Principles of Heat Flow
Principles of Heat Flow
Introduction
• Heat transfer from a warmer fluid to a cooler fluid, usually through a solid wall
separating the two fluids, is common in chemical engineering practice. The heat
transferred may be
• latent heat accompanying a phase change such as condensation or vaporization or
• sensible heat from the rise or fall in the temperature of a fluid without any phase
change.
Typical Examples:
• Reducing the temperature of a fluid by transfer of sensible heat to a cooler fluid,
the temperature of which is increased thereby; condensing steam by cooling
water; and vaporizing water from a solution at a given pressure by condensing
steam at a higher pressure.
• All cases require that heat be transferred by conduction & convection.
Principles of Heat Flow 2
Typical Heat Exchange Equipment
• The sign of 𝑞𝑐 is positive and the sign of 𝑞ℎ is negative because warm fluid loses,
rather than gains, heat.
• The heat lost by warm fluid is gained by the cold fluid.
𝑞𝑐 = −𝑞ℎ
𝑚ℎ 𝐻ℎ𝑎 − 𝐻ℎ𝑏 = 𝑚𝑐 𝐻𝑐𝑏 − 𝐻𝑐𝑎 = 𝑞
• If only sensible heat is transferred and constant specific heats are assumed, the
overall enthalpy balance for a heat exchanger becomes
𝑚ℎ 𝐶𝑝ℎ 𝑇ℎ𝑎 − 𝑇ℎ𝑏 = 𝑚𝑐 𝐶𝑝𝑐 𝑇𝑐𝑏 − 𝑇𝑐𝑎 = 𝑞
• Where 𝐶𝑝𝑐 = specific heat of cold fluid , 𝐶𝑝ℎ = specific heat of hot fluid
• For a condenser
𝑚ℎ 𝜆 = 𝑚𝑐 𝐶𝑝𝑐 𝑇𝑐𝑏 − 𝑇𝑐𝑎 = 𝑞
where 𝑚ℎ = rate of condensation of vapor and
𝜆=latent heat of vaporization of vapor
• The assumption for the above equation is that the vapor enters the condenser as
saturated vapor (no super heat) and the condensate leaves at condensing
temperature without being further cooled.
• If the sensible heat effects are to be considered, for example, if the condensate
leaves at a temperature 𝑇ℎ𝑏 that is less than 𝑇ℎ , the condensing temperature of
the vapor must be written as:
𝑚ℎ [𝜆 + 𝐶𝑝ℎ 𝑇ℎ − 𝑇ℎ𝑏 ] = 𝑚𝑐 𝐶𝑝𝑐 𝑇𝑐𝑏 − 𝑇𝑐𝑎
• where 𝐶𝑝ℎ = specific heat of the condensate
Principles of Heat Flow 9
Heat flux
• The rate of heat transfer per unit area is called as heat flux. The flux varies with
temperature drop ∆𝑇. Where ∆𝑇 is overall local temperature difference
• Δ𝑇 = 𝑇ℎ − 𝑇𝑐
• Where
• 𝑇ℎ = average temperature of the hot fluid
• 𝑇𝑐 = average temperature of the cold fluid