suasana asam/netral berwarna biru}
2. Reaksi Ni
Ni2+ + NH4Cl + NH3 [Ni(NH3)6]2+ {Endapan Merah}
3. ReaksiMn
2Mn2+ + 5NaBiO3 + 14H+ 2MnO4- + 5Bi3+ + 5Na+ + 2H2O {LarutanUngu}

4. Reaksi Zn
Zn2+ + H2S + 2CH3COO- ZnS + 2CH3COOH {Endapan Putih}
5. Reaksi Zn (2)
[Hg(SCN) 4] + Zn2+ Zn[Hg(SCN) 4] {Endapan Biru Muda}